CA2015857A1 - Dynamically vulcanized alloys having improved stiffness/impact balance - Google Patents

Dynamically vulcanized alloys having improved stiffness/impact balance

Info

Publication number
CA2015857A1
CA2015857A1 CA2015857A CA2015857A CA2015857A1 CA 2015857 A1 CA2015857 A1 CA 2015857A1 CA 2015857 A CA2015857 A CA 2015857A CA 2015857 A CA2015857 A CA 2015857A CA 2015857 A1 CA2015857 A1 CA 2015857A1
Authority
CA
Canada
Prior art keywords
dynamically vulcanized
improved stiffness
impact balance
vulcanized alloys
fillers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2015857A
Other languages
French (fr)
Other versions
CA2015857C (en
Inventor
Robert Chester Puydak
Donald Ross Hazelton
Blair Alfred Graham
Narayanaswami Raja Dharmarajan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advanced Elastomer Systems LP
Original Assignee
Robert Chester Puydak
Donald Ross Hazelton
Blair Alfred Graham
Narayanaswami Raja Dharmarajan
Exxon Chemical Patents Inc.
Advanced Elastomer Systems, L.P.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27000277&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2015857(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Robert Chester Puydak, Donald Ross Hazelton, Blair Alfred Graham, Narayanaswami Raja Dharmarajan, Exxon Chemical Patents Inc., Advanced Elastomer Systems, L.P. filed Critical Robert Chester Puydak
Publication of CA2015857A1 publication Critical patent/CA2015857A1/en
Application granted granted Critical
Publication of CA2015857C publication Critical patent/CA2015857C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/011—Crosslinking or vulcanising agents, e.g. accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283—Halogenated homo- or copolymers of iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof

Abstract

A dynamically vulcanized composition comprising a polyolefin resin and an elastomer is provided in which a major portion of fillers or specified additives are present in the polyolefin resin. A process for producing the dynamically vulcanized composition is also provided including the addition of the fillers and/or specified additives after the dynamic vulcanization step. The compositions have improved stiffness to impact balance.
CA002015857A 1989-05-26 1990-05-01 Dynamically vulcanized alloys having improved stiffness/impact balance Expired - Fee Related CA2015857C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US35897489A 1989-05-26 1989-05-26
US358,974 1989-05-26
US07/495,839 US5100947A (en) 1989-05-26 1990-03-19 Dynamically vulcanized alloys having improved stiffness/impact balance
US495,839 1990-03-19

Publications (2)

Publication Number Publication Date
CA2015857A1 true CA2015857A1 (en) 1990-11-26
CA2015857C CA2015857C (en) 2000-08-08

Family

ID=27000277

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002015857A Expired - Fee Related CA2015857C (en) 1989-05-26 1990-05-01 Dynamically vulcanized alloys having improved stiffness/impact balance

Country Status (11)

Country Link
US (1) US5100947A (en)
EP (1) EP0404351B2 (en)
JP (1) JPH0354237A (en)
KR (1) KR0164844B1 (en)
AT (1) ATE141940T1 (en)
AU (1) AU627310B2 (en)
BR (1) BR9002485A (en)
CA (1) CA2015857C (en)
DE (1) DE69028252T3 (en)
ES (1) ES2090097T5 (en)
NO (1) NO902326L (en)

Families Citing this family (124)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6013727A (en) * 1988-05-27 2000-01-11 Exxon Chemical Patents, Inc. Thermoplastic blend containing engineering resin
US5013793A (en) * 1990-07-26 1991-05-07 Exxon Chemical Patents Inc. Dynamically cured thermoplastic olefin polymers and process for producing the same
FR2661915B1 (en) * 1990-05-11 1993-12-24 Rhone Poulenc Chimie ELASTOMETRIC COMPOSITION WITH HALOGENOBUTYL MATRIX REINFORCED BY A SILICA MINERAL FILLER AND ITS USE IN THE PNEUMATIC INDUSTRY.
DE69104986T2 (en) * 1990-07-24 1995-03-23 Exxon Chemical Patents Inc COMPOSITION FOR TIRE CARCASES.
USH1922H (en) * 1991-07-03 2000-11-07 Exxon Chemical Patents Inc. Coating composition
KR950007662B1 (en) * 1991-12-24 1995-07-14 주식회사럭키 Polyolefin resin composition(i) having excellent coating
US6303691B1 (en) * 1992-07-31 2001-10-16 Exxon Mobil Chemical Patents Inc. Impact modification of polyamides
EP0695327A1 (en) * 1993-04-19 1996-02-07 Exxon Chemical Patents Inc. Compatibilized elastomer blends containing grafted polymers of an isoolefin and alkylstyrene
US5290886A (en) * 1993-04-20 1994-03-01 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved low temperature properties
US5397839A (en) * 1993-12-13 1995-03-14 Advanced Elastomer Systems, L.P. Polyester-hydrogenated diene rubber compositions
JP3548619B2 (en) * 1994-03-04 2004-07-28 アドバンスド エラストマー システムズ，エル．ピー． Translucent thermoplastic elastomer
JP3255330B2 (en) * 1994-05-27 2002-02-12 電気化学工業株式会社 Method for producing thermoplastic resin
AT403377B (en) * 1994-09-26 1998-01-26 Danubia Petrochem Polymere METHOD FOR GRAFTING POLYOLEFINES
DE4435534A1 (en) * 1994-10-05 1996-04-11 Danubia Petrochem Deutschland Safe continuous prodn. of homogeneous graft polyolefin without sticking
US5852093A (en) * 1994-11-30 1998-12-22 Nippon Zeon Co., Ltd. Vulcanizable rubber composition, seal used in dynamic state, and sealing material
EP0718347A1 (en) 1994-12-24 1996-06-26 Advanced Elastomer Systems, L.P. Method to adhere thermoplastic elastomer blends to polyester substrates
ES2127001T3 (en) * 1995-02-07 1999-04-01 Dsm Nv THERMOPLASTIC ELASTOMER.
HUP9900573A3 (en) * 1995-05-03 1999-11-29 Exxon Chemical Patents Inc Bay Compatibilized blends of polypropylene and poly(phenylene ether) polymers
US5986000A (en) * 1995-05-22 1999-11-16 Playtex Products, Inc. Soft, flexible composition and method for making same
EP0757077A1 (en) 1995-08-01 1997-02-05 Advanced Elastomer Systems, L.P. Very soft thermoplastic elastomer compositions
US5621045A (en) * 1995-11-13 1997-04-15 Patel; Raman Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber
US6150464A (en) * 1995-12-01 2000-11-21 Advanced Elastomer Systems, L.P. Preferred process for silicon hydride addition and preferred degree of polymerization for silicon hydride for thermoplastic vulcanizates
US5672660A (en) * 1995-12-01 1997-09-30 Advanced Elastomer Systems, L.P. Hydrosilylation crosslinking
WO1997022758A1 (en) * 1995-12-19 1997-06-26 The B.F. Goodrich Company Resilient plastic-elastomer alloy for fender protective structures
US5791278A (en) * 1995-12-19 1998-08-11 Duramax, Inc. Fender protective structure
US6030304A (en) * 1996-03-12 2000-02-29 Wilson Sporting Goods Co. Pressureless tennis ball
EP0889090A1 (en) * 1997-07-04 1999-01-07 Advanced Elastomer Systems, L.P. Thermoplastic elastomer vulcanizate
US6407174B1 (en) * 1997-07-04 2002-06-18 Advanced Elastomer Systems, L.P. Propylene/ethylene/α-olefin terpolymer thermoplastic elastomer vulcanizates
US6207752B1 (en) 1997-12-10 2001-03-27 Advanced Elastomer Systems Lp Thermoplastic vulcanizates of carboxylated nitrile rubber and thermoplastic polyurethanes
US6211275B1 (en) * 1998-11-10 2001-04-03 New Jersey Institute Of Technology Wood substitute composition and process for producing same
US6084031A (en) * 1998-11-30 2000-07-04 Advanced Elastomer Systems, L.P. TPV from hydrosilylation crosslinking of acrylic modified bromo XP-50 butyl rubber
US6284840B1 (en) 1999-04-02 2001-09-04 Acushnet Company Golf ball core compositions containing high Vicat softening temperature, resilient thermoplastic materials
KR20010019162A (en) * 1999-08-25 2001-03-15 신형인 Non Discoloring White Sidewall Rubber Composition
US6451915B1 (en) 2000-12-29 2002-09-17 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved processing and physical property balance
US6462132B2 (en) * 2001-01-09 2002-10-08 Dsm N.V. Thermoplastic elastomer composition and molded articles made thereof
US6433090B1 (en) 2001-01-26 2002-08-13 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved set foams made therefrom
WO2002100940A1 (en) * 2001-06-08 2002-12-19 Thermoplastic Rubber Systems, Inc. Thermoplastic vulcanizates
US6639003B2 (en) * 2001-09-11 2003-10-28 Gregory G. Borsinger Rubber additive
US7452940B2 (en) * 2001-10-11 2008-11-18 Dsm I.P. Assets B.V. Process for the preparation of a dynamically vulcanized thermoplastic elastomer
CA2386646C (en) * 2002-05-16 2010-07-20 Bayer Inc. Rubber compound for a vibration dampening device
JP4683928B2 (en) * 2002-12-18 2011-05-18 株式会社ブリヂストン Clay exfoliation method, composition obtained from the method, and modified rubber containing the composition
US6790911B2 (en) * 2002-12-26 2004-09-14 Advanvced Elastomer Systems, L.P. Thermoplastic elastomers having improved adhesive proterties
US6838495B2 (en) 2003-01-17 2005-01-04 Louis Frank Gatti Rubber composition comprising composite pigment
US6866711B2 (en) 2003-01-17 2005-03-15 Fitzgerald Alphanso Sinclair Composite pigment composition containing silica
KR100546008B1 (en) * 2003-07-14 2006-01-25 정태원 Manufacturing method and composition of polyethylene-based composition containing glass fiber
JP4869931B2 (en) * 2003-09-05 2012-02-08 テクノア エイペックス カンパニー Film comprising an ethylene / alpha-olefin copolymer and its use in medical or hygiene applications
US7964670B2 (en) * 2003-09-05 2011-06-21 Teknor Apex Company Film comprising an ethylene/alpha-olefin copolymer and its use in medical or hygienic applications
US7868096B2 (en) * 2003-09-17 2011-01-11 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and processes for making the same
CA2546233C (en) 2003-11-13 2013-04-23 Dsm Ip Assets B.V. Use of a vulcanised thermoplastic elastomer or styrene-ethylene-butadiene-styrene polymer as infill material in artificial turf systems
EP1531201A1 (en) 2003-11-13 2005-05-18 DSM IP Assets B.V. Use of a vulcanised thermoplastic elastomer or a styrene-ethylene-butadiene-styrene polymer as infill material in artificial turf systems
WO2005049670A1 (en) * 2003-11-14 2005-06-02 Exxonmobil Chemical Patents Inc. Propylene-based elastomers and uses thereof
US20050110193A1 (en) * 2003-11-26 2005-05-26 Envirotech Pumpsystems, Inc. Composition for making polymeric linings
US20060052540A1 (en) 2004-09-09 2006-03-09 Maria Ellul Thermoplastic vulcanizates
US7193018B2 (en) * 2004-09-15 2007-03-20 Advanced Elastomer Systems, Lp. Slip-coat compositions and polymeric laminates
EP1674530A1 (en) * 2004-12-24 2006-06-28 Kraton Polymers Research B.V. High melt strength thermoplastic elastomer composition
US7572855B2 (en) * 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) * 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US8076416B2 (en) 2005-02-04 2011-12-13 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and their use
US7655728B2 (en) * 2005-06-27 2010-02-02 Exxonmobil Chemical Patents Inc. Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders
US7909194B2 (en) * 2005-07-01 2011-03-22 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and sealing devices made therewith
EP1937946B1 (en) * 2005-09-16 2009-01-28 Dayco Fluid Technologies S.p.A. Device for purifying exhaust gases of a vehicle by selective catalytic reduction including a heated piping
CN101287943A (en) * 2005-09-16 2008-10-15 戴科流体技术公司 Multilayered pipe for transmitting and heating fluid
US7872075B2 (en) 2005-10-07 2011-01-18 Exxonmobil Chemical Patents Inc. Peroxide-cured thermoplastic vulcanizates and process for making the same
US7550534B2 (en) * 2005-11-16 2009-06-23 Sabic Innovative Plastics Ip B.V. Thermoplastic method, composition, and article
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7812093B2 (en) * 2005-12-19 2010-10-12 Exxonmobil Chemical Patents Inc. Peroxide-cured thermoplastic vulcanizates and medical devices made therewith
US7601772B2 (en) * 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
WO2007071438A1 (en) 2005-12-23 2007-06-28 Dsm Ip Assets B.V. Use of thermoplastic elastomers in floor covering for animal housing
US8039526B2 (en) * 2006-04-05 2011-10-18 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates including nanoclays and processes for making the same
US7935184B2 (en) * 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
CA2598342C (en) * 2006-09-08 2014-10-14 Lanxess Inc. Peroxide cured thermoplastic vulcanizates comprising butyl rubber
US7935763B2 (en) 2006-10-11 2011-05-03 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions having improved extrusion performance and methods of formation thereof
US7951871B2 (en) * 2006-11-10 2011-05-31 Exxonmobil Chemical Patents Inc. Curing rubber by hydrosilation
WO2008085762A1 (en) * 2007-01-04 2008-07-17 Polyone Corporation Thermally stable thermoplastic vulcanizate compounds
WO2008134173A1 (en) * 2007-05-01 2008-11-06 Advanced Elastomer Systems, L.P. Method for preparing thermoplastic vulcanizates
US8487033B2 (en) * 2007-05-16 2013-07-16 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
WO2008154068A1 (en) * 2007-06-13 2008-12-18 Advanced Elastomer Systems, L.P. Thermoplastic polymer compositions, methods for making the same, and articles made therefrom
WO2009123609A1 (en) * 2008-03-31 2009-10-08 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates
US8877867B2 (en) * 2008-11-06 2014-11-04 Exxonmobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates and extruded articles therefrom
US20110120733A1 (en) 2009-11-20 2011-05-26 Schlumberger Technology Corporation Functionally graded swellable packers
US8247494B2 (en) * 2009-11-23 2012-08-21 Exxonmobil Chemical Patents Inc. Thermoset compositions with dispersed thermoplastic resin therein and process for making them
WO2011081746A1 (en) 2009-12-30 2011-07-07 Exxonmobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates
US8557906B2 (en) 2010-09-03 2013-10-15 Exxonmobil Chemical Patents Inc. Flame resistant polyolefin compositions and methods for making the same
JP5764669B2 (en) * 2010-12-30 2015-08-19 ダウ グローバル テクノロジーズ エルエルシー Thermoplastic vulcanized composition, method for producing the same, and article produced therefrom
EP2574635A1 (en) 2011-09-28 2013-04-03 Lanxess Inc. Process for continuous production of halogen-free thermoplastic elastomer compositions
KR101113114B1 (en) * 2011-10-13 2012-02-07 (주) 웹스 Olefin-based composition used for manufacturing wpc
US10266683B2 (en) 2012-05-10 2019-04-23 Exxonmobil Chemical Patents Inc. Compositions and methods for making them
EP2690136A1 (en) 2012-07-25 2014-01-29 Lanxess Elastomers B.V. Thermoplastic elastomer compositions and process for preparing them
US10240008B2 (en) 2014-05-12 2019-03-26 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and method of making the same
JP6498760B2 (en) 2014-10-24 2019-04-10 エクソンモービル・ケミカル・パテンツ・インク Thermoplastic vulcanizate composition
WO2016085457A1 (en) 2014-11-25 2016-06-02 Exxonmobil Chemical Patents Inc. Method of making thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom
JP6510077B2 (en) * 2015-05-29 2019-05-08 エクソンモービル ケミカル パテンツ インコーポレイテッド Dynamic vulcanized alloy
US10790404B2 (en) 2016-03-30 2020-09-29 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions for photovoltaic cell applications
DE102017217399A1 (en) * 2017-09-29 2019-04-04 Continental Reifen Deutschland Gmbh 3D printable polymeric composition and products
US11725098B2 (en) 2017-12-18 2023-08-15 Celanese International Corporation Thermoplastic vulcanizate conduits for transporting hydrocarbon fluids
US11939473B2 (en) 2018-01-18 2024-03-26 Celanese International Corporation Thermoplastic vulcanizates
US11359083B2 (en) 2018-01-18 2022-06-14 Celanese International Corporation Thermoplastic vulcanizates
CN111918920A (en) 2018-04-10 2020-11-10 埃克森美孚化学专利公司 Thermoplastic vulcanizate composition
CN112997033B (en) 2018-09-14 2023-07-25 国际人造丝公司 Thermoplastic vulcanizate composition, preparation and use in flexible tubular tubing
WO2020055704A1 (en) 2018-09-14 2020-03-19 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions in polymeric inner / pressure sheaths of flexible pipes for oil & gas applications
EP3856835A1 (en) 2018-09-24 2021-08-04 ExxonMobil Chemical Patents Inc. Crosslinked elastomer-polymer blends
US20220112364A1 (en) 2019-03-21 2022-04-14 Exxonmobil Chemical Patents Inc. Pipe Including a Thermoplastic Vulcanizate Composition
EP3956387A1 (en) 2019-04-17 2022-02-23 ExxonMobil Chemical Patents Inc. Method for improving uv weatherability of thermoplastic vulcanizates
US11413800B2 (en) 2019-05-20 2022-08-16 Kraton Polymers Llc Molding compositions and articles made thereof
CN110240775A (en) * 2019-05-29 2019-09-17 泰兴市艾珀耐特复合材料有限公司 A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof
US20220177684A1 (en) 2019-06-13 2022-06-09 Exxonmobill Chemical Patents Inc. Automotive Weather Seals Formed with Thermoplastic Vulcanizate Compositions
JP2022536829A (en) 2019-06-21 2022-08-19 エクソンモービル・ケミカル・パテンツ・インク Thermoplastic vulcanizate composition
EP4021718A1 (en) 2019-08-26 2022-07-06 Celanese International Corporation Thermoplastic vulcanizate compositions and thermoplastic olefinic compositions as insulating layers in non-flexible pipes
WO2021080813A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions and processes for the production thereof
US20230133171A1 (en) 2020-03-18 2023-05-04 Celanese International Corporation Thermoplastic Elastomer Compositions, Their Preparation and Use in Fiber-Reinforced Spoolable Pipes
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
WO2021225813A1 (en) 2020-05-05 2021-11-11 Exxonmobil Chemical Patents Inc. Pipe including a polymethylpentene thermoplastic polymer
JP2023527426A (en) 2020-05-29 2023-06-28 エクソンモービル ケミカル パテンツ インコーポレイテッド Cyclic olefin production method from polymer and its repolymerization method
US20240035572A1 (en) 2020-12-16 2024-02-01 Celanese International Corporation Extrusion Molded Thermoplastic Vulcanizate Gaskets and Methods of Making Such Gaskets
EP4015179A1 (en) 2020-12-21 2022-06-22 Parker Hannifin Corp. Readily processable, oil-resistant thermoplastic vulcanizates
EP4019586A3 (en) 2020-12-21 2022-09-28 Parker Hannifin Corp. High temperature, oil-resistant thermoplastic vulcanizates
US20220195156A1 (en) 2020-12-21 2022-06-23 Parker-Hannifin Corporation Readily-processable, high-temperature, oil-resistant thermoplastic vulcanizates
EP4063449B1 (en) 2021-03-25 2023-12-13 Parker Hannifin Corp. Thermoplastic vulcanizates comprising acrylate rubber and thermoplastic polyurethane
EP4063448B1 (en) 2021-03-25 2023-12-06 Parker-Hannifin Corporation Thermoplastic vulcanizates made of thermoplastic polyurethane and carboxylated nitrile butadiene
EP4196344B1 (en) 2021-06-10 2023-12-27 Nike Innovate C.V. Composite textiles and articles of footwear formed therefrom
CN113563650A (en) * 2021-08-25 2021-10-29 全球能源互联网研究院有限公司 Oil-immersed acoustic vibration suppression damping rubber and preparation method thereof
CN113999517A (en) * 2021-10-12 2022-02-01 中广核三角洲（江苏）塑化有限公司 Antistatic dynamic vulcanized silicone rubber thermoplastic elastomer and preparation method thereof
CN114316606B (en) * 2021-12-31 2023-02-10 东莞市正安有机硅科技有限公司 Polyolefin base material thermoplastic dynamic vulcanized silicone rubber particles and preparation method thereof
EP4299662A1 (en) 2022-06-28 2024-01-03 Parker-Hannifin Corporation Thermoplastic vulcanizates made of polyamide and bimsm rubber

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3037954A (en) * 1958-12-15 1962-06-05 Exxon Research Engineering Co Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber
USRE31518E (en) * 1971-08-12 1984-02-07 Uniroyal, Inc. Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic
US4130535A (en) * 1975-07-21 1978-12-19 Monsanto Company Thermoplastic vulcanizates of olefin rubber and polyolefin resin
DE2822815C2 (en) * 1977-05-26 1994-02-17 Mitsui Petrochemical Ind Process for the preparation of a partially vulcanized thermoplastic composition
US4311628A (en) * 1977-11-09 1982-01-19 Monsanto Company Thermoplastic elastomeric blends of olefin rubber and polyolefin resin
US4202801A (en) * 1977-12-30 1980-05-13 Uniroyal, Inc. Thermoplastic elastomer composition
JPS5723642A (en) * 1980-07-17 1982-02-06 Mitsubishi Petrochem Co Ltd Olefinic polymer composition containing inorganic filler
US4348459A (en) * 1980-11-10 1982-09-07 Uniroyal, Inc. Thermoplastic elastomer and electrical article insulated therewith
CA1255492A (en) * 1984-02-27 1989-06-13 Lawrence Spenadel Elastomeric thermoplastic low voltage insulation
US4593062A (en) * 1984-12-10 1986-06-03 Exxon Research & Engineering Co. Dynamically cured thermoplastic olefin polymers
IT1203607B (en) † 1985-12-20 1989-02-15 So F Ter Spa PROCEDURE FOR PREPARING PLASTO-ELASTOMERIC COMPOSITIONS BASED ON POLYOLEFINS AND EPDM TERPOLYMERS AND PLASTIC-ELASTOMERIC COMPOSITIONS SO OBTAINED
US4735982A (en) * 1986-07-25 1988-04-05 The B. F. Goodrich Company Thermoplastic-rubber polymer alloys and method for producing the same
KR920003034B1 (en) * 1988-06-21 1992-04-13 동양나이론 주식회사 Resin making material
US4957968A (en) * 1988-08-09 1990-09-18 Monsanto Company Adhesive thermoplastic elastomer blends
BR8907741A (en) * 1988-10-28 1991-08-27 Exxon Chemical Patents Inc DYNAMICALLY VULCANIZED ALLOYS OF CRYSTALLINE POLYOLEFIN RESIN AND HALOBUTILE RUBBER MATERIAL
US5073597A (en) * 1989-05-26 1991-12-17 Advanced Elastomer Systems, L. P. Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix

Also Published As

Publication number Publication date
ES2090097T5 (en) 2002-12-01
ES2090097T3 (en) 1996-10-16
EP0404351A3 (en) 1991-07-17
KR900018241A (en) 1990-12-20
AU5589890A (en) 1990-11-29
DE69028252T3 (en) 2003-02-13
JPH0354237A (en) 1991-03-08
KR0164844B1 (en) 1999-03-20
ATE141940T1 (en) 1996-09-15
DE69028252D1 (en) 1996-10-02
AU627310B2 (en) 1992-08-20
NO902326L (en) 1990-11-27
US5100947A (en) 1992-03-31
BR9002485A (en) 1991-08-13
EP0404351B2 (en) 2002-07-24
EP0404351B1 (en) 1996-08-28
EP0404351A2 (en) 1990-12-27
DE69028252T2 (en) 1997-03-13
CA2015857C (en) 2000-08-08
NO902326D0 (en) 1990-05-25

Similar Documents

Publication Publication Date Title
CA2015857A1 (en) Dynamically vulcanized alloys having improved stiffness/impact balance
CA2047909A1 (en) Ethylene copolymer-modified dynamically vulcanized alloys
TW353098B (en) Synthetic latex compositions and articles produced therefrom
EP0485631A4 (en) Polyolefin resin composition
CA2191107A1 (en) Soft thermoplastic elastomers having improved resistance to oil swell and compression set
CA2081067A1 (en) Golf ball core compositions
IL94494A0 (en) Method for the preparation of destructured-starch-based compositions and compositions produced thereby
CA2008032A1 (en) Moldable compositions of activated carbon and molded articles produced therefrom
DE3483538D1 (en) IMPACT MODIFIED POLYOXYMETHYLENE AND MOLDED BODIES MADE THEREOF.
ZA873599B (en) Cured rubber compositions of high modulus
CA2194856A1 (en) Dynamically vulcanizable polyolefin compositions
CA2013613A1 (en) Thermoelastic composition of ethylene-1-olefin copolymer and rubber
EP0040060A3 (en) Compositions of cured epichlorohydrin rubber and nylon
CA2277590A1 (en) Rubber composition for tire tread and pneumatic tire
AU1148588A (en) Polypropylene molding material
JPS5787445A (en) Rubber material
IL91559A (en) Preparation of high modulus rubber composition from epoxidized rubber and nylons
DK0431733T3 (en) Polyolefin compositions with improved impact strength
CA2250626A1 (en) Method for manufacture of elastomeric alloys using recycled rubbers
CA2024917A1 (en) Damper in the form of a shock absorber
ATE243236T1 (en) THERMOPLASTIC MOLDED BODY WITH SEGMENTS OF DIFFERENT STIFFNESS
JPS5641238A (en) Thermoplastic elastomer composition
ES8301258A1 (en) Vulcanisable rubber composition.
ZA855445B (en) Method for increasing the modulus of vulcanizable rubber compositions
JPS56139542A (en) Novel vulcanization accelerator for rubber

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed