CA1288204C - Procedure for manufacturing lignocellulosic material products - Google Patents

Abstract

ABSTRACT OF DISCLOSURE

A procedure for manufacturing lignocellulosic material products and for improving their strength and water resistance characteristics, high-molar mass lignin derivatives being added to the lignocellulosic material, of which at least 35%
by weight are over 5000 in molar mass.

Description

~'~88~04 PROCEDURE FOR MANUFACTURING LIGNOCELLULOSIC MATERIAL PRODUCTS

The present invention concerns a procedure for manufacturing lignocellulo~ic material product~ and for improving their strength and water resistance properties using high-molar mass lignin derivatives. Such products are e.g.
those of the paper and cardboard industry and those of the industry manufacturing building materials, such as corrugated board, cardboard, kraft-liner, paper cores, wood composites, fibreboard and chipboard, and insulation materials. It is possible to improve by the procedure not only the characteristics of products made of primary fibres but also to enable high-grade products to be made of lower grade raw materials such as reclaimed fibres.
In cellulose manufacturing processes in which wood chips are heated in a cooking solution under pressure, about half of the wood is dissolved, forming the so-called waste liquor. One of the main organic components of waste liquor is lignin. In the sulphite process, in which an acid bisulphite/sulphur dioxide solution serves as digesting liquor, lignin is present in the waste liquor in sulphonated form, as so-called lignosulphonates. In this form, lignin is soluble in water also in acid solutions. On the other hand, - in alkaline cellulose manufacturing processes, such as the soda process (NaOH as digesting solution), in the kraft process (NaOH, Na2S, NaHS as digesting solution) or in the oxygen/alkali process (with NaOH in the presence of oxygen), lignin is present in the form of an Na salt in the waste liquor, and it is water-soluble in alkaline solutions.
It is known in the art that the characteristics of e.g. paper, cardboard and fibre boards can be improved by adding lignin to the fibres, most of~en in the form of waste liquor. The problem has, however, been the poor retention of said lignin products, that is, poor adhesion to the fi~res.
For instance, it has been possible to improve the strength properties o~ corrugated board by adding to the fibre stock 6% by weight, calculate~ on the dry matter of the stock, X

th~rmally proce~sed lignin i~olated from sulphite waste liquor (Zellstoff und Papier 24 (1975): 9, 269-70). It is observed, however, in the reference that u~ing lignin cannot be contemplated because the BOD values of the waste liquor become too high owing to its poor retention.
In the Canadian Patent CA 729,140 lignin is used in the form of sulphite waste liquor or black liquor for improving the strength characteristics of paper. Of the dry matter of black liquor only 26% by weight could be made to adhere to the fibres. All the same, the procedure was considered to be economically advantageous because the concora values of the paper increased from 66.3 points to 87.6 points.
A retention of equal degree, about 30% by weight, has al~o been reached in a Russian study (Bumazh Prom. 11 (1984);
18-19), in which kraft lignin was precipitated with alum onto the paper fibres. The lignin quantity used was over 8% by - weight of lignin dry matter, calculated on the dry matter of the fibres. In spite of poor retention, the breaking, punching and rigidity characteristics of the paper could be improved.
The effect of kraft lignin on the strength of fibre board made from waste paper has been compared in an American study (Forest Products J. 28 (1978): 77-82) with the effect of phenol formaldehyde resin. Of the dry matter of the kraft lignin product used, 54.8% by weight was organic matter and 44~ by weight was inorganic matter. When pH was adjusted with sulphuric acid to 4.5, only 15 g dry matter out of 100 g were precipitated. Precipitation could be somewhat improved by raising the precipitation temperature to 70~C; although lignin had to be added 11% by weight, calculated as dry matter related to the dry matter of the fibres, in order to achieve equally good s~rength characteristics as with 3~ by weight phenol formaldehyde addition. Cost calculation analysis revealed that phenolic resin was somewhat more favourable in use than lignin owing to higher lignin addition and oxygen consumption, and to the heating required in precipitating it.
Corrugated board manufactured from reclaLmed fibre stock has been impregnated, in Italy, in a sizing press with 1~8820~

both NSSC waste liquor and black liquor (Eucepa Conference, Florence, October 6-10, 1986, Proc. Vol. II,24; 1-31).
Subsequent to impregnation, the board was dried at 100-140C.
The wa~te liquors originated from poplar and straw cookings.
In most of the experiments, the characteristics of the board improved owing to the impregnation. Better results were obtained using the wa~te liquor at dry matter content 20-30%
by weight than when it was used in dilute solutions, which necessitated performing the impregnation in a plurality of steps. On the other hand, lowering the pH of the waste liquors reduced the strength properties of the board. The board impregnated with waste liquor obtained from straw cooking absorbed more moisture than untreated corrugated board.
Lignin has been chemically modified, particularly for improving its water resistance properties. It has for instance been reacted with amines (Wochenblat fur Papierfabrikation 94 (1966): 4, 107 - 110), whereafter it has been reacted with formaldehyde (US 3,079,353) or peroxide (SU
520,260). Alkali lignin has, for instance , been sulphonated - and used together with starch in order to increase the rigidity of a liner manufactured from waste paper (US
3,644,167). From rice soda black liquor, cyanoethyllignin and aminolignin have been manufactured, and they have been used e.g. in paper sizing (Paperi ja Puu 62 (1980): 10, 589 -592, 614). Lignin has also been heat-treated: e.g.
lignosulphonates at about 250 to 300C, with the purpose of converting them into a form insoluble in water (US 2,934,531 and Zell~toff und Papier la (1960): 11,328-332). Using this kind of products it has been possible to improve the - characteristics of corrugated board and kraft.
Kraft lignin, having average molar mass 25,000-30,000, has been used in manufacturing cardboard, corrugated board and wrapping paper (SU 681,140). As disclosed in said reference, the lignin is added to an aqueous solution containing 2-40% by weight fatty acids and resin acids, and the mixture is heated in an alkali at 80 to 85C before use.

The dry matter content of the mlxture i8 about 14-18% by weight and the pH is 8-9. The fatty acids and re~in acids have probably been added in order to improve the hydrophobic propertie~. When this mixture was added to a cardboard fibre stock in amount 3~ by weight, calculated as dry matter related to the dry matter of the stock, the bursting strength of the cardboard was improved 5% and the tensile strength, 18~.
High-molar mass alkaline kraft lignin has been added 1 to 7~ by weight, calculated as dry matter related to the stock dry matter, to a fibre stock used in manufacturing paper and cardboard (SU 374,407). The lignin is added as an alkaline aqueous solution to the stock, and thereafter, 3~ by weight of divinylstyrene/rubber latex in emulsion form, containing 75% by weight styrene related to the latex dry matter, is added thereto. Thereafter, the components are precipitated with aluminium sulphate. The rigidity of paper and cardboard could hereby be improved, in comparison with products reinforced with latex alone. The additions are comparatively low, only about 1-7~ by weight lignin.
Improved adsorptive paper suitable for lamination can be manufactured by adding to the paper in the sizing press, after web formation, high-molar mass lignin, of which at least 50% by weight is over 5000 in molar mass (FI 58,961).
The lignin product may consist of lignosulphonates or kraft lignin, and the additions are 0.1 to 10% by weight of the dry paper weight. According to the reference, lignin accelerates the absorption of phenolic resin in the paper but does not affect the tensile strength of the paper.
In the Finnish Patent FI 58788, lignin derivatives are used, of which at least 35~ by weight, advantageously 40%
by weight, are over 5000 in molar mass. By mixing them with phenol formaldehyde resin and adjusting pH of the bonding agent to be in the range 8-14, preferably 9-13, a waterresistant bonding agent can be manufactured for chipboard, plywood and fibre boards.
As will be evident from the foregoing, the greatest problems in using lignin as a reinforcing agent for various \ ,.
1 ~-~ 04 material~ has been cauQed by the poor retent~on of lignin product~, that is, their poor adhesion to fibres.
In the Patent SU 681,140, a lignin product having a given average molar mass (2s,000-30,000) has been used.
Since lignin is not homogeneous in structure but consists of lignin derivativeq differing greatly in molar mass, the value stated for the average molar mass in fact fails to specify the kind of the lignin product used. It may consist of very high-molar mass and very low-molar mass lignin derivatives in varying proportions so that the mean of their molar masses will be 25,000-30,000. It is probably because of the poor adhesion to fibres of low-molar mass lignin derivatives that fatty and resin acids had to be used in addition to this instance in order to improve the hydrophobic properties.
lS Endeavours have also been made to improve the retention of lignin and the strength and water resistance properties of fibre material chemically by modifying lignin, but the economy of the procedure has suffered in that case.
With the aid of the procedure of the invention, a decisive improvement is achieved regarding the drawbacks mentioned in the foregoiny. The procedure of the invention is characterized by that which is stated in the characteristic features part of claim 1.
The most significant advantage of the invention is that by applying it, products can be manufactured of various lignocellulosic materials in a sensible way, more advantageously in technical and economical respect than by any other method. Using the procedure now invented, strong bonds, - probably hydrosen bonds, are obtained between the lignin derivativss and the lignocellulosic material, owing to which the products possess excellent strength and water resistance properties. Since the retention of lignin in liynocellulosic material is nearly complete applying the method now invented, lignin can be made adherent to the lignocellulosic material up to 100% by weight, calculated as dry matter related to the dry matter of the lignocellulosic material, at the same time improving the properties of the products. Owing to lignin ,~,~

addition, the production of some products can be increased up to 50~. The procedure enableR recycled raw materials advantagèous in price to be used e.g. instead of virgin fibres. Applying the procedure of the invention, the strength and water reRistance properties of products produced from second grade fibres can ~e improved to be on a level with products based on virgin fibres.
The procedure is also advantageous from the viewpoint of the cellulose mill because the lignin going to fuel can now be utilized. There will be free recovery boiler capacity, and the production of cellulose may therefore be increased without having to invest in a new recovery boiler.
The removal from the waste liquor of the high-molar mass lignin enables the waste liquor to be evaporated to higher dry matter content prior to the recovery boiler, without any difficulties with viscosity. Hereby the energy required in the soda boiler for evaporating water will be less because the quantity of feed water is signi~icantly less.
The procedure is furthermore economically advantageous e.g. from the viewpoint of the plant manufacturing lignocellulosic products because to the lignocellulose suspension, mostly used at high dilution, lignin solution, lignin suspension or lignin powder with partly considerably higher dry matter content is added.
Hereby, the amount of water to be evaporated per ton of product will be less. In addition, lignin is advantageous in price, e.g. compared with many wet-strengths resins, such as urea-formaldehyde resin or polyethylene-imine.
To the lignosellulosic material products manufactured with the procedure of the invention any additives and components, known per se e.g. plastic raw materials may be added for instance for improving the strength and water resistance or other properties of the products. Thus e.g.
resin or resin raw materials, such as phenol formaldehyde resin may be added to the lignocellulosic material in any concentration, for instance less than 10% by weight or less than 5~ by weight calculated as dry matter on the mixture of ()4 the lignin derivatives and resin, e.g. before or after the addition of the lignin derivatives to the lignocellulosic material.
It is to be noted that it is not mandatory in the procedure of the invention to co-polymerize the lignin derivatives in question with resins. So the lignocellulosic material products may be free of resin.
As regards environmental protection, it i8 a remarkable advantage of the present invention that when it is applied the lignin is merely 100% attached to the fibres.
Furthermore, the BOD values of the plantls effluents will not increase, as is the case when impure lignin products containing organic acids and other low-molar mass compounds in abundance are used. When using lignin derivatives according to the invention, no toxic low-molar mass sulphur compounds, ~uch as hydrogen sulphide for instance, are released during the manufacturing process, as are for instance set free from sulphate waste liquor in acid conditions.
The invention is described in the following in detail. The high-molar mass lignin derivatives used in the procedure of the invention are isolated ~.g. from waste liquor of an alkaline cellulose process or from waste liquor after beaching by a lignin fractionating method known in itself in the art, such as precipitation with acid, or by an - 25 ultrafiltration process. At least 35% by weight of the high-molar mass lignin derivatives should have molar mass higher than 5000. The molar mass distributions of lignin derivatives can be determined using gel chromatography~ as is disclosed in detail in the Finnish Patent No. 58788.
The so-called degree of purity of the lignin has a great significance because when impure lignin products are precipitated onto lignocellulosic materials, the impurities will not adhere to fibres and are discharged into the plant~s e~fluent circulation. Of the lignin derivatives used in the procedure of the in~ention, over 7~% by weight of the total dry matter of the lignin fraction should precipitate from a 1-5% by weight solution with 1 M hydrochloric acid at pH 3.

lX~8204 The degree of purity of the lignin fraction can be found out with the aid of hydrochloric acid preclpitation, ~ince low-molar mass phenolic compounds, and other ~norganic and organic impurities, will not be precipitated in such a determination.
5The lignin derivatives of the invention may be used in the form of a dilute solution, of an evaporated concentrated solution, of a suspension, or of a powder, e.g.
spray-dried. Their dry matter content at the moment of use may therefore vary, depending on the manufacturing process of 10the product, in the range 0.1 to 100% by weight.
The acid quantity required to lower pH below 7 may be added to the lignin, to the lignocellulosic material or to the lignocellulose/lignin mixture, depending on which is most advantageous in view of the manufacturing process.
15It is possible to add to the lignocellulosic material, in addition to lignin, bivalent or trivalent metal salts, such alum, ferric or ferrous sulphate, or ferric chloride. Also organic, commonly known cationic precipitation chemicals, such as polyethylene imine, may be used. The 20amount of precipitation chemical added depends on the pH of the lignin derivatives and of the lignocellulosic material, and it is usually 0.5-20% by weight, calculated as dry matter related to the dry matter of the lignin/lignocellulose mixture, advantageously about 1-3~ by weight.
25The amount of high-molar mass lignin derivatives added to the lignocellulosic material varies in general in the range between 1 to 100~ by weight, calculated as dry matter related to the lignocellulosic material dry matter, depending on the reguirements set for the product.
30The lignin derivatives may, as taught by the invention, be added e.g. to finely divided lignocellulosic material, such as to fibres, to chips or to an aqueous suspension ~ade thereof, before the manufacturing process of the product or in conjunction therewith, e.g. on the paper 35machine or in the sizing press. As taught by the invention, the lignin may also be added to the lignocellulosic material, or on the surface of the product produced, or to be produced, ~,~

' .

l~sa204 thereof, a~ a coating or sizing, or it may be added as a bonding agent to the lignocellulosic material between different layer~. The lignocellulo~ic material, or the product manufactured thereof, may also be impregnated with a lignin solution or suspension e.g. when manufacturing insulating materials.
If desired, the lignin derivatives of the invention may also be chemically modified, e.g. by condensation with formaldehyde, by oxidation with air, or by binding amine groups there~o; in most cases, however, fully satisfactory properties are achieved by using the above-mentioned lignin derivatives as such.
The following examples describe the present invention, however without confining it.
Example 1. The effect of the proPerties of li~nin on its retention and on the characteristics of liner made from recla med fibres From a kraft process, black liquor was isolated by ultrafiltration, on the basis of molar masæ, lignin derivatives of different molar mass distribution and purity level. In Table I are stated the characteristics determined for said lignin fractions (R3, R4, R5, R~, Rl3, R24 and R32) and for the kraft black liquor after ultrafiltration.
In Table 1, the molar mass distribution (MWD) of the lignin derivatives are stated as proportion of lignin derivatives exceading molar mass 5000, in per cent by weight of all lignin derivatives. The proportion of precipitating stated in per cent by weight of the total dry matter of the lignin fraction when precipitating lignin from a solution with dry matter content 1-5% by weight with 1 M hydrochloric acid at pH 3. Sodium sulphide, sodium and ash content are stated in per cen~ by weight calculated on the dry matter of the lignin ~raction.

~' Table 1. Characteristics of the examined sulphate lignin fractions and sulphate waste liquor subsequent to ultrafiltration (% b.w.) s Lign. MW~ Prec. Mean Dens. Na2S Ua Ash Vis.
fract. M>5000 lign. cont. (23C) (23C) ~ % ~ g/cm3 % % ~ mPa-s Waste liquor 21 31 27,0 1,1607 5,3 20,4 49,g 2 R3 30 57 23,0 1,1248 2,4 15,7 36,7 3 R4 32 65 25,5 1,1346 2,0 14,5 33,3 3 Rs 35 70 27,8 1,1435 1,6 13,2 31,4 3 Rb 40 78 22,1 1,1028 0,6 10,9 25,2 5 R13 46 82 19,7 1,0872 0,2 9,3 20,6 7 R24 49 87 17,0 1,0709 0,02 7,2 13,1 9 R32 54 89 21,1 1,0878 <0,01 7,3 15,910 As a measure of the degree of purity of lignin one may take the proportion of precipitable lignin, which varied, as can be seen in Table 1, between 31 and 89% by weight. The impure fractions contained large quantities of sodium sulphide, which is converted into toxic hydrogen sulphide gas when pH is lowered into the alkaline range. This phenomenon is already in itself a bar to using impure, lignin derivatives with high content of low-molar mass compounds in the range below pH 7. By using high-molar mass, pure lignin derivatives this drawback was eliminated. The high-molar mass fractions with higher purity also contained less sodium than the low-molar mass fractions, and this is advantageous in view of the acid and/or alum quantity used in precipitation.
~he pH valueQ of the lignin fractions entered in Table 1 were adjusted with sulphuric acid to pH 6.6 and they were added to stock made from reclaimed fibres having consistency 12.2 g/l and pH 6.9. The composition of the stock was: 5~ by weight mag~zines, 30% by weight newsprint and 15%
by weight corrugated board. Lignin was added 5% by weight, calculated as dry matter related to the stock dry matter.

a~o~

Sub~equent to the lignin addition, 1.5~ by weight of alum was added as a 3~ solution, calculated as dry matter related to the stock dry matter. In this example, and in those following thereafter, ~'alum" is understood to mean aluminum sulphate containing crystal water:
Al2~S04)3.16H20. The retention, or the proportion of lignin that has become adherent to fibres of the original lignin quantity, was determined on the basis of ultraviolet absorption measurements (A 280 nm) of the slurry water and the original lignin solution.
Of the stock, sheets were made in the laboratory, having grammages about 150 g/m2 and thickness about 0.29 mm.
From the sheets thus produced, the following characteristics were determined: thickness, density, air permeability (SCAN-P 19:78), compression strength, the so-called SCT
(SCAN-P 46-83) and CCT (Corrugated Crush Test, SCAN-P 42:81), tensile strength and tensile index (SCAN-P 16:76, tensile index = tensile strength divided by base weight), and water uptake of the sheets by the so-called drop of water method (Drop of Water, TAPPI RC-70). The characteristics and retentions are stated in Table 2.

/

12~8~o4 Table 2. The characteristics of the sheets achieved using kraft black liquor and various kraft lignin fractions.

NWD Prec. Ret. Dens. Air Comp. str. Tens. Tens. Water ~5000 lign. perm. CCT SCT str. index Drop % % ~ kg/m3 s/100 kN~m kN/m kN/m Nm/g s ml Without lignin 507 78 1,54 2,19 4,8 35,8 13 Waste liquor 21 31 42 505 110 1,91 2,85 5,4 36,5>300 R3 30 57 77 510 131 1,95 2,85 5,8 38,2 "
- R~ 32 65 81 522 140 2,01 2,86 6,0 39,0 ' Rs 35 70 94 539 158 2,01 3,07 6,1 39,9 R9 40 78 95 516 147 1,88 2,90 5,8 40,0 "
R13 46 82 97 525 165 2,02 3,14 5,9 39,9 "
R24 49 87 99 534 181 2tO4 3,22 6,0 40,0 "
R32 54 8g 98 563 216 2,38 3,66 7,0 42,2 "
As can be seen from the retention values presented in Table 2, low-molar mass lignin derivatives adhered poorly to the fibres. Retentions over 90% were achieved with fractions of which more than 35% by weight had molar mass higher than 5000 and which had degree of purity (proportion of precipitable lignin, over 70% by weight of the total lignin).
The water resistance properties of the sheets improved in all lignin fractions in comparison with sheets produced from reclaimed fibres alone, the water drop penetrating into the latter in about 10 to 20 seconds. In the case of the sheets containing lignin the measurement~ were discontinued when 300 seconds had passed.
The properties of the sheets all improved with increasing molar mass and degree of purity of the lignin.
Improvement of properties could :even be achieved with black liquor alone, but its use, like the use of other impure fractions, is rendered doubtful by poor retention, which would create environmental problems for the mill. A very important characteristic, namely the compression strength (SCT), improved significantly when the molar mas~es of the lignin derivatives increased 235% by weight M ~ 5000 and the degree of purity rose over 70% by weight (Fig. 1).

S Example 2. The effect of PH adlustment on the characteristics of ~iner produced from reclaimed fibres The high-molar mass kraft lignin fraction with 74~
by weight having molar mass higher than S000 and having degree of purity 89% by weight was isolated from kraft black liquor by ultrafiltration. The pH of the fraction as such was 12.6.
The fraction was divided into 8 parts, their pH
values being lowered with sulphuric acid to be in the range pH 3 to lO. In the solutions having pH below 6.5, part of the lignin was present in precipitated form a3 a suspension. The dry matter content of all solutions/suspensions was 3.0% by weight.
From waste paper a stocX was produced which had a consistency of 4 g/l. The stock was divided into batches and their pH was adjusted to 7, S and 3, respectively. The above-mentioned lignin-water suspensions were added to the stock batches so that the lignin addition was 30% by weight, calculated as dry matter related to the stock dry matt~r.
Thereafter, 3% alum was added as a 2% by weight aqueous solution, calculated as dry matter related to the stock dry matter.
From the lignin/stock mixture liner sheets were produced which had base weight were 140-150 g/m2 and thickness about 0.25 mm. The characteristics of the sheets are stated in Table 3.

~.

~ ~8~

Table 3. The effect of the p~ valu~s of recla~med f~br~
stock, draft lignin and lignin/fibre mixture on the characteristics of liner sheets.

Seo~k Lign. Fibre~ D~s. ~ir Comp.s~r. T~s. Cobb~., pH pH lign./al perm. SCT CCT str. valu~
~x~. index k9~D 5/10O kN~m kN/~ N~g q/m~
ml Without lignin 50512b 2,81 1,77 36,2 151 7 12,~ 1~54~ ~04 2,74 1,~5 ~,5 102 " 9 7 536Z08 3,03 1,9S 41,7 5 " ~ 7 4~020~ 2,~4 1,70 41,0 54 " b,~ ~ 5~320 3,02 2,02 41,7 Z1 " 5 5 ~82332 ~,5B 2,11 40,3 Z~
" ~ 5 ~15487 ~,79 2,14 4Z,Z 21 " ~ 4 5795~5 3,7S Z,19 41,~ 25 12,6 10 526193 Z~ 1,72 40,0 197 ~ 10 7 520~8B 2,95 1,77 3q,3 94 53e213 ~07 1,96 3~,7 Z5 ,~ ~ 54~~33 3,3~ 2,02 42~6 Z2 " S ~ ~3302 3,48 2,q7 37,4 17 " 4 4 5493~4 ~,49 z,oa 4Z,6 17 12,~ Y 5~ 2 Z,9~ ~,lZ 3~,7 ~82 " 10 ~ 5412~7 3,14 1,94 ~1 30 " B 5 5~2~4 3,52 ~,03 41,7 18 ~ 4 bO2332 3,~9 2,0~ 3~
" ~ 4 5B1303 3~SO Z,OS 37~4 2B
" 4 4 ~4279 3,~ Z,ll 37,9 1~

- As can be seen in Table 3, the characteristics of the sheets, in particular the SCT, CCT and Cobb values, improved considerably when the pH of the slurry/lignin/alum mixture fell below 7.

,, _ 1~ ~8~ ~

Example 3. The effect of the order of adding lianin, acid and precipitation chemical The pH of a high-molar kraft lignin fraction as in Example 2 was adjusted with sulphuric acid to be pH 5. The dry matter content of the lignin solution was 3~ by weight.
The sulphuric acid quantity required for said pH adjustment was added, in another experiment, directly to stock made from reclaimed fibres, having a consistency of 8 g/l and pH 6.8.
In this case, lignin was added to the stock in the form of a solution having pH 12.6. The lignin addition was about 30%
by weight, calculated as dry matter related to the stock dry matter. For precipita~ion chemical, alum was used in the experiments, this being added in the form of a 3~ by weight solution at 2% by weight, calculated as dry matter related to the fibre stock dry matter.
In the experiments the order of adding kraft lignin, sulphuric acid and alum to the fibre stock was varied. From 2~ the lignin/stock mixtures sheets were produced which has base weight 140-150 q/m2 and thickness 0.25mm. The lignin retention and the characteristics of the sheets are stated in Table 4O

:; 25 Table 4. The effect of order of adding lignin (SA), acidic (H2SO4) and precipitation chemical (alum) on the characteristics of sheets. Cases in which sulphuric acid was added to the lignin in advance are marked (SA + H2SO4).

.' ~

1~8~()4 Ord-r of Ml >t~ . R~t . Den-,. Alr Comp.~tr . ~n~. Co~b~.., addi t~on pH perm. SCT t:CT 5tr .ind.value"
t o ~ t o ~ k % kg/m:'' 5/100 kN~m kN~m Nm~g g/m'' ml Stock ~,Z - gO~5 IZ~ Z,SI 1,77 3~,2 S51 wi thout l i~n~n 1 ~ ( S~
~leSO~ ) ~ 3 ~ ~58S 539 3~77 2~ 1~1 40~2 18 2~ Alum I ) Rlum ~ q bO1 5~?4 ~,e~ 2,24 39,9 19 ~) ~SAIH~S~) 1 ~ H~S~. 5, 7 99 584 49~ 3, 97 Z, 18 4;~, 9 17 Z) SP, 3) Alum 1~ Alun~ 5,7 ~ 571 544 3,q2 2,3~ 44.0 17 Z) SR
3 ) H~1504 1 ) ~eSC1~ 584 3~7 2~Z2 43~ 18 2) l:~lum ~) S~

1) sa S,7 ~7 5'?9 531 3~97 2,~6 45,2 11 2) H~SO~
3) ~lum 1) SCAN-P 12:64, states the water quantity (in g/m2) meter, which the paper or cardboard surface absorbs in 60 seconds from a water column 1 cm in height covering it.

8~()4 A~ can be seen in Table 4, good retention~ were achieved independent of the order in which lignin, ac$d and alum were added, and the characteristics of the sheets improved in all instances in comparison with reclaimed fibre alone.

Example 4. The effect of liqnin quantitY added on the characteristics of reclaimed fibre liner To stock produced from reclaimed fibres, having pH about 7 and consistency about 10 g/l, was added high-molar mass lignin of which 54% had molar mass higher than 5000, at 0, 0.5, 2.5, 5, 7, 10, 15, 20, 30, 40, 50 and 60% by weight as dry matter, calculated on the stock dry matter. The dry matter content of the lignin solution was 3~ and its pH had been ad~usted to be below 7 before addition to the fibre stock. After the lignin addition, alum as 3% solution was added 1.5-2% by weight, calculated as dry matter related to the stocky dry matter. The stock/lignin/alum mixtures had pH values varying between S and 6. The retention was between 94 and 100% in all cases. The grammages of the sheets were about 150 g/m2 and the thicknesses about 0.25 mm; the other characteristics are seen in Table S.

, i3 . ' ' ~able 5. The effect of high-molar ma~s liqnin addition quantity on the characteristics of liner sheets produced from reclaimed fibres.
S~ D~?n~ lr Cc~mp . ~tr . Ten~ . Tens . Cobb,,., W~t~r added p~rm . SCl CCT 5tr . i nd6~x 17rop 'X. kg~m~ 5~100 kN~m kN/m kN~m N~g g/m~
ml 0% 500~4 2,47 1,5~ 5,01 ~4,~1~9 9s 0,5 49~ ~ Z,69 ~,a4 ~,lo ~5,~ z~
~,~ 521 ~ 2,7h 1,a6 ~,33 3~,2 77 52714~ Z,9~ 2 ~,72 ~8,6z7 >3~0 7 5~09S Z,~2 1~89 ~,74 37,5 ~300 ~0 54~t~4 3,00 1,q3 S,30 3~ 5 ~s 54e~07 3,~3 2,03 5,7~ ~,2 24 574244 3,4~ 2,1~ s,ao 39,S24 I~
2S 593274 3,73 2,37 b,~0 41,2 "
5925~ 3,73 2,20 ~,01 40,920 "
S95373 ~,~8 2,43 ~,91 ~9,4ZZ ' ~0239~ 3,~ 2,~6 5,92 40,832 ~0 bl4477 3,97 2,~ S.72 40.~19 ~
The results are also shown in Fig. 2, in which the SCT compression strength, CCT compression strength and tensile strength values are calculated as per cent improvement over the with sheets without lignin. As is seen in Fig. 2, the SCT
values are bettered up to 60% The Cobb~ values, i.e., the amount of water absorbed by the cardboard in 60 seconds, were reduced from 159 to about 22 g/m2, or by 86% when the lignin additions were over 20%.
When comparing the results with the characteristics of sheets made from virgin fibres, e.g. from a kraft stock, one may note that by adding high-molar mass lignin to reclaimed fibres more than 20% by weight, sheets can be produced of which the SCT values are equal to or better than the values of sheets manufactured from a kraft stock (Fig. 3).

, ~8, 04 Example 5. The effect of the dr~ matter content of li~nin on its adhesion to fibres As is seen in Table 6, eleven kraft lignin solutions in the dry matter range 0.1 to 20~ by weight were prepared.
All solutions had pH 5, and the high-molar mass kraft lignin fraction was the same as in Example 2. Part of the kraft lignin was freeze-dried into a finely divided powder. Prior to drying, the pH of the lignin was adjusted to be 5.
The lignin quantity added was 30~ by weiqht as dry matter calculated on the dry matter of stock produced from waste paper. The stock had consistency 8.5 g/l and pH about 7. The alum quantity added after the lignin a~dition was 2.0%
by weight calculated as dry matter related to the stock dry matter, and it was added in the form of a 3% by weight aqueous solution. The retentions that were determined are stated in Table 6.

Table 6. The effect of the dry matter content of high-molar mass kraft lignin on its retention.
Dry matter Retention Consistency of slurry/
cont. of lignin lignin/alum mixture, % % g/l 0,1~ 98,4 3,1 0,15 97,1 4,1 0,20 96,0 4,9 0,40 97,8 6,8 0,60 98,5 7,7 0,80 98,5 8,4 1,0 98,8 8,8 3,0 98,8 10,2 5,0 98,9 10,5 10,0 99,0 10,7 20,0 99,9 10,9 Powder (about 100%) 93,711,0 ~88~04 As can be seen in the t~ble, good retentions were achieved within the entire dry matter range 0.1 to 100%.
Selection of appropriate dry matter content i8 therefore in the first place dependent on the production process used and on whether it is desired to reduce the consumption of water per ton of product, whereby for instance the drying costs will be lower.

Example 6. The effect of the alum quantitY on retention and on the characteristics of liner High-molar mass kraft lignin as in Example 2 was added as a 3~ aqueous solution to stock produced from waste paper, at 30~ by weight, calculated as dry matter related to the stock dry matter. The pH of the lignin solution had been adjusted to about pH 5 with sulphuric acid before addition.
The pH of the stock was adjusted to pH 5.3 prior to lignin addition. The alum addition varied in the range 0 to 10~ by weight ~on the stock dry matter). Liner sheets were produced in the laboratory, with base weight about 150 g/m2 and thickness about 0.25 mm. The retentions and the characteristics of the liner are stated in Table 7.

Table 7. The effect of alum quantity added on retention and on the characteristics of liner sheet.

$~

~l8~0 Alum Ret. D~ns. Air Comp.~tr. T~n-. T~ns. Cobb~
add~ per~. SCT CCT ~tr. ind~x v~lue /. kg~m3 slOO kN~m kN/~ kN~m Nm/q g/m2 ml Without lignin~00 94 2,47 1,5~ 5,0~ 34,~ 2S~
0~7,~ ~21 226 3,03 ~,7~ 4,7~ ~3,B 6 0,5~HI2 ~o 28~ 3,0~ 1 ,ao 4,~8 38,7 26 199,0 583 z~l 4~0~ 1,93 5,00 37,~ 1~
1,5~,0 587 ~ 3,09 1,q2 4,B1 37,~ 18 29q,4 S~3 2~h 3,14 1,77 4,77 37,0 2~
~,5q~,3 601 27~ 3,t5 1,74 4,ZB 34,0 47 39~,3 5~7 313 3,40 ~,11 S,08 3~,~ 24 S9~,0 5~7 32~ 3,49 ~,8~ 5,15 ~,3 2Z
798,2 ~9 2B6 3,52 1,B7 5,4~ 38,3 Z1 1098,B 60~ -~00 3,~1 2,02 5,10 36,2 24 As can be seen in Table 7, alum addition is not indispensable, but even with a small alum addition both the retention~ and the characteristics of the sheets already improve.
ExamPle 7. The effect of preciPitation chemicals on liqnin retention Salts of bivalent and trivalent metals, alum, FeCl3, Fe2( S04 ~ 3, FeSO4 polyaluminiumchloride (PAC), and cationic precipitation chemical, polyethylene imine (Polymin SR, BASF) : 30 were used for precipitation chemical for precipitating the high-molar mass lignin fraction onto reclaimed fibres. The quantity of lignin added was 30% by weight as dry matter, calculated on the slurry dry matter. The degree of purity of the lignin fraction was 89% by weight, and 79% by weight thereof has molar mass higher than 5000. pH of the lignin solution had been adjusted to pH 5 with sulphuric acid prior to precipitation, and its dry matter content was 3.0~. The precipitation chemicals were added as a 3% solution at 2~ by weight of the stock dry matter, taking into account the crystal water in the chemical, if any. The effect of the chemicals on adhesion of the lignin to the fibres is indLcated by the retention values, Table 8.

Table 8. The effect of precipitation chemicals on lignin retention.

Precipitation Lignin pH of stock/lignin/
chemical retention, % prec.chem. mixture - 92,3 6,7 H2SO4 99,5 3,5 Al2(SO4)3-l6H2O 99'9 4,8 Fecl3-6H2o 98,1 4,6 Fe2S04)3 99,6 5,8 FeS04 7H20 PAC 99'7 5'5 Polymin S~ 99,7 6,3 As can be seen in Table 8, it is possible, using various precipitation chemicals, to increase the retention close to 100% without substantially increasing the acidicity;
this is often desirable considering the characteristics of the product, e.g. its sizability and printability. Achieving high retention is also important in view of the plant effluents.
Example 8. Use of hiqh-molar mass bleachina lignin in reinforcement of liner From waste liquor from the alkali extraction step following after chlorination, originating from bleaching alkali-digested cellulose, a high-molar mass lignin fraction was isolated which had a molar mass of 37% by weight of M > 5000, pH about 8 and dry matter con~ent 17% by weight.
Before precipitation, the lignin fraction was diluted to 3 by weight and its pH was adjusted to be below 3.

i~

1~ ~ 8~ O 4 To a stock produced from reclaimed fibres, having pH 7, 30% by weight lignin fraction and 5~ by weight polyamlne were added, both calculated as dry matter related to the stock dry matter. Sheet~ with a grammage of 130 g/m2 and thickness about 0.22 mm were produced in the laboratory. The characteristics determined from the sheets are stated in Table 9.

Table 9. The effect of high-molar mass lignin fraction isolated from bleaching waste liquor on the characteristics of sheets produced from reclaimed fibres.

Density Porosity Compr.Str. Cobb~ Water SCT CCT value Drop kg/m3 s/100 ml kN/m kN/m g/m2 s Without lignin 531 184 2,35 1,34 215 13 Bleaching lign. 605 480 3,04 1,66 146 >300 As c~n be seen in Table 9, good characteristics were also achieved by using high-molecular lignin isolated from bleaching waste liquor.

Example 9. Addition of liqnin to a fibre web (Coatin~) Using high-molar mass kraft lignin with 79% by weight of it exceeding M 5000, six aqueou~ solutions were prepared having 3% by weight dry matter content, and pH 3.
The pH of five solutions was adjusted with sulphuric acid to, respectively, pH 3, 4, 5, 7 and 9. The first three were partly in suspension form. The lignin-water solutions/suspension were added as a kind of coating to reclaimed fibre sheets, from which most of th~ water had been drained through the wire. The addition wa~ 30% by weight, calculated as dry matter related to the dry matter of the fibres. For precipitation chemical, alum was used as a 3~

..~,, j 1~88;~04 solution, the addition being 2% by weight calculated as dry matter related to the dry matter of the fibres. The results are given in Table 10.

Table 10. Addition of lignin as a coating and its effect on the characteristics of reclaimed fibre liner.
Lign. Oen~. ~ir Cc~mpr.str. Tens. ~erls. Cot~b60 pH perm. SCT CCTstr.ind. valu~
k~/m3 s/~OO kN~m kN~m kN/m kN/m g/m2 m~
3 458 3~1 3,9Z 2,3S !5,~ 35,9 g8 4 ~S3 4413 3,7~ Z,37 5,7 37,~ 5 ~41 485 ~?,q8 2,!5~3 ~,3 44,6 31 7 473 131 2,24 l ,2~5 4,S 3'?,2 t~3 '? 4~9 1:50 ~!,12 1,a7 4,4 38,4 1~1 13 531 1~4 2,3~ 1 ,34 4,~ 3:5,7 21:~S
Wi thout l ignin 507 174 Z,~ 1,70 Y, 1 35,Z 199 As can be seen in Table 10, by adding on the surface of sheets a lignin solution with pH ad~usted to be below 7, the characteristics of liner produced from reclaimed fibres could be significantly improved in comparison with liner to which no lignin had been added.
ExamPle 10. The effect of liqnin addition quantitY on the characteristics of liner produced from kraft stock To a kraft stock with a pH of 8.55 and a consistency of 18 g/l before precipitation, 0 to 50% by weight of high-molar mass kraft lignin as in Example 2 was added at 0 to 50%
by weight dry matter, calculated on the stock dry matter, its pH being adjusted to pH 5 before precipitation. For precipitation chemical, alum as a 3% by weight solution was used, added to the fibre at 2% by weight, calculated as dry matter related to the stock dry matter. The grammage of the liner sheets that were produced was about 150 g/m2 and ()4 thickness about 0.26 mm. The other characteristicff, determined at 50% relative humidity, unless otherwise stated, were a~ follows:

Table 11. The effect of high-molar mass kraft lignin on the characteristics of liner produced from ~raft stock.
Lign. Dens. ~ir Comp.str. lens. Tens. CDbb~o 85'~.-added perm. SCT CCT str. ind. value humid.
SCT
k~l/m3 5/ lOO kN/m kN~m kN~nl Nm~g ~3~m2 kN~m ml 550 514 3,~0 1,83 ~,93 *e,5 34 1,,~4 579 ~,5 3,44 1 ,q5 7,54 51 ,6 32 1 ,86 S7C~ ~,O 3,S2 1 ,9q 7,ql S3,4 2'7 ~ ,~0 ~0 5~S5 5,:3 3,45 1 ,90 7,74 5Z,7 25 1 ,90 578 b,2 3,47 ~OO 7,?q S~,~ Z7 1 ,8'?

5~ 7,~1 3,5~ 2,11 8,08 S4,2 26 1,94 ~0 ~5~3 ~,7 3,6S ~J ~9 8, 1'? ~4~ 2 As can be seen in Table 11, also virgin fibres can be reinforced with high-molar mass lignin. The SCT values have here increased by 20%, both at 50% and 85% relative humidity of air. The quantity of lignin added, calculated as 2 5 % by weight dry matter related to the stock dry matter, implies that when for instance the added quantity is 50% by weight, the composition of the stock/lignin mixture is 33% by weight lignin to dry matter and 67~ by weight stock dry matter.
ExamPle 11. Production of fibreboards To a fibre suqpension which had consistency 10 g/l, high-molar mass kraft lignin was added, as a 5% solution, at 1 and 2 . 5% by weight. The lignin was precipitated onto the fibres with alum, added as a 3% solution at 1% by weight, .

- -calculated as dry matter related to the dry matter of the fibres.

The production conditions of fibre board~ were as follows: hot pressing temperature 205C, pressure 0.5 Nm/mm2, and pressing time 6 to 7 minutes. The sheets were post-hardened at 160C for 4 hrs.

The characteristics of the boards are given in Table 12, where also the characteristics of fibre boards made with phenolic resin are stated.

Table 12. The characteristics of fibre board~

Bond i ng ag~nt Quant . F 1 ~xur . Tens . Water Swe I 1 i ng added str. str. uptake % N~mm2 N/mm2 24 h,X 24h,%

Phenolic resin l 501 Z,22 Z7,Z 1~,8 Hiqh-m~lar mass Icr~ft 1 iCInin 1 ~lZ Z,5~ Z3,~ 15,3 D:o 2,5 S4~ 2,~S ~ ,7 As can be seen in Table 12, the results achieved with high-molar mass draft lignin are better than those with phenolic resin. Thus, the strength characteristics of fibreboards could be improved in an economically advantageous way.

..;,~ .~

Claims (15)

1. A procedure for manufacturing various products from lignocellulosic material and for improving their strength and water resistance characteristics, characterized in that to the lignocellulosic material are added highmolar-mass lignin derivatives of which at least 35% by weight of them have molar mass over 5000 in the form of aqueous solution, suspension or powder, and that the acidity is so adjusted that the pH of the lignocellulose/lignin mixture after addition is in the range from pH 2 to pH 7.

2. Procedure according to claim 1, characterized in that at least 40% by weight of the lignin derivatives have molar mass over 5000.

3. Procedure according to claim 1, characterized in that in the aqueous solution of the lignin derivatives at leat 70% by weight of the total dry matter is precipitated from a 1-5%
solution with 1 M hydrochloric acid at pH 3.

4. Procedure according to claim 1, characterized in that the aqueous solution of the lignin derivatives is acidized so that its pH is below 7 before its addition to the lignocellulosic material.

5. Procedure according to claim 1, characterized in that the lignocellulosic material is neutralized or acidized before adding lignin.

6. Procedure according to claim 1, characterized in that the lignin quantity to be added to the lignocellulosic material is 1 to 60% by weight, calculated as lignin dry matter related to the dry matter of the lignocellulosic material.

7. Procedure according to claim 1, characterized in that the dry matter content of the high-molecular lignin derivatives at addition to the lignocellulosic material is in the range 0.1 to 100% by weight.

8. Procedure according to claim 1, characterized in that the lignin derivatives are added to the lignocellulosic material so that the retention of the lignin derivatives is over 90%.

9. Procedure according to claim 1, characterized in that the lignin derivatives originate from alkaline cellulose manufacturing processes.

10. Procedure according to claim 1, characterized in that the lignin derivatives originate from the kraft pulping process.

11. Procedure according to claim 1, characterized in that the lignin derivatives originate from a cellulose bleaching process.

12. Procedure according to claim 1, characterized in that to the lignocellulosic material are added, before or after lignin addition, bivalent or trivalent metal salts, such as alum, ferric or ferrous sulphate or ferric chloride, at 0.5 to 10%
by weight, calculated as dry matter related to the dry matter of the lignin/lignocellulose material.

13. Procedure according to claim 1, characterized in that to the lignocellulosic material are added, before or after the lignin addition, cationic, organic precipitation chemicals, such as polyethylene imine, at 0.5 to 10% by weight, calculated as dry matter related to the dry matter of the lignin/lignocellulose material.

14. Procedure according to any one of claims 1 to 13, characterized in that the lignin derivatives are chemically modified before being added to the lignocellulosic material.

15. Procedure according to any one of claims 1 to 13, characterized in that the lignin is chemically modified after being added to the lignocellulosic material.