CA2034855A1 - Manufacture of polymeric foams - Google Patents

Manufacture of polymeric foams

Info

Publication number
CA2034855A1
CA2034855A1 CA002034855A CA2034855A CA2034855A1 CA 2034855 A1 CA2034855 A1 CA 2034855A1 CA 002034855 A CA002034855 A CA 002034855A CA 2034855 A CA2034855 A CA 2034855A CA 2034855 A1 CA2034855 A1 CA 2034855A1
Authority
CA
Canada
Prior art keywords
polyisocyanate
manufacture
polymeric foams
component
isocyanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002034855A
Other languages
French (fr)
Other versions
CA2034855C (en
Inventor
Louis Muller
Tu Pham
Gabriel Verhelst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman International LLC
Original Assignee
Louis Muller
Tu Pham
Gabriel Verhelst
Imperial Chemical Industries Plc
Huntsman Ici Chemicals Llc
Huntsman International Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB909002240A external-priority patent/GB9002240D0/en
Priority claimed from GB909022196A external-priority patent/GB9022196D0/en
Application filed by Louis Muller, Tu Pham, Gabriel Verhelst, Imperial Chemical Industries Plc, Huntsman Ici Chemicals Llc, Huntsman International Llc filed Critical Louis Muller
Publication of CA2034855A1 publication Critical patent/CA2034855A1/en
Application granted granted Critical
Publication of CA2034855C publication Critical patent/CA2034855C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0895—Manufacture of polymers by continuous processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/917—Specialized mixing apparatus utilized in cell forming process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Graft Or Block Polymers (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Medicinal Preparation (AREA)

Abstract

A method for the preparation of flexible polymeric foam by reacting a polyisocyanate component with an isocyanate-reactive component comprising at least 50% by weight of water, the polyisocyanate component comprising at least two polyisocyanate compositions, one of them being a low NCO isocyanate terminated prepolymer and the second being a high NCO polyisocyanate.
CA002034855A 1990-02-01 1991-01-24 Manufacture of polymeric foams Expired - Lifetime CA2034855C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB909002240A GB9002240D0 (en) 1990-02-01 1990-02-01 Polymeric foams
GB9002240.1 1990-02-01
GB909022196A GB9022196D0 (en) 1990-10-12 1990-10-12 Polymeric foams
GB9022196.1 1990-10-12

Publications (2)

Publication Number Publication Date
CA2034855A1 true CA2034855A1 (en) 1991-08-02
CA2034855C CA2034855C (en) 2002-03-26

Family

ID=26296582

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002034855A Expired - Lifetime CA2034855C (en) 1990-02-01 1991-01-24 Manufacture of polymeric foams

Country Status (15)

Country Link
US (2) US5430072A (en)
EP (1) EP0442631B1 (en)
JP (1) JP3106150B2 (en)
KR (1) KR0173990B1 (en)
AT (1) ATE163658T1 (en)
AU (2) AU636191B2 (en)
CA (1) CA2034855C (en)
DE (1) DE69128974T2 (en)
DK (1) DK0442631T3 (en)
ES (1) ES2112850T3 (en)
GB (1) GB9101903D0 (en)
GR (1) GR3026276T3 (en)
HK (1) HK1008964A1 (en)
NO (1) NO180015C (en)
PT (1) PT96622B (en)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8908490D0 (en) * 1989-04-14 1989-06-01 Ici Plc Prepolymers
AU636191B2 (en) * 1990-02-01 1993-04-22 Huntsman Ici Chemicals Llc Manufacturing of polymeric foams from polyisocyanate compositions
US6376698B1 (en) * 1991-12-17 2002-04-23 Imperial Chemical Industries Plc Prepolymers
DE4204395A1 (en) * 1992-02-14 1993-08-19 Bayer Ag METHOD FOR THE PRODUCTION OF CALTENING POLYURETHANIC SOFT FORMULA SUBSTANCES
EP0566251B2 (en) * 1992-04-16 2002-09-04 Huntsman International Llc Polyisocyanate composition
US5621016A (en) * 1992-04-16 1997-04-15 Imperial Chemical Industries Plc Polyisocyanate compositions and low density flexible polyurethane foams produced therewith
GB9208377D0 (en) * 1992-04-16 1992-06-03 Ici Plc Process for preparing flexible polyurethane foams
GB9208396D0 (en) * 1992-04-16 1992-06-03 Ici Plc Process for making flexible foams
US5447965A (en) * 1993-06-02 1995-09-05 Imperial Chemical Industries Plc Method for the preparation of flexible polymeric foams
GB9311345D0 (en) * 1993-06-02 1993-07-21 Ici Plc Method for the preparation of flexible polymeric foams
GB9320874D0 (en) * 1993-10-11 1993-12-01 Ici Plc Recycling of flexible foam
TW344750B (en) * 1994-06-16 1998-11-11 Ici Plc Process for preparing flexible foams
US5436277A (en) * 1994-07-28 1995-07-25 Basf Corporation Polyisocyanate compositions for the preparation of flexible polyurethane foams
DE19516272A1 (en) * 1995-05-08 1996-11-14 Hermann Leguin Primary element scanner for determining deflection of scanning pin or similar
US5900442A (en) * 1995-05-12 1999-05-04 Imperial Chemical Industries Plc Flexible polyurethane foams
US5821275A (en) * 1997-11-10 1998-10-13 Bayer Corporation Flexible foams and flexible molded foams based on liquid isocyanate-terminated allophanate-modified MDI prepolymer blends and processes for the production of these foams
AU2001281084A1 (en) 2000-08-01 2002-02-13 Huntsman International, Llc Manufacture of mdi-tdi based flexible polyurethane foams
EP1205290B1 (en) * 2000-11-08 2005-08-10 Hennecke GmbH Method and apparatus for continuously producing foam blocks
US6376567B1 (en) 2000-12-07 2002-04-23 Bayer Corporation Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions
US8501165B2 (en) * 2001-12-12 2013-08-06 Promethean Surgical Devices Llc In situ bonds
US20040068078A1 (en) * 2001-12-12 2004-04-08 Milbocker Michael T. In situ polymerizing medical compositions
AU2003268318A1 (en) * 2002-09-03 2004-03-29 Promethean Surgical Devices Llc In situ polymerizing medical compositions
DE10345096A1 (en) * 2003-09-26 2005-04-21 Basf Ag Process for the preparation of isocyanate mixtures
US7632294B2 (en) * 2003-09-29 2009-12-15 Promethean Surgical Devices, Llc Devices and methods for spine repair
DE10349813A1 (en) * 2003-10-24 2005-06-02 Fischerwerke Artur Fischer Gmbh & Co. Kg Multi-component kit for PU-based, low-density, water-driven lightweight foam and brittleness, related uses and methods
ES2427842T3 (en) 2008-01-18 2013-11-04 Japan Tobacco Inc. Pack of cigarettes
US20110054058A1 (en) * 2009-08-31 2011-03-03 William Crooker Emulsified polyol and resultant foam therefrom
US8436073B2 (en) 2009-10-06 2013-05-07 Amcol International Lignite-based foundry resins
US8623959B2 (en) * 2009-10-06 2014-01-07 Joseph M. Fuqua Non-veining urethane resins for foundry sand casting
US8853299B2 (en) * 2009-10-06 2014-10-07 Amcol International Corp. Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance
US8309620B2 (en) * 2009-10-06 2012-11-13 Amcol International Corp. Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance
US8426494B2 (en) * 2009-10-06 2013-04-23 Amcol International Corp. Lignite urethane based resins for enhanced foundry sand performance
CA3121866A1 (en) * 2018-12-21 2020-06-25 Huntsman International Llc Reaction mixture suitable for manufacturing of foam with reduced aldehyde emission

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE581667A (en) * 1958-08-15
GB957748A (en) * 1960-10-22 1964-05-13 Bayer Ag Proportioning and mixing device
CA1042600A (en) * 1972-05-03 1978-11-14 Louis L. Wood Crosslinked hydrophilic polyurethane foams
GB1548370A (en) * 1975-06-24 1979-07-11 Ici Ltd Polyurea foams
EP0005903B1 (en) * 1978-05-30 1983-06-01 Imperial Chemical Industries Plc Process for the manufacture of polyurea foams
EP0010850B2 (en) * 1978-10-03 1990-01-31 Imperial Chemical Industries Plc Liquid polyisocyanate compositions
EP0022617B2 (en) * 1979-07-11 1991-09-25 Imperial Chemical Industries Plc Polyisocyanate compositions and their use in the preparation of polyurethane foams
US4297444A (en) * 1980-02-11 1981-10-27 Texaco Development Corp. Process for rim elastomers with superior high temperature dimensional stability
DE3402698A1 (en) * 1984-01-26 1985-08-08 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING FILLER-CONTAINING POLYURETHANE (UREA) MASSES, FUEL-CONTAINING POLYURETHANE (UREA) MASSES AND THEIR USE
DE3519692A1 (en) * 1985-06-01 1986-12-04 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING ELASTIC POLYURETHANE SOFT FOAMS AND MOLDED BODIES PRODUCED THEREOF
NZ226008A (en) * 1987-09-21 1990-11-27 Ici Plc Process for manufacture of polyurethane foams using methylene diphenyl isocyanates and optionally water as blowing agent
DE3818769A1 (en) * 1988-06-02 1989-12-07 Bayer Ag LIQUID POLYISOCYANATE MIXTURES, A METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR THE PRODUCTION OF POLYURETHANE SOFT FOAMS
US5079276A (en) * 1988-07-20 1992-01-07 Human Industry Corporation Method of manufacturing polyurethane foam
JPH0739506B2 (en) * 1988-09-30 1995-05-01 三菱重工業株式会社 Shape memory polymer foam
GB8908490D0 (en) * 1989-04-14 1989-06-01 Ici Plc Prepolymers
JPH03124741A (en) * 1989-09-29 1991-05-28 Dow Chem Co:The Flexible polyurethane foam and its manufacture
JPH0733423B2 (en) * 1989-10-03 1995-04-12 日本ポリウレタン工業株式会社 Method for producing flexible polyurethane foam
AU636191B2 (en) * 1990-02-01 1993-04-22 Huntsman Ici Chemicals Llc Manufacturing of polymeric foams from polyisocyanate compositions
GB9208377D0 (en) * 1992-04-16 1992-06-03 Ici Plc Process for preparing flexible polyurethane foams

Also Published As

Publication number Publication date
AU2722592A (en) 1992-12-17
DE69128974T2 (en) 1998-07-30
EP0442631A2 (en) 1991-08-21
AU6986691A (en) 1991-08-08
ATE163658T1 (en) 1998-03-15
ES2112850T3 (en) 1998-04-16
DK0442631T3 (en) 1998-12-07
CA2034855C (en) 2002-03-26
EP0442631B1 (en) 1998-03-04
PT96622B (en) 1998-07-31
NO180015B (en) 1996-10-21
AU642355B2 (en) 1993-10-14
US5624972A (en) 1997-04-29
HK1008964A1 (en) 1999-05-21
DE69128974D1 (en) 1998-04-09
JP3106150B2 (en) 2000-11-06
AU636191B2 (en) 1993-04-22
KR0173990B1 (en) 1999-04-01
JPH04213340A (en) 1992-08-04
KR910021427A (en) 1991-12-20
EP0442631A3 (en) 1992-03-18
GB9101903D0 (en) 1991-03-13
NO180015C (en) 1997-01-29
US5430072A (en) 1995-07-04
NO910377L (en) 1991-08-02
PT96622A (en) 1991-10-15
NO910377D0 (en) 1991-01-31
GR3026276T3 (en) 1998-06-30

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
MKEC Expiry (correction)

Effective date: 20121202