CA2095449A1 - Supersaturated Rare Earth Doped Semiconductor Layers by Chemical Vapor Deposition - Google Patents

Supersaturated Rare Earth Doped Semiconductor Layers by Chemical Vapor Deposition

Info

Publication number
CA2095449A1
CA2095449A1 CA2095449A CA2095449A CA2095449A1 CA 2095449 A1 CA2095449 A1 CA 2095449A1 CA 2095449 A CA2095449 A CA 2095449A CA 2095449 A CA2095449 A CA 2095449A CA 2095449 A1 CA2095449 A1 CA 2095449A1
Authority
CA
Canada
Prior art keywords
rare earth
supersaturated
erbium
semiconductor layers
doped semiconductor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2095449A
Other languages
French (fr)
Other versions
CA2095449C (en
Inventor
David B. Beach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Business Machines Corp
Original Assignee
International Business Machines Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Business Machines Corp filed Critical International Business Machines Corp
Publication of CA2095449A1 publication Critical patent/CA2095449A1/en
Application granted granted Critical
Publication of CA2095449C publication Critical patent/CA2095449C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264—Inorganic materials
    • H01L31/028—Inorganic materials including, apart from doping material or other impurities, only elements of Group IV of the Periodic System
    • H01L31/0288—Inorganic materials including, apart from doping material or other impurities, only elements of Group IV of the Periodic System characterised by the doping material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/223—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02365—Forming inorganic semiconducting materials on a substrate
    • H01L21/02367—Substrates
    • H01L21/0237—Materials
    • H01L21/02373—Group 14 semiconducting materials
    • H01L21/02381—Silicon, silicon germanium, germanium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02365—Forming inorganic semiconducting materials on a substrate
    • H01L21/02518—Deposited layers
    • H01L21/02521—Materials
    • H01L21/02524—Group 14 semiconducting materials
    • H01L21/02532—Silicon, silicon germanium, germanium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02365—Forming inorganic semiconducting materials on a substrate
    • H01L21/02518—Deposited layers
    • H01L21/0257—Doping during depositing
    • H01L21/02573—Conductivity type
    • H01L21/02581—Transition metal or rare earth elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02365—Forming inorganic semiconducting materials on a substrate
    • H01L21/02612—Formation types
    • H01L21/02617—Deposition types
    • H01L21/0262—Reduction or decomposition of gaseous compounds, e.g. CVD
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
    • H01L21/205—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy using reduction or decomposition of a gaseous compound yielding a solid condensate, i.e. chemical deposition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S252/00—Compositions
    • Y10S252/95—Doping agent source material
    • Y10S252/951—Doping agent source material for vapor transport
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S438/00—Semiconductor device manufacturing: process
    • Y10S438/914—Doping
    • Y10S438/918—Special or nonstandard dopant

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Electromagnetism (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Vapour Deposition (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

A CVD process for producing a rare earth-doped, epitaxial semiconductor layer on a substrate is disclosed. The process utilizes a silane or germane and a rare earth compound in the gas phase. By this method single phase, rare earth-doped semiconductor layers, supersaturated in the rare earth, are produced. The preferred rare earth is erbium and the preferred precursors for depositing erbium by CVD are erbium hexafluoroacetylacetonate, acetylacetonate, tetramethylheptanedionate and flurooctanedionate. The process may be used to produce optoelectronic devices comprising a silicon substrate and an erbium-doped epitaxial silicon film.
CA002095449A 1992-08-31 1993-05-04 Supersaturated rare earth doped semiconductor layers by chemical vapor deposition Expired - Fee Related CA2095449C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/940,416 US5322813A (en) 1992-08-31 1992-08-31 Method of making supersaturated rare earth doped semiconductor layers by chemical vapor deposition
US940,416 1992-08-31

Publications (2)

Publication Number Publication Date
CA2095449A1 true CA2095449A1 (en) 1994-03-01
CA2095449C CA2095449C (en) 1997-09-16

Family

ID=25474795

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002095449A Expired - Fee Related CA2095449C (en) 1992-08-31 1993-05-04 Supersaturated rare earth doped semiconductor layers by chemical vapor deposition

Country Status (11)

Country Link
US (3) US5322813A (en)
EP (1) EP0586321B1 (en)
JP (1) JPH0785467B2 (en)
KR (1) KR970008339B1 (en)
CN (3) CN1054234C (en)
AT (1) ATE166491T1 (en)
CA (1) CA2095449C (en)
DE (1) DE69318653T2 (en)
ES (1) ES2116426T3 (en)
MX (1) MX9305267A (en)
TW (1) TW229325B (en)

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EP0650200B1 (en) * 1993-10-20 1999-03-10 Consorzio per la Ricerca sulla Microelettronica nel Mezzogiorno Solid state electro-luminescent device and process for fabrication thereof
US6093246A (en) * 1995-09-08 2000-07-25 Sandia Corporation Photonic crystal devices formed by a charged-particle beam
US5976941A (en) * 1997-06-06 1999-11-02 The Whitaker Corporation Ultrahigh vacuum deposition of silicon (Si-Ge) on HMIC substrates
US6040225A (en) * 1997-08-29 2000-03-21 The Whitaker Corporation Method of fabricating polysilicon based resistors in Si-Ge heterojunction devices
US6130471A (en) * 1997-08-29 2000-10-10 The Whitaker Corporation Ballasting of high power silicon-germanium heterojunction biploar transistors
KR100377716B1 (en) * 1998-02-25 2003-03-26 인터내셔널 비지네스 머신즈 코포레이션 Electric pumping of rare-earth-doped silicon for optical emission
US6307625B1 (en) 1998-06-29 2001-10-23 San Diego State University Method and apparatus for determination of carbon-halogen compounds and applications thereof
US6140669A (en) * 1999-02-20 2000-10-31 Ohio University Gallium nitride doped with rare earth ions and method and structure for achieving visible light emission
US6143072A (en) * 1999-04-06 2000-11-07 Ut-Battelle, Llc Generic process for preparing a crystalline oxide upon a group IV semiconductor substrate
US6255669B1 (en) * 1999-04-23 2001-07-03 The University Of Cincinnati Visible light emitting device formed from wide band gap semiconductor doped with a rare earth element
KR100510996B1 (en) * 1999-12-30 2005-08-31 주식회사 하이닉스반도체 Method for optimizing processes of selective epitaxial growth
US6519543B1 (en) * 2000-05-09 2003-02-11 Agere Systems Inc. Calibration method for quantitative elemental analysis
US6734453B2 (en) 2000-08-08 2004-05-11 Translucent Photonics, Inc. Devices with optical gain in silicon
KR100384892B1 (en) * 2000-12-01 2003-05-22 한국전자통신연구원 Fabrication method of erbium-doped silicon nano-dots
US6853447B2 (en) * 2001-02-12 2005-02-08 Analytical Spectral Devices, Inc. System and method for the collection of spectral image data
US6894772B2 (en) * 2001-02-12 2005-05-17 Analytical Spectral Devices System and method for grouping reflectance data
JP2002334868A (en) * 2001-05-10 2002-11-22 Hitachi Kokusai Electric Inc Substrate treatment equipment and method for manufacturing semiconductor device
US20030111013A1 (en) * 2001-12-19 2003-06-19 Oosterlaken Theodorus Gerardus Maria Method for the deposition of silicon germanium layers
US6771369B2 (en) * 2002-03-12 2004-08-03 Analytical Spectral Devices, Inc. System and method for pharmacy validation and inspection
US20040214362A1 (en) * 2003-01-22 2004-10-28 Hill Steven E. Doped semiconductor nanocrystal layers and preparation thereof
US7440180B2 (en) * 2004-02-13 2008-10-21 Tang Yin S Integration of rare-earth doped amplifiers into semiconductor structures and uses of same
US7163878B2 (en) * 2004-11-12 2007-01-16 Texas Instruments Incorporated Ultra-shallow arsenic junction formation in silicon germanium
CN100385693C (en) * 2005-08-18 2008-04-30 中国科学院半导体研究所 Method for raising radiation of silicone based crystal thin film by use of process of plasma
DE102006031300A1 (en) * 2006-06-29 2008-01-03 Schmid Technology Systems Gmbh Method for doping silicon material for solar cells, correspondingly doped silicon material and solar cell
US20080138955A1 (en) * 2006-12-12 2008-06-12 Zhiyuan Ye Formation of epitaxial layer containing silicon
US8283201B2 (en) * 2008-06-05 2012-10-09 American Air Liquide, Inc. Preparation of lanthanide-containing precursors and deposition of lanthanide-containing films
US8269253B2 (en) * 2009-06-08 2012-09-18 International Rectifier Corporation Rare earth enhanced high electron mobility transistor and method for fabricating same
CN102828242B (en) * 2012-09-06 2015-05-27 西安隆基硅材料股份有限公司 Crystalline silicon with lower converting lighting quantum dots and preparation method thereof
US9481917B2 (en) * 2012-12-20 2016-11-01 United Technologies Corporation Gaseous based desulfurization of alloys
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Also Published As

Publication number Publication date
CN1054234C (en) 2000-07-05
JPH0785467B2 (en) 1995-09-13
CN1114225C (en) 2003-07-09
CN1255735A (en) 2000-06-07
JPH06177062A (en) 1994-06-24
EP0586321B1 (en) 1998-05-20
DE69318653D1 (en) 1998-06-25
KR940004714A (en) 1994-03-15
EP0586321A3 (en) 1996-03-27
DE69318653T2 (en) 1999-02-04
CN1255736A (en) 2000-06-07
US5534079A (en) 1996-07-09
EP0586321A2 (en) 1994-03-09
MX9305267A (en) 1994-02-28
TW229325B (en) 1994-09-01
CN1117389C (en) 2003-08-06
ATE166491T1 (en) 1998-06-15
CA2095449C (en) 1997-09-16
KR970008339B1 (en) 1997-05-23
US5646425A (en) 1997-07-08
US5322813A (en) 1994-06-21
ES2116426T3 (en) 1998-07-16
CN1085353A (en) 1994-04-13

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