CA1324258C - Methods of and apparatus for coating optical fiber and products produced thereby - Google Patents
Methods of and apparatus for coating optical fiber and products produced therebyInfo
- Publication number
- CA1324258C CA1324258C CA000576145A CA576145A CA1324258C CA 1324258 C CA1324258 C CA 1324258C CA 000576145 A CA000576145 A CA 000576145A CA 576145 A CA576145 A CA 576145A CA 1324258 C CA1324258 C CA 1324258C
- Authority
- CA
- Canada
- Prior art keywords
- optical fiber
- coating material
- flow path
- path
- die
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/12—General methods of coating; Devices therefor
- C03C25/18—Extrusion
Abstract
Methods of and Apparatus For Coating Optical Fiber and Products Produced Thereby Abstract An optical fiber (21) which has been drawn from a preform (22) is moved into and through a chamber (38) of a housing. A source of vacuum is connected to the chamber to prevent the attachment of air pockets to the optical fiber as it is being moved through the chamber and through an opening of a die. The die includes a flow path (55) which is substantially normal to the path of travel of the optical fiber and the die opening is substantially larger than the diameter of the optical fiber. The thickness of the flow path in a direction along the path of travel is sufficiently small so as to prevent the recirculation of the coating material inthe vicinity of the point of application to the optical fiber. Also, the fiber draw rate, the pressure of the coating material the direction of the flow path relative to the longitudinal axis of the optical fiber and the diameter of the die opening are such that a gap forms between the coating material and the die. That gap is allowed to be maintained because of the pressure differential between ambient atmosphere and the chamber. As a result, the coating material as it leaves the disc-like flow path and is directed toward the optical fiber is bounded by free surfaces instead of by solid surfaces in the immediate vicinity of where it is applied to the optical fiber. This prevents the development of shear fields and allows the diameter of the coated optical fiber to be varied.
Description
" 13242~
Methods of and Apparatus For Coating Optical Fiber and Products Produced Thereby .~
Technical Field This invention relates to methods of and apparatus for coating 5 optical fiber and products produced thereby.
Back~cround of the In~ention Because the surface of optical f~lber is very susceptible to damage caused by abrasion, it becomes necessary to coat the optical fiber, after it is drawn, before it comes into contact with any surface. If stresses placed on 10 the fiber result in a random bending distortion of the flber axis with periodic components in the millimeter range, light rays, or modes, propagating in the fiber may escape from the core. These losses, termed microbending losses, may be very large, often many times the intrinsic loss of the fiber itself. The flber must be isolated from stresses which cause 15 microbending. The properties of fiber coating play a major role in providing this isolation, with coating geometry, modulus and thermal expansion coefficient being the most important factors.
Inasmuch as the application of the coating material must not damage the glass surface, the coating material is applied in a liquid state.
20 Once applied, the coating material must become solidified rapidly before the optical fiber reaches the capstan. This may be accomplished by photocuring, for example.
Those optical fiber performance properties which are affected most by the coating are strength and transmission loss. Coating defects 25 which may expose the optical fiber to subsequent damage arise primarily from improper application of the coating material. Defects such as large bubbles or voids, non-concentric coatings with unacceptably thi~ regions, or intermittent coatings must be overcome.
Two types of coating materials are used commonly. Single 30 coatings, employing a relatively high modulus, e.g. 10~Pa, or an intermediate modulus, e.g. 108Pa, are used i~ applications requiring high fiber strength~ or in cables which employ buffer tubes where fiber sensitivity to microbending is not a significant problem. ~p . :
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: -` 1324258 : .
- The problem of coating optical fibers becomes more complicated because of the functions the coating material must perform. Dual coated optical fibers increasingly are becoming used to obtain design flexibility and improYed performance. Typically, a first or primary coating layer that 5 comprises a relatively low modulus material, e.g. 106-107Pa, is applied to the optical fiber. Such a material reduces microbending losses associated with the cabling, installation or environmental changes during the service ` life of the optical fiber. An outer or secondary coating layer comprising a relatively high modulus material is applied over the primary layer. The 10 outer coating layer is usually of a higher modulus material to provide J, abrasion resistance and low friction for the fiber and the primary coating 3~ layer. This structure isolates the fiber very well from external stresses which would tend to cause local bending. Such stresses may be imposed in two distinct ways. First, non-uniform lateral stresses, imposed by the cable 15 structure surrounding the fiber, may cause bending with periodic components in the microbending regime. The dual coating serves to cushion the optical fiber via the primary layer and to distribute the imposed forces via the secondary layer, so as to isolate the optical fiber from bending moments. Secondly, axial compressive loading of the optical fiber occurs 3 20 when the surrounding cable components contract relative to the fiber. Such contraction results from both the differential thermal contraction of cable materials relative to the glass fiber and from the viscoelastic recovery of residual orientation pre~ent in the cable materials. If the axial compressive load imposed on the optical fiber becomes large enough, the fiber will 25 respond by bending or buckling. The low modulus primary coating is effective in promoting long bending periods for the fiber which are outside the microbending range.
In one method of applying dual layers of coating materials to a moving optical fiber that i9 disclosed in U.S. Patent 4,474,830, an optical 30 fiber is passed through a coating applicator which includes first and second dies. The first die confines a first coating liquid which is maintained at a predetermined level in a reservoir above the first die over a portion of the fiber's length. A second coating liquid is ap~lied onto the optical fiber through a clearance between the first and second dies. The clearance is 35 sufficiently small so that substantially no circulation of the second coatingliquid occurs in the vicinity of the point of application to the fiber. The , . . . . : . . ~ . , ~
~.7 ~32~2~8 second coating liquid which is applied includes a free surface in the immediate vicinity of the point of application to the fiber.
; Notwithstanding the success of the above-described arrangement, efforts have continued to apply a coating material to an S optical fiber as the fiber is being moved at higher and higher manufacturing line speeds. Wanted is a system in which a coating material need not be maintained at a particular level and which does not require the system to hold a relatively large quantity of coating material that must be removed prior to cleaning and other maintenance. Further, it long has been a desire 10 to improve the stringing up of an optical fiber on a draw tower and to reduce the amount of cooling which the optical fiber must experience after being drawn but prior to being coated.
Seemingly, the prior art does not include a coating arrangement which applies two coatings within a single applicator at relatively high line 15 speeds, and which facilitates the string-up of the optical fiber with reducedcooling prior to coating. The sought-after methods and apparatus for coating should be easily and inexpensively implemented.
Summar~ of the Invent;on The foregoing problems have been overcome by the methods and 20 apparatus of this invention. In accordance with methods of this invention, after an optical fiber ha~ been drawn from a preform, it is moved through a 3, chamber in a housing. A pressure differential is established between the chamber and the ambient atmosphere outside the housing. Then successive increments of length of the optical fiber are moved past a disc-like flow path 25 which has at least a component that is normal to the path of travel of the optical fiber and then through a die opening which is substantially larger than the cross-sectional area of the optical fiber. As a result of the cooperation among the pressure feed of the coating material, the speed at which the fiber is moved, the size of the die opening and the normal } 30 component of the flow path, the coating material as it leaves the flow path and i~ directed toward engagement with the fiber becomes bounded by free ~3 ~urfaces. The pressure differential not only allow~ the free surfaces to exist but also avoids the formation of bubbles in ~,he coating material. The coating material is caused to be flowed along the flow path in a direction 35 generally radially inwardly toward the path of travel of the optical fiber into engagement with the optical fiber as it is moved through the die opening.
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`- 13242~8 ~, In a preferred embodiment, the pressure di~ferential is established by connecting the chamber to a source of vacuum. Further, in the preferred embodiment, two vacuum chambers, one after the other, in the path of travel of the optical fiber, are used. This 7 arrangement enhances the bubble-free characteristics of the coating material, particularly when dual coatings are being applied to the moving optical fiber.
In accordance with one aspect of the invention there is provided a method of making an optical fiber having a layer of a coating material thereon, said method including the steps of drawing an optical fiber from a preform, moving the drawn fiber along a path of travel into and through a chamber in a housing, moving the optical fiber from the chamber past a disc-like flow path which has at least a component that is normal to the path of travel of the optical fiber and then through an opening of a die, the die opening being substantially larger than the diameter of the coated fiber, and being characterized by the steps of: establishing a pressure ~' differential between the chamber and ambient atmosphere such that ambient pressure is greater than that in the chamber; while causing a coating material to be flowed along the flow path , 15 generally radially inwardly toward the path of travel into engagement with the moving optical fiber to coat the fiber as it is through the die opening, the thickness of the flow path in a ' direction along the path of travel being such that substantially no recirculation of the coating material occurs in the vicinity of the application of the coating material to the optical fiber and wherein the size of the die opening, the direction of the flow path and the steps of moving the ~7, 20 drawn fiber and causing the coating material to be flowed along the flow path are such as to cause a gap to be formed between the coating material and an adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
In accordance with another aspect of the invention there is provided an apparatus for making an optical fiber having a layer of a coating material thereon, said apparatus including ' means for drawing an optical fiber from a preform, a housing which includes a chamber, a die having an opening which is aligned with said chamber and which is substantially larger than the diameter of the optical fiber, and moving means for advancing the drawn fiber along a path of travel into and through the chamber in the housing and through said die opening; said apparatus ~i 30 being characterized by: means for establishing a pressure differential between said chamber and 7 ambient atmosphere such that the ambient pressure exceeds that in said chamber; guiding means spaced interposed between said chamber and said die opening and including a disc-like flow path which has at least a component which is normal to the path of travel of the optical fiber for directing a coating material into engagement with the moving optical fiber; diameter of the fiber;
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Methods of and Apparatus For Coating Optical Fiber and Products Produced Thereby .~
Technical Field This invention relates to methods of and apparatus for coating 5 optical fiber and products produced thereby.
Back~cround of the In~ention Because the surface of optical f~lber is very susceptible to damage caused by abrasion, it becomes necessary to coat the optical fiber, after it is drawn, before it comes into contact with any surface. If stresses placed on 10 the fiber result in a random bending distortion of the flber axis with periodic components in the millimeter range, light rays, or modes, propagating in the fiber may escape from the core. These losses, termed microbending losses, may be very large, often many times the intrinsic loss of the fiber itself. The flber must be isolated from stresses which cause 15 microbending. The properties of fiber coating play a major role in providing this isolation, with coating geometry, modulus and thermal expansion coefficient being the most important factors.
Inasmuch as the application of the coating material must not damage the glass surface, the coating material is applied in a liquid state.
20 Once applied, the coating material must become solidified rapidly before the optical fiber reaches the capstan. This may be accomplished by photocuring, for example.
Those optical fiber performance properties which are affected most by the coating are strength and transmission loss. Coating defects 25 which may expose the optical fiber to subsequent damage arise primarily from improper application of the coating material. Defects such as large bubbles or voids, non-concentric coatings with unacceptably thi~ regions, or intermittent coatings must be overcome.
Two types of coating materials are used commonly. Single 30 coatings, employing a relatively high modulus, e.g. 10~Pa, or an intermediate modulus, e.g. 108Pa, are used i~ applications requiring high fiber strength~ or in cables which employ buffer tubes where fiber sensitivity to microbending is not a significant problem. ~p . :
- .
: -` 1324258 : .
- The problem of coating optical fibers becomes more complicated because of the functions the coating material must perform. Dual coated optical fibers increasingly are becoming used to obtain design flexibility and improYed performance. Typically, a first or primary coating layer that 5 comprises a relatively low modulus material, e.g. 106-107Pa, is applied to the optical fiber. Such a material reduces microbending losses associated with the cabling, installation or environmental changes during the service ` life of the optical fiber. An outer or secondary coating layer comprising a relatively high modulus material is applied over the primary layer. The 10 outer coating layer is usually of a higher modulus material to provide J, abrasion resistance and low friction for the fiber and the primary coating 3~ layer. This structure isolates the fiber very well from external stresses which would tend to cause local bending. Such stresses may be imposed in two distinct ways. First, non-uniform lateral stresses, imposed by the cable 15 structure surrounding the fiber, may cause bending with periodic components in the microbending regime. The dual coating serves to cushion the optical fiber via the primary layer and to distribute the imposed forces via the secondary layer, so as to isolate the optical fiber from bending moments. Secondly, axial compressive loading of the optical fiber occurs 3 20 when the surrounding cable components contract relative to the fiber. Such contraction results from both the differential thermal contraction of cable materials relative to the glass fiber and from the viscoelastic recovery of residual orientation pre~ent in the cable materials. If the axial compressive load imposed on the optical fiber becomes large enough, the fiber will 25 respond by bending or buckling. The low modulus primary coating is effective in promoting long bending periods for the fiber which are outside the microbending range.
In one method of applying dual layers of coating materials to a moving optical fiber that i9 disclosed in U.S. Patent 4,474,830, an optical 30 fiber is passed through a coating applicator which includes first and second dies. The first die confines a first coating liquid which is maintained at a predetermined level in a reservoir above the first die over a portion of the fiber's length. A second coating liquid is ap~lied onto the optical fiber through a clearance between the first and second dies. The clearance is 35 sufficiently small so that substantially no circulation of the second coatingliquid occurs in the vicinity of the point of application to the fiber. The , . . . . : . . ~ . , ~
~.7 ~32~2~8 second coating liquid which is applied includes a free surface in the immediate vicinity of the point of application to the fiber.
; Notwithstanding the success of the above-described arrangement, efforts have continued to apply a coating material to an S optical fiber as the fiber is being moved at higher and higher manufacturing line speeds. Wanted is a system in which a coating material need not be maintained at a particular level and which does not require the system to hold a relatively large quantity of coating material that must be removed prior to cleaning and other maintenance. Further, it long has been a desire 10 to improve the stringing up of an optical fiber on a draw tower and to reduce the amount of cooling which the optical fiber must experience after being drawn but prior to being coated.
Seemingly, the prior art does not include a coating arrangement which applies two coatings within a single applicator at relatively high line 15 speeds, and which facilitates the string-up of the optical fiber with reducedcooling prior to coating. The sought-after methods and apparatus for coating should be easily and inexpensively implemented.
Summar~ of the Invent;on The foregoing problems have been overcome by the methods and 20 apparatus of this invention. In accordance with methods of this invention, after an optical fiber ha~ been drawn from a preform, it is moved through a 3, chamber in a housing. A pressure differential is established between the chamber and the ambient atmosphere outside the housing. Then successive increments of length of the optical fiber are moved past a disc-like flow path 25 which has at least a component that is normal to the path of travel of the optical fiber and then through a die opening which is substantially larger than the cross-sectional area of the optical fiber. As a result of the cooperation among the pressure feed of the coating material, the speed at which the fiber is moved, the size of the die opening and the normal } 30 component of the flow path, the coating material as it leaves the flow path and i~ directed toward engagement with the fiber becomes bounded by free ~3 ~urfaces. The pressure differential not only allow~ the free surfaces to exist but also avoids the formation of bubbles in ~,he coating material. The coating material is caused to be flowed along the flow path in a direction 35 generally radially inwardly toward the path of travel of the optical fiber into engagement with the optical fiber as it is moved through the die opening.
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`- 13242~8 ~, In a preferred embodiment, the pressure di~ferential is established by connecting the chamber to a source of vacuum. Further, in the preferred embodiment, two vacuum chambers, one after the other, in the path of travel of the optical fiber, are used. This 7 arrangement enhances the bubble-free characteristics of the coating material, particularly when dual coatings are being applied to the moving optical fiber.
In accordance with one aspect of the invention there is provided a method of making an optical fiber having a layer of a coating material thereon, said method including the steps of drawing an optical fiber from a preform, moving the drawn fiber along a path of travel into and through a chamber in a housing, moving the optical fiber from the chamber past a disc-like flow path which has at least a component that is normal to the path of travel of the optical fiber and then through an opening of a die, the die opening being substantially larger than the diameter of the coated fiber, and being characterized by the steps of: establishing a pressure ~' differential between the chamber and ambient atmosphere such that ambient pressure is greater than that in the chamber; while causing a coating material to be flowed along the flow path , 15 generally radially inwardly toward the path of travel into engagement with the moving optical fiber to coat the fiber as it is through the die opening, the thickness of the flow path in a ' direction along the path of travel being such that substantially no recirculation of the coating material occurs in the vicinity of the application of the coating material to the optical fiber and wherein the size of the die opening, the direction of the flow path and the steps of moving the ~7, 20 drawn fiber and causing the coating material to be flowed along the flow path are such as to cause a gap to be formed between the coating material and an adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
In accordance with another aspect of the invention there is provided an apparatus for making an optical fiber having a layer of a coating material thereon, said apparatus including ' means for drawing an optical fiber from a preform, a housing which includes a chamber, a die having an opening which is aligned with said chamber and which is substantially larger than the diameter of the optical fiber, and moving means for advancing the drawn fiber along a path of travel into and through the chamber in the housing and through said die opening; said apparatus ~i 30 being characterized by: means for establishing a pressure differential between said chamber and 7 ambient atmosphere such that the ambient pressure exceeds that in said chamber; guiding means spaced interposed between said chamber and said die opening and including a disc-like flow path which has at least a component which is normal to the path of travel of the optical fiber for directing a coating material into engagement with the moving optical fiber; diameter of the fiber;
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4 a feeding means for causing a coating material to be flowed along the flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is moved through said die opening, the thickness of the flow path in the direction of the path of travel ~, being such that substantially no recirculation of the coating occurs in the vicinity of the ,, l 5 application of the coating material to the optical fiber and wherein said moving means and said ; feeding means the diameter of said die opening and the direction of said flow path are such as to cause a gap to be formed between the coating liquid and the adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fber being bounded by free surfaces.
10 BriefDescription of the Drawin~
~; FIG. 1 is an overall perspective view of a portion of a manufacturing line on which optical fiber is drawn from a preform and covered with one or more coatings of a 1' polymeric material;
, ~ FIG. 2 is an elevational view in section of an apparatus for applying a single layer ~, 15 of a coating material to a moving optical fiber;
F~G. 3 is an end cross-sectional view of an optical fiber which includes a single layer of a coating material;
FIG 4 is a detail view of a portion of the apparatus of FIG. 2;
FIG. S is an elevational view in section of an apparatus of this invention for applying dual layers of coating materials to a moving optical fber;
F~G. 6 is an end cross-sectional view of an optical fiber which includes dual layers of coating materials; and FIG. 7 is a detail view of a portion of the apparatus of FIG. 5.
Detailed Description !.... 25 Referring now to FIG. 1, there is shown an apparatus which is designated generally by the numeral 20 and which is used to draw an optical fiber 21 from a specially ', prepared cylindrical preforsn 22 and then to coat the optical fiber. The optical fiber 21 is formed by locally and symmetrically heating the preEorm 22 which is about 17 mm in diameter and 60 cm in length to a temperature of about 2000C. As the preform æ is fed into and ' : 30 through a furnace 23, optical fiber 21 is drawsl from the molten material.
As can be seen in F~G. 1, the draw system includes the furnace 23, wherein the preform 22 is drawn down to the fiber size, after which the optical fiber 21 is pulled from the heat zone. The diameter of the optical fiber 21 which is measured by a device 24 at a point shortly after the .
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~ 5- 13242~8 , furnace 23 becomes an input into a control system. Within the control system, the measured diameter i5 compared to the desired value and an output signal is generated to adjust the draw speed such that the fiber diameter approaches the desired value.
~ 5 After the diameter of the optical fiber 21 is measured, a3 protective coating or coatings is applied by an apparatus 25 of the invention. Then, after the coated optical fber 21 is passed through a centering gauge 26, a device 27 for treating the coating material and a device 28 for measuring the outer diameter of the coated fiber, it is moved 10 through a capstan 2~ and is spooled for testing and storage prior to subsequent operations or sale. The preservation of the intrinsically high strength of optical rlbers is important during the ribboning, jacketing, connectorization and cabling of the optical fibers and during their service lives.
Preservation of fiber ~trength requires the application of a protective coating, which shields newly drawn optical fiber from the ` deleterious effects of the atmosphere. This coating must be applied in a manner that avoids damage to the surface of the optical fiber 21. For example, should the optical fiber 21 be off-centered with respect to the 20 coating apparatus, damage to the fiber surface which can have an adverse effect on the fiber strength and result in microbending losses may occur during the coating processes. The optical fiber must have a predetermined diameter and be protected from abrasion during subsequent manufacturing ~ -operations installation and service. Minimizing attenuation requires the 25 selection of a suitable coating material and a controlled application of it to the optical fiber 21. It is important that the layer or layers of coating material be disposed concentrically about the optical fiber.
Referring now to FIG. 2, there is shown a coating applicator, which is designated generally by the numeral 30, for applying a single 30 layer 31 (see FIG. 3) of coating material to a moving optical fiber. The applicator 30 includes a housing 32 having a flared entrance 34 and a cylindrically shaped passageway 36. The passageway 36 opens to a chamber 38. A lower end of the chamber 38 communicates with a flared exit 42 which communicates with another cylindrical passageway 44.
: ' ,: , : ' i ' - 6- i32~258 ~; A pressure differential is established between the chamber 38 , and ambient atmosphere with the latter exceeding the former. In a preferred embodiment, the chamber 38 is connected along a conduit 43 to a source of vacuum 45.
The passageway 44 is aligned with and spaced from another ; cylindrical passageway or die opening 46 (see FIGS. 2 and 4) defined by a i wall 48 which is called a land. The land 48 is provided in a block 50 of a die 51 which includes an exit or die opening 52. It is important that the diameter of the passageway 44 is less than that of the passageway 46.
10 Typically, the passageway 46 has a diameter which is equal about to the , product of 1.5 and the outer diameter of the optical fiber. On the other ` hand, the diameter of the passageway 36 may be greater than that of the passageway 4B.
As used herein, the term "die" denotes that portion of the 15 applicator which last confines or aids in confining a given coating layer around the fiber. Unlike some prior art apparatus, it does not necessarily determine directly the size of the coating layer.
The applicator 30 is used to apply a single layer 31 of a coating material 53 (see FIG.2) to an optical fiber 21. For example, the drawn ~; 20 optical flber 21 has an outer diameter of about 125 I m and includes a layer ' 31 of a coating material which has an overall diameter of about 250 ~m.
As can be seen in FIGS. 2 and 4, the die block 50 is spaced through a clearance from a portion 54 of the housing 32 in which is provided the flared exit 42 to provide a flow path 55 having a disc-shaped 25 configuration. The flow path 55 is defined between the portion 54 of housing and the die block 50. Such a disc-like flow path is shown in earlier mentioned U. S. Patent 4,474,830 and in U. S. Patent 4,512,~44.
The clearance is s,uch that at least a component of the flow path is normal to the path 55 of travel of the optical fiber 21. In a preferred 30 embodiment, the flow path 55 i~, normal to a vertical longitudinal axis 57 ofthe apparatus 30. That dimension of the clearance which is parallel to the path of travel of the optical fiber along the axis 57 in the vicinity of the point of application of the coating material i~s referred to as its thickness and typically is less than three times the fiber diameter. Preferably, the 35 clearance is less than twice the optical fiber diameter.
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7 I32~2~g The small thickness of the clearance or flow path in the direction `1 of the path of travel of the optical fiber is desirable in order to prevent the formation of eddys in the coating material 53 which is flowed along the flow passage 55 from a source (not shown). Such an eddy or recirculation 5 current can cause undesirable instabilities which may result in the formation of bubbles in the layer 31 of coating material.
The normality of the disc-like flow passage 55 to the optical fiber 21 in the preferred embodiment is beneficial from several standpoints. This allows the end surface of the portion 54 of the housing to be a broad surface 10 which is desirable for accurate adjustment of the clearance to obtain a uniform flow onto the fiber 21. This design also eases significantly mechanical tolerances in machining elements of the apparatus 30 to obtain a passage of the desired shape in the desired location compared to designs wherein an inner end of a die i9 an edge formed by the intersection of a land 15 and a diagona1 surface. Furthermore, the blunt end of the present design makes it much less fragile, and thus less subject to damage than sharp edge ~s designs.
During the operation of the coating applicator 30 in the preferred embodiment, the chamber 38is connected along the line 43 to the 20 source of vacuum 45. Typically, the line 431s substantially larger than the passageway 36 to restrict the inflow of air. For example, the diameter of the line 43 may be a~ much as the product of ten and the diameter of the -~ passageway 3B. A suitable coating material 53 is flowed along the flow passage 55 into engagement with successive increments of length of the ~3 25 optical flber 21 which are being moved through the coating applicator. In one embodiment, the pressure at the exit of the die block 50 is 7B0 torr whereas that in the passageway 44 adjacent to the flow path 55 is about ~, 52 torr. Advantageously, the vacuum is effective to prevent air from being drawn along the moving optical fiber and becoming entrained as bubbles in the layer of coating material. W~lthout this effective evacuation procedure, a ma~s of bubbles would form in the vicinity of the die. The use of the vacuum causes the tubular column to be stable.
Further, the draw rate of the opl~ical fiber 21, the pressure of the coating material 53, the diameter of the land 48 and the normal component 35 of the flow path 55 cooperate so that a gap 60 (see FIGS. 2 and 4) is formed between the coating material on the optical fiber and the land. In this ~, , .
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, ~ - 8- 1324258 manner, the coating material has a free surface 61 (see particularly FIG. 4), that is, it is unconstrained by a solid surface in the immediate vicinity of the point at which the coating material is applied to the optical flber. Also, a free surface 5~ is allowed to be maintained and oriented toward the S passageway 44. The free surfaces 61 and 5~ which define a membrane of the coating material 53 after it emerges from the disc-like flow path 55 and is directed toward engagement with the moving optical fiber are allowed to ` be maintained because of the pressure differential, despite what may be a relatively thin membrane as the coating material 53 turns from the flow 10 path 55 and is caused to be directed downwardly to engage the moving optical fiber 21. Without this, a mass of bubbles will occur in the vicinity of the membrane and cause its collapse, resulting in a filling of the die opening . 46 and of a portion of the passageway 44.
As a result of this arrangement, the coating material 53 15 accelerates to the velocity of the moving optical fiber 21 by elongational flow in the vicinity of the free surfaces. There are no abrupt changes in the velocity of the coating material 53 as it is being applied to the moving optical fiber 21. This arrangement avoids the establishment of a shear field between the coating liquid on the moving optical fiber and the land 48 and 20 reduces substantially the possibility of any recirculation and the consequentformation of air bubbles within the coating material. Because the surface tension of the coating material, which typically has a viscosity in the range of about 3500 cps, can support the pressure differential which is formed across the free surfaces 5~ and 61, the membrane defined between those two 25 surfaces is maintained and is not penetrated.
The free surface 61 which i9 provided in the vicinity of the die opening not only avoids recirculation of the coating material, but also is beneficial from the standpoint of the outer diameter of the coated optical fiber. W~lthout the presence of a free surface, the outer diameter of the 30 coated optical fiber is determined by the die opening and is fixed. With the arrangement of this invention, the diameter of the coated optical fiber may be changed by changing the pressure feed of the coating material 53.
The gap 60 extends into the die o~pening at least as far as the point of initial contact of the coating material with the optical fiber, and 35 preferably to the upper end of the die land. Also, it should be noted that the coating material may contact the moving optical fiber well below the ,, . -. . . ..
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13242~8 g flow path 55.
As mentioned hereinbefore, it is frequently commonplace toapply dual coatings for a drawn optical fiber. These provide protection for the optical fiber, as well as render the optical fiber more flexible than with a5 single coating layer.
Going now to FIG. 5, there is shown a preferred embodiment of a coating applicator 62 of this invention for applying dual layers of coating materials to a moving optical fiber. An optical fiber 21 having dual layers of coating materials 63 and 64 thereon is shown in FIG. 6.
The coating applicator 62 includes a housing 65 having a flared entrance 66 into which succe sive increments of the optical fiber 21 are advanced. The flared entrance 66 connects to a cylindrical passageway 67 -which opens to a first chamber 68. A lower portion 68 of the first chamber 68 i9 conically shaped and communicates with a cylindrical passageway 70 15 which opens to a second chamber 71. A lower portion 72 of the second chamber 71 is conically shaped and communicates with a cylindrical -~ passageway 73.
-, The applicator 62 is caused to be operated such that a pressure differential exists between the chambers ~8 and 71 and the ambient 20 atmosphere with the ambient pressure being greater than that in the chambers. In a preferred embodiment, the chambers 68 and 71 are ~, ~ connected along line 76 and 77, respectively, to a source of vacuum (not shown in FIG.5).
Aligned with the cylindrical passageways 67, 70 and 73 are first 25 and second dies 81 and 82 having die openings 84 and 86 respectively. It should be observed that the die openings 84 and 86 (see also FIG. 7) which are a~sociated with the first and second dies, respectively, have a substantially larger diameter than those of the passageway 73. On the other hand, the diameters of the passageways ~7 and 70 can be larger or smaller `~ 30 than those of the die openings. However, in a preferred embodiment they are relatively small to inhibit the inflow of air.
Furthermore, the applicator is arranged to provide flow paths for two coating materials. A die block 88 of the~first die 81 includes a surface 88 which is parallel to and spaced from a surface 81 of a portion 82 35 of the housing. The clearance between the surfaces 88 and 81 define a flow path 83 for a first coating material 84 which provides the cushioning layer .. ' .
.
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- lO- 1~242~8 63 for the optical fiber. The flow path 93 has at least a component that is normal to the path of travel of the optical fiber along the longitudinal axis 57. In a preferred embodiment, the flow path ~3 is disc-like and is normal to the path of travel of the optical fiber. Further, the thickness of the flow 5 path û3 in a direction parallel to the path of travel of the optical path is relatively small, being on the order of about 0.005 to 0.025 inch.
Also, a second coating material 103 is pressure fed along a flow path 105 formed between surfaces 107 and 109 of the dies 81 and 82 over the first coating material ~4 and between the first coating material and a 10 land 110 of the second die. The flow path 105 also has at least a component that i3 normal to the path of travel of the optical fiber, and in the preferred embodiment is normal to the axis 5~.
As in the application of a single coating to optical fiber, the - thickness of the clearance in the intermediate vicinity of the point of 15 application of the first coating liquid in the applicator 62 onto the opticalfiber is typically less than three times the diameter of the fiber. For the flow path 105, the thickness also is less than the product of three and the diameter of the optical fiber, and preferably less than 2 times the diameter.
The small thickness is desirable to prevent the formation of an eddy of each 20 coating liquid in the vicinity of the point of application. Such recirculation can cause undesirable instabilities and mixing about the optical fiber or with the previously applied first coating. In addition, for the reasons set forth hereinbefore during the description of a single coating to an optical fiber, it has been found desirable to form the clearance associated with the 25 second die by surfaces perpendicular to the fiber axis 57. As a result, each coating liquid in its associated clearance region flows perpendicularly to the `~ axis of fiber until entering the transition region in the immediate vicinity of the moving optical fiber.
In the arrangement shown in FIGS. 5 and 7, an optical fiber 21 is 30 passed through the frst coating die 81 and thereafter into the second coating die 82 located near the exit of the first die. The chambers 68 and 71 s are connected along conduits 76 and 77 to a source of vacuum. To restrict s the inflow of air, the diameter of each of the~ passageways 67 and 70 is relatively small. Further, in order to facilitate removal of air from the 35 chambers B8 and 71, the diameters of the conduits 76 and 77 are relatively large. A~ a result, in the preferred embodiment, these parameters are such .
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that the ratio of each of the diameters of the conduits 76 and 77 to the diameters of the passageways 67 and 70, respectively, is about ten to one.
The first coating liquid 94 is pressure fed along the flow path 93 onto the ` optical fiber through the clearance formed between the surfaces 8~ and 91 5 and the second coating material 103 is pressure fed along the flow path 105.
The fiber draw rate, the pressure feed of the coating materials and the diameter of the aperture of the die around the optical fiber together with the direction of the flow path are chosen so that a gap forms between the first coating material and the land of the die 81 and between the second '~ 10 coating material and the land of the die 82. The aperture of each die is chosen so that for a given fiber draw rate, coating liquid pressure and direction of the flow path with respect to the axis 57, a gap forms between the optical fiber and the die or between the coated fiber and the die. In this manner, each coating liquid is preferably applied onto the optical flber 15 or onto the inner layer of coating material through a membrane bounded by free surfaces, that is, unconstrained by a solid surface in the immediate vicinity of the point at which the first coating material is applied to the optical fber or at which the second coating material is applied to the first coating. Each gap desirably extends into the aperture of die at least as far 20 as the initial point of contact of the coating liquid with the moving substrate. In this matter, instabilities and non-uniformities associated with 3 prior art techniques are eliminated substantially. As can best be seen in FIG. 7, a gap ~S is formed between the first coating material and a land ~7 of the first die. Also, a gap 101 is formed between the second coating 25 material and a land 110 of the second die. These gaps function in the same manner as the gap 60 in FIG. 2.
The gaps ~5 and 101 are effective to allow free surfaces 112 and :. 114 to be formed between the coating materials ~4 and 103 and the lands ~7 and 110, respectively. Also, it should be noted that free surfaces 11~ and 30 117 are formed and cooperate with the free surfaces 112 and 114, respectively, to define membranes of the coating materials ~4 and 103, respectively, after they emerge from their respective flow paths and are directed toward the optical fiber 21. These ~aps are allowed to develop because of the pressure differentials between the chambers and ambient 35 atmo~phere. Without those pressure differentials, masses of bubbles will form about the juncture of the moving optical fiber 21 and the coating "
- 12- 132~2~8 liquids, destroying the membranes bounded by free surfaces and causing the - die opening~ to be filled with the coating materials.
-' As in the single coating application, the presence of a free surface in the die opening avoids the development of a shear field between 5 the associated land and the moving optical flber. This is particularly important in the second die where the shear field would develop between the layer of first coating material and the second which would disrupt the layer already on the optical fiber. The formation of the gaps helps provide for a smooth transition in the flow of the coating liquids onto the optical 10 fiber and onto the first or inner layer coating material in the region of thedies. It also helps to decouple the gap from any irregularities in the flow of the coating liquids.
Each coating liquid in the present technique accelerates to the fiber velocity by elongational flow in the vicinity of the free surfaces, and 15 there are thus no abrupt changes in the coating liquid velocity as it is applied to the fiber and to the first coating. This technique avoids shear between the first coating material and the land ~7 and between the first and ~econd coating liquids and the land 110, thereby substantially reducing the possibility of mixing between the first and second coating liquids. Once 20 the coating process has reached a stable, steady state condition, the gaps ~ are substantially isolated from the atmosphere and at least partially ; evacuated. This is because the first coating liquid in the upper portion of the die forms a hermetic ~eal on one side, whereas the second coating liquid likewise forms a hermetic seal on the other side of the applied first coating 25 in the vicinity of the gap 101. This is very advantageous in reducing the possibility of bubble entrapment in the second coating material, because there is no contact with the atmosphere that would allow for bubble entrapment between the first and second coatings.
A further advantage is derived from the formation of the gaps 95 30 and 101. Because of them, the diameter of the coated optical fiber may be adjusted by adjusting the pressure feed of the coating materials ~4 and 103.
3 Adjustability is not available in a fixed die which is filled by the coating material. Also in such fixed die arrangemen~ts, the position of the optical 1 fiber within the die opening and the pressure level must be maintained ., 35 accurately otherwise bubbles may result and the coating liquid from the disc-like flow path may back up into the passageway 44 or the b '"', ~ ' ' ' - .
.~ .
- 13- 13242~8 passageway 73.
`~ In the apparatus 62, with the pressure for the first coating material adjusted as noted above for a given flber line speed, the diameter of the optical fiber enclosed in a layer of the first coating material is 5 determined mainly by the feed pressure of the f~lrst coating material. Also, the thickness of the layer of second coating material can readily be adjusted by changing the feed pressure of the second coating material. A desirable feature of the present technique is that the first and second coating thicknesses each can thus be independently adjusted. Because the coating , 10 materials are introduced by a pressure feed through rigid orifices, a uniform concentric thickness of the coatings can be maintained. A further advantage relates to centering of the flber in the coating. Once the composite structure i9 centered, both layers of coating m~terials are concentric about the optical fiber. A convenient way of centering the fiber 15 in the coating applicator is described in "The Centering Of Optical Fiber Coatings by Monitoring Forward-Scattering patters, Theory And Practice,"
by B. R. Eichenbaum in the Bell System Technical Journal, Vol. 5~, page 313 (1~80)-One of the advantages of the methods and apparatus of this i 20 invention relates to string-up of the optical fiber. Under previous arrangementY, an optical fiber had to be pushed blindly through a coating , liquid in an applicator cup and through the die opening therein, particularly after the run of an initial preform. Herein, there is no coating liquid reservoir in the housing but only in the flow passages. As a result, string-up 25 of the optical fiber is far easier for an operator.
Furthermore, there are no operating windows to maintain for the coating materials. In neither system, that for the single layer coating nor that for the dual layers, is there a reservoir level in the applicator that must'J; ' be maintained. Also, because there is no reservoir of coating material in the 30 applicator, it becomes far easier to clean the applicator and to perform other maintenance procedures thereon.
Another advantage of the methods and apparatus of this invention relates to the reduced cooling of th5e drawn flber which is necessary before it is moved into the coating applicator. The air adjacent to 35 the moving optical fiber functions as a heat sink. As its temperature rises, so does its viscosity which increases the probability for entrainment into the i~ .
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:, -- 132~8 . liquid coating material. Also, the higher the temperature of the optical fiber, the greater the reduction in the viscosity of the coating liquid adjacent to the flber. This can have an adverse effect on the coating process. For example, it may become more difficult to maintain a particular S coating liquid level in an entry die thereby resulting in the loss of a hermetic seal which, if present, helps to prevent the entrainrnent of air. Therefore, in - prior art arrangements, it becomes necessary to reduce the line speed of the optical flber or to use enhanced cooling so that the fiber is cooler when it entered the coating applicator.
This problem is overcome by the methods and apparatus of this invention. Because of the established pressure differential, there is substantially no air in the passageway 44 of the applicator 30 or in the passageway 73 of the dual applicator 62 to undergo an increase in viscosity and none to be entrained. Further, because of the relatively short time the 15 optical fiber is in contact with a coating liquid, prior to it forming a layer or layers on the optical fiber, there is insufficient time for the viscosity of the~ coating material to be reduced appreciably. Less cooling of the drawn - optical fiber is necessary and higher line speeds may be used.
It should be understood that the above-described arrangements 20 are simply illustrative of the invention. Other arrangements may be devised by those skilled in the art which will embody the principles of the invention and fall within the scr,pe and spirit thereof.
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10 BriefDescription of the Drawin~
~; FIG. 1 is an overall perspective view of a portion of a manufacturing line on which optical fiber is drawn from a preform and covered with one or more coatings of a 1' polymeric material;
, ~ FIG. 2 is an elevational view in section of an apparatus for applying a single layer ~, 15 of a coating material to a moving optical fiber;
F~G. 3 is an end cross-sectional view of an optical fiber which includes a single layer of a coating material;
FIG 4 is a detail view of a portion of the apparatus of FIG. 2;
FIG. S is an elevational view in section of an apparatus of this invention for applying dual layers of coating materials to a moving optical fber;
F~G. 6 is an end cross-sectional view of an optical fiber which includes dual layers of coating materials; and FIG. 7 is a detail view of a portion of the apparatus of FIG. 5.
Detailed Description !.... 25 Referring now to FIG. 1, there is shown an apparatus which is designated generally by the numeral 20 and which is used to draw an optical fiber 21 from a specially ', prepared cylindrical preforsn 22 and then to coat the optical fiber. The optical fiber 21 is formed by locally and symmetrically heating the preEorm 22 which is about 17 mm in diameter and 60 cm in length to a temperature of about 2000C. As the preform æ is fed into and ' : 30 through a furnace 23, optical fiber 21 is drawsl from the molten material.
As can be seen in F~G. 1, the draw system includes the furnace 23, wherein the preform 22 is drawn down to the fiber size, after which the optical fiber 21 is pulled from the heat zone. The diameter of the optical fiber 21 which is measured by a device 24 at a point shortly after the .
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~ 5- 13242~8 , furnace 23 becomes an input into a control system. Within the control system, the measured diameter i5 compared to the desired value and an output signal is generated to adjust the draw speed such that the fiber diameter approaches the desired value.
~ 5 After the diameter of the optical fiber 21 is measured, a3 protective coating or coatings is applied by an apparatus 25 of the invention. Then, after the coated optical fber 21 is passed through a centering gauge 26, a device 27 for treating the coating material and a device 28 for measuring the outer diameter of the coated fiber, it is moved 10 through a capstan 2~ and is spooled for testing and storage prior to subsequent operations or sale. The preservation of the intrinsically high strength of optical rlbers is important during the ribboning, jacketing, connectorization and cabling of the optical fibers and during their service lives.
Preservation of fiber ~trength requires the application of a protective coating, which shields newly drawn optical fiber from the ` deleterious effects of the atmosphere. This coating must be applied in a manner that avoids damage to the surface of the optical fiber 21. For example, should the optical fiber 21 be off-centered with respect to the 20 coating apparatus, damage to the fiber surface which can have an adverse effect on the fiber strength and result in microbending losses may occur during the coating processes. The optical fiber must have a predetermined diameter and be protected from abrasion during subsequent manufacturing ~ -operations installation and service. Minimizing attenuation requires the 25 selection of a suitable coating material and a controlled application of it to the optical fiber 21. It is important that the layer or layers of coating material be disposed concentrically about the optical fiber.
Referring now to FIG. 2, there is shown a coating applicator, which is designated generally by the numeral 30, for applying a single 30 layer 31 (see FIG. 3) of coating material to a moving optical fiber. The applicator 30 includes a housing 32 having a flared entrance 34 and a cylindrically shaped passageway 36. The passageway 36 opens to a chamber 38. A lower end of the chamber 38 communicates with a flared exit 42 which communicates with another cylindrical passageway 44.
: ' ,: , : ' i ' - 6- i32~258 ~; A pressure differential is established between the chamber 38 , and ambient atmosphere with the latter exceeding the former. In a preferred embodiment, the chamber 38 is connected along a conduit 43 to a source of vacuum 45.
The passageway 44 is aligned with and spaced from another ; cylindrical passageway or die opening 46 (see FIGS. 2 and 4) defined by a i wall 48 which is called a land. The land 48 is provided in a block 50 of a die 51 which includes an exit or die opening 52. It is important that the diameter of the passageway 44 is less than that of the passageway 46.
10 Typically, the passageway 46 has a diameter which is equal about to the , product of 1.5 and the outer diameter of the optical fiber. On the other ` hand, the diameter of the passageway 36 may be greater than that of the passageway 4B.
As used herein, the term "die" denotes that portion of the 15 applicator which last confines or aids in confining a given coating layer around the fiber. Unlike some prior art apparatus, it does not necessarily determine directly the size of the coating layer.
The applicator 30 is used to apply a single layer 31 of a coating material 53 (see FIG.2) to an optical fiber 21. For example, the drawn ~; 20 optical flber 21 has an outer diameter of about 125 I m and includes a layer ' 31 of a coating material which has an overall diameter of about 250 ~m.
As can be seen in FIGS. 2 and 4, the die block 50 is spaced through a clearance from a portion 54 of the housing 32 in which is provided the flared exit 42 to provide a flow path 55 having a disc-shaped 25 configuration. The flow path 55 is defined between the portion 54 of housing and the die block 50. Such a disc-like flow path is shown in earlier mentioned U. S. Patent 4,474,830 and in U. S. Patent 4,512,~44.
The clearance is s,uch that at least a component of the flow path is normal to the path 55 of travel of the optical fiber 21. In a preferred 30 embodiment, the flow path 55 i~, normal to a vertical longitudinal axis 57 ofthe apparatus 30. That dimension of the clearance which is parallel to the path of travel of the optical fiber along the axis 57 in the vicinity of the point of application of the coating material i~s referred to as its thickness and typically is less than three times the fiber diameter. Preferably, the 35 clearance is less than twice the optical fiber diameter.
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7 I32~2~g The small thickness of the clearance or flow path in the direction `1 of the path of travel of the optical fiber is desirable in order to prevent the formation of eddys in the coating material 53 which is flowed along the flow passage 55 from a source (not shown). Such an eddy or recirculation 5 current can cause undesirable instabilities which may result in the formation of bubbles in the layer 31 of coating material.
The normality of the disc-like flow passage 55 to the optical fiber 21 in the preferred embodiment is beneficial from several standpoints. This allows the end surface of the portion 54 of the housing to be a broad surface 10 which is desirable for accurate adjustment of the clearance to obtain a uniform flow onto the fiber 21. This design also eases significantly mechanical tolerances in machining elements of the apparatus 30 to obtain a passage of the desired shape in the desired location compared to designs wherein an inner end of a die i9 an edge formed by the intersection of a land 15 and a diagona1 surface. Furthermore, the blunt end of the present design makes it much less fragile, and thus less subject to damage than sharp edge ~s designs.
During the operation of the coating applicator 30 in the preferred embodiment, the chamber 38is connected along the line 43 to the 20 source of vacuum 45. Typically, the line 431s substantially larger than the passageway 36 to restrict the inflow of air. For example, the diameter of the line 43 may be a~ much as the product of ten and the diameter of the -~ passageway 3B. A suitable coating material 53 is flowed along the flow passage 55 into engagement with successive increments of length of the ~3 25 optical flber 21 which are being moved through the coating applicator. In one embodiment, the pressure at the exit of the die block 50 is 7B0 torr whereas that in the passageway 44 adjacent to the flow path 55 is about ~, 52 torr. Advantageously, the vacuum is effective to prevent air from being drawn along the moving optical fiber and becoming entrained as bubbles in the layer of coating material. W~lthout this effective evacuation procedure, a ma~s of bubbles would form in the vicinity of the die. The use of the vacuum causes the tubular column to be stable.
Further, the draw rate of the opl~ical fiber 21, the pressure of the coating material 53, the diameter of the land 48 and the normal component 35 of the flow path 55 cooperate so that a gap 60 (see FIGS. 2 and 4) is formed between the coating material on the optical fiber and the land. In this ~, , .
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, ~ - 8- 1324258 manner, the coating material has a free surface 61 (see particularly FIG. 4), that is, it is unconstrained by a solid surface in the immediate vicinity of the point at which the coating material is applied to the optical flber. Also, a free surface 5~ is allowed to be maintained and oriented toward the S passageway 44. The free surfaces 61 and 5~ which define a membrane of the coating material 53 after it emerges from the disc-like flow path 55 and is directed toward engagement with the moving optical fiber are allowed to ` be maintained because of the pressure differential, despite what may be a relatively thin membrane as the coating material 53 turns from the flow 10 path 55 and is caused to be directed downwardly to engage the moving optical fiber 21. Without this, a mass of bubbles will occur in the vicinity of the membrane and cause its collapse, resulting in a filling of the die opening . 46 and of a portion of the passageway 44.
As a result of this arrangement, the coating material 53 15 accelerates to the velocity of the moving optical fiber 21 by elongational flow in the vicinity of the free surfaces. There are no abrupt changes in the velocity of the coating material 53 as it is being applied to the moving optical fiber 21. This arrangement avoids the establishment of a shear field between the coating liquid on the moving optical fiber and the land 48 and 20 reduces substantially the possibility of any recirculation and the consequentformation of air bubbles within the coating material. Because the surface tension of the coating material, which typically has a viscosity in the range of about 3500 cps, can support the pressure differential which is formed across the free surfaces 5~ and 61, the membrane defined between those two 25 surfaces is maintained and is not penetrated.
The free surface 61 which i9 provided in the vicinity of the die opening not only avoids recirculation of the coating material, but also is beneficial from the standpoint of the outer diameter of the coated optical fiber. W~lthout the presence of a free surface, the outer diameter of the 30 coated optical fiber is determined by the die opening and is fixed. With the arrangement of this invention, the diameter of the coated optical fiber may be changed by changing the pressure feed of the coating material 53.
The gap 60 extends into the die o~pening at least as far as the point of initial contact of the coating material with the optical fiber, and 35 preferably to the upper end of the die land. Also, it should be noted that the coating material may contact the moving optical fiber well below the ,, . -. . . ..
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13242~8 g flow path 55.
As mentioned hereinbefore, it is frequently commonplace toapply dual coatings for a drawn optical fiber. These provide protection for the optical fiber, as well as render the optical fiber more flexible than with a5 single coating layer.
Going now to FIG. 5, there is shown a preferred embodiment of a coating applicator 62 of this invention for applying dual layers of coating materials to a moving optical fiber. An optical fiber 21 having dual layers of coating materials 63 and 64 thereon is shown in FIG. 6.
The coating applicator 62 includes a housing 65 having a flared entrance 66 into which succe sive increments of the optical fiber 21 are advanced. The flared entrance 66 connects to a cylindrical passageway 67 -which opens to a first chamber 68. A lower portion 68 of the first chamber 68 i9 conically shaped and communicates with a cylindrical passageway 70 15 which opens to a second chamber 71. A lower portion 72 of the second chamber 71 is conically shaped and communicates with a cylindrical -~ passageway 73.
-, The applicator 62 is caused to be operated such that a pressure differential exists between the chambers ~8 and 71 and the ambient 20 atmosphere with the ambient pressure being greater than that in the chambers. In a preferred embodiment, the chambers 68 and 71 are ~, ~ connected along line 76 and 77, respectively, to a source of vacuum (not shown in FIG.5).
Aligned with the cylindrical passageways 67, 70 and 73 are first 25 and second dies 81 and 82 having die openings 84 and 86 respectively. It should be observed that the die openings 84 and 86 (see also FIG. 7) which are a~sociated with the first and second dies, respectively, have a substantially larger diameter than those of the passageway 73. On the other hand, the diameters of the passageways ~7 and 70 can be larger or smaller `~ 30 than those of the die openings. However, in a preferred embodiment they are relatively small to inhibit the inflow of air.
Furthermore, the applicator is arranged to provide flow paths for two coating materials. A die block 88 of the~first die 81 includes a surface 88 which is parallel to and spaced from a surface 81 of a portion 82 35 of the housing. The clearance between the surfaces 88 and 81 define a flow path 83 for a first coating material 84 which provides the cushioning layer .. ' .
.
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- lO- 1~242~8 63 for the optical fiber. The flow path 93 has at least a component that is normal to the path of travel of the optical fiber along the longitudinal axis 57. In a preferred embodiment, the flow path ~3 is disc-like and is normal to the path of travel of the optical fiber. Further, the thickness of the flow 5 path û3 in a direction parallel to the path of travel of the optical path is relatively small, being on the order of about 0.005 to 0.025 inch.
Also, a second coating material 103 is pressure fed along a flow path 105 formed between surfaces 107 and 109 of the dies 81 and 82 over the first coating material ~4 and between the first coating material and a 10 land 110 of the second die. The flow path 105 also has at least a component that i3 normal to the path of travel of the optical fiber, and in the preferred embodiment is normal to the axis 5~.
As in the application of a single coating to optical fiber, the - thickness of the clearance in the intermediate vicinity of the point of 15 application of the first coating liquid in the applicator 62 onto the opticalfiber is typically less than three times the diameter of the fiber. For the flow path 105, the thickness also is less than the product of three and the diameter of the optical fiber, and preferably less than 2 times the diameter.
The small thickness is desirable to prevent the formation of an eddy of each 20 coating liquid in the vicinity of the point of application. Such recirculation can cause undesirable instabilities and mixing about the optical fiber or with the previously applied first coating. In addition, for the reasons set forth hereinbefore during the description of a single coating to an optical fiber, it has been found desirable to form the clearance associated with the 25 second die by surfaces perpendicular to the fiber axis 57. As a result, each coating liquid in its associated clearance region flows perpendicularly to the `~ axis of fiber until entering the transition region in the immediate vicinity of the moving optical fiber.
In the arrangement shown in FIGS. 5 and 7, an optical fiber 21 is 30 passed through the frst coating die 81 and thereafter into the second coating die 82 located near the exit of the first die. The chambers 68 and 71 s are connected along conduits 76 and 77 to a source of vacuum. To restrict s the inflow of air, the diameter of each of the~ passageways 67 and 70 is relatively small. Further, in order to facilitate removal of air from the 35 chambers B8 and 71, the diameters of the conduits 76 and 77 are relatively large. A~ a result, in the preferred embodiment, these parameters are such .
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that the ratio of each of the diameters of the conduits 76 and 77 to the diameters of the passageways 67 and 70, respectively, is about ten to one.
The first coating liquid 94 is pressure fed along the flow path 93 onto the ` optical fiber through the clearance formed between the surfaces 8~ and 91 5 and the second coating material 103 is pressure fed along the flow path 105.
The fiber draw rate, the pressure feed of the coating materials and the diameter of the aperture of the die around the optical fiber together with the direction of the flow path are chosen so that a gap forms between the first coating material and the land of the die 81 and between the second '~ 10 coating material and the land of the die 82. The aperture of each die is chosen so that for a given fiber draw rate, coating liquid pressure and direction of the flow path with respect to the axis 57, a gap forms between the optical fiber and the die or between the coated fiber and the die. In this manner, each coating liquid is preferably applied onto the optical flber 15 or onto the inner layer of coating material through a membrane bounded by free surfaces, that is, unconstrained by a solid surface in the immediate vicinity of the point at which the first coating material is applied to the optical fber or at which the second coating material is applied to the first coating. Each gap desirably extends into the aperture of die at least as far 20 as the initial point of contact of the coating liquid with the moving substrate. In this matter, instabilities and non-uniformities associated with 3 prior art techniques are eliminated substantially. As can best be seen in FIG. 7, a gap ~S is formed between the first coating material and a land ~7 of the first die. Also, a gap 101 is formed between the second coating 25 material and a land 110 of the second die. These gaps function in the same manner as the gap 60 in FIG. 2.
The gaps ~5 and 101 are effective to allow free surfaces 112 and :. 114 to be formed between the coating materials ~4 and 103 and the lands ~7 and 110, respectively. Also, it should be noted that free surfaces 11~ and 30 117 are formed and cooperate with the free surfaces 112 and 114, respectively, to define membranes of the coating materials ~4 and 103, respectively, after they emerge from their respective flow paths and are directed toward the optical fiber 21. These ~aps are allowed to develop because of the pressure differentials between the chambers and ambient 35 atmo~phere. Without those pressure differentials, masses of bubbles will form about the juncture of the moving optical fiber 21 and the coating "
- 12- 132~2~8 liquids, destroying the membranes bounded by free surfaces and causing the - die opening~ to be filled with the coating materials.
-' As in the single coating application, the presence of a free surface in the die opening avoids the development of a shear field between 5 the associated land and the moving optical flber. This is particularly important in the second die where the shear field would develop between the layer of first coating material and the second which would disrupt the layer already on the optical fiber. The formation of the gaps helps provide for a smooth transition in the flow of the coating liquids onto the optical 10 fiber and onto the first or inner layer coating material in the region of thedies. It also helps to decouple the gap from any irregularities in the flow of the coating liquids.
Each coating liquid in the present technique accelerates to the fiber velocity by elongational flow in the vicinity of the free surfaces, and 15 there are thus no abrupt changes in the coating liquid velocity as it is applied to the fiber and to the first coating. This technique avoids shear between the first coating material and the land ~7 and between the first and ~econd coating liquids and the land 110, thereby substantially reducing the possibility of mixing between the first and second coating liquids. Once 20 the coating process has reached a stable, steady state condition, the gaps ~ are substantially isolated from the atmosphere and at least partially ; evacuated. This is because the first coating liquid in the upper portion of the die forms a hermetic ~eal on one side, whereas the second coating liquid likewise forms a hermetic seal on the other side of the applied first coating 25 in the vicinity of the gap 101. This is very advantageous in reducing the possibility of bubble entrapment in the second coating material, because there is no contact with the atmosphere that would allow for bubble entrapment between the first and second coatings.
A further advantage is derived from the formation of the gaps 95 30 and 101. Because of them, the diameter of the coated optical fiber may be adjusted by adjusting the pressure feed of the coating materials ~4 and 103.
3 Adjustability is not available in a fixed die which is filled by the coating material. Also in such fixed die arrangemen~ts, the position of the optical 1 fiber within the die opening and the pressure level must be maintained ., 35 accurately otherwise bubbles may result and the coating liquid from the disc-like flow path may back up into the passageway 44 or the b '"', ~ ' ' ' - .
.~ .
- 13- 13242~8 passageway 73.
`~ In the apparatus 62, with the pressure for the first coating material adjusted as noted above for a given flber line speed, the diameter of the optical fiber enclosed in a layer of the first coating material is 5 determined mainly by the feed pressure of the f~lrst coating material. Also, the thickness of the layer of second coating material can readily be adjusted by changing the feed pressure of the second coating material. A desirable feature of the present technique is that the first and second coating thicknesses each can thus be independently adjusted. Because the coating , 10 materials are introduced by a pressure feed through rigid orifices, a uniform concentric thickness of the coatings can be maintained. A further advantage relates to centering of the flber in the coating. Once the composite structure i9 centered, both layers of coating m~terials are concentric about the optical fiber. A convenient way of centering the fiber 15 in the coating applicator is described in "The Centering Of Optical Fiber Coatings by Monitoring Forward-Scattering patters, Theory And Practice,"
by B. R. Eichenbaum in the Bell System Technical Journal, Vol. 5~, page 313 (1~80)-One of the advantages of the methods and apparatus of this i 20 invention relates to string-up of the optical fiber. Under previous arrangementY, an optical fiber had to be pushed blindly through a coating , liquid in an applicator cup and through the die opening therein, particularly after the run of an initial preform. Herein, there is no coating liquid reservoir in the housing but only in the flow passages. As a result, string-up 25 of the optical fiber is far easier for an operator.
Furthermore, there are no operating windows to maintain for the coating materials. In neither system, that for the single layer coating nor that for the dual layers, is there a reservoir level in the applicator that must'J; ' be maintained. Also, because there is no reservoir of coating material in the 30 applicator, it becomes far easier to clean the applicator and to perform other maintenance procedures thereon.
Another advantage of the methods and apparatus of this invention relates to the reduced cooling of th5e drawn flber which is necessary before it is moved into the coating applicator. The air adjacent to 35 the moving optical fiber functions as a heat sink. As its temperature rises, so does its viscosity which increases the probability for entrainment into the i~ .
~3 ...... ...
"
:, -- 132~8 . liquid coating material. Also, the higher the temperature of the optical fiber, the greater the reduction in the viscosity of the coating liquid adjacent to the flber. This can have an adverse effect on the coating process. For example, it may become more difficult to maintain a particular S coating liquid level in an entry die thereby resulting in the loss of a hermetic seal which, if present, helps to prevent the entrainrnent of air. Therefore, in - prior art arrangements, it becomes necessary to reduce the line speed of the optical flber or to use enhanced cooling so that the fiber is cooler when it entered the coating applicator.
This problem is overcome by the methods and apparatus of this invention. Because of the established pressure differential, there is substantially no air in the passageway 44 of the applicator 30 or in the passageway 73 of the dual applicator 62 to undergo an increase in viscosity and none to be entrained. Further, because of the relatively short time the 15 optical fiber is in contact with a coating liquid, prior to it forming a layer or layers on the optical fiber, there is insufficient time for the viscosity of the~ coating material to be reduced appreciably. Less cooling of the drawn - optical fiber is necessary and higher line speeds may be used.
It should be understood that the above-described arrangements 20 are simply illustrative of the invention. Other arrangements may be devised by those skilled in the art which will embody the principles of the invention and fall within the scr,pe and spirit thereof.
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Claims (11)
1. A method of making an optical fiber having a layer of a coating material thereon, said method including the steps of drawing an optical fiber from a preform, moving the drawn fiber along a path of travel into and through a chamber in a housing, moving the optical fiber from the chamber past a disc-like flow path which has at least a component that is normal to the path of travel of the optical fiber and then through an opening of a die, the die opening being substantially larger than the diameter of the coated fiber, and being characterized by the steps of:
establishing a pressure differential between the chamber and ambient atmosphere such that ambient pressure is greater than that in the chamber; while causing a coating material to be flowed along the flow path generally radially inwardly toward the path of travel into engagement with the moving optical fiber to coat the fiber as it is moved through the die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the coating material occurs in the vicinity of the application of the coating material to the optical fiber and wherein the size of the die opening, the direction of the flow path and the steps of moving the drawn fiber and causing the coating material to be flowed along the flow path are such as to cause a gap to be formed between the coating material and an adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
establishing a pressure differential between the chamber and ambient atmosphere such that ambient pressure is greater than that in the chamber; while causing a coating material to be flowed along the flow path generally radially inwardly toward the path of travel into engagement with the moving optical fiber to coat the fiber as it is moved through the die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the coating material occurs in the vicinity of the application of the coating material to the optical fiber and wherein the size of the die opening, the direction of the flow path and the steps of moving the drawn fiber and causing the coating material to be flowed along the flow path are such as to cause a gap to be formed between the coating material and an adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
2. The method of claim 1, wherein the disc-like flow path has a thickness which is less than three times the largest cross sectional dimension of the optical fiber and the disc-like flow path is bounded by surfaces which are perpendicular to the path of travel of the optical fiber.
3. The method of claim 1, wherein the gap extends into the die opening at least as far as the point at which the coating material first contacts the optical fiber.
4. The method of claim 1, wherein the disc-like flow path is a first disc-like flow path, and subsequently, the optical fiber is moved past a second disc-like flow path, and through a second die opening, each of the flow paths having at least a component that is normal to the path of travel of the optical fiber and each of the die openings being substantially larger than the cross-section of the optical fiber; and applying a source of vacuum to the chamber; while causing first and second coating materials to be flowed along the first and second flow paths, respectively, generally radially inwardly toward the path of travel of the optical fiber to coat the fiber as it is moved through the first and then through the second die opening, the thickness of each flow path in the direction of the path of travel being such that substantially no recirculation of the coating material flowing therein occurs in the vicinity of the application of the coating material to the optical fiber and wherein the steps of moving the optical fiber and causing the coating materials to be flowed and the die openings and the directions of the flow paths are such that a gap forms between each of the coating materials and an associated die surface with each coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
5. The method of claim 4, wherein the drawn optical fiber is moved through a first chamber and then through a second chamber prior to the application of the coating material thereto.
6. An apparatus for making an optical fiber having a layer of a coating material thereon, said apparatus including means for drawing an optical fiber from a preform, a housing which includes a chamber, a die having an opening which is aligned with said chamber and which is substantially larger than the diameter of the optical fiber, and moving means for advancing the drawn fiber along a path of travel into and through the chamber in the housing and through said die opening;
said apparatus being characterized by:
means for establishing a pressure differential between said chamber and ambient atmosphere such that the ambient pressure exceeds that in said chamber;
guiding means spaced interposed between said chamber and said die opening and including a disc-like flow path which has at least a component which is normal to the path of travel of the optical fiber for directing a coating material into engagement with the moving optical fiber;
diameter of the fiber;
feeding means for causing a coating material to be flowed along the flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is moved through said die opening, the thickness of the flow path in the direction of the path of travel being such that substantially no recirculation of the coating occurs in the vicinity of the application of the coating material to the optical fiber and wherein said moving means and said feeding means the diameter of said die opening and the direction of said flow path are such as to cause a gap to be formed between the coating liquid and the adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
said apparatus being characterized by:
means for establishing a pressure differential between said chamber and ambient atmosphere such that the ambient pressure exceeds that in said chamber;
guiding means spaced interposed between said chamber and said die opening and including a disc-like flow path which has at least a component which is normal to the path of travel of the optical fiber for directing a coating material into engagement with the moving optical fiber;
diameter of the fiber;
feeding means for causing a coating material to be flowed along the flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is moved through said die opening, the thickness of the flow path in the direction of the path of travel being such that substantially no recirculation of the coating occurs in the vicinity of the application of the coating material to the optical fiber and wherein said moving means and said feeding means the diameter of said die opening and the direction of said flow path are such as to cause a gap to be formed between the coating liquid and the adjacent die surface with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces.
7. The apparatus of claim 6, wherein the disc-like flow path has a thickness which is less than three times the diameter of the optical fiber.
8. The apparatus of claim 6, wherein the disc-like flow path is bounded by surfaces which are perpendicular to the path of travel of the optical fiber.
9. The apparatus of claim 6, wherein the gap extends into the die opening at least as far as the point at which the coating material first contacts the optical fiber.
10. The apparatus of claim 6, wherein said chamber is a first chamber and said apparatus also includes a second chamber which is aligned with said first chamber, each of said chambers being connected to a source of vacuum.
11. An apparatus for making an optical fiber having first and second layers of coating material thereon, said apparatus including:
means for drawing an optical fiber from a preform;
a housing which includes a chamber;
means for establishing a pressure differential between said chamber and ambient atmosphere such that the ambient pressure is substantially greater than that in said chamber;
a first die including a die opening which is substantially larger than the diameter of the optical fiber;
a second die including a die opening which is substantially larger than the diameter of the optical fiber;
moving means for advancing the optical fiber into and through said chamber along a path of travel and through said first and then through said second die openings;
first flow passage means disposed between said first die opening and said chamber and including a first disc-like flow path which has at least a component that is normal to the path of travel for directing a first coating material into engagement with the moving optical fiber;
first feeding means for causing the first coating material to be flowed along said first flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is being moved through said first die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the first coating material occurs in the vicinity of the application of the first coating material to the optical fiber and wherein said moving means and said feeding means together with the diameter of said first die opening and the direction of said first flow path are such that a first gap forms between the first coating material and an adjacent surface of said first die with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces;
second flow passage means disposed between said first and second die openings and including a second disc-like flow path which has at least a component that is normal to the path of travel for directing a second coating material radially inwardly toward the path of travel into engagement with the first coating material on the optical fiber; and second feeding means for causing the second coating material to be flowed along the second flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is moved through said die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the second coating material occurs in the vicinity of the application of the second coating material to the coated optical fiber and wherein the movement of the optical fiber and said second feeding means together with the size of said second die opening and the direction of said second flow path are such that a second gap forms between the second coating material and an adjacent surface of said second die with the second coating material as it exits the second flow path and is directed into engagement with the first coating material on the moving optical fiber being bounded by free surfaces.
means for drawing an optical fiber from a preform;
a housing which includes a chamber;
means for establishing a pressure differential between said chamber and ambient atmosphere such that the ambient pressure is substantially greater than that in said chamber;
a first die including a die opening which is substantially larger than the diameter of the optical fiber;
a second die including a die opening which is substantially larger than the diameter of the optical fiber;
moving means for advancing the optical fiber into and through said chamber along a path of travel and through said first and then through said second die openings;
first flow passage means disposed between said first die opening and said chamber and including a first disc-like flow path which has at least a component that is normal to the path of travel for directing a first coating material into engagement with the moving optical fiber;
first feeding means for causing the first coating material to be flowed along said first flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is being moved through said first die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the first coating material occurs in the vicinity of the application of the first coating material to the optical fiber and wherein said moving means and said feeding means together with the diameter of said first die opening and the direction of said first flow path are such that a first gap forms between the first coating material and an adjacent surface of said first die with the coating material as it exits the flow path and is directed into engagement with the moving optical fiber being bounded by free surfaces;
second flow passage means disposed between said first and second die openings and including a second disc-like flow path which has at least a component that is normal to the path of travel for directing a second coating material radially inwardly toward the path of travel into engagement with the first coating material on the optical fiber; and second feeding means for causing the second coating material to be flowed along the second flow path radially inwardly toward the path of travel into engagement with the optical fiber to coat the fiber as it is moved through said die opening, the thickness of the flow path in a direction along the path of travel being such that substantially no recirculation of the second coating material occurs in the vicinity of the application of the second coating material to the coated optical fiber and wherein the movement of the optical fiber and said second feeding means together with the size of said second die opening and the direction of said second flow path are such that a second gap forms between the second coating material and an adjacent surface of said second die with the second coating material as it exits the second flow path and is directed into engagement with the first coating material on the moving optical fiber being bounded by free surfaces.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US092,117 | 1987-09-02 | ||
| US07/092,117 US4851165A (en) | 1987-09-02 | 1987-09-02 | Methods of and apparatus for coating optical fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1324258C true CA1324258C (en) | 1993-11-16 |
Family
ID=22231706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000576145A Expired - Fee Related CA1324258C (en) | 1987-09-02 | 1988-08-31 | Methods of and apparatus for coating optical fiber and products produced thereby |
Country Status (9)
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|---|---|
| US (1) | US4851165A (en) |
| EP (1) | EP0306329B1 (en) |
| JP (1) | JPS6479042A (en) |
| KR (1) | KR970005421B1 (en) |
| CN (1) | CN1024180C (en) |
| CA (1) | CA1324258C (en) |
| DE (1) | DE3873860D1 (en) |
| DK (1) | DK172988B1 (en) |
| TW (1) | TW201725B (en) |
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| US20120052213A1 (en) * | 2010-09-01 | 2012-03-01 | Fujikura Ltd. | Method for recoating double clad optical fiber |
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| US10036108B2 (en) * | 2013-11-26 | 2018-07-31 | Corning Incorporated | Apparatus and method for applications of optical fiber coatings |
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| JP7364239B2 (en) | 2017-11-03 | 2023-10-18 | コベストロ （ネザーランズ） ビー．ブイ． | Water barrier system comprising fibers coated with liquid radiation curable SAP composition |
| US11577994B2 (en) * | 2018-03-22 | 2023-02-14 | Sumitomo Electric Industries, Ltd. | Optical fiber manufacturing method and manufacturing device |
| EP3802452A1 (en) | 2018-06-01 | 2021-04-14 | DSM IP Assets B.V. | Radiation curable compositions for coating optical fiber via alternative oligomers and the coatings produced therefrom |
| JP2022506003A (en) | 2018-08-30 | 2022-01-17 | コベストロ （ネザーランズ） ビー．ヴィー． | Radiation-curable composition for coating optical fibers |
| CN109640521B (en) | 2018-11-20 | 2020-06-30 | 奥特斯科技(重庆)有限公司 | Method for manufacturing a component carrier with embedded clusters and component carrier |
| WO2020114902A1 (en) | 2018-12-03 | 2020-06-11 | Dsm Ip Assets B.V. | Filled radiation curable compositions for coating optical fiber and the coatings produced therefrom |
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| US3479053A (en) * | 1967-06-19 | 1969-11-18 | Moulton Development Ltd | Vehicle suspensions |
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| US4154879A (en) * | 1977-01-27 | 1979-05-15 | Polaroid Corporation | Method and apparatus for coating webs with a plurality of liquid layers |
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| SE453642B (en) * | 1982-06-18 | 1988-02-22 | Flutron Ab | PROCEDURE FOR COATING A SURFACE BY APPLYING A LIQUID UNDER PRESSURE, WHERE THE SURFACE IS FIRST EXPOSED TO VACUUM AND THEN PRESS |
| US4455159A (en) * | 1982-09-01 | 1984-06-19 | International Standard Electric Corporation | Method of and apparatus for coating optical fiber with plastics material |
| US4480898A (en) * | 1982-12-29 | 1984-11-06 | At&T Bell Laboratories | Fibers with multiple coatings |
| US4474830A (en) * | 1982-12-29 | 1984-10-02 | At&T Bell Laboratories | Multiple coating of fibers |
| US4512944A (en) * | 1983-06-23 | 1985-04-23 | At&T Technologies, Inc. | Methods of and apparatus for insulating a conductor with a plastic material |
| US4613521A (en) * | 1983-06-30 | 1986-09-23 | At&T Technologies, Inc. | Methods of and apparatus for coating a lightguide fiber |
| EP0200256B1 (en) * | 1985-04-19 | 1989-12-27 | Koninklijke Philips Electronics N.V. | Process and apparatus for coating a fibre |
| NL8502402A (en) * | 1985-09-03 | 1987-04-01 | Philips Nv | OPTICAL FIBER PROVIDED WITH A PLASTIC COATING, AND METHOD AND APPARATUS FOR MANUFACTURING SUCH OPTICAL FIBER. |
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- 1987-09-02 US US07/092,117 patent/US4851165A/en not_active Expired - Lifetime
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- 1988-09-01 DK DK198804862A patent/DK172988B1/en not_active IP Right Cessation
- 1988-09-01 CN CN88107060A patent/CN1024180C/en not_active Expired - Fee Related
- 1988-09-02 JP JP63218665A patent/JPS6479042A/en active Granted
- 1988-09-02 DE DE8888308150T patent/DE3873860D1/en not_active Expired - Lifetime
- 1988-09-02 EP EP88308150A patent/EP0306329B1/en not_active Expired - Lifetime
- 1988-09-02 KR KR1019880011320A patent/KR970005421B1/en not_active IP Right Cessation
- 1988-09-24 TW TW077106665A patent/TW201725B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| JPH054347B2 (en) | 1993-01-19 |
| US4851165A (en) | 1989-07-25 |
| DK486288D0 (en) | 1988-09-01 |
| DK486288A (en) | 1989-03-03 |
| EP0306329A3 (en) | 1990-05-16 |
| KR890005539A (en) | 1989-05-15 |
| CN1031990A (en) | 1989-03-29 |
| EP0306329B1 (en) | 1992-08-19 |
| EP0306329A2 (en) | 1989-03-08 |
| DE3873860D1 (en) | 1992-09-24 |
| TW201725B (en) | 1993-03-11 |
| KR970005421B1 (en) | 1997-04-16 |
| JPS6479042A (en) | 1989-03-24 |
| CN1024180C (en) | 1994-04-13 |
| DK172988B1 (en) | 1999-11-01 |
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