CA2071401A1 - Graft copolymers prepared by two-staged aqueous emulsion polymerization - Google Patents

Graft copolymers prepared by two-staged aqueous emulsion polymerization

Info

Publication number
CA2071401A1
CA2071401A1 CA002071401A CA2071401A CA2071401A1 CA 2071401 A1 CA2071401 A1 CA 2071401A1 CA 002071401 A CA002071401 A CA 002071401A CA 2071401 A CA2071401 A CA 2071401A CA 2071401 A1 CA2071401 A1 CA 2071401A1
Authority
CA
Canada
Prior art keywords
emulsion polymerization
aqueous emulsion
graft copolymers
copolymers prepared
macromonomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002071401A
Other languages
French (fr)
Other versions
CA2071401C (en
Inventor
David Richard Amick
William David Emmons
Dennis Paul Lorah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2071401A1 publication Critical patent/CA2071401A1/en
Application granted granted Critical
Publication of CA2071401C publication Critical patent/CA2071401C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C08F290/046—Polymers of unsaturated carboxylic acids or derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Materials For Medical Uses (AREA)
  • Organic Insulating Materials (AREA)
  • Liquid Crystal Substances (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Dental Preparations (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

This invention relates to a two stage aqueous emulsion polymerization process for making graft copolymers. In the first stage, at least one first ethylenically unsaturated monomer is polymerized in the presence of at least one mercapto-olefin compound to form a macromonomer with terminal functional groups. In the second stage, at least one second ethylenically unsaturated monomer is polymerized in the presence of the macromonomer such that a copolymer is formed with a backbone of polymerized units of the at least one second ethylenically unsaturated monomer and side chains of the macromonomer.
CA002071401A 1991-06-27 1992-06-17 Graft copolymers prepared by two-staged aqueous emulsion polymerization Expired - Fee Related CA2071401C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/722,562 US5247040A (en) 1991-06-27 1991-06-27 Graft copolymers prepared by two staged aqueous emulsion polymerization
US722,562 1991-06-27

Publications (2)

Publication Number Publication Date
CA2071401A1 true CA2071401A1 (en) 1992-12-28
CA2071401C CA2071401C (en) 2004-06-15

Family

ID=24902378

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002071401A Expired - Fee Related CA2071401C (en) 1991-06-27 1992-06-17 Graft copolymers prepared by two-staged aqueous emulsion polymerization

Country Status (22)

Country Link
US (2) US5247040A (en)
EP (1) EP0520668B1 (en)
JP (1) JP3549902B2 (en)
KR (1) KR930000555A (en)
CN (1) CN1068124A (en)
AT (1) ATE156138T1 (en)
AU (1) AU657542B2 (en)
BR (1) BR9202400A (en)
CA (1) CA2071401C (en)
CZ (1) CZ199492A3 (en)
DE (1) DE69221222T2 (en)
FI (1) FI922971A (en)
HK (1) HK1000304A1 (en)
HU (1) HU9202136D0 (en)
IE (1) IE922116A1 (en)
IL (1) IL102291A0 (en)
MX (1) MX9203302A (en)
NO (1) NO922472L (en)
PL (1) PL295052A1 (en)
TR (1) TR26079A (en)
TW (1) TW200497B (en)
ZA (1) ZA924518B (en)

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WO1994014861A1 (en) * 1992-12-29 1994-07-07 Basf Aktiengesellschaft Copolymerisates of vinyl pyrrolidone and vinyl imidazole, a process for producing them and their use in detergents

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CA2188552A1 (en) * 1994-05-19 1995-11-30 Jozef Huybrechts Coatings comprising self-stabilized lattices prepared in an aqueous carrier
FR2720751B1 (en) * 1994-06-03 1996-07-19 Rhone Poulenc Chimie Polyolefinic graft copolymer.
US5700873A (en) * 1995-03-07 1997-12-23 Adhesives Research, Inc. Method of preparation of water-soluble copolymer
DE19524053A1 (en) * 1995-07-01 1997-01-02 Roehm Gmbh Process for the preparation of branched polymers
US5891950A (en) * 1996-05-28 1999-04-06 Eastman Chemical Company Use of stable amino-functional latexes in water-based inks
US6417267B1 (en) 1996-05-28 2002-07-09 Eastman Chemical Company Adhesive compositions containing stable amino-containing polymer latex blends
US5998543A (en) * 1996-05-28 1999-12-07 Eastman Chemical Company Stable amino-containing polymer latex blends
US6028155A (en) * 1997-05-21 2000-02-22 Eastman Chemical Company Surfactant-containing acetoacetoxy-functional and enamine-functional polymers
US5962556A (en) * 1996-10-22 1999-10-05 Eastman Chemical Company Functional latexes resistant to hydrolysis
US5782972A (en) * 1997-03-21 1998-07-21 W.R. Grace & Co.-Conn. Additive for production of highly workable mortar cement
EP0983306B1 (en) * 1997-05-21 2002-08-28 Eastman Chemical Company Process for preparing reactive latex blends which are chemically and physically stable until film formation
US6649679B1 (en) 1997-09-18 2003-11-18 Eastman Chemical Company Stable waterborne polymer compositions containing poly(alkylenimines)
KR100387311B1 (en) * 1997-12-26 2003-08-21 제일모직주식회사 Branched styrene-based thermoplastic resin and preparation method thereof
US6391992B1 (en) * 1998-09-18 2002-05-21 Celanese International Corporation Sulfonate-terminated oligomers of vinyl esters and their vinyl alcohol oligomer derivatives
ATE506400T1 (en) 1998-11-23 2011-05-15 Grace W R & Co IMPROVED PROCESSING AND SERVICE LIFE OF MORTAR BOARDS MADE OF MASONRY MORTAR AND METHOD FOR THE PRODUCTION THEREOF
CA2369599A1 (en) * 1999-05-07 2000-11-16 Hiraku Miyashita Acrylic copolymer, acrylic pressure-sensitive adhesive composition, acrylic pressure-sensitive adhesive tape or sheet, and acrylic adhesive composition
US6462109B1 (en) 1999-10-12 2002-10-08 Eastman Chemical Company Surfactantless latex compositions and methods of making polymer blends using these compositions
US6410005B1 (en) 2000-06-15 2002-06-25 Pmd Holdings Corp. Branched/block copolymers for treatment of keratinous substrates
AR033394A1 (en) * 2000-09-14 2003-12-17 Rohm & Haas A METHOD TO IMPROVE THE PROCESSING IN FUSION OF THERMOPLASTIC POLYMERS, A METHOD TO FORM ARTICLE, AND A PLASTIC ARTICLE.
AR030722A1 (en) * 2000-09-14 2003-09-03 Rohm & Haas ADHESIVE COMPOSITIONS CONTAINING INJERTO COPOLYMERS
US6670419B2 (en) * 2000-09-14 2003-12-30 Rohm And Haas Company Method of toughening thermoplastic polymers and thermoplastic compositions produced thereby
JP2004509213A (en) 2000-09-14 2004-03-25 ローム　アンド　ハース　カンパニー Adhesive composition containing low molecular weight polymer additive
US20040024144A1 (en) * 2000-09-14 2004-02-05 Robert Solomon Aqueous dispersions of comb copolymers and coatings produced therefrom
US6844390B2 (en) * 2001-04-09 2005-01-18 Eastman Chemical Company Modified alkyd compositions comprising polyol latex compositions and processes of making them
US6699931B2 (en) 2001-04-09 2004-03-02 Eastman Chemical Company Modified alkyd compositions comprising diol latex compositions and processes of making the same
US20090005476A1 (en) * 2001-04-09 2009-01-01 Eastman Chemical Company Polyol latex compositions and process of making them
JP4643895B2 (en) * 2002-06-28 2011-03-02 株式会社カネカ Vinyl chloride copolymer resin for paste, composition and method for producing resin
US7186769B2 (en) * 2003-08-12 2007-03-06 Hexion Specialty Chemicals, Inc. Water-dispersible polyester stabilized fluoroalkyl compositions
US7101924B2 (en) * 2003-08-12 2006-09-05 Hexion Specialty Materials, Inc. Water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions
US7173081B2 (en) * 2003-08-12 2007-02-06 Hexion Specialty Chemicals, Inc. Processes to produce water-dispersible polyester stabilized fluoroalkyl compositions
US7189780B2 (en) * 2003-08-12 2007-03-13 Hexion Specialty Chemicals, Inc. Processes to produce water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions
JP2005281571A (en) * 2004-03-30 2005-10-13 Kaneka Corp Hard vinyl chloride resin composition for extrusion
JP2005281570A (en) * 2004-03-30 2005-10-13 Kaneka Corp Vinyl chloride resin composition for injection-molded article
JP2005281569A (en) * 2004-03-30 2005-10-13 Kaneka Corp Vinyl chloride-based resin composition
JP2005281567A (en) * 2004-03-30 2005-10-13 Kaneka Corp Vinyl chloride resin composition for calendering
EP1894951B1 (en) 2006-08-31 2018-11-28 Rohm and Haas Company Aqueous dispersion of polymeric particles
EP1894950A1 (en) * 2006-08-31 2008-03-05 Rohm and Haas France SAS Aqueous dispersion of polymeric particles
US9034964B2 (en) 2010-10-21 2015-05-19 Eastman Chemical Company Waterborne coating compositions containing low-VOC coalescents that are hydroxypivalyl hydroxypivalate esters
US8383710B2 (en) 2010-10-21 2013-02-26 Eastman Chemical Company Waterborne coating compositions containing low-VOC coalescents
US8809447B2 (en) 2010-12-15 2014-08-19 Eastman Chemical Company Acetoacetate-functional monomers and their uses in coating compositions
US9029451B2 (en) 2010-12-15 2015-05-12 Eastman Chemical Company Waterborne coating compositions that include 2,2,4-trimethyl-3-oxopentanoate esters as reactive coalescents
US8809446B2 (en) 2010-12-15 2014-08-19 Eastman Chemical Company Substituted 3-oxopentanoates and their uses in coating compositions
US8759451B2 (en) * 2011-12-21 2014-06-24 The Goodyear Tire & Rubber Company Method of making a graft copolymer
US9156932B2 (en) 2011-12-21 2015-10-13 The Goodyear Tire & Rubber Company Method of making a graft copolymer
EP2607102B1 (en) * 2011-12-21 2016-09-14 The Goodyear Tire & Rubber Company Method of making a graft polymer, copolymer and tire
US9040619B2 (en) 2012-11-08 2015-05-26 Eastman Chemical Company 1,3-diketoamide functional polymers and compositions employing the same
JP6541952B2 (en) * 2014-09-26 2019-07-10 株式会社日本触媒 Macromonomer and method for producing the same
US11518899B2 (en) 2019-09-04 2022-12-06 Eastman Chemical Company Aromatic enol ether paint additives
US10865171B1 (en) 2019-09-04 2020-12-15 Eastman Chemical Company Process to make aromatic enol ethers and olefin isomers of aromatic enol ethers
US10815179B1 (en) 2019-09-04 2020-10-27 Eastman Chemical Company Aromatic dicarbinols
US10889536B1 (en) 2019-09-04 2021-01-12 Eastman Chemical Company Enol ethers
US20210062017A1 (en) 2019-09-04 2021-03-04 Eastman Chemical Company Branched acetal coalescing aids
US10858304B1 (en) 2019-09-04 2020-12-08 Eastman Chemical Company Aromatic enol ethers
US10544076B1 (en) 2019-09-04 2020-01-28 Eastman Chemical Company Method of making a dialdeyhde
US11312873B2 (en) 2019-09-04 2022-04-26 Eastman Chemical Company Aromatic enol ether paint additives
US10865172B1 (en) 2019-09-04 2020-12-15 Eastman Chemical Company Aromatic enol ethers
US10550057B1 (en) 2019-09-04 2020-02-04 Eastman Chemical Company Method of making a dialdeyhde

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014861A1 (en) * 1992-12-29 1994-07-07 Basf Aktiengesellschaft Copolymerisates of vinyl pyrrolidone and vinyl imidazole, a process for producing them and their use in detergents

Also Published As

Publication number Publication date
NO922472L (en) 1992-12-28
US5314977A (en) 1994-05-24
HK1000304A1 (en) 1998-02-20
FI922971A (en) 1992-12-28
DE69221222D1 (en) 1997-09-04
JPH05186542A (en) 1993-07-27
US5247040A (en) 1993-09-21
PL295052A1 (en) 1993-05-31
TW200497B (en) 1993-02-21
AU657542B2 (en) 1995-03-16
KR930000555A (en) 1993-01-15
IE922116A1 (en) 1992-12-30
FI922971A0 (en) 1992-06-26
NO922472D0 (en) 1992-06-23
MX9203302A (en) 1992-12-01
AU1827492A (en) 1993-01-07
CZ199492A3 (en) 1993-01-13
BR9202400A (en) 1993-01-26
JP3549902B2 (en) 2004-08-04
ATE156138T1 (en) 1997-08-15
HU9202136D0 (en) 1992-10-28
CA2071401C (en) 2004-06-15
CN1068124A (en) 1993-01-20
TR26079A (en) 1994-12-15
ZA924518B (en) 1993-03-31
EP0520668B1 (en) 1997-07-30
EP0520668A1 (en) 1992-12-30
IL102291A0 (en) 1993-01-14
DE69221222T2 (en) 1998-02-12

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