CA1127400A - Rotating fluidized bed gasifier system - Google Patents

Rotating fluidized bed gasifier system

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Publication number
CA1127400A
CA1127400A CA359,780A CA359780A CA1127400A CA 1127400 A CA1127400 A CA 1127400A CA 359780 A CA359780 A CA 359780A CA 1127400 A CA1127400 A CA 1127400A
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CA
Canada
Prior art keywords
chamber
steam
bed
gaseous
perforated wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA359,780A
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French (fr)
Inventor
William H. Belke
George B. Grim
Alexander Goloff
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Caterpillar Inc
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Caterpillar Tractor Co
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Publication date
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Publication of CA1127400A publication Critical patent/CA1127400A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/382Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it with a rotatable device only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • C10J3/487Swirling or cyclonic gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/78High-pressure apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B43/00Engines characterised by operating on gaseous fuels; Plants including such engines
    • F02B43/08Plants characterised by the engines using gaseous fuel generated in the plant from solid fuel, e.g. wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023Details
    • B01J2208/027Beds
    • B01J2208/028Beds rotating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/36Moving parts inside the gasification reactor not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606Combustion processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)

Abstract

_21_ ROTATING FLUIDIZED BED GASIFIER SYSTEM

Abstract A rotating fluidized bed gasifier system comprising an annular fluidization chamber containing a bed of carbon containing pulverulent solid materials.
The chamber which is defined by inner and outer spaced apart co-axial, cylindrical, perforated walls rotates about the longitudinal axis of the cylinders.
Steam enters the bed, which is maintained at about 1800°F., through the outer perforated wall and fluidizes the particles. A rotating fluidized bed combustor may be combined with the gasifier. In this embodiment compressed air and powdered coal enter the bed with the steam through the outer perfo-rated wall. Heat exchange tubes pass substantially longitudinally through the rotating fluidized bed.
When employed with compound engines, compressor means provide the compressed air to the gasifier-combustor and the gases exiting the bed are directed into expander means.

Description

~7~

Description Rotatin~_Fluidized ed Gasifier System Technical Field The present inventîon relates generally to fluid-ized bed gasifiers systems and, more particularly,to rotating fluidized bed gasifiers systems especially useful in compound engines.

Background Art In recent years fluidized beds have found many diverse uses in power generating systems and chemical processes. They have served as chemical reactors, particularly for finely divided materials; as incin-erators for liquid, solid or gaseous substances; as pressurized or atmospheric, coal-, lignite-, petroleum-, peat-, wood- and/or paper-fired boiler or combustor units for power generation; and, as sites for various process treatments such as drying, baking, coating, oxidizing, etc.
Typically, fluidized beds which are in use today are static beds established when air or other fluidiz-ing gas is introduced into a plenum chamber under pressure and forced upwardly through a diffusing medium (e.g., membrane, grate) to a superimposed chamber containing a particulate bed, of inert or reactive, finely divided, pulverulent solid material. Gas, forced upwardly through the diffusing medium into the fluidizing chamber under a sufficient predeter-mined pressure, fluidizes the particulates. The gas pressure required to accomplish this is determined~
in part, by the nature and degree of fineness of the powder to be fluidized. Other influencing factors are the depth of the bed and the size, number and design of the plenum chamber compartments and passages into the superimposed fluidizing chamber.
The rate at which an endothermic chemical reac-tion takes place in a fluidized bed between a solid material and a gaseous agent depends to a major e~tent on the rate at which the reactants are brought to-gether, the rate at which the heat of reaction is furnished and the rate at which the reaction products are removed. By and large the gaseous agent also serves as the fluidizing agent. In conventional static fluidized beds, the rate at which the fluidizing gaseous agent can be blown through the bed is limited by the fact that the fluidizing currents within the fluidized zone are vertical, i.e., only the gravity force on the bed particles opposes the balancing gaseous agent force needed to maintain fluidization. If the force opposing the balancing fluidizing force could be in-creased, then the fluidizing agent flow rate through ~0 the bed and the reaction rate of the system would be increased. This can be accomplished using rotating fluidized beds wherein the fluidizing gaseous agent forced through the bed from its periphery opposes the centrifugal force ~ending to throw the bed par-ticles outwardly from the bed axis of rotation toward the bed periphery. The extent of the centrifugal force and, thus, of the opposing fluidizing gaseous agent rate can be controlled by controlling the speed of bed rotation.
Gasifiers, in which steam typically reacts with carbon (coal) to form carbon monoxide and hydrogen, may be fluidized beds in which the steam fluidizes a bed containing carbon and the endothermic reaction takes place at temperatures of at least about 1800F.

7~

These high temperatures are advantageously achievedby channeling the heat generated in a combustor from a conventional carbon-oxygen exothermic reaction into the gasifier fluidized bed. The chemical reactions s are well known and proceed generally as follows:
In the combustor:
C 2 C02~174,000 BTU/mole In the gasifier:
C+H20~54,000 BTU/mole - - D CO+H2 C+2H~0~40,000 BTU/mole ~ C02+2H2 As a result of increasing the reaction rate due to the ability to increase the steam feed rate, rotating fluidizing beds used as gasifiers, e.g., in conven-tional compound engines, are extremely compact and can much more readily be integrated into powerplants.
In some applications where size is critical this can be a considerable advantage, especially when the gasifier is combined with a combustor which burns fuels inherently requiring large volumes, such as powdered coal.
A form of rotating fluidized bed combustor system has been suggested by J. Swithenbank in his article "Rotating Fluidized Bed Combustor/Gasifier". The Swithenbank system includes a vertical shaft around which rotates a generally cylindrical combustor using natural gas as the fuel. The gas is introduced at the center of the combustor, i.e., along the axis of rotation, and is mixed with fluidizing air forced through the bed particles from the bed periphery toward the center. The bed, which is heated by the combustion heat generated and the mixing action ac-companying rotation, preheats the entering fluidizing air. Most of the combustion between the heated air and the natural gas appears to occur outside, rather 1~2~46~(3 than within, the bed itself. Cooling coils passing through the bed carry air which is heated by the com-bustion and serve to control the bed and exhaust gas temperature. Swithenbank states that his combustion system may be operated by burning or gasifying coal granules in the fluidized bed, but discloses no com-bustor configuration suitable for use with coal fuels.
Moreover, Swithenbank's configuration, requiring intro-duction of the fuel along the axis of rotation, detracts from the attainment of maximum energy density because it diminishes the compactness of the system.
See also, Demircan et al, Rotating Fluidized Bed _ombustor, published in "Fluidization" by Cambridge University Press (1978). Other publications of interest in connection with the heat transfer and com-bustion characteristics of natural gas fueled rotating fluidized beds are J. Broughton and G. E. Elliott, Heat Transfer and Combustion in Centrifugal Fluidized Bed, I. Chem E. Symposium Series No. 43 (paper presented at June, 1975 meeting) and G. C. Lindauer et al, Experimental Studies on High Gravity Rotating Fluidized Bed, U.S. Atomic Energy Commission, BNL-50013 (Sept.
1966).
Gasifiers are particularly desirable stages to include in powerplants since the water in the system serves to deter the formation of nitrous oxide type emissions in the combustion gases. However, due to the high thermal input requirement of gasifiers it has proven difficult to devise a gasifier and thermal source which is particularly compact. Accordingly, the present invention is directed to overcoming one or more of the problems as set forth above.

Disclosure of Invention In one aspect of the present invention, there .

is provided a rotating fluidized bed gasifier system for endothermically reacting steam and carbon com-prising: an outer substantially cylindrical elongated perforated wall; an inner substantially cylindrical perforated wall spaced apa-rt and substantially coaxial and co-extensive with the outer perorated wall;
enclosing walls defining within the outer and inner perforated walls a substantially annular fluidization chamber; a fluidizable bed of pulverulent solid parti-cles in the chamber, said par-ticles comprising a minor proportion of carbon particles and a major proportion of inert particles; means for rotating said chamber about the axis to cause the particles to cen~rifugally gravitate toward the outer perforated wall; means for feeding a combustible fuel in a gaseous agent stream into the chamber through the outer perforated wall, the fuel reacting with at least a portion of the gaseous agent in the chamber to generate heat and to form gase-ous combustion products, any unreacted gaseous agent and the gaseous combustion products exiting the chamber through the inner perforated wall; means for intro-ducing steam through the outer perforated wall into the chamber, the steam reacting with at least a portion of the carbon particles in the chamber to form gaseous 2S reaction products, the gaseous reaction products exiting the chamber through the inner perforated wall;
means for maintaining at least a portion of the parti-cles in the chamber at a temperature conducive to the steam-carbon reaction; means for receiving the gaseous reaction products, gaseous combustion products, unre-acted gaseous agent and unreacted steam exiting from the chamber through the inner per~orated wall; and means, communicating with the means for receiving, for directing said unreacted steam, unreacted gaseous agent, gaesous combustion products and gaseous reaction ~`74~3 products exiting said inner perforated wall away from said chamber.
The rotating fluidized bed gasifier is combined with a rotating fluidized bed combustor for outstanding compactness. As the chamber is rotated about its axis, the bed particles contrifugally grav-itate toward the outer wall. Compressed air, a combustible fuel and stearn? enter the chamber through the outer perforated wall and fluidize the bed parti-cles. Generally, the fuel is fed to the fluidized bedwith the air stream, particularly if the fuel is solid, such as powdered coal. The air reacts with the fuel to form hot combustion gases and to raise the bed tem-perature to at least about 1800F. At this temperature the steam reacts with the carbon to form the gaseous reaction products which exit the fluidized bed with the hot combustion gases and unreacted steam and air through the perforated inner wall.
In an especially useful application, the rota~
ting fluidized bed gasifier-combustor combination of the present invention may be employed as a hot gas generator in a conventional compound engine. The compressed air is furnished to the gasifier combustor by one or more turbg and/or positive displacement com-pressors and the generated gases and unreacted air andsteam exiting the fluidization chamber are directed into and through one or more turbo and/or positive displacement expanders.

Brief Description of Drawings Figure 1 is a schematically simplified sec-tional view of one embodiment of the fluidized bed gasifier system of the present invention.
Figure 2 is a side elevational schematic view of a combined rotating fluidized bed gasifier-combustor ~ ~79~

showing the use thereoE in a conventional compound engine system.

Best Mode for Carr~ing_Out the Inventlon The rotating fluidized bed gasifier system of the present invention has wide utility wherever gasifiers may be used but, due to its outstanding com-pactness, is particularly adaptable for integration into powerplants, whether stationary or mobile. Refer-ring to Figure 1 a preferred form of rotating fluidized bed gasifier 101 of the present invention is more clearly depicted. As can be seen in detail the gasifier 101 includes an inlet plenum chamber 102 into which steam passes before it is directed through the .~.'' rotating fluidized bed portion 106 of the gasifier as the fluidizing medium therefor and to react with the carbon content of the bed particles. In a pre-ferred embodiment the bed particles include powdered coal, desirably solvent refined coal to minimize ash removal problems. In an alternative form of the in-vention a gaseous agent, such as compressed air, may be fed to the bed to fluidize or assist in ~luidizing the bed particles. The steam reacts with the carbon in the bed at temperatures of about 1800F. to form carbon monoxide and/or carbon dioxide and hydrogen as reaction products which exit the fluidized bed portion 106 through outlet plenum chamber 116 and are thereafter directed away therefrom.
The rotating fluidized bed portion 106 comprises an outer perforated cylindrical wall 108, an inner perforated cylindrical wall 110 and appropriate en-closing walls 109 de~ining therebetween an annular fluidizing chamber 112 in which pulverulent solid particles 114 are disposed. The perforations in walls 108 and 110 are small enough to contain particles 114 within chamber 112 and to control the exhaust of solid reaction products but large enough to sus-tain the free flow of steam and/or fluidizing air from the inlet plenum cha~ber 102 through wall 108, into and through chamber 112, through wall 110 and into outlet plenum chamber 116. The fluidized bed portion 106 rotates on horizontal, vertical or other appropriate axis, preferably about a longitudinal axis 119 which corresponds to -the axis of coaxial cylindrical walls 108, 110. Rotation is motivated by available rotational means 111, such as appropriate gearing to drives for other conventional engine ~unc-tions, and is controlled to a speed sufficient to 7~

impart a centrifugal force to the particles 114 within the bed. The centrifugal force causes the particles 114 to gravitate away from axis 119 toward outer per-forated wall 108. The flow of fluidizing steam from inlet plenum chamber 102 through perforated outer wall 108 opposes the centrifugally induced movement of the particles 114 and, in so doing, fluidizes the bed. As long as temperatures within the fluidized bed are maintained sufficiently high for the desired gasification reaction to occur, e.g. about 1800F.
to generate carbon monoxide and hydrogen, reaction occurs within the fluidizing chamber 112 between the fluidizing steam and the carbon par~icles, e.~., powdered coal, in the bed to produce hot reac~ion product gases within the bed. These hot reaction product gases are swept out of the bed through inner perforated wall 110 by the continuing flow of fluidizing steam through the bed. The unreacted fluidizing steam and the hot reaction product gases pass from outlet plenum chamber 116 into the core 118 of the gasifier 1~1.
In the preferred embodiment, core 118 is an elongated cylindrical chamber which directs the flow of unre-acted fluidizing steam and reaction product gases through turbo and/or positive displacement expanders to produce useful engine work output.
The bed particles 114 are preferably an admix-ture of inert materials, e.g., sand, dolomite, other sulfur absorbers, or any other inert material ~ener-ally found suitable for use in fluidiæed beds, and a carbonaceous fuel, such as powdered coal. For ex-ample, a suitable combination of materials comprises a particulate mixture of coal, dolomite, sand and coal ash. A generally useful proportion of bed par-ticles is 95% inert materials, 5% fuel. As the re-$~27~
g action with steam proceeds, coal ash is formed andbecomes either a part oE the inert particulate portion of the bed or passes out of the bed through the inner perforated wall llO with the unreacted fluidizing steam and reaction product gases. Any ash which passes out of the bed may be removed from the gas stream by a cyclone separator, not shown. Ash and sulfur remaining in the bed will eventually have to be cir-culated to a cleaning and reclaiming device, not shown.
If solvent re~ined coal is used, ash and sulfur re-moval is generally not a problem since this type of coal permits operation for lengthy periods without any interruption. From time to time the carbon con-tent of the bed will have to be replenished. This may be accomplished by known conventional techniques or by the carbon addition and bed replenishment method discussed in connection with Figure 2 hereof.
The temperature within the bed may be controlled in any desired manner. Desirably bed temperature is controlled by controlling the amount of heat trans-ferred to the bed from tubes (or coils) 120 which pass substantially longitudinally through the bed.
The tubes 120 may, if desired, rotate with the bed portion 106 and are supplied with a high temperature fluid from a heat source, such as combustor 200 shown in phantom in Figure l. The combustor may be conven-tional in design or may be a fluidized bed type.
Thermal energy qenerated in the combustor 200 is trans-ferred to the gasifier lOl by heat pipes 2U2 which are in thermal communication with tubes l~0. It is recommended to control the temperature of the gasi-fier bed to about 1800F. To accomplish this, as a practical matter, the combustor 200 will have to operate at a considerably higher temperature, e.g.

''` ~L~.Z~

at about 2200F. The combustor 200 may also be used to furnish thermal energy from the combustor products to water fed to tubes or coils 204 to pro~uce the steam used as the fluidizing agen~ and reactant in the gasifier. In an alternative embodiment a stationary heat exchanger (not shown) may be employed to furnish thermal energy from the hot combustor gases to water and ~ir. The water is converted to steam for use in the gasifier while the heated air is directed to the combustor as a reactant in the combustion process.
In a most preferred embodiment, the rotating fluidized bed gasifier of the present invention is combined with a combustor, desirably of the rotating fluidized bed type, which generates the thermal energy to achieve th~ at least 1800F. temperatures needed within the gasifier. The resulting combination is so outstandingly compact that it is readily incorpo-rated as the hot power gas generation source in in-tegrated powerplants. With reference to Figure 2 the combined fluidized bed gasifier-combustor of the present invention is shown in combination with ex-emplary compressor and expander elements of an other-wise conventional compound engine. The gasifier-combustor system includes a compressor means 20, which may include one or more turbo and/or positive dis-placement compressors, for furnishing compressed air t~ the gasifier-combustor and expander means 22, 24, which may include one or more turbo and/or positive displacement expanders, for producing useful work ~rom the hot combustion and reaction product gases exiting the gasifier-combustor. In some instances it may be desirable to integra~ly associate at least one compressor and one expander via a shaft assembly 14 to provide a Means for driving the compressor.

In such a case the rotating fluidized bed gasifier-combustor is advantageously mounted for rotation about the shaft assembly 14.
Co~tinuing with reference to Figure 2 the rotat-S ing fluidized bed gasifier-combustor includes a hous-ing 100 through which passes a rotatable shaft as-sembly, such as shaft assembly 14. Compressed air is ducted within hvusing 100 into inlet plenum chamber 102. The compressed air is desirably preheated air, such as exits the recuperator section of a gas turbine engine. Fuel fed through entry port ~04 is mixed with the compressed air prior to entering the inlet plenum chamber 10~ and is conveyed by the air to the rotating fluidized bed portion 106 of the gasifier-combustor. In a preferred embodiment the fuel ispowdered coal, desirably solvent refined coal to minimize ash removal problems. As in the gasifier embodiment described in connection with Figure 1, steam is fed via steam inlets 105 to the rotating fluidized bed portion 106 via inlet plenum chamber 102. The fluidized bed portion 106 is the same as has been described in connection with Figure 1. In-asmuch as at least some combustion will occur within the bed, the perforations in walls 108 and 110 should be small enough to control the exhaust of solid com-bustion products which may be formed but large enough to permit the entry of powdered fuel as well as to sustain the free flow of fluidizing air and steam from the inlet plenum chamber 102. Combustion occurs within the fluidizing chamber 112 between the fluid-izing air and the Euel, e.g., powdered coal, to pro-duce hot combustion gases within the bed. Combus-tion may also occur outside the fluidizing chamber 112, for example within elongated cylindrical co~e ~.~2~

chamber 11~.
Most importantly in connection with the Figure
2 embodiment, the combustion of the powdered coal and ~luidizing air is an exothermic reaction which produces, in situ, approximately 174,000 BTU/mole of carbon combusted. This large generation of heat within or immediately adjacent fluidization chamber 112 rapidly raises the temperature within the bed to the about 1800F. range desired for the endother-mic gasification reaction between the carbon particles in the bed and the steam. The gasification reactions which take place produce hot reaction product gases, namely carbon monoxide, carbon dioxide and hydrogen, within the bed. The hot combustion and reaction product gases produced within the chamber 112 are swept out of the bed through inner perforated wall 110 by the flow of fluidizing air and steam through the bed. The unreacted fluidizing air and steam and the hot combustion and reaction product gases pass from outlet plenum chamber 116 into core 118 where they admix with any combustion gases which may have formed as a result of combustion within core 118.
In the preferred embodiment, where the gasifier-com-bustor of the present invention is used in connection with a conventional powerplant, core 118 directs the flow of unreacted fluidizing air, unreacted steam and combustion and reaction product gases gases through positive displacement reciprocating expander 22.
The expander exhaust gases may usefully be further expanded by passage through the vanes or blades of turbine 24.
The combustion temperature within the gasifier-combustor bed is controlled in part by the ratio of air to fuel fed into the bed. In addition, bed temp-~7~

erature may be controlled by controlling the amount of heat transferred from ~he bed tubes (or coils) 120 which pass substantially longitudinally through the bed. The tubes 120 may, if desired, be used to generate steam from water supplied thereto from steam/
water supply source 122. Alternatively, tubes 120 may be used to superhea~ steam furnished by source 122 thereto. The resulting steam exiting tubes 120 may be collected or recovered in steam collection chamber 124 and optionally be directed into inlet plenum chamber 102 to comprise all or a part of the steam supply to the gasifier-combustor. By pre-de-termining the rate of flow of water or steam through the bed, localized temperatures within the bed are readily controlled. It is recommended to control the temperature of the bed in such a manner that carbon-water gasification reaction temperatures of at least about 1800F. are maintained in at least portions of the bed.
Industrial Applicability The rotating fluidized bed gasifier of the present invention has broad applicability but is particularly useful as a gasifier-combustor incorporated in conven-tional powerplants such as compound engines. Whenoperating in this capacity the fluidized bed portion 106 preferably rotates about the same axis, shaft assembly 14, on which compressor and expander elements are mounted, and rotation is motivated by sui~able gearing to other conventional engine functions. Upon rotation of the shaft assembly 14, the compressor means 20 draws air, preferably heated air, into housing 100, compresses the air, and directs the air flow into inlet plenum chamber 102. Steam is also fed 7~

via inlets 105 to inlet plenum chamber 102. Powdered coal fuel is fed through entry port 104 into the heated compressed air stream and is conveyed with the air stream and steam flow via inlet plenum chamber 102 through perforated outer wall 108 into fluidization chamber 112~ Inasmuch as the rotation of fluidized bed portion 106 causes the particles 114 within chamber 112, which are an admixture of carbon and inert materials, to gravitate toward outer wall 108, the opposing flow of the compressed air stream and steam into the chamber 112 fluidizes the particles. Com-bustion occurs within fluidizing chamber 112 between the compressed air and the powdered coal fuel to pro-duce hot combustion gases and thermal energy within the bed. This raises the temperature of the bed to the approximately 1800F. range desired for the endo-thermic gasification reaction between the carbon particles in the bed and the steam. The gasification reactions which take place produce hot reaction product gases which are swept out of the bed together with the hot combustion gases and the unreacted air and steam through inner perforated wall 110 by the flow of fluidizing compressed air and steam through the bed.
The unreacted compressed air, unreacted steam and the hot combustion and reaction product gases pass through outlet plenum chamber 116 into core 118 and are directed through positive displacement reciprocating expander 22 and then through the vanes of turbine 24 to drive the expander~turbine combination and, through shaft 1~, to drive compressor means 20 as well. Tem-peratures within the bed portion 106 ma~ be controlledand steam for feeding to the gasifier-combustor may be produced by directing water or steam through tubes 120 which extend longi-.~

74~

tudinally through bed portion 106.
Various configuration compound engines are contem-plated. For example, the compressor means 20 ma~
advantageously consist of two centrifugal stages, each having, e.g., a 3.5:1 compression ratio followed by a positive displacement stage capable of handling higher pressures, e.g., about 5-6:1 compression ratio, to produce a final pressure of about 1000 psig. The compressors may be of any type, e.g., reciprocating, rotary, etc.. Intercoolers may be advantageously used between compressor stages. Reciprocating com-pressors and expanders may be logically incorporated into a single engine block with half the cylinders running as compressors and the other half operating as expanders. The two centrifugal compressors may also usefully operate on the same shaft as two tur~
bines, all coupled to the crank, or, in some situa-tions, even running free as a turbocharger. An ex-haust gas boiler can generate steam which is directed to the tubes 120 of the gasifier-combustor to become superheated and/or to act as a temperature control in the bed.
Other aspects, objects and advantages of this invention can be obtainéd from a study of the draw-ings, the disclosure and the appended claims.

Claims (6)

Claims
1. A rotating fluidized bed gasifier system for endothermically reacting steam and carbon com-prising:
an outer substantially cylindrical elongated perforated wall;
an inner substantially cylindrical perforated wall spaced apart and substantially coaxial and co-extensive wth said other perforated wall;
enclosing walls defining within said outer and inner perforated walls a substantially annular fluidi-zation chamber;
a fluidizable bed of pulverulent solid parti-cles in said chamber, said particles comprising a minor proportion of carbon particles and a major proportion of inert particles;
means for rotating said chamber about the axis to cause the particles to centrifugally gravitate toward said outer perforated wall;
means for feeding a combustible fuel in a gaseous agent stream into said chamber through said outer perforated wall, said fuel reacting with at least a portion of said gaseous agent in said chamber to generate heat and to form gaseous combustion products, any unreacted gaseous agent and said gaseous combustion products exiting said chamber through said inner per-forated wall;
means for introducing steam through said outer perforated wall into said chamber, said steam reacting with at least a portion of said carbon particles in said chamber to form gaseous reaction products, said gaseous reaction products exiting said chamber through said inner perforated wall;
means for maintaining at least a portion of said particles in said chamber at a temperature con-ducive to said steam-carbon reaction;

means for receiving said gaseous reaction products, gaseous combustion products, unreacted gaseous agent and unreacted steam exiting from said chamber through said inner perforated wall; and means communicating with said means for receiving, for directing said unreacted steam, unreac-ted gaseous agent, gaseous combustion products and gaseous reaction products exiting said inner perforated wall away from said chamber.
2. A gasifier system, as claimed in 1, wherein said means for maintaining a temperature con-ducive to said steam-carbon reaction includes at least one tube extending substantially longitudinally through said chamber for passing a heat exchange fluid there-through.
3. A gasifier system, as claimed in claim 1, wherein said means for feeding includes chamber means communicating with said outer perforated wall, for combining said fuel with said gaseous agent prior to feeding said agent through said outer perforated wall.
4. A gasifier system, as claimed in claim 1, wherein said means for feeding includes compressor means, operatively associated with said chamber, for providing compressed air as said gaseous agent to said chamber and further including expander means, opera-tively associated with said means for directing, for converting the energy of said gaseous combustion and reaction products and unreacted steam and compressed air to output work.
5. A gasifier system, as claimed in claim 1, wherein said means for introducing steam includes said at least one tube extending substantially longitudi-nally through said chamber, means for passing water or steam into said at least one tube, means for recovering steam therefrom and means for directing said steam into said chamber.
6. A gasifier system, as claimed in claim 1, 2, or 3, wherein the substantially cylindrical space enclosed by said inner perforated wall comprises said means for receiving and means for directing said unreacted steam, unreacted gaseous agent, gaseous com-bustion products and said gaseous reaction products away from said chamber.
CA359,780A 1979-11-01 1980-09-03 Rotating fluidized bed gasifier system Expired CA1127400A (en)

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US06/099,136 US4282009A (en) 1979-11-01 1979-11-01 Rotating fluidized bed gasifier system
PCT/US1979/000929 WO1981001295A1 (en) 1979-11-01 1979-11-01 Rotating fluidized bed gasifier system
USPCT79/00929 1979-11-01

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WO (1) WO1981001295A1 (en)

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US4282009A (en) 1981-08-04
DE2967357D1 (en) 1985-02-28
EP0038795A4 (en) 1982-02-05
EP0038795B1 (en) 1985-01-16
WO1981001295A1 (en) 1981-05-14
JPS56501366A (en) 1981-09-24
EP0038795A1 (en) 1981-11-04

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