CA2033269C

CA2033269C - Corrosion inhibiting emi/rfi shielding coating and method of its use

Info

Publication number: CA2033269C
Application number: CA002033269A
Authority: CA
Inventors: Noredin H. Morgan
Original assignee: Parker Hannifin Corp
Current assignee: Parker Hannifin Corp
Priority date: 1989-12-28
Filing date: 1990-12-27
Publication date: 2003-03-18
Anticipated expiration: 2010-12-27
Also published as: EP0437979B1; EP0437979A3; NO905624L; CA2033269A1; DE69026700T2; EP0437979A2; PT96378A; IL96804A; JPH04132785A; US5284888A; DE69026700D1; ZA9010415B; NO905624D0; IL96804A0; US5061566A

Abstract

A corrosion inhibiting, EMI/RFI shielding composition is provided comprising a polyurethane resin which comprises a hydro~y or amine functional first polymer and an isocyanate terminated second polymer, a stabilized conductive filler, and an azole. In one embodiment of the invention a coating is provided comprising a polyurethane which comprises a fluoroolefin vinyl ether and an isocyanate terminated castor oil prepolymer, a stabilized copper powder, and a triazole selected from the group consisting of alkyl substituted aromatic triazoles and other azoles. The invention further provides a method of coating a substrate with a coating of the invention in order to provide EMI/RFI shielding and prevent corrosion, and a substrate thus coated.

Description

CORROSION INHIBITING EMI/RFI S)~:IELDING COATING
AND METHOD OF TTS ~JSE
BACKGROUND OF THE INVENTION
The present invention relates to a corrosion inhibiting conductive coating which provides I~MI/RFI
shielding and prevents corrosion when applied to conductive substrates.
When dissimilar metal and/or conducive composite 1C) substrates are joined together in the presence of an electrolyte, a galvanic potential is established at the interface between the substrates. If this assembly is exposed to the environment, particularly under severe conditions such as salt fog or salt fog containing a high I_'i concentration of 50~, corrosion of l~he least noble of the substrates will occur, causing Lailure of the assembly.
Mechanisms other than the establishment of galvanic potentials, e.g. crevice corrosion, may also clause corrosion and eventual failure of the part. In these cases one or all-20 of the exposed materials in the assembly may corrode.
Thus, it has long been an object, especially among manufacturers of aircraft mainframes, ~>hips, telecommunication equipment and other such equipment which is to be exposed to the environment, to prevent corrosion at.
25 these interfaces.
Further, it is oaten necessary to provide EMI/RFI
shielding to the equipment described above, as aircraft, ships, etc, frequently utilize electronic systems which either radiate or are susceptible to e7_ectrorr~agnetic or 30 radio frequency interference (EMI/R.FI).

Various methods have been attempted to achieve one or both of these objectives. Conventi~:,nal sh=fielding gaskets have been used in these applicar=ions t:J provide EMI/RFI
shielding. These gaskets generally provide satisfactory '. shielding, but do not address the problem of corrosion. In fact, when the metal filler or mesh in the shielding gasket is different from either of the substrates a galvanic potential is established across all three elements, often causing the gasket itself, and t~ventually the entire assembly, to corrode.
Coatings comprising polymers and ni~Jkel filler have been applied to the substrates in an attempt to improve shielding and reduce corrosion. This approach is capable of providing acceptable shielding effectiveness of the assembly, but under conditions in which the coating remains conductive it has little or no effect on corrosion protection.
Some success in preventing corrosion has been obtained by sealing the interfa~~e with polyth.ioether or 2C) polysulfide sealants containing chromate corrosion inhibitors. However, it is difficult to handle and to dilute these systems enough to use them as sp.rayable coatings, which are generally preferred for t,~eir ease of application. Further, they do ,lot exhibit good thermal stability and become brittle over time.
Thus it is desired to provide a coating which will.
resist the corrosion of conductive substrates, even in several environments, while mai~Ztaining good ~MI/RFI
shielding. It is further desired to provide sucr_ a coating without the use of hazardous chromates.

SUMMARY OF THE INVENTION
The present invent; ion is directed to a corrosion inhibiting EMI/RFI shielding coating c.~mposit_ion. More particularly, the invention is <directed to a c=orrosion inhibiting conductive coating comprising a polyurethane resin which comprises a first polymer selected from the group consisting of isocyanate resins and isocyanate terminated prepolymers, and a~second polymer selected from the group consisting of polymers having an amine functionality, polymers having a hydroxyl functionality, polymers having both amine and hydroxyl functionalities, and mixtures thereof; a stabilized conductive filler; and an azole.
In one embodiment of the invention the corrosion inhibiting coating comprises a polyurethane resin comprising a first polymer selected from the group consisting of isoayanat~ resins and isocyanate terminated castor oil prepolymers, and a second polymer selected from the group coaaiating of polyether polyols, polythiols cad polyamines;
a stabiliz~d copper powder; and a triazole selected from the group consisting of alkyl substituted aromatic triazoles cad other triazoles.
In a preferred embodiment the coating comprises from about 10 to 50 weight percent polyurethane, from about 30 to 80 weight percent stabilized conductive filler, and from about 0.1 to 3 weight percent aromatic triazole, based on the total solids in the coating composition. It is also preferred that the weight ratio of the first to second polymer be from about 1:2 to 1:6, that the second polymer be fluorinated, and that the stabilized conductive filler be a stabilized copper powder.
In its method aspects, the present invention is directed to a method of coating conductive substrates to prevent corrosion when these substrates are exposed to harsh environments, e.g. in naval and aerospace applications, while maintaining good EMI/RFI shielding. This method comprises the steps of a) providing a corrosion inhibiting conductive coating comprising a polyurethane resin which comprises a first polymer selected from the group consisting of iaocyanato rasias and isoayanate terminated prepolymera, and a second polymer selected from the group consisting of polymers having an amine functionality and polymers having a hydroxyl functionality; a stabilized conductive filler; and an aromatic triazole: and b) applying the corrosion inhibiting coating to a conductive substrate. The method may further comprise the .
additional step of curing the coating. The coating may be cured for at least 15 minutes, and preferably 30 minutes at 250°F, or at least 5 days, and preferably 7 days at ambient temperature.
The present invention further provides a substrate coated with a coating according to the invention. The coated substrate may be bonded to a second substrate or a gasket to form an assembled part and ezposed to severe environments such as salt fog with minimal corrosion of the part.
DETAILED DESCRIPTION OF THE INVENTION
The present invention relates to a corrosion inhibiting coating comprising a polyurethane resin, a stabilized conductive filler, and ari aromatic triazole. it has been found that this combination unexpectedly provides excellent corrosion resistance to a variety of conductive substrates, even under severe conditions such as long term exposure to salt fog, salt fog containing a high concentration of S02, etc.
The coating of the invention is generally provided as a two component system, with the hydrozy or amine functional second polymer (part A), and the isocyanate terminated first polymer (part b) being stored separately until the time of i1 i ' !I I
use. generally, the stabilized conductive filler, aromatic triazale, and any other optional ingredients are incorporated in part A. Part A and part B, when stored separately, are I I
generally shelf stable far at least 6 months at ambient temperature. When the two components are mixed, the mixture !I
I will begin to increase in viscosity as it crosslinks until it eventually gels. The time during which the mixture is of a ji workable viscosity, i.e. the pot life of the coating, will vary depending upon the hydroxyl number of the second polymer, the batch size, the solids level of the composition, and any I
optional accelerators, diluents or inhibitors present in the i coating composition. The pot life will generally be from Ii about 15 minutes to about 1 hour. After the coating is Ii applied to a substrate, chain extension and/or cross-linking t1 will continue, but at a slower rate since the coating is now present in a thin film and the exothermic cure reaction is ,I
unable to generate as m~.zch heat as when the mixture was present in a large mass. Thus the cure tame of an t n unaccelerated coating composition in a thin film will generally be at least 5 days, and usually 7 days at ambient I
temperature. If a faster cure is desired the coating may be I
heat cured. In this case, it is preferred that the coating be cured far at least Z5 minutes. and preferably 30 minutes at about 250aF. It is particularly preferred that the coating be i' allowed to dry far approximately 30 minutes at ambient temperature before heat curing. The rate of cure rnay also be accelerated by the addition of optional accelerators such as metallic catalysts, e.g. dibutyltin dilaurate, although the addition of an accelerator will also tend to shorten the pot life of the rnixture.
Many combinations of hydroxy or amine functional and i isocyanate-functional polymers may be successfully used in the . I

i i present invention to form the reacted polyurethane. It is i1 generally preferred that the polyurethane be hydrophobic; it ~ is particularly preferred that the hydroxy or amine functional second polymer be fluorinated. It is also preferred that the second polymer be selected from the group consisting of 'I
;I polyether polyols and polyether amines. The preferred molecular weight and hydroxyl number of the second polymer will vary based on the requirements of the given application;
;.
~i the higher the hydroxyl number, the better the adhesion and .. chemical resistance of the coating, but the shorter its pot life. Additionally, the higher the molecular weight of the second polymer, the better the chemical resistance of the coating. Far most applications, a molecular weight of from 2000 to 150,000 and hydroxyl number of from 25 to 100 are preferred. It is also generally preferred that the hydroxyl or amine functionality be greater than 1. Particularly preferred polymers are fluoroolefin vinyl ethers, such as those commercially available from I.C.I. Americas, Inc. under the tradename LUMIFLONe. These polymers generally have a molecular weight of from about 4000 to 150,000 and a fluorine content of from 25% to 3U%. A particularly preferred i1 palyether amine is polytetramethyleneoxide-di-p-arninobenzoate, '' commercially available from Polaroid Corp. under the tradename POLYAMINFO 1000. Polythials which may be used in the invention include polyether/thioether polyols.
Most isacyanate resins and isocyanate terminated prepolymers may be used in the invention. Methylene diisocyanate and reaction products thereof with castor oil are generally preferred. Particularly preferred is a methylene diisocyanate terminated castor oil prepolymer which is commexcAally available from Aceto Chemical under t~~e cradename URIC 2023. This polymer is preferred because the castor oil is a high purity grade and provides an excellent coating.
The term 'stabilized conductive filler" as used herein refers to any electrically conductive filler which has been treated such that the surfaces of the filler particles are protected from oxidation and the filler remains electrically conductive after such treatment. These stabilized fillers, when used in the coating compositions of the invention, have been found to greatly increase the resistance of the coated substrates to corrosion, especially during long term exposure to salt fog or heat, while maintaining sufficient electrical conductivity to provide EMI/RFI shielding. Such stabilized fillers may be obtained by purchasing them in prestabilized form from a manufacturer of stabilized fillers, or by purchasing unstabilized conductive fillers and treating them to prevent surface oxidation of the particles. A preferred prestablized filler for use in the invention is a stabilized copper powder, which is commercially available in prestablized form from Fujikura Kasei of Japan under the tradename Fujikura~ CP-10.
This prestabilized filler is a silver plated copper powder produced by a substitution plating process. This process is described in detail in Japanese Patent No. 53/134759, and comprises coating copper powder with silver metal using a silver complex salt solution comprising from 3 to 30 weight percent silver nitrate, from 15 to 70 weight percent ammonium bicarbonate, and from 23 to 75 weight percent trisodium ethylenediaminetetraacetic acid. The ratio of silver to copper in the final product is generally from 5:95 to 50:50, and preferably from 10:90 to 30:70. Other prestabilized fillers may also be used in the invention. If it is desired by the user to stabilize the filler this may be accomplished 7a by coating~the surface of the filler particles with a material which will.inhibit oxidation of the particle, generally a noble metal such as gold or silver or a fatty acid. The filler may be coated by mixing or milling the filler with a silver salt and/or a fatty acid, preferably for a period of time adequate to coat substantially all of the filler particles. A method of treating fillers with fatty acids is disclosed in V.S. Patent No. 4,781,980. Fillers ~rhicls may be stabilized iaelnde, but are not limited to copper, nickel, silver plated metals, nickel-graphite fibers and combinations thereof.
Aromatic triazoles are known in the art as organic corrosion inhibitors, and are believed to directly bond to metal surfaces to produce inhibiting complexes. However, when used in conventional conductive coating systems they do not provide adequate corrosion protection in long term salt fog exposure. However, for reasons unknown to the inventor, in the coating of the invention, in combination with a polyurethane and a stabilized metal filler, the aromatic triazole provides excellent corrosion resistance during prolonged salt fog exposures of greater than 1000 hours on A1 3000* series alloys. In the coating of the invention, any azole may be used, preferably an aromatic triazole, an imidazole, or a thiazole, and most preferbly an alkyl substituted aromatic triazole, e.g. tolytriazole and benzotriazole. These chemicals are readily available commercially. A particularly preferred triazole is a proprietary material available from PMC Specialties Group under the.tradename COBRATECO 205. Generally triazoles are acidic, and thus at higher revels the triazole may alter the cure characteristics of the composition, slightly reducing the *Trade-mark _g_ n i chemical resistance of the cured coating. f'or optimal cure i " characteristics, in applications where high chemical I
jI resistance is required, a neutral or alkaline azole, such as 2,5-(aminopentyl)-benzimi.dazole (commercially available from Mobay Chemical, under the tradename Preventol ~'rial Products C.T-3) may be used instead of the triazole component of the .;
coating composition.
Additionally, the coating of the invention may further optionally comprise a chromate salt. This additional I
additive is preferred in applications where the coating is to be applied to a metal and exposed to mechanical abuse which may cause scratching of the coating. It has been found that the addition of chromates to the coating enables the cured coating to "self-heal" when it is scratched, thereby improving the integrity of the coating and the protection of the underlying metal surface. This property is generally not required when the coating is to be used on a non-metal (e. g.
composite) substrate. A preferred chromate salt is zinc chromate, and it is generally preferred that the chromate be ~I present in the composition at a level of from about 0.01 to about 15 weight percent based on the total solids in the !i coating composition. Tt is generally convenient to add the chromate to the composition by first milling it with a portion of the second polymer and then adding it to part A of the composition.
optionally, the coating composition may further comprise such conventional additives as surfactants, accelerators, inhibitors, diluents and active solvents, in amounts which do not deleteriously effect the properties of the coating. In the case of solvents, different solvents may be used depending on whether the coating is to be sprayea, brushed, etc., e.g. if a higher solids coating is desired for I
~~p~~.~''~~~
brush application it may be advantageous to use a low vapor I
pressure solvent such as a di-methyl ester mixture, e.g. a I
I
mixture of dimethyl succinate, dimethyl glutarate'and dimethyl ,I
i adipate to extend the pot life of the composition. A
ij i particularly preferred dimethyl ester mixture comprises about 25% dimethyl succinate, about 55% dimethyl glutarate, and I
ii about 20% dimethyl adipate. The amount of solvent present in Ii the composition will depend on the particular solvent used, i and the desired viscosity of the coating. Tf a low v.o.c.
~' (volatile organic compound) coating is desired, it is generally necessary to brush-apply the coating, so that a n lower level of solvent may be used. e.g. the ratio of solids ii to solvent may be from about 50:50 to 40:60.
In a preferred embodiment of the invention the i polyurethane resin is present in an amount of from about 10 to ~i '! 50 weight percent of the composition, and the first and second i polymers are present in a weight ratio of from about 1:2 to . I
'; 1:6; the stabilized conductive filler is present in an arnount of from about 30 to 80 weight percent of the composition; and the azole is present in an amount of from about 0.1 to 3 weight percent of the composition, based on the total solids in the coating composition. Particularly preferred levels are from 10 to 25 wei ht ;; g percent of the polyurethane, from 40 to 70 weight percent of the filler, and from 0.5 to 1.75 percent of the triazole. A weight ratio of 1:3.2 of the .first to second polymer is particularly preferred. Unless otherwise specified, all weight percents given herein are based on the total weight of solids in the coating composition.
The present invention is further directed to a method of inhabiting corrosion of substrates while maintaining Li~i:irubl 5rxia1u1r1g comprising the steps of a) providing a I

corrosion inhibiting conductive coating according to the ,j invention end b) applying the corrosion inhibiting coating to I. a substrate. This method may further comprise the step of c) curing the coating. The coating may be cured as described i hereinabove, either at room temperature or by heating the substrate. It is preferred that prior to heat curing the coating be allowed to dry for approximately 30 minutes at 'I ambient temperature. The coating may be applied to the .I substrate by doctor blade, brushing, spraying, and other conventional coating techniques. Spraying is generally preferred far convenience.
I
The coating of the invention may be used on any solid I
substrate, e.g. metals such as aluminum or steel, and composites such as metal filled, glass or carbon filled, or i other polymer composites.
The invention further provides a substrate which is covered with a coating o~ the invention. The substrate may be bonded to a second substrate or a gasket, forming an assembled part, and exposed to severe environments such as salt fog with p minimal corrosion of the part. For purposes of EMIlRFI
shielding, the substrates and gasket generally are jelectrically conductive.
The following examples are illustrative of preferred ' embodiments of the invention and not of limiting effect.
Other variations and modifications of the invention may be practiced by those skilled in the art without departing from the spirit and scope of the invention.

A corrosion inhibiting conductive coating of the invention was prepared using the formulation shown in 'i~abi.e I
1. Part A was prepared by first mixing the xylene and the propylene glycol monomethyl ether acetate solvents, then dissolving.the tolytriazole in this solvent mizture, which mizture serves both as a solvent for the triazole powder and a diluent to reduce the viscosity of the coating. Then the stabilized copper powder (Fujikura~ CP-10) was added to the triazole solution and mized well. A conventional fluorocarbon surfactant (FC-430* commercially available from Minnesota Mining and Manufacturing) was then added and mized. Then a 50% solution of a fluoroolefin vinyl ether polymer in zylene (LUMIFLONm601) was added, and the batch was again mized.
2.8 parts of part H, which comprised a methylene diisocyanate terminated castor oil prepolymer (URIC 2023) were then added to 97.2 parts of part A and mixed well. The resulting coating was spray coated on aluminum AL 35* (3000 alloy series), dried 15 minutes at ambient temperature, then cured for 30 minutes at 250°F, and tested, with results as shown in Table 2. The viscosity of the mized coating composition doubled in approzimately 45 minutes, which was considered to be the pot life of the mizture. The coated substrate was tack free, according to ASTM-D-1650, after 15 minutes at ambient temperature.
The data of Table 2 shows that the coating has excellent initial properties, and retains these properties for up to 1000 hours of salt fog exposure. Particularly importantly, a conductive interface having over 80 dB of EMI attenuation is maintained during the 1000 hour salt fog test. Additionally, no corrosion of the substrate was observed after the 1000 hour salt fog test.
*Trade-mark N Sx1C4 W fn ~

ro ro ro ro ~n .u In M Ln M \

Vl ~ CO sT W V) I 1 I 1 f~ et'~D N N e0 l~

H .L: O O e-ir-iri M

.., o 0 0 o n o 0 ro *

v *

w * .~ *

o~ a o .r.r a o w w U

N d.~ N ~ .6.1 r1 ~ r~

N ~ n7N ~ ~ c'4a a a a o x ~ x o N

H r-i(rJO ('>O r-i lA O W O f0N

c%7 r1 r-iM .~"r/ M wi,Cn W d.1 CJ O

6'., .riipJE~JO 8U mJ r1O O C9O C1 w1 U

fl? to O W ~ N O~O C7 O tt~

N: H 01 6d H r1 N tt5!~ r1 I H

V7 e~ . 1 I V~ M
' W. N U r1 "~ ~ N 1 E
-' N

U

W O

ve rr V)C~ UlV1 ",.l'.Ci ~ .~

In !A r1r-i r-1r-1 v ~ ~ ~ ~ A

~ W 1 O

v .,~ .,.~.,-1 .,.I.,-1 H N

~ 4.1 O U O Gs 'V'M 'V~M .L) .N rt V1 d~ r-I

N N I

H ~ a0 II

* H

* * a N
' ~ s~ v~

a o w a as .u v a v .v ro H

d ~n v m v .~ r~

.~.~u~ <na.~<n .r~ .c~ t-n r-11.1 H r-iU d-~ U S-f rW 0 a cd ,f.," f0v v N v v n1 r~4 fix, a ..~ >.~ .,~~ a .~>.~a ~ .ra a~ o v .~.~.~,v rdv Cx ro .u .rio ~ .raL1t# o f1~ 9 v s~ o ro ~ o s~ cn sc ,t'.. H r-1 f-1 H 00 v Ua (~ *

* *

~~~~.9~~:.~
_______________ ___.___ _ _ _ _____________ _ _ _ ______________________ P~r_~ A
I ~2~.~n~~. P r bg We i c~h>~
Xylene 40.39 Propylene glycol monomethyl ether acetate 10.23 Tolytriazole 0.54 iI Stabilized copper powder 27.20 ,I Fluorocarbon surfactant 0.06 !I Fluoroolefin vinyl ether* 16.76 ~~ *50~ solution in xylene I
.; ______._________________________________________ ~I
.. Park .. Component, Parts by Weight Methylene diisocyanate terminated 2.81 castor oil prepolymer ,I
I
t EXAMPLE 2 A corrosion inhibiting coating according to another embodiment of the invention was prepared according to Example 1, except that the tolytriazole was replaced with the same amount of a proprietary triazole available from PMC
I
;~ Specialties Group under the tradename COB32ATEC~ 205. The coating was tested as described in Example 1, with results as (I
Vii, shown in Table 3.
n The data of Table 3 shows that this coating also has excellent initial properties, and retains these properties during prolonged exposure to salt fog.

Gardner Impact Surface Conductivity*
(ohms/square) Initial Direct 80 in-lbs Initial 0.054 Reverse 80 in-lbs 168 hr salt fog** 0.081 366 hr salt fog** 0.12 504 hr salt fog** 0.12 Adhesion (ASTM-D-3359) Initial 5B (pass) *Per Quality Control Test Procedure #95-40-5104 available upon request from Chomerics, Inc.
**Salt Fog Test ASTM-B-117 Example 3 A corrosion inhibiting coating was prepared according to Example 2, with the further addition of 5 weight percent zinc chromate, based on the total solids of the coating.
This coating (Sample 1) was then applied to AL
2024-class III (aluminum 2000 series) and tested using the procedures described in Example 1, with each test being conducted on two specimens. One specimen was tested as coated, while the coating on the other specimen was scratched before initial testing and subsequent exposure to salt fog. The coating of Example 2 (Sample 2) was then tested both as coated and scratched, using identical procedures. The results of this testing are shown in Table 4.
Surface Conductivity* (ohms/square) As Coated Scratched Sample 1 Initial 0.021 0.021 120 hr salt fog** 0.042 0.039 288 hr salt fog** 0.048 0.056 Sample 2 Initial 0.054 0.052 168 hr salt fog** 0.081 1.42 336 hr salt fog** 0.120 20.00 Appearance Sample 1 Initial pass pass 120 hr salt fog** pass pass 288 hr salt fog** pass slightly black at scratches Sample 2 Initial pass pass 168 hr salt fog** pass black with salt deposits 336 hr salt fog** pass black and blistered *Per Quality Control Test Procedure #95-40-5104 available upon request from Chomerics, Inc.
**Salt Fog Test ASTM-B-117 Although the two formulations were not tested after the same number of hours exposure to salt fog, the data of Table 4 does demonstrate that after about 300 hours salt fog the scratched panels coated with the coating which contained zinc chromate retained much better surface conductivity and appearance than those coated with the coating of Example 2.
16a i rya sJy ~y '>
~~ C;1 p.9 lfl i~
'i I
While the present invention has been described with ;I reference to its preferred embodiments, other embodiments, Ij variations and modifications can achieve the same result.
I
Variations, modifications and equivalents of the present i invention will be obvious to those skilled in the art and it I
,i is intended to cover in the appended claims all such ~ modifications and equivalents as fall within the true spirit and scope of this invention.
I
I
i 2544p i --1?-

Claims

1. A corrosion inhibiting conductive coating comprising:

a) a polyurethane resin comprising:

i) a first polymer selected from the group consisting of isocyanate resins and isocyanate terminated prepolymers; and ii) a second polymer selected from the group consisting of polymers having an amine functionality and polymers having a hydrozyl functionality;

b) a stabilized conductive filler; and c) an azole.

2. The coating of claim 1 wherein the first polymer is an isocyanate.

3. The coating of claim 2 wherein the isocyanate is methylene diisocyanate.

4. The coating of claim 1 wherein the first polymer is a methylene diisocyanate terminated castor oil prepolymer.

5. The coating of claim 1 wherein the second polymer is fluorinated.

6. The coating of claim 1 wherein the second polymer is selected from the group consisting of polyether polyols and polyether amines.

7. The coating of claim 1 wherein the second polymer is a fluoroolefin vinyl ether copolymer.

8. The coating of claim 1 wherein the stabilized conductive filler is selected from the group consisting of stabilized copper powder, nickel powder, silver plated metals, nickel-graphite fibers and mixtures thereof.

9. The coating of claim 8 wherein the stabilized copper powder is produced by a process which comprises coating copper powder with silver metal using a silver complex salt solution comprising from 3 to 30 weight percent silver nitrate, from 15 to 70 weight percent ammonium bicarbonate, and from 23 to 75 weight percent trisodium ethylenediaminetetraacetic acid.

10. The coating of claim 1 wherein the stabilized conductive filler is produced by coating an unstabilized conductive filler with a fatty acid.

11. The coating of claim 1 wherein the stabilized conductive filler is produced by coating an unstabilized conductive filler with a noble metal.

12. The coating of claim 1 wherein the azole is selected from the group consisting of aromatic triazoles, imidazoles, and thiazoles.

13. The coating of claim 12 wherein the aromatic triazole is selected from the group consisting of tolytriazole and benzotriazole.

14. The coating of claim 1 further comprising a chromate salt.

15. The coating of claim 14 wherein the chromate salt is zinc chromate.

16. A corrosion inhibiting conductive coating comprising:

(a) from about 10 to 50 weight percent of a polyurethane resin comprising:

(i) a first polymer selected from the group consisting of isocyanates and isocyanate terminated prepolymers; and (ii) a second polymer selected from the group consisting of amines, polythiols and polyether polyols;

19a b) from about 30 to 80 weight percent of a stabilized conductive filler; and c) from about 0.1 to 3 weight percent of an azole selected from the group consisting of aromatic triazoles, imidazoles or thiazoles.

17. The coating of claim 16 wherein the polyurethane resin is from about 10 to 25 weight percent of the coating.

18. The coating of claim 16 wherein the first and second polymers are present in a weight ratio of from about 1:2 to 1:6.

19. The coating of claim 16 wherein the stabilized conductive filler is from about 40 to 70 weight percent of the coating.

20. The coating of claim 16 wherein the aromatic triazole is from about 0.5 to 1.75 weight percent of the coating.

21. The coating of claim 16 wherein the first polymer is an isocyanate.

22. The coating of claim 21 wherein the isocyanate is methylene diisocyanate.

23. The coating of claim 16 wherein the first polymer is a methylene diisocyanate terminated castor oil prepolymer.

24. The coating of claim 16 wherein the second polymer is fluorinated.

25. The coating of claim 16 wherein the second polymer is a fluoroolefin vinyl ether copolymer.

26. The coating of claim 16 wherein the stabilized conductive filler is selected from the group consisting of stabilized copper powder, nickel powder, silver plated metals, nickel-graphite fibers and mixtures thereof.

27. The coating of claim 26 wherein the stabilized copper powder is produced by a process which comprises coating copper powder with silver metal using a silver complex salt solution comprising from 3 to 30 weight percent silver nitrate, from 15 to 70 weight percent ammonium bicarbonate, and from 23 to 75 weight percent trisodium ethylenediaminetetraacetic acid.

28. The coating of claim 16 wherein the stablized conductive filler is produced by coating an unstabilized conductive filler with a fatty acid.

29. The coating of claim 16 wherein the stabilized conductive filler is produced by coating an unstabilized conductive filler with a noble metal.

30. The coating of claim 16 wherein the aromatic triazole is tolytriazole.

31. The coating of claim 16 wherein the aromatic triazole is benzotriazale.

32. A method of inhibiting corrosion of conductive substrates while maintaining EMI/RFI shielding comprising the steps of:

a) providing a corrosion inhibiting conductive coating comprising:

1) a polyurethane resin comprising:

i) a first polymer selected from the group consisting of isocyanates and isocyanate terminated prepolymers; and ii) a second polymer selected from the group consisting of polymers having an amine functionality and polymers having a hydroxyl functionality;

2) a stabilized conductive filler; and 3) an aromatic triazole; and b) applying the corrosion inhibiting coating to a conductive substrate.

33. The method of claim 32 further comprising the step of c) curing the corrosion inhibiting coating.

34. The method of claim 33 wherein the casting is cured for at least 30 minutes at 250°F.

35, The method of claim 33 wherein the coating is cured for at least 5 days at roam temperature.

36. The method of claim 32 wherein the first polymer is a methylene diisocyanate terminated castor oil prepolymer.

37. The method of claim 32 wherein the second polymer is fluorinated.

38. The method of claim 32 wherein the second polymer is selected from the group consisting of polyether polyols and polyether amines.

39. The method of claim 32 wherein the second polymer is a fluoroolefin vinyl ether copolymer.

40. The method of claim 32 wherein the stabilized conductive filler is selected from the group consisting of stabilized copper powder, nickel powder, silver plated metals, nickel-graphite fibers and mixtures thereof.

41. The method of claim 40 wherein the stabilized copper powder is produced by a process which comprises coating copper powder with silver metal using a silver complex salt solution comprising from 3 to 30 weight percent silver nitrate, from 15 to 70 weight percent ammonium bicarbonate, and from 23 to 75 weight percent trisodium ethylenediaminetetraacetic acid.

42. The method of claim 32 wherein the stabilized conductive filler is produced by coating an unstabilized conductive filler with a fatty acid.

43. The method of claim 32 wherein the stabilized conductive.filler is produced by coating an unstabilized conductive filler with a noble metal.

44. The method of claim 32 wherein the coating is applied to the conductive substrate by spraying.

45. The method of claim 32 wherein the conductive substrate is aluminum.

46. A corrosion resistant substrate comprising a conductive substrate and a corrosion inhibiting coating on the surface of said conductive substrate comprising:
a) a polyurethane resin comprising:
i) a first polymer selected from the group consisting of isocyanates and isocyanate terminated prepolymers; and ii) a second polymer selected from the group consisting of polymers having an amine functionality, polymers having a hydroxyl functionality, polymers having both amine and hydroxyl functionalities, and mixtures thereof;
b) a stabilized conductive filler; and c) an azole.

47. The corrosion resistant substrate of claim 46 wherein the conductive substrate is aluminum.

48. The corrosion resistant substrate of claim 96 wherein the conductive substrate is a metal filled composite.

49. Tho corrosion resistant substrate of claim 46 wherein the azole is selected from the group consisting of aromatic triazoles, imidazoles, and thiazoles.

50. The corrosion inhibiting conductive coating of claim 1 wherein the second polymer is polytetramethyleneoxide-di-p-aminobenzoate.

51. The corrosion inhibiting conductive coating of claim 1 wherein the second polymer has a hydroxyl or amine functionality of greater than 1.