CA2022782C - Electrode for plasma arc torch - Google Patents
Electrode for plasma arc torch Download PDFInfo
- Publication number
- CA2022782C CA2022782C CA002022782A CA2022782A CA2022782C CA 2022782 C CA2022782 C CA 2022782C CA 002022782 A CA002022782 A CA 002022782A CA 2022782 A CA2022782 A CA 2022782A CA 2022782 C CA2022782 C CA 2022782C
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- Prior art keywords
- insert
- sleeve
- holder
- electrode
- cavity
- Prior art date
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- Expired - Lifetime
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Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3436—Hollow cathodes with internal coolant flow
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3442—Cathodes with inserted tip
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3452—Supplementary electrodes between cathode and anode, e.g. cascade
Abstract
An electrode for a plasma arc torch and a method of fabricating the same are disclosed, and wherein the electrode includes a copper holder having a lower end which mounts an emissive insert which acts as the cathode terminal for the arc during operation.
Where the torch is used in an oxidizing atmosphere, the copper holder tends to oxidize; and the arc tends to attach to the oxidized copper rather than the insert, which results in the rapid destruction of the holder.
Ta prevent this destruction, the present invention incorporates a sleeve of silver or other metal having a relatively high work function, and which is positioned to surround the insert and form an annular ring on the lower end surface of the holder and thus to surround the exposed end face of the emissive insert. The annular ring serves to prevent arcing from the copper holder, and so that the arc is maintained on the insert.
Where the torch is used in an oxidizing atmosphere, the copper holder tends to oxidize; and the arc tends to attach to the oxidized copper rather than the insert, which results in the rapid destruction of the holder.
Ta prevent this destruction, the present invention incorporates a sleeve of silver or other metal having a relatively high work function, and which is positioned to surround the insert and form an annular ring on the lower end surface of the holder and thus to surround the exposed end face of the emissive insert. The annular ring serves to prevent arcing from the copper holder, and so that the arc is maintained on the insert.
Description
ELECTRODE FOR PLASMA ARC TORCH
Background of the Invention The present invention relates to a plasma arc torch, and more particularly to a novel electrode for use in a plasma arc torch and which has improved service life.
Plasma arc torches are commonly used for the working of metals, including cutting, welding, surface treatment, melting, and annealing. Such torches include an electrode which supports an arc which extends from the electrode to the workpiece in the transferred arc mode of operation. It is also conventional to surround the arc with a swirling vortex of gas, and in some torch designs it is conventional to also~envelope the gas and arc with a swirling jet of water. ' The electrode used in conventional torches of the described type typically comprises an elongate tubular member composed of a material of high thermal conductivity, such as copper or a copper alloy. The forward or discharge end of the tubular electrode includes a bottom end wall having an emissive insert embedded therein which supports the arc. The insert is composed of a material which has a relatively low work function, which is defined in the art as the potential step, measured in electron volts, which permits thermionic emission from the surface of a metal at a given temperature. In view of its low work function, 2027.82 = .--.- .
Background of the Invention The present invention relates to a plasma arc torch, and more particularly to a novel electrode for use in a plasma arc torch and which has improved service life.
Plasma arc torches are commonly used for the working of metals, including cutting, welding, surface treatment, melting, and annealing. Such torches include an electrode which supports an arc which extends from the electrode to the workpiece in the transferred arc mode of operation. It is also conventional to surround the arc with a swirling vortex of gas, and in some torch designs it is conventional to also~envelope the gas and arc with a swirling jet of water. ' The electrode used in conventional torches of the described type typically comprises an elongate tubular member composed of a material of high thermal conductivity, such as copper or a copper alloy. The forward or discharge end of the tubular electrode includes a bottom end wall having an emissive insert embedded therein which supports the arc. The insert is composed of a material which has a relatively low work function, which is defined in the art as the potential step, measured in electron volts, which permits thermionic emission from the surface of a metal at a given temperature. In view of its low work function, 2027.82 = .--.- .
given temperature. In view of its low work function, the insert is thus capable of readily emitting electrons when an electrical potential is applied thereto, and commonly used insert materials include hafnium, zirconium, and tungsten.
A significant problem associated with torches of the described type is the short service life of the electrode, particularly when the torch is used with an oxidizing arc gas, such as oxygen or air. More particularly, the gas tends to rapidly oxidize the copper, and as the copper oxidizes, its work function falls. As a result, the oxidized copper which ' surrounds the insert begins to support the arc in preference to the insert. When this happens, the copper oxide and the supporting copper melt, resulting in the early destruction and failure of the electrode.
It is accordingly an object of the present invention to provide an electrode which is adapted for use in a plasma arc torch of the described type, and which is able to provide a significantly improved service life when the torch is used in an oxidizing atmosphere.
It is also an object of the present invention to pxovide an efficient method of fabricating an electrode having the above characteristics.
Summary of the Invention The above and other objects and advantages of the present invention are achieved in the embodiments illustrated herein by the provision of an electrode which comprises a metallic tubular holder having a front end and a rear end, and a transverse end wall closing the front end. The transverse end wall defines an outer front face, and a cavity is formed in the front face. An insert assembly is mounted in the cavity, and comprises an emissive insert composed of a metallic material which has a relatively low work function so as to be capable of readily emitting ,~ _3_ 20227 82 electrons upon a potential being applied thereto. A
sleeve surrounds the emissive insert so as to separate '. . the insert from contact with the holder. The sleeve has a radial thickness of at least about .01 inches at the front end of the holder, and the sleeve is composed of a metallic material having a work function which is greater than that of the material of the emissive insert.
The emissive insert has an outer end face l0 which lies in the plane of the outer front face of the holder, and the sleeve has an outer annular surface which lies in. the plane of the front face of the holder and surrounds the end face of the insert. Also, the diameter of the outer annular surface of the. sleeve preferably is at least equal to about twice~the longest dimension of said outer end face of the emissive insert.
In the preferred embodiment, the sleeve includes a peripheral surface and a closed bottom wall which are metallurgically bonded to the interior walls of the cavity formed in the outer front face of the . holder. The sleeve thus totally separates the insert from contact with the metal of the holder.
The annular sleeve which surrounds the emissive insert is preferably formed of a metallic material such as silver which has a high resistance to the formation of an oxide. This serves to increase the service life of the electrode, since the silver and any oxide which does form are very poor emitters. As a result, the arc will continue to emit from the emissive insert, rather than.from the copper holder or the sleeve and the result~is an increase in its service life.
B
3a 20 2 27 8 2 In accordance with an aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
a metallic holder having a front end, and a cavity in the front end, and an insert assembly mounted in the cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding the emissive insert so as to separate the emissive insert from contact with the holder, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the emissive insert, and the sleeve being composed of a metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and allows thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
a metallic holder having a front end, and a cavity in the front end, and an insert assembly mounted in the cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding the emissive insert so as to separate the emissive insert from contact with the holder, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the emissive insert, and the sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof, and wherein the second metal ft 3b comprises at least 10% by weight of the alloy of copper and the second metal, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
S In accordance with yet another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing the front end, the transverse end wall having a planar outer front face which is perpendicular to the longitudinal axis, and a cavity formed in the front face and which extends rearwardly along the longitudinal axis, and an insert assembly mounted in the cavity and comprising:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the holder and greater than that of the material of the emissive insert, the metallic sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
3c a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing the front end, the transverse end wall having a planar outer front face which is perpendicular to the longitudinal axis, and a cavity formed in the front face and which extends rearwardly along the longitudinal axis, and an insert assembly mounted in the cavity and comprising:
(a) a generally cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the holder and greater than that of the material of the emissive insert, the metallic sleeve being somposed of an alloy which comprises copper and a second metal which is selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and alloys thereof, and wherein the second metal comprises at least 10% by weight of the alloy of copper and the second metal, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with yet another aspect of the present invention is a plasma torch which comprises:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, the transverse front end wall having a substantially planar outer front face which is perpendicular to the longitudinal axis, a cavity formed in the front face along the longitudinal axis, and an B
3d insert assembly mounted in the cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of the emissive insert, the sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals, the sleeve further having an outer annular surface lying in the plane of the front face of the holder and surrounding the end face of the insert, nozzle means mounted adjacent the transverse front end wall of the electrode and having a bore therethrough which is aligned with the longitudinal axis, means for creating an electrical arc extending from the emissive insert of the electrode through the bore and to a workpiece located adjacent the nozzle means, and means for generating a vortical flow of a gas between the electrode and the nozzle means and so as to create a plasma flow outwardly through the bore and to the workpiece.
In accordance with yet another aspect of the present invention is a plasma torch comprising:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, the transverse front end wall s 3e having a substantially planar outer front face which is perpendicular to the longitudinal axis, a cavity formed in the front face along the longitudinal axis, and an insert assembly mounted in the cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a relatively low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of the emissive insert, the metallic sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof and wherein the second metal comprises at least 10~
by weight of the alloy of copper and the second metal, the sleeve further having an outer annular surface lying in the plane of the front face of the holder and surrounding the end face of the insert, nozzle means mounted adjacent the transverse front end wall of the electrode and having a bore therethrough which is aligned with the longitudinal axis, means for creating an electrical arc extending from the emissive insert of the electrode through the bore and to a workpiece located adjacent the nozzle means, and -- 3f 2422782 means for generating a vortical flow of gas between the electrode and the nozzle means and so as to create a plasma flow outwardly through the bore and to the workpiece.
The present invention also includes a method of fabricating the above described electrode and which comprises the steps of preparing a metallic first blank Wh~cl1 hay a frnr,i- ~~.... ...~~ ~__-_ ~ . _ _ 2o22~.s2 front face of the blank. A second blank is formed which is composed for example essentially of silver and which is configured and sized so as to permit it to be closely received in the cavity. The second blank is then fixedly mounted in the cavity, and an opening is formed in the second blank, such as by drilling, and which is perpendicular to the front face. An emissive insert is then fixedly mounted in the opening of the second blank.
Preferably, the front facelof the metallic blank is then finished to form a substantially planar surface which includes the metallic first blank, the emissive insert, and an annular ring of the second blank which separates the insert from the metallic blank.
Brief Description of the Drawings Some of the objects and advantages of the present invention having been stated, others will appear as the description proceeds, when considered in conjunction with the accompanying drawings, in which Figure 1 is a sectioned side elevation view of a plasma arc torch which embodies the features of the present invention;
Figure 2 is a somewhat enlarged fragmentary sectioned view of the lower portion of a plasma arc torch and illustrating a second embodiment of the nozzle assembly of the torch;
Figures 3-7 are schematic views illustrating the steps of the method of fabricating the electrode in accordance with the present invention;
Figure 8 is an end view of the electrode shown in Figure 7; and Figures 9-12 are sectioned side elevation views of other embodiments of the'electrode of the present invention.
-- 20227-82 w Detailed Description of the Preferred Embodiments Referring initially to the embodiment of Figure 1, a plasma arc torch 10 is illustrated which includes a nozzle assembly 12 and a tubular electrode 14. The electrode 14 is preferably made of copper or a copper alloy, and it is composed of an upper tubular member 15 and a lower, cup-shaped member or holder 16.
More particularly, the upper tubular member 15 is of elongate open tubular construction and it defines the longitudinal axis of the torch. The~member 15 also includes an internally threaded lower end portion 17.
The holder 16 is also of tubular construction, and it includes a lower front end and an upper rear end as seen in Figures 1 and 2. A transverse end wall 18 (Figure 2) closes the front end of the holder 16, and the transverse end wall 18 defines an outer front face 20. The rear end of the holder is externally threaded and is threadedly joined to the lower end portion 17 of the upper tubular member.
The holder 16 is open at the rear end thereof and so that the holder is of cup shaped configuration and defines an internal cavity 22 (Figure 6). Also, the front end wall 18 of the holder includes a cylindrical post 23 which extends rearwardly into the internal cavity 22 and along the longitudinal axis. In addition, a cavity 24 is formed in the front face 20 of the end wall 18 and which extends rearwardly along the longitudinal axis and into a portion of the length of the post 23. The cavity 24 is generally cylindrical and it includes an enlarged or counterbored annular outer end portion 25 for the purposes described below.
An insert assembly 26 is mounted in the cavity and comprises a generally cylindrical emissive insert 28 which is deposed coaxially along the longitudinal axis and which has a circular outer end face 29 lying in the plane of the front face 20 of the holder. The insert 28 also includes a circular inner .- 2022~s2 end face 30 which is disposed in the cavity 24 and which is opposite the outer end face 29. Further, the emissive insert 28 is composed of a metallic material which has a relatively low work function, in a range between about 2.7 to 4.2 ev, and so that it is adapted to readily emit electrons upon an electrical potential being applied thereto. Suitable examples of such materials are hafnium, zirconium, tungsten, and alloys thereof.
A relatively non-emissive sleeve 32 is ' positioned in the cavity 24 coaxially about the emissive insert 28, with the sleeve 32 having a peripheral wall and a closed bottom wall 34 which are metallurgically bonded to the walls of the cavity.
Further, the sleeve 32 includes an annular flange 35 positioned in the counterbored outer end portion 25 of the cavity and so as to define an outer annular surface which lies in the plane of the front face 20 of the holder. Also, the sleeve has a radial thickness of at least about .O1 inches at the front face 20 and along its entire length, and preferably the outer diameter of the annular surface at the front face 20 is at least about twice the diameter of the emissive insert 28. As a specific example, the insert 28 typically has a diameter of about .080 inches and an axial length of about .160 inches, and the annular flange 35 of the sleeve 32 typically has an outer diameter of about .254 inches. The outer diameter of the remainder of the sleeve 32 is typically about .157 inches.
The sleeve is composed of a metallic material having a work function which is greater than that of the material of the holder, and also greater than that of the material of the emissive insert. In this regard, it is preferred that the sleeve be composed of a metallic material having a work function of at least about 4.3 ev. Several metals and alloys are usable for 2022782 .--the non-emissive sleeve of the present invention.
Below is a summary of some relevant properties of several suitable metals:
THERMAL RESISTANCE MELTING WORK
CONDUCTIVITY TO POINT FUNCTION
(BTU-FT.JFTZ-Hr°FZ OXIDATION ~(°F) (evl Silver 242 High 1761 4.5 Gold 172 Very High 1945 4.9 Platinum 42 Very High 3217 5.32 Rhodium 50 High 3560 4.8 Iridium 34 High . 4429 5.4 Palladium 41 Good 2826 4.99 Nickel 53 Good 2647 5.0 The ideal sleeve materials should have high thermal conductivity, high resistance to oxidation, high melting point, high work function, and low cost.
No one material has all of these properties, but the very high thermal conductivity of silver makes it a preferred material. As long as the electrode is well cooled, silver will be at a much lower temperature than the other materials by reason of its high thermal conductivity. Since oxidation and electron emission increase at high temperature, the lower melting point and lower work function of silver become less significant.
In addition to the above listed metals, alloys wherein at least 50% of the composition consists of one or more of the listed metals, are also suitable in fabricating the non-emissive sleeve. Further, the sleeve may be composed of an alloy comprising copper and a second metal which is selected from the listed metals and alloys thereof, and wherein the second metal comprises at least about 10% of the material of the sleeve.
In the illustrated embodiment, the electrode 14 is mounted in a plasma arc torch body 38, which has gas and liquid passageways 40 and 42 respectively. The torch body 38 is surrounded by an outer insulated housing member 44.
_a_ A tube 46 is suspended within the central bore 48 of the electrode 14 for circulating a liquid medium such as water through the electrode structure 14. The tube 46 is of a diameter smaller than the diameter of the bore 48 so as to provide a space 49 for the water to flow upon discharge from the tube 46. The water flows from a source (not shown) through the tube 46, along the post 23, and back through the space 49 to the opening 52 in the torch body 38 and to a drain hose (not shown). The passageway 42 directs the injection water into the nozzle assembly 12 where it is converted into a swirling vortex for surrounding the plasma arc as will be explained in more detail below. The gas passageway 40 directs gas from a suitable source (not shown), through a conventional gas baffle 54 of any suitable high temperature ceramic material into a gas plenum chamber 56 via inlet holes 58. The inlet holes 58 are arranged so as to cause the gas to enter the plenum chamber 56 in a swirling fashion as is well-known. The gas flows out from the plenum chamber 56 through the arc constricting coaxial bores 60 and 62 of the nozzle assembly 12. The electrode 14 upon being connected to the torch body 38 holds in place the ceramic gas baffle 54 and a high temperature plastic insulating member 55. The member 55 electrically insulates the nozzle assembly 12 from the electrode 14.
The nozzle assembly 12 comprises an upper nozzle member 63 and a lower nozzle member 64, with the members 63 and 64 including the first and second bores 60, 62 respectively. Although the upper and lower nozzle members may both be metal, a ceramic material such as alumina is preferred for the lower nozzle member.
The lower nozzle member 64 is separated from the upper nozzle member 63 by a plastic spacer element ' 65 and a water swirl ring 66. The space provided ~ between the upper nozzle member 63 and the lower nozzle 20227 82 --w member 64 forms a water chamber 67. The bore 60 of the upper nozzle member 63 is in axial alignment with the longitudinal axis of the torch electrode 14. Also, the bore 60 is cylindrical, and it has a chamfered upper end adjacent the plenum chamber 56, with a chamfer angle of about 45°.
The lower nozzle member 64 comprises a cylindrical body portion 70 which defines a forward (or lower) end portion and a rearward (or upper) end portion, and with the bore 62 extending coaxially through the body portion. An annular mounting flange 71 is positioned on the rearward end portion, and a frusto-conical surface 72 is formed on the exterior of the forward end portion so as to be coaxial with the second bore 62. The annular flange 71 is supported from below by an inwardly directed flange 73 at the lower end of the cup 74, witty the cup 74 being detachably mounted by interconnecting threads to the outer housing member 44. Also, a gasket 75 is disposed between the two flanges 71 and 73.
The arc constricting bore 62 in the Iower nozzle member 64 is cyl~.ndrical, and it is mairaained in axial alignment with the arc constricting bore 60 in ~:he upper member 63 by a centering sleeve 78 0~: any suitable plastic materi.:xl. °fhe centering sleep°e 78 has a lip at the upper end Thereof which is detach~bly locked into an annular iotcl~a in the upper nozz~~ a member 63. The centering slee ~e 78 exteru.s froarr s~.he upper nozzle i~ bi~;sed engagE vent ag~,ia3sv the ~.~:~~~e.r Member ~i4. The swyrl ring 66 end spacer element u5 a: a assembled prior to insE r°tion of the: aow~,:~ a°~~~t~b ~ r 64 into the sleeve 78. TY.~ water flows from the passageway 42 through ~:,~enings 85 in the sleev~ : 78 to the injection ports 87 of the swirl ring 66, a:~~d which inject the water into the water chamber 67. The ' injection ports 87 are tangentially disposed around the swirl ring 66, to cause the water to form a vortical pattern in the water chamber 67. The water exits the water chamber 67 through the arc constricting bore 62 in the lower nozzle member 64.
A power supply (not shown) is connected to the torch electrode 14 in a series circuit relationship with a metal workpiece which is typically grounded. In operation, the plasma arc is established between the emissive insert of the torch 10 which acts as the cathode terminal for the arc, and the workpiece which is connected to the anode of the power supply, and which is positioned below the lower nozzle member 64.
The plasma arc is started in a conventional manner by momentarily establishing a pilot arc between the electrode 14 and the nozzle assembly 12 which is then transferred to the workpiece through the arc constricting bores 60 and 62 respectively. Each arc constricting bore 60 and 62 contributes to the intensification and collimation of the arc, and the swirling vortex of water envelopes the plasma as it passes through the lower passageway 62.
Figure 2 is a fragmentary view of a second embodiment of a torch in accordance with the present invention. In this embodiment, a nozzle assembly of different design is provided, but the torch is otherwise similar to that shown in Figure 1. More particularly, the nozzle assembly includes an upper nozzle member 90 having a essentially frusto-conical bore 91, and a relatively flat lower nozzle member 92 having a cylindrical bore 93.
Method of Fabrication Figures 3-7 illustrate a preferred method of fabricating the electrode holder of the present invention. As illustrated in Figure 3, a cylindrical blank 94 of copper or copper alloy is provided and which has a front face 95 and an opposite rear face 96.
A counterbored cavity is then formed in the front face, such as by drilling, which forms the above described cavity 22 and annular outer end portion 25.
A second blank 98 is formed, which may for example be composed essentially of silver, and which is configured and sized to substantially fit within the cavity 22. The silver blank 98 may be shaped by machining, but it is preferred to form the blank 98 by a cold heading process similar to that commonly used in the fabrication of nails.
Next, the silver blank 98 is metallurgically bonded into the cavity 22. This process is preferably conducted by first inserting a disc 99 of silver brazing material into the cavity. In one example, the brazing material comprises an alloy composed of 71%
silver, 1/2% nickel, and with the balance composed of copper. .Also, a small amount of flux may be included, so as to remove oxides from the surface of the copper.
After the disc 99 is inserted into the cavity, the silver blank 98 is introduced as illustrated in Figure 4, and the assembly is then heated to a temperature only sufficient to melt the brazing material, which has a relatively low melting temperature as compared to the other components. During the heating process, the silver blank 98 is pressed downwardly into the cavity 22, which causes the melted brazing material to flow upwardly and cover the entirety of the interface between the silver blank 98 and the cavity. Upon cooling, the brazing provides a relatively thin coating which serves to bond the blank 98 in the cavity, with the coating having a thickness on the order of between about .001 to .005 inches.
To complete the fabrication of the holder 16, the silver blank 98 is axially drilled at 100 as illustrated in Figure 6, and a cylindrical emissive insert 28 is then force fitted into the resulting ' opening. The front face of the assembly is then ' preferably finished by machining as indicated in dashed lines in Figure 7, to provide a smooth outer surface which includes a circular outer end face 29 of the .
insert, a surrounding annular ring of the resulting silver sleeve 32, and an outer ring of the metal of the holder.
As a final step, the rear surface 96 of the metallic blank 94 is drilled, to form the blank 94 into an open cup-shaped configuration as illustrated in Figure 6. This drilling operation includes forming an internal open annular ring 1o2 which coaxially surrounds a portion of the metallic blank and thus forms the above described cylindrical post 23. The open annular ring also coaxially surrounds a portion of the axial length of the emissive insert 28 and the silver blank 98. This construction facilitates the removal of heat by the circulating water as described above. The external periphery of the blank 94 may also then be shaped as desired, including the formation of the external threads 104 at the rear end.
Figures 9-12 illustrate other embodiments of electrodes which embody the present invention. More particularly, Figure 9 illustrates an electrode holder 16a wherein the cavity 22a and the non-emissive sleeve 32a which surrounds the insert 28a are of frusto-conical outer configuration. In Figure 10, the holder 16b has a through bore in the lower wall, and the non-emissive insert 32b extends through the bore and is exposed so as to directly contact the cooling water in the inside of the holder. Figure 11 illustrates an elongate solid electrode 16c having a longitudinal bore extending through its entire length, with an elongate insert 28c and surrounding non-emissive sleeve 32c extending the full length of the electrode. The electrode 16d is of similar construction, but includes a frusto-conical cavity, insert 28d, and frusto-conical sleeve 32d at each end.
20227.82 ._ In the drawings and specification, there has been set forth a preferred embodiment of the invention, and although specific terms are employed, they are used in a generic and descriptive sense only and not for purposes of limitation.
A significant problem associated with torches of the described type is the short service life of the electrode, particularly when the torch is used with an oxidizing arc gas, such as oxygen or air. More particularly, the gas tends to rapidly oxidize the copper, and as the copper oxidizes, its work function falls. As a result, the oxidized copper which ' surrounds the insert begins to support the arc in preference to the insert. When this happens, the copper oxide and the supporting copper melt, resulting in the early destruction and failure of the electrode.
It is accordingly an object of the present invention to provide an electrode which is adapted for use in a plasma arc torch of the described type, and which is able to provide a significantly improved service life when the torch is used in an oxidizing atmosphere.
It is also an object of the present invention to pxovide an efficient method of fabricating an electrode having the above characteristics.
Summary of the Invention The above and other objects and advantages of the present invention are achieved in the embodiments illustrated herein by the provision of an electrode which comprises a metallic tubular holder having a front end and a rear end, and a transverse end wall closing the front end. The transverse end wall defines an outer front face, and a cavity is formed in the front face. An insert assembly is mounted in the cavity, and comprises an emissive insert composed of a metallic material which has a relatively low work function so as to be capable of readily emitting ,~ _3_ 20227 82 electrons upon a potential being applied thereto. A
sleeve surrounds the emissive insert so as to separate '. . the insert from contact with the holder. The sleeve has a radial thickness of at least about .01 inches at the front end of the holder, and the sleeve is composed of a metallic material having a work function which is greater than that of the material of the emissive insert.
The emissive insert has an outer end face l0 which lies in the plane of the outer front face of the holder, and the sleeve has an outer annular surface which lies in. the plane of the front face of the holder and surrounds the end face of the insert. Also, the diameter of the outer annular surface of the. sleeve preferably is at least equal to about twice~the longest dimension of said outer end face of the emissive insert.
In the preferred embodiment, the sleeve includes a peripheral surface and a closed bottom wall which are metallurgically bonded to the interior walls of the cavity formed in the outer front face of the . holder. The sleeve thus totally separates the insert from contact with the metal of the holder.
The annular sleeve which surrounds the emissive insert is preferably formed of a metallic material such as silver which has a high resistance to the formation of an oxide. This serves to increase the service life of the electrode, since the silver and any oxide which does form are very poor emitters. As a result, the arc will continue to emit from the emissive insert, rather than.from the copper holder or the sleeve and the result~is an increase in its service life.
B
3a 20 2 27 8 2 In accordance with an aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
a metallic holder having a front end, and a cavity in the front end, and an insert assembly mounted in the cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding the emissive insert so as to separate the emissive insert from contact with the holder, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the emissive insert, and the sleeve being composed of a metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and allows thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
a metallic holder having a front end, and a cavity in the front end, and an insert assembly mounted in the cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding the emissive insert so as to separate the emissive insert from contact with the holder, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the emissive insert, and the sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof, and wherein the second metal ft 3b comprises at least 10% by weight of the alloy of copper and the second metal, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
S In accordance with yet another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing the front end, the transverse end wall having a planar outer front face which is perpendicular to the longitudinal axis, and a cavity formed in the front face and which extends rearwardly along the longitudinal axis, and an insert assembly mounted in the cavity and comprising:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the holder and greater than that of the material of the emissive insert, the metallic sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with another aspect of the present invention is an electrode adapted for supporting an arc in a plasma arc torch and comprises:
3c a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing the front end, the transverse end wall having a planar outer front face which is perpendicular to the longitudinal axis, and a cavity formed in the front face and which extends rearwardly along the longitudinal axis, and an insert assembly mounted in the cavity and comprising:
(a) a generally cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front end and being composed of a metallic material having a work function which is greater than that of the material of the holder and greater than that of the material of the emissive insert, the metallic sleeve being somposed of an alloy which comprises copper and a second metal which is selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and alloys thereof, and wherein the second metal comprises at least 10% by weight of the alloy of copper and the second metal, and whereby the sleeve acts to resist movement of the arc attachment point from the insert to the holder.
In accordance with yet another aspect of the present invention is a plasma torch which comprises:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, the transverse front end wall having a substantially planar outer front face which is perpendicular to the longitudinal axis, a cavity formed in the front face along the longitudinal axis, and an B
3d insert assembly mounted in the cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of the emissive insert, the sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of the metals, the sleeve further having an outer annular surface lying in the plane of the front face of the holder and surrounding the end face of the insert, nozzle means mounted adjacent the transverse front end wall of the electrode and having a bore therethrough which is aligned with the longitudinal axis, means for creating an electrical arc extending from the emissive insert of the electrode through the bore and to a workpiece located adjacent the nozzle means, and means for generating a vortical flow of a gas between the electrode and the nozzle means and so as to create a plasma flow outwardly through the bore and to the workpiece.
In accordance with yet another aspect of the present invention is a plasma torch comprising:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, the transverse front end wall s 3e having a substantially planar outer front face which is perpendicular to the longitudinal axis, a cavity formed in the front face along the longitudinal axis, and an insert assembly mounted in the cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along the longitudinal axis and having an outer end face lying in the plane of the front face of the holder, the emissive insert being composed of a metallic material having a relatively low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in the cavity coaxially about the emissive insert, the sleeve having a radial thickness of at least 0.01 inches at the front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of the emissive insert, the metallic sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof and wherein the second metal comprises at least 10~
by weight of the alloy of copper and the second metal, the sleeve further having an outer annular surface lying in the plane of the front face of the holder and surrounding the end face of the insert, nozzle means mounted adjacent the transverse front end wall of the electrode and having a bore therethrough which is aligned with the longitudinal axis, means for creating an electrical arc extending from the emissive insert of the electrode through the bore and to a workpiece located adjacent the nozzle means, and -- 3f 2422782 means for generating a vortical flow of gas between the electrode and the nozzle means and so as to create a plasma flow outwardly through the bore and to the workpiece.
The present invention also includes a method of fabricating the above described electrode and which comprises the steps of preparing a metallic first blank Wh~cl1 hay a frnr,i- ~~.... ...~~ ~__-_ ~ . _ _ 2o22~.s2 front face of the blank. A second blank is formed which is composed for example essentially of silver and which is configured and sized so as to permit it to be closely received in the cavity. The second blank is then fixedly mounted in the cavity, and an opening is formed in the second blank, such as by drilling, and which is perpendicular to the front face. An emissive insert is then fixedly mounted in the opening of the second blank.
Preferably, the front facelof the metallic blank is then finished to form a substantially planar surface which includes the metallic first blank, the emissive insert, and an annular ring of the second blank which separates the insert from the metallic blank.
Brief Description of the Drawings Some of the objects and advantages of the present invention having been stated, others will appear as the description proceeds, when considered in conjunction with the accompanying drawings, in which Figure 1 is a sectioned side elevation view of a plasma arc torch which embodies the features of the present invention;
Figure 2 is a somewhat enlarged fragmentary sectioned view of the lower portion of a plasma arc torch and illustrating a second embodiment of the nozzle assembly of the torch;
Figures 3-7 are schematic views illustrating the steps of the method of fabricating the electrode in accordance with the present invention;
Figure 8 is an end view of the electrode shown in Figure 7; and Figures 9-12 are sectioned side elevation views of other embodiments of the'electrode of the present invention.
-- 20227-82 w Detailed Description of the Preferred Embodiments Referring initially to the embodiment of Figure 1, a plasma arc torch 10 is illustrated which includes a nozzle assembly 12 and a tubular electrode 14. The electrode 14 is preferably made of copper or a copper alloy, and it is composed of an upper tubular member 15 and a lower, cup-shaped member or holder 16.
More particularly, the upper tubular member 15 is of elongate open tubular construction and it defines the longitudinal axis of the torch. The~member 15 also includes an internally threaded lower end portion 17.
The holder 16 is also of tubular construction, and it includes a lower front end and an upper rear end as seen in Figures 1 and 2. A transverse end wall 18 (Figure 2) closes the front end of the holder 16, and the transverse end wall 18 defines an outer front face 20. The rear end of the holder is externally threaded and is threadedly joined to the lower end portion 17 of the upper tubular member.
The holder 16 is open at the rear end thereof and so that the holder is of cup shaped configuration and defines an internal cavity 22 (Figure 6). Also, the front end wall 18 of the holder includes a cylindrical post 23 which extends rearwardly into the internal cavity 22 and along the longitudinal axis. In addition, a cavity 24 is formed in the front face 20 of the end wall 18 and which extends rearwardly along the longitudinal axis and into a portion of the length of the post 23. The cavity 24 is generally cylindrical and it includes an enlarged or counterbored annular outer end portion 25 for the purposes described below.
An insert assembly 26 is mounted in the cavity and comprises a generally cylindrical emissive insert 28 which is deposed coaxially along the longitudinal axis and which has a circular outer end face 29 lying in the plane of the front face 20 of the holder. The insert 28 also includes a circular inner .- 2022~s2 end face 30 which is disposed in the cavity 24 and which is opposite the outer end face 29. Further, the emissive insert 28 is composed of a metallic material which has a relatively low work function, in a range between about 2.7 to 4.2 ev, and so that it is adapted to readily emit electrons upon an electrical potential being applied thereto. Suitable examples of such materials are hafnium, zirconium, tungsten, and alloys thereof.
A relatively non-emissive sleeve 32 is ' positioned in the cavity 24 coaxially about the emissive insert 28, with the sleeve 32 having a peripheral wall and a closed bottom wall 34 which are metallurgically bonded to the walls of the cavity.
Further, the sleeve 32 includes an annular flange 35 positioned in the counterbored outer end portion 25 of the cavity and so as to define an outer annular surface which lies in the plane of the front face 20 of the holder. Also, the sleeve has a radial thickness of at least about .O1 inches at the front face 20 and along its entire length, and preferably the outer diameter of the annular surface at the front face 20 is at least about twice the diameter of the emissive insert 28. As a specific example, the insert 28 typically has a diameter of about .080 inches and an axial length of about .160 inches, and the annular flange 35 of the sleeve 32 typically has an outer diameter of about .254 inches. The outer diameter of the remainder of the sleeve 32 is typically about .157 inches.
The sleeve is composed of a metallic material having a work function which is greater than that of the material of the holder, and also greater than that of the material of the emissive insert. In this regard, it is preferred that the sleeve be composed of a metallic material having a work function of at least about 4.3 ev. Several metals and alloys are usable for 2022782 .--the non-emissive sleeve of the present invention.
Below is a summary of some relevant properties of several suitable metals:
THERMAL RESISTANCE MELTING WORK
CONDUCTIVITY TO POINT FUNCTION
(BTU-FT.JFTZ-Hr°FZ OXIDATION ~(°F) (evl Silver 242 High 1761 4.5 Gold 172 Very High 1945 4.9 Platinum 42 Very High 3217 5.32 Rhodium 50 High 3560 4.8 Iridium 34 High . 4429 5.4 Palladium 41 Good 2826 4.99 Nickel 53 Good 2647 5.0 The ideal sleeve materials should have high thermal conductivity, high resistance to oxidation, high melting point, high work function, and low cost.
No one material has all of these properties, but the very high thermal conductivity of silver makes it a preferred material. As long as the electrode is well cooled, silver will be at a much lower temperature than the other materials by reason of its high thermal conductivity. Since oxidation and electron emission increase at high temperature, the lower melting point and lower work function of silver become less significant.
In addition to the above listed metals, alloys wherein at least 50% of the composition consists of one or more of the listed metals, are also suitable in fabricating the non-emissive sleeve. Further, the sleeve may be composed of an alloy comprising copper and a second metal which is selected from the listed metals and alloys thereof, and wherein the second metal comprises at least about 10% of the material of the sleeve.
In the illustrated embodiment, the electrode 14 is mounted in a plasma arc torch body 38, which has gas and liquid passageways 40 and 42 respectively. The torch body 38 is surrounded by an outer insulated housing member 44.
_a_ A tube 46 is suspended within the central bore 48 of the electrode 14 for circulating a liquid medium such as water through the electrode structure 14. The tube 46 is of a diameter smaller than the diameter of the bore 48 so as to provide a space 49 for the water to flow upon discharge from the tube 46. The water flows from a source (not shown) through the tube 46, along the post 23, and back through the space 49 to the opening 52 in the torch body 38 and to a drain hose (not shown). The passageway 42 directs the injection water into the nozzle assembly 12 where it is converted into a swirling vortex for surrounding the plasma arc as will be explained in more detail below. The gas passageway 40 directs gas from a suitable source (not shown), through a conventional gas baffle 54 of any suitable high temperature ceramic material into a gas plenum chamber 56 via inlet holes 58. The inlet holes 58 are arranged so as to cause the gas to enter the plenum chamber 56 in a swirling fashion as is well-known. The gas flows out from the plenum chamber 56 through the arc constricting coaxial bores 60 and 62 of the nozzle assembly 12. The electrode 14 upon being connected to the torch body 38 holds in place the ceramic gas baffle 54 and a high temperature plastic insulating member 55. The member 55 electrically insulates the nozzle assembly 12 from the electrode 14.
The nozzle assembly 12 comprises an upper nozzle member 63 and a lower nozzle member 64, with the members 63 and 64 including the first and second bores 60, 62 respectively. Although the upper and lower nozzle members may both be metal, a ceramic material such as alumina is preferred for the lower nozzle member.
The lower nozzle member 64 is separated from the upper nozzle member 63 by a plastic spacer element ' 65 and a water swirl ring 66. The space provided ~ between the upper nozzle member 63 and the lower nozzle 20227 82 --w member 64 forms a water chamber 67. The bore 60 of the upper nozzle member 63 is in axial alignment with the longitudinal axis of the torch electrode 14. Also, the bore 60 is cylindrical, and it has a chamfered upper end adjacent the plenum chamber 56, with a chamfer angle of about 45°.
The lower nozzle member 64 comprises a cylindrical body portion 70 which defines a forward (or lower) end portion and a rearward (or upper) end portion, and with the bore 62 extending coaxially through the body portion. An annular mounting flange 71 is positioned on the rearward end portion, and a frusto-conical surface 72 is formed on the exterior of the forward end portion so as to be coaxial with the second bore 62. The annular flange 71 is supported from below by an inwardly directed flange 73 at the lower end of the cup 74, witty the cup 74 being detachably mounted by interconnecting threads to the outer housing member 44. Also, a gasket 75 is disposed between the two flanges 71 and 73.
The arc constricting bore 62 in the Iower nozzle member 64 is cyl~.ndrical, and it is mairaained in axial alignment with the arc constricting bore 60 in ~:he upper member 63 by a centering sleeve 78 0~: any suitable plastic materi.:xl. °fhe centering sleep°e 78 has a lip at the upper end Thereof which is detach~bly locked into an annular iotcl~a in the upper nozz~~ a member 63. The centering slee ~e 78 exteru.s froarr s~.he upper nozzle i~ bi~;sed engagE vent ag~,ia3sv the ~.~:~~~e.r Member ~i4. The swyrl ring 66 end spacer element u5 a: a assembled prior to insE r°tion of the: aow~,:~ a°~~~t~b ~ r 64 into the sleeve 78. TY.~ water flows from the passageway 42 through ~:,~enings 85 in the sleev~ : 78 to the injection ports 87 of the swirl ring 66, a:~~d which inject the water into the water chamber 67. The ' injection ports 87 are tangentially disposed around the swirl ring 66, to cause the water to form a vortical pattern in the water chamber 67. The water exits the water chamber 67 through the arc constricting bore 62 in the lower nozzle member 64.
A power supply (not shown) is connected to the torch electrode 14 in a series circuit relationship with a metal workpiece which is typically grounded. In operation, the plasma arc is established between the emissive insert of the torch 10 which acts as the cathode terminal for the arc, and the workpiece which is connected to the anode of the power supply, and which is positioned below the lower nozzle member 64.
The plasma arc is started in a conventional manner by momentarily establishing a pilot arc between the electrode 14 and the nozzle assembly 12 which is then transferred to the workpiece through the arc constricting bores 60 and 62 respectively. Each arc constricting bore 60 and 62 contributes to the intensification and collimation of the arc, and the swirling vortex of water envelopes the plasma as it passes through the lower passageway 62.
Figure 2 is a fragmentary view of a second embodiment of a torch in accordance with the present invention. In this embodiment, a nozzle assembly of different design is provided, but the torch is otherwise similar to that shown in Figure 1. More particularly, the nozzle assembly includes an upper nozzle member 90 having a essentially frusto-conical bore 91, and a relatively flat lower nozzle member 92 having a cylindrical bore 93.
Method of Fabrication Figures 3-7 illustrate a preferred method of fabricating the electrode holder of the present invention. As illustrated in Figure 3, a cylindrical blank 94 of copper or copper alloy is provided and which has a front face 95 and an opposite rear face 96.
A counterbored cavity is then formed in the front face, such as by drilling, which forms the above described cavity 22 and annular outer end portion 25.
A second blank 98 is formed, which may for example be composed essentially of silver, and which is configured and sized to substantially fit within the cavity 22. The silver blank 98 may be shaped by machining, but it is preferred to form the blank 98 by a cold heading process similar to that commonly used in the fabrication of nails.
Next, the silver blank 98 is metallurgically bonded into the cavity 22. This process is preferably conducted by first inserting a disc 99 of silver brazing material into the cavity. In one example, the brazing material comprises an alloy composed of 71%
silver, 1/2% nickel, and with the balance composed of copper. .Also, a small amount of flux may be included, so as to remove oxides from the surface of the copper.
After the disc 99 is inserted into the cavity, the silver blank 98 is introduced as illustrated in Figure 4, and the assembly is then heated to a temperature only sufficient to melt the brazing material, which has a relatively low melting temperature as compared to the other components. During the heating process, the silver blank 98 is pressed downwardly into the cavity 22, which causes the melted brazing material to flow upwardly and cover the entirety of the interface between the silver blank 98 and the cavity. Upon cooling, the brazing provides a relatively thin coating which serves to bond the blank 98 in the cavity, with the coating having a thickness on the order of between about .001 to .005 inches.
To complete the fabrication of the holder 16, the silver blank 98 is axially drilled at 100 as illustrated in Figure 6, and a cylindrical emissive insert 28 is then force fitted into the resulting ' opening. The front face of the assembly is then ' preferably finished by machining as indicated in dashed lines in Figure 7, to provide a smooth outer surface which includes a circular outer end face 29 of the .
insert, a surrounding annular ring of the resulting silver sleeve 32, and an outer ring of the metal of the holder.
As a final step, the rear surface 96 of the metallic blank 94 is drilled, to form the blank 94 into an open cup-shaped configuration as illustrated in Figure 6. This drilling operation includes forming an internal open annular ring 1o2 which coaxially surrounds a portion of the metallic blank and thus forms the above described cylindrical post 23. The open annular ring also coaxially surrounds a portion of the axial length of the emissive insert 28 and the silver blank 98. This construction facilitates the removal of heat by the circulating water as described above. The external periphery of the blank 94 may also then be shaped as desired, including the formation of the external threads 104 at the rear end.
Figures 9-12 illustrate other embodiments of electrodes which embody the present invention. More particularly, Figure 9 illustrates an electrode holder 16a wherein the cavity 22a and the non-emissive sleeve 32a which surrounds the insert 28a are of frusto-conical outer configuration. In Figure 10, the holder 16b has a through bore in the lower wall, and the non-emissive insert 32b extends through the bore and is exposed so as to directly contact the cooling water in the inside of the holder. Figure 11 illustrates an elongate solid electrode 16c having a longitudinal bore extending through its entire length, with an elongate insert 28c and surrounding non-emissive sleeve 32c extending the full length of the electrode. The electrode 16d is of similar construction, but includes a frusto-conical cavity, insert 28d, and frusto-conical sleeve 32d at each end.
20227.82 ._ In the drawings and specification, there has been set forth a preferred embodiment of the invention, and although specific terms are employed, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (18)
1. An electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic holder having a front end, and a cavity in said front end, and an insert assembly mounted in said cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding said emissive insert so as to separate said emissive insert from contact with said holder, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said emissive insert, and said sleeve being composed of a metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and allows thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
a metallic holder having a front end, and a cavity in said front end, and an insert assembly mounted in said cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding said emissive insert so as to separate said emissive insert from contact with said holder, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said emissive insert, and said sleeve being composed of a metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and allows thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
2. An electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic holder having a front end, and a cavity in said front end, and an insert assembly mounted in said cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding said emissive insert so as to separate said emissive insert from contact with said holder, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said emissive insert, and said sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof, and wherein said second metal comprises at least 10% by weight of the alloy of copper and the second metal, and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
a metallic holder having a front end, and a cavity in said front end, and an insert assembly mounted in said cavity and comprising an emissive insert composed of a metallic material having a low work function, and a sleeve surrounding said emissive insert so as to separate said emissive insert from contact with said holder, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said emissive insert, and said sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof, and wherein said second metal comprises at least 10% by weight of the alloy of copper and the second metal, and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
3. The electrode as defined in claim 1 or 2 wherein said holder comprises a metal selected from the group consisting of copper and copper alloys.
4. The electrode as defined in claim 1 or 2 wherein said emissive insert comprises a metal selected from the group consisting of hafnium, zirconium, tungsten, and alloys thereof.
5. The electrode as defined in claim 1 or 2 wherein said holder is tubular and has a transverse end wall closing said front end, with said emissive insert defining an outer front face, and wherein said emissive insert has an outer end face which lies in the plane of said front face of said holder, and said sleeve has an outer annular surface which lies in the plane of said front face of said holder and surrounds said end face of said insert.
6. The electrode as defined in claim 5 wherein the diameter of said outer annular surface of said sleeve is at least equal to twice the longest dimension of said outer end face of said emissive insert.
7. The electrode as defined in claim 1 or 2 wherein the material of said sleeve has a work function of at least 4.3 ev.
8. An electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing said front end, said transverse end wall having a planar outer front face which is perpendicular to said longitudinal axis, and a cavity formed in said front face and which extends rearwardly along said longitudinal axis, and an insert assembly mounted in said cavity and comprising:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said holder and greater than that of the material of said emissive insert, said metallic sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals, and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing said front end, said transverse end wall having a planar outer front face which is perpendicular to said longitudinal axis, and a cavity formed in said front face and which extends rearwardly along said longitudinal axis, and an insert assembly mounted in said cavity and comprising:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said holder and greater than that of the material of said emissive insert, said metallic sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals, and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
9. An electrode adapted for supporting an arc in a plasma arc torch and comprising:
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing said front end, said transverse end wall having a planar outer front face which is perpendicular to said longitudinal axis, and a cavity formed in said front face and which extends rearwardly along said longitudinal axis, and an insert assembly mounted in said cavity and comprising:
(a) a generally cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said holder and greater than that of the material of said emissive insert, said metallic sleeve being somposed of an alloy which comprises copper and a second metal which is selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and alloys thereof, and wherein said second metal comprises at least
a metallic tubular holder defining a longitudinal axis and having a front end and a rear end, and a transverse end wall closing said front end, said transverse end wall having a planar outer front face which is perpendicular to said longitudinal axis, and a cavity formed in said front face and which extends rearwardly along said longitudinal axis, and an insert assembly mounted in said cavity and comprising:
(a) a generally cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front end and being composed of a metallic material having a work function which is greater than that of the material of said holder and greater than that of the material of said emissive insert, said metallic sleeve being somposed of an alloy which comprises copper and a second metal which is selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel, and alloys thereof, and wherein said second metal comprises at least
10% by weight of the alloy of copper and the second metal, and whereby said sleeve acts to resist movement of the arc attachment point from said insert to said holder.
10. The electrode as defined in claim 8 or 9 wherein said sleeve has a peripheral surface which is bonded to the walls of said cavity and an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert and having an outer diameter which is at least twice the diameter of said emissive insert.
10. The electrode as defined in claim 8 or 9 wherein said sleeve has a peripheral surface which is bonded to the walls of said cavity and an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert and having an outer diameter which is at least twice the diameter of said emissive insert.
11. The electrode as defined in claim 10 wherein said emissive insert includes an inner end surface in said cavity and which is opposite said outer end surface, and wherein said sleeve has a closed bottom wall which is bonded to an adjacent wall of said cavity and which overlies said inner end surface of said insert and so as to separate said inner end surface from the adjacent wall of said cavity.
12. The electrode as defined in claim 11 wherein said sleeve has an annular flange positioned so as to define said outer annular surface, and with said flange having an outer diameter substantially greater than the outer diameter of the remainder of said sleeve.
13. The electrode as defined in claim 12 wherein said tubular holder is open at said rear end thereof, and so that said holder is of cup shaped configuration and defines an internal cavity.
14. The electrode as defined in claim 13 wherein said transverse end wall of said holder includes a cylindrical post which extends rearwardly into said internal cavity along said longitudinal axis, and with a portion of the longitudinal axis, and with a portion of the longitudinal length of said cavity, and said emissive insert, and said sleeve extending into said post.
15. The electrode as defined in claim 8 or 9 wherein said holder is composed of copper, and the material of said sleeve has a work function of at least 4.3 ev.
16. A plasma torch comprising:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, said transverse front end wall having a substantially planar outer front face which is perpendicular to said longitudinal axis, a cavity formed in said front face along said longitudinal axis, and an insert assembly mounted in said cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of said emissive insert, said sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals, said sleeve further having an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert, nozzle means mounted adjacent said transverse front end wall of said electrode and having a bore therethrough which is aligned with said longitudinal axis, means for creating an electrical arc extending from said emissive insert of said electrode through said bore and to a workpiece located adjacent said nozzle means, and means for generating a vortical flow of a gas between said electrode and said nozzle means and so as to create a plasma flow outwardly through said bore and to said workpiece.
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, said transverse front end wall having a substantially planar outer front face which is perpendicular to said longitudinal axis, a cavity formed in said front face along said longitudinal axis, and an insert assembly mounted in said cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of said emissive insert, said sleeve being selected form the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof wherein at least 50% by weight of the composition of the alloy consists of one or more of said metals, said sleeve further having an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert, nozzle means mounted adjacent said transverse front end wall of said electrode and having a bore therethrough which is aligned with said longitudinal axis, means for creating an electrical arc extending from said emissive insert of said electrode through said bore and to a workpiece located adjacent said nozzle means, and means for generating a vortical flow of a gas between said electrode and said nozzle means and so as to create a plasma flow outwardly through said bore and to said workpiece.
17. A plasma torch comprising:
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, said transverse front end wall having a substantially planar outer front face which is perpendicular to said longitudinal axis, a cavity formed in said front face along said longitudinal axis, and an insert assembly mounted in said cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a relatively low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of said emissive insert, said metallic sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof and wherein said second metal comprises at least 10% by weight of the alloy of copper and the second metal, said sleeve further having an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert, nozzle means mounted adjacent said transverse front end wall of said electrode and having a bore therethrough which is aligned with said longitudinal axis, means for creating an electrical arc extending from said emissive insert of said electrode through said bore and to a workpiece located adjacent said nozzle means, and means for generating a vortical flow of gas between said electrode and said nozzle means and so as to create a plasma flow outwardly through said bore and to said workpiece.
an electrode including a metallic elongate tubular holder defining a longitudinal axis and having a transverse front end wall, said transverse front end wall having a substantially planar outer front face which is perpendicular to said longitudinal axis, a cavity formed in said front face along said longitudinal axis, and an insert assembly mounted in said cavity and which comprises:
(a) a cylindrical emissive insert disposed coaxially along said longitudinal axis and having an outer end face lying in the plane of said front face of said holder, said emissive insert being composed of a metallic material having a relatively low work function so as to be adapted to readily emit electrons upon an electric potential being applied thereto, and (b) a sleeve positioned in said cavity coaxially about said emissive insert, said sleeve having a radial thickness of at least 0.01 inches at said front face and being composed of a metallic material having a work function of at least 4.3 ev and which is greater than that of the material of said emissive insert, said metallic sleeve being composed of an alloy which comprises copper and a second metal which is selected from the group consisting of silver, gold, platinum, rhodium, iridium, palladium, nickel and alloys thereof and wherein said second metal comprises at least 10% by weight of the alloy of copper and the second metal, said sleeve further having an outer annular surface lying in the plane of said front face of said holder and surrounding said end face of said insert, nozzle means mounted adjacent said transverse front end wall of said electrode and having a bore therethrough which is aligned with said longitudinal axis, means for creating an electrical arc extending from said emissive insert of said electrode through said bore and to a workpiece located adjacent said nozzle means, and means for generating a vortical flow of gas between said electrode and said nozzle means and so as to create a plasma flow outwardly through said bore and to said workpiece.
18. The plasma torch as defined in claim 16 and 17 wherein said nozzle means comprises an upper nozzle member mounted adjacent said transverse front end wall of said electrode and having a first bore therethrough and which is aligned with said longitudinal axis, and a lower nozzle member mounted adjacent said upper nozzle member on the side thereof opposite said electrode and having a second bore therethrough which is aligned with said longitudinal axis, and said torch further comprises means for introducing a jet of liquid between said upper and lower nozzle members and so as to envelope said plasma as it passes through said second bore.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/466,205 US5023425A (en) | 1990-01-17 | 1990-01-17 | Electrode for plasma arc torch and method of fabricating same |
| US466,205 | 1990-01-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2022782A1 CA2022782A1 (en) | 1991-07-18 |
| CA2022782C true CA2022782C (en) | 2000-02-08 |
Family
ID=23850909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002022782A Expired - Lifetime CA2022782C (en) | 1990-01-17 | 1990-08-07 | Electrode for plasma arc torch |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5023425A (en) |
| EP (1) | EP0437915B2 (en) |
| JP (1) | JPH03225727A (en) |
| KR (1) | KR930005883B1 (en) |
| CN (1) | CN1028501C (en) |
| AT (1) | ATE114397T1 (en) |
| AU (1) | AU622385B2 (en) |
| BR (1) | BR9004384A (en) |
| CA (1) | CA2022782C (en) |
| DE (2) | DE69014289T3 (en) |
| FI (1) | FI903867A (en) |
| HU (1) | HUT56988A (en) |
| IE (1) | IE902775A1 (en) |
| IL (1) | IL95273A (en) |
| NO (1) | NO903473L (en) |
| PH (1) | PH26870A (en) |
| PL (1) | PL287337A1 (en) |
| RU (1) | RU2028899C1 (en) |
| ZA (1) | ZA906260B (en) |
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| EP3981544A1 (en) * | 2020-10-08 | 2022-04-13 | Linde GmbH | Plus pole electrode |
| RU204342U1 (en) * | 2020-10-12 | 2021-05-21 | Би энд Бартони, спол. с р.о. | ELECTRODE FOR PLASMA ARC BURNER |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL290760A (en) * | 1962-03-30 | |||
| US3597649A (en) * | 1968-02-15 | 1971-08-03 | David Grigorievich Bykhovsky | Device for plasma-arc treatment of materials |
| US3546422A (en) * | 1968-02-15 | 1970-12-08 | David Grigorievich Bykhovsky | Device for plasma arc treatment of materials |
| US3944778A (en) * | 1974-05-14 | 1976-03-16 | David Grigorievich Bykhovsky | Electrode assembly of plasmatron |
| US3930139A (en) * | 1974-05-28 | 1975-12-30 | David Grigorievich Bykhovsky | Nonconsumable electrode for oxygen arc working |
| US4133987A (en) * | 1977-12-07 | 1979-01-09 | Institut Elektrosvarki Imeni E.O. Patona Adakemii Nauk | Electrode assembly for plasma arc torches |
| SE426215B (en) * | 1978-05-11 | 1982-12-20 | Vni Pk I Tech Inst Elektrosvar | NON-MELTING ELECTRODES FOR PLASMA BAKING WELDING AND PROCEDURES FOR PRODUCING THEREOF |
| US4311897A (en) * | 1979-08-28 | 1982-01-19 | Union Carbide Corporation | Plasma arc torch and nozzle assembly |
| SE452862B (en) * | 1985-06-05 | 1987-12-21 | Aga Ab | LIGHT BAGS LEAD |
-
1990
- 1990-01-17 US US07/466,205 patent/US5023425A/en not_active Expired - Lifetime
- 1990-08-01 IE IE277590A patent/IE902775A1/en unknown
- 1990-08-02 IL IL9527390A patent/IL95273A/en active IP Right Grant
- 1990-08-03 FI FI903867A patent/FI903867A/en not_active Application Discontinuation
- 1990-08-06 PH PH40970A patent/PH26870A/en unknown
- 1990-08-07 NO NO90903473A patent/NO903473L/en unknown
- 1990-08-07 CA CA002022782A patent/CA2022782C/en not_active Expired - Lifetime
- 1990-08-07 JP JP2207710A patent/JPH03225727A/en active Granted
- 1990-08-08 ZA ZA906260A patent/ZA906260B/en unknown
- 1990-08-09 AT AT90308761T patent/ATE114397T1/en not_active IP Right Cessation
- 1990-08-09 EP EP90308761A patent/EP0437915B2/en not_active Expired - Lifetime
- 1990-08-09 DE DE69014289T patent/DE69014289T3/en not_active Expired - Fee Related
- 1990-08-09 DE DE199090308761T patent/DE437915T1/en active Pending
- 1990-08-09 AU AU60808/90A patent/AU622385B2/en not_active Ceased
- 1990-08-10 HU HU904975A patent/HUT56988A/en unknown
- 1990-08-22 CN CN90107140A patent/CN1028501C/en not_active Expired - Fee Related
- 1990-09-04 BR BR909004384A patent/BR9004384A/en not_active IP Right Cessation
- 1990-10-15 PL PL28733790A patent/PL287337A1/en unknown
- 1990-11-12 RU SU904831529A patent/RU2028899C1/en active
- 1990-12-06 KR KR1019900020048A patent/KR930005883B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1053380A (en) | 1991-07-31 |
| EP0437915A3 (en) | 1991-12-18 |
| ZA906260B (en) | 1991-05-29 |
| RU2028899C1 (en) | 1995-02-20 |
| EP0437915B1 (en) | 1994-11-23 |
| JPH03225727A (en) | 1991-10-04 |
| US5023425A (en) | 1991-06-11 |
| ATE114397T1 (en) | 1994-12-15 |
| FI903867A0 (en) | 1990-08-03 |
| BR9004384A (en) | 1991-09-03 |
| JPH0570250B2 (en) | 1993-10-04 |
| KR930005883B1 (en) | 1993-06-25 |
| EP0437915A2 (en) | 1991-07-24 |
| PH26870A (en) | 1992-11-16 |
| CA2022782A1 (en) | 1991-07-18 |
| DE69014289T2 (en) | 1995-06-01 |
| CN1028501C (en) | 1995-05-24 |
| IL95273A (en) | 1994-04-12 |
| IL95273A0 (en) | 1991-06-30 |
| DE69014289D1 (en) | 1995-01-05 |
| DE437915T1 (en) | 1992-01-16 |
| HUT56988A (en) | 1991-10-28 |
| NO903473L (en) | 1991-07-18 |
| PL287337A1 (en) | 1991-07-29 |
| NO903473D0 (en) | 1990-08-07 |
| HU904975D0 (en) | 1991-01-28 |
| FI903867A (en) | 1991-07-18 |
| AU622385B2 (en) | 1992-04-02 |
| AU6080890A (en) | 1991-07-18 |
| EP0437915B2 (en) | 1999-12-01 |
| DE69014289T3 (en) | 2000-07-13 |
| IE902775A1 (en) | 1991-07-17 |
| KR910015202A (en) | 1991-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed | ||
| MKEC | Expiry (correction) |
Effective date: 20121202 |