CA2042738A1 - Bleach activation - Google Patents

Bleach activation

Info

Publication number
CA2042738A1
CA2042738A1 CA2042738A CA2042738A CA2042738A1 CA 2042738 A1 CA2042738 A1 CA 2042738A1 CA 2042738 A CA2042738 A CA 2042738A CA 2042738 A CA2042738 A CA 2042738A CA 2042738 A1 CA2042738 A1 CA 2042738A1
Authority
CA
Canada
Prior art keywords
catalysts
hetero
manganese
charge
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2042738A
Other languages
French (fr)
Other versions
CA2042738C (en
Inventor
Thomas Louis F. Favre
Ronald Hage
Karin Van Der Helm-Rademaker
Jean Hypolites Koek
Rudolf Johan Martens
Ton Swarthoff
Marten Robert P. Van Vliet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Thomas Louis F. Favre
Ronald Hage
Karin Van Der Helm-Rademaker
Jean Hypolites Koek
Rudolf Johan Martens
Ton Swarthoff
Marten Robert P. Van Vliet
Unilever Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB909011338A external-priority patent/GB9011338D0/en
Priority claimed from GB909027415A external-priority patent/GB9027415D0/en
Application filed by Thomas Louis F. Favre, Ronald Hage, Karin Van Der Helm-Rademaker, Jean Hypolites Koek, Rudolf Johan Martens, Ton Swarthoff, Marten Robert P. Van Vliet, Unilever Plc filed Critical Thomas Louis F. Favre
Publication of CA2042738A1 publication Critical patent/CA2042738A1/en
Application granted granted Critical
Publication of CA2042738C publication Critical patent/CA2042738C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Abstract

Novel bleach and oxidation catalysts, a method of bleaching substrates using these catalysts and bleaching (detergent) compositions containing the catalysts are reported. The catalysts are a manganese-based co-ordination complex of the general formula :

[LnMnmXp]z Yq wherein Mn is manganese in the IV-oxidation state; n and m are independent integers from 2-8; X represents a co-ordination or bridging species; p is an integer from 0-32; Y is a counter-ion, the type of which is dependent on the charge z of the complex which can be positive, zero or negative; q = z/[charge Y]; and L is a ligand which is an organic molecule containing a number of hetero-atoms selected from N, P, O, and S, which co-ordinates via all or some of its hetero-atoms and/or carbon atoms to the Mn(IV)-center(s), which latter are anti-ferromagnetically coupled.
CA002042738A 1990-05-21 1991-05-16 Bleach activation Expired - Lifetime CA2042738C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB909011338A GB9011338D0 (en) 1990-05-21 1990-05-21 Bleach activation
GB9011338.2 1990-05-21
GB9027415.0 1990-12-18
GB909027415A GB9027415D0 (en) 1990-12-18 1990-12-18 Bleach activation

Publications (2)

Publication Number Publication Date
CA2042738A1 true CA2042738A1 (en) 1991-11-22
CA2042738C CA2042738C (en) 1997-10-14

Family

ID=26297102

Family Applications (2)

Application Number Title Priority Date Filing Date
CA002042738A Expired - Lifetime CA2042738C (en) 1990-05-21 1991-05-16 Bleach activation
CA002042736A Expired - Lifetime CA2042736C (en) 1990-05-21 1991-05-16 Bleach activation

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA002042736A Expired - Lifetime CA2042736C (en) 1990-05-21 1991-05-16 Bleach activation

Country Status (12)

Country Link
US (2) US5244594A (en)
EP (2) EP0458397B1 (en)
JP (2) JPH0765074B2 (en)
KR (2) KR950001046B1 (en)
AU (2) AU622363B2 (en)
BR (2) BR9102085A (en)
CA (2) CA2042738C (en)
DE (2) DE69125309T2 (en)
ES (2) ES2100924T3 (en)
IN (2) IN173875B (en)
MY (2) MY106557A (en)
NO (2) NO911943L (en)

Families Citing this family (433)

* Cited by examiner, † Cited by third party
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