CA1292734C

CA1292734C - In situ comonomer generation in olefin polymerization

Info

Publication number: CA1292734C
Application number: CA000531796A
Authority: CA
Inventors: Max P. Mcdaniel; Douglas Klendworth; Donald D. Norwood; Eric T. Hsieh; Elizabeth A. Boggs
Original assignee: Phillips Petroleum Co
Current assignee: Phillips Petroleum Co
Priority date: 1986-06-16
Filing date: 1987-03-11
Publication date: 1991-12-03
Anticipated expiration: 2008-12-03
Also published as: DE3777629D1; NO872486D0; HU207738B; EP0279890A2; NO168482B; NO872486L; HUT48646A; ES2030018T3; SG78192G; NO168482C; EP0279890B1; EP0279890A3; JPH07103178B2; US4735931A; JPS62297305A

Abstract

Abstract of the Disclosure The catalyst system is produced by first forming a chromium catalyst on a predominantly silica support, activating in an oxygen-containing ambient and thereafter subjecting the thus activated composition to carbon monoxide reduction. The resulting reduced supported chromium catalyst composition is then precontacted with a cocatalyst selected from trialkyl boron compounds and dialkyl aluminum alkoxide compounds, preferably triethyl borane and thereafter contacted with ethylene. This results in a catalyst system which produces comonomer in situ so as to give tough, flexible ethylene copolymers from an essentially pure ethylene feed.

Description

~92~34 32135CA

IN SITU COMONOMER GENERATION IN
OLEFIN POLYMERIZATION
Background of the Invention This invention relates to the polymerization of a mono-l-olefin such as ethylene using a modified silica-supported chromium oxide catalyst.
It is well known that mono-l-olefins such as ethylene can be polymerized with catalyst systems employing vanadium, chromium or other metals on a support such as alumina, silica, aluminum phosphate, titania, zirconia, magnesia and other refractory materials. Initially such catalysts were used primarily to form homopolymers of ethylene. It soon developed, however, that many applications required polymers which were more impact resistant than ethylene homopolymers. Consequently, in order to produce polymer having short chain branching like the more flexible free radical polymerized ethylene polymers, comonomers such as propylene, butene, hexene or other higher olefins were copolymerized with the ethylene to provide resins tailored to specific end uses. The copolymers, however, are more expensive to produce since inventories of different monomers must be kept and also the comonomers are generally more expensive than ethylene. Linear ethylene polymers with short chain branching can be formed from a pure ethylene feed using the old free radical high pressure process, but the conditions necessary to do this make the product too expensive to be commercially competitive.
Summary of the Invention - ~Z~3~

Accordingly it is an object of this invention to provide a low cost route to linear ethylene polymers having toughness imparted by short chain branching;
it is a further object of this invention to provide a process by which ethylene polymers having the properties associated with copolymers can be obtained from a pure ethylene feed;
it is yet a further object of this invention to provide an improved chromium oxide polymerization catalyst; and it is still yet a further object of this invention to provide an improved polymerization process.
It has now been found that comonomers can be generated in situ to give tough olefin copolymers from a pure ethylene feed by utilizing a catalyst comprising chromium on a predominantly silica support which support is first activated in an oxygen-containing ambient, thereafter reduced with carbon monoxide and then precontacted with a cocatalyst selected from trialkyl boron compounds and dialkyl aluminum alkoxide compounds prior to contact with the ethylene monomer.
Description of the Preferred Embodiments The support must be a predominantly silica support. By predominantly silica is meant either an essentially pure silica support or a support comprising at least 90 percent silica, the remaining being primarily other oxides such as alumina, zirconia or titania. Preferably the support contains 95 to 98 weight percent silica and 2 to 12, preferably 2 to 5 weight percent titania (TiO2).
Silica titania supports are well known in the art and can be produced as disclosed in Dietz, U.S. 3,887,494.
The catalyst component must be a chromium compound. The chromium component can be combined with the silica component in any manner known in the art such as by forming a coprecipitate with the silica or forming a coprecipitated tergel of the silica, the titanium component and the chromium component. Alternatively an aqueous solution of a water soluble chromium component can be added to the hydrogel of silica component. Suitable chromium compounds include chromium nitrate, chromium acetate, and chromium trioxide. Alternatively a solution of a lZ~Z'~3~

hydrocarbon soluble chromium component such as tertiary butyl chromate, a diarene chromium compound, biscyclopentadienyl chromium II or chromium acetyl acetonate can be used to impregnate the silica zerogel which results from removal of water from the hydrogel.
The chromium component is used in an amount sufficient to give .05 to 5, preferably 0.5 to 2 weight percent chromium based on the total weight of the chromium and support after activation.
The resulting chromium component on the predominantly silica support is then subjected to activation in an oxygen-containing ambient in the manner conventionally used in the art. Because of economy, the preferred oxygen-containing ambient is air, preferably dry air. The activation is carried out at an elevated temperature for about one half to about 50 hours, preferably 2 to 10 hours at a temperature within the range of 400 to 900C. Under these conditions at least a substantial portion of any chromium in a lower valent state is converted to the hexavalent form by this calcination procedure.
The resulting calcined supported catalyst component is cooled and then subjected to at least partial reduction of the hexavalent chromium to a lower valent state prior to combining with the cocatalyst.
The reducing agent must be carbon monoxide. The carbon monoxide can be employed at temperatures between 300 and 500C although it is more often employed at temperatures in the range of about 350 to 450C. The partial pressure of the reducing gas in the reduction operation can be varied from subatmospheric pressures to relatively high pressures, but the simplest reducing operation is to utilize essentially pure carbon monoxide at about atmospheric pressure.
The reduction time can vary from a few minutes to several hours or more. The extent of reduction can be followed by visual inspection of catalyst color. The color of the initial activated catalyst is generally orange, indicating the presence of hexavalent chromium. The color of the reduced catalyst employed in the invention is blue, indicating that all or substantially all of the initial hexavalent chromium has been reduced to lower oxidation states, generally the divalent state.
The course of the reduction of the air-activated orange catalyst with carbon monoxide can be determined exactly by pulse 9'Z'73~

titration. A known amount of carbon monoxide is added per pulse and the amount of evolved carbon dioxide is measured. When reduction is complete only carbon monoxide will be present and the catalyst is blue in color.
The reduced blue catalyst can be titrated with pulses of oxygen to convert the catalyst to the original orange color. When oxidation is complete, oxygen will be evident in the offgas.
After reduction, the reduced supported catalyst component is cooled to about room temperature, e.g. 25C in an inert atmosphere such as argon or nitrogen to flush out the carbon monoxide. After this flushing treatment the catalyst is kept away from contact with either carbon monoxide or oxygen.
The cocatalyst is either a trialkyl boron component or a dialkyl aluminum oxide component wherein the alkyl group has 1 to 10 carbon atoms, preferably 2 to 4 carbon atoms. By far the most preferred componént is the single compound triethyl borane.
The cocatalyst is used in an amount within the range of 0.5 to 10 weight percent based on the weight of the reduced supported chromium component being treated, with about 1 to 8 weight percent being preferred. The blue color of the reduced supported catalyst component can change to greenish-blue after treatment, however it is believed the chromium remains in the divalent state. Stated in parts per million of the cocatalyst based on diluent only, the cocatalyst is used in an amount within the range of 0.5 to 20 preferably 2 to 8 ppm based on diluent in the reactor.
The order of addition of the components is critical to the operation of this invention. It is essential that the cocatalyst and the reduced supported catalyst be precontacted prior to contact with the monomer. In a batch operation this can be carried out by either pretreating the supported catalyst component with the cocatalyst and then adding the resulting composition to the reactor or the supported catalyst and cocatalyst can be added as separate streams to the reactor and thereafter the monomer can be added. It is preferred however to utilize a precontacting vessel. In this manner the supported catalyst and the cocatalyst can be introduced either continuously or batchwise generally utilizing a solution of the cocatalyst in a solvent or diluent, i2')~73~ 32135CA

preferably the same material bein8 used as a solvent or diluent in the subsequent polymerization reaction. In this precontacting vessel agitation is provided by means of a stirrer, for instance, to obtain free precontacting of the supported catalyst component and the cocatalyst.
Thereafter, the resulting supported catalyst/cocatalyst composition is introduced into the reactor. Preferably the precontacting is carried out immediately prior to the introduction thereof into the reactor although the resulting supported catalyst/cocatalyst composition can be stored under inert conditions if desired prior to being utilized in a polymerization reaction.
The invention is primarily contemplated for in situ generation of comonomer in a polymerization reaction utilizing an essentially pure ethylene feed. By pure ethylene feed is meant polymerization grade ethylene free of any significant amount of other monomers. The affirmative introduction of a comonomer so as to form a copolymer of the ethylene, the introduced comonomer and the comonomers generated in situ could be utilized if desired but this would dilute one important aspect of the invention which is the economy effected by being able to produce copolymers without the use of a separate comonomer feedstream.
While applicants do not wish to be bound by theory, it is believed that comonomer generated in situ is primarily hexene, i.e. the short chain branching in the resulting polymer will be butyl branches.
This is particularly true when operating under conditions so as to give higher density, although some octene may also be present. When operating under conditions to give lower density some butene is produced also.
The amount of comonomer generated in situ can be varied so as to adjust the density to the desired level by increasing the amount of cocatalyst which will increase the amount of in-situ generated comonomer.
By this means, density from 0.920 to 0.960 can be produced, although generally polymers in the density range of 0.930 to 0.955 are made in accordance with the invention. In addition, a small amount of comonomer can be affirmatively added as noted hereinabove to fine tune the density if desired.
Polymerization can be carried out in any manner known in the art such as gas phase, solution or slurry polymerization conditions. A

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stirred reactor can be utilized for a batch process, or the reaction can be carried out continuously in a loop reactor or in a continuous stirred reactor.
A preferred polymerization technique is that which is referred to as a particle form or slurry process wherein the temperature is kept below the temperature at which polymer goes into solution. Such polymerization techniques are well known in the art and are disclosed, for instance, in Norwood, ~.S. 3,248,179.
The preferred temperature in the particle form process is 10 within the range of 200 to 230F (193 to 110C). Two preferred polymerization methods for the slurry process are those employing a loop reactor of the type disclosed in Norwood and those utilizing a plurality of stirred reactors either in series, parallel or combinations thereof wherein the reaction conditions are different in the different reactors.
For instance, in a series of reactors a chromium catalyst which has not been subjected to the reduction step can be utilized either before or after the reactor utilizing the catalyst system of this invention. In another specific instance, a conventional chromium oxide on a predominantly silica support can be utilized in a reactor in parallel with a reactor utilizing the catalyst system of this invention and the resulting polymerization influence combined prior to recovering the polymer.
The molecular weight of the polymer can be controlled by various means known in the art such as adjusting the temperature (higher temperature giving lower molecular weight), introducing hydrogen to lower the molecular weight or varying the catalyst compounds.
Examples All of the supports utilized in the following examples are commercial silica-titania cogel supports containing a nominal 2.5 weight percent titanium containing a chromium component in an amount sufficient to give a nominal 1 weight percent chromium, these percentages being based on the weight of the calcined silica/titania/chromium compound composite. The cogel support has a nominal pore volume of 2.35 grams per ~ 7~ 32135CA

cc and a nominal surface area of 450 m2/g based on nitrogen sorption measurements.
The supported catalysts were calcined by fluidizing a 55 cc portion of the supported catalyst with dry air in a quartz tube heated to the temperature indicated for three hours and then cooling to about 25C
and flushing with argon or nitrogen.
The invention catalysts were prepared by sequential heating of the supported chromium component in air under fluidizing conditions at the temperatures specified in the manner described hereinabove, flushing the air out with nitrogen or argon as the temperature was reduced to the reduction temperature specified and continuing the heating in a CO
ambient for the time specified, generally one half or one hour. The resulting blue-colored supported catalysts were then cooled to about 25C
in the inert gas stream and stored in dry vessels under an inner gaseous atmosphere until ready for testing. The thus activated supported catalysts were then impregnated with the specified quantity of a hydrocarbon solution of the cocatalyst in the absence of air and the solvent removed by gentle evaporation to yield greenish-blue colored supported catalyst compositions.
In the control runs demonstrating the necessity for precontacting the supported catalyst was charged to the reactor in the absence of air and the cocatalyst added separately after contact of the ethylene and the supported catalyst.
Example I
The purpose of Example 1 is to demonstrate that only chromium is active under the conditions employed. For this reason triethyl alDinum was used as a cocatalyst since it was believed to be the best cocatalyst for achieving some degree of polymerization in all of the runs.
A variety of transition metals were supported on Davison's 952 silica. After impregnation all the catalysts were vacuum dried and air activated at 800C, cooled to 400C in nitrogen and finally reduced with carbon monoxide at 340 or 400C. Details of the supported catalyst preparation through the calcination stage are as follows.

lZ~2~73~
` 32135CA

2 wt.% Mo on 952 Silica: 0.94g of ammonium molybdate were dissolved in 40ml of deionized water and impregnated onto 25g of silica.
The catalyst was air activated at 800C (surface area=177 m2/g).
4 wt.% W on 952 Silica: 1.55g of ammonium tungstate were dissolved in 40ml of deionized water and impregnated onto 25g of silica.
The catalyst was air activated at 800C (surface area=177 m2/g).
1 wt.% V on 952 Silica: 0.58g of ammonium vanadate were dissolved in 40 ml of ~2M H2SC4 and impregnated onto 25g of silica. The catalyst was air activated at 800C (surface area=204 m2/g).
6 wt.% U on 952 Silica: 1.35g of uranyl nitrate were dissolved in 25 ml of deionized water and impregnated onto lOg of silica. The catalyst was air activated at 800C (surface area=230 m2/g).
2 wt.% Nb on 952 Silica: Using a nitrogen filled glove box, 0.5g of NbC15 were dissolved in 25ml of absolute ethanol and impregnated onto lOg of silica. The catalyst was air activated at 800C (surface area=248 m /g).
4 wt.% Ta on 952 S_lica: Using a nitrogen filled glove box, 0.85g of TaCl5 were dissolved in 25ml of absolute ethanol and impregnated onto lOg of silica. The catalyst was air activated at 800C (surface area=243 m2/g).
Table 1 shows that the catalyst must be chromium on silica;
other transition metals will not work, even though they are broadly disclosed in the prior art. The C0 reduction time was one half hour.
Conditions used in Table 1 represent the best known.

Run Catalyst Activation Temp. C0 Reduction Temp. Activity 1 Cr/silica 800C 340C 1473/30m 2 V/silica 800C 400C Dead 3 U/silica 800C 400C Trace 4 W/silica 800C 400C Dead Mo/silica 800C 400C Dead 6 Ta/silica 800C 400C Dead 7 Nb/silica 800C 400C Dead 12 ~ 2 7 3 4 32135CA

All runs were made at 95C, adding 1 ml of .5% TEA prior to contact with monomer. After 15-20 minutes of inactivity, another ml of 15% TEA was added in runs 2-7, just in case higher concentrations of TEA were needed.
However, this did not produce any activity. The Cr/silica catalyst of Run 1 produced polymer having an HLMI of 5.4 and a density of 0.9426.
Example II
The purpose of this example is to compare the effect of various supports for the chromium transition metal component which the previous example showed was the only one capable of giving activity in a catalyst preparation procedure involving calcination followed by carbon monoxide reduction.
This example shows the effect of varying the support in the context of the chromium catalyst Example 1 showed to be critical when using the calcination followed by C0 reduction. The supported catalysts were prepared as follows:
1 wt.% Cr on Alumina: 1.17g of chromium nitrate were dissolved in deionized water and impregnated onto 15g of calcined Ketjen G alumina.
The catalyst was air activated at 800C (surface area=258 m2/g).
1 wt.% Cr on Magnesia: 1.17g of chromium nitrate were dissolved in deionized water and impregnated onto 15g of calcined magnesia. The catalyst was air activated at 500C (surface area=45.3 m /g).
1 wt.% Cr on Titania: Some tetra-n-butoxide titanium was hydrolyzed with water to TiO2, washed, and then vacuum dried. After drying, 1.17g of chromium nitrate were dissolved in 25ml of deionized water and impregnated onto 15g of the titania. The catalyst was air activated at 500C (surface area=21.6 m2/g).
1 wt.% Cr on Zirconia: Some tetra-n-butoxide zirconium was r hydrolyzed with water to ZrO2, washed, and then vacuum dried. After drying, 1.17g of chromium nitrate were dissolved in 25ml of deionized water and impregnated onto 15g of the zirconia. The catalyst was air activated at 500C (surface area=103.0 m2/g).
Table 2 shows that, although many supports are broadly disclosed in the prior art, only Cr/silica gives this effect of good activity and lowered density.

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Run Catalyst Activation Temp.Activity HLMI Density,* Cocat.
8 Cr/silica air-800C; C0-340C 2162/30m 52.3 .9276 TEB
9 Cr/silica air-800C3522/40m 4.30 .9588 TEB
10 Cr/AlP04-.4 air-700C; C0-300C 1072/30m1.27 .9577 NONE
11 Cr/AlP04-.4 air-700C; C0-300C 1130/30m9.50 .9530 TEB
12 Cr/AlP04-.4 air-700C; C0-300C 447/30m 5.0 .9598 H2 13 Cr/MgO air-500C; C0-400C DEAD -- -- TEB
14 Cr/ZrO2 air-500C; C0-400C DEAD -- -- TEB
15 Cr/TiO2 air-500C; C0-400C DEAD -- -- TEB
16 Cr/Alumina air-800C; C0-400C 519/30m 0 .9492 TEB
17 Cr/Alumina air-800C; 619/30m 0 .9487 TEB
18 Cr/AlPO4-.9 air-700C; 1890/45m 0.4 .9609 None 19 Cr/AlP04-.9 air-700C; C0-300C 1545/30m66.6 .9650 TEB

Density in g/cc was determined on a compression molded sample cooled at 15C/hour and conditioned for 40 hours at room temperature in accordance with ASTM D1505 and ASTM D1928 condition C.
Runs 8 and 9 used a Cr/silica Tergel having 2 wt.% Ti.
All runs were made at 95C with lml of .5 wt.% TEB precontacted with 0.05 to 0.lg of supported catalyst, except the AlP04 runs were made at 100C.
These runs also show that with the chromium/silica composition the carbon monoxide treatment is essential to effect a lowering of the density.
Table 2 shows that only silica in combination with the CO
treatment works to give high productivity and to lower the density, thus indicating in-situ production of comonomer.
Example III
This example shows the effect of various cocatalysts used with the chromium on silica support which is calcined and subsequently reduced in CO. The cocatalyst which is precontacted with the support prior to contact with the monomer.

Run Cocatalyst Activity MI HLMI Ratio Density lml TEB (OX)* 3522/40 0 4.3 - .9580 21 lml TEB (OX)~ 4675/45 .04 2.7 68 .9588 22 lml TEB2162/30 1.41 51.3 36 .9276 23 lml TEA(l) 1473/30.075 5.37 72 .9426 24 lml TMA(2) 1221/30 0 3.10 - .9435 lml DEZ(3) 2600/30 .05 2.80 55 .9527 26 lml DEALE597/30 .43 26.3 61 .9348 27 lml MgBu1741/30 .10 6.00 60 .9431 28 lml DEAC~4) 629/30 0 1.90 - .9529 not reduced (1) triethyl aluminum (2) trimethyl aluminum (3) diethyl zinc (4) diethylaluminum chloride All runs were made with Tergel catalyst 2% Ti, Air 800C, C0 340C, adding catalyst and cocatalyst to the reactor first with isobutane, i.e. before the ethylene monomer.
Clearly TEB stands alone as the best cocatalyst. DEALE
(diethylaluminum ethoxide) is a second best choice. A comparison of runs 20 and 21 with 22 further shows that the reduction treatment is essential.
Example IV
This example shows another comparison of the different metal alkyls, but at half the concentration in Table 3. The results are shown in Table 4.

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Run Cocatalyst Activity MI HIMI Ratio Density 29 .5ml TEB 1344/30m .83 32.7 39 .9353 .Sml TMA1183/30m .06 3.21 58 .9453 31 .5ml DEZ2256/30m .08 4.50 59 .9529 32 .5ml DEALE 1230/30m .18 9.60 53 .9424 33 .5ml MgBu2 1303/30m .07 3.12 48 .9484 34 .5ml DEAC809/30m 0 2.70 - .9529 .5ml TEA1565/30m .06 4.00 - .9452 All runs were made with Cr/silica-titania, air 800C, C0 340C, polymerization at 95C, with cocatalyst added with the initial isobutane charge of supported catalyst so that the supported catalyst contacted the cocatalyst before monomer addition. Again TEB is clearly superior, and DEALE is the second choice. DEAC and DEZ had no effect at all on the density. Table 5 shows the effect of metal alkyl concentration.

Run Cocatal st Activity MI HIMI Ratio Density 36 None 745/45m.42 30.6 73 .9639 37 .25ml TEB2153/30 .22 10.8 49 .9440 38 .50ml TEB1344/30 .83 32.9 39 .9353 39 l.Oml TEB2162/30 1.4 51.3 36 .9276 Thus it is seen that the more metal alkyl added to the reactor, the lower the density.
Example V
This example shows the results of using different reducing treatments. In each example, Cr/silica-titania catalyst (2hTi) was calcined in air at 800C for three hours, then reduced for 30 minutes at the temperature shown with the treatment listed. Polymerization runs were then made at 95C using TEB as cocatalyst. TEB was added with the initial isobutane charge of supported catalyst, so that the catalyst contacted the TEB before the ethylene. The results are shown in Table 6.

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Reducing Catalyst Flashed Activity Run Treatment Color w Air g/g-30m MI HLMI Ratio Density 40 None Orange NO 4675/45.04 2.70 68 .9588 41 None Orange N0 3522 0 4.30 -- .9580 42 C0-340C Blue YES 2162 1.41 51.2 36 .9276 43 C0-500C Blue YES 2610 0.32 16.8 53 .9346 44 Hexane-200C Green YES 3117/45 0.80 -- .9569 45 Hexane-150C Green NO 2110 0 2.30 -- .9578 46 Hexane-300C Green YES 2030/47 0 0.96 -- .9467 47 Hexane-500C Brown NO DEAD
48 3-Hexene-200C Green YES 222/45 O 1.50 -- .9592 49 3-Hexene-200C Green YES DEAD
50 Methane-400C Blue-Gr YES 4000/30 O 0.61 -- .9472 51 Methane-500C Blue-Gr YES 643/30 0 2.00 -- .9490 52 Acetylene-200C Brown NO DEAD
53 CS -350C Brown NO DEAD
54 Me~H-350C Blue-Gr NO DEAD
55 Ti(OEt)4-300C Blue-GR NO DEAD
The Following Runs made at 102C instead of 95C:
56 None Orange NO 754/45 .42 30.6 -- .9639 57 Hexane-200C Green YES 2000/45 .09 5.47 62 .9556 58 Hexane-300C Green YES 536/46 .17 7.40 44 .9500 59 3-Hexene-200C Green YES DEAD
The Following Runs made at 95C with .5ml instead of lml of cocatalyst solution:
Hexane-200C Green YES 1860/45 0 1.80 -- .9639 61 3-Hexene-150C Green NO 154/30 62 C0-340C Blue YES 1344 .83 32.7 39 .9353 Clearly CO stands alone as the preferred reducing treatment, and the preferred temperature of reduction is 300-600C. No other treatment lowered the density enough to be useful. CO is only treatment that gave a high enough melt index to allow the production of polymers having a spectrum of melt processing characteristics through known process variables to lower and raise the MI.
Example VI
Example VI shows some runs made with diethyl aluminum ethoxide (DEALE) as the cocatalyst. This time a solution of 1 g DEALE in 100 ml 12~2 ~'3~

of isobutane was used. Again the cocatalyst was charged to the reactor with the initial charge of isobutane and supported catalyst so that the catalyst contacted the DEALE before it contacted the ethylene. Again the catalyst was silica titania (2% Ti).

Activation Reactor DEALE FLEX.
Run Air / CO Temp. CONC. ACTIVITY MI HLMI RATIO DEN. MPA ESCR
60850C None 102 lml3870/30 .12 8.0 67 .9577 1347 82 61700C 350C " "970/30 .95 48 50 .9261 -- --62 " " " "2260/85 .97 55 56 .9325 -- --63850C NOÆ " "3790/30 .10 8.9 89 .9584 1290 128 64850C NONE 95 lml9801/51 0 .80 -- .9585 1282 320 " " 96-H2 "6520/55 .28 17.362 .9574 1531 41 66 " " 96-H "2228/84 .22 17.077 .9601 1523 58 67 " 350C - 2 ~2861/50 .28 15.856 .9442 877 200 68 " " " "1480/60 .87 49.156 .9303 501 --69 850CNONE 962ml 10904/60 .02 2.70136 .9587 1290 267 70 850C350C 90-H2lml 1320/47 1.4 80.659 .9283 521 --71 " " 90" 1430/40 .33 19.659 .9317 551 >1000 72 " " 902ml 1390/40 .27 17.665 .9330 572 288 The following catalysts were made by impregnating DEALE on Cat.
73 850CNONE 964ml/g 4142/60 .03 2.7090 .9626 1560 113 74 " " " -H2" 600/52 .19 13.571 .9636 1585 --" " " -H2" 1154/40 .68 37 54 .9640 1710 14 76 " 350C 90-H2" 1400/50 .37 15.843 .9418 789 >1000 77 " " 90" 875/30 .26 16.765 .9381 695 108 Run 60 yielded the following SEC data: Mw=144,000, Mn=17,200, HI=8.3.
Run 61 shows a little broader MWD. Mw=137,000, Mn=11,900, HI=11.4.

Clearly the lowering of density can be achieved by DEALE in combination with CO reduction. Productivity is somewhat lower for each invention run since copolymers were made at fairly high temperatures.
Example VII
The following experiment demonstrates that the reduced catalyst must contact the metal alkyl before it contacts ethylene. A sample of Cr/silica-titania catalyst was calcined at 800C in air as before, then reduced with CO at 340C for 30 minutes. The CO was flushed out with nitrogen as the sample was cooled. Then it was charged to the reactor in the normal way, except that no cocatalyst was added. Instead isobutane 1~9Z ~3~ 32135CA

and ethylene were added and the mixture was stirred for about 10 minutes.
At first no activity was noticed, but after ten minutes some polymerization did begin to show. Then lml of .5% TEB was added to the reactor and a strong polymerization began. After 30 more minutes, the run was stopped and the polymer recovered. Total productivity was 1575 g/g. The polymer had a 4.2 HIMI and a density of .9470. This compares to .9276 when the TEB was added immediately and thereafter the ethylene.
Thus the density lowering effect seems to be suppressed when the ethylene is added before contact of the supported catalyst with the cocatalyst.
While this invention has been described in detail for the purpose of ilustration it is not to be construed as limited thereby but is intended to cover all changes and modifications within the spirit and scope thereof.

Claims

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A method of producing a catalyst system comprising:
(a) forming a chromium catalyst component on a predominantly silica support;
(b) subjecting the composition of (a) to activation in an oxygen-containing ambient at an elevated temperature sufficient to convert at least a portion of any chromium in a lower valent state to the hexavalent state;
(c) thereafter subjecting the activated catalyst composition of (b) to carbon monoxide under reducing conditions; and (d) thereafter contacting the thus reduced supported catalyst composition of (c) with a cocatalyst selected from trialkyl boron compounds and dialkyl aluminum alkoxide compounds.

2. A method according to claim 1 wherein said predominantly silica support is essentially pure silica.

3. A method according to claim 1 wherein said predominantly silica support is a cogel of 95 to 98 weight percent silica, the remainder being a coprecipitated titania component.

4. A method according to claim 1 wherein said activation is carried out in air at a temperature within the range of 400 to 900°C.

5. A method according to claim 1 wherein said carbon monoxide reduction is carried out at a temperature within the range of 300 to 500°C.

6. A method according to claim 1 wherein the reduced supported catalyst component of (c) is contacted in a mixing vessel with a hydrocarbon solution of said cocatalyst.

7. A method according to claim 1 wherein said cocatalyst is triethyl borane.

8. A method according to claim 7 wherein said predominantly silica composition is selected from pure silica and a composition comprising 95 to 98 weight percent silica the remainder being coprecipitated titanium component, said activation being carried out in air at a temperature within the range of 400 to 900°C and said carbon monoxide reduction being carried out at a temperature within the range of 300 to 500°C.

9. A catalyst product produced by the method of claim 8.

10. A catalyst product produced by the method of claim 1.

11. A polymerization process comprising contacting an ethylene feedstream with the catalyst of claim 10 under polymerization conditions and recovering a polymer product.

12. A process according to claim 11 wherein said feedstream consists essentially of pure polymerization grade ethylene.

13. A process according to claim 12 carried out under slurry conditions.

14. A process according to claim 12 carried out in a reactor connected in series with a second reactor utilizing a different catalyst.

15. A process according to claim 11 wherein said polymer product has a density within the range of 0.920 to 0.960.

16. A method according to claim 11 wherein said ethylene feedstream consists essentially of pure polymerization grade ethylene, said support is selected from pure silica and a composition comprising 95 to 98 weight percent silica the remainder being a coprecipitated titanium component, wherein said activation is carried out in air at a temperature within the range of 400 to 900°C, wherein said carbon monoxide reduction is carried out at a temperature within the range of 300 to 500°C and wherein the reduced supported chromium catalyst component is contacted with triethyl borane in a stirred mixing vessel.

17. A process for producing an ethylene copolymer from a feed consisting essentially of polymerization grade ethylene comprising contacting said ethylene with the catalyst of claim 10 and recovering said copolymer as a product of the process.

18. A process according to claim 17 wherein said copolymer has a density within the range of 0.930 to 0.955.

19. A process according to claim 17 wherein said ethylene feedstream consists essentially of pure polymerization grade ethylene, said support is selected from pure silica and a composition comprising 95 to 98 weight percent silica the remainder being a coprecipitated titanium component, wherein said activation is carried out in air at a temperature within the range of 400 to 900°C, wherein said carbon monoxide reduction is carried out at a temperature within the range of 300 to 500°C and wherein the reduced supported chromium catalyst component is contacted with triethyl borane in a stirred mixing vessel.