CA1052158A - Process for forming a layered paper web having improved bulk, tactile impresion and absorbency and paper thereof - Google Patents

Process for forming a layered paper web having improved bulk, tactile impresion and absorbency and paper thereof

Info

Publication number
CA1052158A
CA1052158A CA251,213A CA251213A CA1052158A CA 1052158 A CA1052158 A CA 1052158A CA 251213 A CA251213 A CA 251213A CA 1052158 A CA1052158 A CA 1052158A
Authority
CA
Canada
Prior art keywords
web
fabric
sheet
stratified
bulky
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA251,213A
Other languages
French (fr)
Inventor
George Morgan (Jr.)
Thomas F. Rich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Application granted granted Critical
Publication of CA1052158A publication Critical patent/CA1052158A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/006Making patterned paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/02Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
    • D21F11/04Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type paper or board consisting on two or more layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • Y10T428/24455Paper
    • Y10T428/24463Plural paper components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24661Forming, or cooperating to form cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities
    • Y10T428/24678Waffle-form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities
    • Y10T428/24694Parallel corrugations
    • Y10T428/24711Plural corrugated components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities
    • Y10T428/24694Parallel corrugations
    • Y10T428/24711Plural corrugated components
    • Y10T428/24727Plural corrugated components with planar component

Abstract

PROCESS FOR FORMING A LAYERED PAPER WEB HAVING IMPROVED
BULK, FLEXIBILITY, TACTILE IMPRESSION AND ABSORBENCY
AND PAPER THEREOF

Abstract of the Disclosure A wet-laid composite, soft, bulky and absorbent paper structure is prepared from two or more layers of furnish which are preferably comprised of different fiber types. The layers may be formed from the deposition of separate streams of dilute fiber slurries, the fibers typically being relative-ly long softwood and relatively short hardwood fibers as used in tissue papermaking. The layers are combined to form a unitary web, and the layered, unitary web is de-watered. The moist, layered web is thereafter transferred to an open mesh drying/imprinting fabric. The application of a fluid force to the web creates patterned discrete areas of fibers numbering from about 100 to about 3600 per square inch of projected surface area on the side of the web which contacts the drying/imprinting fabric. These layered structures exhibit significantly improved bulk, flexibility, compressibility, drape and absorptive capacity when compared to prior art paper sheets formed by similar processing tech-niques from a single slurry comprised of a homogeneous mixture of similar fibers. In addition, the structures which are stratified with respect to fiber type typically yield finished paper sheets having significantly improved tactile impression and softness.

Description

Field of the Invention __ .
The present invention relates to improvements in . .
wet-laid and non-woven web manufacturing operations, especially those utilized :Eor producing soft, bulky, and absorbent paper sheets suitable for use in tissue, towelling and sanitary products. In particular, the present invention relates to the provision of a layered composite web formed .~
from individual fiber slurries, said layered web being sub- ~-sequently caused to conform to the surface of an open mesh drying/imprinting fabric by the application of a fluid ~-force to the web and thereafter thermally predried on said fabric as part of a low-density papermaking process. The layered web may be stratified with respect to fiber type or :-~
the fiber content of the respective layers may be essentially the same.

; ~ ~
'' :`1 , ` 20 , ~'.

.' ~', ;.

.: '~, ,:.
~:~
- 2 -, '. ~ :
. , ~ . . . ~. . .

:1~35~58 Unexpectedly, sheets produced by processing a moist, layered paper web as described herein exhibit improved bulk and caliper when compared to similarly-processed,non-layered structures comprised of a homogeneous mixture of similar S fibers. In addition, paper sheets of the present invention are generally perceived as having improvements in softness and tactile impression, particularly on the surface of the sheet having discrete patterned arrays of fibers extending out-wardly therefrom, along with improved overall flexibility ;
and drape. Because of their greater void volume, i.e.,lower overall density, layered paper sheets of the present invention also have particular relevance to sdt, bulky paper sheets exhibiting improved absorptive capacity.

, :
BACRGROUND OF THE INVENTION
In the conventional manufacture of paper sheets `; - for use in tissue, towelling and sanitary products, it is - customary to perform, prior to drying, one or more overall pressing operations on the entire surface of the paper web as laid down on the Fourdrinier wire or other forming surface.
- 20 Conventionally, these overall pressing operations involve subjecting~
a moist paper web supported on a papermaking felt to pressure developed by opposing mechanical members, for example, rolls.

Pressing generally accomplishes the triple function of mechanical water expulsion, web surface smoothing and tensile strength development. In most prior art processes, the , pressure is applied continuously and uniformly across the ; entire surface of the felt. Accompanying the increase in tensile strength in such prior art papermaking processes, however, i5 an increase in stiffness and overall density.

. .

~ - -3-1 ir ~ 5 ;~1 .
Furthermore, the softness o e such conventionally formed, pressed and dried paper webs is reduced not only because their stiffness is increased as a result of increased interfiber hydrogen bonding, but also because their compress-ibility is decreased as a resuit of their increased density.
Creping has long been employed to produce an ~-action in the paper web which disrupts and breaks many of the interfiber bonds already formed in the web. Chemical treatment of the papermaking fibers to reduce their interfiber bonding capacity has also been employed in prior art papermaking techniques.
A significant advance in producing lower density pape~ sheets, however, is disclosed in U.S. Patent 3,301,746 which issued to Sanford et al. on January 31, 1967, said patent being hereby incorporated herein by reference. The aforesaid patent discloses a method of making bulky paper sheets by thermally predrying a web to a predetermined fiber consistency while supported on a drying/imprinting fabric and ~,, .
'l impressing the fabric knuckle pattern in the web prior to final drying. The web is preferably subjected to creping on the dryer drum to produce a paper sheet having a desirable combination of softness, bulk, and absorbency characteristics.
Other papermaking processes which avoid compaction of the entire surface of the web, at least until the web has been thermally predried, are dlsclosed in U.S~ Patent
3,812,000 which issued to Salvucci, Jr. et al. on May 21, 1974; U.S. Patent 3,821,068 which issued to Shaw on :: .
. '
-4- -. . .

., ' .
- . . . . . - .
. . . :. . -3~

June 28, 197~; and U.S. Patent 3,629,056 which issued to Forrest on December 21, 1971.
All of the aforementioned patents disclose low-density papermaking processes and products wherein the web is not stratified. Applicants, however, have unexpectedly ~
discovered that layering of papermaking fibers to form a ~ -stratified web can be employed to particular advantage when ;~
utilized in combination with such low-density papermaking processes. This is accomplished by subjecting the web to a fluid Eorce while supported on an intermediate drying/
imprinting fabric at relatively low fiber consistencies to produce soft, bulky and absorbent paper sheets of unusually high caliper and unusually low density, said paper sheets being particularly suitable for use in tissue, towelling and similar products. ~ ;
Accordingly, it is an object of the present invention `~
to provide an improved soft, bulky and absorbent paper sheet formed by layering similar or dissimilar fiber types, said paper sheet being characterized by an unexpectedly lower density than similarly-produced, non-layered, prior art paper structures comprised of a homogeneous mixture of similar papermaking fibers.
- ~ SUMMARY OF THE INVENTION .
~ The present invention relates to a soft, bulky and , absorbent unitary paper sheet having a basis weight of from " about 5 to about 40 pounds per 3,000 square feet, as measured in an uncreped state, said sheet being characterized by having a structure which in cross-section comprises at least two superposed stratified fibrous layers in contacting ;~relationship for a major portion of their areas, at least one of said stratified fibrous layers being partially ;~

A -~:-. . , ~5;~158 displaced in a plane perpendicular ko said sheet in small discrete deflected areas corresponding to the mesh openings in a foraminous fabric and comprising from about 100 to about 3,600 individual de~lected areas per square inch, ~ ~
as measured in an uncreped state. ~ :.
In a particularly preferred embodiment of the present invention, a soft, bulky and absorbent paper sheet is pro-vided, said sheet having one surface thereof comprised primarily of relatively long papermaking fibers and the opposite surface thereof comprised primarily of relatively short papermaking fibers, said sheet exhibiting an unexpect- ~
edly lower density than a similarly-produced, non-layered ~ :.
~: prior art paper sheet comprised of a homogeneous mixture of said long and short papermaking fibers, without a correspond-~ ing loss in overall tensile strength.

: 20 "' ' ' , ~ 30 ''`;: ~"
- 6 ~

,~S~ 8, In general, soft, bulky and absorbent paper sheets of the present invention are produced by forming a moist paper web comprising at least two superposed stratified layers in contacting. relationship, supporting said web on a foraminous drying/imprinting fabric, subjecting said web to a pressure differential while on said fabric, thereby dis- :~
placing at least one of said stratified layers in a plane perpendicular to said sheet in small discrete deflected areas ~ .
corresponding to the mesh openings in said fabric, and final drying said sheet without disturbing the aforesaid deflected areas.

. ~
BRIEF ~ESCRIPTION OF T~E DRA~INGS
While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter which is regarded as the present invention,~
; it is believed that the invention will be better understood from the following description taken in connection with the ` accompanying drawings, in which: .
..:
?

Figure 1 is a schematic illustration of a preferred embodiment of a papermaking machine suitable for producing ~` a low-density, two-layered paper sheet of the present invention;

,1 ,, Figure 2 is a cross-sectional photograph enlarged about 20 times actual size of a handsheet taken at a point corresponding to that of section line 3-3 in Figure 1 and illustrating generally the degree of molding or penetration of the drying/imprinting fabric by a , -7~
-' l;O~'~lS8 non-layered prior art paper web comprised of a homogeneous-mixture of relatively long softwood pulp ancl relatively short hardwood pulp ~ibers;

.
.
Figure 3 is a cross-sectional photograph enlarged ~ 5. about 20 times actual size of a handsheet taken at a point - corresponding to that of section line 3-3 in Figure 1 illustrating the degree of molding or penetration of the drying/imprinting fabric by a.stratified web comprised primarily of relatively short hardwood pulp fibers on the surface of the web in contact with the clrying/imprinting fabric and primarily of relatively long ~oftwood pulp fibers on its opposite surface;
; , Figure 4 is a photographic plan view enlarged about 20 times actual size of the fabric side of a prior art creped paper sheet processed generally in accordance with the teachings of U. S. Patent 3,301,746, said sheet ~-being formed from a single, homogeneousiy mixed slurry ~:
containing approximately 50 percent softwood and 5n ;, . percent hardwood fibers; ~-:

' ::
~ 1 .
., ~ , . ~

" , , ~: '' .~..... .. . .
. - .. . . . . .

~~ 5~3 Figure 5 is an enlarged photographic sectional view of the creped paper sheet shown in Figure 4 taken looking ~n the cross-machine direction along section line 5-5 in Figure 4;

S Figure 6 is a photographic plan view enlarged about 20 times actual size of the fabric side of - ~ne embodiment of a layered,creped paper sheet of the presPnt invention produced generally in accordance with the process illustrated in Figure l, said shee~ being formed from two identical slurries of essentially the same fiber content, each slurry containing approximately 50 percent softwood and 50 percent hardwood fibers in a homogeneous mixture.

.
: Figure 7 is an enlarged photographic sectional view of the layered, cre~ed paper sheet shown in Figure 5 taken looking in the cross-machine direction along section line 7-7 in Figure 6;
. . .
,' ' ' ' .
Figure 8 is a photographic plan view enlaxged about 20 times actual size of the fabric side of another ~;
embodiment of a layered,creped paper sheet of the present ~
20 - invention produced generally in accordance with the : ~;
process illustrated in Figure 1, said sheet being formed from a slurry of softwood fibers on its fabric sid~ and -.
a slurry of hardwood fibers on its wire side, the total fiber content of said sheet being approximately 50 percent 2S softwood and 50 percent hardwood fibers; . ~

. ,' '::'; ` 1- :

~?5~1C~8 Figure 9 is an enlarged photographic sectional .t view of the layered, creped paper sheet shown in Figure 8 ta~.en looking in the cross-machine direction along section line 9-9 in Figure 8;

Figure 10 lS a photographic plan view enlarged about 20 times actual size of the fabric side of another embodiment of a layered,creped paper sheet of the present invention produced generally in accordance with the process illustrated in Figure 1, said sheet being formed from a slurry of softwood fibers on its wire side and a slurry of hardwood fibers on its fabric side., the total fiber content of said sheet being approxima~ely 50 percent softwood and 50 percent hardwood fibers;
~' .
Figure 11 is an enlarged photographic sectional view of the layered, creped paper sheet shown in Fi~ure 10 taken looking the cross-m~chine direction along section line ~ 11 in Figure 10;
... 1 ~.
i Figure 12 is a photographic plan view enlarged about 2~ times actual size of the fabric side of arl 2C uncreped,layered paper web of the present invention having a fiber composition and layer orientation similar to that .:.. . . .
of the paper sheet shown in Figure 10, said web having been removed from the drying/imprinting fabric prior to , , , compaction thereof between the knuckles .of the fabric .
; 2 and the dryer drum; ;~

:' :.

,'`'~
'.
.
- ~
, --1 0-- , , . ::
: . . - , .

~3~
- , Fi~ure 13 is an enlarged~photographic sectional ' view of the uncreped, layered paper web shown in Figure 12 taken looking in the cross-machine direction along section line 13-13 in Figure 12;

Figure 14 is a photographic plan view enlarged about 20 times actual size of the fabric side of a layered paper web of the type shown in Figure 12, said web having been compacted between the knuckles of a drying/imprinting ~abric and a dryer drum, finally dried and creped;

: . - .
~i~ire 15 is an enlarged sectional view of the creped paper sheet shown in Figure 14 taken looking in~ ;
~:
~he cross-machi.ne direction along section line 15-15 in ~igure 14;

Figure 16 is a photographic perspective view~ ~
15 enlarged about 100 times.actual size of one of the volcano- - :
like cone structures formed in an uncreped, layered paper : web of the present invention; and Figure 17 is a fragmentary schematic illustration of a preferred embodiment of a papermaking machine suitable for ., :.: ..
20 producing a low-density, three-layered fibrous web of the ~.
present invention.

, . .
:- ,. .. .:
, . --1 1-- .
,' ' ' ~.
, , - .
5'~
DESCRIPTIO~ OF T}~E PREFERRED'''EMBODIM:ENTS - ~' Figure 1 is a schematic illustration of a preferred embodiment of a papermaking machine for forming a low-density, multi-layered paper sheet of the present invention.
m e basic layout of the pap~rmaking machine illustrated in Figure 1 is generally in accordance with the teachings of U. S. Patent 3,301,746 which issued to Sanford et al. on January 31, 1967. The papermaking machine illustrated in Figure 1, however, employs an additional headbox and ~orming-system to enable formation of a fibrous web which may be stratified with respect to fiber type.
In the embodiment illustrated in Figure 1, a papermaking furni h comprised primarily of relatively long papermaking fibers, i.e., pre~erably softwood pulp ~ibers having an alverage length of at least about 0.08 inches, and preferably between about 0.08 inches and about 0.1~ inches, is delivered from a headbox l to a fine mesh Fourdrinier wire 3 supported by a breast roll 5. A moist paper web 25 comprised of said long papermaking fibers is formed, and the Fourdrinier wire 3 passes over forming boards 13 and 14, which are de-sirable but not necessarv. The paper web 25 and the Fourdrinier wire 3 then pass over a plurality of vacuum boxes 18 and 20 to remove water from the web and increase the web's fiber consistency.
A secondary papermaking furnish com-prised primarily of relatively short papermaking fibers, i.e., preferably hardwood pulp fibers having an average length between about 0.01 inches and about 0.06 inches, is delivered from a second headbox 2 to a second fine mesh Fourdrinier wire 4 supported by a breast roll 3. A second moist ; 30 paper web 26 comprised of said short papermaking fibers is `~; formed, and the Fourdrinier wire 4 passes over forming boards - -. , , ., - : .
,.-: . . . : :
::: ::: :

s~

15 and 16 and a plurality of vacuum boxes 22 and 2~ to i~ease---the web's fiber consistency.
~he moist hardwood web 26 and Fourdrinier wire 4 there-after pass around Fourdrinier wire return rolls 10 and 11, S and the outermost surface of web 26 is preferably brought i~to intimate contact with the outêrmost surface of the softwood web 25 while each of said webs is at the lowest feasible fiber ~: .
consistency to encourage effective bonding between the webs.
e aforesaid transfer preferably occurs at fiber con-sistencies between about 3 percent and about 20 percent. At fiber consistencies lower than about 3 percent, an uncompacted paper web is easily damaged during transfer from a fine mesh -~
Fourdrinier wire to the surface of another fibrous web, while .; ~
. at fiber consistencies above about 20 percent, it becomes more difficult to securely bond the respective layers into a unitary structure merely by the application of fluid pressure thereto.
;~ Transfer of the hardwood web 26 to the outermosi surface of the softwood web 25 1S preferably accomplished by - the application of vacuum. If desired, steam jets, air jets, etc. may be employed either alone or in combination `~
with vacuum to effect transfer of the moist web. As .~ :
` illustrated in Figure 1, this is accomplished, in a preferred embodiment o~ the present invention, i'ntermediate a stationary vacuum transfer box 6 and an optional slotted steam nozzle 53.
At this point the moist hardwood web 26 is transferred from the uppermost Fourdrinier wire 4 to the outermost surface of the moist softwood web 25 to form a composite web 27 which is essentially stratified with respect to fiber type. Subsequent -~
.

. :

, .
. .

-13- ;

..... .. .. .. . .
" . . ` ' ~.' . . ,. ' - . . . , ' ,~ , 5~3 to the transfer, the composite web 27 is passed over a plu~aiity-of vacuum boxes 29, 31 and 33 to increase its overall fiber consistency and form it into a unitary structure. The uppermost Fourdrinier wire 4, after transfer of the hardwood S web 26, passes around Fourdrinier wire return roll 12 and, after suitable cleaning, guiding and tensioning which are not shown, returns to the uppermost breast roll 9.
. ' ' .
A~ is illustrated in Figure 1, the composite web 27 i5 carried on Fourdrinier wire 3 Around wire return roll ; 10 7 and is brought in contact with a coarser mesh drying/imprinting fabric 37 which has its undersurface 37b con~iguous to a vacuum pickup shoe 36 in such a manner that the uppermost surface 2ia of the composite paper web 27, i.e., the surface containing primarily short papermaking fibers, is placed in contact with the web supporting surface 37a of the drying/
imprinting fabric 37. If desired, a slotted steam no~zle 35 may be provided to assist in transferring the web to the abric. The ~urface of the web 27a contacting the web su~portinq surface 37a of the fabric 37 shall, for convenience, :. 20 -hereinafter be referred to as the fabric side of the web, while the surface of the web contacting the Fourdrinier wire 3 shall hereinafter be referred to as the wire side 27b of the web.

Because the bulk and caliper increases obtained in ; ~5 multi~layered sheets produced in accordance with the present `~ invention is derived primarily from reorientation and penetra-tion of the fibers on the fabric side of the composite web 27 into th~ mesh openings of the drying/imprinting fabric 37, transfer of the composite moist paper web 27 from the Fourdrinier wire 3 to the fabric 37 y . : ~

is extremely critical. Applicants have learned that a significant degree of fiber reorientation and fiber penetration into the mesh openings of the drying/imprinting fabric 37 can generally be achieved utilizing a vacuum pickup shoe 36, as S shown in Figure 1, at composite web fiber consistencies between about 5 and about 25 percent. At fiber consistencies lower than about 5 percent, the composite web 27 possesses little strength and is easily damaged during transfer from the fine mesh Fourdrinier wire to the coarser mesh drying/imprinting fabric merely by application of fluid pressure in the form of vacuum, steam jets, air jets, etc.

~ ~ .
Where vacuum is employed, the vacuum applied to ; the web should be sufficient to cause the fibers on the fabric side of the web to reorient themselves and to penetrate the fabric mesh openings, yet not excessive so as to remove :.!
a significant quantity of fibers from the fabric side of the web by pulling them completely through the fabxic mesh -, openings and into the vacuum pickup shoe. While th~ actual level of vacuum applied to the web to~achieve the desired 20 degree of fiber reorientation and fiber penetration will vary, depending upon such factors as web composition, pickup shoe design, machine speed, fabric design and mesh count, fiber consistency at transfer, etc., applicants have typically .: .
obtained good results utilizing vacuum levels between` ~ `-about 5 and about 15 inches of mercury.

,::

,"" ::

~ . = . , ... . .. . .

~C3S'~L58 'J While applicants do not wish to be held to this theory, the greater degree of fiber reorientation and fiber penetration which account for the increase in caliper, i.e., the decrease in density, of multi-layered paper sheets i of the present invention is believed to be due to the tendency of the layers of composite webs to separate from one another and react as a series of weaker independent webs while moist, at least in respect to deflection and/or re-positioning of the fibers thereof. Thus, the application l of fluid pressure to a layered paper web at relatively low fiber consistency while the web is being supported on a drying/imprinting fabric results in a greater degree of penetration into the mesh openings of the fabric by the fibers in contact therewith.

Figure 2 is a cross-sectional photograph enlarged `~
about 20 times actual size of a non-layered prior art handsheet 55 comprised of a homogeneous mixture of relatively long papermaking fibers and relatively short papermaking fibers, said cross-sectional view being taken ~ at a point corresponding to that of section line 3-3 in Figure 1. The particular drying/imprinting fabric shown is of the semi-twill variety, said fabric having been treated generally in accordance with the teachings of the commonly owned Canadian patent 1,007,911, granted April 5, 1977. ~;
~ ~.'' ., - `
.
; A ~:
.. ~ ,.. ..
.. , .. . . . . . .

The same basic principles are, however, equally applicable to any foraminous fabric suitable for thermally predrying and/or imprinting a web generally in ac~ordance with the teachings of the aforementioned patent to Sanford et al.
The enlarged cross-section of Figure 2 illustrates the tendency of a prior art non-layered web to behave as a unitary :
structure and the tendency of the relatively long, randomly distributed papermaking fibers on the fabric side ~i 55a of the web to bridge across the fabric mesh openings formed by intersecting and adjacent woof and warp monofila- . -ments. As can also be seen in Figure 2, the wire side 55b of the .
non-layered web 55 remains substantially planar and continuous.

In accordance with the fabric terminology utilized herein, woof filaments are those extending generally in the cross~
`? ~
machine direction, while warp filaments are those extending ;.

; generally in the machine directlon.
'''. ' '' ~

- Figure 3 is a-cross-sectional photograph enlarged about 20 times actual size of a layered handsheet 27 of o the present invention, said cross-sectional view being taken at a point corresponding to that of section line 3-3 in Figure 1. The short-fibered portion 26 of the composite .
web 27 is partially displaced in a plane perpendicular . to the web in small discrete deflected areas corresponding to the mesh openings in the drying/imprinting fabric, while ~ the long-fibered portion 25 remains substantially planar `
-. and continuous, thus providing strength and integrity in ~"
; '' ~

. ~ -17-, .. . . . . .

5~
the resultant paper sheets 27. ~ shoul~ be apparent fro~- -- -Fi~ure 3 7 the short papermaking Fibers on the surface of the web in contact with the web supporting surface 37a of the drying/imprinting fabric 37 have less tendency to bridge across the mesh openings in the fabric.
.

In a particularly preferred embodiment of the present invention, tne fabric is characterized by a diagonal free span, i.e., the planar distance as measured from one corner of a projected fabric mesh opening to its diagonally opposite corner, between about 0.005 inches and about 0.080 inches, most preferably between about 0.009 inches and about 0.054 inches, and a fabric mesh count of between about 100 and about 3,600 openinss per square inch, i.e., said fabric having between about 10 and about 60 filaments 15 per inch in ~oth the machine and cross-machine directions. ;
Particularly advantageous results have been obtained in the practice of the present invention with the knuckle -pattern produced by the back side of a semi-twill drying/
imprinting fabric of the type shown in Figures 2 ~nd 3 ~` 20 In a long-fibered/short-fibered web embodiment of the type shown in Figure 3, it is ~referable that the diagonal free span of the drying/imprinting fabric be less than about the average fiber length in the short-fibered strata of the web. If the diagonal free span is greater than the average fiber length in the short-fibered strata of the web, , . .

.`~' . ' .

-~()5~
. . the fibers are too easily pulled ~hrough the fabric mesh .. ~.... .

openings when subjected to fluid pressure, thereby detracting .
from the bulk and caliper of the finished sheets. On the other hand, the diagonal free span of the fabric is preferably greater than about one third, and most preferably greater than about one half, the average fiber length in the short-fibered :
strata of the web in order to minimize bridging of the short fibers across the fabric filaments. In addition, the diagonal .~ free span of the fabric is preferably less than about one third : 10 the average fiber length in the long-fibered strata of the web in :;
oxder to encourage bridging of the long fibers across at least one . .
.. pair of fabric filaments. Accordingly, in.a web embodiment.of the ~ .
type shown in Figure 3,.the short fibers tend to reorient them~
j selves and penetrate the fabric mesh openings during transfer of .l lS the moist stratified web to the drying/imprinting fabric while .

~j t:he long fibers tend to bridge the openings and remain ., .
. substantially planar. ~ .

As has been alluded to earlier herein, the patterned discrete areas which correspond to the fabric mesh openings . 20 and which extend outwardly from the fabric side of a web of .
... . .
the type generally shown in Figure 3 typically assume the .: ~

~ form of totally enclosed pillows, coni$ally grouped arrays : :

-:. of fibers, or a combination thereof. The wire side of the . web which remains substantially continuous and planar ~~ ~

exhibits an uninterrupted patterned surface similar to the ~ ! ;

. textile pique'.

Figure 12 is a plan view photograph enlaxged about 20 times actual size of the fabric side 100a of an uncreped, . layered paper web 100, of the type generally described above, .

30 said web having been subjected to fluid pressure and thermally predried on a 31 X 25 semi-twill drying/imprinting fabric : . .

lSI~
prepared as described in the aforementioned patent appli~ation of Peter G. Ayers and removed from the fabric prior to ; compaction thereof between the knuckles of the fabric and the dryer drum. The web 100 is comprised of appr~ximately 50 percent softwood fibers and 50 percent hardwood fibers, the hardwood fiber strata 103 (Figure 13) being located on the ~abric side lOOa of the web and the softwood strata 102 being located on the wire side lOOb of the web. The impressions 104 of the woo monofilaments extendlng generally in the cross-machine direction and the impressions 105 of the warp monofilaments extending generally ~;
in the machine direction are both clearly apparent in Figure 12. As is also apparent from Fi~ure 13, discrete areas of the short-fibered strata 103 are perpendicularly deflected from the long-fibered strata 102 of the web, said :
- discrete areas exhibiting a ~endency to wrap themselves - about the filaments of the fabric when subjected to fluid ~i , ;' pressure to form volcano-like cone structures 101 comprised , primarily of short fibers extending in a direction generally : i .
- 20 perpendicular to the web. Figure 16 is a perspect~ve photo-graphic view enlarged about 100 times actual size of a volcano-like cone structure 101 of the type formed in the hard-wood strata 103 of the substantially uncompacted, layered paper web 100 shown in Figures 12 and 13. The continuity of the softwood strata 102 at the base of the volcano-like structure is clearly visible. Thus the abric side of the resultant layered paper web exhibits the negative image of the we~ supporting su ff ace of the drying/imprinting fabric, while the pi~ue'-like wire side o the layered paper web ;
exhibits, at least to an extent, the positive image of the ~ web supporting surface of the fabric.

,. . , `
~ - 20 Because the long-fibered ~rata o~ t~e stratified-~eb --I
remains substantially continuous and planar, the overall ~ -tensile strength and integrity of the resulting finished paper sheets do not differ significantly from similarly- -produced non-layered sheets formed from a single homogeneously ;~
mixed slurry of similar fibers. The reorientation and deflection of discrete arrays of short fibers i~ a ~irection perpendicular to the plane of the web does result, however, - in a significant increase in the overall bulk and caliper o~
such layered paper sheets. ~ecause of their greater - interstitial void volume, i.e., lower overall density, the layered sheets exhibit improved total absorptive capacity in addition to improved flexibility, drape and compressibility.
Such finished paper sheets are also generally perceived as ; having significantly improved tactile impression on the fabric side of the web, as well as improved overall softness.
This is believed due not only to the reorientation and isolation of the short fibers on the fabric side of the web, but also to the overall reduction in web density. As can be seen in Figure ,' 20 13, such layered sheets exhibit a density gradient from one - side of the sheet to the other, resulting in a liquid ab-sorption gradient which makes one side of the sheet feel drier to the touch than the other side. This is due to the fact that liquid is transmitted by capillary attraction from the less dense short-fibered side of the sheet to the more dense long- -, . , `j fibered side of the sheet and is retained therein due to the existence of a avorable capillary size gradient between the ; two layers.
i While long-fibered/short-fibered webs of the type generally shown in Figure 3 represent a most preferred :
embodiment of the present invention, applicants have .
, . ` . , . , ,:,~

- , . _ 1~5~
unexpectedly discovered that similar improvements in bulk and caliper may also be obtained, although to a lesser degxee, by layering homogeneously mixed stratas of long and short fibers on one another as shown in Figures 6 and 7, by S layering identical long-fihered stratas on one another~
by layering identical short-fibered stratas on one another, and even by layering long and short papermaking fibers in the reverse order from that described above, i.e., so that the long-fibered strata is on the fabric side of the web as shown in Figures 8 and 9. It should be noted~ however, that when the fiber content of the strata in contact with the drying/
imprinting fabric, i.e., the fabric side of the web, is essentially the same as that of the strata opposite the drying/imprinting fabric, i.e., the wire side of the web, both stratas may be generally displaced in a plane perpendicu-lar to the sheet. In the latter situation, the patterned dis-crete areas of fibers extending outwardly from the fabric side of the sheet may create discontinuities which extend throughout the entire thic~ness of the web, which discontinuities are more clearly apparent from both sides of the resultant paper structure.

The latter embodiments of the present invent~on are, however, generally less preferred since, in most instances, they fail to exhibit all of the other unique properties exhibited by long-fibered/short-fibered stratified webs of the type ~ generally shown in Figure 3.

.
; Following transfer of the composite paper web 27 to the drying/imprinting fabric 37, ;~;
the Fourdrinier wire 3 is passed about wire return roll 8, throuah suitable cleaning, guiding and tensioning apparatus which are not shown,and back to the lowermost breast roll 5.
- ~

~C)S~15~
The drying/imprinting fabric 37 and the layered paper web 27 are directed about directon-changing roll 38 and pass through a hot air, blow-through dryer illustrated schematic-ally at 45 and 46, where the layered paper web is thermally predried without disturbing its relationship to the drying/
imprinting fabric 37. Hot air is preferably directed from the wire side 27b of the layered paper web 27 through the web and the drying/imprinting fabric 37 to avoid any adverse effect on penetration of the fabric mesh openings by the relatively short papermaking fibers located on the fabric side 27a of the web. U.S. Patent 3,303,576 which issued to Sisson on February 14, 1967 discloses a preferred apparatus for thermally predrying the layered paper web 27.
Although the exact means by which thermal predrying is accomplished is not critical, it is critical that the relationship of the moist paper web 27 to the drying~imprint- ;
ing fabric 37 be maintained once established, at least : . , while the web is at relatively low fiber consistency.

According to U.S. Patent 37301,746, thermal predrying is preferably used to effect a web fiber consistency : . -- in the moist paper web of from about 30 percent to about 80 percent. Based on U.S. Patent 3,926,716, issued December 16, 1975, it is now known that web fiber consistencies as high as about 98 percent are feasible.

, ': ,', ~

~ . , : . .
.; , : : ~

' ' ' ~. ,''~ ~

.~ , ., ,: ~ . . . - :

~05;~:1SB
.
Following thermal predrying to the desired fiber ~ ~
consistency, the drying/imprinting fabric 37 and the thermally ~ :
predried, composite paper web 27 pass over a straightening : -roll 39 which prevents the formation of wrinkles in the drying/imprinting fabric, over a fabric return roll 40, and preferably onto the surface of a Yankee dryer drum 50.
Spray nozzles 51 are preferably utilized to apply a small amount of adhesive to the surface of ihe dryer drum 50, as is more fully described in U. S. Patent 3,926,716. The fabric knuckles on the web supporting surface 37a of the : 15 drying/imprinting fabric 37 are, in a preferred embodi-: ment of the present invention, utilized to compact discrete portions of the thermally predried, paper web 27 by passing the .
fabric and the web through the nip formed between a pressure roll 41 and the Yankee dryer drum 50. The drying/imprinting ; 20 fabric 37, after transfer of the web to the Yankee dryer `
: drum 50, returns to the vacuum pickup shoe 36 over fabric return . ~::
` rolls 42, 43, and 44, said drying/imprinting fabric being :
washed free of clinging fibers by water sprays 47 and 48 and . 25 dried by means of a vacuum box 49 during its return. After com- : .
:~ paction between the fabric knuckles and the dryer drum, the thermal~
predried, layered paper web 27 continues from the nip formed ~;~ between the pressure roll 41 and the Yankee dryer drum 50 along the periphery of the Yankee dryer drum 50 for firal drying and is preferably creped from ~he Yankee surface by means of a doctor blade 52.

: ~'':, ~ -2~
. . , ,~. , , - , . , . , . . ,, - :

5;~S8 In yet another embodiment of the present invention, the compaction step between the fabric knuckles and the dryer drum is completely eliminated. The moist layered ~ -paper web 27 is finally dried in place directly on the drying/imprinting fabric 37. Upon removal from the drying/imprinting fabric 37, the layered paper web is preferably subjected to any one of a number of processes designed to provide acceptable stretch, softness and drape in the finished sheet, e.g., mechanical micro-creping carried -~
out between differentially loaded rubber belts and/or a differentially loaded rubber belt and a hard surface. Such mechanical micro-creping processes are generally known in the papermaking industry. In a particularly preferred embodiment of the present invention, the finally dried, layered paper web is confined between a rubber belt at varying tensions and a pulley face to produce micro-creping ~ ~-~` in a system similar to that disclosed in U.S. Patent 2,624,245 issued to Cluett on January 6, 1953, and popularly known as "Clupaking".
- 20 While omission of the aforementioned knuckl~s compaction step and inclusion of mechanical micro-crep~ng may have an adverse effect on the overall tensile strength of the paper sheets, the reduction in strength is generally ~ not so great as to render the finished sheets unsuitable ; for use ln tissue, towelling and similar products. In addition, the overall tensile strength of the such layered -: . ., paper sheets can normally be adjusted upwardly, as desired, - by sub jecting the longer pap~sr-making fibers to additional ` refining prior to web formation, s~s~ ~ ~

~J thereby increasing their tendency to orm papermaking bonds. Dry strength additives well known in the papermaking industry may also be employed Eor this purpose.
.
Figure 4 is a photographic plan view enlarged about 20 times actual size of the fabric side of a prior art, non-layered, creped paper sheet 60 processed generally in accordance with the teachings of U. S. Patent 3,301,746, said sheet being formed from a single, homogeneously mixed slurry containing approximately 50 percent softwood anc :
50 percent hardwood fibers. The sheet was subjected to fluid pressure and thermally predried on a 26 X 22 semi-twill drying/imprinting fabric prepared as described in Canadian patent 1,007,911, compacted hy the fabric knuckles upon transfer to a Yankee dryer drum, Einally dried, ` 15 and creped upon removal from the drum by means of a doctor blade. The finished sheet contains approximately 16 percent crepe. As shown in Figure 5, the sheet has the -i appearance of a lazy corrugation with only a minor portion of the fibers on the fabric side 60a of the sheet extending ; outwardly away from the surface of the sheet when viewed in the cross-machine direction. ~ ~`

:- :
Figure 6 is a plan view enlarged about the same extent `
as Figure ~ of the fabric side 70a of a layered,creped paper sheet 70 of the present invention produced generally ;~ in accordance with the process illustrated in Figure 1, said sheet being formed from two identical slurries of essentiall~ the~

.
: ` :
, , ~'.:
-26- ~ ~
~ A
.. `~`

~5;~5~3 same fiber content, each slurry containing approximately 50 percent softwood and 50 percent hardwood fibers in a homo-: geneous mixture. m e basis weights, processing conditions, drying/imprinting fabric, and degree of crepe were essen~ially the same as those of the non-layered prior art sheet shown in Figures 4 and 5. As should be apparent from a comparison of Figures 5 and 70 the f~bric side 70a of the layered sheet has a greater propoxtion of its fibers deflected outwardly in a direction generally away rom the plane of the sheet. . . -Thus, the layered paper sheet 70 shown in Figures
6 and 7 exhibits a greater overall caliper and consequently a lower density than the similarly-produced, non-layered :~
prior art sheet 60 shown in Figures 4 and 5.

:, :
Figure 8 is a photographic plan view enlarged about 20 times actual size of the fabric side 80a of a layered, creped paper sheet 80 of the present invention : produced generally in accordance with the process illustrated in Figure 1, said sheet being formed from a slurry of softwood fibers 83 on its fabric side 80a and a slurry of hardwood~fibers 82 on its wire side 80b, the total fiber content of said sheet :~ being approximately 50 percent softwood and 50 percent hardwood fibers. The basis weights, processing conditions, .;' drying/imprinting fabric, and degree of crepe were essentially the same as those of the sheets shown in Figures 4 - 7~ A
comparison of Figures 9 and 5 reveals that the fabric side 80a of the sheet has a greater proportion of its fibers : ,.

~ :

' . .
~ .. . . . . . .

~L~5'~LS1~3 . ~ deflected outwardiy in a direction ge~erally away from the ~,-: ~ plane of the sheet. ~t should be noted, however, that the degree of deflection of the reoriented fibers as well as the proportion of fibers affected appears to be less pronounced ~: s than for the sheet 70 shown in Figure 7. This is believed to be due to the lower fiber mobilit~ in the long-fibered strata 83 and the greater tendency of the long fibers to bridge across the fabric mesh openings of the drying/imprinting fabric when compared to a layer comprised either of short fibers or a . 10 homogeneous mixture of short and long fibers. Nonetheless, ' the layered paper sheet 80 illustrated in Figures 8 and 9 exhibits a greater overall caliper and consequçntly a lower ~ensity than the non-layered prior art sheet 60 shown in Figures 4 and 5. :
': ' . ' .:
' 15 Figure 10 is a photographic plan view enlarged :
about 20 times actual size of the fabric side 90a of a layered creped paper sheet 90 produced generally in accordance with the process illustrated in Figure 1, said sheet being formed from a slurry of softwood fibers 92`on its wixe side 90b and a slurry of hardwood fibers 93 on its fabric side 90a, the ; total fiber content of said sheet being approximately 50 : percent softwood and 50 percent hardwood fibers. Although .'.; ' .
,`. : .
,;' , ' ,~
.'; ~
~':
''~ ' '.
: . :

.

' `- ' :

S~'3L5~3 the basis weight and processing conditions utilized were - essentially the same as those of the sheets shown in Figures 4 - 9, a coarser mesh 18 X 16 semi-twill drying/
imprinting fabric prepared as described in Canadian patent 1,007,911 was utilized. The finally dried sheet was creped to a level of approximately 20 percent.
Figure 11 clearly illustrates the discrete, totally enclosed pillow structures 91 characteristic of a preferred embodiment of the present invention. The discre~e, hollowed-out ~0 pillow structures 91 are formed between the long-fihered strata 92 on the wire side 90b of the sheet which remains substantially planar and continuous and the short-fibered ~ strata 93 on the fabric side of the sheet which is partially - displaced in a plane perpendicular to the sheet in small I L5 discrete deflected areas corresponding to the mesh openings of the drying/imprinting fabric. The increased caliper and lower density of the layered paper sheet 90 shown in Figures 10 and 11 are readily apparent when compared to the non-layered prior art sheet 60 shown in Figures 4 and 5. A comparison of Figures 4 and 10 reveals thàt the knuckle impressic~ns on the fabric side of the layered sheet sn are more difficult to discern than on the non-layered prior art sheet ~0 ;
due to the reduced overall density of the layered structure.
The reorientation of the fi~ers in the short-fibered strata 93 of the layered web 90 is also highly apparent in Yigure 11.
In this regard, it should be noted that the dens:ity of the short-fibered strata 93 is lower than that of the long~
fibered strata 92 of the layered sheet, thus creatin~ a favorable capillary size gradient between the fabric side ` 30 of the sheet 90a and the wire side of the sheet 90h.
" :' 29 - `

"' .' .
` A
......... . . . .

l()S~5~3 F-gure 14 is a plan view photograph enlarged about the same extent as Figures 10 and ~2 of the fabric side l~a of a layered, creped paper web 100 of the type generally shown in Figures 12 and 13 after compaction between the fabric knuckles and the dryer drum, final drying and creping thereof gener-ally in accordance with the process illustrated in Figure l. The finished layered sheet 100 illustrated in Figures 14 and 15 contains approximately 20 percent crepe. The layered sheet 100 is generally similar~ to the layered sheet 90 illustrated in Figures 10 and ll~buT
the totally enclosed pillow-like structures 91 shown in Figures 10 and 11 have burst to form volcano-like cone structures 101 on the fabric side lOOa of the sheet. It should be noted, however, that the long-fibered strata 102 of the sheet shown in Figures 14 and 15 remains substantially planar and continuous. Thus the embodiment of applicants' invention shown in Figures 14 and 15 is simply a variant of the embodiment shown in Figures 10 and 11, wherein the short-fibered strata 103 has undergone more extensive reorientation and greater penetration of the mesh openings of the drying/
imprinting fabric.
~ ' ~
The formation of pillow-like structures 91 as - shown in Figure 11 and/or volcano-like cone structures ; 101 as shown in Figures 13, 15, and 16 in a long-fibered/
short-fibered embodiment of applicants' invention such as is generally disclosed in Figure 3 is primarily a function o~
the diagonal free span/fiber length relationship, the fiber ` consistency of the composite web when subjected to fluid pressure on the drying/imprinting fabric and the ~; degree of fluid-pressure applied to the moist paper web. Applicants have further observed that it is not uncommon in layered sheets of the present invention for both the pillow-like structures 91 shown in Figure 11 and the volcano-like cone - structures 101 shown in Figure 15 to be present in a sin~le sheet.

.... .

~1)5;~
Because the benefits of improved bulk and caliper derive~ from layering papermaking fibers in accordance with the present invention dep~nd primarily upon the interac~ion of the fiber strata on the fabric side of the web and the S foraminous drying/imprinting fabric on which the web is subjected to fluid pressure and on which it is thermally predried, any number of prior art forming devices can be utilized to initially form ~he stratified web.

It should also be noted that the pxesent invention :. 10 may be practiced with equal facility by utilizing either a single, internally-divided headbox or two separate headboxes and forming the multi-layered paper web directly on the drying/imprinting fabric, as suggested in Figure 2 of U. S. Patent 3,301,746. Since this latter process does not involve transfer of the web from a fine mesh Fourdrinier forming wire to a coarser mesh drying/imprinting fab~.ic, as illustrated in Figure 1, fluid pressure, preferably in the form of vacuum, is applied directly thereto prior to thermal predrying of the web. With the above noted exception, this variant is in all other respects identical to the processes . described in connection with Figure 1.
.. ` ' . `

.
.:~

- 31 - :

.
,. . .

1 ~s~15~
The present inven~ion is most preferably practiced on paper sheets having a dry, uncreped basis wei~ht between about 5 and about 40, and most preferably between about
7 and about 25 pounds per 3,000 square feet, dependin~ upon S the desired product weight and the product's intended use.
The range of bulk densities associated with the 5 to 40 pound basis weight range is typically between about 0.020 and about 0.200 grams per cubic centimeter while the range of bulk densities associated with the 7 to 25 pound basis weight range is typically `10 between about 0.025 and about 0.130 grams per cubic centimeter, said bulk densities being measured in the uncalendered state under a load of 80 grams per square inch. In general, the bulk density is, at least to a degree, propoxtional to the basis weight of the paper sheet. That is, bulk density tends to increase with an increase in basis weight, but not necessarily as a linear function.
.` ' '~
The stretch properties of finished sheets of the present invention may be varied as desired, depending upon their intended use, by proper selection of the drying/lmprintin~ fabric and by varying the amount of mechanical creping or micro-creping imparted to the sheets.
Since the increase in bulk and caliper of long-fibered/
short-fibered stratified paper sheets of the present invention axe ~
influenced to a large extent by the contribution of the short-fibered ~ -~5 strata of the web, applicants have found that in order to realize the maximum increase in bulk and caliper and consequently the maximum decrease in overall density, the short-fibered strata of the :~

- -composite web should preferably constitu~e at least about 20 percent of the web's total bone dry weight, i.e., the weight of the web at 100 percent fiber consistency, and is most preferably between abou~ 40 percent and about 60 percent of the web's total bone.dry weight, particularly when dealing with webs at the lower end of the basis weight spectrum. ~pplicants have further learned that when the short-fibered strata comprises more than about 80 percent of the web's total bone dry weight, the overall tensile strength of the resultant paper structure decreases. Thus, in a most preferred embodiment of the present invention, the short-fibered strata comprises between about 2~
percent and about 80 percent, and most preferably between about 40 percent and about 60 percent, of the web's total lS bone dry weight.
' , Contamination of the long-fibered strata of the composite web by 5hort papermaking fibers has no apparent negative effects on the finished sheets, at least ; until the concentration of short fibers in the long-f'ibered strata becomes so great as to cause tensile strength de-gradation. Applicants have learned, however/ that the reverse is not true. Due apparently to the lower mobility of the longer papermaking fibers and their increased tendency ; to bridge across intersecting and adjacent filaments of the drying/imprinting fabric and thereby reduce the degree of fiber reorientation and penetration of the fabric mesh ;
openings, applicants have found it desirable, in a most ~ 33~

!

. ". ' - ' `' ', , . - ~ ' , ~ ' ,15~

preferred embodiment of the present invention, to maintain a degree of separation between the short-~ibered and long-~ibered layers such that not more than about 30 percent, and most preferably not more than about 15 percent, of the long paper~aking fibers ~are present in the strata containing primarily short papermaking fibers. As the degree of cross-contamination of the short-fibered stra~a by long fibers increases beyond this level, the desirable improvements in bulk and caliper which are characteristic of long- -fibered/short-fibered stratified paper sheets of the present invention become somewhat less pronounced.

- m e inventive concept disclosed herein may, if Idesired, be extended to low-density, multi-layered paper ?
structures comprised, for example, of a long-fibered layer ~
, .
located intermediate a pair of short-fibered layers to ~., .
` provide improved tactile impression and surface dryness on ~oth surfaces o~ the sheet.
Figure 17 is a fragmentary schematic illustration of one embodiment of a process for forming such a three layered web. An internally divided twin-wire headbox 201 is supplied from separate fibrous slurries so that the uppermost portion of the headbox 207 contains primarily short papermaking fibers while the lowermost portion 20S of the headbox contains primarily long papermaking fibers. A
s~ratified slurry is laid down in the nip formed between a fine mesh Fourdrinier wire 240 operating about rolls 239, 241, 243, 244 and 245 and a coarser mesh imprinting fabric 246 of the type ~eneraily described herein operating about ~-rolls 247, 249 and 250. The short-fibered strata 223 and the 3~ long-fibered strata 224 coalesce sufficiently at their inter-.. ~. " .

~; ~ 34 ~

., , . , . - -- . . - . .. , . . , . . . , . .- ~ :

~OS'~lS~
face to form a unitary web 225 whic~r is stratified with re-spect to fiber type. The stratified weh 225 is ca~lsed to remain in contact with the web supporting surface246a of the imprinting fabric 246 due to the application of fluid pressure to the web at the point of separation between the fine mesh Fourdrinier wire 240 and the coarser mesh imprinting fabric 246. This is preferably accomplished by means of a vacuum pick-up shoe 248 which contacts the undersurface 246b of the imprinting fabric. If desired, an optional slotted steam or air nozzle 242 may also be provided. Since the stratified web 225 is at relatively low fiber consistency at this point, the application of fluid pressure to the web, as described above, causes fiber reorientation and fiber penetration into the fabric mesh openings n the short-fibered strata 223 of the web.

.
If desired, the fiber consistency of the stratified ` web 225 may be further increased by means of vacuum boxes 218 and 220 to approximate that of ~he hardwood strata 226 at the point of transfer. The hard~ood strata ;20 226 is preferably formed by means of a secondary headbox202, a fine mesh ~ourdrinier wire 204, forming boards 215 and 216 and vacuum boxes 222 and 224 of the type generally described in connection with ~igure 1. The hardwood strata ~ 226 is transferred from the fine mesh Fourdrinier wire 204 to the long-fibered strata 224 of the stratified web 225 to foxm a three-layered web 227 in essentially the same manner sho~n in Figure 1. A vacuum transfax box 206 is preferably employed in contact with the undersurface 246b of the imprinting fabric to effect the transfer. If desired, an optional slotted steam or air nozzle 253 may also be provided.

:
..
~ - 35 -.. . . . . ~ . ~ .- .

1~ 8 Following transfer~ the fiber consistency of the three-layered stratified w~b 227 is preferably increased to the upper end of the preferred range, i.e., most pre-ferably to a level betwePn about 20 and 25 percent, by means of vacuum boxes 229, 231 and 2~3. This is generally desirable to mir.imize disturba~ce o ~he deflected areas in the short-fibered strata 223 of the layered web during transfer - -- of ~he web to the drying/imprinting fabric 237. In a most preferred embodiment of the presen~ invention, the drying/imprinting fabric 237 is substantially identical in construc ion to the imprinting fabric 246. As is shown in Figure 17, transfer of the three-layered web from the imprinting fabric 246 to the drying/imprinting fabric 237 is most preferably effected by means of a vacuum pickup shoe 236 which contacts the undersurface 237b of the drying~imprinting fabxic 237. Since steam jets, air jets, etc., tend to - disturb the deflected areas in the hardwood strata 223 of the web, it is preferable not to utilize such transfer - aids at this particular point.
Following transfer of the three-layered strat~fied - web 227 to the web supporting surface 237a of the dryingj imprinting ~abric, the web may be thermally predried and finished in the same manner as the two-iayered web described in connection with Figure 1.
In order to maximize bulk and caliper improvements in a ~hree-layered paper sheet, such as that shown in Fig~re 17, it is preferable to completely dry the web on the drying/
imprinting fabric 237 without compacting the web ;~-~
between the fabric knuckles anci a non-yielding surface after thermal predrying.
,,` ~.
~ 36 -... ~ .. .. . .. . . . .

1~)5;~58 The three-layered embodiment described above is most preferably practiced on paper sheets having a dry, uncxeped basis weight between about 8 and about 40 pounds per 3,000 square feet, de-pending upon the desired product weight and the product's intended use. Such three-layered paper sheets typically exhibit bulk densities between about 0.020 and about 0.200 grams per cubic centimeter.
The present invention has extremely broad application in producing unitary paper sheets having similar or dissimilar sur-face characteristics on opposite sides thereof, in combining extremely low-density and acceptable tensile strength in a single ; paper structure, etcO In general, it gives the papermaker greater . freedom to custom tailox a combination of desired, but previously incompatible sheet characteristics into a single, unitary paper structure.

Although the foregoing descxiption has been ~ ;
. , .
specifically directed toward the utilization of natural papermaking fibers, it will be readily appreciated by those skilled in the art that the present invention may likewise be practiced to ad~antage in layering man-made papermaking fibers or even combina- ;
tions of natural and man-made papermaking fibers to produce finished sheets having extremely high-bulk and low density, as ;
well as other particularly desired properties.
The examples hereinafter set forth serve to illustrate the dramatic increase in bulk and reduction in density without sacrifice in overall tensile strength of layered paper sheets produced in accordance with the present invention in comparison to a non-layered prior art paper sheet produced in a similar manner from a single slurry comprised of a homogeneous~
mixture of similar papermaking fibers. Accordingly, the examples are intended to be illustrative and not limiting, and the scope of the invention is only to be construed by the scope of the appended claims.
~ 37~
~ , . , ~ , ~S:15;~8 Each of the following examples was produced generally in accordance with the process illustrated in Figure 1. A11 examples were subjected to fluid pressure, thermally predried, and subjected to compaction between the fabric knuckles and a dryer drum on a 26 X 22 polyester semi-twill imprinting fabric having a common warp and woof monofilame~t diameter of approx-imately 0.022 inches and a measured diagonal free span of approxi-mately 0.024 inches, said fabric having been treated generally in accordance with the teachings of Canadian patent 1,007,911.
The knuckle imprint area of the fabric comprised approxi-mately 39.1 percent of th~ web's surface. rThe total fiber content of each sheet was comprised of approximately 50 percent refined softwood pulp fibers having an ~verage length of about 0.097 inches and 50 percent unrefined hardwood pulp fibers ~h~v- ~`
ing an average length of about 0.035 inches. Each of the paper webs supported on the drying/imprinting fabric was subjected to compaction by the fabric knuc~les by means of a pressure roll ~ `~
operating against a Yankee dryer drum at a pressure of approxi~lQ~Iy 300 pounds per lineal inch. Each of the sheets was adhered ~0 to the surface of a Yan~ee dryer drum generally in arcordance with the teachings of U.S. patent 3,~26,716 and the finally dried sheets were removed from the surface of the dryer drum by means of a doctor blade having a 30 bevel to produce finished sheets containing approximately 20 percent crepe. ;
The creped basis weights of the examples were, to the extent feasible, held constant, the actual values ranging from ; approximately 14.3 to approximately 14.7 pounds per 3,000 square feet.

3 E~ -- ~
-',' ';:

: ' .';: ~', EXAMPLE I
A non-layered prior art paper sheet was produced generally in accordance with the teachings of U. S.
; ~atent 3,301,746. The fibrous slurry was comprised of homog~neously mixed softwood and hardwood fibers, the softwood fibers ha~ing received 0.48 horsepower-days per ton refining. The homogeneously mixed slurry was laid down on a fine mesh Fourdrinier wire to form a unitary, non-` layered web. The iber consistency of the web at the point of transfer from the Fourdrinier wire to the drying/imprinting fabric was approximately 9.2 percent. A pickup shoe vacuum of approximately 9.6 inches of mercury was applied to the moist paper web to effect transfer to the drying/
imprinting fabric. The web was thermally predried on the fabric to a fiber consistency of approximately 97.1 percent prior to knuckle compaction thereof ` ~
upon transfer to the Yankee dryer. The properties exhiblted by the resulting paper sheet are set forth in TableS I and II.

.' '., ' ~ ' ' ' .~ , . .

~. ' .~.', ' ' ~ '~
- _ 39 _ '` . . ' ' '' ' ' .

EXAMPLE II
-A two-layered paper sheet was produced in accordance with the process illustrated and described in connection with Figure 1. A first fibrous slurry comprised of homogeneously mixed softwood pulp and hardwood pulp fibers, the softwood fibers ha~ing received 0.56 horsepower-days per ton refining, was laid down on a fine mesh Fourdrinier wire to form a first fibrous web. A second fibrous slurry of identical composition was~
laid down from a second headbox onto a second fine mesh Fourdrinier wire to form a second fibrous web. The ; second fibrous web was thereafter combined with said first fibrous web while both webs were at relatively low fiber consistency to form a two-layered moist paper web in accordance with the process illustrated in Figure 1. The fiber consistency of the two-layered web at the point of transfer from the Fourdrinier wire to the drying/imprinting fabric was approximately 9.9 percent. A pickup shoe vacuum of approximately 9.7 inches of mercury was applied to the moist paper web to effect transfer to the ; ;
drying/imprinting fabric. The web was thermally predried ~ -on the fabric to a fiber consistency of approximate3y 94.~ percent pxior to knuckle compaction' thereof .
upon transfer to the Yankeè dryer. The properties `, 25 exhibited by the resulting paper sheet are sat forth in l Tables I and II.
.1 . .

. . ' . 4~
, ' ;~

. ' l~:tS;~
EXAMPLE IIX
.
A two-layered paper sheet was produced in accordance with the process illustrated and described in connection with Figure 1. A ~irst fibrous slu~ry comprised of hardwood pulp - , fibers was laid down on a fine mesh Fourdrinier wire to ~orm a first fibxous web. A second fibrous slurry comprised of softwood pulp fibers, said softwood fibers havin~ received 0.44 horsepower-days per ton refining, was laid down from a second headbox onto a second fine mesh Fourdrinier wire to form a second fibrous web. The second fibrous web was thereafter combined with said first fibrous web while both webs were at relatively low fiber consistency to form a two-layered moist paper web in accordance with the process illustrated in Figure 1. The fiber consistency of the two-layered web at the point of transfer from the Fourdrinier ` wire to the drying/imprinting fabric was approximately 9.6 percent. A pickup shoe vacuum of approximately 9.5 inches of mercury was applied to the moist paper web ~o effect transfer to the drying/imprinting fabric. The web was transferred to the fabric so that the softwood strata was placed in contact with the web supporting surface of the fabric. The web ` was thermally predried on the fabric to a fiber consistency ; of approximately 94.2 percent prior to knuckle compaction thereof upon transfer to the Yankee dryer. The properties ; exhibited by the resulting paper sheet are set forth in Tables I and II.

~ ' ' ' '~

: ' :

~ 15~15?3 EXAMPLE IV
; A two-layered paper sheet was produced in accordance with the process illustrated and described in connection with Figure 1. A first fibrous slurry comprised of softwood fibers, said softwood pulp fibers having received 0.48 horsepower-days per ton re~ining, was laid down on a fine mesh Fourdrinier wire to form a first fibrous web. A second fibrous slurry comprised of hard-wood pulp fibers was laid down from a second headbox onto a second ~, fine mesh Fourdrinier wire to form a second fibrous web.
The second fibrous web was thereafter combined with said first fibrous web while both webs were at relatively ' low fiber consistency to form a two-layered, stratifiea moist paper web in accordance with the process illustrated in Figure 1. The fiber consistency of the two-layered ~;
web at the noint oE transfer from the Fourdrinier wire to the dryina/imprintin~ fabric was approximately 8.9 per-cent. A pickup shoe vacuum of apnroximately 10.0 inches ~, of mercury was applied to the moist ~aper web to effect transfer to the drying/imprinting fabric. The web ~, was transferred to the drying/imprinting fabric so that Its !
hardwood strata was placed in contact with the web supporting surface of the fabric. The web was thermally predriea on the fabric to a fiber consistency of approximately 89.4 percent ` 25 prior to knuckle compaction thereof upon transfer to the Yankee dryer. The properties exhibited by the resulting paper sheet are set forth in Tables I and II. `
EXAMPLE V
two-layered paper sheet was produced in a manner similar to that of ExamPle IV, but the processing conditions ' were varied as follows: (1) the softwood pulp fibers received : - 42 -. '. , ~

~:.,-^:- - - ~., -, - - . .

~5~
0.40 horsepo~er-days per ton refining.; (2) the fiber .." ... .. ..
consisten~y of the two-layered web at the point of transfer from ~he Fourdrinier wire to the drying/imprinting fabric was approximately 9.6 percent; (3~ a pickup shoe ~acuum of approximately 5.0 inches of mercury was applied to the moist paper web to effect tran fer to the drying/
imprinting fabric; and (4) the web was thermally predried on the fabric to a fiber consistency of approximately 85.0 percent prior to knuckle compaction thereof .~
upon transfer to the Yankee dryer. Properties exhibited by the resulting paper sheet are set forth in Tables I and II.

.
~XAMPLE VI
A t~o-layered paper sheet was produced in a manner similar to that of Example IV, but the processing conditions .` 15 were varied as follows: (1) the softwood pulp fibers received 0.40 horsepower-days per ton refining; (2) the fiber consistency of ~.
.~ the two-layered web at the point of transfer from the Fourdrinier wire to the drying/imprinting fabric was . .
approximately 16.5 percent; (3) a p;ckup shoe vacuum of approximately 9.5 inches of mercury was applied to the moist paper web to effect transfer to the drying/imprin~ing . .
: fabric; and (4) the web was thermally predried on the fabric to a fiber consistency of approximately 84.5 percent prior to knuckle compaction thereof upon ; 25 transfer to the Yankee dryer. Properties exhibited by the resulting paper sheet are set forth in Tables I and II.

.`' ~
:, - 43 -~ .

~ . - .

~iS~158 The comparative tests conducted on the various ~xamples described in Tables I and II were carried out as follows:

Dry Caliper This was obtained on a Model 549M motorized micrometer such as i5 available from Testing Machines, Inc.
of Amityville, Long Island, New York. Product sam~les were subjected to a loading of 80 gm. per sq. in~ under a 2 in.
diameter anvil. Ihe micrometer was zeroed to assure that no foreign matter was present beneath the anvil prior to in-serting the samples for measurement and calibrated to assure proper readings. Measurements were read directly from the dial on the micrometer and are expressed in mils.
.'., Calculated Density The density of each sample sheet was calculated by dividing the basis weight of the sample sheet by the caliper of the sample sheet, as measured at 80 gm. per .
sq. in.
'.'~ ' ' ' ,:

Dry Ten~ile Strength mis was obtained on a Thwing-Albert Model QC
tensile tester such as is available fro~ the ~hwing-Albert Instrument Company of Philadelphia, Pennsylvania. Product samples measuring 1 in. by 6 in. were cut in both the ` machine and cross-machine directions. Four sample strips were superimposed on one another and placed in the jaws of the tester, set at a 2 in. gauge length. The crosshead speed during the test was 4 in. per minute. Readings were taken directly from a digital readout on the tester at the point of rupture and divided by four to obtain the tensile strength of an individual sample. Results are expressed in gramsfin.

! -.

S~

Stretch Stretch is the percent machine direction and cross-machine direction elongation of the sheet, as measured at rupture, and is read directly from a second digital readout on the Thwing-Albert tensile tester. Stretch readings were taken concurrently with tensile strength readings.
Machine Direction Tearing Resistance This was obtained on a 200-gram capacity Elmendorf Model 60-5-2 tearing tester such as is available from the Thwing-Albert Instrument Company of Philadelphia, Pennsyl-vania. The test is dasigned to measure the tearing resistance of sheets in which a tear has been started. `~
Product samples were cut to a size of 2-1/2 in. by 3 in., with the 2-1/2 in. dimension aligned parallel to the machine ~;~
direction of the samples. Eight procluct samples were stacked one upon the other and clamped in the jaws of the tester so as to align the direction of tear parallel to the 2-1/2 in.
dimension. A 1/2 in. long cut was then made at the .,! :::
lowermost edge of the stack of samples in a direction paral3~el to the direction of tear. A model 65-1 digital read-out unit, also available from the Thwing-Albert Instrument Company, was zeroed and calibrated using an Elmendorf No. 60 calibration weight prior tà initiating the test. Readings were taken directly from the digital read-out unit and inserted into the following equation~

rTear Tester capacity (gm.) X Reading fro ;
Tearing Resistance = Digital Read-out Unit ~%) 7x 1 Number of plies of Product Tested J 100 Results are expressed in terms of grams/ply of product. ;~

..

, ~

~35X~
Handle-O-~eter This ~s obtained on a Catalog No. 211-3 ..
~andle-O-Meter such as is available from the Thwing-Albert ~
Instrum~nt Company of Philadelphia, Pennsylvania. Handle- -(R~
O-Meter values give an indication of sheet stiffness and `
sliding friction which are in turn relate~ to handle, ~ ~
(R) -~ sotness and drape. Lower Handle-O-Mete~ values are -: indicative of less stiffness, and hence point toward better ;~
handle, softness, and drape. Product samples were cut to a size of 4-1/2 in. by 4-l/2 in., and two samples placed ; adjacent one another across a slot having a width of 0.25 ~
~ :. ~ .
in. for each test. Handle-~-Meter ~alues in the machine -direction were obtained by aligning the machine dire ~ion of the product samp ~ parallel to the Handle-O-Mete lade, while Handle-O-Mete alues in the cross-machine direction : ~
were obtained by aligning the cross-machine direc~ on of ~ ~
the product samples parallel to the Handle-O-Mete lade. -Handle-O-Meter results are expressed in grams.
.! ' :' ` Flexural Rigidity and Bending Modulus In order to quantify sheet properties relating -to tactile impression and drape, resort was had to the l principles of textile testing. Fabric handle, as its name 'l~ implies, is concerned with the feel or tactile impression of the ma-;( terial and so depends on the sense of touch. ~en the handle of a 25 fabric is judged, the sensations of stiffness or limpness, hardness or softness, and roughness or smoothness are all made use of. Drape has a rather different meaning and very broadly is the ability of a fabric to assume a graceful appearance in use~ Experience in the textile 30 industry has shown that fabric stiffness is a key factor in the study of handle and drape.
~ :

- ~os;~

One instrument devised by the textile industry --to measure stiffness is the Shirley Stiffness Tester.
In order to compare the drape and surface feel properties of the paper samples described in Examples I - VI above, a Shirley Stiffness Tester was constructed to determine the "bending length" of the paper samples, and hence to calculate values for "flexural rigidity" and "bending modulus".
' - :
The Shirley Stiffness Tester is described in ASTM Standard Method ~o. 1388. The horizontal platform of the instrument is supported by two side pieces made ; of plastic. The side pieces have engraved on them index lines at the standard angle of deflection of 41-1/2.
Attached to the instrument is a mirror which enables the operator to view both index lines from a convenient position. The scale of the instrument is graduated in centimeters. The scale may be used as a template ~or cutting the specimens to size.

.:
To carry out a test, a rectangular strip of paper, 6 inches by 1 inch, is cut to the same size as the scale .
and then both scale and specimen are transferred to the platform with the specimen underneath. Both are slowly pushed forward. The strip of paper will commence to droop over the edge of the platform as the scale and specimen are advanced. Movement of the scale and the specimen is continued until the tip of the specimen viewed in the - mirror cuts both of the index lines. The amount of over- `
hang, "¦", can immediately be read off from the scale mark `~
opposite a zero line engraved on the side of the platform.

-47 .- -` ' ' , ' , ` :` . ., ... . .. ` . . : `

1~5'~S~
~ Dus to the fact that paper!~ssumes~a permanent set after being subjected to such a stiffness test, four individual specimens were utilized to test the stiffness of the paper along a given axis, and an average value for the particular axis was then calculated. Samples were cut ~n both the machine and cross-machine directions. Fro~
the data collected in both the machine and cross-machine directions, an average overhang value, n 1~, was calculated for the particular paper sample.
' ,' , ' ' The bending length, "c", for purposes of these tests, shall be defined as the length of paper that will bend under its own wPight to a definite extent. It is a measure of the stiffness that determines draping quality.
::
The calculation is as follows:

nc~ cm. x f (e) where f(0) = [cos 1/2 ~ . 8 tan 0] , and n ~ ~l = the average overhang value of the particular paper sample as determined above.

- ' ' ' ' ;:
In the case of the Shirley Stifness Tester, , 20 the angle 0 = 41-1/2, at which angle f(e) or f(41-1/2) = 0.5.
` Therefore, the above calculation simplifies to:

: ( .
' .
Hc" - Ill'' x (0.5) cm.
' ' ' . . ~ . .

. ~ ~ .; '.

3~151 3 Flexural rigidity, "G", is~a measure of stiffness ;---associated with handle. The calculation o flexural rigidity, I'G", in the present instance is as follows:
' , ~Gn = O.1629 x (basis weight of S the particular paper sample in pounds per 3,000 sq. ft.) x "c"3mg.-cm., where "cn = the bending length of the -particular paper sample as determined above, expressed in cm.

`: .

1~ The bending modulus, "q", as reported in the éxamples, is independent of the dimensions of the strip tested and may be regarded as the "intrinsic stifness" of the material. Therefore, this value may be used to compare the stiffness of materials having different thicknesses. For its calculation, the thickness or caliper `~ of ~he paper sample was measured at a pressure of 80 grams per square inch rather than 1 pound per square inch as suggested by ASTM Standard Method ~o. 1388. The 80 gm. caliper pressure was utilized to minimize any tendency toward ~ ;
crushing the sheet and thereby obscuring the differences -between the various examples.
! .
The bending modulus, "q", is then given by~

nq" = 732 x "G" "g"3kg.~sq.cm., ,' ' , ' ~ :~., .
~ ~.
- 49_ - ' ' ' , I .~:.

~5;~
where "G" is the flexural rigidity of the particular paper sample as determined above, expressed in mg.-cm., and "g" is the thickness or caliper of the particular paper sample, expressed - in mils, when subjected to a prassure of 80 gm. per square inch.
, The results o tests performed on sample paper sheets produced during the runs described above are reported in the exampIes hereinbelow in terms of flexural rigidity, "G", and bending modulus, "~", which have relevance with respect to both drape and tactile i~pression.
Lower flexural rigidity and lower bending modulus Yalues . .
, are generally indicative of improved drape and tactile ~
. ., impression.

Compressive Work Value ~ ;
The CWV numbers reported in the tables of examples ~
hereinbelow de~ine the compressive deformation characteristics ~ . : .
(sponainess is part of a total impression of so~tness to a person who handles the paper) of a paper sheet loaded on its opposing flat surfaces. The significance of the ~V
` n~mber is better understood by the reali~ation that the CWV
number represents the total work required to compress the . ~ . .
, !` -surfaces of a single flat paper sheet inwardly toward each ;
other to a unit load of 125 grams per square inch. In accomplishing the foregoing compression test, the thickness ~ -~
of the paper sheet is decreased, and work is done. This ;l work, or expended energy, i5 similar to the work done by , ~ - 50 ~
: -.
! ~

3lS~
.

; a person who pinches the flat surfaces of a flat sheet of paper between his thumb and forefinger to gain an im-pression of its softness. Applicants have found th~t CWV
numbers correlate well with the softness impression obtained by a person who handles a paper sheet.

An Instron Tester Model No. TM was used to measure the CWV numbers by placing a single,4 square inch paper sheet between compression plates. m e sample was then loaded on its flat opposing surfaces at a rate of 0~10 inch of compression deformation per minute until the ;;~
loading per square inch reached 125 grams.
`', The Instron Tester is equipped with a recording unit which integrates the compression movement of the sheet surfaces and the instantaneous loading to give the total . ~.
~` 15 work in inch-grams re~uired to reach the 125 grams per ; ;
square inch loading. This work, expressed as inch-grams per ;
4 square inches of sheet area, is the CWV number used herein.
A higher C~ number is generally indicative of a softer sheet. ` ;~

Compressive Modulus The compressive modulus, as reported in the -~
Examples below, is generally similar to the modulus of "
elastlcity described at pages 7-OS and 7-06 of ~ent's 2S ~lechanical ~n~l~ n. -The compressive modulus may be regarded as the "intrinsic resistance to compression" o the material at a particular . -.:`.-. .:. , . , ",, point on the stress-s~.rain diagram generated during the ,.
test procedure for establishing CWV values, as described above.

~` According to the aforementioned publication, the S modulus of elasticity, or comp~essive modulus "E", is given by the equation: -~ . ' ' .
:: E = -Ae . where ~pll is the applied force, '~" is the length of the sample being tested, "A" is the cross-. sectional area of the sample being tested, and ne" is the total resulting deformation of the sample.

In determining the compressive modulus for paper 15 . samples, the proportional limit of the material being ~ .:
tested is extremely low~ Therefore, the above equation was modified as follows:

` ' where ~ p~'l is the differential force determined by drawing a line tangent to the stress-strain diagram at a predetermined applied load value (in this case 400 grams) and extending the tangent line a pre-' determined distance on each side of the applied load value (in this case from 300 to 500 grams) to yield a differential force,''(~P)I-tin this case 200 grams);

` ' , 1 .
~: . . . - . . . .

S~

''I'' is the caliper of the paper sample being ; tested, as measured at the applied load value (in this case 400 grams);
"A" is the surface area of the paper sample being tested ~in this case 4 sq. in.); and e)" is the differential deformation of the sample being tested, as determined by the end points of the aforementioned tangent line (iOe., the deformation as measured at 300 grams applied load less the deformation as measured at 500 grams applied load).
Lower compressive modulus values are generally ~ ~
desirable in tissues and sanitary products in that they are -indicative of reduced resistance to collapse under loads normally applied to such structures. ~ ;
Absorptive Capacity One facet of a paper sheet's overall absorbency ~ -~
-~ is its absorptive capacity for water. This test was utilized ~ to determine the capacity of each sample sheet to absorb , .
water at a specified flow rate in a specified time. Product samples were cut to a size of 4 in. by 4 in., stacked 8-high, and placed in~a polyurethane holder on an inclined plane of an absorptive capacity tester. The weights of both the sample and of the polyurethane holder `';' ' ' '; ~
~: ' ' ' ~'',:' `~

- -53- ~

'. '',,'' l~S~lSB
were determined prior to wetting of the sample. Samples were placed in the polyurethane holder such that their cross-machine direction was aligned parallel to the inclined plane. Water was introduced at the uppermost end of the inclined plane at a controlled rate of 500 ml./
minute for a period of one minute. The saturated sample i was allowed to remain on the inclined polyurethane holder for an additional 45 seconds after the water had been turned off during which time excess water was removed --from the polyurethane holder, care being taken not to contact the,saturated sample. The weight of the poly-urethane holder and the saturated sample was then measured.
The amount of water absorbed by the sample was determined ,, by subtracting the dry weight of the polyurethane holder and sample from the wet weight of the polyurethane holder and sample., Since the dry weight of the sample was also~
,known, the following calculation was performed:
.-,~, Total Quantity of Water 1 `, Water Absorbed absorbed by Y~nown ~uantity of Sample (gm.)¦
Per unit of Product ~ry Weight o Known Quant y ]
~ample (gm.) ' Results are expressed in terms of grams~of water absorbed/
gram of sample.

~ ' .
i Rate of Absorption Another facet of a paper sheet's overall absorbency is its rate of water absorption. This test was conducted by measuring the time in seconds required for 0.10 ml. of ~ 54 ~
.' .
, ' .
': ~ . . ., - ..

~ L~t5;~1S8 distilled water to be absorbed by a single 4 in. by 4 in.sheet sample using a Reid style tester such as is described in detail in an article by S. ~. Reid entitled "A
~ethod for Measuring the P~ate of Absorption of Water S by Creped Tissue Paper," which appears at pages ~-115 to T-117 of Pulp and Paper Magazine oS Canada, Volume 68, No. 3, Convention Issue, 1967. Tests were conducted by simultaneously opening the stop-cock located between the calibrated pipette and the capillary tip - -contacting the sample and starting a timer, observing the water level in the pipette as the water was being absorbed by the sample, and stopping the timer when exa~tly 0.10 ml. of water had been dispensed from the calibrated pipette.
Readings were taken directly from the timer and are expressed in seconds. Lower times are indicative of a higher rate of water absorption.

Each product characteristic compared in Tables I
and II by means of the hereinbefore described tests was based upon the average value for all such tests actually conducted -~
on the subject example.

' ':
~ -~?~

.'` . ;~' .. .. ~

. : .
.' . - . ~

-~ -~:
~ ~. , . - .

1135'~5~
,l~- ~
~ ~ o Ln ~ L~ ~

:: '~\ U~ o o CO ~
,~ ~ ~ ,~ ,~
_ _ _ ,_ _ ,., '.
'~
~ ~ ~1 ~ _~ In ,: .~
.
U - __ _ . ~ ' ;
H ¦ U _ o~ ~) ~ u:~ oo ~1 ~ . -a~--o ~ ~ ~ ~ ~ I~ ~ ~ :
u~ ~r ~ ~ ~r ~
~ ~ O O O O O O
E~ ~ o o o o o o : ' ~ . . ; ~:
,.~ . _. _ . , ~1 ~ N . . . ~ ~ `
. .Q.~O~ ~1 ~9 o Il') ~) ~r `

O ~ O ~1 a~ N N N
N _ ~ ~ _ _ __ a) u~ .~ ~
Q~ o It~ Ul In ~7 ~ r` ~ ~, .' ~ ~ ~ ,_~ r-l r-l ~1 . . H _ .
- H H ~ H
H H H H

56~
:: ry~ , :

.. .. . , , , . ~

, - -, ~ ,. - - - , - , --------~--------~C ~ r~ ~ I
~ -~ -~ --~

o~ ~ ~ ~ ~ ~ oo :: :
---- -----------::
to ~
U . ~ U h ~ ~

~ __ :-- _ _ ~ ?
~ ' ;' -~';-~ ~, o ~ ~ o r- ~ ~:
`~ ~ _ -i _ -I--_ . .
:` H H ` H ; , H. H H H ~ ~ .

;' - ' ,` ' ~ ' " ' ' -56a~

': ' : ~' .` . In ~ _ _ _ __ _ . . L,'~-l I I I I I ., o ~ --~ r` ~` r~ o co ~
~ ~ ~1 co _1 _~ ~ ~a '; ~- - - - - ~:
~$:r~ ,~ u~ o~ a~ _, ~ ~ :
O O O ~1 1~ C-- N N

'~ __ _ ~
0 ~tu ~1 ~ ~ r` ~ co ,~ ~ a~ u) ~ ~ ~ ~
, , H ¦ 1~ Cl~ U~ cs~ X CO . .:
.`', - ~1. __ _ _ ,:
," . ,~ ,:

. ~ . . O ~ ~ ~O ~ O ~0 W
X ~ ~ o ~ o ~ o o :

.''` `! C~'r _ _ _ ' ;~;
~ CO Il~ ~i ~i N
__ _ _ ~:

~ ~ ~ N ~

. .. - .,. I
H
H H H ~ ~. H

5'~58 ~ ~omparison of the finished sheet characteristic~!
set forth in Tables I and II clearly demonstrates the increased caliper and decreased density of layered paper sheets of th~ present invention when compared to a similarly-produced, non-layered prior axt sheet of comparable basis weight.
This is further reflected in their improved absorptive capacity. As can be seen from Tables I and II, layered paper sheets of the present invention, in general, exhibit overall tensile and stretch characteris~ics comparable to those of the more dense, non-layered, prior art structure.
In ~ddition, such sheets exhibit lower handle-o-meter, flexural rigidity, bending modulus and compressive modulus values as well as higher compressive work values, all of -which are generally indicative of improved softness, drape, flexibility and tactile impression.
It is to be understood that the forms of the in-- vention herein illustrated and described are to be taken as preferred embodiments. Various ch~nges or omissions may be made in the manufacturing process and/or the product wi~hout departing from the spirit or scope of the invention as described in the appended claims.
.. ~ . .
Having thus de~ined and described the invention, what is claimed is: ;
.~ .

~" :
:', ' '':: ' ' ..
- 58 - ~

'' ~ . ''`

Claims (53)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A soft, bulky and absorbent unitary paper sheet having a basis weight of from about 5 to about 40 pounds per 3,000 square feet, as measured in an uncreped state, said sheet being characterized by having a structure which in cross-section comprises at least two superposed stratified fibrous layers in contacting relationship for a major portion of their areas, at least one of said stratified fibrous layers being partially displaced in a plane perpendicular to said sheet in small discrete deflected areas corresponding to the mesh openings in a foraminous fabric and comprising from about 100 to about 3,600 individual deflected areas per square inch, as measured in an uncreped state.
2. The soft, bulky and absorbent paper sheet of Claim 1, therein said discrete deflected areas are of lower density than the remaining portions of said paper sheet.
3. The soft, bulky and absorbent paper sheet of Claim 2, said sheet being further characterized by having an overall bulk density, as measured in an uncalendered state at a loading of 80 grams per square inch, of from about 0.020 to about 0.200 grams per cubic centimeter.

.
4. The soft, bulky and absorbent paper sheet of Claim 1, wherein said superposed stratified fibrous layers are comprised of dissimilar fiber types.
5. The soft, bulky and absorbent paper sheet of Claim 4, said sheet comprising two stratified fibrous layers, one of said stratified fibrous layers being partially deflected in a plane perpendicular to the sheet and the other of said stratified fibrous layers being substantially planar and continuous.
6. The soft, bulky and absorbent paper sheet of Claim 5, wherein the stratified fibrous layer which is partially deflected in a plane perpendicular to the sheet is comprised primarily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches and the stratified fibrous layer which is substantially planar and continuous is comprised pri-marily of relatively long papermaking fibers having an average length of at least about 0.08 inches.
7. The soft, bulky and absorbent paper sheet of Claim 6, wherein at least a portion of said discrete deflected areas in said short-fibered layer interact with said sub-stantially planar and continuous long-fibered layer to form structures which in cross-section have the appearance of totally-enclosed pillows.
8. The soft, bulky and absorbent paper sheet of Claim 6, wherein at least a portion of said discrete deflected areas in said short-fibered layer form structures which in cross-section have the appearance of volcano-like cones..
9. The soft, bulky and absorbent paper sheet of Claim 6, wherein said relatively short papermaking fibers are comprised of hardwood pulp and said relatively long papermaking fibers are comprised of softwood pulp.
10. The soft, bulky and absorbent paper sheet of Claim 6, wherein the bone dry weight of said stratified fibrous layer comprised primarily of relatively short papermaking fibers comprises between about 20 and about 80 percent of he total bone dry weight of said paper sheet.
11. The soft, bulky and absorbent paper sheet of Claim 6, wherein said stratified fibrous layer comprised primarily of relatively short papermaking fibers contains not more than about 30 percent of the relatively long papermaking fibers from which said substantially planar and continuous fibrous layer is comprised.
12. The soft, bulky and absorbent paper sheet of Claim 1, wherein said superposed stratified fibrous layers are comprised of similar fiber types.
13. The soft, bulky and absorbent paper sheet of Claim 12, wherein each of said superposed stratified fibrous layers is displaced in small discrete deflected -areas in a plane perpendicular to said sheet, said discrete deflected areas creating discontinuities extending through-out the entire thickness of said sheet.

-
14. The soft, bulky and absorbent paper sheet of Claim 12, wherein each of said superposed stratified fibrous layers is comprised of a homogeneous mixture of relatively long papermaking fibers having an average length of at least about 0.08 inches and relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches.
15. The soft, bulky and absorbent paper sheet of Claim 12, wherein each of said superposed stratified fibrous layers is comprised primarily of relatively long papermaking fibers having an average length of at least about 0.08 inches.
16. A soft, bulky and absorbent unitary paper sheet having a basis weight from about 7 to about 25 pounds per 3,000 square feet, as measured in an uncreped state, said sheet being characterized by having a structure which in cross-section comprises at least two superposed stratified fibrous layers in contacting relationship for a major portion of their areas, at least one of said stratified fibrous layers being partially displaced in a plane perpendicular to said sheet in a regular pattern of small discrete deflected areas corresponding to the mesh openings in a foraminous fabric and comprising from about 100 to about 3,600 individual de-flected areas per square inch, as measured in an uncreped state.
17. The soft, bulky and absorbent paper sheet of Claim 16, wherein said discrete deflected areas are of lower density than the remaining portions of said paper sheet.
18. The soft, bulky and absorbent paper sheet of Claim 17, said sheet being further characterized by having a bulk density, as measured in an uncalendered state at a loading of 80 grams per square inch, of from about 0.025 to about 0.130 grams per cubic centimeter..

. ,
19. The soft, bulky and absorbent paper sheet of Claim 17, said sheet comprising two stratified fibrous layers, one of said stratified fibrous layers being partially deflected in a plane perpendicular to the sheet and the other of said stratified fibrous layers being substantially planar and continuous.
20. The soft, bulky and absorbent paper sheet of Claim 19, wherein the stratified fibrous layer which is partially deflected in a plane perpendicular to the sheet is comprised primarily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches and the stratified fibrous layer which is substantially planar and continuous is comprised primarily of relatively long papermaking fibers having an average length between about 0.08 and about 0.12 inches.
21. The soft, bulky and absorbent paper sheet of Claim 20, wherein at least a portion of said discrete deflected areas in said short-fibered layer interact with said substantially planar and continuous long-fibered layer to form structures which in cross-section have the appearance of totally-enclosed pillows.
22. The soft, bulky and absorbent paper sheet of Claim 20, wherein at least a portion of said discrete deflected areas in said short-fibered layer form structures which in cross-section have the appearance of volcano-like cone structures.
23. The soft, bulky and absorbent paper sheet of Claim 20, wherein the bone dry weight of said stratified fibrous layer comprised primarily of relatively short hard-wood fibers comprises between about 40 and about 60 percent of the total bone dry weight of said paper sheet.
24. The soft, bulky and absorbent paper sheet of Claim 20, wherein said stratified fibrous layer comprised primarily of relatively short papermaking fibers contains not more than about 15 percent of the relatively long papermaking fibers from which said substantially planar and continuous fibrous layer is comprised.
25. A soft, bulky and absorbent unitary paper sheet having a basis weight of from about 8 to about 40 pounds per 3,000 square feet, as measured in an uncreped state, said sheet being characterized by having a structure which in cross-section comprises at least three superposed stratified fibrous layers, said outermost stratified layers being in contacting relation-ship with said central stratified layer for a major portion of their areas, each of said outermost stratified layers being partially displaced in a plane perpendicular to said sheet in small discrete deflected areas corresponding to the mesh openings in a foraminous fabric and comprising from about 100 to about 3,600 deflected areas per square inch, as measured in an uncreped state, said central stratified layer being substantially planar and continuous.
26. The soft, bulky and absorbent paper sheet of Claim 25, wherein said discrete deflected areas in said outermost stratified fibrous layers are of lower density than the remaining portions of said paper sheet.
27. The soft, bulky and absorbent paper sheet of Claim 26, wherein each of said outermost stratified layers is comprised primarily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches and said central-stratified layer is comprised primarily of relatively long papermaking fibers having an average length of at least about 0.08 inches, said sheet being further characterized by improved tactile impression on both surfaces thereof.
28. The soft, bulky and absorbent paper sheet of Claim 27, said sheet being further characterized by having a bulk density, as measured in an uncalendered state at a loading of 80 grams per square inch, of from about 0.020 to about 0.200 grams per cubic centimeter.
29, A process for the manufacture of a soft, bulky and absorbent unitary paper sheet having a basis weight between about 5 and about 40 pounds per 3,000 square feet, as measured in an uncreped state, which comprises the steps of:
(a) forming a moist paper web comprising at least two superposed stratified fibrous layers in contacting relationship;

(b) supporting said moist paper web on a foraminous fabric having between about 100 and about 3,600 mesh openings per square inch;

(c) subjecting said moist paper web to a pressure differential while on said fabric, thereby partially displacing at least one of said stratified fibrous layers in a plane perpendicular to said sheet in small discrete deflected areas corresponding to the mesh openings in said fabric;
and (d) final drying said sheet without disturbing the deflected areas of said one of said stratified layers.
30. The process of Claim 29, wherein the step of subjecting said moist paper web to a pressure differential is carried out while said web is at a fiber consistency not greater than about 25 percent.
31. The process of Claim 30, wherein the step of subjecting said moist paper web to a pressure differential is carried out by applying vacuum to the undersurface of said fabric.
32. The process of Claim 30, wherein the step of forming a moist paper web is carried out by combining a first stratified fibrous layer comprised pri-marily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches with a second stratified fibrous layer comprised primarily of relatively long papermaking fibers having an average length of at least about 0.08 inches while said fibrous layers are at a fiber consistency not greater than about 20 percent.
33. The process of Claim 32, wherein said foraminous fabric has a diagonal free span between about 0.005 and about 0.080 inches, and the step of supporting said moist paper web on said foraminous fabric is carried out by placing the surface of said web containing primarily short papermaking fibers in contact with the web supporting surface of said fabric.
34. The process of Claim 29, including the steps of thermally predrying said moist paper web to a fiber consistency of at least about 30 percent while on said fabric, and there-after subjecting discrete portions of said thermally predried web to compaction between the knuckles of said fabric and a non-yielding surface.
35. The process of Claim 34, including the steps of adhering said thermally predried paper web to the surface of a dryer drum at discrete locations corresponding to the areas of discrete compaction by the knuckles of said fabric, finally drying said paper web on the sur-face of said dryer drum, and creping said finally dried paper web during removal from said dryer drum by means of a doctor blade.
36. The process of Claim 29, including the steps of finally drying said moist paper web on said fabric and thereafter subjecting said finally dried paper web to mechanical micro-creping upon removal of said web from said fabric.
37. A process for the manufacture of a soft, bulky and absorbent unitary paper sheet having a basis weight between about 7 and about 25 pounds per 3,000 square feet, as measured in an uncreped state, which comprises the steps of:
(a) forming a first moist fibrous web on a foraminous support medium;

(b) superimposing on said first fibrous web a second moist fibrous web to form a stratified moist paper web;
(c) transferring said stratified moist paper web from said foraminous support medium to a foraminous drying/imprinting fabric having between about 100 and about 3,600 mesh openings per square inch and a diagonal free span between about 0.009 and about 0.054 inches by applying fluid pressure to said web while said web is at a fiber consistency between about 5 and about 25 .

percent, thereby partially displacing said fibrous layer in contact with the web supporting surface of said drying/imprinting fabric in small discrete deflected areas corresponding to the mesh openings in said fabric;

(d) thermally predrying said moist paper web to a fiber consistency of at least about 30 per-cent without disturbing the relationship of said web to said fabric; and (e) final drying the paper sheet thus formed.
38. The process of Claim 37, including the step of subjecting discrete portions of said thermally predried paper web to compaction between the knuckles of said fabric and a non-yielding surface.
39. The process of Claim 38, including the steps of adhering said thermally predried paper web to the surface of a dryer drum in discrete locations corresponding to the areas of discrete compaction by the knuckles of said fabric, finally drying said thermally predried paper web on the surface of said dryer drum, and creping said finally dried paper web during removal from said dryer drum by means of a doctor blade.
40. The process of Claim 39, including the step of calendering said finally dried, creped paper sheet to impart uniform caliper thereto.
41. The process of Claim 37, including the steps of finally drying said thermally predried paper web on said fabric and thereafter subjecting said finally dried paper web to mechanical micro-creping upon removal from said fabric.
42. The process of Claim 41, including the step of calendering said finally dried, mechanically micro-creped paper sheet to impart uniform caliper thereto.

.
43. The process of Claim 37, wherein said stratified moist paper web is formed by super-imposing a second moist fibrous web onto a first moist fibrous web of similar fiber content.
44. The process of Claim 37, wherein said stratified moist paper web is formed by super- -imposing a second moist fibrous web onto a first fibrous web of dissimilar fiber content.
45. The process of Claim 44, wherein said first fibrous web is comprised primarily of relatively long papermaking fibers having an average length between about 0.08 and about 0.12 inches, said second fibrous web is comprised primarily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches, and the step of transferring said stratified moist paper web from said foraminous support medium to said drying/
imprinting fabric is carried out by placing the surface of said web containing primarily short papermaking fibers in contact with the web supporting surface of said drying/
imprinting fabric.
46. The process of Claim 45, including the steps of thermally predrying said stratified moist paper web to a fiber consistency between about 30 and about 98 percent without disturbing the relationship of said web to said drying/imprinting fabric, and thereafter subjecting discrete portions of said thermally predried web to compaction between the knuckles of said drying/imprinting fabric and a non-yielding surface.

.
47. The process of Claim 46, including the steps of adhering said thermally predried paper web to the surface of a dryer drum at discrete locations corresponding to the areas of discrete compaction by the knuckles of said drying/imprinting fabric, finally drying said paper web on the surface of said dryer drum, and creping said finally dried paper web during removal from said dryer drum by means of a doctor blade.
48. The process of Claim 47, including the step of calendering said finally dried, creped paper sheet to impart uniform caliper thereto.
49. The process of Claim 45, including the steps of finally drying said thermally predried paper web on said drying/imprinting fabric and thereafter subjecting said finally dried paper sheet to mechanical micro-creping upon removal from said fabric.
50. The process of Claim 45, wherein the step of transferring said moist paper web from said foraminous support medium is carried out by applying vacuum to the undersurface of a foraminous drying/imprinting fabric having .
a diagonal free span which is greater than about one third times yet less than about 1.0 times the average fiber length in the short-fibered portion of said web, said diagonal free span also being less than about one third times the average fiber length in the long-fibered portion of said web.
51. A process for the manufacture of a soft, bulky and absorbent unitary paper sheet having a basis weight between about 8 and about 40 pounds per 3,000 square feet, as measured in an uncreped state, which comprises the steps of:
(a) forming a moist paper web comprising at least two superposed stratified fibrous layers in contacting relationship;

(b) supporting said moist paper web on a first foraminous fabric having between about 100 and about 3,600 mesh openings per square inch;

(c) subjecting said moist paper web to a pressure differential while on said first foraminous fabric, thereby partially displacing the stratified fibrous layer in contact with said fabric in a plane perpendicular to said sheet in small discrete deflected areas corresponding to the mesh openings in said fabric;

(d) superimposing a third fibrous layer on said moist paper web while said web is supported on said first foraminous fabric to form a unitary moist paper web having three stratified fibrous layers;

(e) transferring said moist paper web from said first foraminous fabric to a second foraminous fabric having between about 100 and about 3,600 mesh openings per square inch by applying vacuum to the undersurface of said second foraminous fabric while said web is at a fiber consistency between about 5 and about 25 percent, thereby partially displacing the fibrous layer in contact with the web supporting surface of said fabric in small discrete deflected areas corresponding to the mesh openings in said fabric;

(f) thermally predrying said moist paper web to a fiber consistency of at least about 30 per-cent without disturbing the relationship of said web to said second foraminous fabric; and (g) final drying the paper sheet thus formed.
52. The process of Claim 51, wherein the outermost fibrous layers of said three-layered web are comprised primarily of relatively short papermaking fibers having an average length between about 0.01 and about 0.06 inches and the central layer of said web is comprised primarily of relatively long papermaking fibers having an average length of at least about 0.08 inches, said three-layered web being formed by combining said fibrous layers with one another while at a fiber consistency not greater than about 20 percent.
53. The process of Claim 51, including the steps of finally drying said thermally predried paper web on said second foraminous fabric and thereafter subjecting said finally dried paper web to mechanical micro-creping upon removal from said fabric.
CA251,213A 1975-05-30 1976-04-27 Process for forming a layered paper web having improved bulk, tactile impresion and absorbency and paper thereof Expired CA1052158A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/582,521 US3994771A (en) 1975-05-30 1975-05-30 Process for forming a layered paper web having improved bulk, tactile impression and absorbency and paper thereof

Publications (1)

Publication Number Publication Date
CA1052158A true CA1052158A (en) 1979-04-10

Family

ID=24329469

Family Applications (1)

Application Number Title Priority Date Filing Date
CA251,213A Expired CA1052158A (en) 1975-05-30 1976-04-27 Process for forming a layered paper web having improved bulk, tactile impresion and absorbency and paper thereof

Country Status (18)

Country Link
US (1) US3994771A (en)
JP (1) JPS5221405A (en)
AT (1) AT367351B (en)
AU (1) AU509230B2 (en)
BE (1) BE842308A (en)
CA (1) CA1052158A (en)
CH (1) CH615719A5 (en)
DE (1) DE2623905C3 (en)
DK (1) DK147543C (en)
ES (1) ES448308A1 (en)
FI (1) FI57991C (en)
FR (1) FR2312600A1 (en)
GB (1) GB1543346A (en)
IE (1) IE43844B1 (en)
IT (1) IT1067532B (en)
LU (1) LU75050A1 (en)
NL (1) NL186461C (en)
SE (1) SE428941B (en)

Families Citing this family (473)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042740A (en) * 1974-09-20 1977-08-16 Minnesota Mining And Manufacturing Company Reinforced pillowed microfiber webs
US4112167A (en) * 1977-01-07 1978-09-05 The Procter & Gamble Company Skin cleansing product having low density wiping zone treated with a lipophilic cleansing emollient
US4102737A (en) * 1977-05-16 1978-07-25 The Procter & Gamble Company Process and apparatus for forming a paper web having improved bulk and absorptive capacity
US4133713A (en) * 1977-10-11 1979-01-09 The Procter & Gamble Company Microturbulence generator for papermachine headbox
EP0003377A1 (en) * 1978-01-19 1979-08-08 THE PROCTER & GAMBLE COMPANY Ply-separable absorbent paper sheet and process for its manufacture
US4196045A (en) * 1978-04-03 1980-04-01 Beloit Corporation Method and apparatus for texturizing and softening non-woven webs
JPS5715682Y2 (en) * 1978-12-26 1982-04-01
US4239792A (en) * 1979-02-05 1980-12-16 The Procter & Gamble Company Surface wiping device
US4225382A (en) * 1979-05-24 1980-09-30 The Procter & Gamble Company Method of making ply-separable paper
US4300981A (en) * 1979-11-13 1981-11-17 The Procter & Gamble Company Layered paper having a soft and smooth velutinous surface, and method of making such paper
US4302282A (en) * 1980-01-29 1981-11-24 The Procter & Gamble Company Method of and apparatus for making imprinted paper
US4482429A (en) * 1980-08-29 1984-11-13 James River-Norwalk, Inc. Paper webs having high bulk and absorbency and process and apparatus for producing the same
US4440597A (en) * 1982-03-15 1984-04-03 The Procter & Gamble Company Wet-microcontracted paper and concomitant process
US4464224A (en) * 1982-06-30 1984-08-07 Cip Inc. Process for manufacture of high bulk paper
US5102501A (en) * 1982-08-18 1992-04-07 James River-Norwalk, Inc. Multiple layer fibrous web products of enhanced bulk and method of manufacturing same
SE436049B (en) * 1983-03-30 1984-11-05 Korsnaes Marma Ab PROCEDURE FOR THE PREPARATION OF POWER PAPERS ON A MULTI-WIRE MACHINE PROCEDURE FOR THE PREPARATION OF POWER PAPERS ON A MULTI-WIRE MACHINE
US4637859A (en) * 1983-08-23 1987-01-20 The Procter & Gamble Company Tissue paper
US4529480A (en) * 1983-08-23 1985-07-16 The Procter & Gamble Company Tissue paper
JPS61194309U (en) * 1985-05-29 1986-12-03
US4734162A (en) * 1985-08-14 1988-03-29 The Procter & Gamble Company Hardwood pulp having a tactile sense of softness, and tissue paper webs thereof
US4735738A (en) 1985-10-21 1988-04-05 The Procter & Gamble Company Article with laminated paper orientation for improved fabric softening
US4741941A (en) * 1985-11-04 1988-05-03 Kimberly-Clark Corporation Nonwoven web with projections
JPS6285110U (en) * 1985-11-13 1987-05-30
US4913773A (en) * 1987-01-14 1990-04-03 James River-Norwalk, Inc. Method of manufacture of paperboard
US4834838A (en) * 1987-02-20 1989-05-30 James River Corporation Fibrous tape base material
GB8710428D0 (en) * 1987-05-01 1987-06-03 Beloit Corp Multi-ply web forming apparatus
US5223092A (en) * 1988-04-05 1993-06-29 James River Corporation Fibrous paper cover stock with textured surface pattern and method of manufacturing the same
US4940513A (en) * 1988-12-05 1990-07-10 The Procter & Gamble Company Process for preparing soft tissue paper treated with noncationic surfactant
US5059282A (en) * 1988-06-14 1991-10-22 The Procter & Gamble Company Soft tissue paper
US4959125A (en) * 1988-12-05 1990-09-25 The Procter & Gamble Company Soft tissue paper containing noncationic surfactant
US5164046A (en) * 1989-01-19 1992-11-17 The Procter & Gamble Company Method for making soft tissue paper using polysiloxane compound
US5227242A (en) * 1989-02-24 1993-07-13 Kimberly-Clark Corporation Multifunctional facial tissue
US5211815A (en) * 1989-10-30 1993-05-18 James River Corporation Forming fabric for use in producing a high bulk paper web
US5098519A (en) * 1989-10-30 1992-03-24 James River Corporation Method for producing a high bulk paper web and product obtained thereby
US5160789A (en) * 1989-12-28 1992-11-03 The Procter & Gamble Co. Fibers and pulps for papermaking based on chemical combination of poly(acrylate-co-itaconate), polyol and cellulosic fiber
US5260171A (en) * 1990-06-29 1993-11-09 The Procter & Gamble Company Papermaking belt and method of making the same using a textured casting surface
US5098522A (en) * 1990-06-29 1992-03-24 The Procter & Gamble Company Papermaking belt and method of making the same using a textured casting surface
US5275700A (en) * 1990-06-29 1994-01-04 The Procter & Gamble Company Papermaking belt and method of making the same using a deformable casting surface
US5679222A (en) * 1990-06-29 1997-10-21 The Procter & Gamble Company Paper having improved pinhole characteristics and papermaking belt for making the same
BR9106606A (en) * 1990-06-29 1993-04-20 Procter & Gamble PAPER MANUFACTURING BELT, PROCESS TO PRODUCE A PAPER MANUFACTURING BELT, TEXTURED REAR SIDE PAPER BELT, PROCESS TO PRODUCE AN ABSORBING, SOFT, RESISTANT PAPER TEXTURE AND BRAIDED PAPER MAKING TISSUE
US5087324A (en) * 1990-10-31 1992-02-11 James River Corporation Of Virginia Paper towels having bulky inner layer
US5397625A (en) * 1990-12-20 1995-03-14 Kimberly-Clark Corporation Duo-functional nonwoven material
ES2099793T3 (en) * 1991-01-15 1997-06-01 James River Corp HIGH SOFT TISSUE.
US5164045A (en) * 1991-03-04 1992-11-17 James River Corporation Of Virginia Soft, high bulk foam-formed stratified tissue and method for making same
US5215626A (en) * 1991-07-19 1993-06-01 The Procter & Gamble Company Process for applying a polysiloxane to tissue paper
US5227023A (en) * 1991-08-26 1993-07-13 James River Corporation Of Virginia Multi-layer papers and tissues
US5217576A (en) * 1991-11-01 1993-06-08 Dean Van Phan Soft absorbent tissue paper with high temporary wet strength
US5223096A (en) * 1991-11-01 1993-06-29 Procter & Gamble Company Soft absorbent tissue paper with high permanent wet strength
US5213588A (en) * 1992-02-04 1993-05-25 The Procter & Gamble Company Abrasive wiping articles and a process for preparing such articles
US5262007A (en) * 1992-04-09 1993-11-16 Procter & Gamble Company Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a temporary wet strength resin
US5264082A (en) * 1992-04-09 1993-11-23 Procter & Gamble Company Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a permanent wet strength resin
US5427696A (en) * 1992-04-09 1995-06-27 The Procter & Gamble Company Biodegradable chemical softening composition useful in fibrous cellulosic materials
US5348620A (en) * 1992-04-17 1994-09-20 Kimberly-Clark Corporation Method of treating papermaking fibers for making tissue
US5501768A (en) * 1992-04-17 1996-03-26 Kimberly-Clark Corporation Method of treating papermaking fibers for making tissue
NZ255759A (en) * 1992-08-27 1997-02-24 Procter & Gamble Tissue papers treated with non-ionic surfactant softeners (sorbitan esters)
US5246545A (en) * 1992-08-27 1993-09-21 Procter & Gamble Company Process for applying chemical papermaking additives from a thin film to tissue paper
US5246546A (en) * 1992-08-27 1993-09-21 Procter & Gamble Company Process for applying a thin film containing polysiloxane to tissue paper
US5543067A (en) * 1992-10-27 1996-08-06 The Procter & Gamble Company Waterless self-emulsiviable biodegradable chemical softening composition useful in fibrous cellulosic materials
US5240562A (en) * 1992-10-27 1993-08-31 Procter & Gamble Company Paper products containing a chemical softening composition
US5279767A (en) * 1992-10-27 1994-01-18 The Procter & Gamble Company Chemical softening composition useful in fibrous cellulosic materials
US5474689A (en) * 1992-10-27 1995-12-12 The Procter & Gamble Company Waterless self-emulsifiable chemical softening composition useful in fibrous cellulosic materials
US5312522A (en) * 1993-01-14 1994-05-17 Procter & Gamble Company Paper products containing a biodegradable chemical softening composition
US5494554A (en) * 1993-03-02 1996-02-27 Kimberly-Clark Corporation Method for making soft layered tissues
US5667636A (en) * 1993-03-24 1997-09-16 Kimberly-Clark Worldwide, Inc. Method for making smooth uncreped throughdried sheets
US5334286A (en) * 1993-05-13 1994-08-02 The Procter & Gamble Company Tissue paper treated with tri-component biodegradable softener composition
US5385642A (en) * 1993-05-13 1995-01-31 The Procter & Gamble Company Process for treating tissue paper with tri-component biodegradable softener composition
US5399412A (en) * 1993-05-21 1995-03-21 Kimberly-Clark Corporation Uncreped throughdried towels and wipers having high strength and absorbency
US5607551A (en) * 1993-06-24 1997-03-04 Kimberly-Clark Corporation Soft tissue
US5405501A (en) * 1993-06-30 1995-04-11 The Procter & Gamble Company Multi-layered tissue paper web comprising chemical softening compositions and binder materials and process for making the same
US5981044A (en) * 1993-06-30 1999-11-09 The Procter & Gamble Company Multi-layered tissue paper web comprising biodegradable chemical softening compositions and binder materials and process for making the same
US5437766A (en) * 1993-10-22 1995-08-01 The Procter & Gamble Company Multi-ply facial tissue paper product comprising biodegradable chemical softening compositions and binder materials
US5397435A (en) * 1993-10-22 1995-03-14 Procter & Gamble Company Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials
CA2119432A1 (en) * 1993-11-12 1995-05-13 Greg A. Wendt Method for making stratified tissue
MY131659A (en) * 1993-12-08 2007-08-30 Beloit Technologies Inc Machine and method for forming multiply linerboard from two sheets
US5904811A (en) * 1993-12-20 1999-05-18 The Procter & Gamble Company Wet pressed paper web and method of making the same
US5861082A (en) * 1993-12-20 1999-01-19 The Procter & Gamble Company Wet pressed paper web and method of making the same
CN1070964C (en) * 1993-12-20 2001-09-12 普罗克特和甘保尔公司 Wet pressed paper web and method of making same
US5562805A (en) * 1994-02-18 1996-10-08 Kimberly-Clark Corporation Method for making soft high bulk tissue
US5385643A (en) * 1994-03-10 1995-01-31 The Procter & Gamble Company Process for applying a thin film containing low levels of a functional-polysiloxane and a nonfunctional-polysiloxane to tissue paper
US5389204A (en) * 1994-03-10 1995-02-14 The Procter & Gamble Company Process for applying a thin film containing low levels of a functional-polysiloxane and a mineral oil to tissue paper
US5429686A (en) * 1994-04-12 1995-07-04 Lindsay Wire, Inc. Apparatus for making soft tissue products
CA2142805C (en) * 1994-04-12 1999-06-01 Greg Arthur Wendt Method of making soft tissue products
CA2134594A1 (en) * 1994-04-12 1995-10-13 Kimberly-Clark Worldwide, Inc. Method for making soft tissue products
ATE179473T1 (en) * 1994-06-29 1999-05-15 Procter & Gamble APPARATUS FOR MAKING A PATTERN ON A TAPE HAVING A FELT LAYER AND A PHOTOSENSITIVE RESIN LAYER AND METHOD FOR MAKING THE APPARATUS
US5814190A (en) * 1994-06-29 1998-09-29 The Procter & Gamble Company Method for making paper web having both bulk and smoothness
US5871887A (en) * 1994-06-29 1999-02-16 The Procter & Gamble Company Web patterning apparatus comprising a felt layer and a photosensitive resin layer
US5556509A (en) * 1994-06-29 1996-09-17 The Procter & Gamble Company Paper structures having at least three regions including a transition region interconnecting relatively thinner regions disposed at different elevations, and apparatus and process for making the same
US5549790A (en) * 1994-06-29 1996-08-27 The Procter & Gamble Company Multi-region paper structures having a transition region interconnecting relatively thinner regions disposed at different elevations, and apparatus and process for making the same
US6074527A (en) * 1994-06-29 2000-06-13 Kimberly-Clark Worldwide, Inc. Production of soft paper products from coarse cellulosic fibers
US6200419B1 (en) 1994-06-29 2001-03-13 The Procter & Gamble Company Paper web having both bulk and smoothness
US5582681A (en) * 1994-06-29 1996-12-10 Kimberly-Clark Corporation Production of soft paper products from old newspaper
US6001218A (en) * 1994-06-29 1999-12-14 Kimberly-Clark Worldwide, Inc. Production of soft paper products from old newspaper
US5679218A (en) * 1994-07-29 1997-10-21 The Procter & Gamble Company Tissue paper containing chemically softened coarse cellulose fibers
CA2145554C (en) * 1994-08-22 2006-05-09 Gary Lee Shanklin Soft layered tissues having high wet strength
US5510000A (en) * 1994-09-20 1996-04-23 The Procter & Gamble Company Paper products containing a vegetable oil based chemical softening composition
US5415737A (en) * 1994-09-20 1995-05-16 The Procter & Gamble Company Paper products containing a biodegradable vegetable oil based chemical softening composition
US5487813A (en) * 1994-12-02 1996-01-30 The Procter & Gamble Company Strong and soft creped tissue paper and process for making the same by use of biodegradable crepe facilitating compositions
US5573637A (en) * 1994-12-19 1996-11-12 The Procter & Gamble Company Tissue paper product comprising a quaternary ammonium compound, a polysiloxane compound and binder materials
US5575891A (en) * 1995-01-31 1996-11-19 The Procter & Gamble Company Soft tissue paper containing an oil and a polyhydroxy compound
US5624532A (en) * 1995-02-15 1997-04-29 The Procter & Gamble Company Method for enhancing the bulk softness of tissue paper and product therefrom
US5958185A (en) * 1995-11-07 1999-09-28 Vinson; Kenneth Douglas Soft filled tissue paper with biased surface properties
US5611890A (en) * 1995-04-07 1997-03-18 The Proctor & Gamble Company Tissue paper containing a fine particulate filler
US5830317A (en) * 1995-04-07 1998-11-03 The Procter & Gamble Company Soft tissue paper with biased surface properties containing fine particulate fillers
US5635028A (en) * 1995-04-19 1997-06-03 The Procter & Gamble Company Process for making soft creped tissue paper and product therefrom
US5538595A (en) * 1995-05-17 1996-07-23 The Proctor & Gamble Company Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound
ES2164751T3 (en) 1995-06-19 2002-03-01 Procter & Gamble SUPERIOR DOUBLE SHEETS PERFORATED FOR ABSORBENT ITEMS.
EP0749737B1 (en) * 1995-06-19 1999-11-24 The Procter & Gamble Company Sanitary articles with dual layer topsheet having a selected distribution of large apertures
JPH11510567A (en) * 1995-06-28 1999-09-14 ザ、プロクター、エンド、ギャンブル、カンパニー Crepe tissue paper showing unique combination of physical attributes
US5858554A (en) * 1995-08-25 1999-01-12 The Procter & Gamble Company Paper product comprising adhesively joined plies
US5693406A (en) * 1995-08-25 1997-12-02 The Procter & Gamble Company Multi-ply paper product
US5666744A (en) * 1995-11-02 1997-09-16 James River Corporation Of Virginia Infrared paper drying machine and method for drying a paper web in an infrared paper drying machine
US5578344A (en) * 1995-11-22 1996-11-26 The Procter & Gable Company Process for producing a liquid impermeable and flushable web
US5763044A (en) * 1995-11-22 1998-06-09 The Procter & Gamble Company Fluid pervious, dispersible, and flushable webs having improved functional surface
US5698076A (en) * 1996-08-21 1997-12-16 The Procter & Gamble Company Tissue paper containing a vegetable oil based quaternary ammonium compound
US5672249A (en) * 1996-04-03 1997-09-30 The Procter & Gamble Company Process for including a fine particulate filler into tissue paper using starch
US5700352A (en) * 1996-04-03 1997-12-23 The Procter & Gamble Company Process for including a fine particulate filler into tissue paper using an anionic polyelectrolyte
US6149767A (en) * 1997-10-31 2000-11-21 Kimberly-Clark Worldwide, Inc. Method for making soft tissue
US5865950A (en) * 1996-05-22 1999-02-02 The Procter & Gamble Company Process for creping tissue paper
US5944954A (en) * 1996-05-22 1999-08-31 The Procter & Gamble Company Process for creping tissue paper
US5906711A (en) * 1996-05-23 1999-05-25 Procter & Gamble Co. Multiple ply tissue paper having two or more plies with different discrete regions
EP0904456B1 (en) * 1996-05-23 2001-07-18 The Procter & Gamble Company Multiple ply tissue paper
US5840403A (en) * 1996-06-14 1998-11-24 The Procter & Gamble Company Multi-elevational tissue paper containing selectively disposed chemical papermaking additive
US5776311A (en) * 1996-09-03 1998-07-07 The Procter & Gamble Company Vacuum apparatus having transitional area for controlling the rate of application of vacuum in a through air drying papermaking process
US5885421A (en) * 1996-09-03 1999-03-23 The Procter & Gamble Company Vacuum apparatus for having textured clothing for controlling rate of application of vacuum pressure in a through air drying papermaking process
US5741402A (en) * 1996-09-03 1998-04-21 The Procter & Gamble Company Vacuum apparatus having plurality of vacuum sections for controlling the rate of application of vacuum pressure in a through air drying papermaking process
US5718806A (en) * 1996-09-03 1998-02-17 The Procter & Gamble Company Vacuum apparatus having flow management device for controlling the rate of application of vacuum pressure in a through air drying papermaking process
US5744007A (en) * 1996-09-03 1998-04-28 The Procter & Gamble Company Vacuum apparatus having textured web-facing surface for controlling the rate of application of vacuum pressure in a through air drying papermaking process
US5759346A (en) * 1996-09-27 1998-06-02 The Procter & Gamble Company Process for making smooth uncreped tissue paper containing fine particulate fillers
CA2269705C (en) * 1996-10-24 2004-07-13 The Procter & Gamble Company Layered tissue having improved functional properties
US6146496A (en) * 1996-11-14 2000-11-14 The Procter & Gamble Company Drying for patterned paper webs
US6296736B1 (en) 1997-10-30 2001-10-02 Kimberly-Clark Worldwide, Inc. Process for modifying pulp from recycled newspapers
US5814188A (en) * 1996-12-31 1998-09-29 The Procter & Gamble Company Soft tissue paper having a surface deposited substantive softening agent
US5851352A (en) * 1997-05-12 1998-12-22 The Procter & Gamble Company Soft multi-ply tissue paper having a surface deposited strengthening agent
US6280757B1 (en) * 1997-05-22 2001-08-28 The Procter & Gamble Company Cleansing articles for skin or hair
US6129815A (en) * 1997-06-03 2000-10-10 Kimberly-Clark Worldwide, Inc. Absorbent towel/wiper with reinforced surface and method for producing same
US6623834B1 (en) 1997-09-12 2003-09-23 The Procter & Gamble Company Disposable wiping article with enhanced texture and method for manufacture
CA2248727C (en) * 1997-12-19 2007-08-14 Kimberly-Clark Worldwide, Inc. Mechanical softening of sheet material
US6423183B1 (en) 1997-12-24 2002-07-23 Kimberly-Clark Worldwide, Inc. Paper products and a method for applying a dye to cellulosic fibers
US6180214B1 (en) 1998-01-26 2001-01-30 The Procter & Gamble Company Wiping article which exhibits differential wet extensibility characteristics
US6716514B2 (en) 1998-01-26 2004-04-06 The Procter & Gamble Company Disposable article with enhanced texture
US6270875B1 (en) 1998-01-26 2001-08-07 The Procter & Gamble Company Multiple layer wipe
US6039839A (en) * 1998-02-03 2000-03-21 The Procter & Gamble Company Method for making paper structures having a decorative pattern
US6547924B2 (en) 1998-03-20 2003-04-15 Metso Paper Karlstad Ab Paper machine for and method of manufacturing textured soft paper
US5972456A (en) * 1998-03-23 1999-10-26 Esquivel; Roberto Multi-ply toilet paper product
US6328850B1 (en) * 1998-04-16 2001-12-11 The Procter & Gamble Company Layered tissue having improved functional properties
US6280573B1 (en) 1998-08-12 2001-08-28 Kimberly-Clark Worldwide, Inc. Leakage control system for treatment of moving webs
US6287426B1 (en) 1998-09-09 2001-09-11 Valmet-Karlstad Ab Paper machine for manufacturing structured soft paper
US6387210B1 (en) 1998-09-30 2002-05-14 Kimberly-Clark Worldwide, Inc. Method of making sanitary paper product from coarse fibers
USD415353S (en) 1998-11-04 1999-10-19 Kimberly-Clark Worldwide, Inc. Embossed tissue
USD419779S (en) * 1998-11-04 2000-02-01 Kimberly-Clark Worldwide, Inc. Embossed tissue
USD419780S (en) * 1998-11-04 2000-02-01 Kimberly-Clark Worldwide, Inc. Embossed tissue
USD417962S (en) * 1998-11-04 1999-12-28 Kimberly-Clark Worldwide, Inc. Embossed tissue
US6248210B1 (en) 1998-11-13 2001-06-19 Fort James Corporation Method for maximizing water removal in a press nip
CA2287699A1 (en) * 1998-11-18 2000-05-18 Nancy S. Clungeon Soft highly absorbent paper product containing ketene dimer sizing agents
WO2000037740A1 (en) 1998-12-21 2000-06-29 Kimberly-Clark Worldwide, Inc. Wet-creped, imprinted paper web
US6241850B1 (en) 1999-06-16 2001-06-05 The Procter & Gamble Company Soft tissue product exhibiting improved lint resistance and process for making
WO2001011125A1 (en) 1999-08-03 2001-02-15 Kao Corporation Method of making bulking paper
US6447642B1 (en) * 1999-09-07 2002-09-10 The Procter & Gamble Company Papermaking apparatus and process for removing water from a cellulosic web
US6318727B1 (en) 1999-11-05 2001-11-20 Kimberly-Clark Worldwide, Inc. Apparatus for maintaining a fluid seal with a moving substrate
US6733626B2 (en) 2001-12-21 2004-05-11 Georgia Pacific Corporation Apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength
US6602387B1 (en) 1999-11-26 2003-08-05 The Procter & Gamble Company Thick and smooth multi-ply tissue
US6432267B1 (en) 1999-12-16 2002-08-13 Georgia-Pacific Corporation Wet crepe, impingement-air dry process for making absorbent sheet
US6379498B1 (en) * 2000-02-28 2002-04-30 Kimberly-Clark Worldwide, Inc. Method for adding an adsorbable chemical additive to pulp during the pulp processing and products made by said method
US6447640B1 (en) 2000-04-24 2002-09-10 Georgia-Pacific Corporation Impingement air dry process for making absorbent sheet
US6547926B2 (en) 2000-05-12 2003-04-15 Kimberly-Clark Worldwide, Inc. Process for increasing the softness of base webs and products made therefrom
DE60140492D1 (en) 2000-05-12 2009-12-24 Kimberly Clark Co Method for increasing the softness of base webs
US6607635B2 (en) * 2000-05-12 2003-08-19 Kimberly-Clark Worldwide, Inc. Process for increasing the softness of base webs and products made therefrom
US20030208175A1 (en) * 2000-06-12 2003-11-06 Gross James R. Absorbent products with improved vertical wicking and rewet capability
US6602577B1 (en) 2000-10-03 2003-08-05 The Procter & Gamble Company Embossed cellulosic fibrous structure
US6576090B1 (en) 2000-10-24 2003-06-10 The Procter & Gamble Company Deflection member having suspended portions and process for making same
US6420100B1 (en) 2000-10-24 2002-07-16 The Procter & Gamble Company Process for making deflection member using three-dimensional mask
US6576091B1 (en) 2000-10-24 2003-06-10 The Procter & Gamble Company Multi-layer deflection member and process for making same
US6660129B1 (en) * 2000-10-24 2003-12-09 The Procter & Gamble Company Fibrous structure having increased surface area
US6743571B1 (en) 2000-10-24 2004-06-01 The Procter & Gamble Company Mask for differential curing and process for making same
US6989075B1 (en) * 2000-11-03 2006-01-24 The Procter & Gamble Company Tension activatable substrate
US6610173B1 (en) 2000-11-03 2003-08-26 Kimberly-Clark Worldwide, Inc. Three-dimensional tissue and methods for making the same
KR100909010B1 (en) * 2000-11-14 2009-07-22 킴벌리-클라크 월드와이드, 인크. Improved Multi-Layer Tissue Products
US6602410B1 (en) 2000-11-14 2003-08-05 The Procter & Gamble Comapny Water purifying kits
US6749721B2 (en) 2000-12-22 2004-06-15 Kimberly-Clark Worldwide, Inc. Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition
US6752907B2 (en) * 2001-01-12 2004-06-22 Georgia-Pacific Corporation Wet crepe throughdry process for making absorbent sheet and novel fibrous product
US6582560B2 (en) 2001-03-07 2003-06-24 Kimberly-Clark Worldwide, Inc. Method for using water insoluble chemical additives with pulp and products made by said method
US7749356B2 (en) 2001-03-07 2010-07-06 Kimberly-Clark Worldwide, Inc. Method for using water insoluble chemical additives with pulp and products made by said method
US20030042195A1 (en) * 2001-09-04 2003-03-06 Lois Jean Forde-Kohler Multi-ply filter
US6824650B2 (en) 2001-12-18 2004-11-30 Kimberly-Clark Worldwide, Inc. Fibrous materials treated with a polyvinylamine polymer
US7214633B2 (en) 2001-12-18 2007-05-08 Kimberly-Clark Worldwide, Inc. Polyvinylamine treatments to improve dyeing of cellulosic materials
WO2003054497A2 (en) * 2001-12-20 2003-07-03 Kimberly-Clark Worldwide, Inc. Apparatus and method to measure tension in a moving web
US6649025B2 (en) 2001-12-31 2003-11-18 Kimberly-Clark Worldwide, Inc. Multiple ply paper wiping product having a soft side and a textured side
US7622020B2 (en) * 2002-04-23 2009-11-24 Georgia-Pacific Consumer Products Lp Creped towel and tissue incorporating high yield fiber
US6673203B1 (en) 2002-05-02 2004-01-06 Kimberly-Clark Worldwide, Inc. Soft low lint tissue
US20030228352A1 (en) * 2002-06-07 2003-12-11 The Procter & Gamble Company Cleansing articles for skin or hair
US7115551B2 (en) * 2002-06-07 2006-10-03 The Procter & Gamble Company Cleansing articles for skin or hair
US6918993B2 (en) 2002-07-10 2005-07-19 Kimberly-Clark Worldwide, Inc. Multi-ply wiping products made according to a low temperature delamination process
US7588660B2 (en) 2002-10-07 2009-09-15 Georgia-Pacific Consumer Products Lp Wet-pressed tissue and towel products with elevated CD stretch and low tensile ratios made with a high solids fabric crepe process
US7494563B2 (en) * 2002-10-07 2009-02-24 Georgia-Pacific Consumer Products Lp Fabric creped absorbent sheet with variable local basis weight
EP1556548B1 (en) * 2002-10-07 2008-11-19 Georgia-Pacific Consumer Products LP Process for making a creped cellulosic sheet
US7662257B2 (en) 2005-04-21 2010-02-16 Georgia-Pacific Consumer Products Llc Multi-ply paper towel with absorbent core
US7442278B2 (en) 2002-10-07 2008-10-28 Georgia-Pacific Consumer Products Lp Fabric crepe and in fabric drying process for producing absorbent sheet
US7585389B2 (en) 2005-06-24 2009-09-08 Georgia-Pacific Consumer Products Lp Method of making fabric-creped sheet for dispensers
US8911592B2 (en) 2002-10-07 2014-12-16 Georgia-Pacific Consumer Products Lp Multi-ply absorbent sheet of cellulosic fibers
US7789995B2 (en) * 2002-10-07 2010-09-07 Georgia-Pacific Consumer Products, LP Fabric crepe/draw process for producing absorbent sheet
US6752905B2 (en) * 2002-10-08 2004-06-22 Kimberly-Clark Worldwide, Inc. Tissue products having reduced slough
US6861380B2 (en) 2002-11-06 2005-03-01 Kimberly-Clark Worldwide, Inc. Tissue products having reduced lint and slough
EP1567718B1 (en) * 2002-11-07 2013-04-17 Georgia-Pacific Consumer Products LP Absorbent sheet exhibiting resistance to moisture penetration
US6887350B2 (en) 2002-12-13 2005-05-03 Kimberly-Clark Worldwide, Inc. Tissue products having enhanced strength
US6916402B2 (en) 2002-12-23 2005-07-12 Kimberly-Clark Worldwide, Inc. Process for bonding chemical additives on to substrates containing cellulosic materials and products thereof
US6769146B2 (en) * 2003-01-07 2004-08-03 Milliken & Company Transportation seat with release barrier fabrics
US7067038B2 (en) * 2003-02-06 2006-06-27 The Procter & Gamble Company Process for making unitary fibrous structure comprising randomly distributed cellulosic fibers and non-randomly distributed synthetic fibers
US7052580B2 (en) * 2003-02-06 2006-05-30 The Procter & Gamble Company Unitary fibrous structure comprising cellulosic and synthetic fibers
US7041196B2 (en) * 2003-02-06 2006-05-09 The Procter & Gamble Company Process for making a fibrous structure comprising cellulosic and synthetic fibers
US7381297B2 (en) * 2003-02-25 2008-06-03 The Procter & Gamble Company Fibrous structure and process for making same
CA2532040C (en) * 2003-07-23 2012-09-11 Fort James Corporation Method of curling fiber and absorbent sheet containing same
US7189307B2 (en) 2003-09-02 2007-03-13 Kimberly-Clark Worldwide, Inc. Low odor binders curable at room temperature
US20050045293A1 (en) 2003-09-02 2005-03-03 Hermans Michael Alan Paper sheet having high absorbent capacity and delayed wet-out
KR101087339B1 (en) 2003-09-02 2011-11-25 킴벌리-클라크 월드와이드, 인크. Low odor binders curable at room temperature
US6991706B2 (en) 2003-09-02 2006-01-31 Kimberly-Clark Worldwide, Inc. Clothlike pattern densified web
US7422658B2 (en) * 2003-12-31 2008-09-09 Kimberly-Clark Worldwide, Inc. Two-sided cloth like tissue webs
US7303650B2 (en) * 2003-12-31 2007-12-04 Kimberly-Clark Worldwide, Inc. Splittable cloth like tissue webs
US7476294B2 (en) 2004-10-26 2009-01-13 Voith Patent Gmbh Press section and permeable belt in a paper machine
US7351307B2 (en) * 2004-01-30 2008-04-01 Voith Paper Patent Gmbh Method of dewatering a fibrous web with a press belt
US7476293B2 (en) * 2004-10-26 2009-01-13 Voith Patent Gmbh Advanced dewatering system
US8293072B2 (en) 2009-01-28 2012-10-23 Georgia-Pacific Consumer Products Lp Belt-creped, variable local basis weight absorbent sheet prepared with perforated polymeric belt
EP2492393B1 (en) 2004-04-14 2016-07-06 Georgia-Pacific Consumer Products LP Absorbent product with elevated CD stretch and low tensile ratios made with a high solids fabric crepe process
US20050238701A1 (en) * 2004-04-23 2005-10-27 Joerg Kleinwaechter Fibrous structures comprising a transferable agent
US20050238699A1 (en) * 2004-04-23 2005-10-27 Joerg Kleinwaechter Fibrous structures comprising a surface treating composition and lotion composition
CN1946902A (en) * 2004-04-23 2007-04-11 宝洁公司 Fibrous structures comprising a surface treating composition and a lotion composition
ATE444398T1 (en) * 2004-04-23 2009-10-15 Procter & Gamble FIBER STRUCTURES WITH SURFACE TREATMENT COMPOSITION AND A LOTION COMPOSITION
CN1946903A (en) * 2004-04-23 2007-04-11 宝洁公司 Fibrous structures comprising a transferable agent
US7503998B2 (en) 2004-06-18 2009-03-17 Georgia-Pacific Consumer Products Lp High solids fabric crepe process for producing absorbent sheet with in-fabric drying
US7416637B2 (en) * 2004-07-01 2008-08-26 Georgia-Pacific Consumer Products Lp Low compaction, pneumatic dewatering process for producing absorbent sheet
US7297231B2 (en) 2004-07-15 2007-11-20 Kimberly-Clark Worldwide, Inc. Binders curable at room temperature with low blocking
US20060088696A1 (en) * 2004-10-25 2006-04-27 The Procter & Gamble Company Reinforced fibrous structures
US7510631B2 (en) * 2004-10-26 2009-03-31 Voith Patent Gmbh Advanced dewatering system
US8178025B2 (en) 2004-12-03 2012-05-15 Georgia-Pacific Consumer Products Lp Embossing system and product made thereby with both perforate bosses in the cross machine direction and a macro pattern
US7670459B2 (en) 2004-12-29 2010-03-02 Kimberly-Clark Worldwide, Inc. Soft and durable tissue products containing a softening agent
AU2006210986B2 (en) * 2005-01-31 2010-02-18 The Procter & Gamble Company An array of articles of manufacture
US7691472B2 (en) * 2005-06-23 2010-04-06 The Procter & Gamble Company Individualized seed hairs and products employing same
US7811613B2 (en) 2005-06-23 2010-10-12 The Procter & Gamble Company Individualized trichomes and products employing same
US9266301B2 (en) 2005-06-30 2016-02-23 Nalco Company Method to adhere and dislodge crepe paper
US7582577B2 (en) * 2005-08-26 2009-09-01 The Procter & Gamble Company Fibrous structure comprising an oil system
US8049060B2 (en) * 2005-08-26 2011-11-01 The Procter & Gamble Company Bulk softened fibrous structures
US20070071797A1 (en) * 2005-09-16 2007-03-29 Hernandez-Munoa Diego A Lotioned fibrous structures
US7749355B2 (en) 2005-09-16 2010-07-06 The Procter & Gamble Company Tissue paper
US20070098984A1 (en) * 2005-11-01 2007-05-03 Peterson James F Ii Fiber with release-material sheath for papermaking belts
US7820874B2 (en) * 2006-02-10 2010-10-26 The Procter & Gamble Company Acacia fiber-containing fibrous structures and methods for making same
CA2643188A1 (en) * 2006-02-22 2007-09-07 The Procter & Gamble Company Fibrous structures comprising volatile agents
US7850823B2 (en) * 2006-03-06 2010-12-14 Georgia-Pacific Consumer Products Lp Method of controlling adhesive build-up on a yankee dryer
US7527709B2 (en) * 2006-03-14 2009-05-05 Voith Paper Patent Gmbh High tension permeable belt for an ATMOS system and press section of paper machine using the permeable belt
US8540846B2 (en) 2009-01-28 2013-09-24 Georgia-Pacific Consumer Products Lp Belt-creped, variable local basis weight multi-ply sheet with cellulose microfiber prepared with perforated polymeric belt
US8187421B2 (en) * 2006-03-21 2012-05-29 Georgia-Pacific Consumer Products Lp Absorbent sheet incorporating regenerated cellulose microfiber
US7718036B2 (en) 2006-03-21 2010-05-18 Georgia Pacific Consumer Products Lp Absorbent sheet having regenerated cellulose microfiber network
US8187422B2 (en) 2006-03-21 2012-05-29 Georgia-Pacific Consumer Products Lp Disposable cellulosic wiper
EP1845187A3 (en) 2006-04-14 2013-03-06 Voith Patent GmbH Twin wire former for an atmos system
US7550061B2 (en) * 2006-04-28 2009-06-23 Voith Paper Patent Gmbh Dewatering tissue press fabric for an ATMOS system and press section of a paper machine using the dewatering fabric
US7524403B2 (en) * 2006-04-28 2009-04-28 Voith Paper Patent Gmbh Forming fabric and/or tissue molding belt and/or molding belt for use on an ATMOS system
US7744723B2 (en) * 2006-05-03 2010-06-29 The Procter & Gamble Company Fibrous structure product with high softness
US7741234B2 (en) * 2006-05-11 2010-06-22 The Procter & Gamble Company Embossed fibrous structure product with enhanced absorbency
US8455077B2 (en) 2006-05-16 2013-06-04 The Procter & Gamble Company Fibrous structures comprising a region of auxiliary bonding and methods for making same
DK2792789T3 (en) 2006-05-26 2017-10-16 Georgia Pacific Consumer Products Lp Creepy absorbent fabric web with variable local basis weight
US20080008865A1 (en) 2006-06-23 2008-01-10 Georgia-Pacific Consumer Products Lp Antimicrobial hand towel for touchless automatic dispensers
EP2057016B1 (en) * 2006-08-30 2017-04-26 Georgia-Pacific Consumer Products LP Multi-ply paper towel
US8236135B2 (en) * 2006-10-16 2012-08-07 The Procter & Gamble Company Multi-ply tissue products
US7799411B2 (en) * 2006-10-31 2010-09-21 The Procter & Gamble Company Absorbent paper product having non-embossed surface features
US7914649B2 (en) * 2006-10-31 2011-03-29 The Procter & Gamble Company Papermaking belt for making multi-elevation paper structures
US8357734B2 (en) * 2006-11-02 2013-01-22 Georgia-Pacific Consumer Products Lp Creping adhesive with ionic liquid
US7998313B2 (en) * 2006-12-07 2011-08-16 Georgia-Pacific Consumer Products Lp Inflated fibers of regenerated cellulose formed from ionic liquid/cellulose dope and related products
US8177938B2 (en) * 2007-01-19 2012-05-15 Georgia-Pacific Consumer Products Lp Method of making regenerated cellulose microfibers and absorbent products incorporating same
US9327888B2 (en) 2007-02-23 2016-05-03 The Procter & Gamble Company Array of sanitary tissue products
US7806973B2 (en) * 2007-03-05 2010-10-05 The Procter & Gamble Company Compositions for imparting images on fibrous structures
US20080271864A1 (en) * 2007-05-03 2008-11-06 The Procter & Gamble Company Soft tissue paper having a chemical softening agent applied onto a surface thereof
US20080271867A1 (en) * 2007-05-03 2008-11-06 The Procter & Gamble Company Soft tissue paper having a chemical softening agent applied onto a surface thereof
US20090029101A1 (en) 2007-07-26 2009-01-29 David Mark Rasch Fibrous structures comprising discrete bond regions and methods for making same
US20090038174A1 (en) * 2007-08-07 2009-02-12 Dar-Style Consultants & More Ltd. Kitchen utensil dryer
US20090054858A1 (en) * 2007-08-21 2009-02-26 Wendy Da Wei Cheng Layered sanitary tissue product having trichomes
US20090136722A1 (en) * 2007-11-26 2009-05-28 Dinah Achola Nyangiro Wet formed fibrous structure product
US7914648B2 (en) * 2007-12-18 2011-03-29 The Procter & Gamble Company Device for web control having a plurality of surface features
US7972475B2 (en) 2008-01-28 2011-07-05 The Procter & Gamble Company Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof
US7867361B2 (en) * 2008-01-28 2011-01-11 The Procter & Gamble Company Soft tissue paper having a polyhydroxy compound applied onto a surface thereof
US8080130B2 (en) * 2008-02-01 2011-12-20 Georgia-Pacific Consumer Products Lp High basis weight TAD towel prepared from coarse furnish
CA2651127A1 (en) 2008-02-01 2009-08-01 Georgia-Pacific Consumer Products Lp High basis weight tad towel prepared from coarse furnish
WO2010033536A2 (en) 2008-09-16 2010-03-25 Dixie Consumer Products Llc Food wrap basesheet with regenerated cellulose microfiber
US9649830B2 (en) 2008-12-03 2017-05-16 The Procter & Gamble Company Bonded fibrous sanitary tissue products and methods for making same
US8282775B2 (en) 2009-05-19 2012-10-09 The Procter & Gamble Company Web substrate having optimized emboss area
US8328984B2 (en) 2009-05-19 2012-12-11 The Procter & Gamble Company Web substrate having optimized emboss design
US20100294449A1 (en) * 2009-05-21 2010-11-25 Mcneil Kevin Benson Apparatus suitable for extended nip embossing
US20100294450A1 (en) * 2009-05-21 2010-11-25 Mcneil Kevin Benson Extended nip embossing apparatus
US20100295214A1 (en) * 2009-05-21 2010-11-25 Donn Nathan Boatman High pressure embossing process
US20100297402A1 (en) * 2009-05-21 2010-11-25 Donn Nathan Boatman Paper product produced by a high pressure embossing apparatus
US20100297281A1 (en) * 2009-05-21 2010-11-25 Mcneil Kevin Benson Extended nip embossing apparatus
US20100297286A1 (en) * 2009-05-21 2010-11-25 Donn Nathan Boatman High pressure embossing apparatus
US8034463B2 (en) 2009-07-30 2011-10-11 The Procter & Gamble Company Fibrous structures
US20110045252A1 (en) 2009-08-21 2011-02-24 David Mark Rasch Web materials comprising brown ink
JP5292517B2 (en) 2009-11-02 2013-09-18 ザ プロクター アンド ギャンブル カンパニー Fibrous structure and method for producing the same
CA2780158A1 (en) 2009-11-02 2011-11-05 The Procter & Gamble Company Fibrous structures that exhibit consumer relevant property values
US20110104970A1 (en) 2009-11-02 2011-05-05 Steven Lee Barnholtz Low lint fibrous structures and methods for making same
USD636608S1 (en) 2009-11-09 2011-04-26 The Procter & Gamble Company Paper product
CA2722650C (en) * 2009-12-07 2018-05-01 Georgia-Pacific Consumer Products Lp Method of moist creping absorbent paper base sheet
WO2011087975A1 (en) 2010-01-14 2011-07-21 The Procter & Gamble Company Soft and strong fibrous structures and methods for making same
US8334049B2 (en) 2010-02-04 2012-12-18 The Procter & Gamble Company Fibrous structures
US8449976B2 (en) 2010-02-04 2013-05-28 The Procter & Gamble Company Fibrous structures
US20110189451A1 (en) 2010-02-04 2011-08-04 John Allen Manifold Fibrous structures
US8334050B2 (en) 2010-02-04 2012-12-18 The Procter & Gamble Company Fibrous structures
US8383235B2 (en) 2010-02-04 2013-02-26 The Procter & Gamble Company Fibrous structures
WO2011106584A1 (en) 2010-02-26 2011-09-01 The Procter & Gamble Company Fibrous structure product with high wet bulk recovery
CA2795139C (en) 2010-03-31 2018-05-08 The Procter & Gamble Company Fibrous structure with absorbency, barrier protection and lotion release
US8282783B2 (en) 2010-05-03 2012-10-09 The Procter & Gamble Company Papermaking belt having a permeable reinforcing structure
US8287693B2 (en) 2010-05-03 2012-10-16 The Procter & Gamble Company Papermaking belt having increased de-watering capability
WO2011156300A1 (en) 2010-06-09 2011-12-15 The Procter & Gamble Company Apparatus for separating particles and methods for using same
AU2011268401A1 (en) 2010-06-18 2013-01-10 The Procter & Gamble Company High roll density fibrous structures
US8211271B2 (en) 2010-08-19 2012-07-03 The Procter & Gamble Company Paper product having unique physical properties
US8163130B2 (en) 2010-08-19 2012-04-24 The Proctor & Gamble Company Paper product having unique physical properties
US9220638B2 (en) 2010-09-10 2015-12-29 The Procter & Gamble Company Deformed web materials
US9067357B2 (en) 2010-09-10 2015-06-30 The Procter & Gamble Company Method for deforming a web
WO2012047992A1 (en) 2010-10-07 2012-04-12 The Procter & Gamble Company Sanitary tissue products and methods for making same
MX2013004145A (en) 2010-10-14 2013-05-20 Procter & Gamble Wet wipes.
CA2814765A1 (en) 2010-10-14 2012-04-19 The Procter & Gamble Company Wet wipes and methods for making same
US20120090112A1 (en) 2010-10-14 2012-04-19 Michael Edward Carrier Wet wipes, articles of manufacture, and methods for making same
US8916261B2 (en) 2011-03-04 2014-12-23 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8839717B2 (en) 2011-03-04 2014-09-23 The Procter & Gamble Company Unique process for printing multiple color indicia upon web substrates
US8962124B2 (en) 2011-03-04 2015-02-24 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8839716B2 (en) 2011-03-04 2014-09-23 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US8920911B2 (en) 2011-03-04 2014-12-30 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8758560B2 (en) 2011-03-04 2014-06-24 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8665493B2 (en) 2011-03-04 2014-03-04 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8943959B2 (en) 2011-03-04 2015-02-03 The Procter & Gamble Company Unique process for printing multiple color indicia upon web substrates
US8833250B2 (en) 2011-03-04 2014-09-16 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US8916260B2 (en) 2011-03-04 2014-12-23 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8616126B2 (en) 2011-03-04 2013-12-31 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US8943960B2 (en) 2011-03-04 2015-02-03 The Procter & Gamble Company Unique process for printing multiple color indicia upon web substrates
US8927093B2 (en) 2011-03-04 2015-01-06 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8927092B2 (en) 2011-03-04 2015-01-06 The Procter & Gamble Company Web substrates having wide color gamut indicia printed thereon
US8943957B2 (en) 2011-03-04 2015-02-03 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US8985013B2 (en) 2011-03-04 2015-03-24 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US8943958B2 (en) 2011-03-04 2015-02-03 The Procter & Gamble Company Apparatus for applying indicia having a large color gamut on web substrates
US10011953B2 (en) 2011-04-26 2018-07-03 The Procter & Gamble Company Bulked absorbent members
US9439815B2 (en) 2011-04-26 2016-09-13 The Procter & Gamble Company Absorbent members having skewed density profile
US9440394B2 (en) 2011-04-26 2016-09-13 The Procter & Gamble Company Methods of mechanically deforming materials
US20120277706A1 (en) 2011-04-26 2012-11-01 Luigi Marinelli Methods of Making Absorbent Members Having Density Profile
US9452089B2 (en) 2011-04-26 2016-09-27 The Procter & Gamble Company Methods of making absorbent members having density profile
US9028652B2 (en) 2011-04-26 2015-05-12 The Procter & Gamble Company Methods of making bulked absorbent members
BR112013025715A2 (en) 2011-04-26 2017-03-01 Procter & Gamble methods for the mechanical deformation of materials.
US20120277705A1 (en) 2011-04-26 2012-11-01 Luigi Marinelli Absorbent Members Having Skewed Density Profile
US9452093B2 (en) 2011-04-26 2016-09-27 The Procter & Gamble Company Absorbent members having density profile
US9452094B2 (en) 2011-04-26 2016-09-27 The Procter & Gamble Company Absorbent members having density profile
US8657596B2 (en) 2011-04-26 2014-02-25 The Procter & Gamble Company Method and apparatus for deforming a web
US9534325B2 (en) 2011-04-26 2017-01-03 The Procter & Gamble Company Methods of making absorbent members having skewed density profile
CA2844736C (en) 2011-08-09 2017-02-21 The Procter & Gamble Company Fibrous structures
EP2742181B1 (en) 2011-08-09 2017-03-01 The Procter and Gamble Company Fibrous structures
US9340914B2 (en) 2011-12-02 2016-05-17 The Procter & Gamble Company Fibrous structures and methods for making same
WO2013109659A1 (en) 2012-01-19 2013-07-25 The Procter & Gamble Company Hardwood pulp fiber-containing fibrous structures and methods for making same
US9458574B2 (en) 2012-02-10 2016-10-04 The Procter & Gamble Company Fibrous structures
WO2013133913A1 (en) 2012-03-05 2013-09-12 The Procter & Gamble Company Process for making absorbent component
CN104271837A (en) 2012-05-08 2015-01-07 宝洁公司 Fibrous structures and methods for making same
WO2013181302A1 (en) 2012-06-01 2013-12-05 The Procter & Gamble Company Fibrous structures and methods for making same
US20130327674A1 (en) 2012-06-11 2013-12-12 Jerry Ray Stephens Unique dispensing carton
US20130330512A1 (en) 2012-06-11 2013-12-12 Jerry Ray Stephens Unique material for forming dispensing cartons
US20130327675A1 (en) 2012-06-11 2013-12-12 The Procter & Gamble Company Unique dispensing carton
US20130327816A1 (en) 2012-06-11 2013-12-12 The Procter & Gamble Company Unique material for forming dispensing cartons
WO2014004939A1 (en) 2012-06-29 2014-01-03 The Procter & Gamble Company Textured fibrous webs, apparatus and methods for forming textured fibrous webs
US8968517B2 (en) 2012-08-03 2015-03-03 First Quality Tissue, Llc Soft through air dried tissue
BR112015002815B1 (en) 2012-08-10 2020-04-28 Int Paper Co soft pulp, process for preparing a soft pulp, core, process for preparing a core, absorbent product and process for preparing absorbent product.
US20140041818A1 (en) * 2012-08-10 2014-02-13 International Paper Company Fluff pulp and high sap loaded core
US8815054B2 (en) 2012-10-05 2014-08-26 The Procter & Gamble Company Methods for making fibrous paper structures utilizing waterborne shape memory polymers
WO2014081552A1 (en) 2012-11-20 2014-05-30 The Procter & Gamble Company Nonwoven sanitary tissue products comprising a woven surface pattern
MX2015006261A (en) 2012-11-20 2015-08-14 Procter & Gamble Nonwoven sanitary tissue products comprising a woven surface pattern.
US9410292B2 (en) 2012-12-26 2016-08-09 Kimberly-Clark Worldwide, Inc. Multilayered tissue having reduced hydrogen bonding
US9416494B2 (en) 2012-12-26 2016-08-16 Kimberly-Clark Worldwide, Inc. Modified cellulosic fibers having reduced hydrogen bonding
KR20160018586A (en) * 2013-06-10 2016-02-17 킴벌리-클라크 월드와이드, 인크. Soft and strong engineered tissue
EP3048944B1 (en) 2013-09-24 2020-07-08 The Procter and Gamble Company Wet wipes comprising a fibrous structure and a liquid composition
CA2925730A1 (en) 2013-09-27 2015-04-02 The Procter & Gamble Company Improved fibrous structures containing surfactants and methods for making the same
US9085130B2 (en) 2013-09-27 2015-07-21 The Procter & Gamble Company Optimized internally-fed high-speed rotary printing device
FR3015212A1 (en) 2013-12-19 2015-06-26 Procter & Gamble
CA2932638C (en) 2013-12-19 2021-06-08 The Procter & Gamble Company Sanitary tissue products
CA2932868C (en) 2013-12-19 2021-06-08 The Procter & Gamble Company Sanitary tissue products
GB2540668A (en) 2013-12-19 2017-01-25 Procter & Gamble Sanitary tissue products with free fibers and methods for making same
DE112014005939T5 (en) 2013-12-19 2016-09-29 The Procter & Gamble Company Sanitary tissue products
EP3096620A1 (en) 2014-01-24 2016-11-30 The Procter & Gamble Company Fibrous structures comprising a surface care composition and a bacteriophage
US20150272402A1 (en) 2014-03-25 2015-10-01 The Procter & Gamble Company Fibrous structures
US9238890B2 (en) 2014-03-25 2016-01-19 The Procter & Gamble Company Fibrous structures
US20150272401A1 (en) 2014-03-25 2015-10-01 The Procter & Gamble Company Fibrous structures
US9011644B1 (en) 2014-03-25 2015-04-21 The Procter & Gamble Company Papermaking belt for making fibrous structures
WO2015176063A1 (en) * 2014-05-16 2015-11-19 First Quality Tissue, Llc Flushable wipe and method of forming the same
US10132042B2 (en) 2015-03-10 2018-11-20 The Procter & Gamble Company Fibrous structures
US9988763B2 (en) 2014-11-12 2018-06-05 First Quality Tissue, Llc Cannabis fiber, absorbent cellulosic structures containing cannabis fiber and methods of making the same
US10765570B2 (en) 2014-11-18 2020-09-08 The Procter & Gamble Company Absorbent articles having distribution materials
US10517775B2 (en) 2014-11-18 2019-12-31 The Procter & Gamble Company Absorbent articles having distribution materials
WO2016086019A1 (en) 2014-11-24 2016-06-02 First Quality Tissue, Llc Soft tissue produced using a structured fabric and energy efficient pressing
MX2017006840A (en) 2014-12-05 2018-11-09 Manufacturing process for papermaking belts using 3d printing technology.
US9719213B2 (en) 2014-12-05 2017-08-01 First Quality Tissue, Llc Towel with quality wet scrubbing properties at relatively low basis weight and an apparatus and method for producing same
CA2914092A1 (en) * 2014-12-09 2016-06-09 The Procter & Gamble Company Processes for extracting trichomes from plants and fibrous structures employing same
MX2017008071A (en) 2014-12-19 2017-09-28 Procter & Gamble Coforming processes and forming boxes used therein.
WO2016100125A1 (en) 2014-12-19 2016-06-23 The Procter & Gamble Company Scrubby fibrous structures
US9822285B2 (en) 2015-01-28 2017-11-21 Gpcp Ip Holdings Llc Glue-bonded multi-ply absorbent sheet
US10385516B2 (en) 2015-02-27 2019-08-20 Kimberly-Clark Worldwide, Inc. Soft, strong and bulky tissue
US9938666B2 (en) 2015-05-01 2018-04-10 The Procter & Gamble Company Unitary deflection member for making fibrous structures having increased surface area and process for making same
US9976261B2 (en) 2015-05-01 2018-05-22 The Procter & Gamble Company Unitary deflection member for making fibrous structures having increased surface area and process for making same
US10933577B2 (en) 2015-05-01 2021-03-02 The Procter & Gamble Company Unitary deflection member for making fibrous structures having increased surface area and process for making same
WO2016196711A1 (en) 2015-06-03 2016-12-08 The Procter & Gamble Company Article of manufacture making system
WO2016196712A1 (en) 2015-06-03 2016-12-08 The Procter & Gamble Company Article of manufacture making system
WO2017004115A1 (en) 2015-06-30 2017-01-05 The Procter & Gamble Company Enhanced co-formed/meltblown fibrous web
EP3317445B1 (en) 2015-06-30 2020-12-23 The Procter and Gamble Company Enhanced co-formed/meltblown fibrous web structure and method for manufacturing
EP3325715A1 (en) 2015-07-24 2018-05-30 The Procter and Gamble Company Sanitary tissue products
US10538882B2 (en) 2015-10-13 2020-01-21 Structured I, Llc Disposable towel produced with large volume surface depressions
MX2018004621A (en) 2015-10-13 2019-08-12 First Quality Tissue Llc Disposable towel produced with large volume surface depressions.
WO2017066656A1 (en) 2015-10-14 2017-04-20 First Quality Tissue, Llc Bundled product and system and method for forming the same
US10144016B2 (en) 2015-10-30 2018-12-04 The Procter & Gamble Company Apparatus for non-contact printing of actives onto web materials and articles
US20170164808A1 (en) 2015-12-15 2017-06-15 The Procter & Gamble Company Pre-Moistened Fibrous Structures Exhibiting Increased Mileage
EP3390722B1 (en) 2015-12-15 2020-07-15 The Procter and Gamble Company Fibrous structures comprising three or more regions
US10428463B2 (en) 2015-12-15 2019-10-01 The Procter & Gamble Company Fibrous structures comprising regions having different micro-CT intensive property values and associated transition slopes
US10874279B2 (en) 2015-12-15 2020-12-29 The Procter & Gamble Company Compressible pre-moistened fibrous structures
EP3390718B1 (en) 2015-12-15 2021-03-03 The Procter and Gamble Company Fibrous structures comprising regions having different solid additive levels
US20170164809A1 (en) 2015-12-15 2017-06-15 The Procter & Gamble Company Pre-Moistened Fibrous Structures
EP3390716A2 (en) 2015-12-18 2018-10-24 The Procter and Gamble Company Flushable fibrous structures
EP3390717A1 (en) 2015-12-18 2018-10-24 The Procter and Gamble Company Methods for liberating trichome fibers from portions of a host plant
US10774476B2 (en) 2016-01-19 2020-09-15 Gpcp Ip Holdings Llc Absorbent sheet tail-sealed with nanofibrillated cellulose-containing tail-seal adhesives
US10208426B2 (en) 2016-02-11 2019-02-19 Structured I, Llc Belt or fabric including polymeric layer for papermaking machine
EP3426212B1 (en) 2016-03-11 2020-10-21 The Procter and Gamble Company Compositioned, textured nonwoven webs
WO2017156203A1 (en) 2016-03-11 2017-09-14 The Procter & Gamble Company A three-dimensional substrate comprising a tissue layer
CA3016186C (en) 2016-03-24 2020-04-14 The Procter & Gamble Company Unitary deflection member for making fibrous structures
WO2017165257A1 (en) 2016-03-24 2017-09-28 The Procter & Gamble Company Unitary deflection member for making fibrous structures
WO2017189665A1 (en) 2016-04-26 2017-11-02 The Procter & Gamble Company Sanitary tissue products
US20170314206A1 (en) 2016-04-27 2017-11-02 First Quality Tissue, Llc Soft, low lint, through air dried tissue and method of forming the same
WO2017205229A1 (en) 2016-05-23 2017-11-30 The Procter & Gamble Company Process for individualizing trichomes
US10801141B2 (en) 2016-05-24 2020-10-13 The Procter & Gamble Company Fibrous nonwoven coform web structure with visible shaped particles, and method for manufacture
US20180002848A1 (en) 2016-06-30 2018-01-04 The Procter & Gamble Company Enhanced co-formed/meltspun fibrous web structure
US10463205B2 (en) 2016-07-01 2019-11-05 Mercer International Inc. Process for making tissue or towel products comprising nanofilaments
US10724173B2 (en) 2016-07-01 2020-07-28 Mercer International, Inc. Multi-density tissue towel products comprising high-aspect-ratio cellulose filaments
US10570261B2 (en) 2016-07-01 2020-02-25 Mercer International Inc. Process for making tissue or towel products comprising nanofilaments
EP4050155A1 (en) 2016-08-26 2022-08-31 Structured I, LLC Absorbent structures with high wet strength, absorbency, and softness
US10422078B2 (en) 2016-09-12 2019-09-24 Structured I, Llc Former of water laid asset that utilizes a structured fabric as the outer wire
US10640928B2 (en) 2016-09-19 2020-05-05 Mercer International Inc. Absorbent paper products having unique physical strength properties
CA3037098C (en) 2016-10-25 2023-01-17 The Procter & Gamble Company Differential pillow height fibrous structures
EP3532673B8 (en) 2016-10-27 2022-12-07 The Procter & Gamble Company Deflection member for making fibrous structures
US11583489B2 (en) 2016-11-18 2023-02-21 First Quality Tissue, Llc Flushable wipe and method of forming the same
EP3551150A1 (en) 2016-12-08 2019-10-16 The Procter and Gamble Company Fibrous structures having a contact surface
CA3043530C (en) 2016-12-08 2021-06-01 The Procter & Gamble Company Cleaning pad with split core fibrous structures
CA3043527C (en) 2016-12-08 2021-08-24 The Procter & Gamble Company Pre-moistened cleaning pads
US10697123B2 (en) 2017-01-17 2020-06-30 Gpcp Ip Holdings Llc Zwitterionic imidazolinium surfactant and use in the manufacture of absorbent paper
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
KR20190116335A (en) 2017-02-22 2019-10-14 킴벌리-클라크 월드와이드, 인크. Laminated tissue comprising non-wood fibers
US10895038B2 (en) 2017-05-31 2021-01-19 Gpcp Ip Holdings Llc High consistency re-pulping method, apparatus and absorbent products incorporating recycled fiber
US10619309B2 (en) 2017-08-23 2020-04-14 Structured I, Llc Tissue product made using laser engraved structuring belt
US10792384B2 (en) 2017-12-15 2020-10-06 The Procter & Gamble Company Rolled fibrous structures comprising encapsulated malodor reduction compositions
US11207874B2 (en) 2017-12-26 2021-12-28 The Procter & Gamble Company Methods of making fibrous structures with shaped polymer particles
US10920376B2 (en) 2017-12-26 2021-02-16 The Procter & Gamble Company Fibrous structures with shaped polymer particles
CN111819325B (en) * 2018-01-05 2023-05-12 国际纸业公司 Paper product with increased bending stiffness and transverse strength and method of making same
CA3096843A1 (en) 2018-04-12 2019-10-17 Mercer International, Inc. Processes for improving high aspect ratio cellulose filament blends
WO2019222348A1 (en) 2018-05-15 2019-11-21 Structured I, Llc Manufacturing process for papermaking endless belts using 3d printing technology
DE102018114748A1 (en) 2018-06-20 2019-12-24 Voith Patent Gmbh Laminated paper machine clothing
US11697538B2 (en) 2018-06-21 2023-07-11 First Quality Tissue, Llc Bundled product and system and method for forming the same
US11738927B2 (en) 2018-06-21 2023-08-29 First Quality Tissue, Llc Bundled product and system and method for forming the same
US11180888B2 (en) 2018-06-29 2021-11-23 The Procter & Gamble Company Fibrous structures comprising trichome compositions and methods for obtaining same
US11427960B2 (en) 2018-06-29 2022-08-30 The Procter & Gamble Company Bleaching trichomes to remove proteins
US20200002889A1 (en) 2018-06-29 2020-01-02 The Procter & Gamble Company Process for Separating Trichomes from Non-Trichome Materials
WO2020028735A1 (en) 2018-08-03 2020-02-06 The Procter & Gamble Company Webs with compositions thereon
US11813148B2 (en) 2018-08-03 2023-11-14 The Procter And Gamble Company Webs with compositions applied thereto
JP2021532945A (en) 2018-08-22 2021-12-02 ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company Disposable absorbent goods
US11700979B2 (en) 2018-10-26 2023-07-18 The Procter & Gamble Company Sanitary tissue product rolls
CA3060180A1 (en) 2018-10-26 2020-04-26 The Procter & Gamble Company Sanitary tissue product rolls
US11447916B2 (en) 2018-10-26 2022-09-20 The Procter & Gamble Company Paper towel rolls
US11118311B2 (en) 2018-11-20 2021-09-14 Structured I, Llc Heat recovery from vacuum blowers on a paper machine
CA3064406C (en) 2018-12-10 2023-03-07 The Procter & Gamble Company Fibrous structures
US11332889B2 (en) 2019-05-03 2022-05-17 First Quality Tissue, Llc Absorbent structures with high absorbency and low basis weight
MX2021014205A (en) 2019-05-22 2022-07-04 First Quality Tissue Se Llc Woven base fabric with laser energy absorbent md and cd yarns and tissue product made using the same.
US11590693B2 (en) 2019-05-31 2023-02-28 The Procter & Gamble Company Methods of making a deflection member
CA3081992A1 (en) 2019-06-06 2020-12-06 Structured I, Llc Papermaking machine that utilizes only a structured fabric in the forming of paper
US11124920B2 (en) 2019-09-16 2021-09-21 Gpcp Ip Holdings Llc Tissue with nanofibrillar cellulose surface layer
KR20220085795A (en) * 2019-10-21 2022-06-22 킴벌리-클라크 월드와이드, 인크. Absorbent articles and methods for making same
AU2021400323A1 (en) 2020-12-17 2023-07-06 First Quality Tissue, Llc Wet laid disposable absorent structures with high wet strenght and method of making the same
WO2023081744A1 (en) 2021-11-04 2023-05-11 The Procter & Gamble Company Web material structuring belt, method for making structured web material and structured web material made by the method
WO2023081746A1 (en) 2021-11-04 2023-05-11 The Procter & Gamble Company Web material structuring belt, method for making and method for using
US20230137439A1 (en) 2021-11-04 2023-05-04 The Procter & Gamble Company Web material structuring belt, method for making and method for using
WO2023081747A1 (en) 2021-11-04 2023-05-11 The Procter & Gamble Company Web material structuring belt, method for making and method for using
CN114687238B (en) * 2022-03-09 2023-07-21 海南金海浆纸业有限公司 Preparation method of high-bulk coated paper based on three-layer headbox single-layer net paper making

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB149758A (en) 1919-05-16 1920-08-16 Walter William Colley Improvements in and in the manufacture of creped paper
US1969938A (en) * 1932-10-15 1934-08-14 Jere C Mosher Method of making composite paper
US2018382A (en) * 1934-10-24 1935-10-22 Hummel Ross Fibre Corp Art of ply paper or board manufacture
US2908733A (en) * 1954-09-28 1959-10-13 Texaco Development Corp Process for conducting gaseous reactions
US2881669A (en) * 1955-03-01 1959-04-14 St Annes Board Mill Co Ltd Paper or board product
US2996424A (en) * 1957-02-12 1961-08-15 Kimberly Clark Co Method of creping tissue and product thereof
GB1117731A (en) * 1963-09-17 1968-06-26 Wycombe Marsh Paper Mills Ltd Two-layer paper
US3301746A (en) * 1964-04-13 1967-01-31 Procter & Gamble Process for forming absorbent paper by imprinting a fabric knuckle pattern thereon prior to drying and paper thereof
US3424643A (en) * 1965-11-08 1969-01-28 Kimberly Clark Co Sheet material creped tissue product
US3778341A (en) * 1971-03-17 1973-12-11 Johnson & Johnson Nonwoven textile fabrics and methods of making the same
US3812000A (en) * 1971-06-24 1974-05-21 Scott Paper Co Soft,absorbent,fibrous,sheet material formed by avoiding mechanical compression of the elastomer containing fiber furnished until the sheet is at least 80%dry
US3879257A (en) * 1973-04-30 1975-04-22 Scott Paper Co Absorbent unitary laminate-like fibrous webs and method for producing them
US3905863A (en) * 1973-06-08 1975-09-16 Procter & Gamble Process for forming absorbent paper by imprinting a semi-twill fabric knuckle pattern thereon prior to final drying and paper thereof
GB1504374A (en) * 1974-06-21 1978-03-22 Kimberly Clark Co Creped laminar tissue and process and machine for the manufacture thereof

Also Published As

Publication number Publication date
NL7605733A (en) 1976-12-02
IE43844L (en) 1976-11-30
DK147543B (en) 1984-09-24
DE2623905B2 (en) 1979-08-09
FI761521A (en) 1976-12-01
FR2312600A1 (en) 1976-12-24
IT1067532B (en) 1985-03-16
DE2623905C3 (en) 1980-04-10
AT367351B (en) 1982-06-25
CH615719A5 (en) 1980-02-15
IE43844B1 (en) 1981-06-17
BE842308A (en) 1976-11-29
US3994771A (en) 1976-11-30
ATA392076A (en) 1981-11-15
GB1543346A (en) 1979-04-04
NL186461B (en) 1990-07-02
AU1390476A (en) 1977-11-17
LU75050A1 (en) 1977-02-15
SE7605986L (en) 1976-12-01
DE2623905A1 (en) 1976-12-09
DK147543C (en) 1985-03-11
SE428941B (en) 1983-08-01
DK237376A (en) 1976-12-01
FR2312600B1 (en) 1979-07-13
NL186461C (en) 1990-12-03
JPS5221405A (en) 1977-02-18
FI57991C (en) 1980-11-10
AU509230B2 (en) 1980-05-01
ES448308A1 (en) 1977-12-01
FI57991B (en) 1980-07-31

Similar Documents

Publication Publication Date Title
CA1052158A (en) Process for forming a layered paper web having improved bulk, tactile impresion and absorbency and paper thereof
US3692622A (en) Air formed webs of bonded pulp fibers
CA1052157A (en) Two-ply tissue product
US5654076A (en) Cellulosic fibrous structures having discrete regions with radially oriented fibers therein
US3905863A (en) Process for forming absorbent paper by imprinting a semi-twill fabric knuckle pattern thereon prior to final drying and paper thereof
AU748123B2 (en) Extensible paper web and method of forming
US7497926B2 (en) Shear-calendering process for producing tissue webs
US5897745A (en) Method of wet pressing tissue paper
AU2001259850B8 (en) Process for increasing the softness of base webs and products made therefrom
EP2078108B1 (en) Papermaking machine with an impermeable transfer belt and associated method
US5855739A (en) Pressed paper web and method of making the same
CA1146396A (en) Layered paper having a soft and smooth velutinous surface, and method of making such paper
US7497925B2 (en) Shear-calendering processes for making rolled tissue products having high bulk, softness and firmness
US6103062A (en) Method of wet pressing tissue paper
US6939440B2 (en) Creped and imprinted web
EP2179088A1 (en) Acacia fiber-containing fibrous structures and methods for making same
WO1997033043A1 (en) High-density absorbent structure
EP1657052A1 (en) Process for increasing the softness of base webs and products made therefrom
EP0885330A1 (en) High-density absorbent structure