CA1121272A - Silica with metallic oxides to absorb deodorant for use in ash trays - Google Patents
Silica with metallic oxides to absorb deodorant for use in ash traysInfo
- Publication number
- CA1121272A CA1121272A CA000330181A CA330181A CA1121272A CA 1121272 A CA1121272 A CA 1121272A CA 000330181 A CA000330181 A CA 000330181A CA 330181 A CA330181 A CA 330181A CA 1121272 A CA1121272 A CA 1121272A
- Authority
- CA
- Canada
- Prior art keywords
- composition according
- weight
- deodorizing
- substance
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F19/00—Ash-trays
- A24F19/10—Ash-trays combined with other articles
- A24F19/14—Ash-trays combined with other articles with extinguishers
- A24F19/145—Ash-trays combined with other articles with extinguishers using fluid or sand
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/046—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of a non-organic compound
Abstract
ABSTRACT OF THE DISCLOSURE
A fluid deodorizing composition, particularly for use in ash trays, where it is in direct contact with the butts of cigarettes and cigars, comprising a granular absorbent substance which is incombustible at the combustion temperature of the glowing fire of the cigarettes, containing absorbed therein an oily vapour diffuser substance. The said absorbent substance is amorphous porous silica, containing small amounts of metallic oxides, having a grain size of 20 to 60 mesh per square centimeter, and an absorptive power of up to 1 part by weight of absorbed oily substance per part by weight of absorbing granular substance.
A fluid deodorizing composition, particularly for use in ash trays, where it is in direct contact with the butts of cigarettes and cigars, comprising a granular absorbent substance which is incombustible at the combustion temperature of the glowing fire of the cigarettes, containing absorbed therein an oily vapour diffuser substance. The said absorbent substance is amorphous porous silica, containing small amounts of metallic oxides, having a grain size of 20 to 60 mesh per square centimeter, and an absorptive power of up to 1 part by weight of absorbed oily substance per part by weight of absorbing granular substance.
Description
.
7;2 B~CKG~O~Nm O~ TH~ INVEN~ION
_ =====_===========_===_===
. . .......... ... . . .
1) Field of the in~ention.
The present invention relates to a deodo-izing composition for diffusing air tempering vapors into the surrounding atmosphere. The said composition is particularly, even if not exclusively, apt to be used in ash træys, ænd particularly in ash trays used on vehicles, such as for instance automobile cars, railt~ays cars~ airplanes and the like vehicles. ~-It is known that the ash trays, particularly ~hose ; ~-~
of the "drawer" type or of the type provided with a closure lid, as it is the case of the ash trays ~ed on `~
the vehicules, have the tendency to maintain confined in their inside the odors of the combustion, emanatir~ them ` -~
suddenly into ihe ir~ide of the vehicle as soon as opeYed, ~it~ substantial uncon~ortableness for the users of ~he vehicle, in which the said odors expands with promptness and persistency, due to the reduced volume of the interior of the vehicles.
.
~he above tendency cannot be efficiently contrasted -~
by using the normal vapor diffusing devices~ in consideration of the fact that the said devices require a certain time ir~ order to act, whilst the emanation of the combus~ion odor from the ash trays takes place substantially in~tantaneously and ~ith a high odor concentration at the mosent of the openlng of`the ash tray.
~ , ~Z~
7;2 B~CKG~O~Nm O~ TH~ INVEN~ION
_ =====_===========_===_===
. . .......... ... . . .
1) Field of the in~ention.
The present invention relates to a deodo-izing composition for diffusing air tempering vapors into the surrounding atmosphere. The said composition is particularly, even if not exclusively, apt to be used in ash træys, ænd particularly in ash trays used on vehicles, such as for instance automobile cars, railt~ays cars~ airplanes and the like vehicles. ~-It is known that the ash trays, particularly ~hose ; ~-~
of the "drawer" type or of the type provided with a closure lid, as it is the case of the ash trays ~ed on `~
the vehicules, have the tendency to maintain confined in their inside the odors of the combustion, emanatir~ them ` -~
suddenly into ihe ir~ide of the vehicle as soon as opeYed, ~it~ substantial uncon~ortableness for the users of ~he vehicle, in which the said odors expands with promptness and persistency, due to the reduced volume of the interior of the vehicles.
.
~he above tendency cannot be efficiently contrasted -~
by using the normal vapor diffusing devices~ in consideration of the fact that the said devices require a certain time ir~ order to act, whilst the emanation of the combus~ion odor from the ash trays takes place substantially in~tantaneously and ~ith a high odor concentration at the mosent of the openlng of`the ash tray.
~ , ~Z~
2) Statement of the prior art.
No relevant prior art i~ kno~n to the applicant.
This statement is made for the purposes of complying .qth the duty of disclosure under 37 CFR 1.56.
.
SUL3L4RY 0~ ~HE ~M~ION
c ======= ============
It is there~ore the main object o~ tke present inve~tion to provide a deodorizing composition for use in ash trays, which may obviate to the above mentioned disadvantages, by effecting an efficient and constænt ~ ::
deodori~ation of the ash trays, at the same time at which the objectionable odors are produced in the ash bl~ays . ~:
~.. ...
A further object of the present lllvention i~ a method for tke ~anufacture of the deodorizing composition;:
. . .
of tke invention.
~L~IE~ ~ESCRIP~ION O~ ~E PP.IO~ AR~ DEODORTZEP.S
No relevant prior art i~ kno~n to the applicant.
This statement is made for the purposes of complying .qth the duty of disclosure under 37 CFR 1.56.
.
SUL3L4RY 0~ ~HE ~M~ION
c ======= ============
It is there~ore the main object o~ tke present inve~tion to provide a deodorizing composition for use in ash trays, which may obviate to the above mentioned disadvantages, by effecting an efficient and constænt ~ ::
deodori~ation of the ash trays, at the same time at which the objectionable odors are produced in the ash bl~ays . ~:
~.. ...
A further object of the present lllvention i~ a method for tke ~anufacture of the deodorizing composition;:
. . .
of tke invention.
~L~IE~ ~ESCRIP~ION O~ ~E PP.IO~ AR~ DEODORTZEP.S
3========================-===========-======-= ':, ~he known air tempering deodorizer composltions m3y be subdivided into liquid type compositions which .
may be spr~yed or evaporated into the room environment, -.
and vapor emar~ting compositions embodied into solid or;
semi-solid carriers.
A deodorizer for use in ash trays must ob~iously appertain to the ola3s of the solid aeodorizers. Howe~er~
the kno~ carriers utilized for the "solid" deodorizers `:
,
may be spr~yed or evaporated into the room environment, -.
and vapor emar~ting compositions embodied into solid or;
semi-solid carriers.
A deodorizer for use in ash trays must ob~iously appertain to the ola3s of the solid aeodorizers. Howe~er~
the kno~ carriers utilized for the "solid" deodorizers `:
,
- 4 ' i~.
~2~2 are formed by gelati.no~ masses mainl~ of ~ilica gel~ or other org~nic or anorganic gelatines.
It is obvious thzt such a gelatinous compositio~
cannot be used in an ash tray, into direct contact with the cigarette butts or with the glowing fire of the cigarettes.
:`
A base suitable for a deodorizing composition ~or ash trays~ to be used inside of the ash tra~ into ~ir~ct -~
contact with the cigaret~e butts, must present the `-following featuLres:
a) It must be inco~bustible at the tempera~ure of the glowing fire of the cigarettes.
b) It must be "fluid", in order to be poured out of the ash træy, together with the cigarette butts a~d th~ ash.
c) It must have a good absorptive po~er for ~he deodorizing substances.
d) It must be capable of gradually em~lating the absorbed deodorizing substance into the surrour.ding environ~ent, withou~ being i~fluenced by the locally high temperatures produced by the glowing fire of the cigarettes.
~S~PIP~ION 0~ TH~ lN~3I~IC~
Surprisin~ly, it has been disco~ered that it is possible ~o obtain all the above objects, by usin~, as
~2~2 are formed by gelati.no~ masses mainl~ of ~ilica gel~ or other org~nic or anorganic gelatines.
It is obvious thzt such a gelatinous compositio~
cannot be used in an ash tray, into direct contact with the cigarette butts or with the glowing fire of the cigarettes.
:`
A base suitable for a deodorizing composition ~or ash trays~ to be used inside of the ash tra~ into ~ir~ct -~
contact with the cigaret~e butts, must present the `-following featuLres:
a) It must be inco~bustible at the tempera~ure of the glowing fire of the cigarettes.
b) It must be "fluid", in order to be poured out of the ash træy, together with the cigarette butts a~d th~ ash.
c) It must have a good absorptive po~er for ~he deodorizing substances.
d) It must be capable of gradually em~lating the absorbed deodorizing substance into the surrour.ding environ~ent, withou~ being i~fluenced by the locally high temperatures produced by the glowing fire of the cigarettes.
~S~PIP~ION 0~ TH~ lN~3I~IC~
Surprisin~ly, it has been disco~ered that it is possible ~o obtain all the above objects, by usin~, as
- 5 .. . . . . ..
~2~Z7Z
~bsorbent base for a deodorizing subs-ta~ce, a compo~ition containin~ amorphous porou~ silica together with sl~all ~mourlts Ol metallic oxide$, and preferably alu~
trioxide, calcium oxi~e, mzgnesium oxide, and iron ~rioxide.
~ preferred absorbent base composition ~ay co~tain, i~ W2i~1t /G:
SiO2 from 90 ~o ~5~ and pre~erably 23 from 4 to 7~0 and ~refera~ly 5'~
2 3 from 1 to 2~o ænd preferaD~ 8`~ :
CaO from O to o~ 50p,f and p~e~erably C~
~gO fro~ O to O,5~ a~à prelerably 0~3,- .
a lor the rel~ining water and/or a~alies or traces OI
other oxides. ~ :~
' :, The siliceous component may be porous synthetic silica, or a netur21 infu~orial earthg S for ins-tance Celite, ~ossil Flour, ~ieselguhr9 ~iatom~te~ ~rinolite~
~o~t~in FlouL~ or the like. Tt is al~o ~ossible tv u~e silicates with hi~l absorbing charac~eristics9 as ~lc ~:
(~ hydr~ted magnes~u~ silicate), Bentollite (a v~riet~r Of --bedded clay, co~isti~g mainly o~ silica "~Jith some alumina, and smaller q~antities of ferric o~i.de~ mz~resiu~
oxide and alkalis), or the like mineral silicates.
~ he ingredients of the above co3posi-tion, in po~Jderad form~ are mixed together and -trænsfor~ed~ by an~r ':
~2~Z7Z
~bsorbent base for a deodorizing subs-ta~ce, a compo~ition containin~ amorphous porou~ silica together with sl~all ~mourlts Ol metallic oxide$, and preferably alu~
trioxide, calcium oxi~e, mzgnesium oxide, and iron ~rioxide.
~ preferred absorbent base composition ~ay co~tain, i~ W2i~1t /G:
SiO2 from 90 ~o ~5~ and pre~erably 23 from 4 to 7~0 and ~refera~ly 5'~
2 3 from 1 to 2~o ænd preferaD~ 8`~ :
CaO from O to o~ 50p,f and p~e~erably C~
~gO fro~ O to O,5~ a~à prelerably 0~3,- .
a lor the rel~ining water and/or a~alies or traces OI
other oxides. ~ :~
' :, The siliceous component may be porous synthetic silica, or a netur21 infu~orial earthg S for ins-tance Celite, ~ossil Flour, ~ieselguhr9 ~iatom~te~ ~rinolite~
~o~t~in FlouL~ or the like. Tt is al~o ~ossible tv u~e silicates with hi~l absorbing charac~eristics9 as ~lc ~:
(~ hydr~ted magnes~u~ silicate), Bentollite (a v~riet~r Of --bedded clay, co~isti~g mainly o~ silica "~Jith some alumina, and smaller q~antities of ferric o~i.de~ mz~resiu~
oxide and alkalis), or the like mineral silicates.
~ he ingredients of the above co3posi-tion, in po~Jderad form~ are mixed together and -trænsfor~ed~ by an~r ':
- 6 ~2~;~;7Z
known ~ethod, into a grar.ular product having 2 grGin size comprised betwaen 20 and 65 mesh per cm~
A ty~ical grranulometric analysis of a co~position according to the invention is the follol~ingr:
mesh 0~ 2~o by weight ~ 20 f 28 mesh 27,2/~o by ~eight - 28 ~ 65 mesh 7105~ by weight ; ~;
- 65 mesh 1.1/Co by ~eignt ;~
mhe absorptive power of t'.^e ~o~-e cor~osltion for the oily essences is hig'r~, and preferably cG~p~rl3ed bet~.~een 1:1 æn~ 1:2 parts by ~eigrht Gf absorbed '7ub--7twr~ce ~e~ psrts by weight of absGrbingr substance. A ~ypical e.:F~ple cf ~`c~orptive power between oily substance and abscrb n~ b2se is reppresented by the ratio 44:66.
, .
Ls deodorizing subst~nces to be absorbed in t~e bçse according to the invention, a~l the decdorizing o-l1J
esser¢es normaly employed to this scope ray be 7~lsed~ as e essence, flo~ers essences, or the li~e.
`.'' In order to enhance the fixation o~ the easily e~_porable oily essences, the absorbent CoMpos-il7oq witk the oi1y essence absorbed tkerein is advantageou~ly impreg~laterl with a fixation agent, that is ~ ~apor diffusio~
retarding substance, selected from the class, comprisin~
silico~ oils, hiEh~r alcohols, or plasti'iers. 2.S an .
example of a suit~ble compound which may used as fi~ation agent, the 1,2 propylene glycol is cited~ The s-aid fixation agent is added to the compGsition in amouhn-ts rangin~ from about 10/~ to about 40~ o~ the total a-~o~nt ~ ~`
~, :
_, z~
by weight of the composition~ and preferably ~rom 15 to 20 parts b~o per 100 parts b.w. of the co~position.
The 1,2 propylene glycol has also the additional advantage that it acts as a fungicide and antibacterial agent. A typical example of a composition according to -the present invention may be a~ follows (in % bow~) .
30 - 70~o of absorbent base, as defined above.
10 - 40~o of perfumed oily essence.
10 - 40~0 of fixation agent , The pH of the ~inal product is in the range of 7.
The residual humidity at 105C is of about 0.2 ~xample The following is a manufacturing example of a deodorizing composition according to the invention.
, 57 kg of granulated absorbent base material (for 6~ ef 7~ ~r~6/e,~
instance the product sold in commcrce as Celatom MP 78) , are introduced into a tumbler mixer, provided with spray nozzles ~or spraying the deodorizing essences ænd the fixation agent.
25 kg of oily essence, and for instance ~avender ~SM
5734 produced by Givandan, are introduced through the spray nozzles into contact with the base material inside of the - mixer. As soon as the perfumed oily essence has been completely absorbed by the absorbent base material, 17 kg of 1,2 propylene glycol are added to the mixture, and mixed thoroughly therewith.
The amount of 1,2 propylene glycol may be also partially , ,, : : ;
substituted by a corre~iponding amount of ~iilicon oil.
The mixture is mixed until a complete absorbtion of the liquid components is obtained, whieh is evidenced by the fact that the final product is a free-flowing -granular substance.
It is possible to add to the final produet minor amounts o* eoloring substances, in order to improve its aspect .
The finished produet is fed to a packaging machine. Advantageously~ the product is paekaged into small bagsi eontaining one dose of produet sufficient for ~ ;
one ash tray.
The thus produeed produet is poured by the user into the ash tray. Onee e~hausted, it is poured away, together with the whole eontent of the ash tray.
Having thus deseribed my invention, what I
claim is:
' ' ' ' " ' , '~, .
.
'
known ~ethod, into a grar.ular product having 2 grGin size comprised betwaen 20 and 65 mesh per cm~
A ty~ical grranulometric analysis of a co~position according to the invention is the follol~ingr:
mesh 0~ 2~o by weight ~ 20 f 28 mesh 27,2/~o by ~eight - 28 ~ 65 mesh 7105~ by weight ; ~;
- 65 mesh 1.1/Co by ~eignt ;~
mhe absorptive power of t'.^e ~o~-e cor~osltion for the oily essences is hig'r~, and preferably cG~p~rl3ed bet~.~een 1:1 æn~ 1:2 parts by ~eigrht Gf absorbed '7ub--7twr~ce ~e~ psrts by weight of absGrbingr substance. A ~ypical e.:F~ple cf ~`c~orptive power between oily substance and abscrb n~ b2se is reppresented by the ratio 44:66.
, .
Ls deodorizing subst~nces to be absorbed in t~e bçse according to the invention, a~l the decdorizing o-l1J
esser¢es normaly employed to this scope ray be 7~lsed~ as e essence, flo~ers essences, or the li~e.
`.'' In order to enhance the fixation o~ the easily e~_porable oily essences, the absorbent CoMpos-il7oq witk the oi1y essence absorbed tkerein is advantageou~ly impreg~laterl with a fixation agent, that is ~ ~apor diffusio~
retarding substance, selected from the class, comprisin~
silico~ oils, hiEh~r alcohols, or plasti'iers. 2.S an .
example of a suit~ble compound which may used as fi~ation agent, the 1,2 propylene glycol is cited~ The s-aid fixation agent is added to the compGsition in amouhn-ts rangin~ from about 10/~ to about 40~ o~ the total a-~o~nt ~ ~`
~, :
_, z~
by weight of the composition~ and preferably ~rom 15 to 20 parts b~o per 100 parts b.w. of the co~position.
The 1,2 propylene glycol has also the additional advantage that it acts as a fungicide and antibacterial agent. A typical example of a composition according to -the present invention may be a~ follows (in % bow~) .
30 - 70~o of absorbent base, as defined above.
10 - 40~o of perfumed oily essence.
10 - 40~0 of fixation agent , The pH of the ~inal product is in the range of 7.
The residual humidity at 105C is of about 0.2 ~xample The following is a manufacturing example of a deodorizing composition according to the invention.
, 57 kg of granulated absorbent base material (for 6~ ef 7~ ~r~6/e,~
instance the product sold in commcrce as Celatom MP 78) , are introduced into a tumbler mixer, provided with spray nozzles ~or spraying the deodorizing essences ænd the fixation agent.
25 kg of oily essence, and for instance ~avender ~SM
5734 produced by Givandan, are introduced through the spray nozzles into contact with the base material inside of the - mixer. As soon as the perfumed oily essence has been completely absorbed by the absorbent base material, 17 kg of 1,2 propylene glycol are added to the mixture, and mixed thoroughly therewith.
The amount of 1,2 propylene glycol may be also partially , ,, : : ;
substituted by a corre~iponding amount of ~iilicon oil.
The mixture is mixed until a complete absorbtion of the liquid components is obtained, whieh is evidenced by the fact that the final product is a free-flowing -granular substance.
It is possible to add to the final produet minor amounts o* eoloring substances, in order to improve its aspect .
The finished produet is fed to a packaging machine. Advantageously~ the product is paekaged into small bagsi eontaining one dose of produet sufficient for ~ ;
one ash tray.
The thus produeed produet is poured by the user into the ash tray. Onee e~hausted, it is poured away, together with the whole eontent of the ash tray.
Having thus deseribed my invention, what I
claim is:
' ' ' ' " ' , '~, .
.
'
Claims (12)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A granular deodorizing composition, particular-ly for use in ash trays, where it is in direct contact with the cigarettes or cigars and butts thereof, comprising a solid absorbing substance and an absorbed deodorizing oily essence, said absorbing substance being a granular or powdered free flowing composition of an amorphous porous silica and small amounts of metallic oxides, having a grain size between 20 and 65 mesh, which composition is incombustible at the combustion temperature of the glowing end of a cigarette, cigar or butt thereof.
2. A deodorizing composition according to claim 1, in which the said base substance is composed of from 90 to 95%
by weight of said sillca and from 5 to 10% by weight, calculated on the total weight of the composition, of a mixture of metallic oxides comprising A12O3, Fe2O3, CaO and MgO.
by weight of said sillca and from 5 to 10% by weight, calculated on the total weight of the composition, of a mixture of metallic oxides comprising A12O3, Fe2O3, CaO and MgO.
3. A deodorizing composition according to claim 2, in which the said silica is a porous silicate of the class comprising Talc and Bentonite.
4. A composition according to claim 2, in which the said silica is amorphous porous synthetic silica.
5. A composition according to claim 2, in which the said silica is a natural infusorial earth.
6. A composition according to claim 1, in which the said absorbing substance is a granular substance having a grain size between 28 to 65 mesh cm2.
7 A deodorizing composition according to claim 1, comprising, in combination;
a) a solid absorbing granular material, of a grain size comprised between 25 to 65 mesh per cm2, composed, in weight %, of:
SiO2 from 90 to 95%
A12O3 from 4 to 7%
Fe2O3 from 1 to 2%
CaO from 0 to 0.5%
MgO from 0 to 0.5%
and for the remaining of water and traces of alkalies or other metallic oxides.
b) An oily essence absorbed in the said absorbent base, the amount of oily essence to absorbent base being comprised, in parts by weight, between 1:1.5 to 1:1.
a) a solid absorbing granular material, of a grain size comprised between 25 to 65 mesh per cm2, composed, in weight %, of:
SiO2 from 90 to 95%
A12O3 from 4 to 7%
Fe2O3 from 1 to 2%
CaO from 0 to 0.5%
MgO from 0 to 0.5%
and for the remaining of water and traces of alkalies or other metallic oxides.
b) An oily essence absorbed in the said absorbent base, the amount of oily essence to absorbent base being comprised, in parts by weight, between 1:1.5 to 1:1.
8. A deodorizing composition according to claim 7, including a vapor diffusion fixation agent selected from the group consisting of silicone oils, higher alcohols or plastifiers, or a mixture thereof.
9. A deodorizing composition according to claim 8, in which the said fixation agent is contained in the composition in an amount ranging from 10% to 40% by weight of the composition.
10. A deodorizing composition according to claim 7, in which the solid absorbing grannular material comprises in weight % 92% SiO2, 5% A12O3, 1.8% Fe2O3, 0.2% CaO and 0.3% MgO.
11. A deodorizing composition according to claim 8, containing in percent by weight:
From 30 to 70% of the absorbent base, From 10 to 40% of a perfumed oily essence, From 10 to 40% of the fixation agent, or a mixture of fixation agents, and minor amounts of coloring substances.
From 30 to 70% of the absorbent base, From 10 to 40% of a perfumed oily essence, From 10 to 40% of the fixation agent, or a mixture of fixation agents, and minor amounts of coloring substances.
12. A deodorizing composition according to claim 11, containing in percent by weight 57% of the absorbent base, 25%
of the perfumed oily essence and 17% of the fixation agent.
of the perfumed oily essence and 17% of the fixation agent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT12684/78A IT1103817B (en) | 1978-06-27 | 1978-06-27 | GRANULAR DEODORANT COMPOSITION FOR ASHTRAY |
| IT12684A/78 | 1978-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1121272A true CA1121272A (en) | 1982-04-06 |
Family
ID=11142701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000330181A Expired CA1121272A (en) | 1978-06-27 | 1979-06-20 | Silica with metallic oxides to absorb deodorant for use in ash trays |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4297233A (en) |
| JP (1) | JPS555786A (en) |
| AR (1) | AR218737A1 (en) |
| AT (1) | AT367636B (en) |
| AU (1) | AU520383B2 (en) |
| BE (1) | BE876406A (en) |
| BR (1) | BR7903967A (en) |
| CA (1) | CA1121272A (en) |
| CH (1) | CH642263A5 (en) |
| DE (1) | DE2923793A1 (en) |
| DK (1) | DK149732C (en) |
| ES (1) | ES482384A1 (en) |
| FR (1) | FR2429822B1 (en) |
| GB (1) | GB2024014B (en) |
| GR (1) | GR64856B (en) |
| IT (1) | IT1103817B (en) |
| LU (1) | LU81421A1 (en) |
| NL (1) | NL7904572A (en) |
| SE (1) | SE7905441L (en) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK204682A (en) * | 1981-05-08 | 1982-11-09 | Wellcome Found | Perfume-releasing materials |
| US4440542A (en) * | 1981-09-18 | 1984-04-03 | The Clorox Company | Controlled delivery of immiscible materials into an aqueous system |
| FR2528312A1 (en) * | 1982-06-09 | 1983-12-16 | Goutal Annick | NEW ODORING BODY |
| US4580581A (en) * | 1984-03-12 | 1986-04-08 | Reece Everett E | Self deodorizing ash tray |
| JPS6113961A (en) * | 1984-06-29 | 1986-01-22 | 曽田香料株式会社 | Transparent gel composition containing volatile substance |
| FR2599975B1 (en) * | 1986-06-16 | 1994-06-17 | Pointier Alain | PERFUME DIFFUSER, ODOR ABSORBENT, AND ASHTRAY EXTINGUISHER |
| DE3621068A1 (en) * | 1986-06-24 | 1988-01-14 | Manfred Mayer | Universal dish cube and ashtray which consumes smoke and butts, based on moisture with special extract of biopine fragrance |
| US5108739A (en) * | 1986-08-25 | 1992-04-28 | Titan Kogyo Kabushiki Kaisha | White colored deodorizer and process for producing the same |
| FR2603806A1 (en) * | 1986-09-15 | 1988-03-18 | Rech Bien Etre Sa | Composition for perfume lamp |
| DE3640953C2 (en) * | 1986-11-29 | 1993-11-25 | Hoelter Heinz | Chemisorption filter for filtering air |
| JPS63246167A (en) * | 1987-04-02 | 1988-10-13 | チタン工業株式会社 | White deodorant and its production |
| US5110586A (en) * | 1987-04-02 | 1992-05-05 | Titan Kogyo Kabushiki Kaisha | White colored deodorizer and process for producing the same |
| DE3728423A1 (en) * | 1987-08-26 | 1989-03-09 | Hoelter Heinz | Filter for eliminating bacteria, viruses and air pollutants, preferably for occupied spaces |
| DE3730922A1 (en) * | 1987-09-15 | 1989-04-06 | Hoelter Heinz | Chemisorption composition for eliminating odours and smoke residues, preferably tobacco smoke |
| JPS6427462A (en) * | 1987-07-22 | 1989-01-30 | Kazumasa Ando | Carpet material for ash tray |
| ATE75147T1 (en) * | 1987-11-24 | 1992-05-15 | Pictoris Beta | GRAINY SOLID DEODORIZING AGENT FOR ASHTRAYS AND RELATIVE PACKAGING. |
| US5100659A (en) * | 1988-07-22 | 1992-03-31 | Titan Kogyo Kabushiki Kaisha | White colored deodorizer and process for producing the same |
| JP3163421B2 (en) * | 1989-10-19 | 2001-05-08 | 日揮ユニバーサル株式会社 | Adsorption decomposition deodorant |
| WO1994019020A1 (en) * | 1993-02-23 | 1994-09-01 | Genentech, Inc. | Excipient stabilization of polypeptides treated with organic solvents |
| DE9317403U1 (en) * | 1993-11-12 | 1994-02-10 | Forstmaier Josef | Means of preventing unpleasant smells |
| FR2718978B1 (en) * | 1994-04-22 | 1996-05-15 | Claude Bes | Microgranular adsorbent and absorbent composition for ashtrays and process for its preparation. |
| FR2738462B1 (en) | 1995-09-13 | 1997-11-14 | Jean Marcel | DEODORIZING GRANULES FOR ASHTRAYS |
| EP0820762A1 (en) * | 1996-07-15 | 1998-01-28 | Unilever Plc | Perfume compositions |
| ES2150338B1 (en) * | 1996-10-21 | 2001-06-01 | Sanchez Brigido Garcia | SUPPORT FOR PERFECTED ENVIRONMENT. |
| WO2000021579A1 (en) * | 1998-10-09 | 2000-04-20 | Garcia Sanchez Brigido | Support for improved environmental diffuser |
| US8409618B2 (en) * | 2002-12-20 | 2013-04-02 | Kimberly-Clark Worldwide, Inc. | Odor-reducing quinone compounds |
| US7666410B2 (en) | 2002-12-20 | 2010-02-23 | Kimberly-Clark Worldwide, Inc. | Delivery system for functional compounds |
| US7582308B2 (en) | 2002-12-23 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Odor control composition |
| US7488520B2 (en) * | 2003-10-16 | 2009-02-10 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
| US7754197B2 (en) | 2003-10-16 | 2010-07-13 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using coordinated polydentate compounds |
| US7438875B2 (en) | 2003-10-16 | 2008-10-21 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified silica particles |
| US7879350B2 (en) | 2003-10-16 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using colloidal nanoparticles |
| US7582485B2 (en) | 2003-10-16 | 2009-09-01 | Kimberly-Clark Worldride, Inc. | Method and device for detecting ammonia odors and helicobacter pylori urease infection |
| US7413550B2 (en) | 2003-10-16 | 2008-08-19 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
| US7141518B2 (en) | 2003-10-16 | 2006-11-28 | Kimberly-Clark Worldwide, Inc. | Durable charged particle coatings and materials |
| US7678367B2 (en) | 2003-10-16 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified particles |
| US7837663B2 (en) | 2003-10-16 | 2010-11-23 | Kimberly-Clark Worldwide, Inc. | Odor controlling article including a visual indicating device for monitoring odor absorption |
| US7763061B2 (en) | 2004-12-23 | 2010-07-27 | Kimberly-Clark Worldwide, Inc. | Thermal coverings |
| US8168852B2 (en) * | 2004-12-23 | 2012-05-01 | Kimberly-Clark Worldwide, Inc. | Activated carbon substrates |
| US7338516B2 (en) | 2004-12-23 | 2008-03-04 | Kimberly-Clark Worldwide, Inc. | Method for applying an exothermic coating to a substrate |
| US20060142712A1 (en) * | 2004-12-23 | 2006-06-29 | Kimberly-Clark Worldwide, Inc. | Absorbent articles that provide warmth |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2778774A (en) * | 1954-12-06 | 1957-01-22 | Buslik David | Granular vermiculite deodorants |
| GB872181A (en) * | 1959-03-24 | 1961-07-05 | Watco Ltd | Improvements to floor sweeping compositions |
| US3244635A (en) * | 1962-09-10 | 1966-04-05 | Minerals & Chem Philipp Corp | Sorbent products and method for making same from attapulgite clay |
| GB1051985A (en) * | 1963-02-11 | 1900-01-01 | ||
| US3310472A (en) * | 1963-05-20 | 1967-03-21 | Norda Essential Oil And Chemic | Sea shell perfume diffuser |
| US3449266A (en) * | 1964-05-25 | 1969-06-10 | Drackett Co | Stabilized solid granular perfume composition |
| FR2130060A1 (en) * | 1971-03-19 | 1972-11-03 | Airwick Ind | Air treatment gel - contg kappa and iota carragheenins as gelling agents |
| LU63328A1 (en) * | 1971-06-14 | 1973-01-22 | ||
| JPS5019942A (en) * | 1973-06-28 | 1975-03-03 | ||
| US3909461A (en) * | 1973-07-09 | 1975-09-30 | American Cyanamid Co | Process for preparing powdered cleaning and detergent composition |
| JPS5036648A (en) * | 1973-08-06 | 1975-04-05 | ||
| US3921581A (en) * | 1974-08-01 | 1975-11-25 | Star Kist Foods | Fragrant animal litter and additives therefor |
| US3945950A (en) * | 1974-10-02 | 1976-03-23 | Universal Oil Products Company | Solid perfumed compositions of matter |
| JPS5228027A (en) * | 1975-08-28 | 1977-03-02 | Matsushita Electric Ind Co Ltd | Universal primary-air type gas burner |
| JPS5238027A (en) * | 1975-09-16 | 1977-03-24 | Junichi Arita | Deodorant composition |
| US4020156A (en) * | 1976-02-13 | 1977-04-26 | Norda Incorporated | Controlled fragrance releasing crystal beads |
| JPS52117443A (en) * | 1976-03-24 | 1977-10-01 | Noboru Fujii | Preparation method of granular perfume body |
| SE421042B (en) * | 1976-06-29 | 1981-11-23 | Kockums Chem | WANT TO REDUCE THE QUANTITY OF BIOLOGICAL ACTIVE SUBSTANCE REQUIRED FOR SOME BIOLOGICAL EFFECT |
| JPS5326335A (en) * | 1976-08-24 | 1978-03-11 | Seiwa Sangyo | Utilization method of perfume |
| JPS6010730B2 (en) * | 1976-10-16 | 1985-03-19 | 清光 大久保 | Method for producing fragrance-impregnated alumina or alumina-silica spheres |
-
1978
- 1978-06-27 IT IT12684/78A patent/IT1103817B/en active
-
1979
- 1979-05-07 JP JP5483979A patent/JPS555786A/en active Granted
- 1979-05-11 GB GB7916409A patent/GB2024014B/en not_active Expired
- 1979-05-14 US US06/038,751 patent/US4297233A/en not_active Expired - Lifetime
- 1979-05-21 BE BE0/195280A patent/BE876406A/en not_active IP Right Cessation
- 1979-05-21 CH CH472479A patent/CH642263A5/en not_active IP Right Cessation
- 1979-05-27 AU AU46827/79A patent/AU520383B2/en not_active Expired
- 1979-05-29 AT AT0389179A patent/AT367636B/en not_active IP Right Cessation
- 1979-06-07 GR GR59289A patent/GR64856B/en unknown
- 1979-06-07 FR FR7914530A patent/FR2429822B1/en not_active Expired
- 1979-06-11 NL NL7904572A patent/NL7904572A/en not_active Application Discontinuation
- 1979-06-12 DE DE19792923793 patent/DE2923793A1/en active Granted
- 1979-06-20 SE SE7905441A patent/SE7905441L/en unknown
- 1979-06-20 CA CA000330181A patent/CA1121272A/en not_active Expired
- 1979-06-22 BR BR7903967A patent/BR7903967A/en not_active IP Right Cessation
- 1979-06-22 DK DK264279A patent/DK149732C/en not_active IP Right Cessation
- 1979-06-25 LU LU81421A patent/LU81421A1/en unknown
- 1979-06-27 AR AR277080A patent/AR218737A1/en active
- 1979-06-27 ES ES482384A patent/ES482384A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2429822B1 (en) | 1986-05-16 |
| FR2429822A1 (en) | 1980-01-25 |
| ATA389179A (en) | 1981-12-15 |
| LU81421A1 (en) | 1979-09-12 |
| AU4682779A (en) | 1980-01-03 |
| DE2923793C2 (en) | 1990-12-06 |
| NL7904572A (en) | 1980-01-02 |
| IT7812684A0 (en) | 1978-06-27 |
| DK264279A (en) | 1979-12-28 |
| GB2024014B (en) | 1982-07-07 |
| GB2024014A (en) | 1980-01-09 |
| JPS6366540B2 (en) | 1988-12-21 |
| DK149732B (en) | 1986-09-22 |
| BR7903967A (en) | 1980-03-18 |
| DE2923793A1 (en) | 1980-01-03 |
| AU520383B2 (en) | 1982-01-28 |
| JPS555786A (en) | 1980-01-16 |
| DK149732C (en) | 1987-02-16 |
| SE7905441L (en) | 1979-12-28 |
| AT367636B (en) | 1982-07-26 |
| US4297233A (en) | 1981-10-27 |
| BE876406A (en) | 1979-09-17 |
| IT1103817B (en) | 1985-10-14 |
| CH642263A5 (en) | 1984-04-13 |
| AR218737A1 (en) | 1980-06-30 |
| ES482384A1 (en) | 1980-02-16 |
| GR64856B (en) | 1980-06-05 |
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Legal Events
| Date | Code | Title | Description |
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| MKEX | Expiry |