CA1141895A - Copolymers for pressure-sensitive adhesives based on acrylic esters, vinyl acetate and ethylene - Google Patents
Copolymers for pressure-sensitive adhesives based on acrylic esters, vinyl acetate and ethyleneInfo
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- CA1141895A CA1141895A CA000348092A CA348092A CA1141895A CA 1141895 A CA1141895 A CA 1141895A CA 000348092 A CA000348092 A CA 000348092A CA 348092 A CA348092 A CA 348092A CA 1141895 A CA1141895 A CA 1141895A
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- copolymerizate
- ethylene
- monomeric units
- vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
- Y10T428/2887—Adhesive compositions including addition polymer from unsaturated monomer including nitrogen containing polymer [e.g., polyacrylonitrile, polymethacrylonitrile, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
- Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A b S T R A C T
A copolymer having good properties for use as a pressure-sensitive adhesive from an aqueous dispersion com-prising:
(a) from 10% to 30% by weight of ethylene units, (b) from 29% to 69% by weight of acrylic ester units, (c) from 20% to 55% by weight of vinyl acetate units, (d) from 0.2% to 8% by weight of (meth) acylamide units, and (e) from 0 to 12% of other olefinically-unsaturated monomer units copolymerizable with the above, said copolymer having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measure in tetrahydrofuran, of from 50 to 180; as well as processes to make the same and aqueous dispersions of the same for use as pressure-sensitive adhesives.
A copolymer having good properties for use as a pressure-sensitive adhesive from an aqueous dispersion com-prising:
(a) from 10% to 30% by weight of ethylene units, (b) from 29% to 69% by weight of acrylic ester units, (c) from 20% to 55% by weight of vinyl acetate units, (d) from 0.2% to 8% by weight of (meth) acylamide units, and (e) from 0 to 12% of other olefinically-unsaturated monomer units copolymerizable with the above, said copolymer having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measure in tetrahydrofuran, of from 50 to 180; as well as processes to make the same and aqueous dispersions of the same for use as pressure-sensitive adhesives.
Description
The invention provides a copolymerizate consisting of:
(a) 10% to 30% by weight of ethylene units, tb) 29% to 69% by weight of units of acrylic acid esters of alcohols having from 4 to 12 carbon atoms, (c) 20% to 55% by weight of vinyl acetate units, (d) 0.2% to 8% by weight of monomer units of the general formula:
o CH2 = CR' - C - N(R )2 in which R' = H or CH3 and R" = H or, optionally, sub-stituted alkyl having from 1 to 3 carbon atoms, (e) 0 to 12~ by weight of other olefinically-unsaturated monomer units copolymerizable with the above, said co-polymerizate having a glass transition temperature of -20C to -60C, and a X-value, according to Fikentscher measured in tetrahydrofuran, of 50 to 180.
More particularly, the present invention relates to a copolymerizate containing:
(a) from 10% to 30% by weight of ethylene units, (b) from 29~ to 69% by weight of units of an acrylic acid ester with an alkanol having from 4 to 12 carbon atoms, (c) from 20~ to 55% by weight of vinyl acetate units, : (d) from 0.~% to 8% by weight of monomeric units having the formula:
O
CH2 = CR' - C - N(R )2 wherein R' is a member selected from the group consist-ing of hydrogen and methyl, and R" is a member selected ~141895 from the group consisting of hydrogen, alkyl having from l to 3 carbon atoms, hydroxyalkyl having from l to 3 carbon atoms, alkoxyalkyl having from 1 to 3 carbon atoms, alkanoylalkyl having from 3 to 6 carbon atoms, alkanoylamidoalkyl having from 3 to 6 carbon atoms, and alkenoylamidoalkyl having from 4 to 7 carbon atoms, and (e3 from 0 to12~ by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl and monomers as described in (d), acetate and alkyl acrylate~ said copolymerizate having a glass transition temperature of from -20C to -60C
and a K-value according to Fi~entscher, measured in tetrahydrofuran, of from 50 to 180.
The invention further provides an aqueous pressure-semsitive adhesive dispersion containing:
from 40% to 65% by weight, based on the dispersion, of the copolymerizate described above, from 1.5~ to 8% by weight, based on the copolymerizate, of emulsifiers and/or protective colloids, and from 34% to 59% by weight, based on the dispersion, of water.
The copolymerizate according to the invention has properties which indicate its excellent suitability for use as a pressure-sensitive adhesive. In particular, the influ-ence of component (d) on the total copolymer produces these properties. The pressure-sensitive adhesives made from these copolymers have a very strong cohesion, that is to say, ; splitting within the adhesive layer does not occur. In addition, the necessary outstanding adhesive properties and adhesion properties are present to a high degree. The co-polymers also have the desired resistance to aging. It must be regarded as unexpected that the incorporation by polymeri-zation of small amounts of component (d) has such a favorable effect on the properties of the total copolymer.
The copolymers are manufactures by free-radical-initiated polymerization, in an autoclave, of components (b), (c), (d) and (e) in the specified amounts under an ethylene pressure of from 20 to 120 bar at 10 to 100C.
In principle, the polymerization can be carried out in bulk or in solution but is preferably carried out in an aqueous emulsion.
The acrylic acid esters of alcohols, such as alka-nols having from 4 to 12 carbon atoms are suitable as compon-ent (b). Preferably, alkanols having from 6 to 10 carbon atoms are used, and especially the inexpensive 2-ethylhexyl acrylate. Other examples of such acrylic acid esters are butyl acrylate, hexyl acrylate, heptyl acrylate, octyl acrylate, n-decyl acrylate and dodecyl acrylate. The amounts by weight used range from 29% to 69% by weight, preferably from 29~
to 60~ by weight. Vinyl acetate, component (c), is incor-porated by polymerization in amounts ranging from 20% to 55%
by weight, preferably in amounts ranging from 25% to 50~ by weight.
Component (d), the (meth)acrylamide, is defined by the general formula. It comprises, chemically, acrylic acid amides or methacrylic acid amides. Preferably, the acrylamide or methacrylamide is not substituted. However, both may be substituted on the nitrogen atom by alkyl radi-cals having ~ to 3 carbon atoms, e.g., methyl, ethyl or propyl. These alkyl radicals may also be substituted, how-ever, for example, by hydroxyl groups, such as -CH2OH, or ether groups, such as -CH~OCH3, N-acyl groups, for example, O O
/ky~kefo~
-CH2-NH-C-CH3, -CH2-NH-C-CH=CH2 or ~e~ groups, such as -C(cH3)2-cH2-c-cH3- ~f the two hydrogen atoms on the acrylamide or methacrylamide, preferably only one is substi-tuted. Generally, however, both may be substituted by identi-cal or different substituents. The amounts of the (meth)-acrylamide component (d) used normally range from 0.2% to 8 by weight, preferably from 0.2% to 3% by weight.
The components (b), (c) and (d) polymerize almost quantitatively into the copolymer, so that the amount of them used reappears in full in the copolymer. The amount of component (a), ethylene, is controlled by the application of the pressure. Generally, pressures between 20 and 120 bar are used. The preferred range for the ethylene unit content is from 12% to 25% by weight.
Other monomers [component (e)] can be used in addi-tion to these four monomers so far described, and can be employed in amounts of from 0 to 12%by weight. If employed they are preferably present in amounts of from 0.5% to 8%
by weight. These additional monomers can basically be divided into three groups. The first group includes monomers miscible with water in any ratio. Preference is given to ~,~-unsaturated carboxylic acids, especially ~,~-alkenoic acids having from 3 to 6 carbon atoms and their water-soluble salts, such as acrylic acid and methacrylic acid and salts thereof. Crotonic acid may also be used in this connection.
Further examples of water-soluble monomers are vinyl sul-fonic acid and its water-soluble salts, N-vinyl-N-methyl-acetamide and especially N-vinylpyrrolidone. These compounds are preferably employed in amounts of from 0 to 8% by weight.
11'~1~95 The second group of monomers that may be used as component (e) are multiple olefinically-unsaturated mono-mers, such as, for example, diallyl adipate, triallyl cyan-urate, butanediol diacrylate and alI~ methacrylate. They are preferably used in amounts ranging from 0 to 2% by weight.
The third group of component (e) are the monomer-soluble monomers. Examples are vinyl ethyl ether, styrene, lower alkyl methacrylateS,such as methyl methacrylate, glycidyl (meth)acrylate, hydroxyethyl acrylate and hydroxy-propyl acrylate, vinyl chloride and vinylidene chloride.The monomers of this group are employed in amounts of from 0 to 8% by weight.
The monomers (e) are generally used in amounts ranging from 0 to1-2~ by weight. Monomers already listed under (a) to (d) are not included here.
The polymerization is carried out in conventional autoclaves. In this process, all of the monomers may be introduced initially or only part may be introduced initially and the remainder may be metered in. Preferably, comonomers such as the acrylic acid esters, which are rapidly incorpor-ated into the polymer, are metered in after a delay. The ethylene pressure at from 20 to 120 bar may be held constant throughout the polymerization at from 20 to 120 bar by the pressure of additional ethylene introduced, or it may be varied. These general measures apply to all types of polymerization.
In solution polymerization, solvents, such as, for example, alcohols having from 1 to 5 carbon atoms, esters, ketones, toluène, xylene, liquid hydrocarbons and mixtures thereof, may be used. As free-radical-initiators (0.05% to to 3% by weight), there may be mentioned in this connection azo or peroxidic compounds, for example, azoisobutyronitrile, lauryl peroxide, t.-butyl hydroperoxide, t.-butyl perpivalate, benzoyl peroxide, diisopropyl peroxydicarbonate and also redox systems which additionally contain a reducing agent, such as amines, hydrazines or sulfinic acids. The same radi-cal initiators are also suitable for bulk polymerization.
Preferably, however, the aopolymerizate is manu-factured by the polymerization in an autoclave of components (b) to (e) in the specified amounts in an aqueous emulsion in the presence of from 1.5% to 8% by weight, based on the monomers, of emulsifiers and/or protective colloids, and also free-radical initiators, under an ethylene pressure ranging from 20 to 120 bar and at a temperature ranging from 10 to 9o C ~
In this emulsion polymerization, all of component (d) is preferably present in the autoclave prior to the commencement of polymerization.
The dispersions produced generally have a solid content of 40% to 65% by weight. Dispersing agents may be any emulsifiers and protective colloids normally used in emulsion polymerization. It is possible to use either pro-tective colloids on their own, or emulsifiers on their own, and also mixtures of emulsifiers with protective colloids.
The total amount of emulsifiers and protective colloids is usually from 1.5% to 8% by weight, based on the monomers.
Examples of protective colloids that may be men-tioned are polyvinyl alcohol, partially acetylated polyvinyl alcohols, water-soluble cellulose derivatives, such as hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose or carboxymethylcellulose; water-soluble starch ethers;
11~1895 polyacrylic acid or water-soluble polyacrylic acid copoly-mers with (meth)acrylamide and/or acrylic acid esters;
poly-N-vinyl compounds of acyclic or cyclic carboxylic acid amides. The amounts generally range from 1.5% to 6% by weight, based on the polymerizate.
As emulsifiers there may be used anionic, cationic and nonionic wetting agents in amounts ranging from 1.5~ to 6~ by weight, based on the polymerizate. Suitable anionic emulsifiers are, for example, alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, sulfates of hydroxyalkanols, alkyl and alkylaryl disulfonates, sulfonated fatty acids, sulfates and phosphates of alkyl and alkylaryl polyethoxy-alkanols and sulfosuccinic acid esters. The cationic emul-sifiers which can be used are, for exam~e, alkyl ammonium salts, alkyl phosphonium salts and alkyl sulfonium salts.
Examples of suitable nonionic emulsifiers are the addition products of 5 to 50 mols of ethylene oxide onto straight-chain or branched-chain alkanols having from 6 to 22 car~on atoms, onto alkylphenols, onto higher fatty acids, onto higher fatty acid amides, and onto primary and secondary higher fatty amines, as well as block copolymers of propylene oxide with ethylene oxide.
As emulsifiers, preferably nonionic and/or anionic emulsifiers are used in amounts ranging from 1.5% to 6% by weight, based on the polymerizate, alone or in admixture with protective colloids, preferably in amounts of from 0.5%
to 4~ by weight. The dispersing agents can be metered in or can be present at the start.
The pH during the polymerization is kept between a pH of 2 and 7, preferably between a pH of 3 and 5.
For this purpose, acids, for example, formic acid, acetic acid, hydrochloric acid and sulfuric acid, or bases, for example, ammonia, amines, sodium hydroxide, potassium hydrox-ide and calcium hydroxide, or customary buffer salts, for example, alkali metal acetates, alkali metal carbonates and alkali metal phosphates, may be added.
The free-radical initiators used are the customary completely or partially water-soluble catalysts, especially peroxidic compounds, in amounts ranging from 0.02% to 2% by weight, based on the monomer content. Examples of such free-radical initiators are hydrogen peroxide, sodium persulfate, potassium persulfate and ammonium persulfate, and also tert.-butylhydroperoxide, azo-bis-(2-amidinopropane)-hydrochloride, or azo-bis-(2-cyanovaleric acid). They may be used alone or together with reducing agents in amounts ranging from 0.02%
to 2% by weight, based on the monomer, for example, formalde-hyde sodium sulfoxylate, iron (II) salts, sodium dithionate, sodium hydrogen sulfite, sodium sulfite, sodium thiosulfate or amines as the redox catalysts.
Furthermore, also suitable is the redox catalyst system described in German Patent 1,133,130, German Patent 1,745,567, and United States Patent 3,563,963, consisting of noble metal sols of Group VIII of the Periodic Table of Ele-ments, inorganic or organic peroxides, and hydrogen as the reducing agent and, optionally, heavy metal ions.
Preferably, redox catalysts are used. The free-radical initiators can be present wholly or partially at the start of polymerization and the remainder can be metered in.
Preferably, one or both redox catalyst components is/are metered in during polymerization.
11~1895 In order to regulate the molecular weight, known polymerization regulators, for example, mercaptans, aldehydes or chlorohydrocarbons, may be added during polymerization.
The principal application of the copolymers accord-ing to the invention lies in their use as pressure-sensitive adhesives. Pressure-sensitive adhesives are mostly applied to a wide variety of carrier materialsand used in the form of self-adhesive materials, for example, adhesive tapes or adhe-sive sheets. They must combine the properties of adhesive-ness, cohesion and adhesion to the greatest possible extent.They are intended to adhere to a wide variety of substrates when subjected to gentle pressure with the fingers and to peel off the substrate to which t'ney have been affixed without leav-ing traces of adhesive behind and, in some cases, even de-stroying the substrate. Stability on aging is also a require-ment. The copolymers according to the invention have these properties to a high degree. They can be dissolved in bulk and inorganic solvents and may be used in aqueous emulsion as pressure-sensitive adhesives. The addition of customary additives for pressure-sensitive adhesives, up to 50% of the copolymer is fre~uently desirable. Examples of such additives are fillers, pigments, plasticizers and resins. Examples of fillers that may be considered are chalks, gypsum and barite;
fine types of kaolin, mica powders and types of talc. Examples ; of piyments that may be used are titanium dioxide, zinc oxide and lithopone.
Suitable plasticizers are the so-called "monomer"
plasticizers. These are particularly esters of carboxylic acids with alcohols having from 4 to 13 carbon atoms, and~or tert.-phosphoric acid esters having optionally substituted alkyl groups having from 2 to 10 carbon atoms, particularly haloalkyls, and/or optionally alkyl-substituted phenyl groups.
Particularly preferred carboxylic acid esters are die~ters of phthalic acid with alkanols having from 4 to 13, prefer-ably from 4 to 8, carbon atoms, and also diesters of sebacic acid and adipic acid with alkanols having from 6 to 10 carbon atoms.
Particularly preferred tert.-phosphoric acid esters are, for example, tricresyl phosphate, dicresylphenyl phos-phate, cresyl-d~henyl phosphate, triphenyl phosphate, xylenyl-diphenyl phosphate, dixylenyl-phenyl phosphate, tris(chloro-ethyl) phosphate, diphenyl-octyl phosphate, phenyl-dioctyl phosphate and trioctyl phosphate. The monomer plasticizers may, of course, be used alone or as a mixture.
The pressure-sensitive adhesives according to the invention may have other customary additives added to them, for example, colophony resins, colophony resin derivatives, cumarene resins, indene resins, phenol-formaldehyde resins and hydrocarbon resins, waxes, paraffin oils, solvents, pigments, other polymerization products and/or soluble dyestuffs. If desired, such additives are added in amounts preferably up to a total of about 25% by weight, more especially up to about 15~ by weight, calculated on the final pressure-sensitive adhesive mixture.
Uses that may be mentioned are on adhesive tapes, adhesive sheets, self-adhesive carpets and polyvinyl chloride floor coverings, self-adhesive labels, self-adhesive assembly parts such as decorative strips and hooks. The pressure-sensitive adhesives are ordinarily applied to the carrier in amounts of from 5 to 100 gm/m2.
E X A M P L E S
In the following examples, details are given of the tack (surface stickiness), peel strength (adhesive power), and shear strength (cohesion) of coatings manufactured with the dispersions according to the invention.
The term "adhesive strips",which is used several times, means strips of flexible sheet-like carrier material coated with a film of a dispersion according to the invention.
The numerical data is based on the following methods of analysis.
A. Tack (Surface Stickiness) An adhesive strip 20 cm long and 2.5 cm wide (car-rier material:PVC containing polymer pla~ticizers, 0.1 mm thick) is clamped in the form of a "loop" in the upper jaw of a tensile-testing machine so that it hangs vertically with the layer of adhesive on the outside. A length of about 3 cm of the "loop" is then placed, without applying pressure, on a horizontally secured, carefully cleaned glass plate by moving the two jaws of the tensile-testing machine vertically together at a speed of 100 mm/min. At the same speed, the adhesive strip is then immediately pulled away from the surface of the glass. The highest force required for pulling away the "loop" serves as a measure of the surface stickiness.
The value given is the mean value from five separate measurements, a fresh adhesive strip and a fresh glass surface being used each time.
B. Peel Strength (Adhesive Power) An adhesive strip 20 cm long and 2.5 cm wide is placed, starting from one end and for a length of about 12 cm and in such a way that no air bubbles form, on a carefully 11~1895 cleaned plate of V4A steel. By rolling five times (backwards and forwards) with a 2.2 kg steei roller covered with silicone rubber, the adhesive strip is pressed onto the steel plate.
After stora~e in an air-conditioned room for 8 minutes or 24 hours at 23C and 50% relative atmospheric humidity, a 5 cm length of the adhesive strip is pulled off at a speed of 78 mm/min. at angle of 180. The average force required for this is measured. The values given are mean values from five separate measurements in each case.
C. Shear Strength (Cohesion) An area 2.5 cm x 2.5 cm of a 5 cm long and 2.5 cm wide adhesive strip is placed on a carefully cleaned glass plate so that no air bubbles form and so that the remaining portion of the adhesive strip projects beyond the edge of the glass plate. The strip is pressed onto the place by rolling (five times backwards and forwards) with a 2.2 kg steel roller covered with silicone rubber. After a bonding duration of 8 minutes, the glass plate is secured in a holder at an angle of 2 to the vertical (in order to exclude definitely any peel forces) such that the free end of the adhesive strip points downwards. To this end of the adhesive strip, a weight of 2 kg is secured so that it hangs freely. The free end of the adhesive strip and the reverse of the glass plate form an angle of 178. The time taken for the adhesive strip to detach itself from the glass plate under the pull of the weight is measured. The measurement is carried out in an air-conditioned room at 23C and 50~ relative atmospheric humidity. The values given are mean values from three separate measurements.
- ` 1141895 For all measurements the adhesive dispersions tested were applied to the different carrier sheets with a doctor blade at a thickness such that after drying a uniform polymer layer of 24 to 26 gm/m2 remains.
The glass surface used in the test was cleaned (in the order given) by mechanical removal of visible traces of dirt using water and, if desired, detergents, storage in fresh chromosulfuric acid, storage in a methylethylketone bath and in ethanol bath. V4A-surfaces were similarly cleaned (without storage in chromosulfuric acid).
Before using the test surfaces thus cleaned, the plates were kept for at least 48 hours in an air-conditioned room at 23C and 50~ relative atmospheric humidity.
To determine the wet strength, a 0.1 mm thick adhesive strip of PVC containing polymer plasticizers was affixed to V4A-steel in analogy to the procedure for measur-ing the peel strength, and after the assembly had been stored for three days in water, the peel strength was measured at room temperature.
The reactor employed was 16-liter pressure reactor equipped with a stirrer, several dosing means, coo7ing and heating means, as well as a manometer and temperature measur-ing means. In this reactor, 200 gm of nonylphenyl poly-ethylene glycol ether with 20 mols of ethylene oxide units, 15 gm of sodium dodecylbenzenesulfonate, 30 gm of potassium persulfate, 100 gm of acrylic acid and 165 gm of acrylamide were dissolved in 4,000 gm of water. After deaerating with nitrogen, 2,000 gm of vinyl acetate and 3,000 gm of 2-ethyl-hexyl acrylate were added thereto under stirring. After 1~418~5 displacing the nitrogen with ethylene, the reactor was heated to 50C and ethylene at a pressure of 50 bar was pressed in until the saturation equilibrium was obtained.
The polymerization was carried out by the addition, according to the rate of polymerization, of a solution of 15 gm of sodium formaldehyde sulfoxylate in 700 gm of water over the course of 5 hours. The ethylene pressure was reduced during the pQlymerization to 40 bar. The pressure was then released and the mixture was introduced into a 30-liter stir-ring vessel. The remaining ethylene was removed by stirring and the application of a slight vacuum. A stable plastics dispersion having a viscosity of 3,000 mPa.S and a solids content of 53% was obtained.
The K-value (according to Fikentscher, "Cellulose-chemie" lCellulose Chemistry], Vol. 13, p. 58, 1932; measured in a 1~ tetrahydrofuran solution) of the polymer was 88.
The glass transition temperature was -42C. The dispersion dries to a viscous, very sticky film.
Polymer Composition 1.6% acrylic acid
(a) 10% to 30% by weight of ethylene units, tb) 29% to 69% by weight of units of acrylic acid esters of alcohols having from 4 to 12 carbon atoms, (c) 20% to 55% by weight of vinyl acetate units, (d) 0.2% to 8% by weight of monomer units of the general formula:
o CH2 = CR' - C - N(R )2 in which R' = H or CH3 and R" = H or, optionally, sub-stituted alkyl having from 1 to 3 carbon atoms, (e) 0 to 12~ by weight of other olefinically-unsaturated monomer units copolymerizable with the above, said co-polymerizate having a glass transition temperature of -20C to -60C, and a X-value, according to Fikentscher measured in tetrahydrofuran, of 50 to 180.
More particularly, the present invention relates to a copolymerizate containing:
(a) from 10% to 30% by weight of ethylene units, (b) from 29~ to 69% by weight of units of an acrylic acid ester with an alkanol having from 4 to 12 carbon atoms, (c) from 20~ to 55% by weight of vinyl acetate units, : (d) from 0.~% to 8% by weight of monomeric units having the formula:
O
CH2 = CR' - C - N(R )2 wherein R' is a member selected from the group consist-ing of hydrogen and methyl, and R" is a member selected ~141895 from the group consisting of hydrogen, alkyl having from l to 3 carbon atoms, hydroxyalkyl having from l to 3 carbon atoms, alkoxyalkyl having from 1 to 3 carbon atoms, alkanoylalkyl having from 3 to 6 carbon atoms, alkanoylamidoalkyl having from 3 to 6 carbon atoms, and alkenoylamidoalkyl having from 4 to 7 carbon atoms, and (e3 from 0 to12~ by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl and monomers as described in (d), acetate and alkyl acrylate~ said copolymerizate having a glass transition temperature of from -20C to -60C
and a K-value according to Fi~entscher, measured in tetrahydrofuran, of from 50 to 180.
The invention further provides an aqueous pressure-semsitive adhesive dispersion containing:
from 40% to 65% by weight, based on the dispersion, of the copolymerizate described above, from 1.5~ to 8% by weight, based on the copolymerizate, of emulsifiers and/or protective colloids, and from 34% to 59% by weight, based on the dispersion, of water.
The copolymerizate according to the invention has properties which indicate its excellent suitability for use as a pressure-sensitive adhesive. In particular, the influ-ence of component (d) on the total copolymer produces these properties. The pressure-sensitive adhesives made from these copolymers have a very strong cohesion, that is to say, ; splitting within the adhesive layer does not occur. In addition, the necessary outstanding adhesive properties and adhesion properties are present to a high degree. The co-polymers also have the desired resistance to aging. It must be regarded as unexpected that the incorporation by polymeri-zation of small amounts of component (d) has such a favorable effect on the properties of the total copolymer.
The copolymers are manufactures by free-radical-initiated polymerization, in an autoclave, of components (b), (c), (d) and (e) in the specified amounts under an ethylene pressure of from 20 to 120 bar at 10 to 100C.
In principle, the polymerization can be carried out in bulk or in solution but is preferably carried out in an aqueous emulsion.
The acrylic acid esters of alcohols, such as alka-nols having from 4 to 12 carbon atoms are suitable as compon-ent (b). Preferably, alkanols having from 6 to 10 carbon atoms are used, and especially the inexpensive 2-ethylhexyl acrylate. Other examples of such acrylic acid esters are butyl acrylate, hexyl acrylate, heptyl acrylate, octyl acrylate, n-decyl acrylate and dodecyl acrylate. The amounts by weight used range from 29% to 69% by weight, preferably from 29~
to 60~ by weight. Vinyl acetate, component (c), is incor-porated by polymerization in amounts ranging from 20% to 55%
by weight, preferably in amounts ranging from 25% to 50~ by weight.
Component (d), the (meth)acrylamide, is defined by the general formula. It comprises, chemically, acrylic acid amides or methacrylic acid amides. Preferably, the acrylamide or methacrylamide is not substituted. However, both may be substituted on the nitrogen atom by alkyl radi-cals having ~ to 3 carbon atoms, e.g., methyl, ethyl or propyl. These alkyl radicals may also be substituted, how-ever, for example, by hydroxyl groups, such as -CH2OH, or ether groups, such as -CH~OCH3, N-acyl groups, for example, O O
/ky~kefo~
-CH2-NH-C-CH3, -CH2-NH-C-CH=CH2 or ~e~ groups, such as -C(cH3)2-cH2-c-cH3- ~f the two hydrogen atoms on the acrylamide or methacrylamide, preferably only one is substi-tuted. Generally, however, both may be substituted by identi-cal or different substituents. The amounts of the (meth)-acrylamide component (d) used normally range from 0.2% to 8 by weight, preferably from 0.2% to 3% by weight.
The components (b), (c) and (d) polymerize almost quantitatively into the copolymer, so that the amount of them used reappears in full in the copolymer. The amount of component (a), ethylene, is controlled by the application of the pressure. Generally, pressures between 20 and 120 bar are used. The preferred range for the ethylene unit content is from 12% to 25% by weight.
Other monomers [component (e)] can be used in addi-tion to these four monomers so far described, and can be employed in amounts of from 0 to 12%by weight. If employed they are preferably present in amounts of from 0.5% to 8%
by weight. These additional monomers can basically be divided into three groups. The first group includes monomers miscible with water in any ratio. Preference is given to ~,~-unsaturated carboxylic acids, especially ~,~-alkenoic acids having from 3 to 6 carbon atoms and their water-soluble salts, such as acrylic acid and methacrylic acid and salts thereof. Crotonic acid may also be used in this connection.
Further examples of water-soluble monomers are vinyl sul-fonic acid and its water-soluble salts, N-vinyl-N-methyl-acetamide and especially N-vinylpyrrolidone. These compounds are preferably employed in amounts of from 0 to 8% by weight.
11'~1~95 The second group of monomers that may be used as component (e) are multiple olefinically-unsaturated mono-mers, such as, for example, diallyl adipate, triallyl cyan-urate, butanediol diacrylate and alI~ methacrylate. They are preferably used in amounts ranging from 0 to 2% by weight.
The third group of component (e) are the monomer-soluble monomers. Examples are vinyl ethyl ether, styrene, lower alkyl methacrylateS,such as methyl methacrylate, glycidyl (meth)acrylate, hydroxyethyl acrylate and hydroxy-propyl acrylate, vinyl chloride and vinylidene chloride.The monomers of this group are employed in amounts of from 0 to 8% by weight.
The monomers (e) are generally used in amounts ranging from 0 to1-2~ by weight. Monomers already listed under (a) to (d) are not included here.
The polymerization is carried out in conventional autoclaves. In this process, all of the monomers may be introduced initially or only part may be introduced initially and the remainder may be metered in. Preferably, comonomers such as the acrylic acid esters, which are rapidly incorpor-ated into the polymer, are metered in after a delay. The ethylene pressure at from 20 to 120 bar may be held constant throughout the polymerization at from 20 to 120 bar by the pressure of additional ethylene introduced, or it may be varied. These general measures apply to all types of polymerization.
In solution polymerization, solvents, such as, for example, alcohols having from 1 to 5 carbon atoms, esters, ketones, toluène, xylene, liquid hydrocarbons and mixtures thereof, may be used. As free-radical-initiators (0.05% to to 3% by weight), there may be mentioned in this connection azo or peroxidic compounds, for example, azoisobutyronitrile, lauryl peroxide, t.-butyl hydroperoxide, t.-butyl perpivalate, benzoyl peroxide, diisopropyl peroxydicarbonate and also redox systems which additionally contain a reducing agent, such as amines, hydrazines or sulfinic acids. The same radi-cal initiators are also suitable for bulk polymerization.
Preferably, however, the aopolymerizate is manu-factured by the polymerization in an autoclave of components (b) to (e) in the specified amounts in an aqueous emulsion in the presence of from 1.5% to 8% by weight, based on the monomers, of emulsifiers and/or protective colloids, and also free-radical initiators, under an ethylene pressure ranging from 20 to 120 bar and at a temperature ranging from 10 to 9o C ~
In this emulsion polymerization, all of component (d) is preferably present in the autoclave prior to the commencement of polymerization.
The dispersions produced generally have a solid content of 40% to 65% by weight. Dispersing agents may be any emulsifiers and protective colloids normally used in emulsion polymerization. It is possible to use either pro-tective colloids on their own, or emulsifiers on their own, and also mixtures of emulsifiers with protective colloids.
The total amount of emulsifiers and protective colloids is usually from 1.5% to 8% by weight, based on the monomers.
Examples of protective colloids that may be men-tioned are polyvinyl alcohol, partially acetylated polyvinyl alcohols, water-soluble cellulose derivatives, such as hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose or carboxymethylcellulose; water-soluble starch ethers;
11~1895 polyacrylic acid or water-soluble polyacrylic acid copoly-mers with (meth)acrylamide and/or acrylic acid esters;
poly-N-vinyl compounds of acyclic or cyclic carboxylic acid amides. The amounts generally range from 1.5% to 6% by weight, based on the polymerizate.
As emulsifiers there may be used anionic, cationic and nonionic wetting agents in amounts ranging from 1.5~ to 6~ by weight, based on the polymerizate. Suitable anionic emulsifiers are, for example, alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, sulfates of hydroxyalkanols, alkyl and alkylaryl disulfonates, sulfonated fatty acids, sulfates and phosphates of alkyl and alkylaryl polyethoxy-alkanols and sulfosuccinic acid esters. The cationic emul-sifiers which can be used are, for exam~e, alkyl ammonium salts, alkyl phosphonium salts and alkyl sulfonium salts.
Examples of suitable nonionic emulsifiers are the addition products of 5 to 50 mols of ethylene oxide onto straight-chain or branched-chain alkanols having from 6 to 22 car~on atoms, onto alkylphenols, onto higher fatty acids, onto higher fatty acid amides, and onto primary and secondary higher fatty amines, as well as block copolymers of propylene oxide with ethylene oxide.
As emulsifiers, preferably nonionic and/or anionic emulsifiers are used in amounts ranging from 1.5% to 6% by weight, based on the polymerizate, alone or in admixture with protective colloids, preferably in amounts of from 0.5%
to 4~ by weight. The dispersing agents can be metered in or can be present at the start.
The pH during the polymerization is kept between a pH of 2 and 7, preferably between a pH of 3 and 5.
For this purpose, acids, for example, formic acid, acetic acid, hydrochloric acid and sulfuric acid, or bases, for example, ammonia, amines, sodium hydroxide, potassium hydrox-ide and calcium hydroxide, or customary buffer salts, for example, alkali metal acetates, alkali metal carbonates and alkali metal phosphates, may be added.
The free-radical initiators used are the customary completely or partially water-soluble catalysts, especially peroxidic compounds, in amounts ranging from 0.02% to 2% by weight, based on the monomer content. Examples of such free-radical initiators are hydrogen peroxide, sodium persulfate, potassium persulfate and ammonium persulfate, and also tert.-butylhydroperoxide, azo-bis-(2-amidinopropane)-hydrochloride, or azo-bis-(2-cyanovaleric acid). They may be used alone or together with reducing agents in amounts ranging from 0.02%
to 2% by weight, based on the monomer, for example, formalde-hyde sodium sulfoxylate, iron (II) salts, sodium dithionate, sodium hydrogen sulfite, sodium sulfite, sodium thiosulfate or amines as the redox catalysts.
Furthermore, also suitable is the redox catalyst system described in German Patent 1,133,130, German Patent 1,745,567, and United States Patent 3,563,963, consisting of noble metal sols of Group VIII of the Periodic Table of Ele-ments, inorganic or organic peroxides, and hydrogen as the reducing agent and, optionally, heavy metal ions.
Preferably, redox catalysts are used. The free-radical initiators can be present wholly or partially at the start of polymerization and the remainder can be metered in.
Preferably, one or both redox catalyst components is/are metered in during polymerization.
11~1895 In order to regulate the molecular weight, known polymerization regulators, for example, mercaptans, aldehydes or chlorohydrocarbons, may be added during polymerization.
The principal application of the copolymers accord-ing to the invention lies in their use as pressure-sensitive adhesives. Pressure-sensitive adhesives are mostly applied to a wide variety of carrier materialsand used in the form of self-adhesive materials, for example, adhesive tapes or adhe-sive sheets. They must combine the properties of adhesive-ness, cohesion and adhesion to the greatest possible extent.They are intended to adhere to a wide variety of substrates when subjected to gentle pressure with the fingers and to peel off the substrate to which t'ney have been affixed without leav-ing traces of adhesive behind and, in some cases, even de-stroying the substrate. Stability on aging is also a require-ment. The copolymers according to the invention have these properties to a high degree. They can be dissolved in bulk and inorganic solvents and may be used in aqueous emulsion as pressure-sensitive adhesives. The addition of customary additives for pressure-sensitive adhesives, up to 50% of the copolymer is fre~uently desirable. Examples of such additives are fillers, pigments, plasticizers and resins. Examples of fillers that may be considered are chalks, gypsum and barite;
fine types of kaolin, mica powders and types of talc. Examples ; of piyments that may be used are titanium dioxide, zinc oxide and lithopone.
Suitable plasticizers are the so-called "monomer"
plasticizers. These are particularly esters of carboxylic acids with alcohols having from 4 to 13 carbon atoms, and~or tert.-phosphoric acid esters having optionally substituted alkyl groups having from 2 to 10 carbon atoms, particularly haloalkyls, and/or optionally alkyl-substituted phenyl groups.
Particularly preferred carboxylic acid esters are die~ters of phthalic acid with alkanols having from 4 to 13, prefer-ably from 4 to 8, carbon atoms, and also diesters of sebacic acid and adipic acid with alkanols having from 6 to 10 carbon atoms.
Particularly preferred tert.-phosphoric acid esters are, for example, tricresyl phosphate, dicresylphenyl phos-phate, cresyl-d~henyl phosphate, triphenyl phosphate, xylenyl-diphenyl phosphate, dixylenyl-phenyl phosphate, tris(chloro-ethyl) phosphate, diphenyl-octyl phosphate, phenyl-dioctyl phosphate and trioctyl phosphate. The monomer plasticizers may, of course, be used alone or as a mixture.
The pressure-sensitive adhesives according to the invention may have other customary additives added to them, for example, colophony resins, colophony resin derivatives, cumarene resins, indene resins, phenol-formaldehyde resins and hydrocarbon resins, waxes, paraffin oils, solvents, pigments, other polymerization products and/or soluble dyestuffs. If desired, such additives are added in amounts preferably up to a total of about 25% by weight, more especially up to about 15~ by weight, calculated on the final pressure-sensitive adhesive mixture.
Uses that may be mentioned are on adhesive tapes, adhesive sheets, self-adhesive carpets and polyvinyl chloride floor coverings, self-adhesive labels, self-adhesive assembly parts such as decorative strips and hooks. The pressure-sensitive adhesives are ordinarily applied to the carrier in amounts of from 5 to 100 gm/m2.
E X A M P L E S
In the following examples, details are given of the tack (surface stickiness), peel strength (adhesive power), and shear strength (cohesion) of coatings manufactured with the dispersions according to the invention.
The term "adhesive strips",which is used several times, means strips of flexible sheet-like carrier material coated with a film of a dispersion according to the invention.
The numerical data is based on the following methods of analysis.
A. Tack (Surface Stickiness) An adhesive strip 20 cm long and 2.5 cm wide (car-rier material:PVC containing polymer pla~ticizers, 0.1 mm thick) is clamped in the form of a "loop" in the upper jaw of a tensile-testing machine so that it hangs vertically with the layer of adhesive on the outside. A length of about 3 cm of the "loop" is then placed, without applying pressure, on a horizontally secured, carefully cleaned glass plate by moving the two jaws of the tensile-testing machine vertically together at a speed of 100 mm/min. At the same speed, the adhesive strip is then immediately pulled away from the surface of the glass. The highest force required for pulling away the "loop" serves as a measure of the surface stickiness.
The value given is the mean value from five separate measurements, a fresh adhesive strip and a fresh glass surface being used each time.
B. Peel Strength (Adhesive Power) An adhesive strip 20 cm long and 2.5 cm wide is placed, starting from one end and for a length of about 12 cm and in such a way that no air bubbles form, on a carefully 11~1895 cleaned plate of V4A steel. By rolling five times (backwards and forwards) with a 2.2 kg steei roller covered with silicone rubber, the adhesive strip is pressed onto the steel plate.
After stora~e in an air-conditioned room for 8 minutes or 24 hours at 23C and 50% relative atmospheric humidity, a 5 cm length of the adhesive strip is pulled off at a speed of 78 mm/min. at angle of 180. The average force required for this is measured. The values given are mean values from five separate measurements in each case.
C. Shear Strength (Cohesion) An area 2.5 cm x 2.5 cm of a 5 cm long and 2.5 cm wide adhesive strip is placed on a carefully cleaned glass plate so that no air bubbles form and so that the remaining portion of the adhesive strip projects beyond the edge of the glass plate. The strip is pressed onto the place by rolling (five times backwards and forwards) with a 2.2 kg steel roller covered with silicone rubber. After a bonding duration of 8 minutes, the glass plate is secured in a holder at an angle of 2 to the vertical (in order to exclude definitely any peel forces) such that the free end of the adhesive strip points downwards. To this end of the adhesive strip, a weight of 2 kg is secured so that it hangs freely. The free end of the adhesive strip and the reverse of the glass plate form an angle of 178. The time taken for the adhesive strip to detach itself from the glass plate under the pull of the weight is measured. The measurement is carried out in an air-conditioned room at 23C and 50~ relative atmospheric humidity. The values given are mean values from three separate measurements.
- ` 1141895 For all measurements the adhesive dispersions tested were applied to the different carrier sheets with a doctor blade at a thickness such that after drying a uniform polymer layer of 24 to 26 gm/m2 remains.
The glass surface used in the test was cleaned (in the order given) by mechanical removal of visible traces of dirt using water and, if desired, detergents, storage in fresh chromosulfuric acid, storage in a methylethylketone bath and in ethanol bath. V4A-surfaces were similarly cleaned (without storage in chromosulfuric acid).
Before using the test surfaces thus cleaned, the plates were kept for at least 48 hours in an air-conditioned room at 23C and 50~ relative atmospheric humidity.
To determine the wet strength, a 0.1 mm thick adhesive strip of PVC containing polymer plasticizers was affixed to V4A-steel in analogy to the procedure for measur-ing the peel strength, and after the assembly had been stored for three days in water, the peel strength was measured at room temperature.
The reactor employed was 16-liter pressure reactor equipped with a stirrer, several dosing means, coo7ing and heating means, as well as a manometer and temperature measur-ing means. In this reactor, 200 gm of nonylphenyl poly-ethylene glycol ether with 20 mols of ethylene oxide units, 15 gm of sodium dodecylbenzenesulfonate, 30 gm of potassium persulfate, 100 gm of acrylic acid and 165 gm of acrylamide were dissolved in 4,000 gm of water. After deaerating with nitrogen, 2,000 gm of vinyl acetate and 3,000 gm of 2-ethyl-hexyl acrylate were added thereto under stirring. After 1~418~5 displacing the nitrogen with ethylene, the reactor was heated to 50C and ethylene at a pressure of 50 bar was pressed in until the saturation equilibrium was obtained.
The polymerization was carried out by the addition, according to the rate of polymerization, of a solution of 15 gm of sodium formaldehyde sulfoxylate in 700 gm of water over the course of 5 hours. The ethylene pressure was reduced during the pQlymerization to 40 bar. The pressure was then released and the mixture was introduced into a 30-liter stir-ring vessel. The remaining ethylene was removed by stirring and the application of a slight vacuum. A stable plastics dispersion having a viscosity of 3,000 mPa.S and a solids content of 53% was obtained.
The K-value (according to Fikentscher, "Cellulose-chemie" lCellulose Chemistry], Vol. 13, p. 58, 1932; measured in a 1~ tetrahydrofuran solution) of the polymer was 88.
The glass transition temperature was -42C. The dispersion dries to a viscous, very sticky film.
Polymer Composition 1.6% acrylic acid
2.6% acrylamide 18.0~ ethylene 31.1~ vinyl acetate 46.7% 2-ethylhexyl acrylate.
The coating of 25 ~ dry thickness on a 100 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 3.9 N/2.5 cm;
Peel strength after 8 min. 7 N~2.5 cm, Peel strength after 24 hrs. 12 N/2.5 cm, Shear strength was 660 minutes, Wet strength 7 N/2.5 cm. (N = Newton) The process was carried out as in Example l, but instead of 165 gm of acrylamide, 180 gm of methacrylamide were added, and a monomer mixture of 3,000 gm of vinyl acetate and 2,000 gm of octyl acrylate was added. The ethylene pres-sure was set to 75 atmospheres and was held at this level for 4 hours after the start of polymerization. A stable disper-sion having a solids content of 60% was obtained. The K-value was 67. The glass transi~ion temperature was -48C. The dispersion forms a viscous, sticky film.
Polymer Composition 1.5~ acrylic acid 2.7% methacrylamide 22.0~ ethylene 44.3~ vinyl acetate 29.5% octyl acrylate.
The process was carried out as in Example 1, but a monomer mixture of 2,000 gm of vinyl acetate and l,000 gm of 2-ethylhexyl acrylate and 165 gm of acrylamide was present before the start of polymerization. Fifteen minutes after the start of polymerization, a further 2,000 gm of 2-ethyl-hexyl acrylate were added at a constant rate over the course of 2.5 hours. The dispersion was stable and had a solids content of 54%. The K-value was 85. The glass transition temperature was -41C. The dispersion dried to a viscous, very sticky film.
Polymer Composition 1.6% acrylic acid 2.6% acrylamide 17.0% ethylene 31.5% vinyl acetate 47.3% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on a 100 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 5.8 N/2.5 cm Peel strength after 8 min. 6 N/2.5 cm Peel strength after 24 hrs. 17 N/2.5 cm Shear strength was 420 minutes.
COMPARISON EXAMPLE A
The process was carried out as in Example 1, but no acrylamide was added. A stable pl~astics dispersion having a solids content of 55% by weight was obtained. The soft film formed on drying was very sticky. The K-value of the polymer was 91. The glass transition temperature was -45C.
Polymer Composition 1.6% acrylic acid 18.0~ ethylene 32.2% vinyl acetate 48.2% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on a lC0 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 7.4 N 2.5 cm Peel strength after 8 min. 8N/2.5 Peel strength after 24 hrs. 15 N/2.5 Shear strength was only 80 minutes.
1~1895 The process was carried out as in Example 3, but gm of acrylamide were present before the start of the polymerization. 10 gm of allyl methacrylate were dissolved in the 2,000 gm of 2-ethylhexyl acrylate and metered in therewith. A stable dispersion was obtained. The glass transition temperature was -40C. The dispersion dried to a viscous sticky film.
Polymer Composition 1.5% acrylic acid 0.5% acrylamide 17.0% ethylene 30.7% vinyl acetate 46.0~ 2-ethylhexyl acrylate 0.15% allyl methacrylate.
In a reaction vessel as in Example l, lO0 gm of a sodium nonylphenol polyethylene glycol ether sulfate with lO mols of ethylene oxide, 150 gm of a tridecyl polyethylene glycol ether with 15 mols of ethylene oxide, and 20 gm of acrylamide were dissolved in 4,000 gm of water. After rins-ing with nitrogen, 2,500 gm of vinyl acetate and 600 gm of decyl acrylate were added, while stirring. After displacing the nitrogen with ethylene, the mixture was heated to 50C.
Ethylene was introduced under a pressure of 55 bar.
The polymerization was started by commencing simultaneous addition of a solution of 40 gm of ammonium persulfate in 400 gm of water and a solution of 20 gm of sodium formaldehyde sulfoxylate in 400 gm of water, the solutions being added over the course of four hours.
Fifteen minutes after the start of polymerization, the metering in of 1,900 gm of decyl acrylate and a second addi-tion of 180 gm of acrylamide in 300 gm of water were commenced, both additions being effected at a constant rate over a period of two hours. After 4.5 hours polymerization time, the reac-tion mixture was cooled, a~d the dispersion depressurized.
A stable dispersion which dried to a viscous sticky film was obtained. The glass transition temperature of the polymer was -53C, and the K-value was 85.
Polymer Composition:
The coating of 25 ~ dry thickness on a 100 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 3.9 N/2.5 cm;
Peel strength after 8 min. 7 N~2.5 cm, Peel strength after 24 hrs. 12 N/2.5 cm, Shear strength was 660 minutes, Wet strength 7 N/2.5 cm. (N = Newton) The process was carried out as in Example l, but instead of 165 gm of acrylamide, 180 gm of methacrylamide were added, and a monomer mixture of 3,000 gm of vinyl acetate and 2,000 gm of octyl acrylate was added. The ethylene pres-sure was set to 75 atmospheres and was held at this level for 4 hours after the start of polymerization. A stable disper-sion having a solids content of 60% was obtained. The K-value was 67. The glass transi~ion temperature was -48C. The dispersion forms a viscous, sticky film.
Polymer Composition 1.5~ acrylic acid 2.7% methacrylamide 22.0~ ethylene 44.3~ vinyl acetate 29.5% octyl acrylate.
The process was carried out as in Example 1, but a monomer mixture of 2,000 gm of vinyl acetate and l,000 gm of 2-ethylhexyl acrylate and 165 gm of acrylamide was present before the start of polymerization. Fifteen minutes after the start of polymerization, a further 2,000 gm of 2-ethyl-hexyl acrylate were added at a constant rate over the course of 2.5 hours. The dispersion was stable and had a solids content of 54%. The K-value was 85. The glass transition temperature was -41C. The dispersion dried to a viscous, very sticky film.
Polymer Composition 1.6% acrylic acid 2.6% acrylamide 17.0% ethylene 31.5% vinyl acetate 47.3% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on a 100 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 5.8 N/2.5 cm Peel strength after 8 min. 6 N/2.5 cm Peel strength after 24 hrs. 17 N/2.5 cm Shear strength was 420 minutes.
COMPARISON EXAMPLE A
The process was carried out as in Example 1, but no acrylamide was added. A stable pl~astics dispersion having a solids content of 55% by weight was obtained. The soft film formed on drying was very sticky. The K-value of the polymer was 91. The glass transition temperature was -45C.
Polymer Composition 1.6% acrylic acid 18.0~ ethylene 32.2% vinyl acetate 48.2% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on a lC0 ~ thick PVC sheet produced, when affixed to V4A-steel, the following test values:
Tack 7.4 N 2.5 cm Peel strength after 8 min. 8N/2.5 Peel strength after 24 hrs. 15 N/2.5 Shear strength was only 80 minutes.
1~1895 The process was carried out as in Example 3, but gm of acrylamide were present before the start of the polymerization. 10 gm of allyl methacrylate were dissolved in the 2,000 gm of 2-ethylhexyl acrylate and metered in therewith. A stable dispersion was obtained. The glass transition temperature was -40C. The dispersion dried to a viscous sticky film.
Polymer Composition 1.5% acrylic acid 0.5% acrylamide 17.0% ethylene 30.7% vinyl acetate 46.0~ 2-ethylhexyl acrylate 0.15% allyl methacrylate.
In a reaction vessel as in Example l, lO0 gm of a sodium nonylphenol polyethylene glycol ether sulfate with lO mols of ethylene oxide, 150 gm of a tridecyl polyethylene glycol ether with 15 mols of ethylene oxide, and 20 gm of acrylamide were dissolved in 4,000 gm of water. After rins-ing with nitrogen, 2,500 gm of vinyl acetate and 600 gm of decyl acrylate were added, while stirring. After displacing the nitrogen with ethylene, the mixture was heated to 50C.
Ethylene was introduced under a pressure of 55 bar.
The polymerization was started by commencing simultaneous addition of a solution of 40 gm of ammonium persulfate in 400 gm of water and a solution of 20 gm of sodium formaldehyde sulfoxylate in 400 gm of water, the solutions being added over the course of four hours.
Fifteen minutes after the start of polymerization, the metering in of 1,900 gm of decyl acrylate and a second addi-tion of 180 gm of acrylamide in 300 gm of water were commenced, both additions being effected at a constant rate over a period of two hours. After 4.5 hours polymerization time, the reac-tion mixture was cooled, a~d the dispersion depressurized.
A stable dispersion which dried to a viscous sticky film was obtained. The glass transition temperature of the polymer was -53C, and the K-value was 85.
Polymer Composition:
3.3% acrylamide 13.5% ethylene 41.6~ vinyl acetate 41.0% decyl acrylate.
In a reactor as described in Example 1, 3,600 gm of water, 5 gm of a sulfosuccinic acid monoester with an alkyl-(C12)-polyethylene glycol ether with 6 EO, disodium salt, 6 gm of sodium vinylsulfonate and 100 mg of iron ammonium sulfate were dissolved, and atmospheric oxygen was removed therefrom by purging with nitrogen. Then 600 gm of a monomer mixture consisting of 2,400 gm of vinyl acetate and 3,600 gm of 2-ethylhexyl acrylate were added while stir-ring. The nitrogen was displaced with ethylene and an ethylene pressure of 50 bar was applied. By pumping in 50 cm3 of a solution of 40 gm of ammonium persulfate in 500 gm of water~ana50 cm3 of a solution of 20 gm of sodium formal-dehyde sulfoxylate in 500 gm of water, the polymerization was started.
After the start, the two metered additions were continued at the rate of 50 cm3/hr. Twenty minutes after the start of polymerization, the remaining monomer mixture was added at a rate of 800 cm3/hr. In addition a metered addition (C) consisting of 240 gm of acrylamide, 120 gm of a palyvinyl alcohol having a viscosity of 5 mPa.s (4%) and a degree of hydrolysis of 100, 70 gm of a sodium lauryl poly-ethylene glycol ether sulfate (with 3 mols of EO), and 10 cm3 of ammonia (30%) in 1,000 cm3 of water was effected at a rate of 200 cm3/hr. After the metered addition of the monomer and the metered addition (C) have ended, the remaining amount of redox catalyst was allowed to flow in within one hour.
Thirty minutes after this, the mixture was cooled and the dispersion was depressurized after the pH had been set to 7 with ammonia. A stable dispersion, which dried to a sticky film, was obtained. The glass transition temperature was -41C.
Polymer Composition:
3.2% acrylamide 18.0% ethylene 31.5~ vinyl acetate 47.3% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on various sheets affixed to V4A-steel ~ave the values listed in Table 1.
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t~ `~3 U~ `~ U~ ~ >,~
c~ ~ o ~ o 0~ :~ 0~ 0 O -, ~ U ~ ~ O ~ o . ~.
~141895 In a reactor as described in Example 1, 250 gm of nonylphenol polyethylene glycol ether with 23 mols of ethyl-ene oxide, 30 gm of sodium dodecylbenzenesulfonate, 100 gm of methacrylic acid, 100 gm of acrylamide and 120 gm of N-vinyl pyrrolidone were dissolved in 4,000 gm of water. After purging with nitrogen, 2,000 gm of vinyl acetate and 600 gm of 2-ethylhexyl acrylate were added. After displaa~ing the nitrogen ~Qith ethylene, the mixture was heated to 60C, and ethylene was applied at a pressure of 60 bar until saturation equilibrium was attained.
By simultaneous metering in of a solution of 30 gm of am~[lonium persulfate in 500 ml of water and a solution of 15 gm of sodium formaldehyde sulfoxylate in 500 ml of water at a rate of 150 ml/h, the polymerization was started.
Fifteen minutes after the polymerization had started, a fur-ther 2,400 gm of 2-ethylhexyl acrylate were uniformly metered in over the course of 2.5 hours. The temperature of 60C was maintained for 1.5 hours; then the mixture was depressurized and introduced into a 30-liter stirring vessel and the re-maining ethylene was removed by the application of a slight reduced pressure, while stirring. A stal:)le plastics disper-sion having a viscosity of 300 mPa.s and a solids content of 58% was obtained. The ethylene content of the polymer was 20g6 by weight, and the K-value was 92. The glass transi-tion temperature was -46C. The dispersion dried to an extremely sticky film having good cohesion.
11~1895 Polymer Composition:
45.0% 2-ethylhexyl acrylate 30.0% vinyl acetate 20.0% ethylene 1.5% acrylamide 1.5% methacrylic acid 1.9% N-vinyl pyrrolidone.
A coating of a film of 25 ~ dry thickness on a 100 thick PVC sheet affixed to V4A-steel gave the following 0 test values:
Tack 7.0 N/2.5 cm Peel strength after 8 min. 4 N/2.5 cm Peel strength after 24 hrs. 9.5 N/2.5 cm Shear strength was 800 minutes, Wet strength 7.5 N/2.5 cm.
The preceding specific embodiments are illustrative of the practice of the invention. It is to be understood, however, that other expedients known to those skilled in the art or disclosed herein, may be employed without departing from the spirit of the invention or the scope of the appended claims.
In a reactor as described in Example 1, 3,600 gm of water, 5 gm of a sulfosuccinic acid monoester with an alkyl-(C12)-polyethylene glycol ether with 6 EO, disodium salt, 6 gm of sodium vinylsulfonate and 100 mg of iron ammonium sulfate were dissolved, and atmospheric oxygen was removed therefrom by purging with nitrogen. Then 600 gm of a monomer mixture consisting of 2,400 gm of vinyl acetate and 3,600 gm of 2-ethylhexyl acrylate were added while stir-ring. The nitrogen was displaced with ethylene and an ethylene pressure of 50 bar was applied. By pumping in 50 cm3 of a solution of 40 gm of ammonium persulfate in 500 gm of water~ana50 cm3 of a solution of 20 gm of sodium formal-dehyde sulfoxylate in 500 gm of water, the polymerization was started.
After the start, the two metered additions were continued at the rate of 50 cm3/hr. Twenty minutes after the start of polymerization, the remaining monomer mixture was added at a rate of 800 cm3/hr. In addition a metered addition (C) consisting of 240 gm of acrylamide, 120 gm of a palyvinyl alcohol having a viscosity of 5 mPa.s (4%) and a degree of hydrolysis of 100, 70 gm of a sodium lauryl poly-ethylene glycol ether sulfate (with 3 mols of EO), and 10 cm3 of ammonia (30%) in 1,000 cm3 of water was effected at a rate of 200 cm3/hr. After the metered addition of the monomer and the metered addition (C) have ended, the remaining amount of redox catalyst was allowed to flow in within one hour.
Thirty minutes after this, the mixture was cooled and the dispersion was depressurized after the pH had been set to 7 with ammonia. A stable dispersion, which dried to a sticky film, was obtained. The glass transition temperature was -41C.
Polymer Composition:
3.2% acrylamide 18.0% ethylene 31.5~ vinyl acetate 47.3% 2-ethylhexyl acrylate.
A coating of 25 ~ dry thickness on various sheets affixed to V4A-steel ~ave the values listed in Table 1.
s ,~ ~ o o o o o~ ~ ~o o o o ~ .,, ~ ~ ~ ,, a --. A A A A
U~
V
~,O
00 CO ~ 0 ~ Z
U~ .C
_l ~1 ~
0~ 5 li3 ~ ~ 0 ~ O ~
~ ~$ a) o U:
.~c ~ ~ ~ ~
G 0U~ IJ~
X~ ~
r~ O ' aJ ~ o ~ o u a~
U~ S: N ~ N h a~
.,1 ~ U ~ U ~ ~ O
S~ o-,l ~l o-~ l ~ h E~
s~
t~ `~3 U~ `~ U~ ~ >,~
c~ ~ o ~ o 0~ :~ 0~ 0 O -, ~ U ~ ~ O ~ o . ~.
~141895 In a reactor as described in Example 1, 250 gm of nonylphenol polyethylene glycol ether with 23 mols of ethyl-ene oxide, 30 gm of sodium dodecylbenzenesulfonate, 100 gm of methacrylic acid, 100 gm of acrylamide and 120 gm of N-vinyl pyrrolidone were dissolved in 4,000 gm of water. After purging with nitrogen, 2,000 gm of vinyl acetate and 600 gm of 2-ethylhexyl acrylate were added. After displaa~ing the nitrogen ~Qith ethylene, the mixture was heated to 60C, and ethylene was applied at a pressure of 60 bar until saturation equilibrium was attained.
By simultaneous metering in of a solution of 30 gm of am~[lonium persulfate in 500 ml of water and a solution of 15 gm of sodium formaldehyde sulfoxylate in 500 ml of water at a rate of 150 ml/h, the polymerization was started.
Fifteen minutes after the polymerization had started, a fur-ther 2,400 gm of 2-ethylhexyl acrylate were uniformly metered in over the course of 2.5 hours. The temperature of 60C was maintained for 1.5 hours; then the mixture was depressurized and introduced into a 30-liter stirring vessel and the re-maining ethylene was removed by the application of a slight reduced pressure, while stirring. A stal:)le plastics disper-sion having a viscosity of 300 mPa.s and a solids content of 58% was obtained. The ethylene content of the polymer was 20g6 by weight, and the K-value was 92. The glass transi-tion temperature was -46C. The dispersion dried to an extremely sticky film having good cohesion.
11~1895 Polymer Composition:
45.0% 2-ethylhexyl acrylate 30.0% vinyl acetate 20.0% ethylene 1.5% acrylamide 1.5% methacrylic acid 1.9% N-vinyl pyrrolidone.
A coating of a film of 25 ~ dry thickness on a 100 thick PVC sheet affixed to V4A-steel gave the following 0 test values:
Tack 7.0 N/2.5 cm Peel strength after 8 min. 4 N/2.5 cm Peel strength after 24 hrs. 9.5 N/2.5 cm Shear strength was 800 minutes, Wet strength 7.5 N/2.5 cm.
The preceding specific embodiments are illustrative of the practice of the invention. It is to be understood, however, that other expedients known to those skilled in the art or disclosed herein, may be employed without departing from the spirit of the invention or the scope of the appended claims.
Claims (12)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A copolymerizate containing:
(a) from 10% to 30% by weight of ethylene monomeric units, (b) from 29% to 69% by weight of monomeric units of an acrylic acid ester of an alkanol having from 4 to 12 carbon atoms, (c) from 20% to 55% by weight of vinyl acetate monomeric units, (d) from 0.2% to 8% by weight of monomeric units having the formula:
wherein R' is a member selected from the group consisting of hydrogen and methyl, and R" is hydrogen, and (e) from 0 to 12% by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl acetate and alkyl acrylate and monomers as described in (d), said copolymerizate having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180.
(a) from 10% to 30% by weight of ethylene monomeric units, (b) from 29% to 69% by weight of monomeric units of an acrylic acid ester of an alkanol having from 4 to 12 carbon atoms, (c) from 20% to 55% by weight of vinyl acetate monomeric units, (d) from 0.2% to 8% by weight of monomeric units having the formula:
wherein R' is a member selected from the group consisting of hydrogen and methyl, and R" is hydrogen, and (e) from 0 to 12% by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl acetate and alkyl acrylate and monomers as described in (d), said copolymerizate having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180.
2. The copolymerizate of claim 1 wherein component (a) is present in an amount of from 12% to 25% by weight, component (b) is present in an amount of from 29% to 60% by weight, component (c) is present in an amount of from 25% to 50% by weight and component (d) is present in an amount of from 0.2% to 3% by weight.
3. The copolymerizate of claim 1 wherein said component (e) is present in an amount of from 0.5% to 8%. by weight.
4. The copolymerizate of claim 3 wherein said component (e) are monomeric units of monomers miscible in water in any ratio.
5. A pressure-sensitive adhesive containing an adhesive amount of the copolymerizate of claim 1, 2 or 3.
6. An aqueous pressure-sensitive adhesive dispersion having a content of:
from 40% to 65% by weight, based on the dispersion of the copolymerizate of claim 1, 2 or 3 in a dispersed state, from 1.5% to 8% by weight, based on the copolymerizate, of dispersants selected from the group consisting of emulsifiers, protective colloids, and mixtures thereof, and from 34% to 59% by weight, based on the dispersion, of water.
from 40% to 65% by weight, based on the dispersion of the copolymerizate of claim 1, 2 or 3 in a dispersed state, from 1.5% to 8% by weight, based on the copolymerizate, of dispersants selected from the group consisting of emulsifiers, protective colloids, and mixtures thereof, and from 34% to 59% by weight, based on the dispersion, of water.
7. A process for the production of the copolymerizate of claim 1 consisting of polymerizing components (b), (c), (d) and (e) in amounts sufficient to give the desired ratio of monomer units in the final copolymerizate, by free-radical initiation under ethylene pressure of from 20 to 120 bar at a temperature of from 10°C to 90°C for a time sufficient to complete the polymerization, and recovering said copolymerizate.
8. A process for the production of a copolymerizate containing:
(a) from 10% to 30% by weight of ethylene monomeric units, (b) from 29% to 69% by weight of monomeric units of an acrylic acid ester of an alkanol having from 4 to 12 carbon atoms, (c) from 20% to 55% by weight of vinyl acetate monomeric units, (d) from 0.2% to 8% by weight of monomeric units having the formula:
wherein R' is a member selected from the group consisting of hydrogen and methyl, and R" is hydrogen, and (e) from 0 to 12% by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl acetate and alkyl acrylate and monomers as described in (d), said copolymerizate having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180, consisting of dispersing the monomeric units of components (b), (c), (d) and (e) in amounts sufficient to give the desired ratio of monomer units in the final copolymerizate in water in the presence of from 1.5% to 8% by weight, based on the monomers, of dispersants selected from the group consisting of emulsifiers, protective colloids, and mixtures thereof, polymerizing said dispersion in the presence of free-radical initiators under an ethylene pressure of from 20 to 120 bar and at at a temperature of from 10°C to 90°C for a time sufficient to complete the polymerization and recovering said copolymerizate.
(a) from 10% to 30% by weight of ethylene monomeric units, (b) from 29% to 69% by weight of monomeric units of an acrylic acid ester of an alkanol having from 4 to 12 carbon atoms, (c) from 20% to 55% by weight of vinyl acetate monomeric units, (d) from 0.2% to 8% by weight of monomeric units having the formula:
wherein R' is a member selected from the group consisting of hydrogen and methyl, and R" is hydrogen, and (e) from 0 to 12% by weight of other olefinically-unsaturated monomeric units copolymerizable with ethylene, vinyl acetate and alkyl acrylate and monomers as described in (d), said copolymerizate having a glass transition temperature of from -20°C to -60°C and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180, consisting of dispersing the monomeric units of components (b), (c), (d) and (e) in amounts sufficient to give the desired ratio of monomer units in the final copolymerizate in water in the presence of from 1.5% to 8% by weight, based on the monomers, of dispersants selected from the group consisting of emulsifiers, protective colloids, and mixtures thereof, polymerizing said dispersion in the presence of free-radical initiators under an ethylene pressure of from 20 to 120 bar and at at a temperature of from 10°C to 90°C for a time sufficient to complete the polymerization and recovering said copolymerizate.
9. The process of claim 8 wherein the entire amount of component (d) is present prior to the commencement of polymerization.
10. The process of claim 9 wherein a part of components (b), (c) and (e) are charged after commencement of the polymerization in metered amounts.
11. The process of claim 8 wherein said copolymerizate is recovered as a dry film on a carrier.
12. The copolymerizate produced by the process of claim 9.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792915887 DE2915887A1 (en) | 1979-04-19 | 1979-04-19 | COPOLYMERISATE BASED ON ACRYL ESTERS, VINYL ACETATE AND AETHYLENE |
| DEP2915887.0 | 1979-04-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1141895A true CA1141895A (en) | 1983-02-22 |
Family
ID=6068747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000348092A Expired CA1141895A (en) | 1979-04-19 | 1980-03-21 | Copolymers for pressure-sensitive adhesives based on acrylic esters, vinyl acetate and ethylene |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4322516A (en) |
| EP (1) | EP0017986B1 (en) |
| JP (1) | JPS5910752B2 (en) |
| CA (1) | CA1141895A (en) |
| DE (2) | DE2915887A1 (en) |
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| CN105542062B (en) * | 2016-02-01 | 2018-06-15 | 苏州哈恩新材料有限公司 | A kind of novel acrylic ester glue and preparation method thereof |
| WO2018141489A1 (en) | 2017-01-31 | 2018-08-09 | Basf Se | One-component pressure-sensitive adhesive composition having gel content based on reversible crosslinking via metal salts |
| US20190249043A1 (en) | 2018-02-13 | 2019-08-15 | Celanese International Corporation | Adhesive compositions |
| DE102019103121A1 (en) | 2019-02-08 | 2020-08-13 | Tesa Se | Shrink film and method for sheathing elongated material, in particular lines |
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| DE102019103124B4 (en) | 2019-02-08 | 2022-02-03 | Tesa Se | Thermally hardenable adhesive tape, used for wrapping elongate goods, in particular cables and cable harnesses |
| DE102021210731A1 (en) | 2021-06-04 | 2022-12-08 | Tesa Se | Adhesive tape and method for wrapping elongate goods, in particular cables |
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Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3189581A (en) * | 1961-06-05 | 1965-06-15 | Pittsburgh Plate Glass Co | Pressure sensitive adhesives comprising interpolymers of alkylacrylates, vinyl esters and n-alkoxyalkyl acrylamides |
| US3380851A (en) * | 1965-03-31 | 1968-04-30 | Air Reduction | Nonwoven fabric with vinyl acetateethylene-n-methylol acrylamide interpolymer as binder |
| US3451982A (en) * | 1965-08-04 | 1969-06-24 | Monsanto Co | Terpolymers of ethylene,a vinyl ester and an unsaturated amide |
| BE787415A (en) * | 1971-08-13 | 1973-02-12 | Wacker Chemie Gmbh | ADHESIVE DISPERSIONS |
| DE2202189C3 (en) * | 1972-01-18 | 1982-01-21 | Hoechst Ag, 6000 Frankfurt | Process for the preparation of emulsifier-free polymer dispersions |
| US4032692A (en) * | 1974-01-10 | 1977-06-28 | Ruhrchemie Aktiengesellschaft | Process for adhesive bonding and coating |
| DE2400978B2 (en) * | 1974-01-10 | 1977-01-13 | Ruhrchemie Ag, 4200 Oberhausen | USE OF A MIXED OLEFINE POLYMERIZATE FOR BONDING OR COATING MATERIALS |
| US4044197A (en) * | 1975-03-21 | 1977-08-23 | Wacker-Chemie Gmbh | Thermally self-cross-linkable ethylene/vinyl acetate copolymers |
| DE2541934A1 (en) * | 1975-09-19 | 1977-03-24 | Wacker Chemie Gmbh | SOAP RESISTANT COPOLYMER DISPERSIONS |
| DE2623006B2 (en) * | 1976-05-22 | 1978-04-13 | Ruhrchemie Ag, 4200 Oberhausen | Use of copolymers of ethylene as hot melt adhesives |
-
1979
- 1979-04-19 DE DE19792915887 patent/DE2915887A1/en not_active Withdrawn
- 1979-12-10 JP JP54159310A patent/JPS5910752B2/en not_active Expired
-
1980
- 1980-03-19 US US06/131,785 patent/US4322516A/en not_active Expired - Lifetime
- 1980-03-21 CA CA000348092A patent/CA1141895A/en not_active Expired
- 1980-04-17 DE DE8080102059T patent/DE3061315D1/en not_active Expired
- 1980-04-17 EP EP80102059A patent/EP0017986B1/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6251213B1 (en) | 1992-10-01 | 2001-06-26 | Rohm And Haas Company | Laminating construction adhesive compositions with improved performance |
| US6087425A (en) * | 1994-02-18 | 2000-07-11 | Rohm And Haas Company | Laminating adhesive composition |
| US6180242B1 (en) | 1994-02-18 | 2001-01-30 | Rohm And Haas Company | Laminating adhesive composition |
| US6203916B1 (en) | 1994-02-18 | 2001-03-20 | Rohm And Haas Company | Method for making a laminated article |
| US5652293A (en) * | 1994-05-09 | 1997-07-29 | Rohm And Haas Company | Method for making an aqueous emulsion polymer |
| US5652289A (en) * | 1994-07-29 | 1997-07-29 | Rohm And Haas Company | Method for making an aqueous emulsion polymer |
| US6120638A (en) * | 1996-01-25 | 2000-09-19 | Rohm And Haas Company | Dispersible, high speed book casing-in vinyl ester/(meth)acrylate adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| US4322516A (en) | 1982-03-30 |
| JPS55142013A (en) | 1980-11-06 |
| DE2915887A1 (en) | 1980-11-06 |
| DE3061315D1 (en) | 1983-01-20 |
| JPS5910752B2 (en) | 1984-03-10 |
| EP0017986B1 (en) | 1982-12-15 |
| EP0017986A1 (en) | 1980-10-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |