CA1272364A

CA1272364A - Device for connecting elongate objects

Info

Publication number: CA1272364A
Application number: CA000467194A
Authority: CA
Inventors: John A. Gadsden; David E. Barnwell
Original assignee: Raychem Ltd
Current assignee: Raychem Ltd
Priority date: 1983-11-08
Filing date: 1984-11-07
Publication date: 1990-08-07
Anticipated expiration: 2007-08-07
Also published as: EP0235833A1; EP0141675A1; US4896904A; EP0141675B1; GB2149468B; DE3470933D1; GB8428177D0; GB2149468A

Abstract

ABSTRACT

DEVICE FOR CONNECTING ELONGATE OBJECTS

A device for connecting objects such as rigid pipes that are used to convey fluids. The device comprises a heat-shrinkable tube (10), one portion of which may be partially recovered (11). Inside the tube is located a bonding insert (13) of thermosetting r adhesive, which is attached to a barrier insert (12).
The two pipes to be connected are inserted into either end of the tube such that one pipe fits snugly within a swaged-open end of the other pipe. The device is then heated causing the tube (10) to recover and the bonding insert (13) to melt and flow into the connection between the pipes. The barrier insert (12) prevents the adhesive of the bonding insert from flowing away from the connection.

Description

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Raychem Limited - 1 ~ RK217COM

Device for Connecting Elongat~ Objects This invention relates to forming joints between bodies for example pipes, especially riqid pipes, that are used to convey fluids.

In many instances it is necessary to couple rigid pipes of small diameter, for example, a diameter of from about 2 to 50mm, which are used in connection with ; electrical or mechanical equipment, for example in domestic and in~ustrial refrigeratlon or air condition-ing units or in hydrauIic systems. These joints often need to function effectively under severe conditions, for example where fluids are conveyed along the pipes at elevated temperatures and pressures, for example, sometimes up to 150~C and 40 atmospheres pressure, and where the pipes are under considerable stress, for example due to vibration of moving parts of the equip-ment or thermal expansion. For this reasonr such pipes ~; have hitherto usually been joined by means of metal screw-fit coupling pieces which are expensive and ,:
require the pipe-ends to be screw threaded, or by brazing which is a skilled and time consuming process.

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In addition, the use of brazed pipes ha~ the disa~dvantage that i~
th,y fail in use, e.g. if a leak occur~ in the brazed joint, it is relatively di~ficult to repair the join~ by brazing, especially in the case of dom~estic equip~ent where the repair will need to be carried O-lt in, for example, a domestic Xltchen.
The present invention provides a devlce ~or forming a sealed connectlon between a ~ir~ fluid-conveylng plpe ~nd a ~econd fluid-conveying plpe in which an end region of the second pipe is in~erced into an end of the first pipe to ~orm an overlap region between the pipes, which device comprises a hollow, open-ended polymeric tube that is at least partly heat-shrinkable, at least one bonding insert formed from a solid, fusible, thermosettiny adhesive, the bonding insert being located in~ide, and supported by, the heat-shrinkable tube, and at least one barrier insert located inside the ~ube ad~acent to the bonding in~ert and supported by the tube, ~uch that when the device is positioned around ~he overlap region be~ween the pip~e~ wlth ~he inser~s adjaceDt to the exterior surface o~ the second pipe and the bondiny insert abutting the end of th~e firs~ plpe, and the device is heated, the tube reeover~ and the thermosetting adhe~ive of the bonding insert fuses, the barrier insert restricting flo~
o~ the adhesive away from the overlap region so that the adhesive flow~ in~o the overlap reyion via the end of the firs~ pipe to form a permanent bond between the fluid-conveying pipe~.
In most cases either both hollow objects will b~e, rlgid pipes, for example where a swa~ed joint i~s to be ~orme~d, or one object will be a pipe and the other will ba a coupling piece f ~4, I

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therefore. The pipes may ini~ially have dimen3ions such that one pipe may be ln~erted within the other or they may have substantially the same dimen~ions, in which ~ase either a co~pling pieae will be required or the end of one pipe will be swaged open to receive the other.
~ he pipes ~ay be joined simply by inæertiny the end of one of the pipes within the end o~ the other, posltioning a devlce according to the invention about the pipes so that the bonding inser~ is axially located at or adjacent ~o ~he end of outwardly loca~ed pipe, recovering the devic~ about the pipes and heating the bonding insert to cause the thermosetting adhesive to ~elt and flow between the ends of the pipes.
The inventlon has the advantage that lt enables a joint to be formed ~rom a %tructural adheslve without the necesslty of any ~igging to retaln the jolnt as the adhesive sets. In most cases the joint w111 have sufficient stren~th as soon as it has been formed to allow the pipes (or other objects3 to be used or ~o allow further manufacturing opera~ions to be conducted on the equlpment containing the~ without the risk of fallure of the joint. This i6 particularly important in automated production processes where only a short period of time may be allocated to each operation.
A fur~her advantage o~ the invention is that it enables pipe~ made of different materials, for example copper, steel and alu~lnium plpes, ~o be easily connected together. Prior to thls lnvention such a connection involved aomplex brazing or other difficult and/or expensiye techniques.

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In addi~ion the tube ruggedisqs the ring of ther~oisetting adhe6ive and, when the device is being instialled, the recoYery of the tube about the adhesive provides some force to ~queeze the adhesive between the ; 3a . . j"

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pipes and so increases the reliability of the connect-ion. Moreover, since the operations required in order - to install the device are relatively simple and straightforward, the quality of the completed joint is relatively independent of the skill of the operator.

In many instances the device will be intended to be used to couple a male pipe that is to he inserted within a female pipe in which case the device is preferably arranged so that the barrier insert is located adjacent to the bonding insert and on that side of the bonding insert which is remote from the female part or will, in use, be remote from the female part, of the joint, so that the barrier insert will be caused to contact the male part of the joint. In this way, recovery of the heat-recoverable tube will ;~ force the fused thermosetting adhesive between the male and the female parts of the joint while the barrier insert restricts the fused thermosetting adhesive ~: from flowing away from the joint.
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Preferably the or each barrier insert is fusible or deformable at the temperature required to produce an ade~uate level of cure in the adhesive of the bonding insert.

When the device is being installed, heat is applied causing the adhesive of the bonding insert to ~ melt and to start to cure. Heating is maintained until ; the adhesive reaches a certain temperature (hereinafter referred to as the optimum temperature) which, after ; allowing the 3dhesive to cool, results in an adequate level of cure. By adequate level of cure is meant at .

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least 40~ gel, preferably at least 50~ qel and more preferably at least 70% gel in the cured adhesive. The value of the optimum temperature depends for example, upon the nature of the adhesive and the time allowed 5 for heating the adhesive. Preferably heating times are less than S minutes r and more preferably less than 1 minute. The optimum temperature for epoxy adhesives~
for example, is usually in the range of 100-220C, more usually 150-200C and especially 165-195C. It is, however, difficult for the installer to determine when the adhesive reaches this optimum temperature and thus that sufficient heat has been supplied. The material of the or each barrier insert of the present invention is thus selected such that it will fuse at or near the optimum temperature in order to give a visual indica-tion to the installer that sufficient heat has been supplied to the device. Preferably the barrier insert material is chosen such that it will fuse within 10C
of the optimum temperature, more preferably within 5C.
It is especially preferred that the material will fuse just below the optimum temperature.

Preferred barrier inserts have a relatively sharp melting point, by which is meant a melting point range of no more than 40C, preferably no more than 20C, and especially no more than 10C when measured by a Differ ~ential Scanning Calorimeter at a heatinq rate of 10C
per minute. In addition to giving a precise visual - indication that the optimum temperature has been reached, a sharp melting point enables the barrier insert to remain solid up to a relatively high temper-ature so that it acts as a barrier to prevent the fused thermosetting adhesive flowing away from the .
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joint. It is also possible, however, to have two separate inserts in the device, one as a barrier to the adhesive and the other as a temperature indicator.

Alternatively~ or in addition to this method of visual indication, a thermochromic indicator, such as a thermochromic paint, may be applied, for example, to the outer surface of the dimensionally recoverable tube or to the outer surface of the barrier insert.
The thermochromic indicator is be chosen such that it changes colour when the optimum temperature is reached.
Another method of providing a visual indication that the optimum temperature has been reached is to choose a thermosetting adhesive that changes colour on curinq.

Preferably each barrier insert is attached to its respective bonding insert in order to facilitate i handling of the thermosetting adhesive during manufac ture of the device.

Preferably the barrier insert is in the form of a ring having a ~lange portion that extends axially from the periphery of the ring so that the barrier inser~
extends over one end face and over the outer circum-ferential surface of the bonding insert. To facilitate manufacturing, it is preferred that the outer wall of the ring portion of the barrier insert is tapered so ; 25 that the ring is frusto-conical in shape. The bondinq insert may be bonded to the barrier insert, for example by means of a pressure sensitive, contact, cyanoacryl-ate or anaerobic adhesive or the two inserts may be so formed to enable the bonding insert to be pushed into .A~, '. ~

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the barrier insert and held by friction. The use of such a barrier insert enables the manufacture of the devices to be facilitated since it will protect the relatively fragile thermosetting adhesive from mechan-ical abuse before and during manufact:ure. In additionthe barrier insert significantly improves the robust-ness of the manufactured device since it reduces or eliminates the likelihood of the thermosetting adhesive ring breaking when the connector is mishandled, e.g.
when it is dropped or severely squeezed.

Preferably the or each of the barrier inserts is conformable to the shape and/or size of the object to be connected, in which case it is preferably formed from a fusible material having a melt viscosity suf-ficiently higher than that of the thermosetting adhesive to prevent egress of the fused thermosetting ; adhesive, but low enough such that it will flow upon fusing, allowing the heat-recoverable tube to recover further onto the pipe,~giving a clear visual indication that installation is complete, or it is formed from a heat-shrinkable polymeric material, and preferably one that has a recovery temperature close to or below ~ that of the recoverable tube. Suitable materials that : may be used to form the barrier inserts include, for exampler non-crosslinked thermoplastics such as poly-amides, low, medium or high density polyethylene, ethylene copolymers, e.g. ethylene/vinyl acetate copolymers or polyvinylidene fluoride. Nylon 11 and nylon 12 are especially preferred materials. Alter-natively the barrier insert may be formed from a crosslinked polymeric material which will become sufficiently soft to deform under the recovery forces ~ , . .
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of the recoverable tube without melting when the device is heated.
As stated above~ the tube is dimensionally-recoverable.
Preferably it is dimensionally heat-recoverable. Heat-recoverable articles may, for example, be produced by deforming a dimensional-ly heat-stable configuration to a dimensionally heat-unstable configuration, in which case the article will assume, or tend to assume the original heat-stable configuration on the application of heat alone.
According to one method of producing a heat-recoverable article the polymeric material is first extruded or moulded into a desired shape. The polymeric material is then cross-linked or given the properties of a cross-linked material by means of chemical cross-linking initiation or by exposure to high energy radiation, for example, a high energy electron-beam or gamma ~radiation. The cross-linked polymeric material is heated and deformed and then locked in the deformed condition by quenching or other sui~able cooling methods. The deformed material will retain its shape almost indefinitely until exposed to a temper-ature above its crystalline melting temperature, for example about 120C in the case of polyethylene. Examples of heat-recov-erable articles may be found in United States Patent Specification No. 2,027r962 and United Kingdom Patent Specification No. 990,235.
As is made clear in United States Patent No. 2,027,962, however, :
the original dimensionally stable heat~stabla configuration may be a transient form in a continuous process in which, for example : ' ' , - ~ :
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ii'~k an extruded tube is expanded, whilst hot, to a dimensionally heat unstable form.
Where the device is dimensionally heat-recoverable it may be easily arranged so that the heat applied to the device to cause it to recover will also cause the thermosetting adhesive to melt and flow.
In one preferred arrangement of the device, a portion of the recoverable tube at or near one end region thereof, pre-ferably the end next to the barrier insert, is partially reco~er-ed. This arrangement is especially advantageous when two pipes of differing diameters are to be connected.
The material for forming the tube is preferably formed from rigid plastics ~as defined in ASTM 883-75a) and those semi-rigid plastics having an elastic (Young's) modulus of at least 250 MPa. Such materials usually have a yield strain of at least 10% and generally not more than 100%. Rigid and semi-rigid plastics as defined above that are capable of being rendered dimensionally-recoverable and are therefore suitable for forming ;~ the tube include polyolefins, for example, low or high density polyethylene, polypropylener ethylene copolymersl for example with propylene, butene, vinyl acetate or ethyl acrylate, poly-esters, polyether sulphones, polyphenylene oxide, polyvinyl chloride and fluoropolymers for example polychlorotrifluoroethy-lene, polytetrafluoroethylene and polyvinylidene fluoride, or polyamides, such as those described in British Patent Application No. 2l088,397AI which was published in June 1982, for example :~

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nylon 6,6, nylon 6,10, nylon 11 and nylon 12. Preferred materials for forming -the tube are those having an elastic (Young's) modulus of at least 500 MPa especially at least lGPa, more especially of at least 2GPa, a yield s-tress of from 5 to 75 MPa, especially from 40 to 60 MPa, and an ultimate tensile strength of at least 10 ~Pa, especially at least 30 MPa. The most preferred materials are polyvinylidene fluoride and nylon 11 or 12.
Preferred thermosetting adhesives for use as the bond-ing insert include phenolic adhesi~es, e.g. B-staged phenolic adhesives, or p.referably epoxy adhesi~es. The epoxy adhesive may be a s-staged adhesive. Preferably, however, the epoxy is a latent cure adhesive, and the epoxy resin and the curing agent may exist as separate particles that are mixed together as des-cribed in British Patent Application No. 2,104,800A which was published in March 1~83. Whatever thermosetting adhesive is used, it preferably has a minimum melt viscosity in the range of from 25 to 400 poise, especially from 50 to 250 poise and most espec-ially from 100 to 175 poise during the installation of the device.
The melt viscosity may be measured using a Ferranti Shirley cone and plate viscometer fitted with a small cone and measuring the viscosity at 5 cycles per minute. Preferably the adhesive has a melting point of not higher than 160C, more preferably not higher than 120C and especially not higher than 100C. Preferred adhesives are those that will cure, or at least begin to cure within 5 minutes, preferably within 1 minute and especially with-in 30 seconds at 150C. Also, it is preferred for the adhesive *
i,~, ~ 27065-9 to have a storage life at 23C of at least 1 year.
Preferably the dimensionally-recoverable tube has a quantity of adhesive on at least part of its inner surface to provide at least a temporary bond between the tube and at least one of the elongate objects. This quantity of adhesive is pre-ferably a hot-melt adhesive, most preferab]y an adhesive having a melting point below 175C. Preferably the adhesive has a rela-tively high melt viscosity, e.g. a melt viscosity in the range of from 1500 to 3000 poise and especially from 1750 to 2250 poise at 180C. Alternatively or in addition it is pre~erred for the adhe-sive to have a ring-and-ball softening point of at least 100C, more preferably at least 125C and especially at least 150C, and to exhibit a lap shear strength to metal substrates, e.g.
aluminium, steel or copper, of at least 20N (25mm) 2 at 100C
and at least 100N (25mm) 2 at 23C. In addition it is desirable for the adhesive to be resistant to fluids commonly found in such environments, e.g. compressor oils, halohydrocarbon refrigera~ts, water, detergents and the like. The preferred hot melt adhesives are polyamide adhesives and especially the adhesives described in United States Patents Nos. 4,013,733 to LopeZ et al and 4,181,775 to Corke.
Other adhesives that may be used include vinyl and acrylic homo- and copolymer, polyester and polyolefln hot-melt adhesives or thermosetting adhesives, for example those based on epoxy-polyamide, epoxy-phenolic, epoxy-nitrile rubbers and one-part resin films.
If desired a small protective tube may be provided over at least part of the layer of additional adhesive 1 ' ' :
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in order to allow easy removal of the mandrel on which the device i~
for~ed during ~anufacture. Thls protective tube is especially required if the dimensionally recovarable tube is partially recovered. The protective tube may be an extension of the barrier insert, for example a tubular portion that extends axially from the barrier insert ring on the opposite side o~ ~he ~lange portion.
Suita~le matarials for ~he protective tube include polyamide, especially nylon 11 and nylon ~2, or polyvinylidene fluorlde, which may be uncros~-linked or cross-linked.
The recoverable tube preferably has an initial wall thickne~s (that is, wall thickness before expansion) o~ a~ least O.lmm. The maximum wall thickness is usually determined by the ab$1ity of thick-walled tuhes to recover when heated. This will depend on a number of factors including the diameter of the tube and the polymeric material used to form it. The tube preferably has an initial wall-thickness of not more ~han 3mm and especially an initial wall-~hickness of from 0.25 to 0.75mm.
~ ccording to another aspect of the inventlon disclosed, there is provided a devlce ~or connec~iny a plurality of elongate objec~s, which comprises a rigid open-ended tube that is capable of being joined to the elongate objects to form a connection between tha object~, the tube having at least one dimensionally recoverable skir~
ln the region oi an end thereof which is capable of being recovered about the ~oin between ~he rigid tube and one of the objects, the de~ice having a bonding insert formed from a solid, fusible, thermosettin~ adhesive for providing a per~anent bond bet~een the rigid tube and the objec~.

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Preferably the rigid tube is provided with a skirt and a corresponding bonding insert in the region of each end thereof so that each joint between the rigid tube and an object will be enclosed by a recovered skirt. If the rigid tube is intended to be positioned over the ends of the objects to be connected, the skirt or skirts may have substantially the same ~iameter as that of the rigid tube and may simply form axial extensions of the rigid tube. If, however, the ends of the rigid tube are intended to be positioned within the ends of the pipes to be connected, the skirt or skirts should extend around the ends of the rigid tube and be separated therefrom by an annular space which receives the ends of the pipes.

This form of device is particularly useful for forming ln situ repairs in existing pipes, for example in domestic equipment or in installed pipework in which the installed pipe has failed, for example due to a faulty joint or where the pipe has burst. The pipe ~-~20 may be repaired simply by cutting out an appropriate -length of the failed pipe, and then connecting the remaining pipes by joining the end of each of the pipes to an end of the open-ended rigid base, recovering the or each skirt about the rigid tube and its respec~ive pipe, and heating the or each bonding insert to cause the thermosetting adhesive to melt and flow between the rigid tube and the pipe joined thereto. As described above, it i~ preferred for the or each skirt to be heat-recoverable so that the heat applied to the device to cause the skirt or skirts to recover will also cause the adhesive to melt.

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--Preferably the or each skirt also contains a barrier insert to restrict flow of fused thermosetting adhesive away from the connection when the device is heated. Preferably the or each skirt has a quantity of an additional adhesive, especially a hot-melt adhesive as described above, on its inner surface for forming at least a temporary bond between the tube and the pipe.

The thermosetting adhesive, barrier insert, additional adhesive and the heat-recoverable material forming the skirt are both preferably the same as those described above. In the preferred form of device the skirts are formed by partially recovering one or more connector devices described above onto the rigid tube.
J' The rigid open-ended tube may, if desired, have an internal or external shoulder in order to limit the extent of insertion of the pipe within the rigid tube ; or vice versa. The rigid tube may be formed from a rigid composite, in which case the shoulders may be formed when the tube is moulded, or it may be formed - from a metal, e.g. copper or steel, in which case the shoulders may be formed by swaging the ends of the tube outwards or inwards.

At least one and preferably each end region of the rigid tube is flared outwards to aid flowing of the fused thermosetting adhesive between the rigid tube and the pipe to be connected.

The fIared end region is preferably in the form of a frusto-conica~ portion in which the wall of the rigid ''~', .

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tube tapers outwardly in a direction toward the end of the rigid tube at an angle in the range of from 0.5 to

2, especially from 0.75 to 1.S and most especially about 1 to the axis of the rigid tube. Preferably the axial length of the frusto-conical portion is at least 6 and more preferably at least 9 mm but usually not more than about 20 mm, the optimum length being about 12 mm.

In addition to the frusto-conical portion, the end of the rigid tube is preferably in the form of a frusto-conical lip which is located adjacent to the frusto-conical portion, and also tapers outwardly toward the end of the rigid tube to a greater extent, for example at an angle of from 10 to 40, especially from 15 to 30. The axial length of the lip is prefer-ably in the range of from 1 to 4 mm, especially from 1.5 to 3 mm and most especially about 2 mm. This frusto-conical lip enables a relatively thick fillet of thermosetting adhesive to form at the lip when the device is installed, which reduces the stress concen-trations at the end of the joint.

Preferably the end of the said frusto-conical portion nearest the centre of the rigid tube is adjacent to a cylindrical portion of the rigid tube of constant diameter, the cylindrical portion having a diameter such that it can receive the pipe to be joined with a snug fit. The cy]indrical portion may have the same diameter as the central region of the rigid tube or it may be of slightly larger diameter and be joined to the central region by an internal shoulder~

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According to another aspect, the invention pro-vides a kit for connecting a plurality of elongate objects which comprises a rigid hollow open-ended tube and a plurality of dimensionally recoverable tubular sleeves each of which contains an insert formed from a solid, fusible thermosetting adhe.sive, each sleeve being capable of being positioned about the rigid tube and end of one of the objects and recovered thereon so that the thermosetting adhesive forms a permanent bond between the rigid tube and object. Preferably the or each sleeve comprises a device according to the first aspect of the invention. The rigid tube is preferably identical to that described above.

The above invention has been described with reference to connecting two hollow pipes. However other elongate bodies may also be connected with the device, an example being a connection between a hollow pipe and a solid plug. Also more than two elongate objects, for example three or four objects, may be connected together using a device according to the invention.

In a further aspect the invention provides a device for terminating a hollow object which comprises a rigid element for closinq the hollow object, the rigid element having a dimensionally recoverable s~irt in the region of an end thereof and capable of being recovered about the ~oin between the rigid element and the object, the device having a bonding insert formed - from a solid, flexible, thermosetting adhesive for -30 providing a permanent bond between the element and the object.

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By hollow object is meantl for example, a pipe or an outlet, and by rigid element is meant, for example, a tube with a closed end or a solicl plug. In other respects the device according to this aspect of the 5invention is as described above.

Several devices in accordance with the present invention will now be described by way of example with reference to the accompanying drawings in which:

Figure 1 is a sectional elevation of a form of 10connector device in accordance with the invention;

Figures 2 to 5 illustrate the use of the device shown in figure 1 for forming a connec-tion between a pair of pipes;

15Figure 6 i5 a sectional elevation through one form of barrier insert used in a connector according to the invention;

Figures 7 and 8 are sectional elevations through various forms of connector according to 20the inventlon;

Figures 9 to 14 illustrate further embodiments of the invention, each incorporating a rigid tube.

Figure 1 shows one form of device which comprises .25 a hollow heat-shrinkable, cross-linked polyvinylidene :fluoride tube (1) which has a recovery temperature of ;
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approximately 165C, and lining of polyamide hot~melt adhesive (2) along the entire length of the tube 1.
The tube contains a bonding insert (3~ in the form of a ring of a solid, fusible, epoxy adhesive bonding insert having a melting point of approximately 80C and an initial curing point of approximately 105C, and an annular, solid fusible barrier insert (43 which is made of nylon 12 and has a melting point of approximately 177Co Although the bonding and barrier inserts may be separate, as shown, it is preferred that there is substantially no gap between the two inserts.

Figures 2 to 5 show a method of connecting a pair of pipes (5) and ~6) by means of the device shown in figure 1. The end of pipe (5) is first swaged open to receive pipe (6). Preferably the end of pipe (5) is swaged open to a similar configuration as that o the end regions of the rigid tube (35) in figure 14. Then, after slipping the device over the end of pipe (6), pipe (6) is pushed into the end of pipe (5), and the device is then moved axially along pipe (6) untiI the bonding insert 13) is adjacent to the end o~ pipe (5) as shown in figure 3. The size of the device may conveniently be such in relation to the diameter o pipe (5) that when the device has been moved to its 2S correct position, the end of pipe (5) abuts ~he epoxy ring. When the device is in the correct position, it is simply heated by means of a hot air gun to cause the tube (13 to recover, the hot-melt adhesive ~2) to melt and form a bond to the pipes (5) ana (6), and the :~ 30 bonding insert to melt and flow between the pipes, as shown in figure 4. At this stage the barrier insert

(4) remains solid and prevents the ~used epoxy adhesive from flowing along the pipe (5) away from the connec-tion and forces the adhesive towards the connection to form a permanent bond between the two pipes Further ' , - l9 - RK217COM

heating, giving a total heating time of under 1 minute, causes the barrier insert (4) to melt and flow, as shown in figure 5, indicating that an optimum temperature of approximately 177C has been reached.
The tube (1) recovers further over 1:he melted barrier insert (4) and thus the installer knows that sufficient heat has been supplied to the device.

Figure 6 shows a barrier insert made, for example, by in]ection moulding, and formed from nylon 12 havinq 10 an ou~er diameter of 10.5mm and a bore of 6.45mm. The barrier insert comprises an annular portion (8) of 1.5mm wall thickness and a flanqe portion (9) of 0.75mm radial wall thickness and 2.5mm axial ~ength. A
thermosetting adhesive, preferably epoxy, rinq (not shown) is positioned within the barrier insert so that it fits snugly inside the flange portion and one end ' face thereof abuts the inner side face of the annular portion (8~, the other end face of the adhesive insert preferably being flush with the end of the flange portion (g)~

Figure 7 shows another form of device for forming a direct joint between two pipes wherein one pipe is of small diameter than the other pipe. The device comprises a heat-shrinkable tube (10) formed from cross-linked polyvinylidene fluoride, of which one end ~11) has been partially recovered for easier fitting around the pipe of smaller diameter. The tube (10) and (11) is provided with a thin layer of polyamide hot-melt adhesive (not shown) on its inner surface. A
nylon 12 barrier insert (12) of the form shown in figure 6, is located within the tube (10) adjacent to the partially recovered portion (11~, and an epoxy ~3~L

bonding insert (13) is positioned within the barrier insert (12). If desired a small protective tube (14) of uncoated, thin walled recoverable material may be provided between the heat recoverable tube (10) and (11) and the barrier insert (12) in order to allow easy removal of the mandrel on which the device is formed during manufacture. In order to form a joint, the device is slipped over the end of one of the pipes and after the pipe ends have been pushed together the device is positioned over the joint so that the end of the larger pipe abuts the exposed end face of the bonding insert ~13) or the end edge of the flanqe portion of the barrier insert (12). The device is then heated as described above.

The device shown in figure 8 comprises a tube (15) which has been partially recovered (16) and (17) around the barrier insert ~12). In this device a protective tube (18), which prevents the inner layer of adhesive (not shown) on the recovered portion (16) of the tube from sticking to the mandrel during manufacture~ is formed as an integral part of the barrier insert and is made from nylon 12.

Figure 9 shows a form of device according to the invention in which a heat-shrinkable polyvinylidine -fluoride sleeve (19) which is provided with an internal lining of a polyamide hot-melt adhesive tnot shown), is located over a rigid copper tube (20). The sleeve (19) is longer than the rigid tube (20) so that the ends of the sleeve (19) extend beyond the ends of the rigid tube (20) in the form of a pair of skirts (21), (22).
An epoxy bondin~ insert ~23) i5 located within each :~3~

skirt adjacent to the end of the rigid tube ~20). In - this embodiment, the pipes to be connected are simply pushed into each end of the skirts (21),t22) and the device is heated, causing the heat-shrinkable skirts to recover onto the pipes and causing the bonding inserts to melt.

Figure 10 shows the device of figure 9 with barrier inserts (24) formed from a thermoplastic material or a heat-shrinkable material located within 10 each skirt (21),(22) adjacent to the bonding insert (23) and on that side of the bonding insert remote from the rigid tube (20). When the device is heated, the barrier inserts (24) prevent the fused epoxy adhesive of the bonding inserts (23) from flowing along the pipes away from the joints.

A modification of the device of figure 10 is shown in figure 11 in which the rigid tube ~20) varies in diameter between its end regions to provide a tran-sition between pipes of differinq diameter.

A further form of device is shown in figure 12 in which a rigid copper tube is intended to act as the male part of the joints to the pipes to be connected.
The rigid tube (25) is provided at each end with a connector device (26) similar to that shown in figure 1. Each connector device is partially recovered onto the rigid tube (25) in order to form a skirt (27) that extends around the end region of the rigid tube. Each skirt (27) contains an epoxy bonding insert (28) and, adjacent to the bonding insert and on the side of the bonding insert remote from the ends of rigid tube :, ~34~L

(25), a barrier insert (29) as described above. The pipes to be connected are pushed over the ends of the rigid tube (25) until their ends abut the bondinq inserts ~28) and the skirts are recovered about the pipe ends as described above. The barrier inserts (29) prevent fu~ed epoxy adhesive being ormed away from the pipes under the partially recovered sections of the skirts.

Figure 13 shows a modified version of the device of figure 10 in which a rigid metal tube (30) has two slightly flared open ends (31) and a heat~shrinkable tube (32) formed from cross-linked polyvinylidene fluoride is positioned over, and partially recovered onto~ the rigid tube. The rigid tube (30) is provided with a thin coating of polyamide hot-melt adhesive (not shown) for retaining the rigid tube (30) and inserts therein and for providing a temporary bond to the pipes during installation. A nylon 12 barrier insert (33), of the type shown in figure 6, together with an epoxy bonding insert (34) is located within each end of the heat-shrinkable tube (32) adjacent to each end of the rigid tube (30) so that the bonding insert (34) faces the rigid tube end.

Figure 14 shows a modification of the device of 25 figure 13. Each~end region of the rigid tube ~35) has an internal shoulder (36) and a cylindrical portion (37) of constant diameter. Adjacent to the cylindrical portion (37) a frusto-conical region ~38) is formed in such a way that the wall tapers outwardly from the axis of the tube at an anale alpha to the axis of 1 (the lateral dimensions of the end region of the rigid tube ~` ~

~æ36~

being exaggerated in the drawing for the sake of clarity), and, adjacent to the frusto-conical region (38) the tube ends in a frusto-conical lip (39) which tapers outwards from the axis at an angle of about 35.
The axial length of the frusto-coniccll region (38) is about 12 mmr and of the lip (39) about 2 mm. The axial length of the cylindrical region is about 2~5 to 3.5 mm The volume of thermosetting adhesive in the bonding insert (40) is preferably greater than, eOg. at least 1.5 times, and especially at least twice, the volume of the gap between the internal surface of the tube in the region of the frusto-conical portion ~38) and lip (39), and the external surface of a pipe inserted therein. The device is intended to be used to join two pipes of outer diameter substantially equal to the internal diameter of the cylindrical portion ~37) so that the cylindrical portion (37) will fit snugly about the end of the pipe.

In order to join two pipes, each pipe is inserted into one end of the rigid tube (35) until their ends abut the internal shoulder (36), and the device is then heated for example by means of hot air gun until the heat-recoverable skirts (41), which form part of the heat-recoverable tube (43), have recovered into con-formity with the pipes, the thermosetting adhesive hasflowed and the barrier inserts (42) have fused indic-ating that installation is complete. When the device is heated the thermosetting adhesive forming the bonding insert (40~ will fuse and will be forced into the frusto~conical region (38) between the rigid tube (35) and the pipe to be ~oined by the recovery force of the heat-recoverable skirt (41), the flow of : .

the adhesive away from the rigid tube t35) being prevented by the barrier inserts (42). The connection formed between the pipes in this way is mechanically robust and is capable of withstanding significant pull-out, bending, tortional and vibrational loads, and also of withstanding high internal fluid pressures even at elevated temperatures, e.g. above l00C.

It will be appreciated that the end regions of the rigid tube (35) need not be identical as shown in the drawing, but may for example differ in size, e.g.
length or in the tube diameter, or, if desired, only one end of the tube may be provided with the configur-ation shown.

Figure 15 shows a device for terminating a hollow body such as a pipe or an outlet, and comprises a rigid metal tube (44~ of which one end (45) ~as been closed by crimping and folding the end back. ~ heat-recoverable tube (4~1 is positioned over the rigid tube (44), one end of the recoverable tube (46) extending over the open end of the rigid tube (44~ to form a heat-recoverable skirt (47). A bonding insert (48) and a barrier insert (49) are located inside the recover-able skirt ~47), the bonding insert (48) being adjacent to the ri~id tube (44). To terminate a pipe, for example, the end of the pipe is inserted into the recoverable skirt and the device is heated causing the heat-shrinkable skirt to recover onto the pipe and causing the bonding insert to mel~ and form a permanent , seal between the pipe and rigid tube (44).

.

3~i~

A device according to figure 7 without the pro-tective tube (14) was manufacturecl and comprised a cross-linked polyvinylidene heat-shrinkable tube having a maximum internal diameter of 10.5mm and a minimum internal diameter of 6.5mm and a heat-recovery tempera-ture of 165C. The barrier insert was made of nylon 12 and the bonding insert was made of a thermosetting epoxy adhesive comprising a diglycidyl ether of bis-phenol A, and dicyandiamide. The epoxy adhesive had a melting point of 80C, an initial curing temperature of 105C, and a minimum melt viscosity of 142 poise at 150~C. The heat-shrinkable tube was provided with an inner layer of hot~melt adhesive comprising a blend of polyamide and ethylene acrylic terpolymer having a rin~
and ball softening point of 155C and a melt viscosity of 1900 poise at 130C. A strip of thermochromic indicator was painted along the length of the outer r surface of the heat-shrinkable tube. This indicator changes from green to black at 260C.

This device was used to connect two metal pipes together. The first pipe had an external diameter of 6.4mm (1/4 inch) and was made of copper, and the second pipe had an external diameter of 7.9mm (5/16~ inch and was made of steel. Both pipes had a wall thickness of 0.71mm. One end of the steel pipe was swaged open to form a Erusto-conical portion such that the wall of the frusto-conical portion tapered outwardly from the longitudinal axis of the pipe at an angle of 1 and the axial length of the frusto-conical portion was 12mm~ A
frusto-conical lip was formed adjacent to the frusto-conical portion at the end of the pipe, and tapered outwards from the pipe axis at an angle of 30 and had an axial leng th o f 2mm ~

' '' :

.

Before installing the device the pipes were first cleaned by abrading the end regions with a medium qrade abrasive paper and then degreasing them with 1,1,1-trichloroethane.

The device was then slipped over the copper pipe and the end of the copper pipe firmly inserted into the frusto-conical portion of the steel pipe. The device was then positioned over the joint between the two pipes such that the steel pipe abutted the barrier insert. Using a hot air gun with a reflector attach-ment, which provided an air flow of 450C in the centre of the reflectcr, the device was heated causing the tube to shrink and the epoxy bonding insert to melt and flow into the joint. After heating for 45 seconds the ~barrier insert melted thereby enabling the tube to recover further indicating that enough heat had been applied such that the adhesive had been hea~ed to at least 177C whic~ would result in a cure of at least 70~ gel when the adhesive was cooled. The thermo-chromic paint also changed colour indicating that installation was complete, and ~he hot-melt adhesive exuded from the ends of the heat-recoverab~e ~ube.

The installed device was left undisturbed to cool for 4 minutes~ allowing the adhesive to cure.
.
Twenty-four hours after installing the device, the joint was sub~ected to the following tests with the following results:-' .~

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.' ' "

Test Result _.

Burst Strength -Hydraulic testing at 150C Withstand 141 bar for at least 313 hours Mechanical Strength 1. Bending - 10 deflections ~eak rate at 150C of through 15 less than 0.12g per annum of R12 refri-gerant gas :. .
2. Torsion - 2.5Nm torque Leak rate at 150C of less than 0.15q per annum of R12 refriq-~ erant gas : 3. Vibration - 30Hz at lmm Leak rate at 150C of : 15 amplitude for 2.5 million less than 0O109 per cy~les annum of R12 refriger-: ant gas ; 4. Shock - 10 cycles of rapid Leak rate of less than transfer from 100C to 0.5g per annum of R12 0C in the presence of refrigerant gas a liquid refrigerant '' .

Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. A device for forming a sealed connection between a first fluid-conveying pipe and a second fluid-conveying pipe in which an end region of the second pipe is inserted into an end of the first pipe to form an overlap region between the pipes, which device comprises a hollow, open-ended polymeric tube that is at least partly heat-shrinkable, at least one bonding insert formed from a solid, fusible, thermosetting adhesive, the bonding insert being located inside, and supported by, the heat-shrinkable tube, and at least one barrier insert located inside the tube adjacent to the bonding insert and supported by the tube, such that when the device is positioned around the overlap region between the pipes with the inserts adjacent to the exterior surface of the second pipe and the bonding insert abutting the end of the first pipe, and the device is heated, the tube recovers and the thermosetting adhesive of the bonding insert fuses, the barrier insert restricting flow of the adhesive away from the overlap region so that the adhesive flows into the overlap region via the end of the first pipe to form a permanent bond between the fluid-conveying pipes.

2. A device as claimed in claim 1 wherein the thermosetting adhesive has a melt viscosity in the range of 25 to 400 poise when heated to 150°C.

3. A device as claimed in claim 1 wherein the thermosetting adhesive is an epoxy adhesive.

4. A device as claimed in claim 1 wherein the tube has a quantity of adhesive on at least part of its inner surface to provide at least a temporary bond between the tube and at least one of the elongate objects.

5. A device as claimed in claim 4, wherein the quantity of adhesive on the inner surface of the tube comprises a hot-melt adhesive.

6. A device as claimed in claim 4, wherein the quantity of adhesive is a polyamide hot-melt adhesive.

7. A device as claimed in claim 1 wherein the tube is formed from a material having an elastic modulus of at least 250 MPa.

8. A device as claimed in claim 7, wherein the material is cross-linked polyvinylidene fluoride or a cross-linked polyamide.

9. A device as claimed in claim 1 wherein the or each barrier insert comprises material capable of fusing or deforming during installation of the device.

10. A device as claimed in claim 9, wherein the barrier insert has a melt viscosity higher than the melt viscosity of the thermosetting adhesive.

11. A device as claimed in claim 9, wherein the barrier insert is fusible or deformable at the temperature required to produce an adequate level of cure in the thermosetting adhesive.

12. A device as claimed in claim 11, wherein the barrier insert is fusible or deformable within the temperature range of 100-200°C.

13. A device as claimed in claim 11, wherein the melting point range of the barrier insert is no more than 40°C.

14. A device as claimed in claim 9, wherein the barrier insert is a thermoplastic polymer.

15. A device as claimed in claim 14, wherein the thermoplastic is a polyamide.

16. A device as claimed in claim 14, wherein the thermoplastic is nylon 11 or nylon 12.

17. A device as claimed in claim 1, wherein the bonding insert is in the form of a ring.

18. A device as claimed in claim 1, wherein the barrier insert is in the form of a ring.

19. A device as claimed in claim 18, wherein the outer wall of the barrier insert ring is tapered.

20. A device as claimed in claim 1, wherein the bonding insert and barrier insert are in a side-by-side relationship with substantially no gap between them.

21. A device as claimed in claim 1, wherein each barrier insert is attached to its respective bonding insert.

22. A device as claimed in claim 21, wherein the barrier insert is in the form of a ring having a flange portion that extends axially from the periphery of the ring so that the barrier insert extends over one face and at least part of the outer circumferential surface of the bonding insert.

23. A device as claimed in claim 1, wherein a portion of the tube at or near one end region thereof is partially recovered.

24. A device as claimed in claim 4, wherein a protective tube is positioned over at least part of the quantity of adhesive that provides at least a temporary bond between the tube and at least one elongate object.

25. A device as claimed in claim 24, wherein the protective tube forms an integral part of the barrier insert.

26. A device as claimed in claim 1, wherein the or each barrier insert is attached to its respective bonding insert.

27. A device as claimed in claim 1, wherein the or each carrier insert is in the form of a ring having a flange portion that extends axially from the periphery of the ring so that the barrier insert extends over one face and at least part of the outer circumferential surface of its respective bonding insert.

28. A method of forming a sealed connection between a first fluid-conveying pipe and a second fluid-conveying pipe which comprises inserting an end region of the second pipe into an end of the first pipe to form an overlap region between the pipes, positioning a device as claimed in claim 1 around the overlap region so that the insert are adjacent the exterior surface of the second pipe and the bonding insert abuts the end of the first pipe and heating the device so that the tube recovers and the thermosetting adhesive of the bonding insert melts and flows into the overlap region.

29. A method as claimed in claim 28 wherein one of the pipes is made from a different material from the other pipe.