CA2087444A1 - Polymer mixture for producing films - Google Patents

Polymer mixture for producing films

Info

Publication number
CA2087444A1
CA2087444A1 CA002087444A CA2087444A CA2087444A1 CA 2087444 A1 CA2087444 A1 CA 2087444A1 CA 002087444 A CA002087444 A CA 002087444A CA 2087444 A CA2087444 A CA 2087444A CA 2087444 A1 CA2087444 A1 CA 2087444A1
Authority
CA
Canada
Prior art keywords
polymer mixture
starch
polyolefine
producing films
maleic anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002087444A
Other languages
French (fr)
Other versions
CA2087444C (en
Inventor
Ivan Tomka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BioTec Biologische Naturverpackungen GmbH and Co KG
Original Assignee
Ivan Tomka
Biotec Biologische Naturverpackungen Gmbh & Co. Kg
Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ivan Tomka, Biotec Biologische Naturverpackungen Gmbh & Co. Kg, Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg filed Critical Ivan Tomka
Publication of CA2087444A1 publication Critical patent/CA2087444A1/en
Application granted granted Critical
Publication of CA2087444C publication Critical patent/CA2087444C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/04Starch derivatives, e.g. crosslinked derivatives
    • C08L3/06Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869Acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

Abstract

In order to produce a polymer mixture essentially consisting of starch and a polyolefine, up to 70 wt % of thermoplastically processable starch is mixed with 10 to 40 wt % polyolefine and to 35 wt % ethylene acrylate maleic anhydride copolymer.
During this mixing process an esterification reaction takes place between the maleic anhydride groups in the copolymer with free hydroxyl groups in the starch according to the general reaction process (T).
CA002087444A 1991-05-18 1992-05-12 Polymer mixture for producing films Expired - Lifetime CA2087444C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4116404.0 1991-05-18
DE4116404A DE4116404A1 (en) 1991-05-18 1991-05-18 POLYMERMISCHUNG FOR THE MANUFACTURE OF FOILS
PCT/CH1992/000091 WO1992020740A1 (en) 1991-05-18 1992-05-12 Polymer mixture for producing foils

Publications (2)

Publication Number Publication Date
CA2087444A1 true CA2087444A1 (en) 1992-11-19
CA2087444C CA2087444C (en) 2005-11-29

Family

ID=6432013

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002087444A Expired - Lifetime CA2087444C (en) 1991-05-18 1992-05-12 Polymer mixture for producing films

Country Status (10)

Country Link
US (1) US5314934A (en)
EP (1) EP0539544B1 (en)
JP (1) JP3137198B2 (en)
AT (1) ATE113635T1 (en)
AU (1) AU1670592A (en)
CA (1) CA2087444C (en)
DE (2) DE4116404A1 (en)
HK (1) HK1006847A1 (en)
HU (1) HU211429B (en)
WO (1) WO1992020740A1 (en)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5321064A (en) * 1992-05-12 1994-06-14 Regents Of The University Of Minnesota Compositions of biodegradable natural and synthetic polymers
DE4237535C2 (en) * 1992-11-06 2000-05-25 Biotec Biolog Naturverpack Biodegradable polymer blend, process and film
US5844023A (en) 1992-11-06 1998-12-01 Bio-Tec Biologische Naturverpackungen Gmbh Biologically degradable polymer mixture
US5910520A (en) * 1993-01-15 1999-06-08 Mcneil-Ppc, Inc. Melt processable biodegradable compositions and articles made therefrom
US5403875A (en) * 1994-05-12 1995-04-04 Rohm And Haas Company Melt-processed polymer blends
EP0698883B1 (en) 1994-08-25 2000-06-14 topac MultimediaPrint GmbH Holder for a disc-like recording medium
US5883144A (en) 1994-09-19 1999-03-16 Sentinel Products Corp. Silane-grafted materials for solid and foam applications
KR980700469A (en) 1994-12-22 1998-03-30 뢰르크스 위프겐, 포메란쯔 반프리트 TECHNICAL AND NON-TECHNICAL TEXTILE PRODUCTS AND PACKAGING METERIALS
ATE242295T1 (en) 1995-04-07 2003-06-15 Biotec Biolog Naturverpack BIODEGRADABLE POLYMER BLEND
DE19536505A1 (en) * 1995-09-29 1997-04-10 Biotec Biolog Naturverpack Biodegradable filter material and process for its manufacture
US5861461A (en) * 1995-12-06 1999-01-19 Yukong Limited Biodegradable plastic composition, method for preparing thereof and product prepared therefrom
US6168857B1 (en) 1996-04-09 2001-01-02 E. Khashoggi Industries, Llc Compositions and methods for manufacturing starch-based compositions
DE19624641A1 (en) 1996-06-20 1998-01-08 Biotec Biolog Naturverpack Biodegradable material consisting essentially of or based on thermoplastic starch
US6221928B1 (en) 1996-11-15 2001-04-24 Sentinel Products Corp. Polymer articles including maleic anhydride
DE19750846C1 (en) 1997-11-17 2000-01-27 Biop Biopolymer Gmbh Process for the production of a component for the production of polymer mixtures based on starch
AU1070900A (en) * 1998-12-23 2000-07-31 Bayer Aktiengesellschaft Biodegradable polymer materials or ternary polymer mixtures on a polysaccharide or polysaccharide derivative basis
NZ503231A (en) 1999-03-08 2001-09-28 Humatro Corp Absorbent, flexible structure comprising pseudo-thermoplastic starch fibers, plasticizer (such as sorbitol, PVA)
US6231970B1 (en) 2000-01-11 2001-05-15 E. Khashoggi Industries, Llc Thermoplastic starch compositions incorporating a particulate filler component
US6573340B1 (en) 2000-08-23 2003-06-03 Biotec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials
US20030203196A1 (en) * 2000-11-27 2003-10-30 Trokhan Paul Dennis Flexible structure comprising starch filaments
US7029620B2 (en) 2000-11-27 2006-04-18 The Procter & Gamble Company Electro-spinning process for making starch filaments for flexible structure
US6811740B2 (en) 2000-11-27 2004-11-02 The Procter & Gamble Company Process for making non-thermoplastic starch fibers
DE10062848C1 (en) 2000-12-11 2002-04-04 Biop Biopolymer Gmbh Thermoplastic starch material, used for making moldings, films or fibrous raw materials and melt coating, is obtained by extruding natural starch in the presence of destructurization agent and storage for retrogradation
EP1229075B2 (en) 2001-02-01 2011-08-31 BIOP Biopolymer Technologies AG Process for producing a thermoplastic polymer composite based on starch containing integrated nanoscopic particles
US7241832B2 (en) * 2002-03-01 2007-07-10 bio-tec Biologische Naturverpackungen GmbH & Co., KG Biodegradable polymer blends for use in making films, sheets and other articles of manufacture
US7297394B2 (en) 2002-03-01 2007-11-20 Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable films and sheets suitable for use as coatings, wraps and packaging materials
US7276201B2 (en) * 2001-09-06 2007-10-02 The Procter & Gamble Company Process for making non-thermoplastic starch fibers
EP1295898A1 (en) * 2001-09-25 2003-03-26 Basell Polyolefine GmbH Process for preparing polymer additives and polyolefin compositions with improved paint adhesion
DE10214327A1 (en) * 2001-10-23 2003-05-22 Innogel Ag Zug Polysaccharide-based network and process for its manufacture
US6723160B2 (en) 2002-02-01 2004-04-20 The Procter & Gamble Company Non-thermoplastic starch fibers and starch composition for making same
DE10208858A1 (en) 2002-03-01 2003-09-11 Kalle Gmbh & Co Kg Smoke and water vapor permeable food casing made of a thermoplastic mixture
DE10258227A1 (en) * 2002-12-09 2004-07-15 Biop Biopolymer Technologies Ag Biodegradable multilayer film
US7172814B2 (en) * 2003-06-03 2007-02-06 Bio-Tec Biologische Naturverpackungen Gmbh & Co Fibrous sheets coated or impregnated with biodegradable polymers or polymers blends
US6977116B2 (en) * 2004-04-29 2005-12-20 The Procter & Gamble Company Polymeric structures and method for making same
US6955850B1 (en) * 2004-04-29 2005-10-18 The Procter & Gamble Company Polymeric structures and method for making same
GB0410388D0 (en) * 2004-05-11 2004-06-16 Adept Polymers Ltd An extrusion process
US7629405B2 (en) * 2004-11-19 2009-12-08 Board Of Trustees Of Michigan State University Starch-polyester biodegradable graft copolyers and a method of preparation thereof
US20090160095A1 (en) * 2004-11-19 2009-06-25 Board Of Trustees Of Michigan State University Biodegradable thermoplasticized starch-polyester reactive blends for thermoforming applications
US7989524B2 (en) * 2005-07-19 2011-08-02 The United States Of America, As Represented By The Secretary Of Agriculture Fiber-reinforced starch-based compositions and methods of manufacture and use
US20070021515A1 (en) * 2005-07-19 2007-01-25 United States (as represented by the Secretary of Agriculture) Expandable starch-based beads and method of manufacturing molded articles therefrom
US7909003B2 (en) 2006-08-07 2011-03-22 J. W. Pet Company, Inc. Chew toys comprising biologically degradable material
AR065041A1 (en) * 2007-01-26 2009-05-13 Du Pont COMPOSITION THAT INCLUDES A BIOPOLIMERO
FR2927087B1 (en) * 2008-02-01 2011-02-11 Roquette Freres SOLUBLE STARCH THERMOPLASTIC COMPOSITIONS AND PROCESS FOR PREPARING SUCH COMPOSITIONS.
FR2934272B1 (en) * 2008-07-24 2013-08-16 Roquette Freres PROCESS FOR THE PREPARATION OF COMPOSITIONS BASED ON AMYLACEOUS MATERIAL AND SYNTHETIC POLYMER
US8016980B2 (en) * 2008-11-25 2011-09-13 Dixie Consumer Products Llc Paper products
TW201121783A (en) * 2009-07-23 2011-07-01 Setec Pty Ltd Multilayer film
FR2955329B1 (en) * 2010-01-15 2013-02-01 Roquette Freres PROCESS FOR THE PREPARATION OF PLASTICIZED STARCH THERMOPLASTIC COMPOSITIONS AND COMPOSITIONS
BR112013012342A2 (en) 2010-11-23 2019-09-24 Procter & Gamble thermoplastic starch compositions
US20120178858A1 (en) 2011-01-10 2012-07-12 Andrew Julian Wnuk Isosorbide-Plasticized Starch And Uses Thereof
EP2710072A1 (en) 2011-05-20 2014-03-26 The Procter and Gamble Company Molded articles of starch-polymer-wax-oil compositions
MX2013013588A (en) 2011-05-20 2014-01-08 Procter & Gamble Films of starch-polymer-wax-oil compositions.
RU2013156459A (en) 2011-05-20 2015-06-27 Дзе Проктер Энд Гэмбл Компани COMPOSITIONS CONTAINING STARCH, POLYMER AND OIL, METHODS FOR PRODUCING AND USING THEREOF
MX2013013516A (en) 2011-05-20 2014-02-27 Procter & Gamble Fiber of starch- polymer -oil compositions.
FR2993275B1 (en) * 2012-07-13 2014-08-01 Roquette Freres STARCH-BASED THERMOPLASTIC COMPOSITION COMPRISING A FUNCTIONAL COMPOUND GROWTH COPOLYMER
US20140142225A1 (en) 2012-11-20 2014-05-22 The Procter & Gamble Company Starch-Thermoplastic Polymer-Soap Compositions and Methods of Making and Using the Same
EP2922912A1 (en) 2012-11-20 2015-09-30 The Procter & Gamble Company Starch-thermoplastic polymer-grease compositions and methods of making and using the same
US20140272370A1 (en) 2013-03-15 2014-09-18 The Procter & Gamble Company Renewable Thermoplastic Starch-Polyolefin Compositions Comprising Compatibilizer and Flexible Thin Films Made Therefrom
EP2799231A1 (en) 2013-04-30 2014-11-05 The Procter & Gamble Company Flexible package
EP2799232A1 (en) 2013-04-30 2014-11-05 The Procter & Gamble Company Flexible package
EP2999447B1 (en) 2013-05-20 2019-10-23 The Procter and Gamble Company Nonwoven webs with visually distinct bond sites and method of making
US9464188B2 (en) 2013-08-30 2016-10-11 Kimberly-Clark Worldwide, Inc. Simultaneous plasticization and compatibilization process and compositions
WO2015066588A1 (en) 2013-11-04 2015-05-07 The Procter & Gamble Company Thermoplastic polymer compositions having co-continuous plate-like morphology
JP2017517598A (en) 2014-05-12 2017-06-29 ザ プロクター アンド ギャンブル カンパニー Film with fine texture with improved tactile feel and / or reduced noise perception
US10752759B2 (en) 2015-06-30 2020-08-25 BiologiQ, Inc. Methods for forming blended films including renewable carbohydrate-based polymeric materials with high blow up ratios and/or narrow die gaps for increased strength
US11879058B2 (en) 2015-06-30 2024-01-23 Biologiq, Inc Yarn materials and fibers including starch-based polymeric materials
US11674018B2 (en) 2015-06-30 2023-06-13 BiologiQ, Inc. Polymer and carbohydrate-based polymeric material blends with particular particle size characteristics
US20170002184A1 (en) 2015-06-30 2017-01-05 BiologiQ, Inc. Articles Formed with Biodegradable Materials and Strength Characteristics of Same
US11926940B2 (en) 2015-06-30 2024-03-12 BiologiQ, Inc. Spunbond nonwoven materials and fibers including starch-based polymeric materials
US11926929B2 (en) 2015-06-30 2024-03-12 Biologiq, Inc Melt blown nonwoven materials and fibers including starch-based polymeric materials
US11111355B2 (en) 2015-06-30 2021-09-07 BiologiQ, Inc. Addition of biodegradability lending additives to plastic materials
US10920044B2 (en) 2015-06-30 2021-02-16 BiologiQ, Inc. Carbohydrate-based plastic materials with reduced odor
US10919203B2 (en) 2015-06-30 2021-02-16 BiologiQ, Inc. Articles formed with biodegradable materials and biodegradability characteristics thereof
US11149144B2 (en) 2015-06-30 2021-10-19 BiologiQ, Inc. Marine biodegradable plastics comprising a blend of polyester and a carbohydrate-based polymeric material
US10995201B2 (en) 2015-06-30 2021-05-04 BiologiQ, Inc. Articles formed with biodegradable materials and strength characteristics of the same
US11046840B2 (en) 2015-06-30 2021-06-29 BiologiQ, Inc. Methods for lending biodegradability to non-biodegradable plastic materials
US11674014B2 (en) 2015-06-30 2023-06-13 BiologiQ, Inc. Blending of small particle starch powder with synthetic polymers for increased strength and other properties
US11111363B2 (en) 2015-06-30 2021-09-07 BiologiQ, Inc. Articles formed with renewable and/or sustainable green plastic material and carbohydrate-based polymeric materials lending increased strength and/or biodegradability
US11359088B2 (en) 2015-06-30 2022-06-14 BiologiQ, Inc. Polymeric articles comprising blends of PBAT, PLA and a carbohydrate-based polymeric material
US20210100260A1 (en) 2017-04-06 2021-04-08 Cryovac, Llc Film, package and method for cheese ripening and preservation
EP3466385B1 (en) 2017-10-06 2020-05-27 The Procter & Gamble Company Absorbent article or wipe comprising a nonwoven material with bicomponent fibers comprising antimony-free polyethylene terephthalate
EP3466389B1 (en) 2017-10-06 2020-05-20 The Procter & Gamble Company Absorbent article comprising a carded resin-bonded nonwoven web with fibers comprising antimony-free polyethylene terephthalate
EP3466388B1 (en) 2017-10-06 2020-05-20 The Procter & Gamble Company Absorbent article comprising a nonwoven material with antimony-free polyethylene terephthalate
JP7253331B2 (en) * 2018-06-05 2023-04-06 日泉ポリテック株式会社 Molded sheet of thermoplastic starch/olefin resin composition and method for producing same
EP4076719A1 (en) 2019-12-20 2022-10-26 Crystaphase Products Inc. Resaturation of gas into a liquid feedstream

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2676929A (en) * 1951-08-23 1954-04-27 Electric Storage Battery Co Stock material for microporous articles and methods of making the same from starch and polyethylene
US3719664A (en) * 1971-10-27 1973-03-06 Staley Mfg Co A E Warp sizing agent
US4133784A (en) * 1977-09-28 1979-01-09 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable film compositions prepared from starch and copolymers of ethylene and acrylic acid
JPS55157643A (en) * 1979-05-28 1980-12-08 Nichiden Kagaku Kk Polymer composition
US4524164A (en) * 1983-12-02 1985-06-18 Chemical Process Corporation Thermosetting adhesive resins
AU4078089A (en) * 1988-08-23 1990-03-23 Peter John Whiteley Decorative glass
IE66735B1 (en) * 1988-11-03 1996-02-07 Biotec Biolog Naturverpack Thermoplastically workable starch and a method for the manufacture thereof
IL93620A0 (en) * 1989-03-09 1990-12-23 Butterfly Srl Biodegradable articles based on starch and process for producing them
FR2644792B1 (en) * 1989-03-24 1992-08-14 Inst Francais Du Petrole MIXTURES OF THERMOPLASTIC POLYMERS WITH REDUCED HYDROCARBON PERMEABILITY
US5162392A (en) * 1989-05-19 1992-11-10 Agri-Tech Industries, Inc. Injection moldable biodegradable starch polymer composite
US5026745A (en) * 1989-06-12 1991-06-25 Aristech Chemical Corporation Biodeteriable plastics and blends
DE3919659A1 (en) * 1989-06-16 1990-12-20 Basf Ag METHOD FOR PRODUCING ETHYLENE COPOLYMERS FILLED WITH NON-FIBERED CARBOHYDRATES AND THE USE THEREOF
IL94587A (en) * 1989-06-19 1997-04-15 Novon International Polymer base blend compositions containing destructurized starch
IL94588A0 (en) * 1989-06-22 1991-04-15 Warner Lambert Co Polymer base blend compositions containing destructurized starch
IL94647A0 (en) * 1989-07-06 1991-04-15 Warner Lambert Co Polymer base blend compositions containing destructurized starch
PT94594B (en) * 1989-07-11 1997-02-28 Warner Lambert Co PROCESS FOR THE PREPARATION OF COMPOSITIONS OF POLYMERIC BASE MIXTURES CONTAINING DESERATED FROST
YU129090A (en) * 1989-07-11 1992-12-21 Warner-Lambert Company PREPARATIONS OF POLYMER MIXTURES CONTAINING DESTRUCTURED STARCH
YU128990A (en) * 1989-07-11 1993-05-28 Warner-Lambert Co. PREPARATIONS OF POLYMER MIXTURES CONTAINING DESTRUCTURED STARCH
KR910002990A (en) * 1989-07-18 1991-02-26 토마스 디. 몰리터노 Polymer Based Mixing Composition Containing Degraded Starch
PL286007A1 (en) * 1989-07-18 1991-03-11 Warner Lambert Co Polymer mixture, method for manufacturing a thermoplastic product and a method for manufacturing a thermoplastic alloy
FI102480B1 (en) * 1989-07-18 1998-12-15 Warner Lambert Co Polymer-based blend compositions containing modified starch
JPH0725944B2 (en) * 1989-07-20 1995-03-22 ワーナー・ランバート・カンパニー Polymer-based blend composition containing modified starch
IT1232909B (en) * 1989-08-07 1992-03-05 Butterfly Srl POLYMERIC COMPOSITION FOR THE PRODUCTION OF BIODEGRADABLE PLASTIC ITEMS INCLUDING DESTRUCTURED STARCH AND ETHYLENE COPOLYMER
NL8902321A (en) * 1989-09-15 1991-04-02 Cargill Bv MATERIAL CONTAINING A POLYMER OF UNSATURATED HYDROCARBON AND A STARCH DERIVATIVE.
US5087650A (en) * 1990-12-05 1992-02-11 Fully Compounded Plastics, Inc. Biodegradable plastics

Also Published As

Publication number Publication date
EP0539544B1 (en) 1994-11-02
EP0539544A1 (en) 1993-05-05
HU9300119D0 (en) 1993-04-28
ATE113635T1 (en) 1994-11-15
DE4116404A1 (en) 1992-11-19
HUT68437A (en) 1995-06-28
WO1992020740A1 (en) 1992-11-26
DE59200729D1 (en) 1994-12-08
HK1006847A1 (en) 1999-03-19
JPH06500149A (en) 1994-01-06
CA2087444C (en) 2005-11-29
AU1670592A (en) 1992-12-30
JP3137198B2 (en) 2001-02-19
US5314934A (en) 1994-05-24
HU211429B (en) 1995-11-28

Similar Documents

Publication Publication Date Title
CA2087444A1 (en) Polymer mixture for producing films
AU627797B2 (en) Ambient temperature curing polymer compositions
EP1033385A3 (en) Method of producing a shaped article from a cellulose solution
CA2036693A1 (en) Cold-stretched products comprising a propylene-based resin composition and process for producing the same
EP0144681A3 (en) Process for the preparation of polymeric compositions
CA2038931A1 (en) Polymer composition including destructured starch and an ethylene copolymer
CA2109657A1 (en) A biodegradable polyethylene composition chemically bonded with starch and a process for preparing thereof
IE820158L (en) Polymer of ethylene
CA2132721A1 (en) Biodegradable compositions produced by reactive blending of synthetic and naturally occurring polymers
GB1455475A (en) Water-swellable polymer products and their preparation
GB1408141A (en) Polymeric compositions
EP0796873A4 (en) (meth)acrylic syrup, process for preparing the same, and process for preparing molding material containing (meth)acrylic syrup
GB1430560A (en) Powder coating composition
CA2177594A1 (en) Process for the preparation of water-dilutable coating binders based on acrylate copolymers, and their use
CA2085917A1 (en) A process for preparing thermoplastic resin composition with excellent hcfc resistance
CA2177613A1 (en) Process for the preparation of water-dilutable coating binders, and the use thereof
ZA892445B (en) Crosslinked polymer compositions,a process for their production and moulded articles obtained
CA2099750A1 (en) Process for Producing Polymer Blends
ES488892A1 (en) Process for the preparation of copolymers and their utilisation.
JPS57128711A (en) Resin solution for magnetic coating material
CA2062194A1 (en) Self-crosslinkable resin
JPS5513718A (en) Novel resin composition
JPS57164114A (en) Low-shrinkage unsaturated polyester resin composition
GB1496600A (en) Sheet moulding compounds
CA2055904A1 (en) Resin composition

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
MKEC Expiry (correction)

Effective date: 20121202