CA2093412A1 - Novel hydroconversion process employing catalyst with specified pore size distribution - Google Patents

Novel hydroconversion process employing catalyst with specified pore size distribution

Info

Publication number
CA2093412A1
CA2093412A1 CA002093412A CA2093412A CA2093412A1 CA 2093412 A1 CA2093412 A1 CA 2093412A1 CA 002093412 A CA002093412 A CA 002093412A CA 2093412 A CA2093412 A CA 2093412A CA 2093412 A1 CA2093412 A1 CA 2093412A1
Authority
CA
Canada
Prior art keywords
tpv
ang
novel
size distribution
pore size
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002093412A
Other languages
French (fr)
Other versions
CA2093412C (en
Inventor
Gerald Verdell Nelson
Govanon Nongbri
Roy Earl Pratt
David Edward Sherwood, Jr.
Pei-Shing Eugene Dai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/870,970 external-priority patent/US5399259A/en
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of CA2093412A1 publication Critical patent/CA2093412A1/en
Application granted granted Critical
Publication of CA2093412C publication Critical patent/CA2093412C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B01J35/615—
    • B01J35/635—
    • B01J35/66—
    • B01J35/69—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina

Abstract

Heavy hydrocarbons are hydrotreated to increase content of components boiling below 1000°F by contact with Group VIII non-noble metal oxide and Group VI-B metal oxide on alumina having a Total Surface Area of 150-240 m2/g, a Total Pore Volume, (TPV) of 0.7-0.98, and a Pore Diameter Distribution whereby <= 20 0 of the TPV is present as primary micropores of diameter <= 100.ANG., at least about 34% of TPV is present as secondary micropores of diameter of about 100.ANG.-200.ANG., and about 26%-46% of the TPV is present as mesopores of diameter >= 200.ANG..
CA 2093412 1992-04-20 1993-04-05 Novel hydroconversion process employing catalyst with specified pore size distribution Expired - Lifetime CA2093412C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/870,970 US5399259A (en) 1992-04-20 1992-04-20 Hydroconversion process employing catalyst with specified pore size distribution
US870,970 1992-04-20
US95317692A 1992-09-29 1992-09-29
US07/953,176 1992-09-29

Publications (2)

Publication Number Publication Date
CA2093412A1 true CA2093412A1 (en) 1993-10-21
CA2093412C CA2093412C (en) 2002-12-31

Family

ID=27128179

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2093412 Expired - Lifetime CA2093412C (en) 1992-04-20 1993-04-05 Novel hydroconversion process employing catalyst with specified pore size distribution

Country Status (2)

Country Link
US (2) US5435908A (en)
CA (1) CA2093412C (en)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5868923A (en) * 1991-05-02 1999-02-09 Texaco Inc Hydroconversion process
US5827421A (en) * 1992-04-20 1998-10-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution and no added silica
US5928499A (en) * 1993-10-01 1999-07-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume
US6015485A (en) * 1994-05-13 2000-01-18 Cytec Technology Corporation High activity catalysts having a bimodal mesopore structure
US5968348A (en) * 1994-05-16 1999-10-19 Texaco Inc. Hydroconversion process employing a phosphorus loaded NiMo catalyst with specified pore size distribution
US5817594A (en) * 1994-11-03 1998-10-06 Shell Oil Company Catalyst and hydrotreating process
AU1959997A (en) * 1996-02-14 1997-09-02 Texaco Development Corporation Low pressure process for the hydroconversion of heavy hydrocarbo ns
US6387248B2 (en) * 1997-11-06 2002-05-14 Texaco Inc. Method of preparing a catalyst for use in the hydrotreating of high boiling hydrocarbon feedstocks
GC0000065A (en) 1998-09-01 2004-06-30 Japan Energy Corp Hydrocracking catalyst, producing method threof, and hydrocracking method.
CA2320485C (en) † 1998-12-08 2005-02-08 Japan Energy Corporation Catalyst for hydrofining and method for preparation thereof
JP4303820B2 (en) * 1999-01-26 2009-07-29 日本ケッチェン株式会社 Hydrotreating catalyst and hydrotreating method
US6933409B1 (en) 1999-05-13 2005-08-23 Symyx Technologies, Inc. Amination of aromatic hydrocarbons and heterocyclic analogs thereof
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
WO2001026805A1 (en) * 1999-10-14 2001-04-19 China Petrochemical Corporation Catalyst for hydrorefining distillate oil, its carrier and preparation thereof
US6239066B1 (en) * 1999-11-04 2001-05-29 Shell Oil Company Process for forming high activity catalysts
IT1317868B1 (en) 2000-03-02 2003-07-15 Eni Spa SUPPORTED COBALT CATALYST, PARTICULARLY USEFUL IN THE REACTION OF FISCHER-TROPSCH.
DE60120692T2 (en) * 2000-05-19 2006-10-19 Johnson Matthey Plc CATALYSTS WITH HIGH COBAL SURFACE
US6508999B1 (en) 2000-11-21 2003-01-21 Shell Oil Company Aluminum trihydroxide phase
US6589908B1 (en) 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
JP4638610B2 (en) * 2001-01-05 2011-02-23 日本ケッチェン株式会社 Hydrotreating catalyst and hydrotreating method
KR100398058B1 (en) * 2001-05-18 2003-09-19 주식회사 경동도시가스 Modified θ-alumina-supported nickel reforming catalysts and its use for producing synthesis gas from natural gas
JP3786007B2 (en) * 2001-05-29 2006-06-14 住友金属鉱山株式会社 Catalyst for hydrotreating aromatic compounds in hydrocarbon oils
JP4612229B2 (en) * 2001-06-08 2011-01-12 日本ケッチェン株式会社 Catalyst for hydrotreating heavy hydrocarbon oil and hydrotreating method
US6897175B2 (en) * 2001-10-09 2005-05-24 General Electric Catalyst and method for the alkylation of hydroxyaromatic compounds
US6799615B2 (en) * 2002-02-26 2004-10-05 Leslie G. Smith Tenon maker
FR2839902B1 (en) * 2002-05-24 2007-06-29 Inst Francais Du Petrole HYDROREFINING AND / OR HYDROCONVERSION CATALYST AND USE THEREOF IN HYDROCARBON CHARGING HYDROCARBON PROCESSES
US6676606B2 (en) * 2002-06-11 2004-01-13 Koninklijke Philips Electronics N.V. Ultrasonic diagnostic micro-vascular imaging
US7074740B2 (en) * 2002-07-02 2006-07-11 Chevron U.S.A. Inc. Catalyst for conversion processes
US6958309B2 (en) * 2002-08-01 2005-10-25 Conocophillips Company Hydrothermal pretreatment for increasing average pore size in a catalyst support
US7390766B1 (en) * 2003-11-20 2008-06-24 Klein Darryl P Hydroconversion catalysts and methods of making and using same
US20050109674A1 (en) * 2003-11-20 2005-05-26 Advanced Refining Technologies Llc Hydroconversion catalysts and methods of making and using same
EP1753844B1 (en) * 2004-04-28 2016-06-08 Headwaters Heavy Oil, LLC Hydroprocessing method and system for upgrading heavy oil
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
BRPI0510346A (en) * 2004-04-28 2007-10-30 Headwaters Heavy Oil Llc fixed bed hydroprocessing methods and systems for upgrading an existing fixed bed system
MXPA06012528A (en) 2004-04-28 2007-08-02 Headwaters Heavy Oil Llc Ebullated bed hydroprocessing methods and systems and methods of upgrading an existing ebullated bed system.
FR2887557B1 (en) * 2005-06-23 2012-11-02 Inst Francais Du Petrole INTEGRATED ENCHARING OF EXTRACTION AND TREATMENT PROCESSES OF EXTRA HEAVY OR BITUMINOUS BRUT
MXPA05012893A (en) * 2005-11-29 2007-11-23 Mexicano Inst Petrol Catalyst for the hydrodesulfurization of residues and heavy crudes.
PL1960101T3 (en) 2005-12-14 2015-02-27 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
DE102007011471B4 (en) * 2006-03-09 2021-09-30 Shell Internationale Research Maatschappij B.V. Catalyst combination for the hydrogenating processing of vacuum gas oils and / or visbreaker gas oils
CN101332433B (en) * 2007-06-27 2011-07-20 中国石油化工股份有限公司 Catalytic cracking catalyst, preparation method and use thereof
MX2007009504A (en) * 2007-08-07 2009-02-06 Mexicano Inst Petrol Catalyst for the first stage of hydro demetallization in a hydro processing system with multiple reactors for the improvement of heavy and extra-heavy crudes.
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US8575063B2 (en) * 2008-10-27 2013-11-05 Hongying He Nickel-based reforming catalysts
US8372268B2 (en) * 2009-03-24 2013-02-12 Shell Oil Company High surface area composition for use in the catalytic hydroconversion of a heavy hydrocarbon feedstock, a method making such composition and its use
KR101841689B1 (en) * 2009-10-30 2018-03-29 삼성전자주식회사 Mesoporous complex catalyst and process for preparing the same
JP5805761B2 (en) * 2010-08-13 2015-11-04 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Hydrotreating catalyst produced from waste catalyst fine powder and use thereof
CN103052445B (en) * 2010-08-13 2015-09-16 国际壳牌研究有限公司 Can be used for composition containing chelating agent and polar additive in hydrocarbon feed hydrotreatment and production and preparation method thereof
KR101917198B1 (en) 2010-12-20 2019-01-24 셰브런 유.에스.에이.인크. Hydroprocessing catalysts and methods for making thereof
PL2750792T3 (en) 2011-09-01 2022-01-31 Advanced Refining Technologies, Llc Catalyst support and catalysts prepared therefrom
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
TWI579043B (en) * 2012-02-17 2017-04-21 先進精鍊科技有限公司 Spheroidal catalyst support and preparation method thereof
TWI611836B (en) * 2012-02-17 2018-01-21 Advanced Refining Technologies Llc. Catalyst support and preparation method thereof
TWI594795B (en) 2012-05-21 2017-08-11 蜆殼國際研究所 Improved catalyst and process for hydroconversion of a heavy feedstock
TWI632235B (en) 2012-06-20 2018-08-11 美商先進精鍊科技有限公司 Catalyst for hydrodesulfurization of residuum hydrocarbon feedstocks and preparaton method thereof
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US10220379B2 (en) * 2014-05-01 2019-03-05 Shell Oil Company Catalyst and its use for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US9956553B2 (en) 2016-06-28 2018-05-01 Chevron U.S.A. Inc. Regeneration of an ionic liquid catalyst by hydrogenation using a macroporous noble metal catalyst
US11118119B2 (en) 2017-03-02 2021-09-14 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with less fouling sediment
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
US11318448B2 (en) 2018-01-31 2022-05-03 Advanced Refining Technologies Llc Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds
CA3057131A1 (en) 2018-10-17 2020-04-17 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993598A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3993599A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3989645A (en) * 1974-02-07 1976-11-02 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US4082695A (en) * 1975-01-20 1978-04-04 Mobil Oil Corporation Catalyst for residua demetalation and desulfurization
US4069139A (en) * 1975-12-29 1978-01-17 Exxon Research & Engineering Co. Hydrodesulfurization of oil utilizing a narrow pore size distribution catalyst
US4066572A (en) * 1976-10-12 1978-01-03 Nalco Chemical Company Phospha-alumina gel and method of preparation
US4225421A (en) * 1979-03-13 1980-09-30 Standard Oil Company (Indiana) Process for hydrotreating heavy hydrocarbons
US4357263A (en) * 1979-10-22 1982-11-02 Mobil Oil Corporation Catalyst for the upgrading of aromatic liquids
FR2486094B1 (en) * 1980-07-02 1985-03-22 Catalyse Soc Prod Francais
US4549957A (en) * 1981-06-17 1985-10-29 Amoco Corporation Hydrotreating catalyst and process
US4548709A (en) * 1983-04-29 1985-10-22 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with dual pore size distribution alumina catalyst
US4588709A (en) * 1983-12-19 1986-05-13 Intevep, S.A. Catalyst for removing sulfur and metal contaminants from heavy crudes and residues
US4642179A (en) * 1983-12-19 1987-02-10 Intevep, S.A. Catalyst for removing sulfur and metal contaminants from heavy crudes and residues
FR2570385B1 (en) * 1984-09-14 1987-08-21 Raffinage Cie Francaise PROCESS FOR HYDROPROCESSING HYDROCARBON CHARGES AND CATALYST FOR CARRYING OUT SAID METHOD
US4941964A (en) * 1988-03-14 1990-07-17 Texaco Inc. Hydrotreatment process employing catalyst with specified pore size distribution
US5094994A (en) * 1988-05-13 1992-03-10 Texaco Inc. Catalyst composition for hydroprocessing petroleum feedstocks
US5047142A (en) * 1988-05-13 1991-09-10 Texaco Inc. Catalyst composition and method for hydroprocessing petroleum feedstocks
JP2631712B2 (en) * 1988-08-18 1997-07-16 コスモ石油株式会社 Catalyst composition for hydrotreating heavy hydrocarbon oil and hydrotreating method using the same
US5266300A (en) * 1989-08-02 1993-11-30 Texaco Inc. Method of making porous alumina
US5215955A (en) * 1991-10-02 1993-06-01 Chevron Research And Technology Company Resid catalyst with high metals capacity

Also Published As

Publication number Publication date
US5545602A (en) 1996-08-13
US5435908A (en) 1995-07-25
CA2093412C (en) 2002-12-31

Similar Documents

Publication Publication Date Title
CA2093412A1 (en) Novel hydroconversion process employing catalyst with specified pore size distribution
AU4411589A (en) Hydrodemetalation and hydrodesulfurization using a catalyst of specified macroporosity
CA2158594A1 (en) Hydroprocessing catalyst and use thereof
CA2007317A1 (en) Polymer hydrogenation catalysts
CA2093410A1 (en) Improved hydroconversion process employing catalyst with specified pore size distribution
DE69317617D1 (en) Hydroconversion process
EP0228270A3 (en) Catalysts comprising silica supported on a boehmite-like surface, their preparation and use
ES8704756A1 (en) Nickel/alumina catalyst, its preparation and use.
DK0582347T3 (en)
CA2360121A1 (en) Hydroprocessing catalyst and use thereof
ATE232231T1 (en) HYDROCONVERSION PROCESS USING A CATALYST CONTAINING PHOSPHORUS WITH SPECIFIC PORE SIZE DISTRIBUTION
CA2162017A1 (en) Catalyst and hydrotreating process
AU2588001A (en) A thermally stable, high surface area, modified mesoporous alluminophosphate
DK1392431T3 (en) Hydro treatment catalyst with high content of macropores and their use
CA2081130A1 (en) Hydroprocessing catalyst composition
CA2170883A1 (en) An olefin polymerization or copolymerization catalyst
CA2113897A1 (en) Hydroprocessing catalyst
CA2258563A1 (en) A hydrofining catalyst of a distillate oil and production method
EP0237240A3 (en) Process for the production of hydrogenating catalysts
AU2567688A (en) Process for the preparation of hydrotreating catalysts from hydrogels
GR3002130T3 (en) High macropore selective hydrogenation catalyst
JPS57205484A (en) Converting heavy hydrocarbon oil to light hydrocarbon oil
CA2113896A1 (en) Production of hydrocracked lubricants
JPS6447449A (en) Hydrocarbon converting catalyst
JPS57102235A (en) Catalyst for modification of heavy-duty hydrocarbon oil

Legal Events

Date Code Title Description
EEER Examination request