CA1154628A - Crystallized, readily water-dispersible sugar product - Google Patents
Crystallized, readily water-dispersible sugar productInfo
- Publication number
- CA1154628A CA1154628A CA000386880A CA386880A CA1154628A CA 1154628 A CA1154628 A CA 1154628A CA 000386880 A CA000386880 A CA 000386880A CA 386880 A CA386880 A CA 386880A CA 1154628 A CA1154628 A CA 1154628A
- Authority
- CA
- Canada
- Prior art keywords
- product
- sugar
- crystallized
- instant
- sugar product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/56—Cocoa products, e.g. chocolate; Substitutes therefor making liquid products, e.g. for making chocolate milk drinks and the products for their preparation, pastes for spreading, milk crumb
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D10/00—Batters, dough or mixtures before baking
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F5/00—Coffee; Coffee substitutes; Preparations thereof
- A23F5/24—Extraction of coffee; Coffee extracts; Making instant coffee
- A23F5/36—Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee
- A23F5/40—Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee using organic additives, e.g. milk, sugar
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/346—Finished or semi-finished products in the form of powders, paste or liquids
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/52—Liquid products; Solid products in the form of powders, flakes or granules for making liquid products ; Finished or semi-finished solid products, frozen granules
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/231—Pectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/10—Puddings; Dry powder puddings
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B50/00—Sugar products, e.g. powdered, lump or liquid sugar; Working-up of sugar
- C13B50/002—Addition of chemicals or other foodstuffs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate
Abstract
Abstract of the Disclosure A crystallized sugar product containing a food ingre-dient is prepared by concentrating a sugar syrup at a temperature in the range of about 250°F. to about 300°F. to a solids content of about 90 to 98% by weight, the sugar syrup containing no more than about 20% by weight non-sucrose solids, admixing the concen-trated sugar syrup with a predetermined amount of the food ingredient, subjecting the admixture to impact beating within a crystallization zone until a cry-stallized sugar product made up of aggregates of fondant-size sucrose crystals and the food ingredient is formed, the crystallized sugar product having a moisture content of less than 2.5% by weight, and re-covering the crystallized sugar product from the crystallization zone. The resulting sugar product is dry, granular, free-flowing, non-caking, and readily dispersible in water. The resulting sugar product may be either an intermediate food product, such as a gelatin concentrate, or an instant food product, such as an instant chocolate pudding mix, which con-tains all of the dry food ingredients for the final food product.
Description
2~
Back~round of the Invent on This invention relates to a granular, ~reP-flowing, non-caking sugar incorporated product. More speci-fically, this invention relates to a crystallized and readily water-dispersible sugar incorporated product and to a method for producing the sugar incorporated product.
Many food ingredients are sold by the food industry in powder or granular form. For example, gums, gelatin, emulsifiers, starches, cocoa and flavorants, which are used as thickening, stabilizing, gelling, coloring and flavoring agents in food products, are sold in powder form.
Food ingredients which are used in powdered form are not totally satisfactory. Because of their high affinity for water, these powdered ~ood ingredients are not readily dispersed in water. The granules tend to clump together and float on the surface when they are mixed with liquids. In general, vigorous agitation while heating is needed to dissolve or disperse pow-dered food ingredients in liquids.
Other problems also exist with powdered food ingredi-ents. Powdered food ingredients have a tendency to cake upon standing and an additive is needed to pre-vent this. Powdered food ingredients are mechanically blended. It is difficult to obtain a uniform blend
Back~round of the Invent on This invention relates to a granular, ~reP-flowing, non-caking sugar incorporated product. More speci-fically, this invention relates to a crystallized and readily water-dispersible sugar incorporated product and to a method for producing the sugar incorporated product.
Many food ingredients are sold by the food industry in powder or granular form. For example, gums, gelatin, emulsifiers, starches, cocoa and flavorants, which are used as thickening, stabilizing, gelling, coloring and flavoring agents in food products, are sold in powder form.
Food ingredients which are used in powdered form are not totally satisfactory. Because of their high affinity for water, these powdered ~ood ingredients are not readily dispersed in water. The granules tend to clump together and float on the surface when they are mixed with liquids. In general, vigorous agitation while heating is needed to dissolve or disperse pow-dered food ingredients in liquids.
Other problems also exist with powdered food ingredi-ents. Powdered food ingredients have a tendency to cake upon standing and an additive is needed to pre-vent this. Powdered food ingredients are mechanically blended. It is difficult to obtain a uniform blend
3~ 6~
of the powdered ood ingredients because they sepa-rate or settle out upon standingO Consequently, in order to use the correct proportions or ingredi-ents in a package, the consumer must use the entire package rather than just a part of the package.
Another problem is that a percentage of the blend components is lost as dust during mechanical blending.
"Instant" food products, that is, powdered food pro-ducts which contain all of the food ingredients in a single package, encounter the same problems of difficulty of dispersion, tendency to cake, tendency to settle out, and dust losses.
It would be desirable to produce powdered food ingre-dients which avoid these problems.
It would also be desirable to produce instant food products which avoid these problems.
In the manufacture of sugar products, a process known as the transforming process is used to convert a sugar syrup into a dry sugar product. The sugar product is granular, free-flowing, non-caking, and is readily dispersed or dissolved in water. The transforming process has been described in U.S.
Patents Nos. 3,149,682 (Tippens et al.), 3,365,331 (Miller et al.), 4,159,210 ~Chen et al.), and our co Canadian patent pending, co-assigned/application entitled "Cry-stallized, Readily Water-Dispersible Sugar Product Containing Heat Sensitive, Acidic or High Invert Sugar Substances."* In Tippens et al., the method comprises concentrating a sugar syrup to a *filed 28 September, 1981 ~5~6~ :
solids content of about 95-97% by heating the sugar syrup to a temperature of about 250-265F., and subjecting the xesulting supersaturated sugar syrup to a heat dissipation operation simultaneously with vigorous agitation. The ~ethod produces a dry sugar product comprising aggregates of fondant-~ -size (3-50 micxons) sucrose crystals. ~iller et al.
10describes a similar process in whi~h impact beating -~
is used to crystallize the sugar product from the supersaturated sugar syru~.
The feed syrup which is erilployed in the processes of Tippens et al. and Miller et al. has a purity in the range of 85-97~ by weight sucrose. Thus, the feed syrup may not contain more than about 15% by weight non-sucrose solids.
Both Tippens et al. and ~liller et al. disclose that sugar products prepared in accordance with their invention are useful as carriers for additive mate-rials which may have a food value or a taste value or a color value or medicinal value or the like.
24 The food additive may be added at any step in the process, such as during concentration, crystalliza-tion, co~minution, screening, or by a separate blending and mixing operation with the sugar product, depending on the nature of the additive material.
Theoretically, it is possible to adapt the sugar transforming process so that a food ingredient is crystallized with the sucrose crystals from a sugar syrup containing the food ingredient. The resulting product would be granular, homogeneous, dry, free-flowing and non-caking. In addition, because the structure o the product would be porous clusters of micro-sized sucrose crystals intimately associated with the food ingredient, the food ingredient would be readily dispersible or dissolvable in liquid.
Accordingly it is an object of this invention to provide a product which incorporates a food ingredi-ent into a crystalline sugar matrix.
It is also an object of this invention to provide thi5 sugar product in dry, granular, free-flowing, non-caking form.
It is also an object o~ this invention to provide this sugar product in a form in which the food ingredient is readily dispersed or dissolvecl in liquid.
It is also an object of this invention to provide a sugar product which contains all of the dry food ingredients needed to make a final food product.
It is also an object of this invention to provide a method for preparing this sugar product.
These and other objects are accomplished by means of the present invention described below.
Summary of the Invention By means of the present invention, a crys~allized sugar product is prepared which incorporates a food ingredient into a sugar matrix. The product is homo geneous, dry, granular, free-flowing, and non-caking.
The product is composed of agglomerates or aggregates of minute, fondant-size sucrose crystals intimately associated with the food ingredient. Due to its porous structure, the crystalli2ed sugar product is readily dispersed or dissvlved in water.
15 The crystallized sugar product of the present inven- -tion is prepared by concentrating a sugar syrup at a tempexature in the range of about 250F. to about 300F. to a solids content of about 90 to ~8% by weight, said sugar syrup containing no more than about 20~ by weight non-sucrose solids; admixing the concentrated sugar syrup with the food ingredient; ~-subjecting the mixture to impact beating within a crystallization zone until a crystallized sugar pro-duct made up of aggregates of fondant-size sucrose crystals and the food ingredient is formed, the crystallized sugar product having a moisture content of less than-2.5% by weight; and recovering the crystallized sugar product from the crystallization zone. I desired, the resulting crystallized sugar produc~ may be dried to a moisture content of less than 1% by weight, followed by screening to a uniform size and packaging.
6~2~
' Detailed De-sc-ription of the Invention The accompanying drawing is a flow chart illustrat-ing a preferred process or scheme for preparing a crystallized sugar product in accordance with the present invention.
Referring to the flow chart, a feed sugar syrup 10 is concentrated by evaporation 12 to a supersatu-rated sugar syrup 14 having a solids content of about 90 to 98%. Concentration of the feed syrup is performed at an elevated temperature in the range of about 250-300F., and may be performed at atmospheric pressure or under vacuum. The feed syrup may be concentrated in a vacuum pan evapora-tor, in a rising and falling concentrator, or in a heat exchange evaporator under suitable conditions.
Thè solids content of the feed syrup should be at least 80% sucrose. Non-sucrose solids in the feed syrup may comprise additional mono- or disaccahrides or modified dextrins, for example, dextrose, invert sugar, fructose, corn syrup solids, or mixtures thereof.
The resulting supersaturated sugar syrup 14 having a solids content of about 90-98% is maintained at a temperature not less than about 240F. in order to prevent premature crystallization. A predetermined weight of the food ingredient 16, such as a gelatin, emulsifier, gum, starch, cocoa powder, etc., is added to the concentrated syrup with vigorous mechanical agitation, such as by Lmpact beat ng, within a crystallization zone. Alternatively, the concen-trated sugar syrup may be added to a predeterminedamount of the food ingredient and mixed in a similar manner. The device used for mechanical agitation could be a beater-crystallizer, a Turbulizer, a nucleator - crystallizer, a high speed or shear mixer, ox a blender.
Impact beating is continued within the crystallization zone until the supersaturated syrup/food ingredient mixture is transformed, crystallized 20, and aggolomer-ated 22. A crystalline sugar incorpoxated product 24is recovered from the crystallization zone. The latent heat of crystallization is sufficient to evaporate the moisture so that the product is substantially dry, i.e., has a moisture content of less than about 2.5% by weight.
If desired, the crystallized sugax product 24 may be further dried to a moisture content of less than 1%, followed by screening, milling, and packaging 26.
During crystallization, it is desirable to remove the heat of crystallization to prevent overheating within the crystallization zone. The heat of crystallization can be removed or dissipated by indirect heat exchange, e.g., by surro~mding the crystallization zone with a water jacket, or, preferably, by forced air flow through the beater-crystallizer, e.g., with a vapor separator.
Suitable app~ratus -for carrying out the process of the present invention in a continuous operation is described in U.S. Patent No. 3,365,331 (Miller et al.).
~ 8-In order to ensure maximum homogeneity in the final product, it is desirable to introduce the food ingre-dient into the concentrated syrup as early in theprocess as practical. However, in most cases, the food - ingredient is introduced during the sugar crystalliza-tion step. The food ingredient becomes thoroughly mixed in the earlier stages of the cry~stallization step as the concentrated syrup is transformed from the liquid state to a semi-solid state. Consequently, when the syrup reaches the relatively dry agglomerated state, the resulting product is a homogeneous blend of the co-crystallized sugar and the food ingredient.
The physical structure of the crystallized sugar pro-duct is highly dependent on the rate and temperature of impact beating and crystallization, and on the degree of sugar transformation. l`he optimum time for the concentrated syrup mixture to spend in the crystallization zone during impact: beating depends on several factors, including: (a) the nature of the non-sucrose solids (such as invert sugar and ash) in the feed syrup; (b) the nature and characteristics of the food ingredient (such as moisture content, invert sugar content, pH, etc.); (c) the concentration of the food ingredient in the mixture; and (d) the tempera-ture used for concentration of the food syrup.
In structure, the crystallized sugar products of the present invention are comprised of aggregates or agglomerates of fondant-size sucrose crystals, e.g., in the range of about 3-50 microns, intima~ely associ-ated with the non-sucrose solids. The agglomerates _9_ form a loose, lacey network bonded together at their interfaces by point contact. Accordingly, aqueous liquid can rapidly penetrate the porous cluster of agglomerates and free each of the particles making up the agglomerates. The particles thus become readily dispersed and/or dissolved in the aqueous liquid.
,;
In the crystallized sugar product of the present invention, the food ingredient is incorporated as an integral part of the sugar matrix and there is no tendency for the active ingredient to separate or settle out during handling, packaging, or storage.
The resulting product is granular, free-flowing, non-caking, and is readily dispersed or dissolved in water.
The structure and properties of the crystallized sugar products prepared in accordance with this invention are distinctly diferent from dry-blended sugar products and from sugar products prepared by the seed crystallization process of U.S. Pat.
3,248,226 or by the candy melt process of U.S. Pat.
3,341,334. For example, a gelatin/sugar product prepared in accordance with this invention is com-posed of clusters of micro~sized sucrose crystals coated with gelatin. This permits rapid dissolu-tion o the gelatin in cold water. In contxast, a gelatin/sugar product prepared by seed crystalliza-tion is composed of large, fluffy crystals which tend to clump and float on the surface when dispersed in a liquid. A gelatin/sugar pxoduct prepared by the candy melt process is composed of coarse, dense crystals which sink to the bottom of a liquid.
Typical profiles of emulsifier/sugar products, cocoa/
sugar products, and gelatin/sugax products prepared in accordance with this invention are presented in Tables I, II, and III, below.
~5 Table I
, ~
Mono- Mono- and glyceride Diglycerides Lecithin Product Product'Product _ _ .
Preparat'ion D'~ta ~levated Tempera-ture 255F. 265F. 260F.
10 Solids Content of . '.
S~persaturated Syrup 95.4% 96.5% 96.1% ' Crystallization Time 195 Secs. 125 Secs.165 Secs.
Finished Product Analvsis Sucrose Content 94.32~ 92.01% 89.61%
Invert Sugar 0.12% 0.10% 0.09%
Moisture Con-tent ' 0.2 % 0.3 % 0.2 %
Emulsifier 5 ~ 7.5 % 10 %
Screen Analysis (Tyler~
# 14 2.0 % 3~2 % 6.7 ~ -# 35 4.5 % 6.1 % 11.2 %
# 60 32.1 % 40.1 % 36.5 %
#100 34.2 % 24.3 % 34.4 %
#150 21.2 % 21.4 % lO.S %
#200 4.5 % 4.7 % 0.6 %
Pan 1.5 % 0.2 % 0.1 %
Table II
Cocoa Product Cocoa Product Preparation_Data Elevated Temperature 255F. 255F.
Solids Content of Super-saturated Syrup 95.0~ 95.0%
Crystallization Time Requixed 175 Seconds185 Seconds Finished Product ~Analysis . .
Sucrose Content 71.53~ 71.69 Invert Sugar 0.14% 0.16 Moisture Content 0.82% 0.65 Cocoa Powder 27.50% 27.50 S~reen Analysls (Tyler) #14 2.~ 1.6%
#35 3.2% 3.5%
#60 46.5% 40.6%
#100 31.8% 34.6%
#150 12.~ 15.9%
#200 3.2~ 1.4%
Pan 1.5% 2.4%
Table III
^Gelatin Product Gelatin_Product Pre~axation Data Elevated Temperature 260F. 265F.
Solids Content of Supersaturated Syrup 95.0% 96.5%
Crystallization Time 170 Seconds 185 Seconds Finished Product Analysis Sucrose Content88.53% 78.31% - ' Invert Sugar 0.14% 0.16%
Moistur2 Content1.05~ 1.45%
Gelatin Powder 10% 20%
pH 4.98 4.90 Color (10% Solution) 69 ASC Units 73 ASC Units Scxeen Analysis (T~ler) # 14 2.~% 1.6%
# 35 3.2% 3.5%
# 60 46.5% 40.5~ :
~100 31.8% 34.6%
~150 12.4% 15.9%
~200 3.2% 1.4~
Pan 1.5% 2.4%
~-32 A wide variety of pxoducts may be prepared in accord-ance with the present invention. These products may be either intermediate food products or instant food pro-ducts. By instant food products, it is meant that the product contains all of the dry food ingredien~s needed to make the final food. In contrast, intermediate food products, such as concentrates, must be blended with other food ingredients to make the food. In the pr~pa-ration of intermediate food products or consentrates, it is desirable that the amount of food ingredient contained in the sugar incorporated product be equal to or les5 than the total amount of sugar in the syrup, i.e.l the food ~ngredient should comprise about 0.05-50%
by weight of the crystallized sugar product.
The following examples illustrate various embodiments of this invention but are not meant: in any way to limit the scope thereof.
A dry, readily dispersible gelatin concentrate may be prepared in accordance with this invention. Desirably, the product contains about 0.5-30~ by weight gelatinO
Example 1 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95% solids content. An amount of gelatin equal to 10% by weight of the sugar was then added with controlled agitation (impact beating). Impact beating was continued until the mixture was converted into a substantially dry powder. As the crystallization of the sugar proceeded, . .
. . .
~ ~ 5 4 ~
the gelatin particles were incorpora*ed into the sugar matrix of fondant-size sucrose crystals. The heat of crystallization which accompanied the reaction aided in removing moisture to give a substantially dry powdered product.
Example 2 A gelatinJsugar product was prepared as in Example 1 except that, instead of adding the gelatin to the supersaturated sugar solution, the supersaturated sugar solution was added to the gelatin with impact beating.
Impact beating was continued and crystallization pro-ceeded~ eventually resulting in the formation of a dry powdered product.
Example 3 1300 grams of sucrose solution (65 Brix) was heated to 265F. to form a supersaturated syrup of approxi-mately 97~ solids. 200 grams of gelatin powder tthrough a Tyler #100 mesh screen) was added to the heated syrup with vigorous mechanical agitation using a Hobart mixer. Stirring was continued until the mixture was transformed and agglomerated into a ~ry powder. The finished product was screened through a Tyler #35 mesh screen.
Gelatin concentrates made in this manner were used in the formation of several food products containing gela-tin, such as, mashmallow mix, stabilized icing mix, and gelatin dessert mix. The product was readily 6;~,~
dispersed and dissolved in either hot or cold wat~r and formed a firm gelled or stabilized product.
In another embodiment of the present invention, ~arious stabilizers, such as pectin, carrageenan, guar gum, agar-agar, xanthan gum, or sodi~m alginate may be incorporated into a crystallized sugar product. De-sirably, the product comprises about 0.1-25~ by weight of the solution.
Example 4 A sugar incorporated pectin was prepared in accord-ance with the process described in Example 3. This pectin concentrate was then used in the formulation of several food products, such as jelly mix, syrup spread mix, and beverage drink mix. The finished products possessed an instantly dispersing and dis-solving nature when mixed with hot or cold watex without any detectable lumping. They provided a firm gelled texture or a stabilizing or thickening property similar to that of products prepared by con-ventional processes.
In another embodiment, various emulsifiers, such asmono- and diglycerides, propylene glycol esters, sor-bitan esters~ polyoxyethylene sorbitan estexs, lactylated estexs, or lecithins, may be incorporated into a crystalliæed sugar product. Desirably, the product comprises 0.1-25~ by weight of the stabilizer.
~5~
Example 5 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95 solids content. An amount of monoglycerol tMyverol 18-07, Kodak) equal to 5% by weight of the sugar was then added with controlled agitation (impact beating).
Impact beating was continued until the mixture was converted into a substantiall~ dry powder. As the crystallization of the sugar proceeded, the emulsifier was incorporated with the fondant-size sugar particles i~to a sugar matrix. The heat of crystallization which accompaniedthe reaction aided in removing moisture resulting in a substantially dry powdered product. The finished product was screened through a Tyler #35 mesh screen.
Example 6 An emulsifier/sugar product was prepared as in Example 5 except that the supersaturated sugar solution was added to the emulsifier with impact beating. Impact beating was continued and crystallization proceeded, eventually resulting in the formation of a dry powder similar to that of Example S.
Example 7 A sugar incorporated monoglyceride product was prepared according to the process described in Example 3. The product prepared in this manner was used in the formu~
lation of several food products, such as, cake mix and icing mix. The crystallized product, when added to cake mix or icing mix, provides excellent emulsion characteristics. For example, cake volume, porosity, and appearance, and icing stability and density were improved with the sugar incorporated emulsifier as compared with a conventional emulsifier.
In another embodiment, a cocoa or carob product may be prepared in accordance with the present inventionO
Desirably, the product comprises about 0.5-35% by weight cocoa or carob.
Example 8 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95% solids content. An amount of cocoa powder ~Hershey Challenge No. lO0) equal to 25~ by weight of the sugar solution was then added with controlled agitation. Stirring of the sugar solution and the cocoa powder resulted in the formation of a slurry and coating of the cocoa parti-cles with the syrupO Stirring was continued until the mixture was converted into a dry powder. As the crystallization of the sugar proceeded, the cocoa powder particles were incorporated with the crystal-lized sugar. The heat of crystallization which accompanied the reaction aided in removing moisture and gave a substantially dry powdered product.
Example 9 A cocoa/sugar product was prepared as in Example 8 except that the supersaturated sugar solution was ~.nl~
-19- , added to the cocoa powder with agitation to form a slurry, thereby coating the cocoa powder with the syrup. Agitation was continued and crystallization was continued, eventually resulting in the formation of a dry powdered product similar to that of Example 8~
Exa~ple 10 580 grams of granulated sugar and 200 grams of brown sugar were dissolved in water and the solution heated until a product was obtained which contained 96%
solids. 200 grams of cocoa powder supplied by Hershey was added to the supersaturated syrup with agitation.
Stirring was continued until the mixture was trans-formed into a dry powder. The finished product was then screenedthrough a Tyler #35 mesh screen. The sugar incorporated cocoa product ~was used in the formulation of several food products containing cocoa, such as chocolate milk drink and pudding. These products were readily dispersible in cold water without any evidence of lumping.
In another emobodiment, various modified starches, such as, waxy maize starch, tapioca starch, corn starch, or wheat starch, may be incorporated into a crystallized sugar product. Desirably, the product comprises about 0.5-35% by weight starch.
Example 11 , The modified starch (Stir-N-Set, National Starch)/sugar ~.nl, ~5~6~i~
:
~20~
product was prepared according to the process described in Example 10~ The sugar incorporated modified starch was used in the formulation of several instant food products containing starch, such as, pie filling, pastry filling, pudding, and spoonable salad dressings.
This product was readily dispersihle in cold water without mechanical agitation.
In another embodiment, various fibers, such as corn bran, soy hulls, beet pulps, or wood cellulosel may be incorporated into a crystallized sugar product.
The fibers may be acidic, enzymatic, or oxidized modi-fied such as alpha-cellulose, microcrystalline cellu-lose or other cellulosic fibers. Desirably, the product comprises about O.S-35~ by weight fiberO
Example 12 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated sugar solut:ion of approximately 95~ solids content. An amount of alpha-cellulose (Paniplus, Keycei BH 200) equal to 25% by weight of the sugar solution was then added with contr~lled agitation.
Stirring was continued until the moisture was con-verted into a dry powder. The incorporated product permits ready or instant dispersibility in liquid.
In another embodiment, various proteins, such as soy proteins, yeast proteins, milk proteins, wheat proteins, or egg proteins, are incorporated into a crystallized sugar product. The proteins may be acidic, enzymatic, or oxidized modified, such as, caseinates, lactalbumen, ~ f.
d ~3 wheat gluten, or soy albumen. Desirably, the product comprises about 0.5-35% by weight protein.
Example 13 95Q grams of granulated sugar and 50 grams of total invert sugar were dissolved in water and the solution 10 was heated until a product was obtained which con-tained 96% solids. 300 grams of soy protein concen-trates produced by Far-Mar, Inc. was added to the supersaturated sugar solution with agitation. Stirring was continued until the mixture was transformed into a 15 substantially dry product. As the crystallization of the sugar proceeded, the soy protein particles were incorporated into the crystallized sugar. The heat of crystallization, which developed during the exothermic ; reaction, aided in removing moisture, resulting in a 20 substantially dry particle.
In another embodiment, various sugar substitutes, such as saccharin and its salts, aspartame (aspartyl-phenyl-alanine-methyl-ester), glycyrrhizin and its derivatives, 25 cyclamate and its salts, miraculin (synsepalum dulsifi-cum), sorbitol, mannitol, or xylitol, are incorporated into a crystalline sugar matrix. Desirably, the prodct comprises up to 50% by weight sugar suhstitute.
Example_14 A sugar solution prepared from 92~ sucxose and 8%
aspartame (dry weight basis) was heated to 260F. to form a supersaturated syrup of approximately 93.5%
~5~
solids content. The heated syrup was subjected to mechanical agitation (impact beating). ~mpact beat-ing was continued until the mixture was transformedand agglomerated into a dry powder. As the transor-mation of the sugar proceeded, the synthetic sweetener cocrystallized with the fondant size sugar particles.
The heat of crystalliæation aided in removing moisture, resulting in a substantially "dry" product. The finished product was screened to a uniform size through a Tyler No. ~8 mesh screen. The cocrystallized product made in this manner was used as a low calorie sugar product. Assuming aspartame is 200 times as sweet as sucrose, O.S gram of the aspartame-sucrose product containing 2 calories provides the same sweetness as one teaspoonful (4.5 grams) of sugar containing 18 calories.
Example_15 The incorporation method used was the same as that described in Example 14. However, instead of an aspartame-sugar solution, a saccharin-sugar solution containing 99.8% of conventional brown sugar and 0.2%
saccharin (dry weight basis) was used. The cocrystal-lized product has the same sweetness as sucrose with one-half the caloric content. The relative sweetness of saccharin was assumed to be 550 times that of sucrose.
Example 16 An instant chocolate pudding was prepared by dry blend-ing the following ingredients:
~5~
170.0 grams of pregelatinized starch llo . n grams of cocoa powder (Hershey) 15.0 grams of tetrasodium pyrophosphate 8.0 grams of disodium phosphate 2.0 grams of monosodium phosphate lO.0 grams of calcium acetate 5.0 grams of non-fat dry milk solid~;
480 grams of granulated sugar and 200 grams of brown sugar were dissolved in 300 grams of water, and then cooked to 265F. The hot syrup was added to the dry blend with agitation until complete crystalliza-tion was obtained. The final product was screened through a Tyler #35 mesh screen.
120 grams of this material dispersed instantly in two cups of cold milk and produced a firm pudding after lO minutes at refrigeration tempe!ratures.
Example 17 An instant chcolate milk drink was prepared in accord-ance with the present invention. 800 grams of granu-lated sugar was dissolved in 300 ml. of water and then heated to 270F. The hot syrup was then added ~o 200 grams of carrageenan with agitation. The agitation was continued until a dry granular produ~t was obtained.
The finished product was screened through a #28 mesh screen. 25 grams of this material dispersed rapidly in one cup of cold milk and produceda chocolate milk drink with good flavor and body.
Example 18 An instant gelatin dessert mix was prepared by dis-solving 800 grams of granulated sugar in 300 ml. of water at 270F~ To this syrup was added 80 grams of gelatin powder, 1 gram of citric acid, and 0.1 cc of artificial strawberry flavor mix with agitation to form a dry product. The finished product was screenedthrough a Tyler #28 mesh screen. 20 grams of the finished product was easily dispexsed with slight agitation in one cup of cold water and produced a good, ~ir~ gelled dessert after 2.5 hours of xefri-geration~
~9 An instant ice cream mix was prepared by dry blending the following ingredients in a Hobart mixer:
350 grams o spray-dried butter supplied by Borden 210 grams of non-fa~ dry milk solids 2510 grams of stabilizer (sodium alginate) 0.5 grams of di- and monoglycerides Coloring and flavoring (as desired).
440 grams of granulated sugar was dissolved in 350 grams of water and heated to 270F. The hot syrup was added to the dry blend with agitation until complete crystal-lization was obtained. 42.5 grams of this material dispersed easily in 70 grams of cold water and produced a stabilized ice cream after blending in a Waring~
Blender and aging in a freezer.
Example 20 A chocolate sugar product was prepared by dry blending the following ingredi~nts in a Hobart mixer:
150 gxams of cocoa powder 100 grams of milk solids 5 grams of pure vanilla powder 2 yrams of caramel color.
753 yrams of brown sugar was dissolved in water and heated to 265F. The hot syrup was added to the dry blend with mechanical agitation until complete cry-stallization was obtained. The incorporated product has an instantly dispersible property when mixed with a liquid, such as cold milk.
Example 21 A nutritional supplement was prepared by dry blending 45 grams of essential amino acids with 100.7 grams of partially hydrogenated soybean o:il and emulsifier.
846 grams of brown sugar was dissolved in water and heated to 265F. The hot syrup was added to the dry blendwith vigorous agitatlon until crystallization was complete. The sugar matrix acted as a carrier for the nutrients and resulted in a free-flowing, stable, non-perishable dry powder.
Exampl _ 22 A dry cake base was prepared by dry blending 370 grams of cake flour, 130 grams of shortening, and 20 grams of dry milk. 426 grams of sugar was dissolved in water and heated to 250F. The supersaturated sugar syrup was then added to the dxy blend with mechanical agita-tion until the sugar was transformed. The cake base was mixed with other ingredients (egg white, baking powder, emulsifier and flavors) by dry blending to form a complete cake mix. Due to the formation of sugar/flour/fat agglomerates by the sugar transforming process,the cake prepared from this cocrystallized mix has a higher volume (porosity) and better appear-ance than that prepared from a traditional dry blended product.
Example 23 A complete coffee beverage mix was prepared by dry blend-ing 200 grams of instant coffee and 200 grams of non-dairy cream. 800 grams of sugar was dissolved in water and heated to 27QF. The supersaturated sugar syrup was then added to the dry blend ~with mechanical agita-tion until the sugar was transformed. The incorporated product is a free-flowing, homog~eneous, granulated powder with instantly dispersible property. A complete coffee drink can be prepared by reconstitution of 12 grams of this base with 1 cup of hot water. Similarly, a complete instant tea mix can also be produced in the same manner by incorporating instant tea powder and other ingredients into the sugar crystals~
All of th~ sugar incorporated products of the present invention are dry, granular, free-flowing, and non-caking. They are readily dispersible or dissolved in water. In addition, they are homogeneous and do not separate or settle out~
While the invention has been described with reference to specific embodiments, these were for purposes of illustration only and should not be construed to limit the scope of the present invention.
-
of the powdered ood ingredients because they sepa-rate or settle out upon standingO Consequently, in order to use the correct proportions or ingredi-ents in a package, the consumer must use the entire package rather than just a part of the package.
Another problem is that a percentage of the blend components is lost as dust during mechanical blending.
"Instant" food products, that is, powdered food pro-ducts which contain all of the food ingredients in a single package, encounter the same problems of difficulty of dispersion, tendency to cake, tendency to settle out, and dust losses.
It would be desirable to produce powdered food ingre-dients which avoid these problems.
It would also be desirable to produce instant food products which avoid these problems.
In the manufacture of sugar products, a process known as the transforming process is used to convert a sugar syrup into a dry sugar product. The sugar product is granular, free-flowing, non-caking, and is readily dispersed or dissolved in water. The transforming process has been described in U.S.
Patents Nos. 3,149,682 (Tippens et al.), 3,365,331 (Miller et al.), 4,159,210 ~Chen et al.), and our co Canadian patent pending, co-assigned/application entitled "Cry-stallized, Readily Water-Dispersible Sugar Product Containing Heat Sensitive, Acidic or High Invert Sugar Substances."* In Tippens et al., the method comprises concentrating a sugar syrup to a *filed 28 September, 1981 ~5~6~ :
solids content of about 95-97% by heating the sugar syrup to a temperature of about 250-265F., and subjecting the xesulting supersaturated sugar syrup to a heat dissipation operation simultaneously with vigorous agitation. The ~ethod produces a dry sugar product comprising aggregates of fondant-~ -size (3-50 micxons) sucrose crystals. ~iller et al.
10describes a similar process in whi~h impact beating -~
is used to crystallize the sugar product from the supersaturated sugar syru~.
The feed syrup which is erilployed in the processes of Tippens et al. and Miller et al. has a purity in the range of 85-97~ by weight sucrose. Thus, the feed syrup may not contain more than about 15% by weight non-sucrose solids.
Both Tippens et al. and ~liller et al. disclose that sugar products prepared in accordance with their invention are useful as carriers for additive mate-rials which may have a food value or a taste value or a color value or medicinal value or the like.
24 The food additive may be added at any step in the process, such as during concentration, crystalliza-tion, co~minution, screening, or by a separate blending and mixing operation with the sugar product, depending on the nature of the additive material.
Theoretically, it is possible to adapt the sugar transforming process so that a food ingredient is crystallized with the sucrose crystals from a sugar syrup containing the food ingredient. The resulting product would be granular, homogeneous, dry, free-flowing and non-caking. In addition, because the structure o the product would be porous clusters of micro-sized sucrose crystals intimately associated with the food ingredient, the food ingredient would be readily dispersible or dissolvable in liquid.
Accordingly it is an object of this invention to provide a product which incorporates a food ingredi-ent into a crystalline sugar matrix.
It is also an object of this invention to provide thi5 sugar product in dry, granular, free-flowing, non-caking form.
It is also an object o~ this invention to provide this sugar product in a form in which the food ingredient is readily dispersed or dissolvecl in liquid.
It is also an object of this invention to provide a sugar product which contains all of the dry food ingredients needed to make a final food product.
It is also an object of this invention to provide a method for preparing this sugar product.
These and other objects are accomplished by means of the present invention described below.
Summary of the Invention By means of the present invention, a crys~allized sugar product is prepared which incorporates a food ingredient into a sugar matrix. The product is homo geneous, dry, granular, free-flowing, and non-caking.
The product is composed of agglomerates or aggregates of minute, fondant-size sucrose crystals intimately associated with the food ingredient. Due to its porous structure, the crystalli2ed sugar product is readily dispersed or dissvlved in water.
15 The crystallized sugar product of the present inven- -tion is prepared by concentrating a sugar syrup at a tempexature in the range of about 250F. to about 300F. to a solids content of about 90 to ~8% by weight, said sugar syrup containing no more than about 20~ by weight non-sucrose solids; admixing the concentrated sugar syrup with the food ingredient; ~-subjecting the mixture to impact beating within a crystallization zone until a crystallized sugar pro-duct made up of aggregates of fondant-size sucrose crystals and the food ingredient is formed, the crystallized sugar product having a moisture content of less than-2.5% by weight; and recovering the crystallized sugar product from the crystallization zone. I desired, the resulting crystallized sugar produc~ may be dried to a moisture content of less than 1% by weight, followed by screening to a uniform size and packaging.
6~2~
' Detailed De-sc-ription of the Invention The accompanying drawing is a flow chart illustrat-ing a preferred process or scheme for preparing a crystallized sugar product in accordance with the present invention.
Referring to the flow chart, a feed sugar syrup 10 is concentrated by evaporation 12 to a supersatu-rated sugar syrup 14 having a solids content of about 90 to 98%. Concentration of the feed syrup is performed at an elevated temperature in the range of about 250-300F., and may be performed at atmospheric pressure or under vacuum. The feed syrup may be concentrated in a vacuum pan evapora-tor, in a rising and falling concentrator, or in a heat exchange evaporator under suitable conditions.
Thè solids content of the feed syrup should be at least 80% sucrose. Non-sucrose solids in the feed syrup may comprise additional mono- or disaccahrides or modified dextrins, for example, dextrose, invert sugar, fructose, corn syrup solids, or mixtures thereof.
The resulting supersaturated sugar syrup 14 having a solids content of about 90-98% is maintained at a temperature not less than about 240F. in order to prevent premature crystallization. A predetermined weight of the food ingredient 16, such as a gelatin, emulsifier, gum, starch, cocoa powder, etc., is added to the concentrated syrup with vigorous mechanical agitation, such as by Lmpact beat ng, within a crystallization zone. Alternatively, the concen-trated sugar syrup may be added to a predeterminedamount of the food ingredient and mixed in a similar manner. The device used for mechanical agitation could be a beater-crystallizer, a Turbulizer, a nucleator - crystallizer, a high speed or shear mixer, ox a blender.
Impact beating is continued within the crystallization zone until the supersaturated syrup/food ingredient mixture is transformed, crystallized 20, and aggolomer-ated 22. A crystalline sugar incorpoxated product 24is recovered from the crystallization zone. The latent heat of crystallization is sufficient to evaporate the moisture so that the product is substantially dry, i.e., has a moisture content of less than about 2.5% by weight.
If desired, the crystallized sugax product 24 may be further dried to a moisture content of less than 1%, followed by screening, milling, and packaging 26.
During crystallization, it is desirable to remove the heat of crystallization to prevent overheating within the crystallization zone. The heat of crystallization can be removed or dissipated by indirect heat exchange, e.g., by surro~mding the crystallization zone with a water jacket, or, preferably, by forced air flow through the beater-crystallizer, e.g., with a vapor separator.
Suitable app~ratus -for carrying out the process of the present invention in a continuous operation is described in U.S. Patent No. 3,365,331 (Miller et al.).
~ 8-In order to ensure maximum homogeneity in the final product, it is desirable to introduce the food ingre-dient into the concentrated syrup as early in theprocess as practical. However, in most cases, the food - ingredient is introduced during the sugar crystalliza-tion step. The food ingredient becomes thoroughly mixed in the earlier stages of the cry~stallization step as the concentrated syrup is transformed from the liquid state to a semi-solid state. Consequently, when the syrup reaches the relatively dry agglomerated state, the resulting product is a homogeneous blend of the co-crystallized sugar and the food ingredient.
The physical structure of the crystallized sugar pro-duct is highly dependent on the rate and temperature of impact beating and crystallization, and on the degree of sugar transformation. l`he optimum time for the concentrated syrup mixture to spend in the crystallization zone during impact: beating depends on several factors, including: (a) the nature of the non-sucrose solids (such as invert sugar and ash) in the feed syrup; (b) the nature and characteristics of the food ingredient (such as moisture content, invert sugar content, pH, etc.); (c) the concentration of the food ingredient in the mixture; and (d) the tempera-ture used for concentration of the food syrup.
In structure, the crystallized sugar products of the present invention are comprised of aggregates or agglomerates of fondant-size sucrose crystals, e.g., in the range of about 3-50 microns, intima~ely associ-ated with the non-sucrose solids. The agglomerates _9_ form a loose, lacey network bonded together at their interfaces by point contact. Accordingly, aqueous liquid can rapidly penetrate the porous cluster of agglomerates and free each of the particles making up the agglomerates. The particles thus become readily dispersed and/or dissolved in the aqueous liquid.
,;
In the crystallized sugar product of the present invention, the food ingredient is incorporated as an integral part of the sugar matrix and there is no tendency for the active ingredient to separate or settle out during handling, packaging, or storage.
The resulting product is granular, free-flowing, non-caking, and is readily dispersed or dissolved in water.
The structure and properties of the crystallized sugar products prepared in accordance with this invention are distinctly diferent from dry-blended sugar products and from sugar products prepared by the seed crystallization process of U.S. Pat.
3,248,226 or by the candy melt process of U.S. Pat.
3,341,334. For example, a gelatin/sugar product prepared in accordance with this invention is com-posed of clusters of micro~sized sucrose crystals coated with gelatin. This permits rapid dissolu-tion o the gelatin in cold water. In contxast, a gelatin/sugar product prepared by seed crystalliza-tion is composed of large, fluffy crystals which tend to clump and float on the surface when dispersed in a liquid. A gelatin/sugar pxoduct prepared by the candy melt process is composed of coarse, dense crystals which sink to the bottom of a liquid.
Typical profiles of emulsifier/sugar products, cocoa/
sugar products, and gelatin/sugax products prepared in accordance with this invention are presented in Tables I, II, and III, below.
~5 Table I
, ~
Mono- Mono- and glyceride Diglycerides Lecithin Product Product'Product _ _ .
Preparat'ion D'~ta ~levated Tempera-ture 255F. 265F. 260F.
10 Solids Content of . '.
S~persaturated Syrup 95.4% 96.5% 96.1% ' Crystallization Time 195 Secs. 125 Secs.165 Secs.
Finished Product Analvsis Sucrose Content 94.32~ 92.01% 89.61%
Invert Sugar 0.12% 0.10% 0.09%
Moisture Con-tent ' 0.2 % 0.3 % 0.2 %
Emulsifier 5 ~ 7.5 % 10 %
Screen Analysis (Tyler~
# 14 2.0 % 3~2 % 6.7 ~ -# 35 4.5 % 6.1 % 11.2 %
# 60 32.1 % 40.1 % 36.5 %
#100 34.2 % 24.3 % 34.4 %
#150 21.2 % 21.4 % lO.S %
#200 4.5 % 4.7 % 0.6 %
Pan 1.5 % 0.2 % 0.1 %
Table II
Cocoa Product Cocoa Product Preparation_Data Elevated Temperature 255F. 255F.
Solids Content of Super-saturated Syrup 95.0~ 95.0%
Crystallization Time Requixed 175 Seconds185 Seconds Finished Product ~Analysis . .
Sucrose Content 71.53~ 71.69 Invert Sugar 0.14% 0.16 Moisture Content 0.82% 0.65 Cocoa Powder 27.50% 27.50 S~reen Analysls (Tyler) #14 2.~ 1.6%
#35 3.2% 3.5%
#60 46.5% 40.6%
#100 31.8% 34.6%
#150 12.~ 15.9%
#200 3.2~ 1.4%
Pan 1.5% 2.4%
Table III
^Gelatin Product Gelatin_Product Pre~axation Data Elevated Temperature 260F. 265F.
Solids Content of Supersaturated Syrup 95.0% 96.5%
Crystallization Time 170 Seconds 185 Seconds Finished Product Analysis Sucrose Content88.53% 78.31% - ' Invert Sugar 0.14% 0.16%
Moistur2 Content1.05~ 1.45%
Gelatin Powder 10% 20%
pH 4.98 4.90 Color (10% Solution) 69 ASC Units 73 ASC Units Scxeen Analysis (T~ler) # 14 2.~% 1.6%
# 35 3.2% 3.5%
# 60 46.5% 40.5~ :
~100 31.8% 34.6%
~150 12.4% 15.9%
~200 3.2% 1.4~
Pan 1.5% 2.4%
~-32 A wide variety of pxoducts may be prepared in accord-ance with the present invention. These products may be either intermediate food products or instant food pro-ducts. By instant food products, it is meant that the product contains all of the dry food ingredien~s needed to make the final food. In contrast, intermediate food products, such as concentrates, must be blended with other food ingredients to make the food. In the pr~pa-ration of intermediate food products or consentrates, it is desirable that the amount of food ingredient contained in the sugar incorporated product be equal to or les5 than the total amount of sugar in the syrup, i.e.l the food ~ngredient should comprise about 0.05-50%
by weight of the crystallized sugar product.
The following examples illustrate various embodiments of this invention but are not meant: in any way to limit the scope thereof.
A dry, readily dispersible gelatin concentrate may be prepared in accordance with this invention. Desirably, the product contains about 0.5-30~ by weight gelatinO
Example 1 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95% solids content. An amount of gelatin equal to 10% by weight of the sugar was then added with controlled agitation (impact beating). Impact beating was continued until the mixture was converted into a substantially dry powder. As the crystallization of the sugar proceeded, . .
. . .
~ ~ 5 4 ~
the gelatin particles were incorpora*ed into the sugar matrix of fondant-size sucrose crystals. The heat of crystallization which accompanied the reaction aided in removing moisture to give a substantially dry powdered product.
Example 2 A gelatinJsugar product was prepared as in Example 1 except that, instead of adding the gelatin to the supersaturated sugar solution, the supersaturated sugar solution was added to the gelatin with impact beating.
Impact beating was continued and crystallization pro-ceeded~ eventually resulting in the formation of a dry powdered product.
Example 3 1300 grams of sucrose solution (65 Brix) was heated to 265F. to form a supersaturated syrup of approxi-mately 97~ solids. 200 grams of gelatin powder tthrough a Tyler #100 mesh screen) was added to the heated syrup with vigorous mechanical agitation using a Hobart mixer. Stirring was continued until the mixture was transformed and agglomerated into a ~ry powder. The finished product was screened through a Tyler #35 mesh screen.
Gelatin concentrates made in this manner were used in the formation of several food products containing gela-tin, such as, mashmallow mix, stabilized icing mix, and gelatin dessert mix. The product was readily 6;~,~
dispersed and dissolved in either hot or cold wat~r and formed a firm gelled or stabilized product.
In another embodiment of the present invention, ~arious stabilizers, such as pectin, carrageenan, guar gum, agar-agar, xanthan gum, or sodi~m alginate may be incorporated into a crystallized sugar product. De-sirably, the product comprises about 0.1-25~ by weight of the solution.
Example 4 A sugar incorporated pectin was prepared in accord-ance with the process described in Example 3. This pectin concentrate was then used in the formulation of several food products, such as jelly mix, syrup spread mix, and beverage drink mix. The finished products possessed an instantly dispersing and dis-solving nature when mixed with hot or cold watex without any detectable lumping. They provided a firm gelled texture or a stabilizing or thickening property similar to that of products prepared by con-ventional processes.
In another embodiment, various emulsifiers, such asmono- and diglycerides, propylene glycol esters, sor-bitan esters~ polyoxyethylene sorbitan estexs, lactylated estexs, or lecithins, may be incorporated into a crystalliæed sugar product. Desirably, the product comprises 0.1-25~ by weight of the stabilizer.
~5~
Example 5 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95 solids content. An amount of monoglycerol tMyverol 18-07, Kodak) equal to 5% by weight of the sugar was then added with controlled agitation (impact beating).
Impact beating was continued until the mixture was converted into a substantiall~ dry powder. As the crystallization of the sugar proceeded, the emulsifier was incorporated with the fondant-size sugar particles i~to a sugar matrix. The heat of crystallization which accompaniedthe reaction aided in removing moisture resulting in a substantially dry powdered product. The finished product was screened through a Tyler #35 mesh screen.
Example 6 An emulsifier/sugar product was prepared as in Example 5 except that the supersaturated sugar solution was added to the emulsifier with impact beating. Impact beating was continued and crystallization proceeded, eventually resulting in the formation of a dry powder similar to that of Example S.
Example 7 A sugar incorporated monoglyceride product was prepared according to the process described in Example 3. The product prepared in this manner was used in the formu~
lation of several food products, such as, cake mix and icing mix. The crystallized product, when added to cake mix or icing mix, provides excellent emulsion characteristics. For example, cake volume, porosity, and appearance, and icing stability and density were improved with the sugar incorporated emulsifier as compared with a conventional emulsifier.
In another embodiment, a cocoa or carob product may be prepared in accordance with the present inventionO
Desirably, the product comprises about 0.5-35% by weight cocoa or carob.
Example 8 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated syrup of approximately 95% solids content. An amount of cocoa powder ~Hershey Challenge No. lO0) equal to 25~ by weight of the sugar solution was then added with controlled agitation. Stirring of the sugar solution and the cocoa powder resulted in the formation of a slurry and coating of the cocoa parti-cles with the syrupO Stirring was continued until the mixture was converted into a dry powder. As the crystallization of the sugar proceeded, the cocoa powder particles were incorporated with the crystal-lized sugar. The heat of crystallization which accompanied the reaction aided in removing moisture and gave a substantially dry powdered product.
Example 9 A cocoa/sugar product was prepared as in Example 8 except that the supersaturated sugar solution was ~.nl~
-19- , added to the cocoa powder with agitation to form a slurry, thereby coating the cocoa powder with the syrup. Agitation was continued and crystallization was continued, eventually resulting in the formation of a dry powdered product similar to that of Example 8~
Exa~ple 10 580 grams of granulated sugar and 200 grams of brown sugar were dissolved in water and the solution heated until a product was obtained which contained 96%
solids. 200 grams of cocoa powder supplied by Hershey was added to the supersaturated syrup with agitation.
Stirring was continued until the mixture was trans-formed into a dry powder. The finished product was then screenedthrough a Tyler #35 mesh screen. The sugar incorporated cocoa product ~was used in the formulation of several food products containing cocoa, such as chocolate milk drink and pudding. These products were readily dispersible in cold water without any evidence of lumping.
In another emobodiment, various modified starches, such as, waxy maize starch, tapioca starch, corn starch, or wheat starch, may be incorporated into a crystallized sugar product. Desirably, the product comprises about 0.5-35% by weight starch.
Example 11 , The modified starch (Stir-N-Set, National Starch)/sugar ~.nl, ~5~6~i~
:
~20~
product was prepared according to the process described in Example 10~ The sugar incorporated modified starch was used in the formulation of several instant food products containing starch, such as, pie filling, pastry filling, pudding, and spoonable salad dressings.
This product was readily dispersihle in cold water without mechanical agitation.
In another embodiment, various fibers, such as corn bran, soy hulls, beet pulps, or wood cellulosel may be incorporated into a crystallized sugar product.
The fibers may be acidic, enzymatic, or oxidized modi-fied such as alpha-cellulose, microcrystalline cellu-lose or other cellulosic fibers. Desirably, the product comprises about O.S-35~ by weight fiberO
Example 12 A sugar solution of 65 Brix was heated to 255F. to form a supersaturated sugar solut:ion of approximately 95~ solids content. An amount of alpha-cellulose (Paniplus, Keycei BH 200) equal to 25% by weight of the sugar solution was then added with contr~lled agitation.
Stirring was continued until the moisture was con-verted into a dry powder. The incorporated product permits ready or instant dispersibility in liquid.
In another embodiment, various proteins, such as soy proteins, yeast proteins, milk proteins, wheat proteins, or egg proteins, are incorporated into a crystallized sugar product. The proteins may be acidic, enzymatic, or oxidized modified, such as, caseinates, lactalbumen, ~ f.
d ~3 wheat gluten, or soy albumen. Desirably, the product comprises about 0.5-35% by weight protein.
Example 13 95Q grams of granulated sugar and 50 grams of total invert sugar were dissolved in water and the solution 10 was heated until a product was obtained which con-tained 96% solids. 300 grams of soy protein concen-trates produced by Far-Mar, Inc. was added to the supersaturated sugar solution with agitation. Stirring was continued until the mixture was transformed into a 15 substantially dry product. As the crystallization of the sugar proceeded, the soy protein particles were incorporated into the crystallized sugar. The heat of crystallization, which developed during the exothermic ; reaction, aided in removing moisture, resulting in a 20 substantially dry particle.
In another embodiment, various sugar substitutes, such as saccharin and its salts, aspartame (aspartyl-phenyl-alanine-methyl-ester), glycyrrhizin and its derivatives, 25 cyclamate and its salts, miraculin (synsepalum dulsifi-cum), sorbitol, mannitol, or xylitol, are incorporated into a crystalline sugar matrix. Desirably, the prodct comprises up to 50% by weight sugar suhstitute.
Example_14 A sugar solution prepared from 92~ sucxose and 8%
aspartame (dry weight basis) was heated to 260F. to form a supersaturated syrup of approximately 93.5%
~5~
solids content. The heated syrup was subjected to mechanical agitation (impact beating). ~mpact beat-ing was continued until the mixture was transformedand agglomerated into a dry powder. As the transor-mation of the sugar proceeded, the synthetic sweetener cocrystallized with the fondant size sugar particles.
The heat of crystalliæation aided in removing moisture, resulting in a substantially "dry" product. The finished product was screened to a uniform size through a Tyler No. ~8 mesh screen. The cocrystallized product made in this manner was used as a low calorie sugar product. Assuming aspartame is 200 times as sweet as sucrose, O.S gram of the aspartame-sucrose product containing 2 calories provides the same sweetness as one teaspoonful (4.5 grams) of sugar containing 18 calories.
Example_15 The incorporation method used was the same as that described in Example 14. However, instead of an aspartame-sugar solution, a saccharin-sugar solution containing 99.8% of conventional brown sugar and 0.2%
saccharin (dry weight basis) was used. The cocrystal-lized product has the same sweetness as sucrose with one-half the caloric content. The relative sweetness of saccharin was assumed to be 550 times that of sucrose.
Example 16 An instant chocolate pudding was prepared by dry blend-ing the following ingredients:
~5~
170.0 grams of pregelatinized starch llo . n grams of cocoa powder (Hershey) 15.0 grams of tetrasodium pyrophosphate 8.0 grams of disodium phosphate 2.0 grams of monosodium phosphate lO.0 grams of calcium acetate 5.0 grams of non-fat dry milk solid~;
480 grams of granulated sugar and 200 grams of brown sugar were dissolved in 300 grams of water, and then cooked to 265F. The hot syrup was added to the dry blend with agitation until complete crystalliza-tion was obtained. The final product was screened through a Tyler #35 mesh screen.
120 grams of this material dispersed instantly in two cups of cold milk and produced a firm pudding after lO minutes at refrigeration tempe!ratures.
Example 17 An instant chcolate milk drink was prepared in accord-ance with the present invention. 800 grams of granu-lated sugar was dissolved in 300 ml. of water and then heated to 270F. The hot syrup was then added ~o 200 grams of carrageenan with agitation. The agitation was continued until a dry granular produ~t was obtained.
The finished product was screened through a #28 mesh screen. 25 grams of this material dispersed rapidly in one cup of cold milk and produceda chocolate milk drink with good flavor and body.
Example 18 An instant gelatin dessert mix was prepared by dis-solving 800 grams of granulated sugar in 300 ml. of water at 270F~ To this syrup was added 80 grams of gelatin powder, 1 gram of citric acid, and 0.1 cc of artificial strawberry flavor mix with agitation to form a dry product. The finished product was screenedthrough a Tyler #28 mesh screen. 20 grams of the finished product was easily dispexsed with slight agitation in one cup of cold water and produced a good, ~ir~ gelled dessert after 2.5 hours of xefri-geration~
~9 An instant ice cream mix was prepared by dry blending the following ingredients in a Hobart mixer:
350 grams o spray-dried butter supplied by Borden 210 grams of non-fa~ dry milk solids 2510 grams of stabilizer (sodium alginate) 0.5 grams of di- and monoglycerides Coloring and flavoring (as desired).
440 grams of granulated sugar was dissolved in 350 grams of water and heated to 270F. The hot syrup was added to the dry blend with agitation until complete crystal-lization was obtained. 42.5 grams of this material dispersed easily in 70 grams of cold water and produced a stabilized ice cream after blending in a Waring~
Blender and aging in a freezer.
Example 20 A chocolate sugar product was prepared by dry blending the following ingredi~nts in a Hobart mixer:
150 gxams of cocoa powder 100 grams of milk solids 5 grams of pure vanilla powder 2 yrams of caramel color.
753 yrams of brown sugar was dissolved in water and heated to 265F. The hot syrup was added to the dry blend with mechanical agitation until complete cry-stallization was obtained. The incorporated product has an instantly dispersible property when mixed with a liquid, such as cold milk.
Example 21 A nutritional supplement was prepared by dry blending 45 grams of essential amino acids with 100.7 grams of partially hydrogenated soybean o:il and emulsifier.
846 grams of brown sugar was dissolved in water and heated to 265F. The hot syrup was added to the dry blendwith vigorous agitatlon until crystallization was complete. The sugar matrix acted as a carrier for the nutrients and resulted in a free-flowing, stable, non-perishable dry powder.
Exampl _ 22 A dry cake base was prepared by dry blending 370 grams of cake flour, 130 grams of shortening, and 20 grams of dry milk. 426 grams of sugar was dissolved in water and heated to 250F. The supersaturated sugar syrup was then added to the dxy blend with mechanical agita-tion until the sugar was transformed. The cake base was mixed with other ingredients (egg white, baking powder, emulsifier and flavors) by dry blending to form a complete cake mix. Due to the formation of sugar/flour/fat agglomerates by the sugar transforming process,the cake prepared from this cocrystallized mix has a higher volume (porosity) and better appear-ance than that prepared from a traditional dry blended product.
Example 23 A complete coffee beverage mix was prepared by dry blend-ing 200 grams of instant coffee and 200 grams of non-dairy cream. 800 grams of sugar was dissolved in water and heated to 27QF. The supersaturated sugar syrup was then added to the dry blend ~with mechanical agita-tion until the sugar was transformed. The incorporated product is a free-flowing, homog~eneous, granulated powder with instantly dispersible property. A complete coffee drink can be prepared by reconstitution of 12 grams of this base with 1 cup of hot water. Similarly, a complete instant tea mix can also be produced in the same manner by incorporating instant tea powder and other ingredients into the sugar crystals~
All of th~ sugar incorporated products of the present invention are dry, granular, free-flowing, and non-caking. They are readily dispersible or dissolved in water. In addition, they are homogeneous and do not separate or settle out~
While the invention has been described with reference to specific embodiments, these were for purposes of illustration only and should not be construed to limit the scope of the present invention.
-
Claims (37)
1. A method for preparing a crystallized sugar product containing a food ingredient, comprising:
(a) concentrating a sugar syrup at a tempera-ture in the range of about 250°F. to about 300°F. to a solids content of about 90% to 98% by weight, said sugar syrup containing no more than about 20% by weight of non-sucrose solids;
(b) admixing the concentrated sugar syrup with a predetermined amount of the food ingredient;
(c) subjecting the admixture to impact beating within a crystallization zone until a crystallized sugar product is formed, said crystallized sugar product made up of aggregates of fondant-size sucrose crystals and the food ingredient and having a moisture content of less than 2.5% by weight; and (d) recovering said crystallized sugar product from said crystallization zone.
(a) concentrating a sugar syrup at a tempera-ture in the range of about 250°F. to about 300°F. to a solids content of about 90% to 98% by weight, said sugar syrup containing no more than about 20% by weight of non-sucrose solids;
(b) admixing the concentrated sugar syrup with a predetermined amount of the food ingredient;
(c) subjecting the admixture to impact beating within a crystallization zone until a crystallized sugar product is formed, said crystallized sugar product made up of aggregates of fondant-size sucrose crystals and the food ingredient and having a moisture content of less than 2.5% by weight; and (d) recovering said crystallized sugar product from said crystallization zone.
2. The method of Claim 1 further comprising drying said crystallized sugar product to a moisture content of less than about 1% by weight.
3. A crystallized sugar product made in accordance with the method of Claim 1 wherein said food ingredient com-prises, on a dry weight basis, about 0.05% to about 50 of the crystallized sugar product.
4. The crystallized sugar product of Claim 3 wherein said food ingredient is an emulsifier.
5. The crystallized sugar product of Claim 4 comprising, on a dry weight basis, about 0.1% to about 25% by weight of monoglycerides, diglycerides, propylene glycol esters, sorbitan esters, polysorbate esters, polyoxyethylene sorbitan esters, lactylated esters, or lecithins.
6. The crystallized sugar product of Claim 3 wherein the food ingredient is gelatin.
7. The crystallized sugar product of Claim 6 comprising, on a dry weight basis, about 0.5% to about 30% gelatin.
8. The crystallized sugar product of Claim 3 wherein the food ingredient is a stabilizer.
9. The crystallized sugar product of Claim 8 comprising, on a dry weight basis, about 0.1% to about 25% of pectin, carrageenan, guar gum, agar-agar, xanthan gum or sodium alginate.
10. The crystallized sugar product: of Claim 3 wherein the food ingredient is cocoa or carob.
11. The crystallized sugar product: of Claim 10 comprising, on a dry weight basis, about 0.5% to about 35% of cocoa or carob.
12. The crystallized sugar product of Claim 3 wherein the food ingredient comprises a modified starch.
13. The crystallized sugar product of Claim 12 comprising, on a dry weight basis, about 0.5% to about 35% of waxy maize starch, tapioca starch, corn starch, or wheat starch.
14. The crystallized sugar product of Claim 3 wherein the food ingredient is an edible fiber.
15. The crystallized sugar product of Claim 14 wherein the fiber is acidic, enzymatic, or oxidized modified.
16. The dry crystallized sugar product of Claim 14 com-prising, on a dry weight basis, about 0.5% to about 35%
of alpha-cellulose, microcrystalline cellulose, corn bran, soy hulls, beet pulp, wood cellulose, or other cellulosic fibers.
of alpha-cellulose, microcrystalline cellulose, corn bran, soy hulls, beet pulp, wood cellulose, or other cellulosic fibers.
17. The crystallized sugar product of Claim 3 wherein the food ingredient is a protein.
18. The crystallized sugar product of Claim 17 compris-ing, on a dry weight basis, about 0.5% to about 35% of soy proteins, yeast proteins, milk proteins, wheat pro-teins, egg proteins, caseinates, lactalbumen, wheat gluten, or soy albumen.
19. The crystallized sugar product of Claim 3 wherein said food ingredient is a sugar substitute.
20. The crystallized sugar product of Claim 19 compris-ing, on a dry weight basis, about 0.05% to about 50% of saccharin and its salts, aspartame, glycyrrhizin and its derivatives, cyclamate and its salts, miraculin, sorbitol, mannitol, or xylitol.
21. A crystallized sugar product made in accordance with the method of Claim 1 wherein said crystallized sugar product comprises an instant food product.
22. An instant chocolate pudding product made in accordance with the method of Claim 1.
23. The instant chocolate pudding product of Claim 22 comprising, on a dry weight basis, about 10% to about 20% starch, about 5% to about 15% cocoa, about 0% to about 3% tetrasodium pyrophosphate, about 0% to about 2%
disodium phosphate, about 0% to about 0.5% monosodium phosphate, about 0% to about 2% calcium acetate, about 0%
to about 1.0% non-fat dry milk solids, and the remainder substantially sugar.
disodium phosphate, about 0% to about 0.5% monosodium phosphate, about 0% to about 2% calcium acetate, about 0%
to about 1.0% non-fat dry milk solids, and the remainder substantially sugar.
24. An instant chocolate milk product made in accordance with the method of Claim 1.
25. The instant chocolate milk product of Claim 24 comprising, on a dry weight basis, about 15% to about 25% cocoa, about 0% to about 5% carrageenan, and the remainder substantially sugar.
26. An instant gelatin product made in accordance with the method of Claim 1.
27. The instant gelatin product of Claim 26 comprising, on a dry weight basis, about 5% to about 15% gelatin, about 0% to about 0.4% citric acid, about 0.01% flavoring, and the remainder substantially sugar.
28. An instant ice cream product made in accordance with the method of Claim 1.
29. The instant ice cream product of Claim 28 comprising, on a dry weight basis, about 30% to about 40% butter, about 15% to about 25% dry milk solids, about 0% to about 2% stabilizer, about 0% to about 0.1% mono- and di-glycerides, about 0% to about 0.1% coloring and flavoring, and the remainder substantially sugar.
30. An instant chocolate sugar product made in accordance with the method of Claim 1.
31. The instant chocolate sugar product of Claim 30 comprising, on a dry weight basis, about 10% to about 20% cocoa, about 5% to about 15% milk solids, about 0%
to about 1% vanilla, about 0% to about 0.2% caramel color, and the remainder substantially sugar.
to about 1% vanilla, about 0% to about 0.2% caramel color, and the remainder substantially sugar.
32. An instant nutritional supplement made in accordance with the method of Claim 1.
33. The instant nutritional supplement of Claim 32 comprising, on a dry weight basis, about 2% to about 10%
essential amino acids, about 5% to about 15% partially hydrogenated soybean oil and emulsifier, and the remainder substantially sugar.
essential amino acids, about 5% to about 15% partially hydrogenated soybean oil and emulsifier, and the remainder substantially sugar.
34. An instant cake base made in accordance with the method of Claim 1.
35. The instant cake base of Claim 34 comprising, on a dry weight basis, about 30% to about 50% flour, about 10%
to about 15% shortening, about 1% to about 5% dry milk, and the remainder substantially sugar.
to about 15% shortening, about 1% to about 5% dry milk, and the remainder substantially sugar.
36. An instant coffee or tea product made in accordance with the method of Claim 1.
37. The instant coffee or tea product of Claim 36 com-prising, on a dry weight basis, about 10% to about 35%
instant coffee or tea, about 10% to about 35% non-dairy cream, and the remainder substantially sugar.
instant coffee or tea, about 10% to about 35% non-dairy cream, and the remainder substantially sugar.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/199,551 US4338350A (en) | 1980-10-22 | 1980-10-22 | Crystallized, readily water-dispersible sugar product |
| US199,551 | 1980-10-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1154628A true CA1154628A (en) | 1983-10-04 |
Family
ID=22738015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000386880A Expired CA1154628A (en) | 1980-10-22 | 1981-09-29 | Crystallized, readily water-dispersible sugar product |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4338350A (en) |
| EP (1) | EP0052919A3 (en) |
| JP (1) | JPS6056478B2 (en) |
| CA (1) | CA1154628A (en) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4423085A (en) * | 1982-04-23 | 1983-12-27 | Amstar Corporation | Cocrystallized sugar-nut product |
| US4464403A (en) * | 1983-02-03 | 1984-08-07 | General Foods Corporation | Instant pudding composition containing cocoa and process |
| CN87106705A (en) * | 1986-09-15 | 1988-05-11 | 约翰·马克斯韦尔·怀尔德曼 | Powdered molasses product |
| US5456932A (en) * | 1987-04-20 | 1995-10-10 | Fuisz Technologies Ltd. | Method of converting a feedstock to a shearform product and product thereof |
| US5387431A (en) * | 1991-10-25 | 1995-02-07 | Fuisz Technologies Ltd. | Saccharide-based matrix |
| US5516537A (en) * | 1987-04-20 | 1996-05-14 | Fuisz Technologies Ltd. | Frozen comestibles |
| GB8804958D0 (en) * | 1988-03-02 | 1988-03-30 | Unilever Plc | Granular beverage material for tea coffee/cocoa & method of its preparation |
| BE1001556A4 (en) * | 1988-03-30 | 1989-12-05 | Raffinerie Tirlemontoise Sa | SUCROSE PRODUCTS CONTAINING HIGHLY SWEETENING SWEETENERS AND PROCESSES FOR OBTAINING SAME. |
| FR2634355B1 (en) * | 1988-07-25 | 1990-09-14 | Beghin Say Sa | NOVEL FOOD SWEETENER BASED ON SUCROSE AND INTENSE SWEETENER AND PROCESS FOR PREPARING THE SAME |
| US5085876A (en) * | 1988-11-16 | 1992-02-04 | The Nutrasweet Company | Fast dissolving sweetening agent including caramel |
| ATE99879T1 (en) * | 1991-03-28 | 1994-01-15 | Nestle Sa | DRY BASIC MATERIAL OF CRYSTALLIZED SUGAR, COCOA AND OTHER INGREDIENTS AND PROCESS FOR ITS PRODUCTION. |
| CA2102607A1 (en) * | 1991-05-17 | 1992-11-18 | Richard C. Fuisz | Enzyme systems |
| US5576042A (en) * | 1991-10-25 | 1996-11-19 | Fuisz Technologies Ltd. | High intensity particulate polysaccharide based liquids |
| PL170554B1 (en) * | 1991-12-17 | 1996-12-31 | Fuisz Technologies Ltd | Method of obtaining an anti-ulcerous composition |
| EP0564077A3 (en) * | 1992-02-20 | 1994-08-17 | Gen Foods Inc | Low-fat confectionary material and process for making same |
| US5654003A (en) * | 1992-03-05 | 1997-08-05 | Fuisz Technologies Ltd. | Process and apparatus for making tablets and tablets made therefrom |
| ES2060544B1 (en) * | 1993-03-26 | 1995-04-01 | Cia Gral Del Algarrobo De Espa | A SYRUP CONSTITUTED BY THE NATURAL SUGARS OF LA ALGARROBA AND PROCESS FOR ITS OBTAINING |
| US5476678A (en) * | 1993-04-23 | 1995-12-19 | Amway Corporation | Composition for and method of producing a fiber fortified chewy or soft-textured confection candy |
| US5895664A (en) * | 1993-09-10 | 1999-04-20 | Fuisz Technologies Ltd. | Process for forming quickly dispersing comestible unit and product therefrom |
| US5597416A (en) * | 1993-10-07 | 1997-01-28 | Fuisz Technologies Ltd. | Method of making crystalline sugar and products resulting therefrom |
| US5851553A (en) * | 1993-09-10 | 1998-12-22 | Fuisz Technologies, Ltd. | Process and apparatus for making rapidly dissolving dosage units and product therefrom |
| US5518551A (en) * | 1993-09-10 | 1996-05-21 | Fuisz Technologies Ltd. | Spheroidal crystal sugar and method of making |
| US5622719A (en) * | 1993-09-10 | 1997-04-22 | Fuisz Technologies Ltd. | Process and apparatus for making rapidly dissolving dosage units and product therefrom |
| US5346377A (en) * | 1993-10-07 | 1994-09-13 | Fuisz Technologies Ltd. | Apparatus for flash flow processing having feed rate control |
| US5549757A (en) * | 1994-06-10 | 1996-08-27 | Ingredient Technology Corporation | Process for recrystallizing sugar and product thereof |
| US6020002A (en) * | 1994-06-14 | 2000-02-01 | Fuisz Technologies Ltd. | Delivery of controlled-release system(s) |
| US5567439A (en) * | 1994-06-14 | 1996-10-22 | Fuisz Technologies Ltd. | Delivery of controlled-release systems(s) |
| US5445769A (en) * | 1994-06-27 | 1995-08-29 | Fuisz Technologies Ltd. | Spinner head for flash flow processing |
| US5582855A (en) * | 1994-07-01 | 1996-12-10 | Fuisz Technologies Ltd. | Flash flow formed solloid delivery systems |
| DE4424866C1 (en) * | 1994-07-14 | 1995-08-17 | Pfeifer & Langen | Prepn. of stable, non-caking sugar-based gelling aid for making jelly |
| US5843922A (en) * | 1994-07-29 | 1998-12-01 | Fuisz Technologies Ltd. | Preparation of oligosaccharides and products therefrom |
| US5556652A (en) * | 1994-08-05 | 1996-09-17 | Fuisz Technologies Ltd. | Comestibles containing stabilized highly odorous flavor component delivery systems |
| US5433962A (en) * | 1994-08-25 | 1995-07-18 | The Procter & Gamble Company | Rapidly soluble flavored instant coffee product |
| US5554400A (en) * | 1994-08-25 | 1996-09-10 | The Procter & Gamble Company | Infusion beverage product comprising co-agglomerated creamer and sweetener suitable for bag and filter pack brewing |
| US5587198A (en) * | 1995-05-31 | 1996-12-24 | Fuisz Technologies Ltd. | Positive hydration method of preparing confectionery and product therefrom |
| CA2173780A1 (en) * | 1995-06-01 | 1996-12-02 | Randy Grote | Method for providing nutrition in a variety of compositional forms |
| US5904948A (en) * | 1995-06-01 | 1999-05-18 | Nestec Ltd. | Method for manufacturing a balanced, nutritionally complete coffee composition |
| US5686108A (en) * | 1995-09-27 | 1997-11-11 | Amway Corporation | Brassica vegetable supplement and process for manufacture |
| DE69625320T2 (en) * | 1995-10-27 | 2003-10-02 | Nestle Sa | Nutritious coffee composition |
| FR2742164B1 (en) * | 1995-12-11 | 1999-01-29 | Beghin Say Eridania | MICROCRYSTALLINE SUGAR: COMPOSITION AND METHOD OF OBTAINING |
| CA2203357A1 (en) | 1996-05-06 | 1997-11-06 | Mark V. Hembling | Quick-setting gel mix |
| US5997937A (en) * | 1996-05-06 | 1999-12-07 | Kraft Foods, Inc. | Quick-setting gel mix |
| US5914320A (en) * | 1996-07-19 | 1999-06-22 | The Procter & Gamble Company | Co-milled mixtures comprising polyol and method of making |
| US6660049B1 (en) | 1996-07-31 | 2003-12-09 | Natural Soda Aala, Inc. | Process for control of crystallization of inorganics from aqueous solutions |
| US5738900A (en) * | 1996-08-30 | 1998-04-14 | Kraft Foods, Inc. | Process for making a readily-dispersible, dry food mix |
| GB9711231D0 (en) * | 1997-05-30 | 1997-07-23 | Kemin Ind Inc | Food processing procedure |
| US6387432B1 (en) * | 1998-06-12 | 2002-05-14 | General Mills, Inc. | Dried marshmallow methods of preparation for increasing bowl life |
| US6180158B1 (en) * | 1998-06-12 | 2001-01-30 | General Mills, Inc. | Process for aerated confection |
| US6436455B2 (en) * | 1998-06-15 | 2002-08-20 | General Mills, Inc. | Multi-colored aerated confectionery products |
| US6716458B1 (en) * | 1999-08-06 | 2004-04-06 | Bryon J. Tarbet | Nutritional supplement |
| WO2003059094A1 (en) * | 2002-01-15 | 2003-07-24 | Mars Incorporated | Methods to reduce agglomeration of granular foods |
| US20040131752A1 (en) * | 2003-01-06 | 2004-07-08 | Best Eric T. | Melt-resistant fudge article and methods of using same |
| DE10315614A1 (en) * | 2003-04-04 | 2004-10-21 | Dr. August Oetker Nahrungsmittel Kg | Process for the preparation of a food preparation, consisting of a mixture of animal and / or microbially produced gelling agents and types of sugar wetted with liquid or alcohol, which has gelling and / or thickening properties in cold aqueous solutions, emulsions and water-containing foods, and a product produced according to it |
| US7329428B2 (en) * | 2003-10-28 | 2008-02-12 | Kraft Foods Holdings, Inc. | Process for manufacture of aerated confections with dry blend of sugar and gelatin |
| US20050095323A1 (en) * | 2003-10-29 | 2005-05-05 | Kraft Foods Holdings, Inc. | Method of preparing soy-containing confectionary type products |
| US20070184163A1 (en) * | 2006-02-07 | 2007-08-09 | International Flavors, & Fragrances Inc. | Non-hygroscopic flavor particles |
| WO2008133563A1 (en) * | 2007-04-26 | 2008-11-06 | Swedish Match North Europe Ab | Moist non-tobacco snuff product |
| WO2008018643A1 (en) * | 2006-08-11 | 2008-02-14 | Ajinomoto Co., Inc. | Carbonated beverage and method of producing carbonated beverage |
| US20090181128A1 (en) * | 2008-01-10 | 2009-07-16 | Better Bowls | Consumable product |
| EP2515680B1 (en) | 2009-12-22 | 2015-04-22 | Firmenich S.A. | Active ingredient delivery system |
| CN104543271A (en) * | 2010-05-10 | 2015-04-29 | 卡吉尔公司 | Cocoa powder compositions |
| EP2649888B1 (en) | 2012-04-10 | 2020-02-19 | Swedish Match North Europe AB | A smokeless tobacco composition comprising non-tobacco fibers and a method for its manufacture |
| TR201720995A2 (en) * | 2017-12-21 | 2018-03-21 | Eti Gida Sanayi Ve Ticaret Anonim Sirketi | Molasses Powder And Production Method Of This Powder |
| EP4118243A1 (en) * | 2020-03-09 | 2023-01-18 | Cargill, Incorporated | Sweetener composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1467007A (en) * | 1922-07-26 | 1923-09-04 | People Of The United States | Maple product |
| US1970870A (en) * | 1932-03-31 | 1934-08-21 | Skazin Lev | Nonmottling and nonhardening maple sugar and process of making the same |
| FR77963E (en) * | 1960-06-01 | 1962-05-18 | Corn Products Co | New sweet products |
| US3169888A (en) * | 1962-03-05 | 1965-02-16 | American Sugar | Pressed crystal sugar tablet and method of manufacturing same |
| US3194682A (en) * | 1963-04-03 | 1965-07-13 | American Sugar | Sugar product and method of producing same |
| US3305447A (en) * | 1963-06-12 | 1967-02-21 | American Sugar | Tabletting sugar and method of preparing same |
| US3365331A (en) * | 1964-07-06 | 1968-01-23 | American Sugar | Sugar process and product |
| US3248226A (en) * | 1964-09-28 | 1966-04-26 | Jr Aubrey P Stewart | Methods for increasing the solubility of powdered material and products resulting therefrom |
| US3341334A (en) * | 1966-01-25 | 1967-09-12 | Gen Foods Corp | Cold water soluble gelatin made with candy melts |
| US3642535A (en) * | 1970-01-21 | 1972-02-15 | American Sugar | Tabletting sugar, method of preparing compositions containing same |
| US3656971A (en) * | 1970-01-30 | 1972-04-18 | George R Reimer | Low density frostings |
| US3656972A (en) * | 1970-03-23 | 1972-04-18 | Gen Mills Inc | Whip topping |
| US3726691A (en) * | 1971-03-25 | 1973-04-10 | Procter & Gamble | Process for producing polyglycerol ester fluffy frosting mixes |
| US3874924A (en) * | 1973-09-13 | 1975-04-01 | Cpc International Inc | Non-hygroscopic, water-soluble sugar products and process for preparing the same |
| DE2359250A1 (en) * | 1973-09-24 | 1975-04-03 | Gen Foods Corp | PROCESS FOR THE MANUFACTURING OF FLAVOR AND FLAVOR MIXTURES |
| US4031255A (en) * | 1975-07-03 | 1977-06-21 | General Foods Corporation | Fixing acetaldehyde in sucrose |
| US4159210A (en) * | 1978-06-15 | 1979-06-26 | Amstar Corporation | Maple sugar product and method of preparing and using same |
-
1980
- 1980-10-22 US US06/199,551 patent/US4338350A/en not_active Expired - Lifetime
-
1981
- 1981-09-01 EP EP81303982A patent/EP0052919A3/en not_active Ceased
- 1981-09-29 CA CA000386880A patent/CA1154628A/en not_active Expired
- 1981-10-20 JP JP56168510A patent/JPS6056478B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0052919A2 (en) | 1982-06-02 |
| EP0052919A3 (en) | 1982-11-24 |
| JPS6056478B2 (en) | 1985-12-10 |
| JPS57122759A (en) | 1982-07-30 |
| US4338350A (en) | 1982-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1154628A (en) | Crystallized, readily water-dispersible sugar product | |
| EP0052413B1 (en) | Crystallized, readily water-dispersible sugar product containing heat sensitive, acidic or high invert sugar substances | |
| US5853785A (en) | Dry mix for producing a slush beverage | |
| JP2509403B2 (en) | Premixes for the production of whipped foods | |
| US4311717A (en) | Stabilizing agent for dry mix food products | |
| CA2067595C (en) | Use of hydrocolloids for formulating and processing of low fat water activity confectionery products and process | |
| US4689238A (en) | Composite food product | |
| US4818554A (en) | Aerated food product based on raw milk and method for its preparation | |
| US4346121A (en) | Process for preparing crumb products | |
| JPH11123069A (en) | Low calorie acidic protein drink and its production | |
| EP0099947B1 (en) | Process for producing natural fruit candy | |
| JPS62104544A (en) | Filling for sugarless cheese cake and dry mix used in production thereof | |
| US4395429A (en) | Expandable food composition | |
| US3365305A (en) | Aerated food products and method | |
| US4423085A (en) | Cocrystallized sugar-nut product | |
| US3244528A (en) | Dried honey-milk product | |
| US4869917A (en) | Powdered mix for producing a three-layered dessert and process therefore | |
| US4307123A (en) | Frozen dessert composition | |
| EP0772977B1 (en) | Dry mix for producing a slush beverage | |
| US4500552A (en) | Gelatin dessert product | |
| JPH01218553A (en) | Low calorie ice cream type product low in fat content and containing no sucrose | |
| AU2002364394A1 (en) | Mousse | |
| EP0262791B1 (en) | Process for making candy coated snack foods, such as popcorn | |
| US4568553A (en) | Finely ground acidulents in highly-dutched cocoa pudding mixes | |
| EP0296849B1 (en) | Process for the preparation of an instant tea product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |