CA1170315A - Vacuum-arc plasma apparatus for producing coatings - Google Patents

Vacuum-arc plasma apparatus for producing coatings

Info

Publication number
CA1170315A
CA1170315A CA000378498A CA378498A CA1170315A CA 1170315 A CA1170315 A CA 1170315A CA 000378498 A CA000378498 A CA 000378498A CA 378498 A CA378498 A CA 378498A CA 1170315 A CA1170315 A CA 1170315A
Authority
CA
Canada
Prior art keywords
cathode
solenoid
consumable
tubular anode
end portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000378498A
Other languages
French (fr)
Inventor
Valentin G. Padalka
Ivan I. Axenov
Viktor G. Bren
Leonid P. Sablev
Rimma I. Stupak
Vladimir M. Khoroshikh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of CA1170315A publication Critical patent/CA1170315A/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/48Generating plasma using an arc
    • H05H1/50Generating plasma using an arc and using applied magnetic fields, e.g. for focusing or rotating the arc
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/32Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C23C14/325Electric arc evaporation

Abstract

ABSTRACT

The invention comprises a tubular anode, a consu-mable cathode with a working end portion and an igni-ting electrode for forming a cathode spot of an arc dis-charge on the consumable cathode, both elements being disposed coaxially within the tubular anode, a solenoid encircling the tubular anode and disposed coaxially therewith. The solenoid is so disposed relative to the tubular anode, the consumable cathode and the igniting electrode that it projects beyond the igniting electrode at the side opposite to the working end portion of the consumable cathode by a distance exceeding half a length of the portion of the solenoid, disposed around the con-sumable cathode. The number of turns per length unit of the portion of the solenoid, disposed around the consu-mable cathode, is greater than the number of turns per length unit in the remaining portion of the solenoid.
The invention is utilized for producing coatings.
The drawing given in the specification.

Description

li7()315 ~ VACU~-AR~ A~ APPl~RATU~

The invention relates to vacuum-arc plasma appara-tu3 and can be utilized for application of metallic coa-ting~, cleaning and pickling surfaces, spraying a getter material.
In the vacuum evaporization of metals such coating~
as anticorrosive, wear-re~istant, refractory, antifric-tion, superconductive, optical etc. are produced.
Vacuum application of coatings can be carried out by means of an electron-beam apparatus wherein metal vapour is formed in evaporization of metals from cruci-bles by an electron beam. The use of crucibles does not permit producing coatings from refractory metals. Moreo-ver, the coatings thus obtained are contaminated by a crucible material.
The vacuum-arc plasma apparatus makes it possible to produce pure coatings from any metals, refractory ones among them.
In ~uch an apparatus a consumable cathode i~ eva-porized by means of an arc discharge, a plasma flow of the metal being evaporized is formed, said metal being in a highly ionized state at a high value of energy and concentration of particles, and in the following conden-sation thereof forming a coating.
Vacuum-arc plasma apparatuses create a diverging 117()315 plasma flow of a material being evaporized, the coeffi-cient of utilization of the pla~ma flow in the applica-tion of coatings i~ low. The pla~ma flow of the materi-al being evaporized i8 to be focused to produce coatings.
Known in the art i~ a vacuurn-arc apparatu~ (USSR
Author'~ Certificate No. 416,789), compriqing a consu-mable cathode, an anode dispo~ed coaxially therewith, and an igniting electrode.
An arc di~charge between the con~umable cathode and anode i8 excited by means of the igniting electrode.
The consumable cathode generate~ a wide divergent flow of metallic plasma, the efficiency of utilization of the material being evaporized for producing coating~
is low. For thi~ rea~on the utilization of the above apparatus for vacuum metallization is inexpedient.
Also known in the art is an impuls generator of metallic plasma (A.S.Gilmour, D,L.Lochwood, Pulsed me-tallic-plasma generators, Proc. IEEE, 60, 8, 977, 1972~, compriqing a consumable cathode, a solenoid dis-posed coaxially therewith, an anode di~posed within the ~olenoid and an igniting electrode. The igniting elec-trode enclrcles the con~umable cathode and is separated therefrom by an insulator. The ignition of an arc dis-charge i~ accompli~hed by a ¢urrent pulse cau~ing eva-porization of a co~ductive film from the ~urface of said inqulator. The film i~ re~tored during the burning ll~ ~;~iS

of the arc discharge, The flow o~ metallic plasma, gene-rated by the consumable cathode, is focused by an a~ial-ly-~nmetrical magnetic field o~ the solenoid, thereby acquiring a narrower directional diagram.
The above apparatus increases the efficiency of utilization of the evaporized material of a con~u~ble cathode. However, an increase in the flow of the evapo-rized material of a _onsumable cathode at the outlet of the apparatus i9 limited by a partial reflection of ions from a magnetic barrier created at the end~ of the sole-noid. Moreover, the above generator is not ~uitable for operation in a ~tationary operation mode because of de-sign feature~ of the igniting electrode.
Known in the art is a vacuum-arc pla~ma apparatus allowing the efficiency of utilization of the evaporized material of a con~umable cathode to be increa~ed in a stationary operation mode (I.I.Aksenov, V.G.Padalka, V,T,Toloka, V.M,Khoroshikh, Fokusirovka potoka metalli-cheskoi plazmy, generiruemogo statsionarnym erozionnym elektrodugovym uskoritelem, Sb."I~tochniki i uskoriteli plazmy, Vyp. 3, Kharkov, 1978, ~.45-50).
The apparatus comprises a con~umQble cathode pro-vided with a working end portion, a solenoid being co-a~ial therewith, a tubular anode dispo~ed within the ~o-lenoid, and an igniting electrode.
In thi~ apparatus, the igniting electrode e~cites li7~315 an arc discharge. The flow of metallic pla~ma, genera-ted by the con~umable cathode, i~ focused by an a2ially--~ymmetric field of the ~olenoid. Such an arrangement permit~ obtaining a narrower directional diagram of the metal being evaporized and increa~ing the efficiency of utilization thereof.
However, in the above device a portion of the ion component of the plasma fiow i~ reflected from an elec-tromagnetic barrier occuring in the operation of the de-vice due to the deviation of magnetic lines of force at the end o~ the ~olenoid, ~aid portion missing the ~ub-~trate. Another disadvantage of the above device i8 an un~table ignition and burning of the arc diocharge, which can be explained by the following rea30ns. In the case of location of the igniting electrode at the wor-king end portion of the con~umable cathode there occur failure~ in the operation becau~e of the damage of the lgniting electrode cau~ed by a ~tationary arc di~charge~
The igniting electrode being disposed at a side ~urface of the consumable cathode, the stability of the ignition proce~s i~ disturbed ~ince a cathode ~pot being e~cited on the side surface is thrown by the magnetic field of the solenoid to the side opposite to the working end portion of the consumable cathode. Such "throwing a~ide"
terminate~ with extinction of the arc di~charge. ~ponta-neous "running~-out" of the cathode spot from the wor-l.t~7( )315 king end portion of the consumable cathode to the ~ide~urface thereof terminate i~ a ~imilar ~a~.
~ he object of the invention is the provision of a vacuum-arc plasma apparatus ~herein a solenoid i~ ~o constructed and di~posed that the eificiency o~ utili-zation of the evaporized material of a consumable ca-thod i~ increaRed an~ stable operation of the appars-tus is upgraded.
The above object o~ the i~s~tion i~ attained b~
mean8 Or an apparatu~ including a tubular anode, a con-~umable cathode pro~ided with a working end portion and disposed withi~ the tubular anode in a coaxial relati-onship there~ith; an i8nitine electrode ~or iormi~g a cathode spot on the con~umable cathode and dispoRed ~ithIn the tubular anode; a ~olenoid encircliDB the tu-~ular anode and di~po~ed coRxially there~ith and pro-~ecting beyond the i~niting electrode at the side oppo-~ite to the wor~ing end portion of the co~sumable ca-thode to a length exceeding half a length o~ the por-tion of the ~olenoid ~hich is di~o~ed around the con-~umable cathode, and ha~rine a number of turn~ per len~th unit of the portion of the solenoid ~hich i8 di~po~ed around the con~umable cathode, e~:ceeding tho number Or turns per length unit of the remaining portion of the ~olenoid~

l ~'~'( );~lS

Such an arrangement make~ it po~sible to obtain a magnetic field who~e maximum i8 ~hifted from the igni-ting electrode to the side oppo3ite to the working end portion. Therefore, in the proce~s of operation of the apparatu~, the plasma flow generated by the consumable cathode is injected into a longitudinal axially-~ymmet-rical magnetic field with a "plug" beyond the working end portion of the con~umable cathode. The pla~ma flow, not meeting a retarding potential barrier on its path, pa~ses to the apparatus outlet without any ob~tacles.
Moreover, equipotential surface~ which are positive re-lative to the consumable cathode and converge beyond the igniting electrode at the side oppo~ite to the working end portion of the consumable cathode, provide a suffi-ciently effective reflection of the ion component of plasma to the apparatus outlet, and a radial constitu-ent of the electrical field e~isting in~ide the tubular anode prevents ions from drifting to the wall~.
The above arrangement of the ~olenoid further pro-vides for optimum condition~ requered for ~table igniti-on and maintenance of the arc discharge. In fact, during ignition the cathode spot i~ initiated on the side sur-face of the con~umable cathode within the region where an acute angle between magnetic line~ of force and the surface of the con~umable cathode is directed to the working end portion thereof. In accordance with the ac-~ ()3 15 u~e angle rule, the cathode spot drifts, in thi~ c~se,over the side ~urrace of t~e con~umable ca~hode toward~
the workin~ end portion thereof.
As a re~ult, practically all the ions ~enerated by the consumable cathode are transported without any lo~-se~ to the outlet of the apparatu~, thereby determining the highest e~icienc~ o~ utilization of the e~aporized material Ln the stable operation of the above apparatus.
In accordance ~ith the in~ention, the solenoid i~
expedient to be 80 constructed that the number o~ turns per length unit of the ~olenoid aroun~ the ¢on~umable cathode be at least t~o times more than thab oi the re-mainIng portion o~ the solenoid.
Inve~ti~tions ha7e demonstrated th~t the above con~idered mechaniam Or stabilization o~ the cathode ~pot i~ er~ective only in the case where the number of turns per length unit oi the ~olenoid ~round the con8umable cat-hode exceed~ the number of turns per length unit in the remaini~g portion of the ~olenoid at lea~t t~o times.
The inventivn i8 ~uIther described in greater deta-il ~ith rererence to the accompanying dra~inB in ~hich the vacuum-arc pla~ma apparatus of the in~ention i~ ~ho~m i~a a ~chemati~al ~ectional vie~-~ ~acuum-are pla~a apparatu~ ¢ompri~e~ a con~umable cathode ~ having a side ~urface 2 and a workine end po~
tion 3, a 3elenoid 4 di~po~ed cosxiall~ with the consu-mable cathode l, a tubular anode 5 disposed within the solenoid 4, an igniting electrode 6 mounted on a ceramic jumper 7, both being adjacent the side surface 2 of the consumable cathode 1, The tubular anode 5 is fixed inside a cylindri-cal body 8 whereon the solenoid 4 is mounted.
A portion 9 of the solenoid 4 encircles the con-sumable cathode l and has a length of lOO mm. More than a half of the portion 9 of the solenoid 4 (56 mm in the present case) extends beyond the igniting electrode 6 at the side opposite to the working end 3 of the consumable cathode l. The consumable cathode l and the ignitiny electrode 6 are provided with respective vacuum current inputs lO and ll passing through an end cover 12 which is mounted on the cylindrical body 8.
The cylindrical body 8 is connected with a vacuum chamber 13 wherein a substrate 14 is mounted. A
cavity 15 is provided for cooling the tubular anode 5.
A cavity for cooling the consumable cathode 1 is not shown in the drawing, An igniting-pulse generator is designated by the reference numeral 16, and a power supply for an arc discharge, by 17.
A DC power supply for the solenoid 4 is not 2S shown in the drawing, The vacuum-arc plasma apparatus operates as fol-i ~' 1.~7(j315 lows.
~ he power ~upply 17 fsr an arc discharge is ~wit-ched on. ~ext, the power ~upply for the ~olenoid 4 (not ~hown) i~ switched on and a magnetic field iq obtained, whose line~ of force are di~posed as ~hown in the dra-wing by dotted line~.
Ma~imum magnetic field intensity of the solenoid 4 i~ located in that portion thereof which i~ di~posed cloqe to the igniting electrode 6 at the ~ide opposite to the working end portion 3. ~he igniting-pulse genera-tor 16 for the igniting electrode 6 is switched on, and a ~urface ~park discharge i~ obtained over the ceramic jumper 7 of the igniting electrode 6, which discharge form~ a cathode ~pot of the arc discharge between the side ~urface 2 of the con~umable cathode 1 and the tu-bular anode 5.
Then the cathode spot drifts toward~ the working end portion 3 of the consumable cathode 1 due to the fact that, in the area where the cathode Rpot appears, the magnetic lines of force intersect the side surface
2 of the consumable cathode 1 at an acute angle directed toward3 the working end portion 3 of the consumable ca-thode 1, and moves to the working end portion 3 while accompli~hing chaotic ~hifts.
Under the action of an electrical field whoqe form of equipotential~ i~ determined by the topography of a magnetic field, the generated plasma flow of the evapo-rized material of the consumable cathode 1 is directed completely towards the substrate 14.
The plasma flow of the evaporized material of the consumable cathode 1 i5 transported along the tubular anode 5 practically without any lo~es since the radial electric field prevent~ the drift of the ion component of plasma onto the walls of the tubular anode 5.

Claims (2)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:-
1. A vacuum-arc plasma apparatus, comprising:
- a tubular anode, - a consumable cathode with a working end portion and disposed within the tubular anode coaxially therewith;
- an igniting electrode for forming a cathode spot on the consumable cathode, disposed within the tubular anode;
- a solenoid, which:
- encircles the tubular anode and is disposed coaxially therewith, and - projects beyond the igniting electrode at the side opposite to the working end portion of the consumable cathode by a length exceeding half a length of the portion of the solenoid, disposed around the consumable cathode, and - has a number of turns per length unit of the portion of the solenoid, disposed around the consumable cathode, which exceeds the number of turns per length unit in the remaining portion of the solenoid.
2. An apparatus as set forth in claim 1, wherein the number of turns per length unit of the portion of the solenoid, disposed around the consumable cathode is at least two times greater than the number of turns per length unit of the remaining portion of the solenoid.
CA000378498A 1980-06-25 1981-05-28 Vacuum-arc plasma apparatus for producing coatings Expired CA1170315A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SU2933851 1980-06-25
SU802933851A SU1040631A1 (en) 1980-06-25 1980-06-25 Vacuum arc apparatus

Publications (1)

Publication Number Publication Date
CA1170315A true CA1170315A (en) 1984-07-03

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ID=20899404

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000378498A Expired CA1170315A (en) 1980-06-25 1981-05-28 Vacuum-arc plasma apparatus for producing coatings

Country Status (12)

Country Link
US (1) US4551221A (en)
JP (1) JPS6036468B2 (en)
BR (1) BR8103781A (en)
CA (1) CA1170315A (en)
CH (1) CH655632B (en)
DE (1) DE3152131C2 (en)
FR (1) FR2485863B1 (en)
GB (1) GB2092419B (en)
IT (1) IT1171327B (en)
SE (1) SE427003B (en)
SU (1) SU1040631A1 (en)
WO (1) WO1982000075A1 (en)

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Also Published As

Publication number Publication date
CH655632B (en) 1986-04-30
DE3152131C2 (en) 1986-09-04
SU1040631A1 (en) 1983-09-07
FR2485863B1 (en) 1986-12-12
WO1982000075A1 (en) 1982-01-07
FR2485863A1 (en) 1981-12-31
JPS57500931A (en) 1982-05-27
GB2092419B (en) 1983-12-14
SE427003B (en) 1983-02-21
JPS6036468B2 (en) 1985-08-20
IT8148744A0 (en) 1981-06-24
SE8200941L (en) 1982-02-16
GB2092419A (en) 1982-08-11
DE3152131A1 (en) 1982-08-26
BR8103781A (en) 1982-03-09
US4551221A (en) 1985-11-05
IT1171327B (en) 1987-06-10

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