CA1113639A - Catalyst for condensation of hydrolyzable silanes and storage stable compositions thereof - Google Patents
Catalyst for condensation of hydrolyzable silanes and storage stable compositions thereofInfo
- Publication number
- CA1113639A CA1113639A CA294,094A CA294094A CA1113639A CA 1113639 A CA1113639 A CA 1113639A CA 294094 A CA294094 A CA 294094A CA 1113639 A CA1113639 A CA 1113639A
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- CA
- Canada
- Prior art keywords
- group
- carbon atoms
- silane
- less
- valence
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
- C08G77/08—Preparatory processes characterised by the catalysts used
Abstract
A composition of matter comprising hydrolyzable silane compounds and an aromatic of an organoatomic cation of a Group Va, VIa, VIIa atom can be storage stable and may be subsequently cured by exposure to radiation.
Description
,357 ~ 3~ ~ ~
CATALYST ~OR CONDENSATION 0~ HYDROLYZABLE
SXLANES AND STORA~E STABLE COMPOSITIONS TIIEREOF
The present invention relates to the condensa-tion polymerization of silanes. Polymerizable silanes are those sillcon containing compounds which have at least one labile group thereonO With one labile group on the silicon atom, only a dimer would be produced.
With two labile groups a linear polymer would result from condensation, and with three or more labile groups, three-dimensional reslns (cross-linked) would be generated. Hydrolyzable silanes according to the present lnvention may be represented by the formula:
XmSiR4 m wherein X is a labile group, R is a hydrocarbyl group, and m is an integer 2, 3 or 4.
By the term labile group, as used in the practice of the present invention is meant any hydrolyzable group ~; and hydrogen~ Exemplary labile groups are alkoxy sub-` stituted alkoxyl, aryloxy, acyloxy, halogen, and hydrogen~
these types of silanes being well known in the artO
These labile groups may contain heteroatoms, and may be linearg branched or cyclic as long as the labile group is hydrolyzable.
The term hydrocarbyl is defined in the practice - of the present invention as groups resulting from the removal of hydrogen from the carbon atoms of a hydro-carbon, including hydrocarbons con~aining one or more heteroatoms selected from oxygen, sulfur and nitrogen.
Exemplary hydrocarbyl groups include aromatic groups ~'` . ' ~ .
` ~
containing~ one to ten carbonc; (e.g.~ phenyl, naphth~ll and a benzothlenyl) and aliphatic groups containing 1 to 18 carbon atoms. The aliphatic groups may be linear~
branched or cycllc (eOg , methyl, ethyl, isopropyl~
propyl, cyclohexyl, octyl, dodecyl~ octadecyl~ ethoxy-ethyl, ethoxyethoxyethyl, thioethox~ethyl, tetrah~dro~
furyl, tetrahydrothienyl, dloxanyl, etc.)O The hydrocarbyl group may be substituted with a non-basic functional or non-functional group such as halogen, alkoxy, epoxy, phenoxy, cyano, ~inyl, allyl, acryloxy, ~ methacryloxy and the llke. For example, R may be - CH2=CR'-COO(CH2)n (where R is H or CH3 and n is 0 or 1-8).
Exemplary classes of polymerizable silanes j 15 are hydrolyzable silanes falling within the general formula as silanes, silanols, siloxanes~ alkoxysllanes, aryloxysilanes, acyloxysilanes, haloalkylsilanes, haloarylsilanes, etc~ It ls generally well known in the silane condensation art that almost any functional group can be introduced into the side chain of an alkyl or aryl-substituted silane without affectlng functionality of the silane during condensation, so that a detailed description of operational substituents is unnecessary.
Specific compounds falling into the broad class of polymerizable silanes are, for example:
(CH3)3siocH3 CH3Si(OCH3)3 ~; CH3Si(C6H13)3 (CH3)2si(oc2Hs)cH CH2
CATALYST ~OR CONDENSATION 0~ HYDROLYZABLE
SXLANES AND STORA~E STABLE COMPOSITIONS TIIEREOF
The present invention relates to the condensa-tion polymerization of silanes. Polymerizable silanes are those sillcon containing compounds which have at least one labile group thereonO With one labile group on the silicon atom, only a dimer would be produced.
With two labile groups a linear polymer would result from condensation, and with three or more labile groups, three-dimensional reslns (cross-linked) would be generated. Hydrolyzable silanes according to the present lnvention may be represented by the formula:
XmSiR4 m wherein X is a labile group, R is a hydrocarbyl group, and m is an integer 2, 3 or 4.
By the term labile group, as used in the practice of the present invention is meant any hydrolyzable group ~; and hydrogen~ Exemplary labile groups are alkoxy sub-` stituted alkoxyl, aryloxy, acyloxy, halogen, and hydrogen~
these types of silanes being well known in the artO
These labile groups may contain heteroatoms, and may be linearg branched or cyclic as long as the labile group is hydrolyzable.
The term hydrocarbyl is defined in the practice - of the present invention as groups resulting from the removal of hydrogen from the carbon atoms of a hydro-carbon, including hydrocarbons con~aining one or more heteroatoms selected from oxygen, sulfur and nitrogen.
Exemplary hydrocarbyl groups include aromatic groups ~'` . ' ~ .
` ~
containing~ one to ten carbonc; (e.g.~ phenyl, naphth~ll and a benzothlenyl) and aliphatic groups containing 1 to 18 carbon atoms. The aliphatic groups may be linear~
branched or cycllc (eOg , methyl, ethyl, isopropyl~
propyl, cyclohexyl, octyl, dodecyl~ octadecyl~ ethoxy-ethyl, ethoxyethoxyethyl, thioethox~ethyl, tetrah~dro~
furyl, tetrahydrothienyl, dloxanyl, etc.)O The hydrocarbyl group may be substituted with a non-basic functional or non-functional group such as halogen, alkoxy, epoxy, phenoxy, cyano, ~inyl, allyl, acryloxy, ~ methacryloxy and the llke. For example, R may be - CH2=CR'-COO(CH2)n (where R is H or CH3 and n is 0 or 1-8).
Exemplary classes of polymerizable silanes j 15 are hydrolyzable silanes falling within the general formula as silanes, silanols, siloxanes~ alkoxysllanes, aryloxysilanes, acyloxysilanes, haloalkylsilanes, haloarylsilanes, etc~ It ls generally well known in the silane condensation art that almost any functional group can be introduced into the side chain of an alkyl or aryl-substituted silane without affectlng functionality of the silane during condensation, so that a detailed description of operational substituents is unnecessary.
Specific compounds falling into the broad class of polymerizable silanes are, for example:
(CH3)3siocH3 CH3Si(OCH3)3 ~; CH3Si(C6H13)3 (CH3)2si(oc2Hs)cH CH2
-2-~',`~''~ .
~ ~ 3~3 ;' ~OC(C~13)2 (C~13)2Sl~ I
OC(CH3)2 CH3Si(c~H5)(Oc2H5)2
~ ~ 3~3 ;' ~OC(C~13)2 (C~13)2Sl~ I
OC(CH3)2 CH3Si(c~H5)(Oc2H5)2
3 (CH2)3si(ocH3)3 (NC5H4)SiCH3(0c2H5)2 2C C(cH3)coo(cH2)3sicH3~oc2H5)2 H3C_cH2_o-CH2-CH2-SiCH3(OC2H5)2 ( 3 4 (CH2=CH-CH2)2si(OcH3)2 It is also known that polymers having at least one pendant or terminal polymerizable silane group may be cured by various techniques. Exemplary curable silyl-substituted polymers of this type are the poly-merizable silane-terminated polyurethanes described in U.S. Patent NoO 3,632,557 (particularly col. 5~ line 57 to col~ 6, line 6) and the free radical polymerized polymers of olefinically unsaturated silanes and their copolymers with other copolymerizable olefinically unsaturated monomers such as are described in U.S. -Patent Nos. 3,449,293; 3,453,230; 3,542,585 and 3,706,697 Various techniques are known in the art for controlling the condensatlon or hydrolysis reaction.
Many different catalyst systems for condensation of silanes are also known in the art. Each of the various ', :~:
: : . . ....
;: ~, , ~ -: I .
6~9 ~echniques and catalysts adds its own partlcular qualities to the requlrements of the reaction and the properties of the product. For example, strong acids ~avor the forma-tion o~ low molecular weight cyclic polymer units, silanols are stabilized in nearly neutral solutlons and preferentially condense to siloxanes in the presence o~
strong bases, Lewis acid metal salt catalysts such as stannous chloride require heat, and hydrolyzable metal esters will cure at room temperatures. Combinations of the catalysts and reaction conditions can be used to ad~ust these variables to a most desired balance for a particular intended use.
The present invention relates to a new catalyst system for hydrolyzable silanes which catalyzes the condensation reaction of silanes. These catalysts are storage stable when anhydrously mixed with the silane and are activated by incident radiation in the presence of catalytic amounts of moisture (e.g., atmospheric moisture is sufficient). The catal~sts of this invention are rapid acting cat,alysts and generate polymers with excellent properties.
More particularly the present invention relates to storage stable anhydrous compositions of a hydrolyzable ; silane and an onium catalyst and to a process of con-: 25 densing hydrolyzable silanes in the presence of onium `~ catalysts.
An onium catalyst useful in the practice of the present invention is an aromatic (which includes di-aromatic, triaromatic~ and tetraaromatic as well as monoaromatic), organic adduct of an aromatic organo-3~3~
a-tomic cation oE a Group Va, VIa, or VIIa atom par-I ticularly phosphorous, antimony, sulfur, nitrogen, and iodine atoms, and an anion.* When -the nominative atom is a halogen, the compound must be at least diaromatic.
Aromatic, as used in the description of the yroups on the catalysts of the present invention means an aromatic ring (hydrocarbon, or 5, 6, or 7 membered heterocycle comprised of only C, N, S, O, and Se atoms with no more than one atom in the ring selected from S, O, or Se . ~ 10 atoms) so attached to the nominative atom that it is at least as electron withdrawing as benzene. For ~ O
example, phenacyl ~ -C-CH2, would be a useful aromatic ~ group (being at least as electron withdrawing as ben-;; 15 zene), but benzyl ~ CH2- would not be useful because :
of instability of the compound which would irnpair :~ storage stability. Representative aromatic rings are phenyl, naphthyl, thienyl, pyranyl, furanyl and pyrazolyl, substituted or not.
:
:` 20 A descriptive formula for the onium catalysts `~ of the present invention would be R2) A-~
( n (R )a ~ wherein R .LS an aromatic gro.up at least as electron `. 25 withdrawing as benzene, . ~ :
,:
:
*For purposes of convenience in describing these onium catalysts, the Group Va, VIa, or VIIa atom that provides the major nomenclature for the adduct (e.g., phosphorous :
in phosphonium, sulfur in sulfonium, iodine in iodonium, :
etc.) will be called the nominative atom.
, ` ~ :
~3~i39 Rl ls alkyl (straight, branched, cyclic or substitll-ted), or alkenyl having 1 to 18 carbon ; atoms, ` n is a positive who:Le integer of at least 1 (preferably 2) up to the valence of A plus one, a is 0 or a positive whole integer of up -to the valence of A (preferably A minus 1), 'f~ n plus a is equal -to the valence of A plus one, A is a group Va, VIa, or VIIa atom, and is an anion, with the proviso that when A is halogen, n is at least 2.
~` These onium materials are already known in the 15 art. For example, Belgian Patents 833,472; 828,668;
`~ 828,669; and 828,670 show the use of certain onium compounds as cationic polymerization catalysts for specific monomers such as organosilicon cyclics, vinyl resins, cyclic ethers, cyclic esters, cyclic sulfides, epoxy resins, phenolic resins, polyamines, lactones, ;~ styrene, urea/formaldehyde and melamine/formaldehyde :
resins. The only known ~isclosure of utility in these ; references with regard to silicon containing polymers is believed to be in Belgian Patent 828,670 wherein cyclic organosilicons are polymerized by a ring opening -~ catalytic action, much in the same manner that epoxy resins are polymerized. ~o catalysis for silane conden-sation as described in the present invention is shown.
~; Other organo groups attached to the Group Va, or VIa .
nominative atom can be the same aromatic group or a ~'. ~.
,....,. ~
3~
~ substltuted or unsubstituted alkyl or cycloalkyl group.
`~ The organo groups may also be dlrect:ly attached one to another via a bond, a methylene group, a -CO- group, an S02 group, an oxygen~ or sulfur or the llke. One or more of the organo groups can shar~e two atoms in a condensed ring system.
Specific classes of' hydrol~zable silanes ~or use in the compositions of the inventlon are those having the general formulae:
Rm 4SiXm, R2[0-CO NH-R3-NH-Co-Y-R5-Si(oR6)3]p and ¦CH2 C ---~rH CA ~
L(~ = C - ~ q)rs~o~6)~ L ~ t wherein R, X, and m are as defined herein above and R2 is a polyvalent radical which is the residue resulting from the removal of p hydroxyl groups from a polyhydroxy compound having a molecular weight of from 200 to 6000~ p is an integer o~
from 1 to 60 R3 is a divalent alkylene group having from 1 to 18 carbon atoms or a divalent aromatic radical having from 6 to 18 carbon atoms and is the alkyl or aromatic portion of a diisocyanate compound on removal of the iso- ;~
cyanate groups. R3, for example, can be aliphatic cycloaliphatic, araliphatic or aromaticO Y is a divalent bridglng group selected from -O-, -S-, and -NR4- wherein R4 ls hydrogen or a lower ` -7-~L363~
~ alkyl group hav~ng from 1 to ~ carbon atoms. R5 $ ls a divalent hydrocarbon radical or a divalent hydrocarbon ether radical having from 1 to 18 carbon atoms, and R6 is a lower alkyl group having 1 to 6 carbon atoms or phenyl, wherein R14 is hydrogen or methyl, Q is an alkylene : group of up to 4 carbon atoms and A is selected - ~rom hydrogen, methyl, chlorine, alkoxycarbonyl having 2 to 18 carbon atoms~ phenyl, and nitrlle and at least one A is hydrogen, methyl or chlorine~
: s has a value of at least 1 and the sum of s and t is between about 2 and 40; and r is 0 or 1.
The preferred hydrolyzable sillcon-containing :.
;~ compounds are epoxy-terminated silanes having the general i 15 formulae:
O
H2C~CH~R8tqSi(OR7)3 and ~ ~R8tqSi(OR7)3 ;~ where R8 is a non-hydrolyzable divalent hydrocarbon group (aliphatic, aromatic, or aliphatic and aromatlc containing) of less than 20 carbon atoms or a divalent group of less thar. 20 carbon atoms composed of C, H 9 N, S and O atoms (these atoms are khe only atoms which may appear in the backbone of the divalent group), the last being in the form of ether linkages. No two heteroatoms may be ad~acent within the backbone of the divalent hydrocarbon groupO Thi.s description defines divalent hydrocarbon .
groups for the hydrolyzable epoxy-terminated silanes in the practice of this invention The value of q is -: ., ~; 0 or 1 and Rl is an aliphatic hydrocarbon group of less ~:, '`,.~' ~ . ~.
fi~
than 10 carbon atoms, an acyl group of less than 10 carbon ~- atoms, or a group of formula (CH2CH20)kZ in which k is an inieger of at least 1, and Z is an aliphatic hydro-carbon group of less than 10 carbon atoms or hydro~en.
Suitable hydrolyzable epoxy-terminated silanes for use in the composltions employed ln this invention can be a silane of the above formula in which R8 is any divalent hydrocarbon group such as methylene, ethylene, decalene, phenylene, cyclohexylene, cyclo-pentylene, methylcyclohexylene, 2-ethylbutylene and allene or an ether group such as -CH2-CH2-0-CH2-CH2-, (CH2-CH20)2-C~2 CH2 ' ~ 0-CH2-CH2- and -CH2o (CH2)3 ' R7 can be any aliphatic hydrocarbon group of less than 10 carbon atoms such as methyl, ethyl, isopropyl, butyl, vinyl, alky~ or any acyl group of less than 10 carbon atoms such as formyl, acetyl, propionyl, or any group of the formula (CH2CH20)kZ in which k is an integer of at least 1, for example 2, 5 and 8, and Z
is hydrogen or any aliphatic hydrocarbon group o~ less than 10 carbon atoms such as methyl, ethyl, isopropyl, butyl, vinyl and allylO -Additionally, materials copolymerizable with silanes (or in the case o~ epoxy-terminated silanes, with epoxy groups~ may be added to the reactive compo-. ~ j ~-~; 25 sitions. Conventional additives such as fillers, dyes, ;:
f~ow control agents, thickeners, radiation absorbers (e.g., ultraviolet radiation absorbers to enhance the ` radiation sensitivity of the catalysts), and such additives as are ~nown to be desirable in silane or siloxane compositions maybe used within the scope o~
. , ~
g_ ~`~
: '- ` ,''~' . ~ .
P3~D
the present inventionO The rnost preferred epoxy-terminated silanes are those represented by the formula:
CH2~C~I~R9)u-O-RlO-Si(OR')~
O
: 5 wherein R9 and R10 are independently alkylene groups of up to 4 carbon atoms, R' i5 an alkyl group of up to 6 carbon atoms, and u is O or 1~
The presence or catalytic amounts of molsture has been found to be necessary in the initiation of the condensation of silanes in the practice of this : invention. Atmospheric moisture will usually be suffi-cient, but water may be added to the system if desired or if polymerization is needed in the absence of air ~; 15 for any particular application.
~: Examples of suitable onium salts include, but are not limited to:
A. Onium Salts Having a Perlodic Group Va Cation
Many different catalyst systems for condensation of silanes are also known in the art. Each of the various ', :~:
: : . . ....
;: ~, , ~ -: I .
6~9 ~echniques and catalysts adds its own partlcular qualities to the requlrements of the reaction and the properties of the product. For example, strong acids ~avor the forma-tion o~ low molecular weight cyclic polymer units, silanols are stabilized in nearly neutral solutlons and preferentially condense to siloxanes in the presence o~
strong bases, Lewis acid metal salt catalysts such as stannous chloride require heat, and hydrolyzable metal esters will cure at room temperatures. Combinations of the catalysts and reaction conditions can be used to ad~ust these variables to a most desired balance for a particular intended use.
The present invention relates to a new catalyst system for hydrolyzable silanes which catalyzes the condensation reaction of silanes. These catalysts are storage stable when anhydrously mixed with the silane and are activated by incident radiation in the presence of catalytic amounts of moisture (e.g., atmospheric moisture is sufficient). The catal~sts of this invention are rapid acting cat,alysts and generate polymers with excellent properties.
More particularly the present invention relates to storage stable anhydrous compositions of a hydrolyzable ; silane and an onium catalyst and to a process of con-: 25 densing hydrolyzable silanes in the presence of onium `~ catalysts.
An onium catalyst useful in the practice of the present invention is an aromatic (which includes di-aromatic, triaromatic~ and tetraaromatic as well as monoaromatic), organic adduct of an aromatic organo-3~3~
a-tomic cation oE a Group Va, VIa, or VIIa atom par-I ticularly phosphorous, antimony, sulfur, nitrogen, and iodine atoms, and an anion.* When -the nominative atom is a halogen, the compound must be at least diaromatic.
Aromatic, as used in the description of the yroups on the catalysts of the present invention means an aromatic ring (hydrocarbon, or 5, 6, or 7 membered heterocycle comprised of only C, N, S, O, and Se atoms with no more than one atom in the ring selected from S, O, or Se . ~ 10 atoms) so attached to the nominative atom that it is at least as electron withdrawing as benzene. For ~ O
example, phenacyl ~ -C-CH2, would be a useful aromatic ~ group (being at least as electron withdrawing as ben-;; 15 zene), but benzyl ~ CH2- would not be useful because :
of instability of the compound which would irnpair :~ storage stability. Representative aromatic rings are phenyl, naphthyl, thienyl, pyranyl, furanyl and pyrazolyl, substituted or not.
:
:` 20 A descriptive formula for the onium catalysts `~ of the present invention would be R2) A-~
( n (R )a ~ wherein R .LS an aromatic gro.up at least as electron `. 25 withdrawing as benzene, . ~ :
,:
:
*For purposes of convenience in describing these onium catalysts, the Group Va, VIa, or VIIa atom that provides the major nomenclature for the adduct (e.g., phosphorous :
in phosphonium, sulfur in sulfonium, iodine in iodonium, :
etc.) will be called the nominative atom.
, ` ~ :
~3~i39 Rl ls alkyl (straight, branched, cyclic or substitll-ted), or alkenyl having 1 to 18 carbon ; atoms, ` n is a positive who:Le integer of at least 1 (preferably 2) up to the valence of A plus one, a is 0 or a positive whole integer of up -to the valence of A (preferably A minus 1), 'f~ n plus a is equal -to the valence of A plus one, A is a group Va, VIa, or VIIa atom, and is an anion, with the proviso that when A is halogen, n is at least 2.
~` These onium materials are already known in the 15 art. For example, Belgian Patents 833,472; 828,668;
`~ 828,669; and 828,670 show the use of certain onium compounds as cationic polymerization catalysts for specific monomers such as organosilicon cyclics, vinyl resins, cyclic ethers, cyclic esters, cyclic sulfides, epoxy resins, phenolic resins, polyamines, lactones, ;~ styrene, urea/formaldehyde and melamine/formaldehyde :
resins. The only known ~isclosure of utility in these ; references with regard to silicon containing polymers is believed to be in Belgian Patent 828,670 wherein cyclic organosilicons are polymerized by a ring opening -~ catalytic action, much in the same manner that epoxy resins are polymerized. ~o catalysis for silane conden-sation as described in the present invention is shown.
~; Other organo groups attached to the Group Va, or VIa .
nominative atom can be the same aromatic group or a ~'. ~.
,....,. ~
3~
~ substltuted or unsubstituted alkyl or cycloalkyl group.
`~ The organo groups may also be dlrect:ly attached one to another via a bond, a methylene group, a -CO- group, an S02 group, an oxygen~ or sulfur or the llke. One or more of the organo groups can shar~e two atoms in a condensed ring system.
Specific classes of' hydrol~zable silanes ~or use in the compositions of the inventlon are those having the general formulae:
Rm 4SiXm, R2[0-CO NH-R3-NH-Co-Y-R5-Si(oR6)3]p and ¦CH2 C ---~rH CA ~
L(~ = C - ~ q)rs~o~6)~ L ~ t wherein R, X, and m are as defined herein above and R2 is a polyvalent radical which is the residue resulting from the removal of p hydroxyl groups from a polyhydroxy compound having a molecular weight of from 200 to 6000~ p is an integer o~
from 1 to 60 R3 is a divalent alkylene group having from 1 to 18 carbon atoms or a divalent aromatic radical having from 6 to 18 carbon atoms and is the alkyl or aromatic portion of a diisocyanate compound on removal of the iso- ;~
cyanate groups. R3, for example, can be aliphatic cycloaliphatic, araliphatic or aromaticO Y is a divalent bridglng group selected from -O-, -S-, and -NR4- wherein R4 ls hydrogen or a lower ` -7-~L363~
~ alkyl group hav~ng from 1 to ~ carbon atoms. R5 $ ls a divalent hydrocarbon radical or a divalent hydrocarbon ether radical having from 1 to 18 carbon atoms, and R6 is a lower alkyl group having 1 to 6 carbon atoms or phenyl, wherein R14 is hydrogen or methyl, Q is an alkylene : group of up to 4 carbon atoms and A is selected - ~rom hydrogen, methyl, chlorine, alkoxycarbonyl having 2 to 18 carbon atoms~ phenyl, and nitrlle and at least one A is hydrogen, methyl or chlorine~
: s has a value of at least 1 and the sum of s and t is between about 2 and 40; and r is 0 or 1.
The preferred hydrolyzable sillcon-containing :.
;~ compounds are epoxy-terminated silanes having the general i 15 formulae:
O
H2C~CH~R8tqSi(OR7)3 and ~ ~R8tqSi(OR7)3 ;~ where R8 is a non-hydrolyzable divalent hydrocarbon group (aliphatic, aromatic, or aliphatic and aromatlc containing) of less than 20 carbon atoms or a divalent group of less thar. 20 carbon atoms composed of C, H 9 N, S and O atoms (these atoms are khe only atoms which may appear in the backbone of the divalent group), the last being in the form of ether linkages. No two heteroatoms may be ad~acent within the backbone of the divalent hydrocarbon groupO Thi.s description defines divalent hydrocarbon .
groups for the hydrolyzable epoxy-terminated silanes in the practice of this invention The value of q is -: ., ~; 0 or 1 and Rl is an aliphatic hydrocarbon group of less ~:, '`,.~' ~ . ~.
fi~
than 10 carbon atoms, an acyl group of less than 10 carbon ~- atoms, or a group of formula (CH2CH20)kZ in which k is an inieger of at least 1, and Z is an aliphatic hydro-carbon group of less than 10 carbon atoms or hydro~en.
Suitable hydrolyzable epoxy-terminated silanes for use in the composltions employed ln this invention can be a silane of the above formula in which R8 is any divalent hydrocarbon group such as methylene, ethylene, decalene, phenylene, cyclohexylene, cyclo-pentylene, methylcyclohexylene, 2-ethylbutylene and allene or an ether group such as -CH2-CH2-0-CH2-CH2-, (CH2-CH20)2-C~2 CH2 ' ~ 0-CH2-CH2- and -CH2o (CH2)3 ' R7 can be any aliphatic hydrocarbon group of less than 10 carbon atoms such as methyl, ethyl, isopropyl, butyl, vinyl, alky~ or any acyl group of less than 10 carbon atoms such as formyl, acetyl, propionyl, or any group of the formula (CH2CH20)kZ in which k is an integer of at least 1, for example 2, 5 and 8, and Z
is hydrogen or any aliphatic hydrocarbon group o~ less than 10 carbon atoms such as methyl, ethyl, isopropyl, butyl, vinyl and allylO -Additionally, materials copolymerizable with silanes (or in the case o~ epoxy-terminated silanes, with epoxy groups~ may be added to the reactive compo-. ~ j ~-~; 25 sitions. Conventional additives such as fillers, dyes, ;:
f~ow control agents, thickeners, radiation absorbers (e.g., ultraviolet radiation absorbers to enhance the ` radiation sensitivity of the catalysts), and such additives as are ~nown to be desirable in silane or siloxane compositions maybe used within the scope o~
. , ~
g_ ~`~
: '- ` ,''~' . ~ .
P3~D
the present inventionO The rnost preferred epoxy-terminated silanes are those represented by the formula:
CH2~C~I~R9)u-O-RlO-Si(OR')~
O
: 5 wherein R9 and R10 are independently alkylene groups of up to 4 carbon atoms, R' i5 an alkyl group of up to 6 carbon atoms, and u is O or 1~
The presence or catalytic amounts of molsture has been found to be necessary in the initiation of the condensation of silanes in the practice of this : invention. Atmospheric moisture will usually be suffi-cient, but water may be added to the system if desired or if polymerization is needed in the absence of air ~; 15 for any particular application.
~: Examples of suitable onium salts include, but are not limited to:
A. Onium Salts Having a Perlodic Group Va Cation
4-acetophenyltriphenylammonium chloride Diphenylmethylammonium tetrafluoroborate ~:~ Tetra(4-chlorophenyl)phosphonium iodide Tetraphenylph~Dphonium iodide ~ Tetraphenylphosphonium hexafluorophosphate :~ (4-bromophenyl)triphenylphosphonium hexa-fluorophosphate Tetraphenylarsonium tetrafluoroborate Tetraphenylbismonium chloride Di-(l-naphthyl)dimebhylammonium tetrafluoro-. borate Tri-(3-thlenyl)methylammonium tetrafluoroborate `' --10--., ' .
, L3~
Dlphenacyldimethylammonium hexafluorophosphate Examples of these and other onium salts and : their preparation are disclosed in Belgiwn Patent 828,668.
B. Onium Salts Having a Periodic Group VIa Gation Triphenylsulfonium hexafluoroantimonate 4-chlorophenyldiphenylsulfonium tetrafluoro-borate Triphenylsulfonium iodide 4-cyanophenyldiphenylsulfonium iodide ; lO Triphenylsulfonium sulfate 2-Nitrophenylphenylmethylsulfonium sulfate Triphenylsulfonium acetate Triphenylsulf'onium trichloroacetate ; Triphenyl teluronium pentachlorobismutate ~ -Triphenyl selenonium hexafluoroantimonate Examples of these and other onium salts having a Periodic Group VIa cation and their preparation are -~ -given in Belgium Patents 828,670 and 833,4720 C. Onium Salts Having a Perlodic Group VIIa Cation Diphenyliodonium iodide 4-Chlorophenylphenyllodonium iodide Diphenyliodonium chloride 4-Trifluoromethylphenylphenyliodonium tetra-fluoroborate .
-` 25 Diphenyliodonium sulfate ; Di(4-methoxyphenyl)iodonium chloride Diphenyliodonium trichloroacetate 4-methylphenylphenyliodonium tetrafluoroborate ~ Diphenylbromonium chloride :~ 30 1-(2-carboethoxynaphthyl)phenyliodonium chloride ' 2,2'-Diphenyliodonium hexafluorophosphate i3~
Examples o~ these and other halonium salts and their preparation are disclosed in Belgium Patent Nos~
828,669 and 8453746.
The amount of latent photocatalytic onium salt used in the photopolymerlzable compositions of the inven-tion is not critical but can be from about 0.01 to about 10.0% by weight of polymerizable silane, and preferably 0.5 to 5% by weight of the total weight of condensable silane compositionO The use of greater amounts of onium salt generally does not afford increased poly-merization and the use of less tends to reduce the extent of polymerlzation.
The compositions of the invention are prepared by mixin~ the onium salt with the hydrolyzable silicon-containing compound until a solution is formed. Becausemany of the onlum salts have limited solubility in the silicon-containing compound, it is often preferable to first dissolve the onium salt in a liquid diluent that is inert to the components of the composition and then mix this solution into the silicon-containing compound.
Suitable inert diluents include alcohols such as ethanol 3 esters such as ethyl acetate, ethers such as diethyl ether, halohydrocarbons such as dichloroethane, -~ ~ and nitriles such as acetonitrile. For storage stability, these solvents and the solutions must be anhydrous.
The composltions of the invention can be used for preparation o~ coatings for various substrates;
however, oils, sealants, caulking materlals and rub~ers ~` c~n also be prepared ~rom the compositions of the inven-tion and are particularly useful where such materials ~ 3~
need be prepared in sltu by irradiation. The composi-tions of the invention can be applied to substrates by spraying~ brushing, dipping, roller coating, flow coatlng or any o~ the methods used in commerc~al coating opera-tions.
The compositions of the invention may contaln certain additives to alter the properties o~ the polymerized or cured product. rrhus, there may be added dyes, pigments, plasticizers, ~illers and the like as - 10 long as these materials do not prevent sufficient penetration into the composition by radiation effective for activating the photocatalytic onium salt.
The photopolymerization and curing o~ the compositions of the invention occurs on exposure of the composition to any source of radiation emitting actinic radiation at a wavelength within the ultraviolet and visible range of the spectrum to which the photo-`~ catalyst has absorption peaksO Suitable sources of radiation include mercury, xenon, carbon arc and tungsten filament lamps, sunlight, etc= Exposuresmay be less than one second to ten minutes or more depending upon the amounts Or particular hydrolyzable silane materials and photocatalytic onium salt belng utilized and upon the radiation source, distance from . .
the source and the thickness of the material being polymerized. The composition may also be polymerized by exposure to electron beam irradiationu Dosages of from less than 1 megarad to 100 megarads or more are ` generally necessary to effect polymerization or curing.
By use of electron beam irradiation, highly filled .:
; -13-;3 '.
compositlons can be ef~ectively cured at a raster rate than by exposure to actinlc radiation.
The polymerizatlon or curing of the compositlon is a triggered reaction, ite., once degradation o~ the photocatalytic onlum salt has been initiated by exposure to radiation, the polymerization or curlng proceeds and will continue even after termlnating radiation.
The use of thermal energy during or after exposure to radiation greatly accelerates polymerization or curing.
The pre~erred latent photocatalytic onium salts for use with the preferred hydrolyzable epoxy-terminated silanes are of two types, viz., the aromatic iodonium and the aromatic sulfonium salts of halogen-containing complex anions and highly ~luorinated aliphatic sulfonic and sulfonylic protonic acidsO
The aromatic iodonium salts are of the formulae:
~Ar [ \~ +
wherein Arl and Ar2 are aromatic groups having 4 to 20 carbon atoms and are selected from phenyl, naphthyl, thienyl, furanyl and pyrazolyl groups; W is selected : ' ' ' ' ' 11 ' 11 from O, S, S=O, C=O, O=S=0, R -N where R is aryl of 6 to 20 carbon atoms or acyl of 2 to 20 carbon atoms (such as phenyl, acyl, benzoyl, etc~); a carbon-to-carbon bond; or ~12-C-R13, where R12 and R13 are selected from hydrogen, alkyl groups o~ 1 to 4 carbon :
~ atoms, and alkenyl groups of 2 to 4 carbon atoms; and :
~.3~;3''3 b is zero or l; and Q i5 a halogen-con~ainin~ complex anion selected from tetrafluoroborate, hexaf`luorophosphate, hexafluoroarsenate, hexachloroantimonate and hexafluoro-antimonate; a fluoroaliphatic sulfonic acld; a bis-(fluoroaliphatlcsulfonyl)methane; or a bls(fluoro- -aliphaticsulfonyl)imide. ~luoroaliphatic sul~onic acids, methanes and imides and their preparation are disclosed in U.S. Patent No. Il,049,861. Preferred compounds from thls group include those where n-0. Further preferred materials have Arl and Ar2 as a phenyl group.
The aromatlc sulPonium salts are of the formulae:
Arl Arl (w)~l l Ar2 ~ ~ and Ar2 ; 15 Rl Rl wherein Arl and Ar2 can be the same or di~ferent, selected from aromatic (as defined above ~or aromatic iodonium salts) and Rl, W, and Q are the same as defined before. Preferred compounds of this class are those in which Ar2 and Rl are phenyl.
Suitable examples of the preferred aromatic onium salt photocatalysts include:
diphenyliodonium tetra~luoroborate - diphenyliodonium hexafluorophosphate diphenyliodonium hexafluoroarsenate diphenyliodonium hexachloroantimonate diphenyliodonium hexafluoroantimonate diphenyliodonium bis(trifluoromethylsulfonyl)-methane --.. . .
Other sultable preferred aromatic onium salt photocatalysts are the corresponding triphenyLsulfonlum salts. Still other preferred salts are listed in Belgian Patent 845,746 and include triphenylsulfon~um hexa-~luorophosphate, tritolylsul~onium hexa~luorophosphate,methyldiphenylsulfonium tetrarluoroborate~ etc.
The aromatic iodonium salt photocatalysts useful in the photopolymerizable composltions o~ the invention are of themselves photosensitive only in the ultraviolet. They, however, are sensitized to the near ultraviolet and the visible range of the spectrum by sensitizers for known photolyzable iodonium compounds in accordance with the teachings of UOS. Patent 3,729,313. Illustrative sensitizers include amino-; 15 triarylmethane dyes and colored aromatic polycyclic hydrocarbons O
The aromatic sulfonium salt photocatalysts are also generally only sensitive in the ultraviolet.
They, too, are sensitized to the near ultraviolet and visible range of the spectrum by aromatic tertiary am nes and aromatic polycyclic compounds having at least three fused benzene rings and having an ioniza-tion energy less than about 7O9 ev, as calculated by the method of F~ A. Matsen, J. Chem. Physics 24, 602 (1956).
The preferred compositions o~ the invention containing hydrolyzable epoxy-terminated silanes and an aromatic 'Lodonium or sulfonium salt having an anion of ~ ;
halogen-containing complex, or highly fluorlnated ali-phatic su:Lfonic or sulfonylic protonic acid as 3~39 photocatalyst can also contain up to about 50% by weight or more of a comonomer which is capable o~ catlonic polymerization such as styrene, methyl styrene, vinyl amides and vinyl ethers. The most preferred cationically polymerized comonomers, however, are the epoxy compounds such as 1,4-butanediol diglycidyl ether, the digl~cidDl ether of bisphenyl A, 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate, and 1,4-bis(2,3-epoxypropoxy) butane.
In the following examples wh~ch will serve to illustrate the present invention, all parts are parts by i weight and all percentages are given as percentages by weight, unless otherwise indicated.
. . , To 100 parts of dimethyldimethoxysilane was added 1 part of diphenyliodonium chloride. The anhydrous mixture was stirred to dissolve the catalyst and then a layer 5 mm thick was exposed, in the presence . .
of atmospheric moisture, to the radiation of a mercury vapor lamp at a distance of 7 inches (17.5 cm). After ~ :.
about one minuta, the mixture had polymerlzed to a viscous material having a viscosity of about l,Q00,000 centipoise.
~ Similar results were obtained when the -~ 25 diphenyliodonium chloride was replaced by diphenyl-s iodonium iodide, diphenyliodonium hexafluorophosphate, triphenylsulfonium chloride 9 triphenylsulfonium hexa-'~; fluoroantimonate and triphenylsulfonium bis(trifluoro-methylsulfonyl)methane.
The above experiments were repeated for each ,,~ .
~' `:`:
"-' ~ . , .
:
6;;39 catalyst using amount~ o~ the photocatalysts ranglng from 0.05 to 5% by we~ght, and similar results were obtained.
Samples of` each of the unpolymerlzed anhydrous composi-tions when stored in the absence of moisture and light remained unpolymerized for at least two monthsO
Into 100 parts of phenyltriethoxysilane was added 2.5 parts of dlphenyliodonium chloride and 0 25 parts of 2-ethyl-9,10-dimethoxyanthracene. The compo-sitlon was stored in a tightly stoppered brown bottle.After at least two months, the composition was stlll fluid. The composition was coated onto polyethylene-terephthalate and exposed to a 275 watt sunlamp at a distance of five inches (12 7 cm)O After about one hour, a friable film was obtained. Similar results were obtained when diphenyliodonium lodide, diphenyl-`~ iodonium hexafluorophosphate, triphenylsulfonium chloride, triphenylsulfonium hexafluoro-antimonate, and triphenylsulfonium bis(trifluoromethylsulfonyl)-methane was used in place of diphenyliodonium chlorideO
A trialkoxysilyl-endcapped polymer was prepared by con~ointly reactlng polyoxypropylene glycol (molecular weight 3000), toluene diisocyanate, and y-aminopropyl-triethoxysilane~ To 100 parts of this polymer was added1 part of diphenyliodonium chloride and 0.2 parts of 2-ethyl-9,10-dimethoxyanthracene in 15 ml of ethyl acetateD The mixture was stirred until all materials were comp:Letely dispersed. The mixture was pressed into a squeeze tube and sealed therein~ After two weeks ::
3'~3 a thin bead Or the material was pressed frorn the tube and exposed to a sunlamp ror about ~ive minutes whereon it cured to a tough rubbery material.
When the experiment was repeated using triphenylsulfonium bromide in place of the diphenyl-iodonium chlorlde, even a~ter three months, the material could be squeezed from the squeeze tube and cured by exposure to a sunlamp for about five minutes.
, EXAMPLE 4 Example 2 was repeated using vinyltriethoxy-sllane in place of phenyltriethoxysilane. After two i~ minub~ exposure to a sunlamp, a coherent film had ~ormed which could be stripped from the substrate as a sel~-`; supporting film. When the mixture was coated onto polyethyleneterephthalate primed with polyvlnylidene-chloride, a tenaciously adherent film was obtained that had water repellent characteristicsO
When the example was repeated using as catalyst di(4-tolyl)iodonium hexafluorophosphate, the coating ~ 20 mixture also cured in about two minutesO
;~ EXAMPLE 5 ~, ~
~ An oligomer having pendant trimethoxy silane :
groups was prepared by heating in an oil bath at 80C
a mixture of 87.3 parts of y-methacryloxypropyltri-methoxysilane, 12~7 parts o~ 3-mercaptopropanediol-1,2 , :~
and 0O500 parts azobislsobutyronitrile. The mixture ~ rapidly exothermed to 84.5C whereon it was removed j~ from the oil bath and allowed to cool~ An oligomer having pendant trimethoxy silane groups and a weight average molecular weight of about 900 was obtained.
`:
.
A coa~-Lng compositlon was prepared by dissolving 100 g Or the above described oligomer in 100 g dry acetone and adding 500 g diphenylic)donium hexafluorophosphate ,~ and 0.5 g 2-chlorothioxanthone. The mixture was coated , 5 at about 5 micron thlckness onto cellulose acetate butyrate and the acetone allowed to evaporate. The coating was then expo~ed for flve minutes to a sunlamp whereon a coating showing significant reslstance to scratching by steel wool was obtained.
A trimethoxysilane terminated poly(alkylene ether) was prepared by mixing one mole of polyoxyethylene diol having a molecular welght of about 400 with 2 moles ~ of r-isocyanatopropyltrimethoxysilane and stirring the ; 15 mixture under substantially anhydrous conditions for ~ about 2 hours at about 60C~ To 40 parts of the ~.~
product was added 360 parts acetone, 1 part diphenyl-iodonium hexafluorophosphate and 0.1 part of 2-ethyl-9,10-dimethoxyanthracene. The mixture was stirred until dispersed and coated at about 5 microns onto a glass plate and exposed to a sunlamp for 5 minutes.
The plate was rinsed with water and dried. On exposing the plate to the vapors from a steam bath, no fog was produced on the coated surfaceO Even when the plate was rinsed repeatedly with water, the antifogging properties of the coating remalned.
To 105 g of 3-(2,3-epoxypropoxy)propyltri-. .
- methoxysilane was added 0005 g diphenyliodonium hexafluorophosphate and the solution obtained was coated ~ .
~ -20-`::
.
~3~;33 on a sultable substrate such as 100 mlcron primed poly-ester. The coating was exposed to an ultravlolet lamp ror ~our minutes. The resulting coating was abraded in ; accordance with ASTM D968 and the abrasion obtained measured accord~ng to A5TM D1003. A percentage increase of 4% (~ Haze) was obtained.
Initial Haze - Final Haze ~ H ~~ Initial Haze - X 100 The coating also had an excellent resistance to abrasion by steel wool.
These values compare favorably w~th haze values for commercially available coating material~, Polyester (polyethylene terephthalate) displays a haze of 78%, acrylate resins 60%~ Lexan 77%, and ABCITE ~ AR 22%.
Abrasion resistant coating made according to the teachings of U.S. Patent No. 4~049,861 from the same monomer used in this example also display haze values below 10%o The excellent abrasion resistance obtained in the practice o~ the present invention is surprising ~ in view of the general di~ficulty in finding satis-;~ 20 factory catalysts for the cure of epoxy-terminated silanes and the rapidity of cure with the catalysts of the present invention.
When 3-(2,3-epoxypropoxy)propyltrimethoxysilane was replaced in Example 7 by a preconde~sate of that silane (prepared by heating a solution of 16O5 g of the silane in 160 5 g of ethanol and 8.o g o~ water containing 1 drop of Ool N hydrochloric acid at 80C
to strip off alcohol), a haze increase of only 1.3%
: ~ .
was obtained~ The coatlng had excellent reslstance to abrasion by steel wool.
?, When Example 7 was repeaked using 2(3,4-
, L3~
Dlphenacyldimethylammonium hexafluorophosphate Examples of these and other onium salts and : their preparation are disclosed in Belgiwn Patent 828,668.
B. Onium Salts Having a Periodic Group VIa Gation Triphenylsulfonium hexafluoroantimonate 4-chlorophenyldiphenylsulfonium tetrafluoro-borate Triphenylsulfonium iodide 4-cyanophenyldiphenylsulfonium iodide ; lO Triphenylsulfonium sulfate 2-Nitrophenylphenylmethylsulfonium sulfate Triphenylsulfonium acetate Triphenylsulf'onium trichloroacetate ; Triphenyl teluronium pentachlorobismutate ~ -Triphenyl selenonium hexafluoroantimonate Examples of these and other onium salts having a Periodic Group VIa cation and their preparation are -~ -given in Belgium Patents 828,670 and 833,4720 C. Onium Salts Having a Perlodic Group VIIa Cation Diphenyliodonium iodide 4-Chlorophenylphenyllodonium iodide Diphenyliodonium chloride 4-Trifluoromethylphenylphenyliodonium tetra-fluoroborate .
-` 25 Diphenyliodonium sulfate ; Di(4-methoxyphenyl)iodonium chloride Diphenyliodonium trichloroacetate 4-methylphenylphenyliodonium tetrafluoroborate ~ Diphenylbromonium chloride :~ 30 1-(2-carboethoxynaphthyl)phenyliodonium chloride ' 2,2'-Diphenyliodonium hexafluorophosphate i3~
Examples o~ these and other halonium salts and their preparation are disclosed in Belgium Patent Nos~
828,669 and 8453746.
The amount of latent photocatalytic onium salt used in the photopolymerlzable compositions of the inven-tion is not critical but can be from about 0.01 to about 10.0% by weight of polymerizable silane, and preferably 0.5 to 5% by weight of the total weight of condensable silane compositionO The use of greater amounts of onium salt generally does not afford increased poly-merization and the use of less tends to reduce the extent of polymerlzation.
The compositions of the invention are prepared by mixin~ the onium salt with the hydrolyzable silicon-containing compound until a solution is formed. Becausemany of the onlum salts have limited solubility in the silicon-containing compound, it is often preferable to first dissolve the onium salt in a liquid diluent that is inert to the components of the composition and then mix this solution into the silicon-containing compound.
Suitable inert diluents include alcohols such as ethanol 3 esters such as ethyl acetate, ethers such as diethyl ether, halohydrocarbons such as dichloroethane, -~ ~ and nitriles such as acetonitrile. For storage stability, these solvents and the solutions must be anhydrous.
The composltions of the invention can be used for preparation o~ coatings for various substrates;
however, oils, sealants, caulking materlals and rub~ers ~` c~n also be prepared ~rom the compositions of the inven-tion and are particularly useful where such materials ~ 3~
need be prepared in sltu by irradiation. The composi-tions of the invention can be applied to substrates by spraying~ brushing, dipping, roller coating, flow coatlng or any o~ the methods used in commerc~al coating opera-tions.
The compositions of the invention may contaln certain additives to alter the properties o~ the polymerized or cured product. rrhus, there may be added dyes, pigments, plasticizers, ~illers and the like as - 10 long as these materials do not prevent sufficient penetration into the composition by radiation effective for activating the photocatalytic onium salt.
The photopolymerization and curing o~ the compositions of the invention occurs on exposure of the composition to any source of radiation emitting actinic radiation at a wavelength within the ultraviolet and visible range of the spectrum to which the photo-`~ catalyst has absorption peaksO Suitable sources of radiation include mercury, xenon, carbon arc and tungsten filament lamps, sunlight, etc= Exposuresmay be less than one second to ten minutes or more depending upon the amounts Or particular hydrolyzable silane materials and photocatalytic onium salt belng utilized and upon the radiation source, distance from . .
the source and the thickness of the material being polymerized. The composition may also be polymerized by exposure to electron beam irradiationu Dosages of from less than 1 megarad to 100 megarads or more are ` generally necessary to effect polymerization or curing.
By use of electron beam irradiation, highly filled .:
; -13-;3 '.
compositlons can be ef~ectively cured at a raster rate than by exposure to actinlc radiation.
The polymerizatlon or curing of the compositlon is a triggered reaction, ite., once degradation o~ the photocatalytic onlum salt has been initiated by exposure to radiation, the polymerization or curlng proceeds and will continue even after termlnating radiation.
The use of thermal energy during or after exposure to radiation greatly accelerates polymerization or curing.
The pre~erred latent photocatalytic onium salts for use with the preferred hydrolyzable epoxy-terminated silanes are of two types, viz., the aromatic iodonium and the aromatic sulfonium salts of halogen-containing complex anions and highly ~luorinated aliphatic sulfonic and sulfonylic protonic acidsO
The aromatic iodonium salts are of the formulae:
~Ar [ \~ +
wherein Arl and Ar2 are aromatic groups having 4 to 20 carbon atoms and are selected from phenyl, naphthyl, thienyl, furanyl and pyrazolyl groups; W is selected : ' ' ' ' ' 11 ' 11 from O, S, S=O, C=O, O=S=0, R -N where R is aryl of 6 to 20 carbon atoms or acyl of 2 to 20 carbon atoms (such as phenyl, acyl, benzoyl, etc~); a carbon-to-carbon bond; or ~12-C-R13, where R12 and R13 are selected from hydrogen, alkyl groups o~ 1 to 4 carbon :
~ atoms, and alkenyl groups of 2 to 4 carbon atoms; and :
~.3~;3''3 b is zero or l; and Q i5 a halogen-con~ainin~ complex anion selected from tetrafluoroborate, hexaf`luorophosphate, hexafluoroarsenate, hexachloroantimonate and hexafluoro-antimonate; a fluoroaliphatic sulfonic acld; a bis-(fluoroaliphatlcsulfonyl)methane; or a bls(fluoro- -aliphaticsulfonyl)imide. ~luoroaliphatic sul~onic acids, methanes and imides and their preparation are disclosed in U.S. Patent No. Il,049,861. Preferred compounds from thls group include those where n-0. Further preferred materials have Arl and Ar2 as a phenyl group.
The aromatlc sulPonium salts are of the formulae:
Arl Arl (w)~l l Ar2 ~ ~ and Ar2 ; 15 Rl Rl wherein Arl and Ar2 can be the same or di~ferent, selected from aromatic (as defined above ~or aromatic iodonium salts) and Rl, W, and Q are the same as defined before. Preferred compounds of this class are those in which Ar2 and Rl are phenyl.
Suitable examples of the preferred aromatic onium salt photocatalysts include:
diphenyliodonium tetra~luoroborate - diphenyliodonium hexafluorophosphate diphenyliodonium hexafluoroarsenate diphenyliodonium hexachloroantimonate diphenyliodonium hexafluoroantimonate diphenyliodonium bis(trifluoromethylsulfonyl)-methane --.. . .
Other sultable preferred aromatic onium salt photocatalysts are the corresponding triphenyLsulfonlum salts. Still other preferred salts are listed in Belgian Patent 845,746 and include triphenylsulfon~um hexa-~luorophosphate, tritolylsul~onium hexa~luorophosphate,methyldiphenylsulfonium tetrarluoroborate~ etc.
The aromatic iodonium salt photocatalysts useful in the photopolymerizable composltions o~ the invention are of themselves photosensitive only in the ultraviolet. They, however, are sensitized to the near ultraviolet and the visible range of the spectrum by sensitizers for known photolyzable iodonium compounds in accordance with the teachings of UOS. Patent 3,729,313. Illustrative sensitizers include amino-; 15 triarylmethane dyes and colored aromatic polycyclic hydrocarbons O
The aromatic sulfonium salt photocatalysts are also generally only sensitive in the ultraviolet.
They, too, are sensitized to the near ultraviolet and visible range of the spectrum by aromatic tertiary am nes and aromatic polycyclic compounds having at least three fused benzene rings and having an ioniza-tion energy less than about 7O9 ev, as calculated by the method of F~ A. Matsen, J. Chem. Physics 24, 602 (1956).
The preferred compositions o~ the invention containing hydrolyzable epoxy-terminated silanes and an aromatic 'Lodonium or sulfonium salt having an anion of ~ ;
halogen-containing complex, or highly fluorlnated ali-phatic su:Lfonic or sulfonylic protonic acid as 3~39 photocatalyst can also contain up to about 50% by weight or more of a comonomer which is capable o~ catlonic polymerization such as styrene, methyl styrene, vinyl amides and vinyl ethers. The most preferred cationically polymerized comonomers, however, are the epoxy compounds such as 1,4-butanediol diglycidyl ether, the digl~cidDl ether of bisphenyl A, 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate, and 1,4-bis(2,3-epoxypropoxy) butane.
In the following examples wh~ch will serve to illustrate the present invention, all parts are parts by i weight and all percentages are given as percentages by weight, unless otherwise indicated.
. . , To 100 parts of dimethyldimethoxysilane was added 1 part of diphenyliodonium chloride. The anhydrous mixture was stirred to dissolve the catalyst and then a layer 5 mm thick was exposed, in the presence . .
of atmospheric moisture, to the radiation of a mercury vapor lamp at a distance of 7 inches (17.5 cm). After ~ :.
about one minuta, the mixture had polymerlzed to a viscous material having a viscosity of about l,Q00,000 centipoise.
~ Similar results were obtained when the -~ 25 diphenyliodonium chloride was replaced by diphenyl-s iodonium iodide, diphenyliodonium hexafluorophosphate, triphenylsulfonium chloride 9 triphenylsulfonium hexa-'~; fluoroantimonate and triphenylsulfonium bis(trifluoro-methylsulfonyl)methane.
The above experiments were repeated for each ,,~ .
~' `:`:
"-' ~ . , .
:
6;;39 catalyst using amount~ o~ the photocatalysts ranglng from 0.05 to 5% by we~ght, and similar results were obtained.
Samples of` each of the unpolymerlzed anhydrous composi-tions when stored in the absence of moisture and light remained unpolymerized for at least two monthsO
Into 100 parts of phenyltriethoxysilane was added 2.5 parts of dlphenyliodonium chloride and 0 25 parts of 2-ethyl-9,10-dimethoxyanthracene. The compo-sitlon was stored in a tightly stoppered brown bottle.After at least two months, the composition was stlll fluid. The composition was coated onto polyethylene-terephthalate and exposed to a 275 watt sunlamp at a distance of five inches (12 7 cm)O After about one hour, a friable film was obtained. Similar results were obtained when diphenyliodonium lodide, diphenyl-`~ iodonium hexafluorophosphate, triphenylsulfonium chloride, triphenylsulfonium hexafluoro-antimonate, and triphenylsulfonium bis(trifluoromethylsulfonyl)-methane was used in place of diphenyliodonium chlorideO
A trialkoxysilyl-endcapped polymer was prepared by con~ointly reactlng polyoxypropylene glycol (molecular weight 3000), toluene diisocyanate, and y-aminopropyl-triethoxysilane~ To 100 parts of this polymer was added1 part of diphenyliodonium chloride and 0.2 parts of 2-ethyl-9,10-dimethoxyanthracene in 15 ml of ethyl acetateD The mixture was stirred until all materials were comp:Letely dispersed. The mixture was pressed into a squeeze tube and sealed therein~ After two weeks ::
3'~3 a thin bead Or the material was pressed frorn the tube and exposed to a sunlamp ror about ~ive minutes whereon it cured to a tough rubbery material.
When the experiment was repeated using triphenylsulfonium bromide in place of the diphenyl-iodonium chlorlde, even a~ter three months, the material could be squeezed from the squeeze tube and cured by exposure to a sunlamp for about five minutes.
, EXAMPLE 4 Example 2 was repeated using vinyltriethoxy-sllane in place of phenyltriethoxysilane. After two i~ minub~ exposure to a sunlamp, a coherent film had ~ormed which could be stripped from the substrate as a sel~-`; supporting film. When the mixture was coated onto polyethyleneterephthalate primed with polyvlnylidene-chloride, a tenaciously adherent film was obtained that had water repellent characteristicsO
When the example was repeated using as catalyst di(4-tolyl)iodonium hexafluorophosphate, the coating ~ 20 mixture also cured in about two minutesO
;~ EXAMPLE 5 ~, ~
~ An oligomer having pendant trimethoxy silane :
groups was prepared by heating in an oil bath at 80C
a mixture of 87.3 parts of y-methacryloxypropyltri-methoxysilane, 12~7 parts o~ 3-mercaptopropanediol-1,2 , :~
and 0O500 parts azobislsobutyronitrile. The mixture ~ rapidly exothermed to 84.5C whereon it was removed j~ from the oil bath and allowed to cool~ An oligomer having pendant trimethoxy silane groups and a weight average molecular weight of about 900 was obtained.
`:
.
A coa~-Lng compositlon was prepared by dissolving 100 g Or the above described oligomer in 100 g dry acetone and adding 500 g diphenylic)donium hexafluorophosphate ,~ and 0.5 g 2-chlorothioxanthone. The mixture was coated , 5 at about 5 micron thlckness onto cellulose acetate butyrate and the acetone allowed to evaporate. The coating was then expo~ed for flve minutes to a sunlamp whereon a coating showing significant reslstance to scratching by steel wool was obtained.
A trimethoxysilane terminated poly(alkylene ether) was prepared by mixing one mole of polyoxyethylene diol having a molecular welght of about 400 with 2 moles ~ of r-isocyanatopropyltrimethoxysilane and stirring the ; 15 mixture under substantially anhydrous conditions for ~ about 2 hours at about 60C~ To 40 parts of the ~.~
product was added 360 parts acetone, 1 part diphenyl-iodonium hexafluorophosphate and 0.1 part of 2-ethyl-9,10-dimethoxyanthracene. The mixture was stirred until dispersed and coated at about 5 microns onto a glass plate and exposed to a sunlamp for 5 minutes.
The plate was rinsed with water and dried. On exposing the plate to the vapors from a steam bath, no fog was produced on the coated surfaceO Even when the plate was rinsed repeatedly with water, the antifogging properties of the coating remalned.
To 105 g of 3-(2,3-epoxypropoxy)propyltri-. .
- methoxysilane was added 0005 g diphenyliodonium hexafluorophosphate and the solution obtained was coated ~ .
~ -20-`::
.
~3~;33 on a sultable substrate such as 100 mlcron primed poly-ester. The coating was exposed to an ultravlolet lamp ror ~our minutes. The resulting coating was abraded in ; accordance with ASTM D968 and the abrasion obtained measured accord~ng to A5TM D1003. A percentage increase of 4% (~ Haze) was obtained.
Initial Haze - Final Haze ~ H ~~ Initial Haze - X 100 The coating also had an excellent resistance to abrasion by steel wool.
These values compare favorably w~th haze values for commercially available coating material~, Polyester (polyethylene terephthalate) displays a haze of 78%, acrylate resins 60%~ Lexan 77%, and ABCITE ~ AR 22%.
Abrasion resistant coating made according to the teachings of U.S. Patent No. 4~049,861 from the same monomer used in this example also display haze values below 10%o The excellent abrasion resistance obtained in the practice o~ the present invention is surprising ~ in view of the general di~ficulty in finding satis-;~ 20 factory catalysts for the cure of epoxy-terminated silanes and the rapidity of cure with the catalysts of the present invention.
When 3-(2,3-epoxypropoxy)propyltrimethoxysilane was replaced in Example 7 by a preconde~sate of that silane (prepared by heating a solution of 16O5 g of the silane in 160 5 g of ethanol and 8.o g o~ water containing 1 drop of Ool N hydrochloric acid at 80C
to strip off alcohol), a haze increase of only 1.3%
: ~ .
was obtained~ The coatlng had excellent reslstance to abrasion by steel wool.
?, When Example 7 was repeaked using 2(3,4-
5 epoxycyclohexyl)ethyltrimethoxysilane in 1.5 g of i~o-propanol in place o~ 3-(2,3-epoxypropoxy)propyltrimethoxy-silane, there was obtained a scratch resistant coating having a % haze of 7.0%. The coating had excellent resistance to abrasion by steel wool.
Example 8 was repeated in a series of experi-ments in which the following catalysts were used in place of diphenyl iodonium hexafluorophosphate. The increase in haze (~ Haze) obtained for each also is given.
Catalyst ~ Haze f~a. Diphenyliodonium hexafluoroantimonate 2.9%
,- b. Diphenyliodonium tetrafluoroborate 130 7%
c. Diphenyliodonium hexafluorophosphate 1D 3~
d. Triphenylsulfonium hexafluoroantimonate 208%
I e, Triphenylsulfonium hexafluorophosphate lo 3%
'~ Samples from each of the experiments also '~ :
,;~ exhibited resistance to abrasion by steel woolO
EXAMPLE ll _ _ A solution of 2 parts of a precondensate pre-pared as described in Example 8, 1 part of tetraethoxy-silane, and 0.1 part of diphenyliodonium hexafluoro--- phosphate in 3 parts isopropanol were coated onto a 100 micron polyester sheet and exposed to a 140 wakt ultraviolet lamp for 30 seconds. The resulking coating '~
. ' ' .
, ;3~
was found to have a ~ Haze of 2.0 when tested in accordance with ASTM D968 and D1003 A solution was prepared by rnixing 5 grams of a precondensate o~ 3-(2,3-epoxypropoxy)propyldimethoxy-silane (prepared as described in Example 8), 5 grams of a precondensate of tetraethoxysilane (prepared by heatlng at reflux a mixture Or 16.5 g tetraethoxysilane, 16.5 g ethanol and 8.o g water containing 1 drop o~
0.1 N HCl at 80C to strip o~f ethanol), 1.65 g isopropanol, and 0.2 g diphenyliodonium hexafluoro-phosphate. The solution was coated onto a primed sheet of polymethylmethacrylate by flow coating and irradiated with an ultraviolet lamp for five minutes.
An abrasion resistant coating was obtained which had a ~ Haze of 4.5.
Example 7 was repeated, however, adding to the coating composition 0.4 g tetraisopropyl titanate.
Following exposure to the irradiation of an ultraviolet la~p, a coating having resistance to abrasion by sand and steel wool was obtained -The effect of photocatalyst concentration was illustrated by adding the following concentrations of catalyst to tetraethoxysilane, coating the material onto ~ glass and irradiating the coating for five minutes with ; a 140 watt ultraviolet lamp at a distance of about 20 cm.
:
' ~'~ ' ` -, , 3~
a % ~2I P~6 No polymerization b. 0.05% " Friable, hard coating c. 0 5% " "
d. 1.0% " "
e. 2.0% " ~
r. o . o~ 03S SbF6 No polymerization g. 0.05% " Friable~ hard coatlng h. 0.5% "
io 1~ 0%
J ~ 2 ~ 0%
~` The effectlveness of other onium salts for catalyzing the photopolymerization of hydrolyzable silicon-containing compounds is illustrated by adding 1.0% by weight of the following onium salts to tetra-ethoxysilane, coating the material onto glass and irradiating the coating with a 140 watt ultraviolet lamp at a distance of about 20 cm and noting the time required for formation of a tack~ree surface.
:
~; 20 PhotocatalystTime to Tack-Free State a~ 02(CH3)2N PF615 minutes ~`~ b- 04P PF6( ) ; cO 03S Cl ( 2 )2 hours ;
d. 02I Cl (2) 16 hours ' 25 (1) In solution (2) Plus 0.2% by weight 2-ethyl-9,10-dimethoxyanthracene ; EXA_PLE 16 ; To illustrate a composition of the invention useful for providing a scratch resistant coatlng on photographic film, Llo parts of 1,4-bis(3,4-epoxypropoxy)-. . . .
.: ,,i . . . ~ . .
-. ~, .. ..
3~
~utane, 60 ~arts of 3~(2,3-epox~propoxy)propyltrimethoxy-silane, and 1 part of diphenyliodonium hexafluorophosphate were mixed and stored in a light tlght vessel where it could be k~pt unpolymerlzed ~or at least three months.
Strips of developed 35 mm photographic fllm (both triacetate and polyester) were continuously coated with an about 100 mlcron thickness of the composition and exposed for 6 seconds to the radiation Or a 140 watt ultraviolet lamp whereon a scratch resistant coating on each was obtained that had a A Haze of 8 to 10%.
Protection Or photographic materials, including microfiche, prints, transparencies, etc. is provided n~t only by coating of the surface of the emulsion layers but, especially in transparent materials such as microfilms and slides, coating of the backside layer or base improves the durability of the film and resistance to scratches.
To 4 gm of a precondensate (by condensation of silane groups) of 3-(2~3-epoxypropoxy3propyltrimethoxy-silane was added Q.2 gm of (CH3)3C6H5N Cl and 0002 gm 2-chlorothioxanthone and 2 gm of ethanol to facilitate solubility. This solution was coated on 100 micron primed polyesterO The coating was exposed to a 140 watt ultraviolet lamp for 60 minutes after which time the compositlon had cured to a tough abrasion resistant coating. A sample of the above coated film which was allowed to set exposed only to fluorescent room lighting became tack free after 12 hours but was not abrasion resistant at that time.
Example 8 was repeated in a series of experi-ments in which the following catalysts were used in place of diphenyl iodonium hexafluorophosphate. The increase in haze (~ Haze) obtained for each also is given.
Catalyst ~ Haze f~a. Diphenyliodonium hexafluoroantimonate 2.9%
,- b. Diphenyliodonium tetrafluoroborate 130 7%
c. Diphenyliodonium hexafluorophosphate 1D 3~
d. Triphenylsulfonium hexafluoroantimonate 208%
I e, Triphenylsulfonium hexafluorophosphate lo 3%
'~ Samples from each of the experiments also '~ :
,;~ exhibited resistance to abrasion by steel woolO
EXAMPLE ll _ _ A solution of 2 parts of a precondensate pre-pared as described in Example 8, 1 part of tetraethoxy-silane, and 0.1 part of diphenyliodonium hexafluoro--- phosphate in 3 parts isopropanol were coated onto a 100 micron polyester sheet and exposed to a 140 wakt ultraviolet lamp for 30 seconds. The resulking coating '~
. ' ' .
, ;3~
was found to have a ~ Haze of 2.0 when tested in accordance with ASTM D968 and D1003 A solution was prepared by rnixing 5 grams of a precondensate o~ 3-(2,3-epoxypropoxy)propyldimethoxy-silane (prepared as described in Example 8), 5 grams of a precondensate of tetraethoxysilane (prepared by heatlng at reflux a mixture Or 16.5 g tetraethoxysilane, 16.5 g ethanol and 8.o g water containing 1 drop o~
0.1 N HCl at 80C to strip o~f ethanol), 1.65 g isopropanol, and 0.2 g diphenyliodonium hexafluoro-phosphate. The solution was coated onto a primed sheet of polymethylmethacrylate by flow coating and irradiated with an ultraviolet lamp for five minutes.
An abrasion resistant coating was obtained which had a ~ Haze of 4.5.
Example 7 was repeated, however, adding to the coating composition 0.4 g tetraisopropyl titanate.
Following exposure to the irradiation of an ultraviolet la~p, a coating having resistance to abrasion by sand and steel wool was obtained -The effect of photocatalyst concentration was illustrated by adding the following concentrations of catalyst to tetraethoxysilane, coating the material onto ~ glass and irradiating the coating for five minutes with ; a 140 watt ultraviolet lamp at a distance of about 20 cm.
:
' ~'~ ' ` -, , 3~
a % ~2I P~6 No polymerization b. 0.05% " Friable, hard coating c. 0 5% " "
d. 1.0% " "
e. 2.0% " ~
r. o . o~ 03S SbF6 No polymerization g. 0.05% " Friable~ hard coatlng h. 0.5% "
io 1~ 0%
J ~ 2 ~ 0%
~` The effectlveness of other onium salts for catalyzing the photopolymerization of hydrolyzable silicon-containing compounds is illustrated by adding 1.0% by weight of the following onium salts to tetra-ethoxysilane, coating the material onto glass and irradiating the coating with a 140 watt ultraviolet lamp at a distance of about 20 cm and noting the time required for formation of a tack~ree surface.
:
~; 20 PhotocatalystTime to Tack-Free State a~ 02(CH3)2N PF615 minutes ~`~ b- 04P PF6( ) ; cO 03S Cl ( 2 )2 hours ;
d. 02I Cl (2) 16 hours ' 25 (1) In solution (2) Plus 0.2% by weight 2-ethyl-9,10-dimethoxyanthracene ; EXA_PLE 16 ; To illustrate a composition of the invention useful for providing a scratch resistant coatlng on photographic film, Llo parts of 1,4-bis(3,4-epoxypropoxy)-. . . .
.: ,,i . . . ~ . .
-. ~, .. ..
3~
~utane, 60 ~arts of 3~(2,3-epox~propoxy)propyltrimethoxy-silane, and 1 part of diphenyliodonium hexafluorophosphate were mixed and stored in a light tlght vessel where it could be k~pt unpolymerlzed ~or at least three months.
Strips of developed 35 mm photographic fllm (both triacetate and polyester) were continuously coated with an about 100 mlcron thickness of the composition and exposed for 6 seconds to the radiation Or a 140 watt ultraviolet lamp whereon a scratch resistant coating on each was obtained that had a A Haze of 8 to 10%.
Protection Or photographic materials, including microfiche, prints, transparencies, etc. is provided n~t only by coating of the surface of the emulsion layers but, especially in transparent materials such as microfilms and slides, coating of the backside layer or base improves the durability of the film and resistance to scratches.
To 4 gm of a precondensate (by condensation of silane groups) of 3-(2~3-epoxypropoxy3propyltrimethoxy-silane was added Q.2 gm of (CH3)3C6H5N Cl and 0002 gm 2-chlorothioxanthone and 2 gm of ethanol to facilitate solubility. This solution was coated on 100 micron primed polyesterO The coating was exposed to a 140 watt ultraviolet lamp for 60 minutes after which time the compositlon had cured to a tough abrasion resistant coating. A sample of the above coated film which was allowed to set exposed only to fluorescent room lighting became tack free after 12 hours but was not abrasion resistant at that time.
Claims (18)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. An anhydrous, storage-stable, polymerizable composition comprising at least one hydrolyzable silane represented by the formula:
XmSiR4-m wherein X is a hydrolyzable group or hydrogen, R is a hydrocarbyl group, and m is 2, 3 or 4, and an organic aromatic onium catalyst comprising an aroma-tic adduct of (1) a diaromatic, triaromatic, or tetraaromatic organoatomic cation of Group Va, VIa, or VIIa atom and (2) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group having 1 to 18 carbon atoms, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one.
XmSiR4-m wherein X is a hydrolyzable group or hydrogen, R is a hydrocarbyl group, and m is 2, 3 or 4, and an organic aromatic onium catalyst comprising an aroma-tic adduct of (1) a diaromatic, triaromatic, or tetraaromatic organoatomic cation of Group Va, VIa, or VIIa atom and (2) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group having 1 to 18 carbon atoms, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one.
2. The polymerizable composition of claim 1 wherein said Group Va, VIa, or VIIa atom is selected from the group consisting essentially of phosphorous, sulfur, nitrogen, iodine or antimony.
3. The polymerizable composition of claim 2 wherein the organic aromatic catalyst is a diphenyl, triphenyl, or tetraphenyl organic adduct.
4. The polymerizable composition of claim 1 wherein the anion is selected from the group consisting of tetrafluoroborate, hexafluorophosphate, hexafluorosenate, hexachloroantimonate, bis(perfluoroalkylsulfonyl)methane, iodide, bromide, chloride, fluoride, sulfate, acetate, or trichloroacetate.
5. The polymerizable composition of claim 4 wherein a is 0 and R2 is a phenyl.
6. The polymerizable composition of claim 4 wherein R2 is a phenyl group, naphthyl group, thienyl group, pyranyl group, furanyl group or pyrazolyl group.
7. The polymerization composition of claim 4 wherein R1 is alkyl.
8. The polymerizable composition of claim 1 wherein the silane is represented by the formulae:
and where R8 is a non-hydrolyzable divalent hydrocarbon group of less than 20 carbon atoms or a divalent group of less than 20 carbon atoms the backbone of which is composed of only C, N, S, and O atoms with no two heteroatoms adjacent within the backbone of the divalent groups, q is 0 or 1 and R7 is an aliphatic hydrocarbon group of less than 10 carbon atoms, an acyl group of less than 10 carbon atoms, or a group of formula (CH2CH2O)kZ in which k is an integer of at least 1, and Z is an aliphatic hydrocarbon group of less than 10 carbon atoms or hydrogen.
and where R8 is a non-hydrolyzable divalent hydrocarbon group of less than 20 carbon atoms or a divalent group of less than 20 carbon atoms the backbone of which is composed of only C, N, S, and O atoms with no two heteroatoms adjacent within the backbone of the divalent groups, q is 0 or 1 and R7 is an aliphatic hydrocarbon group of less than 10 carbon atoms, an acyl group of less than 10 carbon atoms, or a group of formula (CH2CH2O)kZ in which k is an integer of at least 1, and Z is an aliphatic hydrocarbon group of less than 10 carbon atoms or hydrogen.
9. The polymerizable composition of claim 8 wherein the silane is represented by the formula wherein R9 and R10 are independently alkylene groups of up to 4 carbon atoms, R` is an alkyl group of up to 6 carbon atoms, and u is 0 or 1.
10. A method for the condensation of a hydrolyzable silane comprising irradiating a composition comprising:
1) a hydrolyzable silane, 2) a catalytic amount of H2O, and 3) an onium catalyst comprising a) a diaromatic, triaromatic, or tetraaromatic organic adduct of an organoatomic cation of a group Va, VIa, or VIIa atom, and b) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A
plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one, with at least a sufficient intensity of radiation to activate the onium catalyst and initiate the condensation reaction.
1) a hydrolyzable silane, 2) a catalytic amount of H2O, and 3) an onium catalyst comprising a) a diaromatic, triaromatic, or tetraaromatic organic adduct of an organoatomic cation of a group Va, VIa, or VIIa atom, and b) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A
plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one, with at least a sufficient intensity of radiation to activate the onium catalyst and initiate the condensation reaction.
11. A method for the condensation of silane according to claim 10 wherein said Group Va, VIa, or VIIa atom is selected from the group consist-ing of phosphorous, sulfur, nitrogen, iodine, or antimony.
12. The method of claim 10 wherein the organic adduct is a diphenyl, triphenyl, or tetraphenyl organic adduct.
13. The method of claim 10 wherein the polymerizable silane is repre-sented by the formulae:
and where R8 is a non-hydrolyzable divalent hydrocarbon group of less than 20 carbon atoms or a divalent group of less than 20 carbon atoms the backbone of which is composed of only C, N, S, and O atoms with no two heteroatoms adjacent within the backbone of the divalent groups, q is 0 or 1 and R7 is an aliphatic hydrocarbon group of less than 10 carbon atoms, an acyl group of less than 10 carbon atoms, or a group of formula (CH2CH2O)kZ in which k is an integer of at least 1, and Z is an aliphatic hydrocarbon group of less than 10 carbon atoms, or hydrogen.
and where R8 is a non-hydrolyzable divalent hydrocarbon group of less than 20 carbon atoms or a divalent group of less than 20 carbon atoms the backbone of which is composed of only C, N, S, and O atoms with no two heteroatoms adjacent within the backbone of the divalent groups, q is 0 or 1 and R7 is an aliphatic hydrocarbon group of less than 10 carbon atoms, an acyl group of less than 10 carbon atoms, or a group of formula (CH2CH2O)kZ in which k is an integer of at least 1, and Z is an aliphatic hydrocarbon group of less than 10 carbon atoms, or hydrogen.
14. The method of claim 12 wherein the polymerizable silane is repre-sented by the formula wherein R9 and R10 are independently alkylene groups of up to 4 carbon atoms, R` is an alkyl group of up to 6 carbon atoms, and u is 0 or 1, and the anion X is selected from tetrafluoroborate, hexafluoroantimonate, hexafluorophos-phate and hexafluoroarsenate.
15. An anhydrous, storage-stable, polymerizable composition comprising at least one hydrolyzable silane represented by the formula:
XmSiR4-m wherein X is a hydrolyzable group or hydrogen, R is a hydrocarbyl group, and m is 2, 3 or 4, and an organic aromatic onium catalyst comprising an aroma-tic adduct of (1) an aromatic organoatomic cation of a Group Va, VIa, or VIIa atom and (2) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A
plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one, with the proviso that when the Group Va, VIa, or VIIa atom is a halogen atom, the organoatomic cation must be at least diaromatic.
XmSiR4-m wherein X is a hydrolyzable group or hydrogen, R is a hydrocarbyl group, and m is 2, 3 or 4, and an organic aromatic onium catalyst comprising an aroma-tic adduct of (1) an aromatic organoatomic cation of a Group Va, VIa, or VIIa atom and (2) an anion, which onium catalyst is represented by the formula:
wherein R2 is an aromatic group at least as electron withdrawing as benzene, R1 is an alkyl or alkenyl group, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A
plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one, with the proviso that when the Group Va, VIa, or VIIa atom is a halogen atom, the organoatomic cation must be at least diaromatic.
16. The polymerizable composition of claim 1, 2 or 3 wherein R is CH2=CR'COO(CH2)n- wherein R is H or CH3 and n is 0 or 1-8 and m is 3.
17. The method of claim 10, 11 or 12 wherein R is CH2=CR'COO(CH2)n-wherein R is H or CH3 and n is 0 or 1-8 and m is 3.
18. The method of claim 10 wherein A is sulfur or iodine, a is zero and R1 is a phenyl group.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/764,817 US4101513A (en) | 1977-02-02 | 1977-02-02 | Catalyst for condensation of hydrolyzable silanes and storage stable compositions thereof |
US764,817 | 1977-02-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1113639A true CA1113639A (en) | 1981-12-01 |
Family
ID=25071871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CA294,094A Expired CA1113639A (en) | 1977-02-02 | 1977-12-29 | Catalyst for condensation of hydrolyzable silanes and storage stable compositions thereof |
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US (1) | US4101513A (en) |
JP (1) | JPS5397098A (en) |
AU (1) | AU505454B2 (en) |
BE (1) | BE863547A (en) |
BR (1) | BR7800619A (en) |
CA (1) | CA1113639A (en) |
CH (1) | CH658461A5 (en) |
DE (1) | DE2804283C2 (en) |
FR (1) | FR2379575A1 (en) |
GB (1) | GB1572760A (en) |
IT (1) | IT1104149B (en) |
MX (1) | MX147159A (en) |
NL (1) | NL184785C (en) |
NZ (1) | NZ186365A (en) |
SE (1) | SE443792B (en) |
ZA (1) | ZA78622B (en) |
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-
1977
- 1977-02-02 US US05/764,817 patent/US4101513A/en not_active Expired - Lifetime
- 1977-12-29 CA CA294,094A patent/CA1113639A/en not_active Expired
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1978
- 1978-01-30 NL NLAANVRAGE7801049,A patent/NL184785C/en not_active IP Right Cessation
- 1978-01-30 SE SE7801068A patent/SE443792B/en not_active IP Right Cessation
- 1978-02-01 IT IT47870/78A patent/IT1104149B/en active
- 1978-02-01 JP JP1038378A patent/JPS5397098A/en active Granted
- 1978-02-01 FR FR7802742A patent/FR2379575A1/en active Granted
- 1978-02-01 DE DE2804283A patent/DE2804283C2/en not_active Expired
- 1978-02-01 ZA ZA00780622A patent/ZA78622B/en unknown
- 1978-02-01 CH CH1116/78A patent/CH658461A5/en not_active IP Right Cessation
- 1978-02-01 NZ NZ186365A patent/NZ186365A/en unknown
- 1978-02-01 GB GB4084/78A patent/GB1572760A/en not_active Expired
- 1978-02-01 AU AU32905/78A patent/AU505454B2/en not_active Expired
- 1978-02-01 BR BR7800619A patent/BR7800619A/en unknown
- 1978-02-01 BE BE184815A patent/BE863547A/en not_active IP Right Cessation
- 1978-02-02 MX MX172294A patent/MX147159A/en unknown
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SE443792B (en) | 1986-03-10 |
SE7801068L (en) | 1978-08-03 |
JPS5529101B2 (en) | 1980-08-01 |
AU3290578A (en) | 1979-08-09 |
JPS5397098A (en) | 1978-08-24 |
DE2804283A1 (en) | 1978-08-10 |
US4101513A (en) | 1978-07-18 |
BE863547A (en) | 1978-08-01 |
NL184785C (en) | 1989-11-01 |
FR2379575B1 (en) | 1980-05-16 |
NZ186365A (en) | 1980-03-05 |
IT7847870A0 (en) | 1978-02-01 |
NL184785B (en) | 1989-06-01 |
GB1572760A (en) | 1980-08-06 |
BR7800619A (en) | 1978-12-05 |
DE2804283C2 (en) | 1984-11-15 |
MX147159A (en) | 1982-10-19 |
CH658461A5 (en) | 1986-11-14 |
IT1104149B (en) | 1985-10-14 |
NL7801049A (en) | 1978-08-04 |
ZA78622B (en) | 1978-12-27 |
FR2379575A1 (en) | 1978-09-01 |
AU505454B2 (en) | 1979-11-22 |
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