CA2061021A1 - Acrylic adhesive composition and organoboron initiator system - Google Patents

Acrylic adhesive composition and organoboron initiator system

Info

Publication number
CA2061021A1
CA2061021A1 CA2061021A CA2061021A CA2061021A1 CA 2061021 A1 CA2061021 A1 CA 2061021A1 CA 2061021 A CA2061021 A CA 2061021A CA 2061021 A CA2061021 A CA 2061021A CA 2061021 A1 CA2061021 A1 CA 2061021A1
Authority
CA
Canada
Prior art keywords
acrylic adhesive
initiator system
adhesive composition
adhesive compositions
organoboron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2061021A
Other languages
French (fr)
Other versions
CA2061021C (en
Inventor
Martin M. Skoultchi
Nicholas V. Merlo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ablestik Laboratories
Original Assignee
Ablestik Laboratories
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ablestik Laboratories filed Critical Ablestik Laboratories
Publication of CA2061021A1 publication Critical patent/CA2061021A1/en
Application granted granted Critical
Publication of CA2061021C publication Critical patent/CA2061021C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

Abstract

A two-part initiator system useful in acrylic adhesive compositions comprising in one-part a stable organoboron amine complex and in the second part an organic acid destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides a fast, room temperature cure with good stability and exhibiting both high tensile strength and high peel strength.
CA 2061021 1991-04-29 1992-02-11 Acrylic adhesive composition and organoboron initiator system Expired - Fee Related CA2061021C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/692,766 US5106928A (en) 1991-04-29 1991-04-29 Acrylic adhesive composition and organoboron initiator system
US692,766 1991-04-29

Publications (2)

Publication Number Publication Date
CA2061021A1 true CA2061021A1 (en) 1992-10-30
CA2061021C CA2061021C (en) 1998-12-22

Family

ID=24781936

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2061021 Expired - Fee Related CA2061021C (en) 1991-04-29 1992-02-11 Acrylic adhesive composition and organoboron initiator system

Country Status (9)

Country Link
US (1) US5106928A (en)
EP (1) EP0511464B1 (en)
JP (1) JPH0772264B2 (en)
KR (1) KR950009549B1 (en)
CA (1) CA2061021C (en)
DE (1) DE69201093T2 (en)
ES (1) ES2067965T3 (en)
HK (1) HK51195A (en)
SG (1) SG28341G (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0561352A1 (en) * 1992-03-17 1993-09-22 National Starch and Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5539070A (en) * 1994-02-22 1996-07-23 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
WO1996032397A1 (en) * 1995-04-14 1996-10-17 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive compositions made therewith
WO1996032398A1 (en) * 1995-04-14 1996-10-17 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5686544A (en) * 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US5691065A (en) * 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5872197A (en) * 1995-08-11 1999-02-16 Minnesota Mining & Manufacturing Company Initiator system and adhesive composition made therewith
US5883208A (en) * 1995-11-07 1999-03-16 Minnesota Mining And Manufacutring Company Initiator system and adhesive composition made therewith
US5935711A (en) * 1996-10-23 1999-08-10 3M Innovative Properties Company Organoborane amine complex initiator systems and polymerizable compositions made therewith
US5952409A (en) * 1996-01-31 1999-09-14 3M Innovative Properties Company Compositions and methods for imparting stain resistance and stain resistant articles
US6252023B1 (en) 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6383655B1 (en) 1998-06-12 2002-05-07 3M Innovative Properties Company Low odor polymerizable compositions useful for bonding low surface energy substrates
US6479602B1 (en) 2000-03-15 2002-11-12 3M Innovative Properties Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
US6812308B2 (en) 2000-11-21 2004-11-02 3M Innovative Properties Company Initiator systems and adhesive compositions made therewith

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US5385958A (en) * 1993-03-05 1995-01-31 Dymax Corporation Activator formulation and composition utilizing same
US5310835A (en) * 1993-09-30 1994-05-10 National Starch And Chemical Investment Holding Corporation Transparent two-part acrylic adhesive composition and the method of use thereof
EP1029906B1 (en) * 1994-02-22 2004-12-08 Minnesota Mining And Manufacturing Company Bonded composite containing polymerisable acrylic composition made with polymerisation initiator systems based on organoborane amine complexes
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
CN1132852C (en) * 1998-06-12 2003-12-31 美国3M公司 Initiator systems and adhesive compositions made therewith
BR9815905A (en) * 1998-06-12 2001-02-20 Minnesota Mining And Manucturi Polymerizable composition for use with an aerobic initiator, useful kit for bonding low surface energy substrates, binder and polymerized compositions, substrate, and bonding process for at least one low surface energy substrate
DE19841342A1 (en) * 1998-09-10 2000-04-20 Merck Patent Gmbh New reactive systems made from polymerizable monomers containing peroxides and stabilized boralkyl compounds
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US6486090B1 (en) 1999-11-04 2002-11-26 3M Innovative Properties Company Initiator/hydroxide and initiator/alkoxide complexes, systems comprising the complexes, and polymerized compositions made therewith
US6410667B1 (en) * 1999-11-04 2002-06-25 3M Innovative Properties Company Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith
US6806330B1 (en) * 1999-12-17 2004-10-19 Dow Global Technologies Inc. Amine organoborane complex polymerization initiators and polymerizable compositions
EP1201722A1 (en) * 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisation initiators, polymerisable compositions, and uses thereof
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US6734268B2 (en) * 2001-12-31 2004-05-11 3M Innovative Properties Company Metal salt modifiers for bonding compositions
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
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US6660805B1 (en) * 2002-05-16 2003-12-09 Lord Corporation Two-part adhesive: part A-monomer, toughener(s), optional adhesion promotor and reducing agent; part B-epoxy resin
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US7098279B2 (en) * 2002-10-22 2006-08-29 Loctite (R&D) Limited Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
US7250091B2 (en) * 2003-02-13 2007-07-31 Dow Global Technologies Inc Method of forming a seating system
RU2340503C2 (en) * 2003-02-13 2008-12-10 Дау Глобал Текнолоджиз Инк. Improved instrument cluster unit and method for its manufacturing
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US20040229990A1 (en) * 2003-05-16 2004-11-18 Lord Corporation Acrylic structural adhesive having improved T-peel strength
US20040242817A1 (en) * 2003-05-29 2004-12-02 Lord Corporation Internally coordinated organoboranes
WO2004108483A2 (en) 2003-06-02 2004-12-16 Dow Global Technologies Inc. Air bag system and method of forming the same
KR20060081656A (en) * 2003-06-09 2006-07-13 다우 글로벌 테크놀로지스 인크. Stabilized organoborane polymerization initiators and polymerizable compositions
US20040259990A1 (en) * 2003-06-18 2004-12-23 Sonnenschein Mark F. Paint formulation for a low surface energy substrate
US7360519B2 (en) 2003-07-10 2008-04-22 Dow Global Technologies, Inc. Engine intake manifold assembly
US7638007B2 (en) * 2003-08-13 2009-12-29 Dow Global Technologies, Inc Method for joining substrates and objects
CN1835992B (en) * 2003-08-13 2010-10-06 陶氏环球技术公司 Method for joining substrates and objects
GB0326286D0 (en) 2003-11-11 2003-12-17 Vantico Gmbh Initiator systems for polymerisable compositions
US8501886B2 (en) * 2003-12-22 2013-08-06 Dow Global Technologies Llc Accelerated organoborane amine complex initiated polymerizable compositions
JP2007515547A (en) * 2003-12-22 2007-06-14 ダウ グローバル テクノロジーズ インコーポレイティド Accelerated organoborane amine complex-initiated polymerizable composition
JP4959343B2 (en) * 2004-01-22 2012-06-20 ヘンケル コーポレイション Polymerizable composition for bonding and sealing low surface energy substrates for fuel cells
US20070172989A1 (en) * 2004-02-27 2007-07-26 Akzo Nobel N.V. Polymerization initiator systems containing aluminum compounds as curing inhibitors and polymerizable compositions made therewith
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JP5242168B2 (en) * 2005-01-04 2013-07-24 ダウ・コーニング・コーポレイション Organosilicon functional boron amine catalyst complex and curable composition prepared therefrom
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US7408012B1 (en) 2005-04-18 2008-08-05 Loctite (R&D) Limited Adhesive bonding systems having adherence to low energy surfaces
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US7682663B2 (en) * 2006-02-23 2010-03-23 Bowling Green State University Remote curing of polymer coating by gaseous, vaporous or aerosol initiating agent
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Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0561352A1 (en) * 1992-03-17 1993-09-22 National Starch and Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US6284381B1 (en) 1994-02-22 2001-09-04 3M Innovative Properties Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5539070A (en) * 1994-02-22 1996-07-23 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US6248846B1 (en) 1994-02-22 2001-06-19 3M Innovative Properties Company Polymerizable compositions comprising organoborane amine complexes
US5690780A (en) * 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5691065A (en) * 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
WO1996032398A1 (en) * 1995-04-14 1996-10-17 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5684102A (en) * 1995-04-14 1997-11-04 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive compositions made therewith
US5681910A (en) * 1995-04-14 1997-10-28 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhsesive compositions made therewith
US5621143A (en) * 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5616796A (en) * 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5718977A (en) * 1995-04-14 1998-02-17 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5795657A (en) * 1995-04-14 1998-08-18 Minnesota Mining And Manufaturing Company Organoborane polyamine complexes and adhesive compositions made therewith
WO1996032397A1 (en) * 1995-04-14 1996-10-17 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive compositions made therewith
US6093778A (en) * 1995-08-11 2000-07-25 3M Innovative Properties Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US5686544A (en) * 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US5872197A (en) * 1995-08-11 1999-02-16 Minnesota Mining & Manufacturing Company Initiator system and adhesive composition made therewith
US5990036A (en) * 1995-08-11 1999-11-23 3M Innovative Properties Company Initiator system and adhesive composition made therewith
US5994484A (en) * 1995-08-11 1999-11-30 3M Innovative Properties Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US6008308A (en) * 1995-08-11 1999-12-28 3M Innovative Properties Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US6027813A (en) * 1995-11-07 2000-02-22 3M Innovative Properties Company Initiator system and adhesive composition made therewith
US5883208A (en) * 1995-11-07 1999-03-16 Minnesota Mining And Manufacutring Company Initiator system and adhesive composition made therewith
US5952409A (en) * 1996-01-31 1999-09-14 3M Innovative Properties Company Compositions and methods for imparting stain resistance and stain resistant articles
US5935711A (en) * 1996-10-23 1999-08-10 3M Innovative Properties Company Organoborane amine complex initiator systems and polymerizable compositions made therewith
US6383655B1 (en) 1998-06-12 2002-05-07 3M Innovative Properties Company Low odor polymerizable compositions useful for bonding low surface energy substrates
US7189303B2 (en) 1998-06-12 2007-03-13 3M Innovative Properties Company Initiator systems and adhesive compositions made therewith
US6252023B1 (en) 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6384165B1 (en) 1999-03-19 2002-05-07 3M Innovative Properties Co. Organoborane amine complex initiator systems and polymerizable compositions made therewith
US6479602B1 (en) 2000-03-15 2002-11-12 3M Innovative Properties Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
US6812308B2 (en) 2000-11-21 2004-11-02 3M Innovative Properties Company Initiator systems and adhesive compositions made therewith

Also Published As

Publication number Publication date
JPH0772264B2 (en) 1995-08-02
SG28341G (en) 1995-09-18
HK51195A (en) 1995-04-13
EP0511464A1 (en) 1992-11-04
JPH0598216A (en) 1993-04-20
DE69201093T2 (en) 1995-05-11
EP0511464B1 (en) 1995-01-04
US5106928A (en) 1992-04-21
DE69201093D1 (en) 1995-02-16
ES2067965T3 (en) 1995-04-01
KR950009549B1 (en) 1995-08-24
KR920019899A (en) 1992-11-20
CA2061021C (en) 1998-12-22

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