CA2087181A1 - Group IVB, VB and VIB Metal Hydrocarbyloxides, with Alumoxane for Olefin Polymerization - Google Patents
Group IVB, VB and VIB Metal Hydrocarbyloxides, with Alumoxane for Olefin PolymerizationInfo
- Publication number
- CA2087181A1 CA2087181A1 CA2087181A CA2087181A CA2087181A1 CA 2087181 A1 CA2087181 A1 CA 2087181A1 CA 2087181 A CA2087181 A CA 2087181A CA 2087181 A CA2087181 A CA 2087181A CA 2087181 A1 CA2087181 A1 CA 2087181A1
- Authority
- CA
- Canada
- Prior art keywords
- alumoxane
- group ivb
- olefin polymerization
- vib metal
- hydrocarbyloxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
The invention is a catalyst system including a Group IVB, VB or VIB transition metal hydrocarbyloxide component and an alumoxane component which may be employed in liquid, slurry or bulk phase reactors to polymerize ethylene and .alpha.-olefins to produce a high molecular weight, narrow molecular weight distribution homo- and co-polymer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US553,485 | 1990-07-13 | ||
US07/553,485 US5079205A (en) | 1990-07-13 | 1990-07-13 | Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2087181A1 true CA2087181A1 (en) | 1992-01-14 |
CA2087181C CA2087181C (en) | 1998-07-07 |
Family
ID=24209576
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002087181A Expired - Fee Related CA2087181C (en) | 1990-07-13 | 1991-07-12 | Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization |
Country Status (5)
Country | Link |
---|---|
US (1) | US5079205A (en) |
EP (1) | EP0539446A1 (en) |
JP (1) | JP2678688B2 (en) |
CA (1) | CA2087181C (en) |
WO (1) | WO1992001006A1 (en) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5204304A (en) * | 1991-06-04 | 1993-04-20 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
CA2124187C (en) * | 1991-11-25 | 2001-08-07 | Howard William Turner | Polyonic transition metal catalyst composition |
ZA94612B (en) * | 1993-01-29 | 1995-07-28 | Dow Chemical Co | Ethylene interpolymerization |
US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
US5374597A (en) * | 1993-02-12 | 1994-12-20 | Quantum Chemical Corporation | Vanadium based olefin polymerization catalyst |
US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
US5523136A (en) * | 1993-04-30 | 1996-06-04 | Cypress Packaging | Packaging film, packages and methods for using them |
JP3349277B2 (en) * | 1994-07-26 | 2002-11-20 | 新日本石油株式会社 | Method for producing polyolefin |
US5792534A (en) | 1994-10-21 | 1998-08-11 | The Dow Chemical Company | Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
US5869575A (en) * | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
USRE38429E1 (en) * | 1996-03-12 | 2004-02-17 | Tyco Plastics Services Ag | Stretch wrap films |
US5814399A (en) * | 1996-03-12 | 1998-09-29 | Tenneco Packaging | Stretch wrap films |
US5749202A (en) * | 1996-03-12 | 1998-05-12 | Tenneco Packaging | Stretch wrap films |
US5998017A (en) * | 1996-03-12 | 1999-12-07 | Tenneco Packaging | Stretch wrap films |
US5902684A (en) * | 1996-03-12 | 1999-05-11 | Tenneco Packaging Inc. | Multilayered Metallocene stretch wrap films |
US5976682A (en) * | 1996-03-12 | 1999-11-02 | Tenneco Packaging | Stretch wrap films |
US5752362A (en) * | 1996-03-12 | 1998-05-19 | Tenneco Packaging | Stretch wrap films |
HU223533B1 (en) | 1996-06-17 | 2004-08-30 | Exxonmobil Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US6376035B1 (en) | 1996-12-05 | 2002-04-23 | Pactiv Corporation | Zipper fins for plastic bags |
US5851070A (en) * | 1996-12-05 | 1998-12-22 | Tenneco Packaging Inc. | Seals for plastic bags |
US5919535A (en) | 1996-12-05 | 1999-07-06 | Tenneco Packaging | Fins for plastic bags |
US5989725A (en) * | 1997-01-16 | 1999-11-23 | Tenneco Packaging | Clear high molecular weight film |
US6013378A (en) * | 1997-03-17 | 2000-01-11 | Tenneco Packaging | HMW HDPE film with improved impact strength |
US5889128A (en) * | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
US6093480A (en) * | 1997-05-21 | 2000-07-25 | Tenneco Packaging | Stretch wrap films |
US5907942A (en) * | 1997-05-21 | 1999-06-01 | Tenneco Packaging | Stretch wrap films |
US5907943A (en) * | 1997-06-11 | 1999-06-01 | Tenneco Packaging Inc. | Stretch wrap films |
US5922441A (en) * | 1997-06-11 | 1999-07-13 | Tenneco Packaging Inc. | Stretch wrap films |
US6083611A (en) * | 1997-11-12 | 2000-07-04 | Tenneco Packaging, Inc. | Roll wrap film |
US6749814B1 (en) | 1999-03-03 | 2004-06-15 | Symyx Technologies, Inc. | Chemical processing microsystems comprising parallel flow microreactors and methods for using same |
US6825296B2 (en) * | 2002-03-29 | 2004-11-30 | The University Of Hong Kong | Catalyst component for olefin polymerization |
KR100639696B1 (en) * | 2005-07-01 | 2006-10-30 | 에스케이 주식회사 | ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMERS OR ETHYLENE COPOLYMERS WITH alpha;-OLEFINS |
KR101060838B1 (en) * | 2006-04-24 | 2011-08-30 | 에스케이이노베이션 주식회사 | Bis-arylaryloxy catalyst system for preparing ethylene homopolymer or copolymer with α-olefin |
KR101146875B1 (en) * | 2006-11-01 | 2012-05-16 | 에스케이이노베이션 주식회사 | Transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and olefins using the same |
KR101151606B1 (en) * | 2007-12-31 | 2012-06-08 | 에스케이이노베이션 주식회사 | Transition metal complexes, catalysts composition containing the same, and process for preparing ethylene homopolymers or copolymers of ethylene and a-olefins using the same |
KR101186489B1 (en) | 2008-01-07 | 2012-09-27 | 에스케이이노베이션 주식회사 | Transition metal complexes, and catalysts compositions for preparing ethylnene homopolymers or copolymers |
KR101142115B1 (en) * | 2008-01-07 | 2012-07-06 | 에스케이이노베이션 주식회사 | Transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and -olefins using the same |
KR101142117B1 (en) * | 2008-09-25 | 2012-05-09 | 에스케이이노베이션 주식회사 | Transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and ?-olefins using the same |
KR101142122B1 (en) * | 2008-09-30 | 2012-05-09 | 에스케이이노베이션 주식회사 | New transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and ?-olefins using the same |
KR102300853B1 (en) | 2014-05-29 | 2021-09-13 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | New Transition metal complexes, catalyst compositions containing the same for olefin polymerization and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3367600D1 (en) * | 1982-07-12 | 1987-01-02 | Cities Service Co | Co-catalyst dispension method |
FR2546522B1 (en) * | 1983-05-25 | 1985-07-26 | Ato Chimie | PROCESS FOR THE PREPARATION OF A TRANSITIONAL METAL COMPONENT FOR A CATALYTIC SYSTEM FOR OLEFIN POLYMERIZATION |
JPS61141708A (en) * | 1984-12-14 | 1986-06-28 | Ube Ind Ltd | Polymerization of ethylene |
JPS6272631A (en) * | 1985-09-26 | 1987-04-03 | Mitsui Petrochem Ind Ltd | Oligomerization of alpha-olefin |
EP0241560B1 (en) * | 1985-10-11 | 1991-04-03 | Sumitomo Chemical Company, Limited | Catalyst for olefin polymerization and process for preparing olefin polymer by using the same |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
JPH0662703B2 (en) * | 1986-06-24 | 1994-08-17 | 出光興産株式会社 | Method for producing polyolefin |
US4774301A (en) * | 1987-06-08 | 1988-09-27 | The Dow Chemical Company | Zirconium containing catalysts and method of use |
JP2741890B2 (en) * | 1988-11-14 | 1998-04-22 | 三井化学株式会社 | Olefin polymerization catalyst and olefin polymerization method using the catalyst |
KR900009719A (en) * | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | New Ethylene-Propylene Copolymer |
US5068489A (en) * | 1989-12-28 | 1991-11-26 | Union Carbide Chemicals And Plastics Technology Corporation | Preparation of very low molecular weight polyethylene in a fluidized bed |
-
1990
- 1990-07-13 US US07/553,485 patent/US5079205A/en not_active Expired - Lifetime
-
1991
- 1991-07-12 WO PCT/US1991/004929 patent/WO1992001006A1/en not_active Application Discontinuation
- 1991-07-12 EP EP91913207A patent/EP0539446A1/en not_active Withdrawn
- 1991-07-12 CA CA002087181A patent/CA2087181C/en not_active Expired - Fee Related
- 1991-07-12 JP JP3512467A patent/JP2678688B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0539446A1 (en) | 1993-05-05 |
JP2678688B2 (en) | 1997-11-17 |
CA2087181C (en) | 1998-07-07 |
WO1992001006A1 (en) | 1992-01-23 |
JPH05507958A (en) | 1993-11-11 |
US5079205A (en) | 1992-01-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |