CA1210320A

CA1210320A - Fracturing fluids containing bouyant inorganic diverting agent and method of use in hydraulic fracturing of subterranean formations

Info

Publication number: CA1210320A
Application number: CA000448886A
Authority: CA
Inventors: Robert B. Earl; Huy X. Nguyen; David B. Larson
Original assignee: Dowell Schlumberger Canada Inc
Current assignee: Dowell Schlumberger Canada Inc
Priority date: 1983-03-25
Filing date: 1984-03-05
Publication date: 1986-08-26
Also published as: GB2137262A; FR2543214B1; GB2137262B; GB8407369D0; FR2543214A1; NO841164L; US4509598A; NO163976B; NO163976C

Abstract

ABSTRACT OF THE DISCLOSURE

The growth of upward vertical fractures during a hydraulic fracturing process is inhibited or prevented by (1) initiating the fracture with a first fluid which is a pad fluid, and (2) extending the fracture with a second fluid comprising a carrier fluid and a bouyant inorganic diverting agent. The second fluid is preferably pumped at a minimum rate to extend the fracture and carry the diverting agent without screening out. After the diverting agent is implaced, a viscous pad fluid and fracture fluid are subsequently pumped at treatment rates and pressures to complete the fracturing process.

Description

2~ 1)3`2~

FRACTURING FLUIDS CONTAINING BOUYANT INORGANIC
DIVERTING AGENT AND ME~OD OF USE IN HYDRAULIC
FRACTURING OF SUBTERRANEAN FORMATIONS

This invention per~ains to certain compositions of matter and the use of such compositions in the hydraulic ~racturing of subterranean forma~ions penetrated by a borehole (welIbore.). More specifically, this in~ention relates to S compositions of matter and a method of controlling the direction of growth of fracture~ created during hydraulic fracturing.

Hydraulic fracturing is a well known stimulation technique used to recover formation fluids (e.g. oil and gas) from subterranean formations. In hydraulic frac~uring, a fracturing fluid is injected through a wellbore to the formation to be treated at a rate and pressure at least sufficient to initiate and/or è~tend a fracture into the ~ormation. Generally, a "pad ~luid" is injected initially to establish forma~ion breakdown (i.e., to initiate the f~acture.) and i~jectivity. The fracturing fluid usually carries a proppant into ~he fracture to hold the fracture.open once the external pumping pressure is relieved. The phy~ical requirements placed on the pad fluid and the subse~uent fracturing fluid are, in many 29,921-F ~ $

~ -2- ~ Z. ~3~

instances, differen~ and the fluids are optimized according to their intended function.

The fracture(s) created during hydraulic fracturing can take di.fferent configura~ions and orienta-tions., relative to th~ wellbore. Eve~ though con-siderable information is aYailable to the service company engineer designing the frac~uring treatment from well log~ing, field experience, and core analysis, most attempts to control the fracture have been limited to a selection o~ the zone to be fractured, the point of injection into the zone, and selection of the treatment ~luid and pump rates~ This results in a fracture geome~ry determined primarily by the prevailing geologic stresses in the formatio~ txeated, supplemented by the inhere~t.strength o~ ~he formation and i.ts composite mak~up~ .I the operator.is fortunate the fracture p~oce~d~ horizo~talIy within the pay zone. In ma~y instances, ~owever, th~ fracture proceeds vertically.

It is desirable to limit and control the ~0 extent of vertical frac~ures. Unless verti~al fractures are limited and controlled, th~re is a possibility of fracturing out of ~he pay zone and into a barren zone or into a zone bearing undesirable fluids (e.g. water or brine) which could cause.formation damage and con-tamination o~ fluids in each 20ne. In addition,fracturins 1uids consume~ in initiatIn~ and/or extending such unwa~ted verti~L ~ractures are wasted.

There ha~e been some prior attempts to control fracture geometry and/or ~o limit vertical fractures. For ex~mple, Hanson et al. (USP 3,151,678) described a fracturing process in which var.ious rates of injection were used a~d 29,921-F -2-.. ....

~3- ~112~ai3~2~

the proppant in the fluid acted both as a proppant ~o prevent closurF~ and as a semipermeable plug which closed off paths of least resistance. Hanson (USP

3 ,159, 217 ) also a~tempted to achieve more effective fractures by including in the fracturing ~luid certain solid pla~tically def~rmable charges or ~lugs having a density equaL ~o or differe~t ~rom the treatment fluia.
~anson said that the density of such charges could be increased by adding heavier weigh~ing materials ~e.g.
BaS04 and Fe203) or dLecreased by adding lighter weighting materials (e.g. cellulose or small hollow bodies, i.e., glass beads ) .

In an a~tempt to control the direction of ~he vertical l~racture up or down, Prater (USP 3,372,752) simultaneousl.y injected two or more fracturing fluids of dii~erent dengitie~ ~lonS3~ ~th a propp~t that matched th~-density Q~ on~ oi~ the fluids, e~g., water~
a~ a light oil containl~ aeratad glass beads having a specific gravity of about 0.7 (column 3, lines 319).

Ceramics having internal voids was described by Harold L. Graham and Othar M Kiel (USP 3,39g,727) as a proppant suitable~ ~or partial monolayer propping in ~racturing treatme~t. Included under the te~m ceramics were particles of glass, porcelain, or alumina 2~ con~aining. gas bubbles.

Braunlich (USP 3,335,797) taught a method for co~r~lling ~he do~nward growth of a vertical fracture by a mu-ltiple step fracturi~g process which selectively placed a heav~ proppan~ in ~he lower portion of a frac~ure and diverted subsequent fluids upwardly and horizontally. ~he co~cept of "similarly" preve~ting 29,921-F -3-` , ~4 ~2~3~ `

upward growth of vertical fractures using a bouyant material instead of the heavy proppant has been a topic of primary academic concern. See, for example, SPE
9260 (1980~; SPE/DOE 11637 (1983); and seminar paper SPE/DOE 11606 (1983) presented by J. D. M~Lennan et al.

The present invention resides in an improvement in the method of hydraulically fracturing a subterranean formation comprising the steps of: (1) initiating the fracture with a first fluid, and (2) extending the fracture wi~l a second fluid comprising a carrier fluid and an inert, bouyant, inorga~ic, diverting agent in an amount s~fficient',to i~hibi~ or prevent the growth of an upward vertical fracture. The second fluid, which i5 a new ~omposition'of matter, is injected through the wellbore and into th~ formation at a rate and pressure high enough:to extend the fracture and to carry the di~erting age~t i~to the fracture without screening ou~, b~t low enoug~ to permi~ th~ diverting agent to accu~ulate in ~he upper portion of ~he fracture and ~orm a com~acted barrier zone which is capable of diverting subse~uently injecte~ fluids downwardly and horizontaLly. The diverting agent has a specific gravity less than the carrier fluid and it is bouyant in ~he secoind fluid; because o~ this property, it ~orms the compacted barr~r zone within a short period of time, However, as added assurance that adequate time ha~ ~e~n pr w ided for ~he di~erti~ age~t to ~igrate upwardl~ the f~acture and form ~he compacted barrier zone, a compati~le third fluid i~ pre~erably injected~
~30 immediately a~ter the second fluid ln the fracturing process at a rate and pressure to accomplish ~he inte~ded result~ Usually, the injection rate and pressure is chosen to h:~ essentially the same for the second and ~9,921~F 4--5- ~z~32~

third fluids as a matter of operating convenience. The fracturing process is then continued by subse~uently injecting a viscous pad fluid an~ a proppantbearing or acid fracturing fluid at ract~re rates and pressure to extend the fracture.

Th~ novel process is most effective in fracturi~g pay xones bounded ~y ~ormations having in situ stresses less than or essentially the same as the pay zone. One me~hod of determining such stress contrasts is by creating one or more mi,crohydraulic fractures in ~he pay zone and in the bounding formations. In creating these microhydraulic- ~ractures, a minimum amount (e.g.
5~ gallons) of hydraulic fluid is injected at low rates until formation.breakdown and a smaIl amount of fracture extension occurc~ the well is shut in and the shutin pressure de~ermined;~ the shu~in pressure i~ an indication .~ the i~ si~,stres~:fiela.. ~his-process can be repeated a.number ~ times until.the,shutin pressure-stabilizes a~d ~ better ~statistically) value determined~ This known techni~ue i~ outlined by J. D. ~cLennan and J.C.
Roegier~ in SPE 11064 (1982). While the in situ stresses likel~ play the dominant role in fracture geometry, Young's ~odulus and other i~ situ mechanical characteris~ics of the ~orma~ion play a contributing but generally 2S .lesser role. Such factors ca~ be determined, if desired, via lab~ratory core tes~ing using known procedures.

The fir~t fluid is. a pad fluid. It is used to ini~iate the racture. Pad fluids, are well known.in the art..Aqueous pad.fluids are preferably used in this invention. Such aqueous fluids are usually water, light ~rines, dilute acids, or water thickened with a polymexic viscosifier (e.g. guar, hydroxypropylguar, 29~921-F . ~ -5~
.

6 ~.2~ 2~ .

.
- xanthan gum, polyacrylamide, hydroxyethylcellulose, and the like) or an oili~ater emulsion containing up to about 5 percent (vol/vol) of a light hydrocarbon (e.g.
kerosene~ diesel oil, Ptc.). The pad fluid is selected -to be compatible with the second fluid. For e~ample an agueous pad fluid would ucually be chosen over a hydroca~bo~base pad 1uid where an ayueous second fluid is to be used.

Th~ second fluid is a novel composition of m~tter. It comprises. a carrier fluid an~ a bouyant inorganic dive~ting-agent. The second fluld can also contain conventional.additives if desired, such as bacteri~ide~,. clay control agen~s (e.g. water soluble cationic polymers.)., f~uid los~ additives (e.g. silica 15. flour~, and the lik~.

Th~ c~rrie~.fluid.ca~ be a hydrocarbonbase flu~d, but it i~..preferably an.aqueousbase ~luid. Such agueous fluids are usually water, light brines, dilute acids, or water thickened with a polymeric viscosifier (e.g. guar, hydroxypropylguar, xanthan gum, polyacrylamide, hydroxyethylcellulose, and the like) or an oilinwater emulsion containing up to ~bout 5 perce~t (vol/vol) of a light hydrocarban (e.g. kerosene, diesel oil, etc.).
Thè carrier fluid preferably has a viscosity of ies~
than abou~ 20 centipoise at 20C; in general the more vis~ous ~he-carrier fluidr ~he~ longer it takes for the di~erting agent to migrate out of the second f~uid after implacement.in the fracture (e.g. fram a ~ew minutes to a fèw hours), but th~s factor is easily d~termined from a visual observation in single laboratory experiments.. Examples of such carrier fluids include: water; 5 weight percent (%) aqueous 29,921-F -6-.. .. . . .. _ . . . . . . . .. .. . .. . .

~7~ ~2~2~

solutions of guar or hydroxypropylguar, NaCl, ~Cl, or NH4Cl; aqueous 1%, 5% or 15% HCl, and the like.

The diverting agent used herein is likewise selected from a known class of particulate materials, any one (.ar mi~tur~) o~ whi~ can be used herein.
Preferred materials are glas~ or ceramic spheres or beads having a specific gravity less than about 1Ø
Glass or cera~ic spheres ~aving a specific gravity of from 0.6 to 0.7 are most preferred. It is also p.referred that. ~he diverting agent has a particle size of fro~ 70 to 120 mesh. The diverti~g agent is subjected to shear durlng. the proces~ as it passes through the pump(s.) a~d piping and injection into the formation.
It is also subjected to formation temperatures and ele~ated.pressure durin~ implacement and during the~
sub~equent ~racturing treabmen~. For the diverting a~ent to p~rform e~fec~ively, i~ must b~ essentially inert.to the carrier fIuid an~ relatively stable during mixing and iniectio~ in~o the formation and it must remain bouyant throughout the injection process into ~he ormation. This means that the diverting agent must ha~e a crush strength greater than the pressure applied during inj.ection. For example, the gla~s and ceram~c spheres used herein.are ~ypes o~ inorganic "ballons" which can be crushed, but generally have about 9095 p~rcen~ of original floaters in a given mass o~ di~rtin~ age~t i~ the carrier fluid at abmospheric condi~io~ and.hav~ a high.percentage (e.g. about 80~5 perce~t or more) floater~ after being subjected to a hydrostatic pressure of about 14Q kg/cm2 (2~00 psi).

The amount of diverting agent present in the second fluid can be varied to co~venience~ Because of 29,921-F -7--8- ~ æ 1o 32 0 the low bulk density of the material, it has been found convenient to blend the second fluid to contain from 30 to 120 kg~met3 (0.25 to 1.0 pounds of diverting agent per gallon~ of ~luid, total volume ba~is, but higher loading levels could be used. ~he second fluid re~uires -increasang amounts of hydraulic horsepower to pump the fl-uid.at any gi~e~ rate as the amount o~ diverting agent increases.

The particulate diverting agent can be blended with the carrier fluid using con~entional blending te~hniques. ~or ~xample, the diver~ing agent can be placed into a hopper and fed into a flowing s~ream of carrier fluid through a.solids metering sys~em (e.g. a starwheel feeder) and pumped through a pressure pump into.and through ~he~ txeatmen~ conduit; the turbulence of the fIo~in~ ~Iui~ i~ gener~lly sufficient to keep .th~ diYert~ng.agen~ ~uspe~ded during th~ injection pro~ess.

The total amount of second fluid injected can be varied to convenience, so long as sufficient diverting agant is implaced to divert subsequently injected fluids downwardly and horizontally and thereby inhibit or prevent the upward growth of a vertical ~racture.
Amo~nts of rom about 2.54 cm tl inch) or more ~f the diverting agent generally form an efective barrier ~one~

Th~ third fluid is optional in ~he process..
I~ used, it is selec~ed to be compa~ible with ~he second fluid and it i~ normally injected a~ essentially the same rate and pressure as the second fluid as a matte.r of operational co~venience. The purpose of 29,921-F -8-_ .. .. .

~2~C)3~

using the ~hird ~luid is to providP additional time for the divertin~ agent to migrate upward and form the barrier zone. The composition of this third fluid can be varied but, as noted above, it should be compatible with the second fluid, For example, if the serond ~luid is~ a~ aqueousbase ~luid, then the ~hird fluid is adva~tageously a~ a~ueousbase fluid. ~s an operational convPnience, the~ ~hird fluid is generally the same composition as the second fluid e~cept without the diverting agent.

A~ter the second fluid (or optional third fluid~, a ~iscou5- pad fluid and a fra turing fluid are injected at fractuxe rat~s and pressure. The composi-tions of the pad fluid and fracture fluid are con~en-tionaL. The pad fluid i5 usually a clear fluid (i.e.without proppa~t) an~ is preferably a~ aqueousbase fluid~ he form~of a geIIed liquid or foam. Th@
fracture ~luid.is also preferably an aqueousbase fluid For proppan~bearing fracture fluids, the fluid is usually in ~he form of a gelled liquid or foam. The gelled liquids usually contain a polymeric gelling agent (e.g. guar, ~ydroxypropylguar, hydroxyathyl-cellulose, etc.) i~ crosslinked or uncrosslinked form.
The pH of thes~ flulids can be acid, neutral or basic.
For frac~ure acidizing treatments, which are encompassed in thi~ inven*ion, ~he fracture ~luid is usually a clear liquid (without proppant) in gelled or ungelled ~orm and ~s usually aqueous hydrochloric (HC13 acid of up to abou~ 28 perc~nt HCl. The selection of ~olumes, i~jection rates, and pressures for ~he pad fluid and fracture fluid are within the skill of the service company engineer desig~ing the fractuxe ~reatment.
~owever, it has baen found advantageous to inject the ~9,921-F _g -10- ~2~03~

viscous pad fluid at gradually increasing rates and pressures (relative to the previous second or third fluid) until fracture rates and pressures are reached.
This latter technique seems to protect the barrier zone of diverting agent.

Experimental A well in the ~ancos formation was treated by:

"~ ,. 1. Injecting llS355 li~ers (3000 gallons) af a pad fluid consis.ting of water thickened with 5 weight.percent of.a polyme~ic viscosifier (i.e. hydroxy-prop~lguar), hereafter called WF5, at a rate of 1.1 `' met3/min (7.barrels per minute, BPM) to cause breakdown and establi~h.injectivity.

2. Iniecting ~ second fluid consisti~g of WEC with various amou~ts of c~rtain alumina silicate microspheres. Tha microspheres had a specific gravity o~ from Q.6 to 0.7, a bulk density of about 448 kg/met3 (28 pounds per cubic foot), and 95 percent of the material had a mesh size of from 70 to 120 mes~h, and atleast 95 percent of ~he material were classified as "original floatars" in the WF5 at atmospheric conditions.
This diverting agent also passed the hydraulic stress t~s~ wi~h o~er 85 perc~nt o~ the microsph~res survi~ing as ~Iaaters i~ ~lydrauli~ pressure testing at 140 kg/cm2 0 psi).

The second fluid was injec~ed in stages:
3785 liters (1000 gallons) of fluid containing 112.5 kg ~250 pounds) of diverting agent/ 3785 liters (1000 gallons~ (#/1000) of fluid at 1.1 met3/min; 18g2.5 29,921-F -10- .
, 21~3~

liters Q~ fluid containing 500 ~/lO00 at 1.1 met3/min.
and 5677.5 liters of fluid containing lO00 #/lO00 at 0.477 met3/min.

3.. A third fluid, 7570 liters of WF5, was in3ec~ed at 0.477 met3/min~

4. A ~iscous aqueous pad fluid 113.5 met3 (30,000 gallons) and fracture fluid 197 met3 (5~,030 gallons) were ~hen injected at 3.18 met3/min (20 BPM).
.The pad fluid contained 13,5.90 kg (30,000 pounds) of a fluid loss additive (lO0 mesh sand~ in a commercial a~ueous base fluid sold by Dowell Division o The Dow Chemical Company under the designation: Dowell~ "YFC02", but it contained ~0,7~0 kg (135,000 pounds) of 20/40 mesh sand as proppant. The proppan~ was added in .stages.ranging in conce~rations o~ from 1000 #/lO00 initially t~ 4000 #/lO0~-in the final 56,775 liters ~ ,QOa gallon~.) o~ tha;fracture ~luid~ The Dowell "YFCo2"~is an aqueousbase fluid~containing a polymeric viscosifier (i~e. guar or hydroxypropyiguar) in amounts of about 40 ~/1000 (in this treatment) crosslinked with a conventional o~gano metallic crosslinkers, viscosity breakers, bactericides., etc. and about 25 volume percent of the DoweIl 'IYFC02'l was carbon dioxide (measured as a liquid). A~ter the proppan~beari~g ~racture fluid, ~he well was shut i~ or ~ period and 1owed back in a conventional manner.

Reg. T~

29,921-F

_ . ._ .. _. ..... .

Claims

1. A method of hydraulically fracturing a subterranean formation penetrated by a wellbore by injecting a fracturing fluid through the wellbore and against the formation at a rate and pressure at least sufficient to initiate and/or extend a fracture into the formation, comprising: (1) initiating the fracture with a first fluid which is a pad fluid; and (2) extending the fracture with a second fluid comprising a carrier fluid and a bouyant inorganic diverting agent in an amount sufficient to inhibit or prevent the growth of an upward vertical fracture; said second fluid being injected through the wellbore and into the formation at a rate and pressure high enough to extend the fracture and to carry the diverting agent into the fracture but low enough to permit the diverting agent to accumulate in the upper portion of the fracture and form a com-pacted barrier zone which is capable of diverting sub-sequently injected fluids downwardly and/or horizontally.

2. The method of Claim 1 comprising the additional step of further extending the fracture by subsequently injecting a third fluid compatible with said second fluid into said fracture.

3. The method of Claim 1 or 2 comprising the additional step of further extending the fracture by subsequently injecting a proppantbearing fracturing fluid or acid fracturing fluid into said fracture at fracture rates and pressures.

4. The method of Claim 1 wherein said second fluid is an aqueousbase fluid.

5. The method of Claim 4 wherein said second fluid comprises a carrier fluid having a vis-cosity of less than about 20 centipoise at 20°C.

6. The method of Claim 1 wherein said diverting agent comprises glass or ceramic spheres having a specific gravity less than about 1Ø

7. The method of Claim 6 wherein said spheres have a specific gravity of from 0.6 to 0.7.

8. The method of Claim 1 wherein said diverting agent has a particle size of from 70 to 120 mesh.

9. The method of Claim 8 wherein said diverting agent is alumina silicate microspheres having a particle size of from 70 to 120 mesh.

10. A method of hydraulically fracturing a subterranean formation penetrated by a wellbore by injecting a fracturing fluid through the wellbore and against the formation at a rate and pressure at least sufficient to initiate and/or extend a fracture into the formation, comprising: (1) initiating the fracture with a first fluid which is an aqueous pad fluid, (2) extending the fracture with a second fluid comprising (a) an aqueous carrier fluid having a viscosity less than about 20 centipoise at 20°C, and (b) a bouyant inorganic diverting agent having a specific gravity of less than about 1.0, said second fluid being injected through the wellbore and into the formation at a rate and pressure high enough to extend the fracture and to carry the diverting agent into the formation but low enough to permit the diverting agent to accumulate in the upper portion of the fracture and form a compacted barrier zone which is capable of diverting subsequently injected fluids downwardly and/or horizontally, (3) further extending. the fracture with an aqueous third fluid which is compatible with said second fluid and is injected at essentially the same rate and pressure as said second fluid, and (4) further extending the fracture by injecting an aqueous proppantbearing or acid fracturing fluid at fracture rates and pressure.

11. The method of Claim 10 wherein said carrier fluid is water or an aqueous solution containing up to about 5 weight percent of a polymeric viscosifier, NaC1, KC1, NH4C1 and/or up to about 15 weight percent HC1 and wherein said diverting agent comprises glass or ceramic spheres having a specific gravity less than about 1Ø

12. The method of Claim 11 wherein said diverting agent is alumina silicate microspheres having a specific gravity of from 0.6 to 0.7 and a particle size of from 70 to 120 mesh.