CA2071978A1 - Thermocompensating susceptor - Google Patents

Abstract

A thermocompensating susceptor (52) is described comprising a microwave transparent sheet (54), e.g. paper, paperboard or plastic, having a layer (56) thereon of a dried dispersion comprising a film forming vehicle together with two kinds of dispersed particles including microwave interactive particles such as a metal, metal oxide, carbon or graphite that absorbs microwave energy to produce heat in a microwave oven and electrically nonconductive thermocompensating particles of a mineral hydrate containing bound water of crystallization and having a dissociation temperature between about 100 ·F and 500 ·F, at which temperature the bound water is released therefrom to prevent overheating of the laminate.

Description

WO9l/10337 2 Q7 19 7 8 PCT/US90/06114 MICROWAVE SUS~l~R WIT~ ATE~UAI0R FOR HEAT CO~L

Field of the Invention The invention relates to a susceptor adapted to produce heat when exposed to microwaves.

Back~round of the Invention In the prior art, a variety of substances incl~ding metal particles, ferrites, carbon or graphite particles, oxides of the metals zinc, germanium, barium, tin, iron and the like have been incorporated into coatings for producing heat in a microwave oven, i.e. to act as a heating susceptor for the purpose of absorbing lS a portion of the microwave energy and converting it to heat. Various other chemical susceptors such as salts are employed in an aqueous solution for this purpose as described in patent 4,283,427. A quantity of free water must be provided to dissolve the salt so that it is in 20 an ionic form that will interact with the microwave ~
energy to produce heat. This requires that the wet ~ -product be placed in a pouch that is sealed at its edges. This wet product has many disadvantages ~`
including its bulk, fluidity and the complexity of the 25 manufacturin~ operation. Patents 4,264,668 and `~
4,518,651 describe coatings containing carbon black.
However, it has been found that carbon-containing heat producing coatings, when heated in a microwave oven, can be subject to a runaway heating condition that often 30 produces arcing, sparking, burning or charring of the -backing sheet to which they are applied. Patents 4,806,718; 4,808,780; 4,810,84S and 4,818,831 describe ceramic devices for microwave heating, primarily green ceramics, which employ a quantity of bound water to 3S produce heating. The ceramic gel itself produces heat.
In developing the present invention it was found that when carbon was used alone with à film - former, such as a standard ink base, that burning and uncontrolled temperature rise occurs. Many of the .' . ' ' WO91/10337 ' 2 0 719 7 8 PCT/US90/06114 packages burst into flames when heated in a microwave oven. It was also found that when carbon was mixed with an aqueous acrylic dispersion, the resulting susceptor would burn the package. A rapid, uncontrolled temperature rise occurs. Discoloration appears at about 400F. Then ignition follows almost immediately. The package starts to brown at about 400F and then quickly begins to burn which is, of course, unacceptable. Once the package begins to carbonize, this facilitates further heating and accelerates the burning reaction which causes burning to occur at an even faster rate.
This can be referred to as runaway heating.
An important ob~ective of the invention to provide a microwave susceptor layer that can be applied at little or no pressure as a fluid and which, upon exposure to microwave heating, will produce a uniform heat without unacceptable arcing, popping, sparking or burning. It is another objective to obtain uniformity of heating in different portions of the package and also from one sample to another. The susceptor composition should have characteristics that allow it to be applied as a fluid by a variety of methods including roll printing, silk screen printing, spraying, dipping brushing and the like. The composition should preferably be useful with gravure printing, one application method found to allow especially good coating weight control. The fluid susceptor, sometimes referred to herein for convenience as "ink", should be capable of being applied directly onto a backing such as paper, paperboard or the like without the requirement for multiple superimposed coatings, plastic sheets or high pressure which increase production costs and capital requirements. ;~
When applied by printing, the fluid susceptor composition should have all tne qualities of a good printing ink including the proper rheological properties: viscosity, dilatency and thixotropy to ..

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,' ' -'' " ' ' .'' ' ' . .," . ' ~' , 2 0 7 1 9 7 ~ PCT/US9O/06114 avoid problems such as misting, splattering or dripping from freshly printed surfaces moving at high speed and must also transfer easily from the supply roll to the printing roll. The susceptor fluids or inks of the present invention should also produce coatings of uniform thicknesses and be able to form both a continuous and interrupted coating, e.g. a coating with a multiplicity of openings or uncoated spots within a i.
coated area.
It is a further object of the invention to control or stabilize the heat produced by a microwave interactive material in contact therewith by providing a cooling effect at a selected temperature or at a plurality of temperatures within a selected temperature range to compensate for the heat produced by the microwave interactive material in heat conductive relationship therewith.
A more specific object is to control heating of a susceptor so that it can be used on paper without the paper charring or catching on fire.
When printing is the application method, -~
another object is to enable printing of the susceptor to be accomplished using standard printing equipment at normal speeds, up to 1200 feet per minute. A further object is to provide a susceptor for heating foods which is food safe.
Yet another object is to match or exceed the performance of commercially available microwave susceptors that employ vapor deposited semiconductive aluminum coatings.
When overheating occurs at the periphery or along the edge of a susceptor, it is an object to reduce or eliminate overheating, charring or burning of this kind along the edge of a printed susceptor.
These and other more~detailed and specific objects of the invention will be apparent in view of the accompanying drawings and specification which set forth `
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, .:` , by way of example but a few of the various forms of the invention that will be apparent tO those skilled in the art once the principles described herein are understood.

Summary of the Invention The invention provides a thermocompensating susceptor. The susceptor preferably includ~s a microwave transparent backing sheet formed from a microwave transparent substance such as plastic resin, paper or paperboard that is stable during heating up to at least about 400F and a microwave susceptor layer applied to the backing. The susceptor layer comprise`s a dried dispersion composed of an apparently homogeneous microscopically heterogeneous mixture of at least two finely divided phases. The dispersion incudes organic film forming resin particles or binders dispersed in a liquid dispersant and, most preferably, two other kinds ~ -of dispersed particles. One kind of particle comprises a microwave interactive particle selected to absorb microwave energy and product heat. The other particle comprises electrically nonconductive thermocompensating particles of a mineral hydrate containing bound water of crystallization and having a dissociation temperature in the range of between about 100F to 600~F and preferably between about 250F to 450F. The mineral hydrate attenuator functions to limit and control runaway heating of the susceptor during heating in a microwave oven. This is due to a cooling effect produced by the hydrate. Prior to heating, water molecules are tightly bound in the compound. When heated, the attenuator retains water molecules until the initial dissociation temperature is reached and then begins to give them off.
It appears to be the release of the water molecules which produces a cooling effect, thereby stabilizing the temperature of the packaging material until all of the water molecules have been released. However, because the water molecules are tightly bound in the hydrate, ... , , . . .. :

" . ` ' : . ' ' WO 91tlO337 2 0 71~ 7 8 PCT/US90/06114 the coating can be considered dry to the touch and can be used to form a stable coating that can be exposed, e.g. on the outside of a package, if desired and preferably does not rub off easily.
The susceptor layer can be applied by a variety of methods including printing, dipping, spraying, brushing and the like~

The Fi~ures Fig. l is a perspective view showing sheet material to which a susceptor fluid is applied in accordance with one form of the invention;
Fig. 2 is a perspective view of a susceptor in accordance with another form of the invention;
Fig. 3 is a plan view of a susceptor in accordance with another form of the invention;
Fig. 4 is similar to Fig. 3 but having a different pattern;
Fig. 5 is an enlarged view of a portion of Fig.
4; and, Figs. 6-ll are graphs showing the heating characteristics of susceptors described in examples 1-7.

Detailed DescriPt~on of the Invention The present invention provides a backing sheet composed of a microwave transparent sheet material such as paper, paperboard or plastic that is transparent to microwave energy that has a susceptor layer or coating thereon. The susceptor coating comprises a dispersion composed of a fluid vehicle or binder in which most preferably is uniformly and homogeneously suspended two kinds of dispersed particles. One kind is an electrically conductive microwave interactive particle -~
which produces heat in a microwave field. The other is an electrically nonconductive non-microwave interactive mineral attenuator hydrate in particulate form for dissipating, spreading and/or modulating the energy WO91/10337 ~ 0 7 1 9 7 8 PCT/US90/06114 absorbed and converted to heat by the conductive particles. Thus the dispersed phase comprises two kinds of uniformly intermixed suspended particles of different compositions. Only the conductive particles interact with microwave energy directly to produce heat. Both suspended materials are composed of microscopic size particles that remain dispersed or in suspension in the vehicle until used. During heatin~ the suspended attenuator particles prevent locali2ed energy buildup and runaway heating that would otherwise occur.
In accordance with the present invention the backing consists of a sheet of paper, paperboard, plastic film or other flexible microwave transparent organic polymeric sheet material. The backing sheet material can, for example, be 15 to 50 pound greaseproof kraft paper or paperboard such as 18 or 20 point paperboard, plastic film such as polyester, nylon, cellophane or the like. The susceptor coating applied to this backing sheet forms a bilayer. The fluid ~0 vehicle or film former serves as a binder or matrix to hold the coating together and to the backing. The vehicle of the susceptor can comprise any suitable vehicle or binder such as an acrylic or maleic resin, -e.g. maleic rosin ester, polyvinyl acetate, protein or soluble shellac. The best printability and drying is provided by acrylic resins. The shelf life and dispersion ability are also better with acrylic resins ;~-and, accordingly, an acrylic resin vehicle is preferred but is not essential. Thus, as the dispersion or "ink"
dries, the acrylic particles present in the emulsion coagulate or flow together to form a fi-lm. A liquid dispersant or solvent present in the vehicle can be water with or without an amine such as ammonia. A
variety of other vehicles known to the art can also be 35 used, however, water based vehicles are preferred. A -~
suitable water based dispersion can be an alkaline solution of an acidic resin. Upon drying, the resin may .

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W091/10337 2~q 197 ~ PCT/US90/06114 become water insoluble and form a film. Other film formers such as a polyvinyl acetate adhesive emulsion can be employed alone or with an acrylic resin. The pH
of the vehicle can be controlled as required, e.g. with sodium hydroxide. The vehicle typically contains about - 50% to 80~ solids. The balance is water.
In one preferred form of the invention, there are uniformly and homogeneously suspended in the vehicle at least two kinds of dispersed particles. The first is the microwave interactive heat producing particle, e.g.
carbon, optionally together with suspended metal particles such as aluminum, bronze or nickel particles in a minor amount of, say, about l~ to 20~ by weight of the heat producing particles.
The electrically conductive carbon particles dispersed in the vehicle should be of a suitable carbon black such as channel black, furnace black, lamp black or other suitable source of carbon. The energy attenuator will affect various forms of carbon. While various suitable carbon black is 90F Black (Inmont Printing Inks Division of BASF Corporation, Chicago, Illinois, [I.P.I.]). Carbon black is typically present in an amount of about l to 5 times the amount of film forming resin solids basis.
Also dispersed in the vehicle, and preferably uniformly an homogeneously intermixed with the susceptor particles, are particles of an electrically nonconductive microwave noninteractive inorganic hydrated mineral attenuator adapted to release water oî
crystallization endothermically for dissipating or , compensating in part for the heat produced by the microwave interactive particles. The attenuator is preferably used in an amount from about 2 to 20, and most preferably used in an amount from about lO to 12, times the amount of carbon bl~ck or other susceptor (heater) present when used for popping popcorn. The attenuator is present in a sufficient amount to prevent , : . ' ' , : .
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WO91/10337 2 0 7 1 9 7 8 PCT/US90/~114 localized overheating, sparking and burning. Various hydrated mineral attenuators can be employed in accordance with the invention to stabilize and control the heating characteristics of the microwave interactive susceptor particles. These hydrated mineral attenuator particles do not produce heat themselves. When heated in heat conductive relationship with the heat producing particles, they provide a cooling effect. The attenuator particles remain relatively inert until the dissociation temperature is reached. At this point water molecules are released to produce a cooling effect which stabilizes the temperature of the susceptor at the point reached when the water molecules begin to evolve until all of the water is driven off. In addition, each crystal may have se~uential dissociation temperatures, i.e. H20 molecules begin to be liberated at temperatures much lower than the dissociation temperatures listed in Table l. When used in the invention, the onset of cooling occurs at a much lower temperature. Table l temperatures are taken from The Handbook of Chemistry and Physics and indicate temperatures at which the crystals become completely anhydrous. At that time normal heating continues.
Examples of suitable hydrated mineral attenuator materials that can be employed in accordance with the invention are listed in the following table.

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W091t10337 2 0 7 1 9 7 8 PCT/US90/06114 TAB~E 1 Complete Dissociation Mineral Attenuator Formula Temperature Zinc l Phenol 4 Zn(C6H5S04)2 3H 2 257~F
Sulfonate Octahydrate Zirconium Chloride zrOCl2 H20 302F
Octahydrate ~horium Hypo ThP20~ llH20 320F
Phosphate Hydrate l5 Magnesium MgPtClO~6H20 356F
Chlorplatinate Hexahydrate Alumina Trihydrate Al203 3H20 392F
Zinc Iodate Dihydrate Zn(IO3) 2 ' 2H20 392F
Thallium Sulfate Tl2~S04)3 7H20 428~F
Heptahydrate Sodium Pyrophosphate Na2H2P207 H20 428F
Hydrate Potassium Ruthenate K2RUo6 H2o 392F
Hydrate Manganese Chloride MnCl2 4H20 3890F
Tetrahydrate 35 Magnesium Iodate Mg(IO3)z 4H20 4lOF
Tetrahydrate Magnesium Bromate Mg(BrO3)z~6H20 392F
Hexahydrate Magnesium Antiomonate MgOsb205~l2H20 392F
Hydrate Dysprosium Sulfate Dy2(so4)3~8H2o 392F
Octahydrate Cobalt Orthophosphate Co3(PO~) 2 8H20 293F
Octahydrate 50 Calcium Ditartrate CaC4H406 4H20 392F
Tetrahydrate Calcium Chromate CaCrO~ 2H20 392F
Dihydrate ~ . .

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Beryllium Oxalate BeC2O4 3H2O 428F
Trihydrate Sodium Thiosulfate Na2S2O3 5H2O 212F
Pentahydrate Nagnesium Sulfate MgSO4 7H 2 536F
Heptahydrate l0 Potassium Sodium KOCOCHOHCHOHCOONa-4H2O l58F
Tartrate Tetrahydrate Zinc Sulfate znSO4 7H2O
Heptahydrate Both kinds of suspended particles are preferably dispersed in the vehicle conventionally until uniform dispersion is obtained as will be understood by those skilled in the printing art. Only enough of the attenuator needs to be provided to reduce the tendency for overheating to occur in the finished susceptor. If too much is present the heating effect will be reduced, but if too little is present, hot spots or burning may occur.
Ninor amounts of known ink additives can be :
provided for improving flow and drying properties as well as the properties of the finished susceptor film.
When an acrylic dispersion is used as a film former, an amine such as ammonia or an organic amine of any suitable known composition useful in printing inks can be employed to form a stable vehicle suspension. Sodium hydroxide can be used to control the pH.

The invention will be better understood by reference to the figures which illustrate the invention by way of example.
As shown in Figure l, a web l0 is unwound from ` `:
supply roll 12, from left to rlght in the drawings. A
fluid dispersion, for convenience referred to herein as ~ink," present in supply pan 18 is picked up by a gravure roll 20 which is engraved with a repeating . ~ ~
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, . : , ' pa~tern 21 adapted to pick up the ink l9. Excess ink is removed by a doctor blade 22. The web passes over roll 13 and beneath a back-up roll 24 which presses the web against roll 20 to pick up the ink carried in the engraved areas 2l and thereby provide a spaced series of successive rectangular susceptor patches 26. The printed web 12 is dried, then passes over roll 25 and is later formed into containers, e.g. bags, trays, food support sheets, etc. It will be seen that the ink l9 carried in the pattern 2l has a rectangular shape in this case to provide a rectangular printed susceptor film 26. The film 26 is dried conventionally as by means of infrared and/or hot air dryers (not shown) or other suitable drying methods known to the art. When desired, another layer of flexible or non-flexible microwave transparent sheet material such as paper, paperboard or plastic (not i.~wn) can be adhesively bonded over the ink layer 2~ _o enclose and encapsulate it between two sheets of microwave transparent material.
When spraying is used, the rolls 20-2S are replaced with a spraying nozzle (not shown) that is used to apply the dispersion to the backing web lO. In the alternative, when the web is dipped it is immersed in the fluid susceptor, withdrawn and then dried.
The susceptor coating 26 can comprise between about 1-20 weight percent of the conductive microwave interactive susceptor particles and about 0.5-5 weight percent of the film forming substrate or matrix. When carbon is used as the interactive material, it is preferred to use about 2-lO percent by weight of carbon black. The amount of the compensating attenuator material depends upon how much heat is produced, how e fective t~:~ attenuator material is in cooling, how many bound water molecules are present, and the dissociation temperature. When the susceptor 26 is to be used in a package for popping popcorn in a microwave oven, the printed susceptor patches 26 can be a solidly .
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.. ,.. .. . :, , WO91/10337 2 0 7 ~ ~ ~ 8 PCT/US90/06114 printed rectangle about 4 to 6 inches on a side at a weight of typically about 15-25 pounds per ream (432,000 square inches). The carbon content in the dried ink film is on the order of about 2~ to 20~, and the attenuator content will be about 20~ to 90% by weight of the dried film. The viscosity of the fluid ink and the characteristics of the printing roll controls the basis weight of the ink film applied to the paper sheet 10.
More or less water or other solvent can be used to control the viscosity within a limited range. ~etter control can be provided with the printing roll 20 by using a courser or finer pattern of half-tone dots engraved at 21. The formula of the dispersion 19, and primarily the amount of attenuator, is ad~usted to regulate the cooling effect. The amount of carbon or other heater present and the amount of the dispersion laid down control the amount of heat produced.
Halftone printing can be employed as a way of achieving a precise laydown of the dispersion. The desired basis weight of the patch 26 depends on the formula of the dispersion. For popping popcorn, the basis weight of the patch is typically about 15-25 lb -per ream (432,000 square inches).
Refer now to Figure 2 which illustrates another optional form of the invention. Shown in Figure 2 is a backing sheet 54 which in this case is a 20-point food .grade paperboard on which is printed a susceptor 52 having an outline shaped to conform generally to the outline of a food product to be placed against it. The susceptor 52 in this case comprises an area about 4~
inches square. In the center is a solidly printed area 56 surrounded by a halftone printed area 58. This is surrounded by an area 60 which is approximately 50~ open unprinted areas in the form of small unprinted circles or squares surrounded by grid~lines. By using this form of the invention a greater amount of heat can be provided by the solidly printed center portion 56 ;`

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precisely where the food is located while a reduced amount of heat is provided at 58 and 6D surrounding the food to supply additional heat but also assist in preventing runaway or excessive heating at the edges of the susceptor 52. The area 56 has lO0~ coverage, area 58 has 80% coverage, and area 60 has 50% coverage.
Refer now to Figure 3 which illustrates a further modified form of the invention which in this case comprises a greaseproof kraft paper backing 70 upon which is printed a chevron-shaped susceptor 62 having a solidly printed center section 64 surrounded by a printed grid portion 66 that is 80~ printed and 20% open area. Using the susceptor 62, a greater amount of heat can be provided at the center with a reduced amGunt produced at the periphery by virtue of the reduction in the amount of susceptor material printed on the backing 70 at the edge. This reduces overheating, particulaxly at the edge of the patch 62. Area 64 is 80~ covered and area 66 is 50~ covered. The embodiments described in Figures 2 and 3 provide an outer area or circular band in which the concentration of susceptor is low enough to keep the paper from igniting if this is a problem. It has been found that the burning or overheating is most likely to take place at the edge of the printed susceptor area. Reduced coverage in this zone reduces chance of damage or ignition of the susceptor backing sheet.
Refer now to Figures 4 and 5 which illustrate still another form of the invention. In this case a paper sheet such as 50 pound greaseproof kraft paper sheet 72 is printed with a susceptor 74 having stripes 76 that are solidly printed alternating with stripes that are 80% printed and 20~ open. In this way, the amount of heat provided can be tailored to the precise amount of heat required so that the likelihood of uncontrolled heating is reduced.

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WO91/10337 2~7~ 9~8 PCT/US90/06114 The microwave interactive heat producing substance, i.e. susceptor material, will now be described in more detail. Various metals can be employed such as aluminum, copper, zinc, nickel, lead, stainless steel, iron, tin, chromium, manganese, silver, gold or their oxides. A variety of ferrites can be employed such as barium ferrite, zinc ferrite, magnesium ferrite, copper ferrite or other suitable ferromagnetic materials and alloys such as alloys of manganese, tin and copper or manganese, aluminum and copper, and carbides such as silicon carbide, iron carbide, strontium carbide and the like, as well as carbon. Qf these carbon is preferred because of its availability, cost and heating characteristics. The amount of microwave interactive susceptor such as carbon employed can be adjusted to obtain the desired rate of temperature rise to the dissociation point, say 392F.
~he heat produced must be adjusted to fit the thermal requirements of the food item.
Ad~ustment of the hydrated attenuator present in the formula is accomplished by choosing one or a mixture of two or more of the appropriate dissociation temperature, as well as the number of water molecules bound in the compound. It is believed that a greater number of water molecules present in the crystal structure of the attenuator will increase its cooling capacity. If two or more different hydrated attenuator particles are employed, it may be possible in some cases to obtain a stepped heating curve if required by particular heating conditions or to release water molecules progressively to lengthen the temperature range over which the cooling effect can b0 achieved.
If desired, the invention can also be applied to microwave susceptors of the type which employ a backing such as plastic film ~o which is applied a thin, semi-conductive layer of metal usually by vacuum electro-deposition. The hydrated mineral attenuator , ~c . .. . ,., . ~

, , particles can be incorporated as a layer above or below the metal coating or on the opposite side of the backing to ~eep the metallized sheet from overheating to the point where degradation is the problem.
The attenuator of the type described can also be applied as a separate layer ad~acent to a layer of carbon or other heat producing susceptor and in heat conductive relationship with it to cool the susceptor during microwave heating.
In one preferred form of the invention a stable dispersion containing hydrated attenuator particles in accordance with the invention is laminated between a relatively gas and vapor impervious sheet and a relatively porous sheet such as kraft paper which forms the o1~tside surface of a container such as a food container. Upon heating, the flow of water molecules from the susceptor coating will be toward the outside of the container because of the porosity of the kraft paper layer, thereby venting the water vapor and other gases into the atmosphere and preventing it from reaching the food.
The invention can be employed for heating, toasting, browning or crisping a variety of foods such as meat or fish patties, fish sticks, french fried potatoes, griddle foods including french toast, pancakes, waffles, pizza or for popping popcorn.
The invention will be better understood by reference to the following examples of various ink compositions employed in accordance with the invention.
All quantities are expressed on a weight basis.

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WO91/10337 20i~97~ PCT/USgO/06114 EXAMPLES
Example 1~ Attenuator is Alumina Trihydrate (Al2O3-3H2O) component weiqht (arams) percent Al2O3 3H2O 58.00 47.56 NaOH (.OlN) 23.50 19.27 H2O 15.44 12.66 Polyvinyl Acetate Adhesive Emulsion* 18.00 14.76 Carbon Black 5.05 4.14 Acrylic Resin1.45 1.19 Silicone Defoamer .51 .42 121.95 100.00 * Duracet 12 by Franklin International, Inc. contains 44% moisture.

Example 2: Attenuator is Alumina Trihydrate (Al2O3 3H2O) componentwei~ht (qrams)percent Al2O3-3H2O67.00 46.90 NaOH (.01N)24.00 16.80 H2O 30.15 21.10 Carbon Black9.86 6.90 Polyvinyl Acetate Adhesive Emulsion* 9.006.30 Acrylic Resin 2.83 1.98 Silicone Defoamer .02 .01 142.8699.99 ~`

Example 3: Attenuator is Sodium Thiosulfate Pentahydrate (Na2S2O3~5H2O) componentweiqht (qrams)percent Na2S2O3 SH 70 31.18 49.71 H2O 28.03 44.69 Carbon Black2.72 4.34 Acrylic Resin .78. 1.24 Silicone Defoamer .01 .02 62.72 100.00 :

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3~ 2 0 ~ 1 ~7 8 PCT/US90/n6114 Example 4: Attenuator is Magnesium Sulfate Heptahydrate (MgSO4~7H2O) componentweiaht (qrams~ percent MgSO4 7H2O 64.85 58.06 H2O 39.56 35.42 Carbon Black5.65 5.06 Acrylic Resin1.62 1.45 Silicone Defoamer .01 .01 111.69 100.00 Example 5: Attenuator is Zinc Sulfate Heptahydrate ( zns04 7H20) comPonentweiaht tqrams) percent ZNSO4 7H2O 84.40 62.54 H2O 41.07 30.43 Carbon Black 7.35 5.45 Acrylic Resins2.11 1.56 Silicone Defoamer .02 .01 134.95 99.99 ExamPle 6: Attenuator is Potassium Sodium Tartrate Tetrahydrate (KOCOCHOHCHOHCOONa 4H2O) component weiaht (qrams) percent XOCOCHOHCHOHCOONa~4H2050.18 54.74 H2O 35.86 39.12 Carbon Black 4.37 4.77 Acrylic Resin1.25 1.36 Silicone Defoamer .01 .01 91.67 100.00 ' :~, .'' , ' :~
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WO91/10337 2 0 7 i 9 7 8 PCT/US90/06114 Example 7: Control; Carbon Black with no mineral attenuator component weiqht (~rams) percent H2O 113.43 94.67 Carbon Black4.96 4.14 Acrylic Resin1.42 1.19 Silicone Defoamer .01 .01 119.82 100.00 Example 8: Control; Alumina Trihydrate (Al2O3~3H2O) componentweiaht (arams) percent Al2O3-3H2O 62.62 NaOH (.01N)3.54 37.38 9.47 100.00 Example 9: Control; Sodium Thiosulfate Pentahydrate (Na2S2O3 5H2O) componentweiah~ (arams) percent Na2S203 5H 25 9 62.62 H2O 3.54 37.38 9.47 100.00 ~:
Example 10: Control; Magnesium Sulfate Heptahydrate (MgSo4 7H 2 ) componentweiqht (arams) percent MgSO4-7H 2 62.62 H2O 3.54 37.38 9.47 100.00 .
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Example 11: Control; Zinc Sulfate Heptahydrate ( Z nSO4 7 H 2 ) component weiaht tqrams) percent ZNSo4-7H20 3 54 62 62 9.47 100.00 Example 12: Control; Potassium Sodium ~artrate Tetrahydrate tKOCOCHOHCHOHCOONa 4H~O) component weiqht (qrams) percent KOCOCHOHCHOHCOONa 4H20 5.93 62.62 H20 3.54 37.38 9,47 100.00 The following table presents the composition, basis weight and other characteristics of the dried film for Examples 1-7.

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' 2~71978 Susceptor coatings are prepared and applied to a backing as follows.
After determining the target level of the microwave interactive component per unit area (gm/M2 ) of the dried heater patch or strip, the formula of the liquid dispersion is calculated, then mixed and diluted with water to an appropriate consistency for laboratory draw downs. A sample of the dispersion is analyzed for "~ solids".
A portion of the liquid dispersion is applied by drawing it down on 25 lb. greaseproof paper w~th an appropriate drawn down rod. The selection of one of the numbered draw down rods is based upon the desired basis weight of the dry susceptor film. Completed "draw downs" are hung vertically and allowed to air dry.
A comparison of the weights of the precisely cut pieces of plain paper and paper containing the dry susceptor film will yield basis weight of the film.
Another quantity of the dried dispersion is analyzed for % solids.
Samples are cut from the dried draw downs.
A special fixture was constructed from 3/8"
sheets of G7 High Temperature Fiberglass. Two pieces of the sheet stock were cut into squares measuring 6-3/4"
on each side. A central aperture (4-3/4" square) was machined into each square, yielding two identical frames. The test sample is held securely between the two frames, allowing unimpeded microwave exposure from both directions.
A Litton 1000 watt commercial microwave oven (Model: VEND-10) was used for these tests.
Temperatures were derived by scanning infrared radiation given off by the sample during heating in the microwave oven. The results are shown in Figures 6-11.
A sample of the coat~d material prepared as in Examples 1-7 is placed between the two halves of the test fixture and the halves secured. The fixture -. .
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containing the sample is placed in the oven cavity in an upright position. The sample fixture should be centered laterally, parallel to and 2-l/2" back from the door, with the face of the sheet lO containing the susceptor patch 26 facing the door. The door is then closed. The infrared instrument is focused if necessary, and a video cassette recorder is started.
A normal test sequence is 60 seconds at full power in a lO00 watt oven. However, testing is discontinued if the test sample`is thermally consumed before the end of a normal test period.
The infrared temperature apparatus records a new set of complete temperatures every 33 milliseconds for the entire time. Any number of comparisons are possible with the accumulated data.
Hard copies of the screens are obtained by using 3Smm photography to capture the video display at 5 second intervals.
The results of the tests are shown i Figures 6-ll. Figure 6: In control Example 7, the specimen burst into flames after about 5-6 seconds. In Example l, the temperature leveled off at about 180F and no combustion occurred.
Figure 7: In the sample marked MPET laminate (top curve), a specimen of semiconductive vacuum aluminized polyester film as described in patent 4,735,513 is used as an example of the prior art for comparative purposes. The lower curve resulted from the composition of the invention as described in Example 2.
Heating approached 280F after about 5-15 seconds and leveled off.`
Figure 8: The upper curve represents heating achieved with the composition of Example 3. The lower curve resulted from control Example 9 (no heat producinq susceptor material present).

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Figure 9: The upper curve shows heating with the composition of Example 4 and the lower curve shows control Example lO.
Figure lO shows the heating curves achieved from Example 5 and control Example ll, respectively.
Fi~ure ll shows the heating that resulted from Example 6 and control Example 12.
In each example, when hydrated mineral attenuator is used it had a cooling effect on the carbon contained in the composition. When the mineral attenuator was used without the microwave interactive susceptor (carbon), almost no heat was produce~ This shows that they hydrate itself produces no more heat than plain paper (Figure 6).
Many variations of the present invention within the scope of the appended claims will be apparent to those skilled in the art once the principles described herein are understood.

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Claims (30)

WHAT IS CLAIMED IS:

1. A microwave susceptor construction comprising:
(a) a backing; and, (b) microwave susceptor material positioned on said backing; said microwave susceptor material including:
(i) a sufficient amount of microwave active material for heating of said susceptor material upon absorption of microwave energy of appropriate wavelength; and, (ii) mineral hydrate attenuator material containing bound water; said mineral hydrate attenuator material exhibiting dissociation of water upon a selected absorption of heat; said mineral hydrate attenuator material being provided: in heat conductive relationship with said microwave active material; and, in an amount sufficient to absorb heat and selectively inhibit overheating of said microwave susceptor construction during use.

2. A construction according to claim 1 wherein said mineral hydrate attenuator material is a material which exhibits dissociation of water at a temperature of no greater than about 500°F (260°C).

3. A construction according to claim 2 wherein said backing comprises a flexible sheet of material.

4. A construction according to claim 2 wherein said backing comprises a sheet of material selected from the group consisting of: paper;
paperboard; and, plastic film.

5. A construction according to claim 1 wherein:
(a) said microwave active material comprises a layer of vacuum deposited material; and, (b) said mineral hydrate attenuator material comprises particulate material retained in heat conductive relationship with said layer of vacuum deposited material.

6. A construction according to claim 5 wherein said mineral hydrate material is retained in heat conductive relationship with said layer of vacuum deposited material by a binder.

7. A construction according to claim 6 wherein said binder is selected from the group consisting of: acrylic resins; maleic resins; polyvinyl adhesives; and, mixtures thereof.

8. A construction according to claim 1 wherein:
(a) said microwave susceptor material includes a binder;
(i) said microwave active material comprising particulate material suspended within said binder; and, (ii) said mineral hydrate attenuator material comprising particulate material suspended within said binder.

9. A construction according to claim 8 wherein said microwave susceptor material comprises a halftone printing on said backing.

10. A construction according to claim 8 wherein said binder is selected from the group consisting of: acrylic resins; maleic resins; polyvinyl acetate adhesives; and, mixtures thereof.

11. A construction according to claim 8 wherein said microwave active particulate material comprises at least one member selected from the group consisting of carbon, microwave active metals; and, microwave active oxides.

12. A construction according to claim 11 wherein said microwave active material includes at least one member selected from the group consisting of:
carbon; nickel; zinc; tin; chromium; iron; gold; silver;
magnesium; copper; manganese; aluminum; cobalt; barium;
nickel oxides; zinc oxides; tin oxides; chromium oxides;
iron oxides; gold oxides; silver oxides; magnesium oxides; copper oxides; manganese oxides; aluminum oxides; cobalt oxides; barium ferrite; zinc ferrite;
magnesium ferrite; copper ferrite; silicon carbide; iron carbide and strontium ferrite.

13. A construction according to claim 8 wherein said mineral hydrate attenuator material includes at least one material selected from the group consisting of: zinc 1 phenol 4 sulfonate octahydrate;
thorium hypophosphate hydrate; magnesium chloroplatinate hexahydrate; thorium selenate hydrate; aluminum oxide tribydrate; zinc; zinc iodate dihydrate; thallium sulfate heptahydrate; sodium pyrophosphate hydrate;
potassium ruthenate hydrate; manganese chloride tetrahydrate; magnesium iodate tetrahydrate; magnesium bromate hexahydrate; magnesium antimonate hydrate;
dysprosium sulfate octahydrate; cobalt orthophosphate octahydrate; calcium ditartrate tetrahydrate; calcium chromate dihydrate; beryllium oxalate trihydrate;

magnesium sulfate heptahydrate; potassium sodium tartrate tetrahydrate; and, zinc sulfate heptahydrate.

14. A construction according to claim 1 wherein said mineral hydrate attenuator material includes:
(a) a first mineral hydrate attenuator having a temperature of dissociation at a first temperature; and, (b) a second mineral hydrate attenuator having a temperature of dissociation at a second temperature; said second temperature being different from said first temperature.

15. A construction according to claim 14 wherein:
(a) said first temperature is no greater than 500°F (260°C); and, (b) said second temperature is no greater than 500°F (260°C).

16. A construction according to claim 1 wherein:
(a) said backing is microwave transparent and comprises an organic sheet which is stable to heating up to at least about 400°F
(204°C);
(b) said microwave susceptor material comprises a dried dispersion of finely divided particles of at least a first kind and a second kind;
(i) said first kind of finely divided particles comprising said microwave active material; and, (ii) said second kind of finely divided particles comprising said mineral attenuator material and having a dissociation temperature at which bound water is released therefrom between about 100°F (38°C) and 500°F
(260°C).

17. A construction according to claim 16 wherein said mineral hydrate attenuator material includes:
(a) a first mineral hydrate attenuator having a temperature of dissociation at a first temperature; and, (b) a second mineral hydrate attenuator having a temperature of dissociation at a second temperature; said second temperature being different from said first temperature.

18. A construction according to claim 16 wherein:
(a) said backing comprises paper or paperboard;
(b) said dispersion comprises an acrylic resin binder; and, (c) said second kind of finely divided particles comprise aluminum oxide trihydrate.

19. A construction according to claim 18 wherein said aluminum oxide trihydrate comprises 20-30%, by weight, of said microwave susceptor material.

20. A construction according to claim 16 wherein said backing includes different amounts of microwave susceptor material in different areas thereof.

21. A construction according to claim 20 wherein said susceptor material is oriented on said backing in a pattern defining a first, central, region and a second, peripheral, region; said central region including a greater amount of susceptor material than said peripheral region.

22. A construction according to claim 1 wherein:
(a) said mineral hydrate attenuator is electrically nonconductive and has a dissociation temperature of between about 100°F and 500°F; and, (b) said mineral hydrate attenuator is retained within said microwave susceptor material by a binder.

23. A construction according to claim 22 wherein said mineral hydrate attenuator os suspended within a coating applied to said substrate.

24. A method of inhibiting overheating of a microwave interactive material upon exposure to microwave energy; said method including a step of:
(a) providing, in heat conductive relationship with the microwave interactive material, a binder film including mineral hydrate attenuator material containing bound water of hydration; the attenuator being provided in an amount sufficient to exhibit dissociation of the bound water, at a selected temperature upon absorption of heat from the microwave interactive susceptor material, to inhibit overheating.

25. A method of preparing a thermocompensating microwave susceptor construction; said method including the steps of:

(a) providing a liquid including:
(i) a binder;
(ii) an effective amount of microwave active particulate material;
(iii) an effective amount of mineral hydrate attenuator material exhibiting dissociation of water upon absorption of a selected amount of heat; and, (b) applying the liquid to a backing and drying same.

26. The method according to claim 25 wherein said liquid comprises an emulsion.

27. The method according to claim 25 wherein said liquid comprises a resin dispersion including resin selected from the group consisting of: acrylic resins;
maleic resins; and, mixtures thereof.

28. The method according to claim 25 wherein said step of applying the liquid to a backing comprises a step of printing a pattern on the substrate with the liquid.

29. A susceptor construction prepared according to the process of claim 25.

30. A susceptor construction prepared according to the process of claim 28.