CA1318655C - Immobilizing particulate absorbents by conversion to hydrates - Google Patents
Immobilizing particulate absorbents by conversion to hydratesInfo
- Publication number
- CA1318655C CA1318655C CA000577822A CA577822A CA1318655C CA 1318655 C CA1318655 C CA 1318655C CA 000577822 A CA000577822 A CA 000577822A CA 577822 A CA577822 A CA 577822A CA 1318655 C CA1318655 C CA 1318655C
- Authority
- CA
- Canada
- Prior art keywords
- absorbent
- hydrate
- water
- aqueous liquid
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002250 absorbent Substances 0.000 title claims abstract description 88
- 230000002745 absorbent Effects 0.000 title claims abstract description 86
- 230000003100 immobilizing effect Effects 0.000 title claims abstract description 8
- 150000004677 hydrates Chemical class 0.000 title abstract description 21
- 238000006243 chemical reaction Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229920000642 polymer Polymers 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000011780 sodium chloride Substances 0.000 claims abstract description 12
- 229920000058 polyacrylate Polymers 0.000 claims description 7
- 229920002785 Croscarmellose sodium Polymers 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 150000008054 sulfonate salts Chemical group 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 8
- 229940063557 methacrylate Drugs 0.000 claims 8
- 229920002472 Starch Polymers 0.000 claims 6
- 239000008107 starch Substances 0.000 claims 6
- 235000019698 starch Nutrition 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims 4
- 229920000193 polymethacrylate Polymers 0.000 claims 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 2
- 229940105329 carboxymethylcellulose Drugs 0.000 claims 2
- 229920006037 cross link polymer Polymers 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- -1 polypeopylene Polymers 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000000641 cold extrusion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000000416 hydrocolloid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WWYNJERNGUHSAO-XUDSTZEESA-N (+)-Norgestrel Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](CC)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 WWYNJERNGUHSAO-XUDSTZEESA-N 0.000 description 1
- 241000743339 Agrostis Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920006266 Vinyl film Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000005392 carboxamide group Chemical class NC(=O)* 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/3179—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31794—Of cross-linked polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31884—Regenerated or modified cellulose
- Y10T428/31888—Addition polymer of hydrocarbon[s] only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31975—Of cellulosic next to another carbohydrate
Abstract
ABSTRACT OF THE DISCLOSURE
The invention provides absorbent compositions, a method for handling and immobilizing particulate absorbents and absorbent articles produced therefrom.
Absorbent materials such as cross-linked, water-soluble and water-swellable particulate polymers are immobilized and safely handled by adding thereto an aqueous liquid such as water or saline in amounts sufficient to form hydrates in which the water comprises from 20% to 80% by weight of the total hydrate. The hydrates may be extruded, sprinkled, or sprayed and can be incorporated into absorbent articles such as diaper and tampons by conventional means. The hydrates unexpectedly increase the total water absorbency of the absorbent on a dry basis.
J? 1227
The invention provides absorbent compositions, a method for handling and immobilizing particulate absorbents and absorbent articles produced therefrom.
Absorbent materials such as cross-linked, water-soluble and water-swellable particulate polymers are immobilized and safely handled by adding thereto an aqueous liquid such as water or saline in amounts sufficient to form hydrates in which the water comprises from 20% to 80% by weight of the total hydrate. The hydrates may be extruded, sprinkled, or sprayed and can be incorporated into absorbent articles such as diaper and tampons by conventional means. The hydrates unexpectedly increase the total water absorbency of the absorbent on a dry basis.
J? 1227
Description
1 ~1 8655 IMMOBILIZING PARTICULATE
ABSO BENTS BY CONVERSION TO HYDRATES
BACRGROUND OF THE INVENTION
The present invention relates to absorbent compo~itions, a method for handling and immobilizing particulate absorbents and absorbent articles produced therefrom.
~ bsorption of mobile aqueous liquids have conventionally been accompli~hed by the ~se of sponge or batting. ~ore recently, water-insoluble but water-swellable polymers having high absorptive capacity have been developed for immobilizing water and aqueous fluids.
These polymers are particula~e, i.e., pulverulent or granular and have no structural integrity. They are frequently referred to in the art as ~superabsorbents~, ~hydrogelsU or ~hydrocolloids~ and have been incorporated in the cellulosic absorbent structure of diapers, sanitary napkins and other absorbent articles to increase their absorptive efficiency. The expected advantage of incorporating these particulate materials is diminished by the shifting of the particulate materials generally requiring special construction to immobilize them within the structure of the articles.
These particulate absorbents also present a health hazard to both the manufacturers and users because the particulates can be inhaled and swell inside the respiratory passages on contact with water vapor or liquid.
In an effort to overcome these disadvantages methods of treating such parSiculate polymer6 with liquids to immobilize them have been described in the art.
For example, in U.S. Patent No. 4,410,571 immobilized superabsorbent compositions are de6cribed which are prepared by mixlng a water-insoluble, water-swellable polymer absorbent and a liquid polyhydroxy J&J 1227 organic compound auch as glycerol or ethylene glycol. In this manner the superabsorbent is converted to a non-particulate immobilized form which can be foamed and is rendered self-supporting.
In U.S. Patent No. 4,605,401, an absorption ~aterial is provided consisting of an absorbent permanently fixed on or in a support material obtained by treating the support material with a partially water-softened absorbent followed by drying. The preferred absorption material is an absorbent softened with an organic solvent containing up to 60~ water.
U.S. Patent No. 4,444,830 deals with an aqueous polymer solution containing from 5~ to 60% by weight of polymer which is formulated into an absorbent composition.
The aqueous polymer solution is coated on a base fluffing material, dried and the dried coated substrate iB
disintegrated into an absorbent hydrophilic fluff.
SUMMARY OF THE INVENTION
The present invention provides a method of safely handling or immobilizing water insoluble, water 6wellable absorbents by employing an aqueous liquid such as water as the treating medium to form an absorbent hydrate.
It has been found that water alone is an excellent adjunct for the ab~orbent rendering it safe to handle, and significantly reducing the cost of treatment of the absorbent in relation to organic liquids herein-b~fore described. It has also been found that absorbent hydrates comprising water and absorbent according to the present invention can be formed which increase the water absorbency or retention capacity of the ~uper-absorbent under pressure rather than reducing such absorbency or retention as might be expected.
The hydrates are formed by merely adding an aqueous liquid 6uch as water or saline to the super-absorbent with mixing in amounts sufficient to comprise J&J 1227 from 20~ to ~0% by weight of total composition. Theresulting hydrates may be e~trudable and can be incorpoeated into absorbent articles by conventional extrusion techniques, or ~ay be sprinkled or sprayed onto absorbent articles.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
According to the invention, the addition of water to an absorbent ~aterial immobilizes the absorbent material rendering it safe to handle. When the absorbent material iB mixed with water it can be incorporated into absorbent products such as diapers, tampons and the like.
The hydrates are themselves absorbent and based on the dry superabsorbent content of the hydrate may absorb more water than dry absorbent alone. When incorporated into absorbent material such as fluffy wood pulp they retain ~ore water than the fluffly wood pulp alone and almost as much as dry absorbent incorporated into the pulp.
The hydrates can be extruded without expanding to a uniform consistency and can be applied to a temporary or ultimate surface. The ultimate surface is hereinafter referred to as the substrate. For making a film, sheet, or coated substrate, any method of application conventionally employed for coating or preparing films, e.g. knife-coating, spray-coating, reverse-roll coating, gravure-coating, cold extrusion coating or casting, sprinkling and the l$ke, may be employed. Preferred methods are cold extrusion coating and 6prinkling.
~ hen use as a coating on a substrate is contemplated, the substrate is of materials generally employed for absorbent articles, such as cellulose, vinyl films, polypeopylene, polyester, polyethylene, nylon, metal foils, elastomers, cloth, nonwovens of various fibers, and the like. Coating on a substrate may be of the entire surface of the substrate, in ~trips, in rows, or in any other predetermined pattern.
J~J 1227 I 3 1 ~655 The amount of water used in forming the hydrates of the invention may vary from about 20~ to 80~ by weight of the total weight of the composition and pre~erably from about 30~ t~ 50% by weight of the composition, the remainder being absorbent.
The hydrates are prepared quite easi~y by merely co~bining the absorbent and wa~er with mixing until a tacky, agglo~erate is formed.
The actual amounts of absorbent in the hydrate6 within the scope previously indicated i8 dependent on the level of absorption required in ~he ultimate environment.
Thus, if the absorption is to be accomplished by a diaper, and the subctrate is a diaper pad, the hydrate will contain absorbent sufficient to supply the desired lS absorptive capacit, in the pad substrate. The hydrates are useful in the manufacture of numerous absorbent articles. They are especially useful where high capaci~y is desirable, such as in articles to be worn. Thus, they are particularly useful for diapers and incontinence pads, and also for sanitary napkins, bandages and the like. In diapers, the absorbent hydrates may be used as the sole absorbent or as a component improving the quality of the existing absorbent. In the manufacture of diapers in which the hydrate is incorporated as an improvement to the li~uid receiving portion of the diaper, the hydrate is applied to the Rurface of the aqueous liguid receiving portion of the article, namely batting, and the resulting modified batting provided with moisture impermeable backing and a moisture permeable top sheet. Alternative-ly, the absorbent hydrate may be coated on a conventionalnon-ab30rbent moisture impermeable diaper backing without batting and thereafter laminated with a conventional moisture permeable top sheet to provide a thin diaper.
In the case of sanitary napkins, the hydrates ~ay be applied to the cellulosic absorbent surface and wrapped in a conventional manner to produce a napkin of improved absorbent capacity.
J~J 1227 1 3 1 ~655 , . , In the case of bandages, the hydrates may be coated onto an aqueous liquid permeable but gel impervious ~aterial, e.g. non woven fabrics such as rayon or polyester fabrics, and then inserted in the gauze bandage.
The e~pression ~absorbent~ r~fers to ~ater-insoluble, water-swellable polymers as hereinafter described having an enhanced capacity for removing water or aqueou~ fluids. The water-insoluble, water-swellable polymers are lightly cro6s-linked polymers containing a plurality of hydrophilic groups, such as carboxyl, carboxamide, sulfonate salt or hydroxyl groups, along the polymer chain in sufficient porportions so tha~ the polymer would be water-soluble if it were not for the crosa-linking thereof. ln these polymers, the hydrophilic qroups constitute at least 25% and up to 72~ of the molecular 6tructure. The materials are of sufficient molecular weight or degree of cross-linking to be water insoluble while being water-swellable. Many of the suitable materials are those which have been reported to have an average molecular weight per cross-linkage in the range of from about 13,000 to about 300,000 but are not limited thereto. The most common and best known of such materials are polyacrylate modified polysaccharides, cross-linked ~ynthetic polyacrylates such as sodium and potas~ium poly(methacrylates), cross-linked carboxymethyl-celluloses or cross-linked poly(alkylene oxides) as hereinafter defined. Other graft polymers of poly-saccharides and natural gums such as xantham gum, locust gu~, guar gum and the like or blends thereof are al60 suitable provided they meet the requirements of water insolubility and water ~wellability. One such polymer is a 6tarch grafted polyacryla~e. The water-insoluble, water-swellable polymers have a gel capacity of at least about 10. 8y ~gel capacity~ i8 meant the weight of aqueou~ fluid which can be imbibed and held per unit weight of polymer, i.e., grams of fluid per gram of polymer. Stated another way, the absorbent polymers have J&J 1227 an ~bsorbent capacity of at least 10 times the weight of the material 1n dry form. The capacity may be up to 1500 times or more of the weight of the material in dry form;
commonly it i5 about lS to 70 times the dry weight. The materials are frequently spoken of in the art as ~hydrogels~, ~hydrocolloids~ or ~superabsorbents~. Many of the water-6wellable polymers are available commercially.
The polymers are used 1n particulate form. By ~particulate form~ i8 ~eant a ~ub6tance in the form of fine discrete particles. They may be variously shaped such as spherical, rounded, angular, acicular, irregular, or fibrous. The particles generally range in ~ize from about 1 micron to 2 x 104 microns in diameter or cross-section (largest dimension when not spherical). Theparticles are preferably of finely divided powder of particle size of from about 1 to about 103 microns.
The preferred synthetic acrylate polymer absorbents are those which have a salt group, an acid group, or which have both an amide group and a salt or acid group. These have been represented in the literature, e.g. U.S. Patent No. 3,686,024.
The invention i9 not limited to the use of water or saline alone as a treatment medium for the absorbents.
Absorbencies of hydrates made according to the invention are not significantly different if water used to wet the superabsorbent is replaced by saline. Other aqueous solutions containing dyes as urine wetness indicators or preservatives to prevent microbiological growth in the aqueous composition may be employed.
In addition to the foregoing components, the composition may have included therein minor amounts of other additives which may impart desirable properties to the absorbent product. Thus, a surface active wetting agent, particularly a non-ionic surface active agent may be included to enhance liquid uptake. A surface active J&J 1227 :'~
agent i6 of particular advantage in a~sisting vertical transport of liquids. Repre~entative surface active agentQ are those commonly described such as alkyl aryl polyether alcohols or alkyphenyl ethers of polyethylene glycol, e.g. reaction product of l-oc~ylphenol or nonylphenol with ethylene oxide. Fine fibrous cellulose such as cellulose flour, silicates and the like also have similar effect. Activated charcoal or other adsorbent may be included for odor uptake. Fragrance, coloring, etc.
~ may be included for a pleasing effect. Inert materials containing bound water such as silicates, aluminum hydrate and the like may be employed to modify the texture of the sheet. Similar results may be achieved employing slightly wet ethylene glycol or glycerol, e.g. commercial glycerine. If the absorbent immobilizing composition contains a low level of pulverulent absorbent, there i~ a slight tendency for the absorbent to settle. The composition may be modified to include small quantities of materials to af~ect its spreading properties. Suitable viscosity modifiers include silicated powders, clays, zinc oxide, inert fillers and like materials. Generally, the additives, if employed, do not constitute more than about 25~ of the total hydrate.
In order to more completely describe the present invention the following Examples are given.
Examples 1-3 In these Examplec absorbent hydrates were prepared by adding water or a 1~ aqueous sodium chloride solution (sa1ine) in separate experiments to each of three superabsorbents with stirring. Each hydrate contained about 33% by weight of superab~orbent and 67~ by weight of water. The hydrates comprised agglomerated particles of superabsorbent having a slightly tacky texture.
Teabag absorbencies of the hydrates were measured by placing 0.2 - 0.4 9 of hydrate in a teabag, stapling J&J 1227 the open end of the bag, immer~ing the bag in the saline for 10 second6, recording the uptake in weight of the bag, and also recording uptakes of the same bag at 30 seconds, and 60 ~econds. After the 60 second uptake each bag was squeezed by hand until the bag ruptured, and the new uptake recorded in order to determine the capacity of the hydrate to retain absorbed water.
As a control, dry superabsorbent was also subjected to the teabag absorbency test in each case.
Table 1 below summarizes teabag absorbencies of each dry superabsorbent, each superabsorbent hydrate and each superabsorbent hydrate calculated on the basis of the dry powder alone in the hydrate.
J&J 1227 N
C
C) .Q ~ O O O ~ c~
~1-~ ~ ~ ~ ~ ~ ~ ~D
e o ~ c~
U E~ u~
.,~ ~ ~ .,., E
O ~ 3~
U~ 5o ,~ o o c~ ~r C~D ~ ~ ~ ~ O~
O
~ ~ -~t)o ~ 0 X O U ~ O
~aa u~
O
_I ~ _I
N
~ a ~ .
.,4 co a~ ~ ~ tr P u~
~- ~q o O
~ ~ ~ ^ ~ ~ O
.cl a) o J~ ~ U7 ~ ~1 0 O ~ _ ,~ C O o~ ~ CD ~ O~
-I U ~ ~r ~ o ~C ~ O U tl; ~ ~ o o a~
_ :~
~ ¦ E E U ~ c 8~1 ,., .~ 8~ ~ o ,~
e m ~ ~ O v ~q ~ O ~ o o~
O _I ~ ~ ~ ~ ~ ~ ~ ~ o ~n ~ _,, o ~ ~ c D El ~ ~ U oO 11 \ --I ~ ~D
~ a~ ~ u D 1~3 ~ u~ o o ,~
E~ C C
~1 C ~
P ~D dP ~ ,, C
8 n ~ ~ ~
~q 8 ~n ~n o .Q ,~
a~
R
!1~ N
~ o In As Table l 6hows, in each Example, the superabsorbent in hydrate form, i.e., ba~ed on dry superabsorbent, absorb more water or saline than the dry superab60rbent alone and retains at least a~ much liquid after squeezing.
Examples 4 to 8 In the following Examples four composites each comprising an absorbent hydrate according to the inven~ion were placed between two-one gram layers of fluffed wood pulp and ~easured for absorbency on a TEF0 tester.
(Marketing/~echnology Service, Inc., Kalamazoo, Michigan).
Fluffed wood pulp i8 used as an absorbent for articles Quch as diapers. A layer of fluffy wood pulp containing no hydrate (Ex. 4) and a composite containing 0.3 9 of dry superabsorbent (Ex. 8) were used as controls. In u6ing the TEF0 tester, the composite is subjected to passage of a saline solution under pressure, and the amount of leakage of saline through the composite is determined as a measure of the composite's ability to retain the saline solution. In these Examples, 50 ml of saline solution at 7 ml/sec was poured over each composite on the tester, at pressures of lO0 pascals, (pa), 3 Kpa after 5 minutes and 5 Rpa after lO minutes.
The hydrates of the composites of Examples 5, 6 &
7 contained 0.3 9 of superabsorbent and 0~6 g of water prepared as in Examples 1-3. In the case of Example 5, the hydrate was placed in rows between the layers of fluffed wood pulp (Placed in Rows). In Example 6, the hydrate was sprinkled between the layers (Sprinkled). In Example 7, the hydrate was sprinkled between the pulp layer and allowed to stand overnight at room temperature ~Sprinkled, Stand). This allows water vapor to either combine with the superabsorbent or escape from it depending on the rel~tive humidity in the room simulating the treatment a commercial diaper would receive in which J~J 1227 1 31 ~3655 no att~ampt is made to seal th~ diape!,r ~nd preven'c water 1088 from the diaper durir,$ mainten~nce, di~tribution or storage . The super~b~orbent used in all compositea was a 3~ poly~po~a~ium ~crylate). Arasorb 720 i~ ~Arakawa Chet!n., S Inc.) ~ , Tabl~ 2 summari2es the results o the testing in terms o~ overflow and fluid re~ai~ed by the aompo~ite at the three pr~sure~.
T~ble 2 Ex. 4 ~X~ 5 Ex~ 6 Ex. 7 Ex. 8 Wood Pulp None Hyd~a~e ~ydra~e ~drate Dry Filler S::ontent Placed Sprinkled Sprinkled ~;uper-In ~ows . S~and ~b~ bent _ _ .. .
@lOQ pa Overflow O n ~.6 0.13 1.3 Fluid Retalned 4~ 45 45 43 47 ~ 3 Kpa FlUid Retained 22 ~9 ~8 30 31 5 E~pa ~0 ~lUid Re~ained . 20 :~5 2g ~6 ~7 As Ta~le 2 5hOW~, ~ll of the abo~r~ aonpo~1te~
containir~g ~uperab~o~bent hydrate hold more fluid ~der pre~sure than pUlp ~lone ~nd hold nearly a~3 m~ch f lu~d a~
the dry superabsorbent.
e /~ K
- : . - . . ; . :,.. .
ABSO BENTS BY CONVERSION TO HYDRATES
BACRGROUND OF THE INVENTION
The present invention relates to absorbent compo~itions, a method for handling and immobilizing particulate absorbents and absorbent articles produced therefrom.
~ bsorption of mobile aqueous liquids have conventionally been accompli~hed by the ~se of sponge or batting. ~ore recently, water-insoluble but water-swellable polymers having high absorptive capacity have been developed for immobilizing water and aqueous fluids.
These polymers are particula~e, i.e., pulverulent or granular and have no structural integrity. They are frequently referred to in the art as ~superabsorbents~, ~hydrogelsU or ~hydrocolloids~ and have been incorporated in the cellulosic absorbent structure of diapers, sanitary napkins and other absorbent articles to increase their absorptive efficiency. The expected advantage of incorporating these particulate materials is diminished by the shifting of the particulate materials generally requiring special construction to immobilize them within the structure of the articles.
These particulate absorbents also present a health hazard to both the manufacturers and users because the particulates can be inhaled and swell inside the respiratory passages on contact with water vapor or liquid.
In an effort to overcome these disadvantages methods of treating such parSiculate polymer6 with liquids to immobilize them have been described in the art.
For example, in U.S. Patent No. 4,410,571 immobilized superabsorbent compositions are de6cribed which are prepared by mixlng a water-insoluble, water-swellable polymer absorbent and a liquid polyhydroxy J&J 1227 organic compound auch as glycerol or ethylene glycol. In this manner the superabsorbent is converted to a non-particulate immobilized form which can be foamed and is rendered self-supporting.
In U.S. Patent No. 4,605,401, an absorption ~aterial is provided consisting of an absorbent permanently fixed on or in a support material obtained by treating the support material with a partially water-softened absorbent followed by drying. The preferred absorption material is an absorbent softened with an organic solvent containing up to 60~ water.
U.S. Patent No. 4,444,830 deals with an aqueous polymer solution containing from 5~ to 60% by weight of polymer which is formulated into an absorbent composition.
The aqueous polymer solution is coated on a base fluffing material, dried and the dried coated substrate iB
disintegrated into an absorbent hydrophilic fluff.
SUMMARY OF THE INVENTION
The present invention provides a method of safely handling or immobilizing water insoluble, water 6wellable absorbents by employing an aqueous liquid such as water as the treating medium to form an absorbent hydrate.
It has been found that water alone is an excellent adjunct for the ab~orbent rendering it safe to handle, and significantly reducing the cost of treatment of the absorbent in relation to organic liquids herein-b~fore described. It has also been found that absorbent hydrates comprising water and absorbent according to the present invention can be formed which increase the water absorbency or retention capacity of the ~uper-absorbent under pressure rather than reducing such absorbency or retention as might be expected.
The hydrates are formed by merely adding an aqueous liquid 6uch as water or saline to the super-absorbent with mixing in amounts sufficient to comprise J&J 1227 from 20~ to ~0% by weight of total composition. Theresulting hydrates may be e~trudable and can be incorpoeated into absorbent articles by conventional extrusion techniques, or ~ay be sprinkled or sprayed onto absorbent articles.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
According to the invention, the addition of water to an absorbent ~aterial immobilizes the absorbent material rendering it safe to handle. When the absorbent material iB mixed with water it can be incorporated into absorbent products such as diapers, tampons and the like.
The hydrates are themselves absorbent and based on the dry superabsorbent content of the hydrate may absorb more water than dry absorbent alone. When incorporated into absorbent material such as fluffy wood pulp they retain ~ore water than the fluffly wood pulp alone and almost as much as dry absorbent incorporated into the pulp.
The hydrates can be extruded without expanding to a uniform consistency and can be applied to a temporary or ultimate surface. The ultimate surface is hereinafter referred to as the substrate. For making a film, sheet, or coated substrate, any method of application conventionally employed for coating or preparing films, e.g. knife-coating, spray-coating, reverse-roll coating, gravure-coating, cold extrusion coating or casting, sprinkling and the l$ke, may be employed. Preferred methods are cold extrusion coating and 6prinkling.
~ hen use as a coating on a substrate is contemplated, the substrate is of materials generally employed for absorbent articles, such as cellulose, vinyl films, polypeopylene, polyester, polyethylene, nylon, metal foils, elastomers, cloth, nonwovens of various fibers, and the like. Coating on a substrate may be of the entire surface of the substrate, in ~trips, in rows, or in any other predetermined pattern.
J~J 1227 I 3 1 ~655 The amount of water used in forming the hydrates of the invention may vary from about 20~ to 80~ by weight of the total weight of the composition and pre~erably from about 30~ t~ 50% by weight of the composition, the remainder being absorbent.
The hydrates are prepared quite easi~y by merely co~bining the absorbent and wa~er with mixing until a tacky, agglo~erate is formed.
The actual amounts of absorbent in the hydrate6 within the scope previously indicated i8 dependent on the level of absorption required in ~he ultimate environment.
Thus, if the absorption is to be accomplished by a diaper, and the subctrate is a diaper pad, the hydrate will contain absorbent sufficient to supply the desired lS absorptive capacit, in the pad substrate. The hydrates are useful in the manufacture of numerous absorbent articles. They are especially useful where high capaci~y is desirable, such as in articles to be worn. Thus, they are particularly useful for diapers and incontinence pads, and also for sanitary napkins, bandages and the like. In diapers, the absorbent hydrates may be used as the sole absorbent or as a component improving the quality of the existing absorbent. In the manufacture of diapers in which the hydrate is incorporated as an improvement to the li~uid receiving portion of the diaper, the hydrate is applied to the Rurface of the aqueous liguid receiving portion of the article, namely batting, and the resulting modified batting provided with moisture impermeable backing and a moisture permeable top sheet. Alternative-ly, the absorbent hydrate may be coated on a conventionalnon-ab30rbent moisture impermeable diaper backing without batting and thereafter laminated with a conventional moisture permeable top sheet to provide a thin diaper.
In the case of sanitary napkins, the hydrates ~ay be applied to the cellulosic absorbent surface and wrapped in a conventional manner to produce a napkin of improved absorbent capacity.
J~J 1227 1 3 1 ~655 , . , In the case of bandages, the hydrates may be coated onto an aqueous liquid permeable but gel impervious ~aterial, e.g. non woven fabrics such as rayon or polyester fabrics, and then inserted in the gauze bandage.
The e~pression ~absorbent~ r~fers to ~ater-insoluble, water-swellable polymers as hereinafter described having an enhanced capacity for removing water or aqueou~ fluids. The water-insoluble, water-swellable polymers are lightly cro6s-linked polymers containing a plurality of hydrophilic groups, such as carboxyl, carboxamide, sulfonate salt or hydroxyl groups, along the polymer chain in sufficient porportions so tha~ the polymer would be water-soluble if it were not for the crosa-linking thereof. ln these polymers, the hydrophilic qroups constitute at least 25% and up to 72~ of the molecular 6tructure. The materials are of sufficient molecular weight or degree of cross-linking to be water insoluble while being water-swellable. Many of the suitable materials are those which have been reported to have an average molecular weight per cross-linkage in the range of from about 13,000 to about 300,000 but are not limited thereto. The most common and best known of such materials are polyacrylate modified polysaccharides, cross-linked ~ynthetic polyacrylates such as sodium and potas~ium poly(methacrylates), cross-linked carboxymethyl-celluloses or cross-linked poly(alkylene oxides) as hereinafter defined. Other graft polymers of poly-saccharides and natural gums such as xantham gum, locust gu~, guar gum and the like or blends thereof are al60 suitable provided they meet the requirements of water insolubility and water ~wellability. One such polymer is a 6tarch grafted polyacryla~e. The water-insoluble, water-swellable polymers have a gel capacity of at least about 10. 8y ~gel capacity~ i8 meant the weight of aqueou~ fluid which can be imbibed and held per unit weight of polymer, i.e., grams of fluid per gram of polymer. Stated another way, the absorbent polymers have J&J 1227 an ~bsorbent capacity of at least 10 times the weight of the material 1n dry form. The capacity may be up to 1500 times or more of the weight of the material in dry form;
commonly it i5 about lS to 70 times the dry weight. The materials are frequently spoken of in the art as ~hydrogels~, ~hydrocolloids~ or ~superabsorbents~. Many of the water-6wellable polymers are available commercially.
The polymers are used 1n particulate form. By ~particulate form~ i8 ~eant a ~ub6tance in the form of fine discrete particles. They may be variously shaped such as spherical, rounded, angular, acicular, irregular, or fibrous. The particles generally range in ~ize from about 1 micron to 2 x 104 microns in diameter or cross-section (largest dimension when not spherical). Theparticles are preferably of finely divided powder of particle size of from about 1 to about 103 microns.
The preferred synthetic acrylate polymer absorbents are those which have a salt group, an acid group, or which have both an amide group and a salt or acid group. These have been represented in the literature, e.g. U.S. Patent No. 3,686,024.
The invention i9 not limited to the use of water or saline alone as a treatment medium for the absorbents.
Absorbencies of hydrates made according to the invention are not significantly different if water used to wet the superabsorbent is replaced by saline. Other aqueous solutions containing dyes as urine wetness indicators or preservatives to prevent microbiological growth in the aqueous composition may be employed.
In addition to the foregoing components, the composition may have included therein minor amounts of other additives which may impart desirable properties to the absorbent product. Thus, a surface active wetting agent, particularly a non-ionic surface active agent may be included to enhance liquid uptake. A surface active J&J 1227 :'~
agent i6 of particular advantage in a~sisting vertical transport of liquids. Repre~entative surface active agentQ are those commonly described such as alkyl aryl polyether alcohols or alkyphenyl ethers of polyethylene glycol, e.g. reaction product of l-oc~ylphenol or nonylphenol with ethylene oxide. Fine fibrous cellulose such as cellulose flour, silicates and the like also have similar effect. Activated charcoal or other adsorbent may be included for odor uptake. Fragrance, coloring, etc.
~ may be included for a pleasing effect. Inert materials containing bound water such as silicates, aluminum hydrate and the like may be employed to modify the texture of the sheet. Similar results may be achieved employing slightly wet ethylene glycol or glycerol, e.g. commercial glycerine. If the absorbent immobilizing composition contains a low level of pulverulent absorbent, there i~ a slight tendency for the absorbent to settle. The composition may be modified to include small quantities of materials to af~ect its spreading properties. Suitable viscosity modifiers include silicated powders, clays, zinc oxide, inert fillers and like materials. Generally, the additives, if employed, do not constitute more than about 25~ of the total hydrate.
In order to more completely describe the present invention the following Examples are given.
Examples 1-3 In these Examplec absorbent hydrates were prepared by adding water or a 1~ aqueous sodium chloride solution (sa1ine) in separate experiments to each of three superabsorbents with stirring. Each hydrate contained about 33% by weight of superab~orbent and 67~ by weight of water. The hydrates comprised agglomerated particles of superabsorbent having a slightly tacky texture.
Teabag absorbencies of the hydrates were measured by placing 0.2 - 0.4 9 of hydrate in a teabag, stapling J&J 1227 the open end of the bag, immer~ing the bag in the saline for 10 second6, recording the uptake in weight of the bag, and also recording uptakes of the same bag at 30 seconds, and 60 ~econds. After the 60 second uptake each bag was squeezed by hand until the bag ruptured, and the new uptake recorded in order to determine the capacity of the hydrate to retain absorbed water.
As a control, dry superabsorbent was also subjected to the teabag absorbency test in each case.
Table 1 below summarizes teabag absorbencies of each dry superabsorbent, each superabsorbent hydrate and each superabsorbent hydrate calculated on the basis of the dry powder alone in the hydrate.
J&J 1227 N
C
C) .Q ~ O O O ~ c~
~1-~ ~ ~ ~ ~ ~ ~ ~D
e o ~ c~
U E~ u~
.,~ ~ ~ .,., E
O ~ 3~
U~ 5o ,~ o o c~ ~r C~D ~ ~ ~ ~ O~
O
~ ~ -~t)o ~ 0 X O U ~ O
~aa u~
O
_I ~ _I
N
~ a ~ .
.,4 co a~ ~ ~ tr P u~
~- ~q o O
~ ~ ~ ^ ~ ~ O
.cl a) o J~ ~ U7 ~ ~1 0 O ~ _ ,~ C O o~ ~ CD ~ O~
-I U ~ ~r ~ o ~C ~ O U tl; ~ ~ o o a~
_ :~
~ ¦ E E U ~ c 8~1 ,., .~ 8~ ~ o ,~
e m ~ ~ O v ~q ~ O ~ o o~
O _I ~ ~ ~ ~ ~ ~ ~ ~ o ~n ~ _,, o ~ ~ c D El ~ ~ U oO 11 \ --I ~ ~D
~ a~ ~ u D 1~3 ~ u~ o o ,~
E~ C C
~1 C ~
P ~D dP ~ ,, C
8 n ~ ~ ~
~q 8 ~n ~n o .Q ,~
a~
R
!1~ N
~ o In As Table l 6hows, in each Example, the superabsorbent in hydrate form, i.e., ba~ed on dry superabsorbent, absorb more water or saline than the dry superab60rbent alone and retains at least a~ much liquid after squeezing.
Examples 4 to 8 In the following Examples four composites each comprising an absorbent hydrate according to the inven~ion were placed between two-one gram layers of fluffed wood pulp and ~easured for absorbency on a TEF0 tester.
(Marketing/~echnology Service, Inc., Kalamazoo, Michigan).
Fluffed wood pulp i8 used as an absorbent for articles Quch as diapers. A layer of fluffy wood pulp containing no hydrate (Ex. 4) and a composite containing 0.3 9 of dry superabsorbent (Ex. 8) were used as controls. In u6ing the TEF0 tester, the composite is subjected to passage of a saline solution under pressure, and the amount of leakage of saline through the composite is determined as a measure of the composite's ability to retain the saline solution. In these Examples, 50 ml of saline solution at 7 ml/sec was poured over each composite on the tester, at pressures of lO0 pascals, (pa), 3 Kpa after 5 minutes and 5 Rpa after lO minutes.
The hydrates of the composites of Examples 5, 6 &
7 contained 0.3 9 of superabsorbent and 0~6 g of water prepared as in Examples 1-3. In the case of Example 5, the hydrate was placed in rows between the layers of fluffed wood pulp (Placed in Rows). In Example 6, the hydrate was sprinkled between the layers (Sprinkled). In Example 7, the hydrate was sprinkled between the pulp layer and allowed to stand overnight at room temperature ~Sprinkled, Stand). This allows water vapor to either combine with the superabsorbent or escape from it depending on the rel~tive humidity in the room simulating the treatment a commercial diaper would receive in which J~J 1227 1 31 ~3655 no att~ampt is made to seal th~ diape!,r ~nd preven'c water 1088 from the diaper durir,$ mainten~nce, di~tribution or storage . The super~b~orbent used in all compositea was a 3~ poly~po~a~ium ~crylate). Arasorb 720 i~ ~Arakawa Chet!n., S Inc.) ~ , Tabl~ 2 summari2es the results o the testing in terms o~ overflow and fluid re~ai~ed by the aompo~ite at the three pr~sure~.
T~ble 2 Ex. 4 ~X~ 5 Ex~ 6 Ex. 7 Ex. 8 Wood Pulp None Hyd~a~e ~ydra~e ~drate Dry Filler S::ontent Placed Sprinkled Sprinkled ~;uper-In ~ows . S~and ~b~ bent _ _ .. .
@lOQ pa Overflow O n ~.6 0.13 1.3 Fluid Retalned 4~ 45 45 43 47 ~ 3 Kpa FlUid Retained 22 ~9 ~8 30 31 5 E~pa ~0 ~lUid Re~ained . 20 :~5 2g ~6 ~7 As Ta~le 2 5hOW~, ~ll of the abo~r~ aonpo~1te~
containir~g ~uperab~o~bent hydrate hold more fluid ~der pre~sure than pUlp ~lone ~nd hold nearly a~3 m~ch f lu~d a~
the dry superabsorbent.
e /~ K
- : . - . . ; . :,.. .
Claims (24)
1. An absorbent hydrate comprising a mixture of (a) a particulate water-insoluble, water-swellable absorbent polymer; and (b) an aqueous liquid.
2. The absorbent hydrate of claim 1 wherein said aqueous liquid is water.
3. The absorbent past of claim 1 wherein said aqueous liquid is saline.
4. The absorbent hydrate of claim 1 wherein said absorbent polymer is a cross-linked polymer containing a plurality of hydrophilic groups selected from the group consisting of carboxyl, carboxamide, sulfonate salt and hydroxyl.
5. The absorbent hydrate of claim 1 wherein said absorbent polymer is a polysodium acrylate or polysodium meth-acrylate.
6. The absorbent hydrate of claim 1 wherein said absorbent polymer is a polypotassium acrylate or polypotassium methacrylate.
7. The absorbent hydrate of claim 1 wherein said absorbent polymer is a starch grafted polyacrylate or polymeth-acrylate.
8. The Absorbent hydrate of claim 1 wherein said absorbent polymer is a cross-linked carboxy methyl cellulose.
9. An absorbent hydrate comprising a mixture of (a) a cross-linked particulate water-insoluble, water-swellable absorbent polymer selected from the group consisting of a polysodium acrylate, a polysodium J&J 1227 methacrylate, polypotassium acrylate, polypotassium methacrylate, a starch grafted polyacrylate, a starch grafted polymethacrylate, and carboxy methyl cellulose;
and (b) from 20% to 80% by weight of the total weight of said hydrate of an aqueous liquid.
and (b) from 20% to 80% by weight of the total weight of said hydrate of an aqueous liquid.
10. The absorbent hydrate of claim 9 wherein said aqueous liquid is selected from the group consisting of water and saline.
11. The absorbent hydrate of claim 9 wherein said aqueous liquid comprises from 30% to 50% by weight of the total weight of said hydrate.
12. An absorbent article containg the absorbent hydrate of claim 1.
13. An absorbent article containing the absorbent hydrate of claim 9.
14. A method for immobilizing a particulate water-insoluble, water swellable absorbent polymer comprising combining an aqueous liquid with said polymer to form a hydrate.
15. The method of claim 14 wherein said aqueous liquid is water.
16. The method of claim 14 wherein said aqueous liquid is saline.
17. The method of claim 14 wherein said absorbent polymer is a cross-linked polymer containing a plurality of hydrophilic groups selected from the group consisting of carboxyl, carboxamide, sulfonate salt and hydroxyl.
J&J 1227
J&J 1227
18. The method of claim 14 wherein said absorbent polymer is a polysodium acrylate or polysodium methacrylate.
19. The method of claim 14 wherein said absorbent polymer is a polypotassium acrylate or polypotassium methacrylate.
20. The method of claim 14 wherein said absorbent polymer is a starch grafted polyacrylate or polymethacrylate.
21. The method of claim 14 wherein said absorbent polymer is a cross-linked carboxy methyl cellulose.
22. A method for immobilizinq a cross-linked particulate water-insoluble water-swellable absorbent polymer selected from the group consisting of a polysodium acrylate, a polysodium methacrylate, polypotassium acrylate, polypotassium methacrylate, a starch grafted polyacrylate, a starch grafted polymethacrylate, and carboxy methyl cellulose comprising combining an aqueous liquid with said polymer to form a hydrate wherein the aqueous liquid comprises from 20% to 80% by weight of the total hydrate.
23. The method of claim 22 wherein said aqueous liquid is selected from the group consisting of water and saline.
24. The method of claim 22 wherein said aqueous liquid comprises from 30% to 50% by weight of the total weight of said hydrate.
J&J 1227
J&J 1227
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US07098650 US4826880B1 (en) | 1987-09-21 | 1987-09-21 | Immobilizing particulate absorbents by conversion to hydrates |
US98,650 | 1987-09-21 |
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CA1318655C true CA1318655C (en) | 1993-06-01 |
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CA000577822A Expired - Fee Related CA1318655C (en) | 1987-09-21 | 1988-09-19 | Immobilizing particulate absorbents by conversion to hydrates |
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US (1) | US4826880B1 (en) |
EP (1) | EP0309187B1 (en) |
JP (1) | JPH01230671A (en) |
AR (1) | AR247751A1 (en) |
AT (1) | ATE182471T1 (en) |
AU (1) | AU2223788A (en) |
BR (1) | BR8804860A (en) |
CA (1) | CA1318655C (en) |
DE (1) | DE3856353T2 (en) |
ES (1) | ES2133267T3 (en) |
GR (1) | GR1000150B (en) |
MX (1) | MX165440B (en) |
PH (1) | PH24708A (en) |
PT (1) | PT88560B (en) |
ZA (1) | ZA887023B (en) |
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CN104780885A (en) | 2012-11-13 | 2015-07-15 | 宝洁公司 | Absorbent articles with channels and signals |
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US9216116B2 (en) | 2012-12-10 | 2015-12-22 | The Procter & Gamble Company | Absorbent articles with channels |
US10639215B2 (en) | 2012-12-10 | 2020-05-05 | The Procter & Gamble Company | Absorbent articles with channels and/or pockets |
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PL2740452T3 (en) | 2012-12-10 | 2022-01-31 | The Procter & Gamble Company | Absorbent article with high absorbent material content |
ES2655690T3 (en) | 2013-06-14 | 2018-02-21 | The Procter & Gamble Company | Absorbent article and absorbent core formation channels when wet |
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PL2886092T3 (en) | 2013-12-19 | 2017-03-31 | The Procter And Gamble Company | Absorbent cores having channel-forming areas and c-wrap seals |
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EP2949302B1 (en) | 2014-05-27 | 2018-04-18 | The Procter and Gamble Company | Absorbent core with curved channel-forming areas |
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EP2949300B1 (en) | 2014-05-27 | 2017-08-02 | The Procter and Gamble Company | Absorbent core with absorbent material pattern |
PL2949299T3 (en) | 2014-05-27 | 2018-01-31 | Procter & Gamble | Absorbent core with absorbent material pattern |
DE112016001234T5 (en) | 2015-03-16 | 2017-12-14 | The Procter & Gamble Company | ABSORPTIONS WITH IMPROVED CORE |
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MX2017014428A (en) | 2015-05-12 | 2018-04-10 | Procter & Gamble | Absorbent article with improved core-to-backsheet adhesive. |
US10543129B2 (en) | 2015-05-29 | 2020-01-28 | The Procter & Gamble Company | Absorbent articles having channels and wetness indicator |
EP3167859B1 (en) | 2015-11-16 | 2020-05-06 | The Procter and Gamble Company | Absorbent cores having material free areas |
EP3238676B1 (en) | 2016-04-29 | 2019-01-02 | The Procter and Gamble Company | Absorbent core with profiled distribution of absorbent material |
EP3238678B1 (en) | 2016-04-29 | 2019-02-27 | The Procter and Gamble Company | Absorbent core with transversal folding lines |
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-
1987
- 1987-09-21 US US07098650 patent/US4826880B1/en not_active Expired - Lifetime
-
1988
- 1988-09-14 AU AU22237/88A patent/AU2223788A/en not_active Abandoned
- 1988-09-16 GR GR880100616A patent/GR1000150B/en not_active IP Right Cessation
- 1988-09-19 CA CA000577822A patent/CA1318655C/en not_active Expired - Fee Related
- 1988-09-19 MX MX013069A patent/MX165440B/en unknown
- 1988-09-20 ES ES88308683T patent/ES2133267T3/en not_active Expired - Lifetime
- 1988-09-20 BR BR8804860A patent/BR8804860A/en not_active IP Right Cessation
- 1988-09-20 PT PT88560A patent/PT88560B/en not_active IP Right Cessation
- 1988-09-20 ZA ZA887023A patent/ZA887023B/en unknown
- 1988-09-20 AT AT88308683T patent/ATE182471T1/en not_active IP Right Cessation
- 1988-09-20 DE DE3856353T patent/DE3856353T2/en not_active Expired - Fee Related
- 1988-09-20 AR AR88311989A patent/AR247751A1/en active
- 1988-09-20 PH PH37566A patent/PH24708A/en unknown
- 1988-09-20 EP EP88308683A patent/EP0309187B1/en not_active Revoked
- 1988-09-20 JP JP63233830A patent/JPH01230671A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0309187B1 (en) | 1999-07-28 |
DE3856353D1 (en) | 1999-09-02 |
EP0309187A2 (en) | 1989-03-29 |
PT88560B (en) | 1993-05-31 |
GR880100616A (en) | 1989-06-22 |
ZA887023B (en) | 1990-05-30 |
PT88560A (en) | 1989-07-31 |
US4826880B1 (en) | 2000-04-25 |
ES2133267T3 (en) | 1999-09-16 |
BR8804860A (en) | 1989-04-25 |
GR1000150B (en) | 1991-09-27 |
DE3856353T2 (en) | 2000-01-13 |
PH24708A (en) | 1990-10-01 |
EP0309187A3 (en) | 1989-08-23 |
MX165440B (en) | 1992-11-11 |
ATE182471T1 (en) | 1999-08-15 |
AR247751A1 (en) | 1995-03-31 |
US4826880A (en) | 1989-05-02 |
AU2223788A (en) | 1989-04-20 |
JPH01230671A (en) | 1989-09-14 |
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MKLA | Lapsed |