CA2100165A1 - Microwave-active tape having a cured polyolefin pressure-sensitive adhesive layer - Google Patents
Microwave-active tape having a cured polyolefin pressure-sensitive adhesive layerInfo
- Publication number
- CA2100165A1 CA2100165A1 CA002100165A CA2100165A CA2100165A1 CA 2100165 A1 CA2100165 A1 CA 2100165A1 CA 002100165 A CA002100165 A CA 002100165A CA 2100165 A CA2100165 A CA 2100165A CA 2100165 A1 CA2100165 A1 CA 2100165A1
- Authority
- CA
- Canada
- Prior art keywords
- microwave
- tape
- active
- olefin
- sensitive adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
- B65D81/3446—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3439—Means for affecting the heating or cooking properties
- B65D2581/3445—Microwave reactive adhesives, e.g. also used in valves or lids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3463—Means for applying microwave reactive material to the package
- B65D2581/3466—Microwave reactive material applied by vacuum, sputter or vapor deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3471—Microwave reactive substances present in the packaging material
- B65D2581/3472—Aluminium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3471—Microwave reactive substances present in the packaging material
- B65D2581/3477—Iron or compounds thereof
- B65D2581/3478—Stainless steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3486—Dielectric characteristics of microwave reactive packaging
- B65D2581/3494—Microwave susceptor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
- C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
Abstract
A piece of microwave-active tape which is odor-free and physiologically inert can be adhered to a food package and remains strongly adhered during cooking at temperatures of at least 200 ·C. The tape has layers of microwave-active material and a pressure-sensitive adhesive which is a polymeric .alpha.-olefin that has been cured to afford a "Peel Value" of at least 5 N/dm and a "Shrink Back" at 220 ·C of less than 5 %. The tape can have a flexible backing such as a low-adhesion carrier web which can be stripped off from a piece of the tape that has been applied to a microwave food package, or when the backing is heat-resistant, it can be left in place.
Description
~.. W092/13923 2 1 ~ ~ 1 6 ~ PCr/~S~ 8~
.. . ~
I
~IC:R07~AVE-AC~IVE TAPE ~IAVING A CIT~ED
POLYOLE~IN PRESS~R2-SENSITIVB AD~ESIVE LAYER
~ackground of the Inventio~
l. Field of the Invention The invention relates to pressure-sensitive adhPsive tapes and further to their uses on foo~
packages.
.. . ~
I
~IC:R07~AVE-AC~IVE TAPE ~IAVING A CIT~ED
POLYOLE~IN PRESS~R2-SENSITIVB AD~ESIVE LAYER
~ackground of the Inventio~
l. Field of the Invention The invention relates to pressure-sensitive adhPsive tapes and further to their uses on foo~
packages.
2. Background Art The use of microwave energy revolutionized food preparation and has now become com~on place.
However, the advantages associated with microwavP
usage are tempered with compromises to food appearances, texture and some~imes ease of preparation To co~pensate for the microwave oven's inability to crisp and brown the surface of foods and to prevent foods, highly absorptive of microwave ~.
energy from being overheated, resulting in toughening ~`. and dehydration of the food, two specific "microwave active" packaging oomponents have been developed:
microwave susceptors and microwave shields.
Microwave susceptors are devices which heat in response to microwave energy, converting microwave energy into thermal energy to produce browning and/or crisping of food surfaces placed in contact with microwave susceptors. Suscept~ors may be constructed by a variety o~ methods such as vacuum metallization of polymer substrates, or conductive particles .` . dispersed in a suitable binder. Microwave susceptors convert a portion ~f the incident microwave energy into sensi~le heat.
,' :
'~
, ~ .. . :. ~ , ~ ,. , . , . .. . :
2 1 ~
W092/13~23 PCr/US~ 0 Microwave shields are devices that do not heat appreciably in response to microwave enPrgy, but reflect virtually all incident microwaves. Metallic foils are generally employed as microwave shieldsO
Microwave active devices that are microwave absorbing or shielding are disclosed in U.S. Patent No. 4,190,757. The food packaging described in the , '757 patent includes a heating body that is a laminate of a supporting sheet and a layer of an 'labsorptive lossy substance." The packaging also includes a shield, such as metallic foil to reflect microwaves. However, the metallic foil can be perforated to allow a proportion of the microwave energy to reAch the food.
The food packaging described in U.S.-Patent No. 4,230,924 includes a flexible sheet of dielectric material~ such as polyester substrate having an ultrathin metallic coating that is subdivided into islands with nonmetallic gaps or strips therebetween.
When the ~ood package is placed in a microwave oven, some of the microwave energy passes through the sheet. A lesser amount o~ the microwave energy is converted into ther~al energy by the metallic coating, which functions as a ~icrowave absorber~
thus permitting browning or crisping of adjacent food.
The subject matter of U.S. Patent No.
4,267,420 is similar to that of the '924 patent, upra, but includes an additional heet or substxate of plastic la~inated to the metallic coating.
The microwave susceptor packaging described in the aforementioned patents allows the surface of packaged food to be heated by thermal energy. ThP
combination o~ microwa~e and thermal heating permits browning and crisping times to be correlated with heating time~. , ,.
- - . , ' . , ; ~
,: - -, .
- : , .
~,; WO92/13923 21~ O 15 ~ PCTtVS9~8$~0 An alternative use of a microwave susceptor is to vent a vapor-tight package. U.S. Patent No~
4,640,838 describes a microwave susceptor incorporated into a tape that has a low-adhesion carrier web bearing a layer o~ graphite or carbon black particles and a layer of pressure-sensitive adhesive (PSA) by which a piece of the tape is adhered to a package. After the carrier web is stripped off, the package is placed in a microwave oven and heat generated in the graphite or carbon black layer automatically vents the package. Package venting is achieved by softening and weakening the package material underneath the tape. Alternatively, when the tape covers an opening in the package material below the susceptor, venting is achieved by sof~ening and weakening the tape itself.
Generally, microwave susceptor packaging consists of aluminum vapor-coated poly(e~hylene terephthalate) ("PET") subs~rate, adhesive laminated to paper or paperboard such as is in U.S. Patent Nos.
4,641,005 and 4,735,513. The packaging is formed into popcorn bags, pizza trays and the like.
~icrowave susceptors ~ashioned into a pressure ~ensitive tape or into an adhesive label~
advantageously per~it the user the flexibility of ~ attaching the tape or l~bel at any position on a ; finished product. A previously co~mercialized microwave susceptor label that ~mployed an acrylic-based PSA, produced a noxious odor when the label was heated. The odor arising from heating the labels apparently caused the labels to be withdrawn from the market shortly a~ter their introduction.
8u~ary o~ the Prossnt Invnntion , Briefly, the present invention provides a novel microwave active tape comprising a PSA layer -' ' . . . .
.
wo ~ 1 6 ~ P~/vs~/0~
such that a piece of the tape can be selectively adhered to any portion of a food package. The PSA of the novel tape is virtually odor-~ree when heated.
Furthermore, the PSA of the novel tape is used on food packages without physiological hazard and without affecting the taste of the food.
The present invention comprises: :
a) a backing layer b) a layer of microwave active material, and c) a pressure-sensitive adhesive, applied to said layer of microwave active material.
The PSA is a polymeric ~-olefin that has been cured to afford a "Peel Value" (defined below) of at least 5 N/dm and a "Shrink Back" a~ 220C
(defined below) of less than 5%.
In another aspect, the present invention provides a method of selectively heating and/or hrowning foods, tha~ require disproportionate heating times, comprising positioning a first piece of the novel microwave active tape adjacent to a portion of ~ood requiring crisping and browning and posi ioning a second piece of microwave active tape adjacent to a ~ 25 portion of ~ood that requires slower cooking times, -: wherein said ~irst piece of tape is a microwave susceptor ~hat converts a portion of the microwave energy into thermal energy and said second piece of tape is a microwave shield that essentially reflects microwave energy.
In another aspect, the present invention provides a method of steam venting comprising the steps of positioning a piece of microwave susceptor tape on the outside of an air-tight polymer package co~taining food, or over a portion of a heat-sealed seam of such package. As the food is ~icrowaved, steam evolves and causes the package to expand. The .
.
. ~ . . , ~ , . . . :
r- wo 92/,3923 2 f ~ ~ :I 6 ~ Pcr/us~g/08810 .~
piece of tape adhered to the outside of the package heats and softens the underlyi~g packaging, which ruptures and allows the steam to escape.
Alternatively, a piece of tape positioned over the package heat-seal seam heats and softens the heat-seal at that point and allows it to open and vent as . the steam pressure within the package builds.
Advantageously, the PSA of the novel tape adheres strongly to cardboard, plastic substrates, and other materials commonly used in microwave food packages, including low-energy non-polar subs~rates such as poly(4-methylpent-1-ene), and remains strongly adhered at temperatures from -20C to 200C
and even higher temperatures to which a microwave active tape can be heated in a microwave oven,-` without production of the noxious odors present in the earlier described tapes. During cooking, the adheæive resists shrinkage and prevents the backing from shrinking, thus allowing the absorbing or ~ 2G shielding function of the tape to continue throughout : the cooking operation. Because of the adhesive's stability, the tape may be stored indefinitely without noticeable degradation. Additionally, a piece of the tape can be adhered to any part of a microwave food package without requiring special app~ratus generally needed when an a~hesive is activated by heat or solvent. Also, the tape can be used as an automatic steam release device for ~ thermoplastic packaging to preven~ package bursting from built-up steam pressure during microwave ` heating.
i~ In this application:
"shrink back" means a value measured by a ~ test method herein~fter described;
.~ 35 "peel value" means the force required to remove ~ PSA coated sample at a speci~ic angle and .
: ~ .
. ' :.
~. . . . . . .
, ~, ; , . j . . . . .
- . . . ,: .~ . .
. . - : , ' ::
.
. . : . .: :
2 1 ~
However, the advantages associated with microwavP
usage are tempered with compromises to food appearances, texture and some~imes ease of preparation To co~pensate for the microwave oven's inability to crisp and brown the surface of foods and to prevent foods, highly absorptive of microwave ~.
energy from being overheated, resulting in toughening ~`. and dehydration of the food, two specific "microwave active" packaging oomponents have been developed:
microwave susceptors and microwave shields.
Microwave susceptors are devices which heat in response to microwave energy, converting microwave energy into thermal energy to produce browning and/or crisping of food surfaces placed in contact with microwave susceptors. Suscept~ors may be constructed by a variety o~ methods such as vacuum metallization of polymer substrates, or conductive particles .` . dispersed in a suitable binder. Microwave susceptors convert a portion ~f the incident microwave energy into sensi~le heat.
,' :
'~
, ~ .. . :. ~ , ~ ,. , . , . .. . :
2 1 ~
W092/13~23 PCr/US~ 0 Microwave shields are devices that do not heat appreciably in response to microwave enPrgy, but reflect virtually all incident microwaves. Metallic foils are generally employed as microwave shieldsO
Microwave active devices that are microwave absorbing or shielding are disclosed in U.S. Patent No. 4,190,757. The food packaging described in the , '757 patent includes a heating body that is a laminate of a supporting sheet and a layer of an 'labsorptive lossy substance." The packaging also includes a shield, such as metallic foil to reflect microwaves. However, the metallic foil can be perforated to allow a proportion of the microwave energy to reAch the food.
The food packaging described in U.S.-Patent No. 4,230,924 includes a flexible sheet of dielectric material~ such as polyester substrate having an ultrathin metallic coating that is subdivided into islands with nonmetallic gaps or strips therebetween.
When the ~ood package is placed in a microwave oven, some of the microwave energy passes through the sheet. A lesser amount o~ the microwave energy is converted into ther~al energy by the metallic coating, which functions as a ~icrowave absorber~
thus permitting browning or crisping of adjacent food.
The subject matter of U.S. Patent No.
4,267,420 is similar to that of the '924 patent, upra, but includes an additional heet or substxate of plastic la~inated to the metallic coating.
The microwave susceptor packaging described in the aforementioned patents allows the surface of packaged food to be heated by thermal energy. ThP
combination o~ microwa~e and thermal heating permits browning and crisping times to be correlated with heating time~. , ,.
- - . , ' . , ; ~
,: - -, .
- : , .
~,; WO92/13923 21~ O 15 ~ PCTtVS9~8$~0 An alternative use of a microwave susceptor is to vent a vapor-tight package. U.S. Patent No~
4,640,838 describes a microwave susceptor incorporated into a tape that has a low-adhesion carrier web bearing a layer o~ graphite or carbon black particles and a layer of pressure-sensitive adhesive (PSA) by which a piece of the tape is adhered to a package. After the carrier web is stripped off, the package is placed in a microwave oven and heat generated in the graphite or carbon black layer automatically vents the package. Package venting is achieved by softening and weakening the package material underneath the tape. Alternatively, when the tape covers an opening in the package material below the susceptor, venting is achieved by sof~ening and weakening the tape itself.
Generally, microwave susceptor packaging consists of aluminum vapor-coated poly(e~hylene terephthalate) ("PET") subs~rate, adhesive laminated to paper or paperboard such as is in U.S. Patent Nos.
4,641,005 and 4,735,513. The packaging is formed into popcorn bags, pizza trays and the like.
~icrowave susceptors ~ashioned into a pressure ~ensitive tape or into an adhesive label~
advantageously per~it the user the flexibility of ~ attaching the tape or l~bel at any position on a ; finished product. A previously co~mercialized microwave susceptor label that ~mployed an acrylic-based PSA, produced a noxious odor when the label was heated. The odor arising from heating the labels apparently caused the labels to be withdrawn from the market shortly a~ter their introduction.
8u~ary o~ the Prossnt Invnntion , Briefly, the present invention provides a novel microwave active tape comprising a PSA layer -' ' . . . .
.
wo ~ 1 6 ~ P~/vs~/0~
such that a piece of the tape can be selectively adhered to any portion of a food package. The PSA of the novel tape is virtually odor-~ree when heated.
Furthermore, the PSA of the novel tape is used on food packages without physiological hazard and without affecting the taste of the food.
The present invention comprises: :
a) a backing layer b) a layer of microwave active material, and c) a pressure-sensitive adhesive, applied to said layer of microwave active material.
The PSA is a polymeric ~-olefin that has been cured to afford a "Peel Value" (defined below) of at least 5 N/dm and a "Shrink Back" a~ 220C
(defined below) of less than 5%.
In another aspect, the present invention provides a method of selectively heating and/or hrowning foods, tha~ require disproportionate heating times, comprising positioning a first piece of the novel microwave active tape adjacent to a portion of ~ood requiring crisping and browning and posi ioning a second piece of microwave active tape adjacent to a ~ 25 portion of ~ood that requires slower cooking times, -: wherein said ~irst piece of tape is a microwave susceptor ~hat converts a portion of the microwave energy into thermal energy and said second piece of tape is a microwave shield that essentially reflects microwave energy.
In another aspect, the present invention provides a method of steam venting comprising the steps of positioning a piece of microwave susceptor tape on the outside of an air-tight polymer package co~taining food, or over a portion of a heat-sealed seam of such package. As the food is ~icrowaved, steam evolves and causes the package to expand. The .
.
. ~ . . , ~ , . . . :
r- wo 92/,3923 2 f ~ ~ :I 6 ~ Pcr/us~g/08810 .~
piece of tape adhered to the outside of the package heats and softens the underlyi~g packaging, which ruptures and allows the steam to escape.
Alternatively, a piece of tape positioned over the package heat-seal seam heats and softens the heat-seal at that point and allows it to open and vent as . the steam pressure within the package builds.
Advantageously, the PSA of the novel tape adheres strongly to cardboard, plastic substrates, and other materials commonly used in microwave food packages, including low-energy non-polar subs~rates such as poly(4-methylpent-1-ene), and remains strongly adhered at temperatures from -20C to 200C
and even higher temperatures to which a microwave active tape can be heated in a microwave oven,-` without production of the noxious odors present in the earlier described tapes. During cooking, the adheæive resists shrinkage and prevents the backing from shrinking, thus allowing the absorbing or ~ 2G shielding function of the tape to continue throughout : the cooking operation. Because of the adhesive's stability, the tape may be stored indefinitely without noticeable degradation. Additionally, a piece of the tape can be adhered to any part of a microwave food package without requiring special app~ratus generally needed when an a~hesive is activated by heat or solvent. Also, the tape can be used as an automatic steam release device for ~ thermoplastic packaging to preven~ package bursting from built-up steam pressure during microwave ` heating.
i~ In this application:
"shrink back" means a value measured by a ~ test method herein~fter described;
.~ 35 "peel value" means the force required to remove ~ PSA coated sample at a speci~ic angle and .
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rate of removal measured by a test method hereinafter described;
"IV" means inherent viscosity of the polyolefin PSA;
"microwave active" means a component which affects change in microwave energy incident upon it;
S'microwave susceptor" is a microwave active component that converts a portion of the incident microwave energy into sensible heat; and "microwave shield~' is a microwave active component that reflects virtually all incident microwave energy.
Brisf D~3cript$on o~ the Dr~wing~
Figure 1 is a schematic representation o~ a side ele~ation of a roll of microwave active tape of this invention.
Figure 2 is a cross sectional view of a . preferred embodiment of a microwave active tape Figure 3 is a cross sectional view of an alternative embodiment of a microwave susceptor tape.
Figure 4 is a top view of a microwaveable food package to which pieces of microwave active tape -~ 25 of the invention have been adhered.
Figure 5 ls a cross sectional view of Figure 4.
-~: Figure 6 is a cross sectional view of a `~ microwaveable food package with a vent tape oomprising a piece of microwave active tape.
. .
. Detailed D~sGriptio~ of tha Pref~rred Embodi~ent ; This invention relates to microwave active tapes, particularly to pressure-sensitive adhesive tapes and further to their uses on food packages.
:
.
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.
~ W092/13923 2 ~ ~ O ~ 5 ~ PCT/VS9~
t Referring to Figure 1, microwave active tape 10 unwound from roll 11. The tape 10 comprises a heat-resistant polymeric or paper backing 12 bearing micro~ave active layer 14. Overlying ; 5 microwave active layer 14 is pressure-sensitive adhesive (PSA) layer 16.
Although heat-resistant polymeric backing 12 as described can be biaxially-oriented poly(ethylene terephthalate), biaxially-oriented polypropylene, or poly(4-methylpent-1-ene), any similar high temperature melt extrudable thermoplastic substrates known to those skilled in the art may be used and still be within the spirit and scope of the present invention.
Microwave active layer 1~ is a thin vapor deposited layer that primarily converts microwave energy to thermal energy.
Referring to Figure 2, a preferred : 20 embodiment of microwave active tape 10 is described that co~prises a heat-resistant backing layer 12, microwave-active layer 14 adjacent to one surface of said backing layer 12, and pressure sensitive adhesive (PSA) layer 16 coated directly on the . e~posed surface of microwave active layer 14. To permit winding of the tape on a roll without ; blocking, i.e., sticking to itself, release liner 17 may~be placed over the exposed sur~ace oP PSA layer 16. Alternatively, rel~ase c~ating 18 may be applied to the upper surface of backing layer 12.
Optionally, both treated release liner 17 and release coating 18 may be used.
~icrowave active layer 14 of novel tape 10 ~-can be constructed from either micr~wave absorbing : 35 material or microwave shielding material. Examples of absorbing matexial and shielding material are well-known in the art, for speci~ic examples, see . :
:
~ . , : : . ~ , . :
' ' , ' :' ";,' ,': , ,.;'. .. ~ '.; ' ' . W092/139~ ~ 9 '~ PCT/US9R/0881~
U.S. Pat. No. 4,640,838 that discloses microwave absorbing materials may include graphite or carbo~
black particles dispersed in a binder material; U.S. I
Pat. No. 4,190,757 discloses metal oxide.particles or other absorptive lossy substances; U.S. Pat. No.
"IV" means inherent viscosity of the polyolefin PSA;
"microwave active" means a component which affects change in microwave energy incident upon it;
S'microwave susceptor" is a microwave active component that converts a portion of the incident microwave energy into sensible heat; and "microwave shield~' is a microwave active component that reflects virtually all incident microwave energy.
Brisf D~3cript$on o~ the Dr~wing~
Figure 1 is a schematic representation o~ a side ele~ation of a roll of microwave active tape of this invention.
Figure 2 is a cross sectional view of a . preferred embodiment of a microwave active tape Figure 3 is a cross sectional view of an alternative embodiment of a microwave susceptor tape.
Figure 4 is a top view of a microwaveable food package to which pieces of microwave active tape -~ 25 of the invention have been adhered.
Figure 5 ls a cross sectional view of Figure 4.
-~: Figure 6 is a cross sectional view of a `~ microwaveable food package with a vent tape oomprising a piece of microwave active tape.
. .
. Detailed D~sGriptio~ of tha Pref~rred Embodi~ent ; This invention relates to microwave active tapes, particularly to pressure-sensitive adhesive tapes and further to their uses on food packages.
:
.
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.
~ W092/13923 2 ~ ~ O ~ 5 ~ PCT/VS9~
t Referring to Figure 1, microwave active tape 10 unwound from roll 11. The tape 10 comprises a heat-resistant polymeric or paper backing 12 bearing micro~ave active layer 14. Overlying ; 5 microwave active layer 14 is pressure-sensitive adhesive (PSA) layer 16.
Although heat-resistant polymeric backing 12 as described can be biaxially-oriented poly(ethylene terephthalate), biaxially-oriented polypropylene, or poly(4-methylpent-1-ene), any similar high temperature melt extrudable thermoplastic substrates known to those skilled in the art may be used and still be within the spirit and scope of the present invention.
Microwave active layer 1~ is a thin vapor deposited layer that primarily converts microwave energy to thermal energy.
Referring to Figure 2, a preferred : 20 embodiment of microwave active tape 10 is described that co~prises a heat-resistant backing layer 12, microwave-active layer 14 adjacent to one surface of said backing layer 12, and pressure sensitive adhesive (PSA) layer 16 coated directly on the . e~posed surface of microwave active layer 14. To permit winding of the tape on a roll without ; blocking, i.e., sticking to itself, release liner 17 may~be placed over the exposed sur~ace oP PSA layer 16. Alternatively, rel~ase c~ating 18 may be applied to the upper surface of backing layer 12.
Optionally, both treated release liner 17 and release coating 18 may be used.
~icrowave active layer 14 of novel tape 10 ~-can be constructed from either micr~wave absorbing : 35 material or microwave shielding material. Examples of absorbing matexial and shielding material are well-known in the art, for speci~ic examples, see . :
:
~ . , : : . ~ , . :
' ' , ' :' ";,' ,': , ,.;'. .. ~ '.; ' ' . W092/139~ ~ 9 '~ PCT/US9R/0881~
U.S. Pat. No. 4,640,838 that discloses microwave absorbing materials may include graphite or carbo~
black particles dispersed in a binder material; U.S. I
Pat. No. 4,190,757 discloses metal oxide.particles or other absorptive lossy substances; U.S. Pat. No.
4,230,924 discloses ultrathin metallic substrates, having resistivities in the range of 1 to 300 ohms :
per square, or vapor-deposited substrates of aluminum or st~inless steel having resistivities in the range of 300-1200 ohms per square, that are inexpensive and currently used in the food packaging industry.
Microwave shielding materials include relatively thick substrates o~ electrically conductive metals such as aluminum foil that reflect lS microwave energy without appreciably generating thermal energy. The degree of shielding can be : reduced by perforations or by dividing the foils in~o ~- islands surrounded by microwave transparent gaps.
Microwave active layer 14 may be selected such that the resulting microwave tape 10 is a susceptor, or a shield. Microwave active layer 14 may be a metallized substrate or a metal foil. I~ a metallized layer is used as microwave active layer : 14, the thickness of the layer will determine wh.ther ~ 25 the resulting tape is a ~usceptor or a shield.
-, Although a vacuum m~tallization process is preferably e~ployed to deposit a metallic layer on backing layer 12, other proce~ses known in the art can also be : used, such a~ electroless or electrolytic deposition methods. The process is continued until the desired - thickness of the layer i5 obtained. Generally, a thin vacuum metallized poly(ethyle~e terephthalate) .(PET) layer at thicknesses in the range of 50 to 500 Angstrom (A) units are used for microwave susceptors.
: 35 Metals used for the susceptor layer are typically aluminum or stainless steel, although other metals or metal alloys may also be used. Typically, a metallic .. . . . .
,. , . . .,: - . , . .. . :: .. . . ,. . , , ., : . . :.
WO 92/13923 2 1 Q O I ~ 3 PCr~lJS~ 8~
. y`l -*
layer having a thickness greater than 1 micrometer (~m) will essentially reflect microwaves, without arcing or appreciable heating.
Generally, a metal foil having a thickness greater than 1 micrometer is used as a microwave shield. The metal foil, typically aluminum, is adhesive laminated to backing layer 12. A continuous metal foil shields microwaves, that is, it reflects virtually all incident microwave energy. Metal mesh, grids or perforations in the metal or metal foil;
having apertures or openings greater than about 2 ~m in diameter, will provide partial shielding.
Referring to Figure 3, another embodiment of microwave~active tape 20 is described. Tape 20 comprises microwave active layer 24, wherein microwave active layer 24 comprises particles dispersed in an organic binder, and PSA layer 16 is coated directly on the exposed surface of microwave active layer 24. As shown in Figure 2 or 3, release liner 17 may be placed over the exposed surface of PSA layer 16. Alternatively, release coating 18 may ~- be used. Optionally, both release liner ~7 and release coating 18 may be u~ed.
~ The conductivP particles disper~ed in a ~: 25 suitable organic binder extruded or calendared into a flat substrate will produce a microwaYe susceptor.
` Organic binders include but are not limited to soluble polyester (Vitel~ PE-222, GoodyPar Chemicals), and silicone resin (RTV~ 615, G.E.
Silicone Prod. Div.). The conductiYe particles :~ include but are not limited to carbon black, graphite, or metal powder or flakes. Thin coatings of conductive paints such as those containing graphite, carbon black, metal particles or flakes on a suitable high temperature polymer backing may also be used for susceptors. Conductive paints such as Isolex~ RFI/EMI Coating Systems (Bee Chemical Co.), ' , , .
: ' .' , : . ` . :
W092/13g23 2 ~ ~ O L 6 ~ PCT/USg1~08B8~
which contain for example, graphite, silver or nickel and Advanced Polymer Thick Film (Hunt Advanced coatings and Chemicals), which also contain graphite, .
silver or nickel are useful in the practice of the present invention. -The descriptions referring to Figures 4 to 6 can be fabricated from either embodiment as shown in Figures 2 or 3.
Figure 4 shows microwave food package 40 whereon microwave transparent thermoplastic layer 44 seals package 40. Thermoplastic layer 44, without any active tape 10 (not shown) adhered to the surface, extends over the opening of first food ~ compartment 41 allowing all microwave energy incident upon layer 44 to pass through to the food (not shown). A piece of tape lOB, fabricated to be microwave shielding extends over the opening of second food compartment 42. By perforating microwave active layer 14 (not shown) of microwave tape l9B, only a portion of the incident microwave energy passPs through perforations 34, reaching the food (not shown) in second food compartme~t 42.
Referring to Figure 5, which shows a - cross-section of microwave package 40 of Figure 4;
25 . piece of tape lOA, fabricated to be microwave absorbing is adhered to the bottom of first food compartment 41. .Piece of tape lOB is adhered to the outer surface of ther~oplastic layer 44 that seals the opening of second food compartment 42.
P~rforations 34 permit microwave energy to pass : through an otherwise shi~lding piece of tape lOB.
. Figure 6 shows microwave package 50 comprising molded plastic tray 51, sealed with thermoplastic layer 44. A piece o~ microwave susceptor tape lOA is positioned and adhered by means o~ PSA layer 16 to the out~r sur~ace of thermoplastic .-substrate 44. Heat generated in microwave susceptor .` ' . ~ ' - : - . . . . . . . :
.
, . .; ~ .
~ W09~/139~3 2 1 0 ~ 1 ~ S PCT/U~91/0~810 layer l4 (not shown) softens a~d weakens thermoplastic substrate 44, such that vapor generated ~' (not shown) within microwave package 50 perforates the substrate and vents through the piece of tape lOA.
Pressure sensitive adhesives used in the present invention include but are not limited to curable adhesive compositions comprising (a) one or more poly(~-olefin) polymers derived from monomers containing 6 to lO carbon atoms and (b) a photoactive crosslinking agent. The.PSA selected is capable of adhering to the surface o~ a package or container on contact and during storage conditions, which can range from -20C to room temperature. The PSA is.:
sufficiently hPat resistant to allow the microwave, acti~e tape to re~ain adhered to the package without allowing oriented backings to curl or shrink more than 5% of their linear dimensions at temperatures exceeding 200C for a period of time normally . 20 expected in microwave cooking. Furthermore, the PSA
'- desirably is virtually ~ree of noxious odors ~ven at elevated temperatures, physiologically inert, and is ' capable of adhereing aggressively to both polar and -.: non-polar substrates.
'` 25 Another pressure sensitive adhesive that ~ may be used to practice the present invention is a i radiation curable poly(~-ole~in) containing adhesive composition that is pressure-sensitive at room temperature and upon cure yields an adhesive ~ 30 substrate having an excellent balance of peel and ': shear adhesion. The radiation curable PSA preferably has an inherent viscosity (IV) value of 3 to 4 and is coated from solution or hot-melt extrusion die coated . ' ,'` by methods well-known to those s~illed in the art.
.. 35 Preferably the PSA used in the prasent ' invention is disclosed in assignee's co-pending ., .
... . . - - - - .
:. . .
- , ' ',,~ . ,' , . , ,' :, . ' : '. , WO92/13923 2 ~ ~ ~ 3 PCT/US~
patent application Serial No. 07/403,622, filed Septemher 6, 1989 and comprises:
(a) at least one polymer comprised of: 85 to lO0 mole percent, preferably 85 to 99 mole percent of one or more C6 to C10 ~-olefin monomers, and 15 to 0 mole percent, preferably 15 to l mole percent, of one or more non-conjugated poIyene monomers, wlth the pro~iso that the mole percentage of all monomers sum to 100, and (b~ sufficient photoactive crosslinking agent to cro~slink the composition upon irradiatio~ from a ~ource o~ actinic radiation.
The preferred PSA polymer useful in the present invention has a glass transition temperature (Tg) in the range of -70C to 0C and an inherent viscosity in the range of 1.5 to 9.0 dl/g. The PSA's are hot-melt coatable when the inherent viscosity of the radiation curable poly(~-olefin) polymer is in the range of 1.5 to ~.0 dl/g. However, radiation curable poly(~-olefin) polymer having inherent - ` viscosities in the range of 4.0 to 9.0 dl/g may be coated ~rom toluene solution by methods well known to `~ 25 those skilled in the art to yield cured PSA films -~ having ~uperior shrink back, scorch values and crack values. Number average ~olecular wei~hts of the . polymers are generally in the range o~ 5,000 to `~ 50,000,000. .
The preferred PSA radiation-curable ~-olefin polymers used i~ the present invention have the yeneral ~ormula:
. ( 2 ICH )~(-cH2lcH.-)y 35 Rl R2 . .
R1 can be selected from monovalent hydrocarbon groups , containing.4 to 8 carbon atoms. Representative : examples include, but are not limited to: 1 : , , . .
~ W~92/13923 2 ~ j P~T/U~ a~
butyl, l-pentyl, 1-hexyl, 1-heptyl, 1-octyl; and branched hydrocarbon radicals such as 2-methyl-butyl, 2-ethyl-butyl, 3-methyl-hexyl, 2-ethyl-hexyl, 5-methyl-hexyl, 5-ethyl-hexyl, etc.
R2 can be a monovalent hydrocarbon group containing one or more ethylenically unsaturated ~roups selected from the group consisting of:
(-CH2-)nR~ -Ar-R3, (~CH2~)nQ~R3 n = 0 to 14.
R3 can be a C2 to C10 monovalent hydrocarbon group containing one or more ethylenically unsaturated groups.
Ar can be a divalent aromatic group containing 1 or 2 fused or catenated aro~atic rings with from 0 to ~- 15 8 substituents selected from th~ group consisting of alkyl, aryl, cycloalkyl, alkoxy, and aryloxy containing from 1 to 12 carbon atoms.
Q can be a divalent group selected from the group consisting of:
-O- and - Si -R
R4 and R5 ar0 the same or different C1 to C10 monovalent organic groups selected from the group consisting of alkyl, cycloalkyl, alkaryl, aryl, alkoxy and aryloxy.
x is the mole percent of one or more C6 to ClO ~-olefin monomer(s), the total ranging from 85 to 100 mole percent; and y is the mole percent of one or more non-conjugated polyene monomer(s), the total y ranging from 15 to 0 mole percent, with the proviso that (x + y) = 100 mole peroent.
Additional variations of radiation curable polyolefin pressure sensitive adhesives used in the ' ' `
. : ~. . , , : , ,: ~ : `. .. ..
,:
W092/13923 2 ~ 5 ~ PCT/USg~ 0 ,~
1~
present invention may be found in the co-pending patent applicatio~ identified as Serlal No.
07/403,622, filed September 6, 1989.
A second pressure sensitive adhesive that may be used in the fabrication of the present invention is disclosed in assignee's co-pending : patent application Serial No. 07/~05,653, ~iled October 30, 1990 and comprises a curable blend of (a) : an ~-olefin polymer containing ethylenic unsaturation, (b) a crosslinker having at least 2 hydrosilyl groups, and (c) a hydrosilatio~ catalyst.
~: This PSA preferably has an IV of at least 1.5.
The ~-olefin polymer of the second PSA
composition has the general formula:
(~Ml)a~~M2)b-~M3~)c : a, b, and c are numbers designating the relative molar amounts of M1, M2, and M3 units tha~ are randomly located in the bacXbone chain of the polymer such that the polymer has the weight average molecular weight in the range of 30,000 - to 3.5 million, a is at least 60 mole ~ of (a - b) wherein b can be zero, and c is 0.1 to 10 mole % of (a + b I c).
1 is an ethanediyl repeat unit having a pendent hydrocarhyl group having 4 to 12 carbon atoms.
M2, when present, is diff2rent ~rom M1, and is an ethanediyl repeat unit selected from 1) ethylene, 2) unit~ having a pendent hydro~arbyl - 30 group selected from linear ar~ branched alkyl groups having 1 to 18 carbon atoms, cyclic alkyl groups and aryl groups having 5 to 18 carbon atoms, and ` 3~ 1,2-cyclopentylene and ~ . .
1,2-cyclohexylene groups having 5 to 18 carbon atoms.
' .
.
. ' .
. .. .. . . . . . .. . .
.i. W092/13923 2 ~ PCT/US91~8l~
M3 is an ethanediyl repeat unit having a pendent ethylenically-unsaturated aliphatic or aryl group selected from the group consisting of r 1) linear and branched mono- and polyethylenically-unsaturated hydrocarbyl groups having 3 to 18 carbon atoms, 2) cyclic mono- and polyethylenically-unsaturated aliphatic groups optionally containing at least one of oxygen and nitrogen heteroatoms, the groups having 5 to 18 carbon atoms, 3) aryl groups substituted by mono~ or polyethylenically-unsaturated groups ha~ing a total of 7 to 18 carbon atoms, and 4) cycloalkylene groups having 6 to 18-carbons atoms wherein the cyclic group has at least 6 carbon atoms in the ring, provided that the ethylenically-unsaturated (C=C) moiety is not bonded directly to a backbone carbon atom.
Additional variations of pressure sen~itive adhesives based on ethylenically-unsaturated ~-olefi~ ' polymers cured wi~h hydrosilane and used in the present invention may be found in the co-pending patent application identified as Serial No.
07/605,~53.
A third ~lternative for a pressure sensitive adhesive for use in th~ fabxication of the -~ present invention are ~oisture-curable polyolefin based adhesives and are disclosed in assignee's co-pending patent application Serial No. 07/585,227, filed September 19, 1990. The PSA based on the moisture-curable ~-olef in polymers are hot melt coatable when their IV value is in the ranq~ of 1.5 to 4.0 dl~g. However, moisture curable poly(-olefin) polymers having an inherent viscosity of 4.0 to 9~0 dltg can be coated ~rom solution by methods 2 1 0~ PCT/US9~0B810 well known to those in the art. Such cured PSA films have superior shrink back, scorch values and crack values.
The moisture-curable -olefin polymer of the . 5 third PSA composition has a hydrocarbyl backbone and the general formula:
(-M4)dt M5)e-~M6_)f d, e, and are numbers designating the relative molar amounts of M4, M5, and ~6 units that are randomly located in the backbone chain of th~
polymer such that the polymer has the weight : average molecular weight of at least 30,000, d is at l~ast 60 mole % of (d + e) wherein e can ~- be zero, and f is 0.1 to 10 mole ~ of (d + e +
f)- -M4 is a repeat unit present in a polymer formed upon polymerization of an ~-olefin having 6 to 14 ` carbon atoms.
M5 is a saturated or unsaturated repeat unit present in a polymer formed upon polymerization of ethylenically-unsaturated hydrocarbons selected from ~-olefins having 2 to 20 carbon atoms, non-conjugated dienes having 5 to 20 carbon atoms, and non-conjugated ~ono- and poly~thylenically~
unsaturated mono- and polycyclic hydrocarbons :~ having 6 to 20 carbon atoms.
M6 is the ~ame as ~5 but is substituted by a hydrolyzable or condensable silyl group.
;: Additional variation~ of ~oisture curable polyolefin pressure sensitive adhesi~e used in the ; present invention ray be found in the co-pending patent application idanti~ied as Serial No.
07/585,227.
Any polymeric ~-olefin that has an inherent viscosity of at least 5 tends to afford a "Shrink Back" at 220C o~ least 5 N/dm and so does not need to be cured to be used in the fabrication of the .
,. . .
~ .
. . .: . . . : . ~,, , .. : : ,. . :, : . , , . . . . .. . . , . : .
~ W~92/13923 2~ 5 PCT/~g~ o microwave susceptor tapes of the present invention.
However, high IV values render the adhesive difficult to coat at commercially useful line speeds.
Other useful pressure sensitive adhesives 5 that may be used in the fabrication of the present invention are obtained from blends of uncured polymeric ~-olefins with various combinations of ~ thermoplastic polymers.
Testinq ~here indicated, the test procedures used in the examples to evaluate and compare the properties of the tapes are industry standard tes~sO
These tests are described in detail in various publications of the American Society for Testing Materials (ASTM), Philadelphia, PA and the Pressure Sensitive Tape Council (PSTC), Glenview, IL.
References to these standards are also given.
Sh~ink ~ckL scQ~h-valuç! and~Craç~ V~
: 1) A thin coating of aluminum is deposiked by vapor-deposition onto 0.96-mil (24.4-~m) biaxially-oriented poly(ethylene terephthalate) ~; 25 substrate, to a thickness affoxding approxi~ately 50%
optical trans~ission.
- 2) The pressure-sensitive adhesive to be evaluated (dried coating weight 3.8 mg/cm2) is coated onto the vapor-coated side of the poly(ethylene terephthalate) substrate to produce a microwaue susceptor tape of the invention.
3) A piece of the tape 3 1I X 3 1 ( 7, 5 cm X 7 0 5 cm) is cut and adhered by its pressure~sensitive adhesive layer to the clay-coated side of a larger ` paperboard having a basis weight of 330 g/m2 ~ using a 2" (5 cm) wide, 4-lb. (l.8-Xg) hard rubber roller, rolled back and forth three times in each direction.
::
.
.
- : .: i- - , , ., :, . , i. , :: . : .
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., .~ ., ., - ,:, . , . . . :. -,: . - . . : ~ . --. ,: - . . .
W092/13923 2 1 ~Ql~ a ~CT/~91/08~10 4) Using a felt-tip pen, the piece of tape is outlined.
5) The sample is aged for at least 12 hours before proceeding.
per square, or vapor-deposited substrates of aluminum or st~inless steel having resistivities in the range of 300-1200 ohms per square, that are inexpensive and currently used in the food packaging industry.
Microwave shielding materials include relatively thick substrates o~ electrically conductive metals such as aluminum foil that reflect lS microwave energy without appreciably generating thermal energy. The degree of shielding can be : reduced by perforations or by dividing the foils in~o ~- islands surrounded by microwave transparent gaps.
Microwave active layer 14 may be selected such that the resulting microwave tape 10 is a susceptor, or a shield. Microwave active layer 14 may be a metallized substrate or a metal foil. I~ a metallized layer is used as microwave active layer : 14, the thickness of the layer will determine wh.ther ~ 25 the resulting tape is a ~usceptor or a shield.
-, Although a vacuum m~tallization process is preferably e~ployed to deposit a metallic layer on backing layer 12, other proce~ses known in the art can also be : used, such a~ electroless or electrolytic deposition methods. The process is continued until the desired - thickness of the layer i5 obtained. Generally, a thin vacuum metallized poly(ethyle~e terephthalate) .(PET) layer at thicknesses in the range of 50 to 500 Angstrom (A) units are used for microwave susceptors.
: 35 Metals used for the susceptor layer are typically aluminum or stainless steel, although other metals or metal alloys may also be used. Typically, a metallic .. . . . .
,. , . . .,: - . , . .. . :: .. . . ,. . , , ., : . . :.
WO 92/13923 2 1 Q O I ~ 3 PCr~lJS~ 8~
. y`l -*
layer having a thickness greater than 1 micrometer (~m) will essentially reflect microwaves, without arcing or appreciable heating.
Generally, a metal foil having a thickness greater than 1 micrometer is used as a microwave shield. The metal foil, typically aluminum, is adhesive laminated to backing layer 12. A continuous metal foil shields microwaves, that is, it reflects virtually all incident microwave energy. Metal mesh, grids or perforations in the metal or metal foil;
having apertures or openings greater than about 2 ~m in diameter, will provide partial shielding.
Referring to Figure 3, another embodiment of microwave~active tape 20 is described. Tape 20 comprises microwave active layer 24, wherein microwave active layer 24 comprises particles dispersed in an organic binder, and PSA layer 16 is coated directly on the exposed surface of microwave active layer 24. As shown in Figure 2 or 3, release liner 17 may be placed over the exposed surface of PSA layer 16. Alternatively, release coating 18 may ~- be used. Optionally, both release liner ~7 and release coating 18 may be u~ed.
~ The conductivP particles disper~ed in a ~: 25 suitable organic binder extruded or calendared into a flat substrate will produce a microwaYe susceptor.
` Organic binders include but are not limited to soluble polyester (Vitel~ PE-222, GoodyPar Chemicals), and silicone resin (RTV~ 615, G.E.
Silicone Prod. Div.). The conductiYe particles :~ include but are not limited to carbon black, graphite, or metal powder or flakes. Thin coatings of conductive paints such as those containing graphite, carbon black, metal particles or flakes on a suitable high temperature polymer backing may also be used for susceptors. Conductive paints such as Isolex~ RFI/EMI Coating Systems (Bee Chemical Co.), ' , , .
: ' .' , : . ` . :
W092/13g23 2 ~ ~ O L 6 ~ PCT/USg1~08B8~
which contain for example, graphite, silver or nickel and Advanced Polymer Thick Film (Hunt Advanced coatings and Chemicals), which also contain graphite, .
silver or nickel are useful in the practice of the present invention. -The descriptions referring to Figures 4 to 6 can be fabricated from either embodiment as shown in Figures 2 or 3.
Figure 4 shows microwave food package 40 whereon microwave transparent thermoplastic layer 44 seals package 40. Thermoplastic layer 44, without any active tape 10 (not shown) adhered to the surface, extends over the opening of first food ~ compartment 41 allowing all microwave energy incident upon layer 44 to pass through to the food (not shown). A piece of tape lOB, fabricated to be microwave shielding extends over the opening of second food compartment 42. By perforating microwave active layer 14 (not shown) of microwave tape l9B, only a portion of the incident microwave energy passPs through perforations 34, reaching the food (not shown) in second food compartme~t 42.
Referring to Figure 5, which shows a - cross-section of microwave package 40 of Figure 4;
25 . piece of tape lOA, fabricated to be microwave absorbing is adhered to the bottom of first food compartment 41. .Piece of tape lOB is adhered to the outer surface of ther~oplastic layer 44 that seals the opening of second food compartment 42.
P~rforations 34 permit microwave energy to pass : through an otherwise shi~lding piece of tape lOB.
. Figure 6 shows microwave package 50 comprising molded plastic tray 51, sealed with thermoplastic layer 44. A piece o~ microwave susceptor tape lOA is positioned and adhered by means o~ PSA layer 16 to the out~r sur~ace of thermoplastic .-substrate 44. Heat generated in microwave susceptor .` ' . ~ ' - : - . . . . . . . :
.
, . .; ~ .
~ W09~/139~3 2 1 0 ~ 1 ~ S PCT/U~91/0~810 layer l4 (not shown) softens a~d weakens thermoplastic substrate 44, such that vapor generated ~' (not shown) within microwave package 50 perforates the substrate and vents through the piece of tape lOA.
Pressure sensitive adhesives used in the present invention include but are not limited to curable adhesive compositions comprising (a) one or more poly(~-olefin) polymers derived from monomers containing 6 to lO carbon atoms and (b) a photoactive crosslinking agent. The.PSA selected is capable of adhering to the surface o~ a package or container on contact and during storage conditions, which can range from -20C to room temperature. The PSA is.:
sufficiently hPat resistant to allow the microwave, acti~e tape to re~ain adhered to the package without allowing oriented backings to curl or shrink more than 5% of their linear dimensions at temperatures exceeding 200C for a period of time normally . 20 expected in microwave cooking. Furthermore, the PSA
'- desirably is virtually ~ree of noxious odors ~ven at elevated temperatures, physiologically inert, and is ' capable of adhereing aggressively to both polar and -.: non-polar substrates.
'` 25 Another pressure sensitive adhesive that ~ may be used to practice the present invention is a i radiation curable poly(~-ole~in) containing adhesive composition that is pressure-sensitive at room temperature and upon cure yields an adhesive ~ 30 substrate having an excellent balance of peel and ': shear adhesion. The radiation curable PSA preferably has an inherent viscosity (IV) value of 3 to 4 and is coated from solution or hot-melt extrusion die coated . ' ,'` by methods well-known to those s~illed in the art.
.. 35 Preferably the PSA used in the prasent ' invention is disclosed in assignee's co-pending ., .
... . . - - - - .
:. . .
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patent application Serial No. 07/403,622, filed Septemher 6, 1989 and comprises:
(a) at least one polymer comprised of: 85 to lO0 mole percent, preferably 85 to 99 mole percent of one or more C6 to C10 ~-olefin monomers, and 15 to 0 mole percent, preferably 15 to l mole percent, of one or more non-conjugated poIyene monomers, wlth the pro~iso that the mole percentage of all monomers sum to 100, and (b~ sufficient photoactive crosslinking agent to cro~slink the composition upon irradiatio~ from a ~ource o~ actinic radiation.
The preferred PSA polymer useful in the present invention has a glass transition temperature (Tg) in the range of -70C to 0C and an inherent viscosity in the range of 1.5 to 9.0 dl/g. The PSA's are hot-melt coatable when the inherent viscosity of the radiation curable poly(~-olefin) polymer is in the range of 1.5 to ~.0 dl/g. However, radiation curable poly(~-olefin) polymer having inherent - ` viscosities in the range of 4.0 to 9.0 dl/g may be coated ~rom toluene solution by methods well known to `~ 25 those skilled in the art to yield cured PSA films -~ having ~uperior shrink back, scorch values and crack values. Number average ~olecular wei~hts of the . polymers are generally in the range o~ 5,000 to `~ 50,000,000. .
The preferred PSA radiation-curable ~-olefin polymers used i~ the present invention have the yeneral ~ormula:
. ( 2 ICH )~(-cH2lcH.-)y 35 Rl R2 . .
R1 can be selected from monovalent hydrocarbon groups , containing.4 to 8 carbon atoms. Representative : examples include, but are not limited to: 1 : , , . .
~ W~92/13923 2 ~ j P~T/U~ a~
butyl, l-pentyl, 1-hexyl, 1-heptyl, 1-octyl; and branched hydrocarbon radicals such as 2-methyl-butyl, 2-ethyl-butyl, 3-methyl-hexyl, 2-ethyl-hexyl, 5-methyl-hexyl, 5-ethyl-hexyl, etc.
R2 can be a monovalent hydrocarbon group containing one or more ethylenically unsaturated ~roups selected from the group consisting of:
(-CH2-)nR~ -Ar-R3, (~CH2~)nQ~R3 n = 0 to 14.
R3 can be a C2 to C10 monovalent hydrocarbon group containing one or more ethylenically unsaturated groups.
Ar can be a divalent aromatic group containing 1 or 2 fused or catenated aro~atic rings with from 0 to ~- 15 8 substituents selected from th~ group consisting of alkyl, aryl, cycloalkyl, alkoxy, and aryloxy containing from 1 to 12 carbon atoms.
Q can be a divalent group selected from the group consisting of:
-O- and - Si -R
R4 and R5 ar0 the same or different C1 to C10 monovalent organic groups selected from the group consisting of alkyl, cycloalkyl, alkaryl, aryl, alkoxy and aryloxy.
x is the mole percent of one or more C6 to ClO ~-olefin monomer(s), the total ranging from 85 to 100 mole percent; and y is the mole percent of one or more non-conjugated polyene monomer(s), the total y ranging from 15 to 0 mole percent, with the proviso that (x + y) = 100 mole peroent.
Additional variations of radiation curable polyolefin pressure sensitive adhesives used in the ' ' `
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,:
W092/13923 2 ~ 5 ~ PCT/USg~ 0 ,~
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present invention may be found in the co-pending patent applicatio~ identified as Serlal No.
07/403,622, filed September 6, 1989.
A second pressure sensitive adhesive that may be used in the fabrication of the present invention is disclosed in assignee's co-pending : patent application Serial No. 07/~05,653, ~iled October 30, 1990 and comprises a curable blend of (a) : an ~-olefin polymer containing ethylenic unsaturation, (b) a crosslinker having at least 2 hydrosilyl groups, and (c) a hydrosilatio~ catalyst.
~: This PSA preferably has an IV of at least 1.5.
The ~-olefin polymer of the second PSA
composition has the general formula:
(~Ml)a~~M2)b-~M3~)c : a, b, and c are numbers designating the relative molar amounts of M1, M2, and M3 units tha~ are randomly located in the bacXbone chain of the polymer such that the polymer has the weight average molecular weight in the range of 30,000 - to 3.5 million, a is at least 60 mole ~ of (a - b) wherein b can be zero, and c is 0.1 to 10 mole % of (a + b I c).
1 is an ethanediyl repeat unit having a pendent hydrocarhyl group having 4 to 12 carbon atoms.
M2, when present, is diff2rent ~rom M1, and is an ethanediyl repeat unit selected from 1) ethylene, 2) unit~ having a pendent hydro~arbyl - 30 group selected from linear ar~ branched alkyl groups having 1 to 18 carbon atoms, cyclic alkyl groups and aryl groups having 5 to 18 carbon atoms, and ` 3~ 1,2-cyclopentylene and ~ . .
1,2-cyclohexylene groups having 5 to 18 carbon atoms.
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.i. W092/13923 2 ~ PCT/US91~8l~
M3 is an ethanediyl repeat unit having a pendent ethylenically-unsaturated aliphatic or aryl group selected from the group consisting of r 1) linear and branched mono- and polyethylenically-unsaturated hydrocarbyl groups having 3 to 18 carbon atoms, 2) cyclic mono- and polyethylenically-unsaturated aliphatic groups optionally containing at least one of oxygen and nitrogen heteroatoms, the groups having 5 to 18 carbon atoms, 3) aryl groups substituted by mono~ or polyethylenically-unsaturated groups ha~ing a total of 7 to 18 carbon atoms, and 4) cycloalkylene groups having 6 to 18-carbons atoms wherein the cyclic group has at least 6 carbon atoms in the ring, provided that the ethylenically-unsaturated (C=C) moiety is not bonded directly to a backbone carbon atom.
Additional variations of pressure sen~itive adhesives based on ethylenically-unsaturated ~-olefi~ ' polymers cured wi~h hydrosilane and used in the present invention may be found in the co-pending patent application identified as Serial No.
07/605,~53.
A third ~lternative for a pressure sensitive adhesive for use in th~ fabxication of the -~ present invention are ~oisture-curable polyolefin based adhesives and are disclosed in assignee's co-pending patent application Serial No. 07/585,227, filed September 19, 1990. The PSA based on the moisture-curable ~-olef in polymers are hot melt coatable when their IV value is in the ranq~ of 1.5 to 4.0 dl~g. However, moisture curable poly(-olefin) polymers having an inherent viscosity of 4.0 to 9~0 dltg can be coated ~rom solution by methods 2 1 0~ PCT/US9~0B810 well known to those in the art. Such cured PSA films have superior shrink back, scorch values and crack values.
The moisture-curable -olefin polymer of the . 5 third PSA composition has a hydrocarbyl backbone and the general formula:
(-M4)dt M5)e-~M6_)f d, e, and are numbers designating the relative molar amounts of M4, M5, and ~6 units that are randomly located in the backbone chain of th~
polymer such that the polymer has the weight : average molecular weight of at least 30,000, d is at l~ast 60 mole % of (d + e) wherein e can ~- be zero, and f is 0.1 to 10 mole ~ of (d + e +
f)- -M4 is a repeat unit present in a polymer formed upon polymerization of an ~-olefin having 6 to 14 ` carbon atoms.
M5 is a saturated or unsaturated repeat unit present in a polymer formed upon polymerization of ethylenically-unsaturated hydrocarbons selected from ~-olefins having 2 to 20 carbon atoms, non-conjugated dienes having 5 to 20 carbon atoms, and non-conjugated ~ono- and poly~thylenically~
unsaturated mono- and polycyclic hydrocarbons :~ having 6 to 20 carbon atoms.
M6 is the ~ame as ~5 but is substituted by a hydrolyzable or condensable silyl group.
;: Additional variation~ of ~oisture curable polyolefin pressure sensitive adhesi~e used in the ; present invention ray be found in the co-pending patent application idanti~ied as Serial No.
07/585,227.
Any polymeric ~-olefin that has an inherent viscosity of at least 5 tends to afford a "Shrink Back" at 220C o~ least 5 N/dm and so does not need to be cured to be used in the fabrication of the .
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~ W~92/13923 2~ 5 PCT/~g~ o microwave susceptor tapes of the present invention.
However, high IV values render the adhesive difficult to coat at commercially useful line speeds.
Other useful pressure sensitive adhesives 5 that may be used in the fabrication of the present invention are obtained from blends of uncured polymeric ~-olefins with various combinations of ~ thermoplastic polymers.
Testinq ~here indicated, the test procedures used in the examples to evaluate and compare the properties of the tapes are industry standard tes~sO
These tests are described in detail in various publications of the American Society for Testing Materials (ASTM), Philadelphia, PA and the Pressure Sensitive Tape Council (PSTC), Glenview, IL.
References to these standards are also given.
Sh~ink ~ckL scQ~h-valuç! and~Craç~ V~
: 1) A thin coating of aluminum is deposiked by vapor-deposition onto 0.96-mil (24.4-~m) biaxially-oriented poly(ethylene terephthalate) ~; 25 substrate, to a thickness affoxding approxi~ately 50%
optical trans~ission.
- 2) The pressure-sensitive adhesive to be evaluated (dried coating weight 3.8 mg/cm2) is coated onto the vapor-coated side of the poly(ethylene terephthalate) substrate to produce a microwaue susceptor tape of the invention.
3) A piece of the tape 3 1I X 3 1 ( 7, 5 cm X 7 0 5 cm) is cut and adhered by its pressure~sensitive adhesive layer to the clay-coated side of a larger ` paperboard having a basis weight of 330 g/m2 ~ using a 2" (5 cm) wide, 4-lb. (l.8-Xg) hard rubber roller, rolled back and forth three times in each direction.
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W092/13923 2 1 ~Ql~ a ~CT/~91/08~10 4) Using a felt-tip pen, the piece of tape is outlined.
5) The sample is aged for at least 12 hours before proceeding.
6) The sample is placed on l/4" (0.6 cm) plastic shims centered on the floor of a microwave oven (625 watt, 0.045 m'), wherein the shims are outside of the outlined area.
7) The microwave oven is operated at full power for 30 seconds, thus heating the surface of ~he vapor~deposited aluminum to about 220C (as measured with Luxtron~ MIW fluoroptic~probes of a Luxtron~
model 750 system from Luxtron, Mountain View, CA, typically the surface temperature at the center of the sample is about 5OC higher than at the edges).
model 750 system from Luxtron, Mountain View, CA, typically the surface temperature at the center of the sample is about 5OC higher than at the edges).
8) The back side of the paperboard is examined and if the entire outlined area is discolored (scorched), the test is continued. If not, the test will be invalid due to insu~ficient 2Q heating.
9) The maximum shrinkage of the tape is measured from any edge of the outline. The shrinkage value obtained is the "Shrink Back" of the sampleO
5% or less is considered to be in an acceptable range.
lO) The face of the tape is examined for the "Scorch Value":
l = no scorching 2 = slight scorching 3 = brown color 4 - face disrupted (adhesive oozing) Ratings 1-3 are acceptable for many purposes.
ll) The face of the tape is examined for the "Crack Value", that is any cracking of the poly(ethylene terephthalate) substrate:
l = no cracking visible to naked eye 2 = cracking barely visible to naked eye .
.
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WO 92/13923 2 ~ ~ ~u ~ & ~ PCI'/US9~/!i8~1:D
3 = cracking readily apparent 4 - adhesive oozing through cracks Ratings ~-3 are acceptable for many purposes.
Peel Value ~ASTM D 3330-78: PSTC - 1 !lIt75!1 The peel adhesion is the force required to remove a PSA coated test specimen from a test panel measured at a specific angle and rate of removal. In the examples, this force is expressed in Newtons pe~
deci~eter width (N/dm) of coated sheet. The procedure followed is:
1) A test specimen 25.4 mm wide is applied to a horizontally positioned clean glass test plate. A 2.2 kg rubber roller is used to press a 12.7 cm length of specimen into firm contact with the glass surface.
2) The free end of the specimen is doubled back nearly touching itself so the angle of removal is 180. The free end is attached to the adhPsion tester scaleO
3) The glass test plate is clamped in the jaws of tensile testing machine whieh moves the plate away from the scale at a constant rate of 2.3 meters per minute.
4) The scal~ reading is recorded as the tape is peeled from the glass surface, and the "Peel Value" in N/dm is calculated.
... .
Examples ,:
Advantages of this invention are further illustrated by ths following examples, but the particular matèrials and amounts thereof recited in these examples, as well as other conditions and .
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details, should not be construed to unduly limit this invention.
In making each of the ~-olefin polymers, pressure-sensitive adhesives, and tapes as described below, all parts are given by weight. Unless otherwise stated or apparent all materials used in the following examples are commercially availableO
SYNT~ESIS~OF PQ~XQ~IN PRESS~RE-SENSIII~E ADHESIVES
FoR MIÇROWAV;~ ,~CTIV~i ~APl~ ATIONS
Radiation-curab~e Polyolefins Polymers-~
A solution of 112 grams (l.o mole) 1-octene in 450 grams of heptane was polymerized with lo millimoles of diethylaluminum chloride (Et2AlC1) and 4 millimoles of aluminum activated reduced titanium trichloride (AATiCl3) (Stauffer Chemical Co., IncO) at 300C for 4 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture to control the viscosity. Ths (IV) polymer yields and inherent viscosities were:
. Polymer Yield l~) IV (dl/
25A1 85 2.9 A2 80 4.0 A3 78 4.9 . .
. Polym~s B
A solution of 109.8 grams (0.98 mole) 1-octene and 2.16 grams (0.02 mol~) of 4-vinylcyclohex-1-ene (molar charge ratio 98:2) in 450 grams of heptane was - pol~merized with Et2AlCl (5 millimoles) and AATiCl3 t2.S millimole~) ~t 30C for 6 hoursO. The polymer yields and inherent viscosities were:
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~ WO92/13923 2 ~ O ~1 ~ .7 Pcr/~)s~a~o~o !
~1 Polymer Yield (~) IV ldl/
Bl 62 2.8 B2 65 5.0 Polymers c A solution of 84 grams (1.0 mole) 1-hexene in 450 grams of heptane was polymerized with the required amount of Et2AlCl (16 millimoles) and AATiCl3 (4.0 millimoles) at 30C for 24 hours. The polymer yields and inherent viscosities were:
Pol~mer Yield (~) IV ~dl/q~
C1 82 1.9 c2 88 2.9 c3 80 6.5 PolYmer D
A solution of 79.8 grams (0.95 mole) 1-hexene and 5.4 gra~s (0.05 mol) 4-vinylcyclohex-1-ene (molar ; 20 charge ratio 95:5) in 450 grams of heptane was : polymerized with Et2AlCl (10 millimoles) and AATiCl3 (4 millimoles) at 30C for 4 hours. During the course of the reaction, hydrogen was bubbled througb the reaction mixture to control the viscosity. The ~ 25 polymer yield was 68 percent and inherent viscosity : was 3.8 dl/gram.
, Thermall~-Cu~able ~ydxosiloxane Polyolefins .
~lymr~_~
A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5j in 450 grams of heptane was polymerized with ~t2AlCl (16 millimoles) and ~ATiC13 (4 millimoles) 2t 50C for 10 hours. During th~ :
course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer .
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WO92/l39232 1~ Q 3 6 ~
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was 52 per~ent, lnherent viscosity was 1.9 dl/gram.
The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.
Polymer F .
A solution of 106.4 grams (0.95 mole) 1-octene and 5.5 grams (0.0509 mole) 1,7-octadiene (molar .
charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl~
(4.0 millimoles) at 50~C for 10 hours. During the course of the reaction, hydrogen was bubblPd through the reaction mixture. The conversion of the polymer was 65 percent, inherent viscosity was 2.1 dl/gram~
The composition of monomers in the copolymer was 97O3 mole ratio from NMR analysis.
Radiation~Curable HydrosilQxane Polyolefins ~; POlymer_G
A solution of 985.94 grams (11.715 mole) 1- .
hexene and 58.24 grams (0.4831 moIe) 1,7-octadiene (molar-charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiC~3 (6.97 millimoles) at 25~C ~or 20 hours. During the course of the reaction, hydrogen was bubbled through the reac~ion mixture. The conver ion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram.
The composition of mono~ers in the copolymer was :
97.8:2.2 mole ratio from N~R analysis.
Polymer H
A solution of 416.53 grams (3.711 mole) 1-octene and 8.35 grams (Ø0753 mole) 1,7-octadiene (molar charge ratio 98:2) in 450 grams of heptane was polymerized with Et2AlCl (4.14 millimol~s) and AATiCl3 (2.75 millimoles) at 25C for 26 hours~ During the course of the reaction, hydrogen was bubbled through .. . ,. ~ .................................. .
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the reaction mixture. The conversion of the polymer was 56 percent, inherent viscosity was 1.3 dl/g. The composition of monomers in the copolymer was 99:1 mole ratio from NMR analysis.
Moisture-curable Polvolefin .
Polymer I
50 grams of l-hexene-1,7-octadiene (97:3 molar ratio) copolymer having an inherent viscosity in heptane of 1.9 dl/gram was dissolved in 500 grams of toluens. This was refluxed under nitrogen, and about 20 ml of toluene was distilled out to ensure the removal of the water in the system. 2.9 grams of triethoxysilane was added together with bis~divinyltetramethyldisiloxane)Pt(0) catalyst in an amount sufficient to give 100 pp~ of platinum based on combined quantity of polyolefin and alXoxysilane.
The reaction wa~ run for 48 hours. Progress of t~le reaction was monitored by spectral analysis. At the end of the reaction, the copolymer was precipitated in dry methanol under anhydrous conditions. The silane moiety o~ th~ copolymer was found to be 207 mole percent using spectral analysis.
~ essu~e ~ensitive ~dhesive Tapes Solutions of each of tacki~ied and non-tackified Polymers A-D and 1.0 wt% (based on polymer) benzophenone in toluene were knife coated onto the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly~ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thick~ess affording approximat ly 50% optical transmission. The dry coating weights were 3.8 mg/cm2. The hand spreads were cured in . ~ . : . :
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~4 nitrogen in an RPC Processor Model #QC1202 ANIR (from PPG Industries) at 30 cm/sec (60 ft/min).with two standard medium pressure mercury lamps operating at 80 watts/cm2. The lamps were located at a distance of about 9.5 cm from the backing.
The microwave tape performance of various tackified and non-tackified polymexs cured under different conditions is given in Table l. This data shows that in general, radiation curable poly(~-olefin) polymers with higher inherent viscosities produce cured adhesive films having superior shrink back, scorch values, and crack - values. The data also shows that in general, bl~nding tackifying resins with the poly(~-olefin) prior to cure produces cured adhesive films having higher peel adhesion values.
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'7 Pressur~e-Sensitive Adhesive Tapes 31~50 Either Polymer E or Polymer F, hydro-siloxane having the formula Me35iO(SiMeHO)355iMe3 wherein Me=methyl, (amounts indicated in Table 2) and 1.25 parts of 2-ethylhexyl maleate, an inhibitor included to prevent room temperature cure of the composition were dissolved in 300 parts of toluene. A
pressure-sensitive adhesive composition (approximately 33% nonvolatiles) was obtained by adding a platinum catalyst, bis(divinyltetramethyldisiloxane)Pt(0) to this mixture in an amount indicated in Table 2. The composition was coated on the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording approximately 50% optical transmission. The solvent was evaporated off at room temperature followed by heating at 150C for 5 minutes to ensure complete CUre (probably Curing for one minute at that temperature would be suf~icient). The dry coating weights ~ere 3.8 mg/cm2.
Microwave perormance of various tapes were evaluated, and the results are summarized in Table 2.
The ~ata show that moderate to high concentrations of hydro-siloxane crosslinker are required to produce cured PSA films having acceptable shrink back, scorch va1ues, and crack values.
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W092t13923 ~ &v,;, PCT/lJ59R/0~8 ~9 Pressure-Sensitive Adhesive Tapes_5l-62 Either Polymer G or Polymer H, and a hydro-siloxane having the formula Me3SiO(SiMeHO)35SiMe3, (amounts indicated in Table 3) were dissolved in 300 parts of toluene. A pressure-sensitive adhesive composition (approximately 33% nonvolatiles) was obtained by adding cyclopentadienyltrimethylplatinum (CpPtMe3), a thermally stable photocatalyst, to this mixture in an amount indicated in Table 3. The composition was coated on th~ vapor coated side o~
0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor deposited aluminum having a thickness affording approximately 50% optical transmission. The sol~t was evaporated off at room ~emperature. The hand spreads were cured in nitrogen in an RPC Processor Model #ZC1202 ANIR (from PPG Industries) at 30 cm/sec (60 ft/min) with two standard ~edium pressure mercury lamps operating at 80 watts/cm2. The lamps were located at a distance of about 9.5 cm from the backing. The dry coating weights were 3.8 mg/cm2~
Microwave performance of various tapes were evaluated, and the results are summarized in Table 3, This data shows that when the inherent viscosity o~
the radiatio~ curable hydro-silox~ne poly(~-olefin) polymPr is greater that l.5 dl/g, the cured PSA ~ilms tend to have acceptable shrink back, scorch values, and crack values.
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Pressure-Sensitive Adhesive Tapes 63-7?
Solutions of tackified and non-tacXified Polymer I in toluene ~olvent were knire coated on the - s vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording approximately 50~ optical transmission. Some of the solutions contained dibutyltindilaurate catalyst as indicated in Table 4O
The dry coating weights were 3.8 mg/cm~. The microwave tape performance of various tackified and non-tackified polymers under different conditions is give~ in Table 4. Tapes No. 63 and 64, as comparative examples are included in Table 4 to show the need to hydrosilate an ~-olefin polymer in order to moisture-cure the polymerO
Microwave performance of various tapes were evaluated, and the results are su~marized in Table 4.
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zl = Butyl rubber~ 269 (Exxon Chemicals) Z2 = generic name VISTANEX~ MNL-140 (Exxon Chemicals) 0 Z3 = Copolymer of isooctyl acrylate and acrylic acid (95/5) Z4 = 60 parts styrene/isoprene/styrene block copolymer (Kraton 1107~ Shell Chemical Co.) plus 40 parts WINGT~CX PLUS~ (Goodyear Chemical .
Co . ) Z5 = microwave susc~ptor adhesive (NoO 24848~, Swift Adhesives, Downers Grove, IL) The blend was Xnife coated on the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording - approximately 50% optical transmission. After drying as in Examples 1-30, the dry coating weights were 3O8 mg/cm2.
The microwave performance of the tapes is given in Table 5. The data generally shows that as the concentration of radiation curable poly(~-olefin) polymer in the blend increases, the microwave performance of uncured PSA ~ilms generally i-proves.
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Various modifica~ions and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention, and it should be understood that this invention is not to be unduly limited to the illustrative embodiments set forth herein.
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5% or less is considered to be in an acceptable range.
lO) The face of the tape is examined for the "Scorch Value":
l = no scorching 2 = slight scorching 3 = brown color 4 - face disrupted (adhesive oozing) Ratings 1-3 are acceptable for many purposes.
ll) The face of the tape is examined for the "Crack Value", that is any cracking of the poly(ethylene terephthalate) substrate:
l = no cracking visible to naked eye 2 = cracking barely visible to naked eye .
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3 = cracking readily apparent 4 - adhesive oozing through cracks Ratings ~-3 are acceptable for many purposes.
Peel Value ~ASTM D 3330-78: PSTC - 1 !lIt75!1 The peel adhesion is the force required to remove a PSA coated test specimen from a test panel measured at a specific angle and rate of removal. In the examples, this force is expressed in Newtons pe~
deci~eter width (N/dm) of coated sheet. The procedure followed is:
1) A test specimen 25.4 mm wide is applied to a horizontally positioned clean glass test plate. A 2.2 kg rubber roller is used to press a 12.7 cm length of specimen into firm contact with the glass surface.
2) The free end of the specimen is doubled back nearly touching itself so the angle of removal is 180. The free end is attached to the adhPsion tester scaleO
3) The glass test plate is clamped in the jaws of tensile testing machine whieh moves the plate away from the scale at a constant rate of 2.3 meters per minute.
4) The scal~ reading is recorded as the tape is peeled from the glass surface, and the "Peel Value" in N/dm is calculated.
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Examples ,:
Advantages of this invention are further illustrated by ths following examples, but the particular matèrials and amounts thereof recited in these examples, as well as other conditions and .
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details, should not be construed to unduly limit this invention.
In making each of the ~-olefin polymers, pressure-sensitive adhesives, and tapes as described below, all parts are given by weight. Unless otherwise stated or apparent all materials used in the following examples are commercially availableO
SYNT~ESIS~OF PQ~XQ~IN PRESS~RE-SENSIII~E ADHESIVES
FoR MIÇROWAV;~ ,~CTIV~i ~APl~ ATIONS
Radiation-curab~e Polyolefins Polymers-~
A solution of 112 grams (l.o mole) 1-octene in 450 grams of heptane was polymerized with lo millimoles of diethylaluminum chloride (Et2AlC1) and 4 millimoles of aluminum activated reduced titanium trichloride (AATiCl3) (Stauffer Chemical Co., IncO) at 300C for 4 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture to control the viscosity. Ths (IV) polymer yields and inherent viscosities were:
. Polymer Yield l~) IV (dl/
25A1 85 2.9 A2 80 4.0 A3 78 4.9 . .
. Polym~s B
A solution of 109.8 grams (0.98 mole) 1-octene and 2.16 grams (0.02 mol~) of 4-vinylcyclohex-1-ene (molar charge ratio 98:2) in 450 grams of heptane was - pol~merized with Et2AlCl (5 millimoles) and AATiCl3 t2.S millimole~) ~t 30C for 6 hoursO. The polymer yields and inherent viscosities were:
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Bl 62 2.8 B2 65 5.0 Polymers c A solution of 84 grams (1.0 mole) 1-hexene in 450 grams of heptane was polymerized with the required amount of Et2AlCl (16 millimoles) and AATiCl3 (4.0 millimoles) at 30C for 24 hours. The polymer yields and inherent viscosities were:
Pol~mer Yield (~) IV ~dl/q~
C1 82 1.9 c2 88 2.9 c3 80 6.5 PolYmer D
A solution of 79.8 grams (0.95 mole) 1-hexene and 5.4 gra~s (0.05 mol) 4-vinylcyclohex-1-ene (molar ; 20 charge ratio 95:5) in 450 grams of heptane was : polymerized with Et2AlCl (10 millimoles) and AATiCl3 (4 millimoles) at 30C for 4 hours. During the course of the reaction, hydrogen was bubbled througb the reaction mixture to control the viscosity. The ~ 25 polymer yield was 68 percent and inherent viscosity : was 3.8 dl/gram.
, Thermall~-Cu~able ~ydxosiloxane Polyolefins .
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A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5j in 450 grams of heptane was polymerized with ~t2AlCl (16 millimoles) and ~ATiC13 (4 millimoles) 2t 50C for 10 hours. During th~ :
course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer .
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The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.
Polymer F .
A solution of 106.4 grams (0.95 mole) 1-octene and 5.5 grams (0.0509 mole) 1,7-octadiene (molar .
charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl~
(4.0 millimoles) at 50~C for 10 hours. During the course of the reaction, hydrogen was bubblPd through the reaction mixture. The conversion of the polymer was 65 percent, inherent viscosity was 2.1 dl/gram~
The composition of monomers in the copolymer was 97O3 mole ratio from NMR analysis.
Radiation~Curable HydrosilQxane Polyolefins ~; POlymer_G
A solution of 985.94 grams (11.715 mole) 1- .
hexene and 58.24 grams (0.4831 moIe) 1,7-octadiene (molar-charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiC~3 (6.97 millimoles) at 25~C ~or 20 hours. During the course of the reaction, hydrogen was bubbled through the reac~ion mixture. The conver ion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram.
The composition of mono~ers in the copolymer was :
97.8:2.2 mole ratio from N~R analysis.
Polymer H
A solution of 416.53 grams (3.711 mole) 1-octene and 8.35 grams (Ø0753 mole) 1,7-octadiene (molar charge ratio 98:2) in 450 grams of heptane was polymerized with Et2AlCl (4.14 millimol~s) and AATiCl3 (2.75 millimoles) at 25C for 26 hours~ During the course of the reaction, hydrogen was bubbled through .. . ,. ~ .................................. .
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the reaction mixture. The conversion of the polymer was 56 percent, inherent viscosity was 1.3 dl/g. The composition of monomers in the copolymer was 99:1 mole ratio from NMR analysis.
Moisture-curable Polvolefin .
Polymer I
50 grams of l-hexene-1,7-octadiene (97:3 molar ratio) copolymer having an inherent viscosity in heptane of 1.9 dl/gram was dissolved in 500 grams of toluens. This was refluxed under nitrogen, and about 20 ml of toluene was distilled out to ensure the removal of the water in the system. 2.9 grams of triethoxysilane was added together with bis~divinyltetramethyldisiloxane)Pt(0) catalyst in an amount sufficient to give 100 pp~ of platinum based on combined quantity of polyolefin and alXoxysilane.
The reaction wa~ run for 48 hours. Progress of t~le reaction was monitored by spectral analysis. At the end of the reaction, the copolymer was precipitated in dry methanol under anhydrous conditions. The silane moiety o~ th~ copolymer was found to be 207 mole percent using spectral analysis.
~ essu~e ~ensitive ~dhesive Tapes Solutions of each of tacki~ied and non-tackified Polymers A-D and 1.0 wt% (based on polymer) benzophenone in toluene were knife coated onto the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly~ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thick~ess affording approximat ly 50% optical transmission. The dry coating weights were 3.8 mg/cm2. The hand spreads were cured in . ~ . : . :
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~4 nitrogen in an RPC Processor Model #QC1202 ANIR (from PPG Industries) at 30 cm/sec (60 ft/min).with two standard medium pressure mercury lamps operating at 80 watts/cm2. The lamps were located at a distance of about 9.5 cm from the backing.
The microwave tape performance of various tackified and non-tackified polymexs cured under different conditions is given in Table l. This data shows that in general, radiation curable poly(~-olefin) polymers with higher inherent viscosities produce cured adhesive films having superior shrink back, scorch values, and crack - values. The data also shows that in general, bl~nding tackifying resins with the poly(~-olefin) prior to cure produces cured adhesive films having higher peel adhesion values.
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'7 Pressur~e-Sensitive Adhesive Tapes 31~50 Either Polymer E or Polymer F, hydro-siloxane having the formula Me35iO(SiMeHO)355iMe3 wherein Me=methyl, (amounts indicated in Table 2) and 1.25 parts of 2-ethylhexyl maleate, an inhibitor included to prevent room temperature cure of the composition were dissolved in 300 parts of toluene. A
pressure-sensitive adhesive composition (approximately 33% nonvolatiles) was obtained by adding a platinum catalyst, bis(divinyltetramethyldisiloxane)Pt(0) to this mixture in an amount indicated in Table 2. The composition was coated on the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording approximately 50% optical transmission. The solvent was evaporated off at room temperature followed by heating at 150C for 5 minutes to ensure complete CUre (probably Curing for one minute at that temperature would be suf~icient). The dry coating weights ~ere 3.8 mg/cm2.
Microwave perormance of various tapes were evaluated, and the results are summarized in Table 2.
The ~ata show that moderate to high concentrations of hydro-siloxane crosslinker are required to produce cured PSA films having acceptable shrink back, scorch va1ues, and crack values.
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W092t13923 ~ &v,;, PCT/lJ59R/0~8 ~9 Pressure-Sensitive Adhesive Tapes_5l-62 Either Polymer G or Polymer H, and a hydro-siloxane having the formula Me3SiO(SiMeHO)35SiMe3, (amounts indicated in Table 3) were dissolved in 300 parts of toluene. A pressure-sensitive adhesive composition (approximately 33% nonvolatiles) was obtained by adding cyclopentadienyltrimethylplatinum (CpPtMe3), a thermally stable photocatalyst, to this mixture in an amount indicated in Table 3. The composition was coated on th~ vapor coated side o~
0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor deposited aluminum having a thickness affording approximately 50% optical transmission. The sol~t was evaporated off at room ~emperature. The hand spreads were cured in nitrogen in an RPC Processor Model #ZC1202 ANIR (from PPG Industries) at 30 cm/sec (60 ft/min) with two standard ~edium pressure mercury lamps operating at 80 watts/cm2. The lamps were located at a distance of about 9.5 cm from the backing. The dry coating weights were 3.8 mg/cm2~
Microwave performance of various tapes were evaluated, and the results are summarized in Table 3, This data shows that when the inherent viscosity o~
the radiatio~ curable hydro-silox~ne poly(~-olefin) polymPr is greater that l.5 dl/g, the cured PSA ~ilms tend to have acceptable shrink back, scorch values, and crack values.
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Pressure-Sensitive Adhesive Tapes 63-7?
Solutions of tackified and non-tacXified Polymer I in toluene ~olvent were knire coated on the - s vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording approximately 50~ optical transmission. Some of the solutions contained dibutyltindilaurate catalyst as indicated in Table 4O
The dry coating weights were 3.8 mg/cm~. The microwave tape performance of various tackified and non-tackified polymers under different conditions is give~ in Table 4. Tapes No. 63 and 64, as comparative examples are included in Table 4 to show the need to hydrosilate an ~-olefin polymer in order to moisture-cure the polymerO
Microwave performance of various tapes were evaluated, and the results are su~marized in Table 4.
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zl = Butyl rubber~ 269 (Exxon Chemicals) Z2 = generic name VISTANEX~ MNL-140 (Exxon Chemicals) 0 Z3 = Copolymer of isooctyl acrylate and acrylic acid (95/5) Z4 = 60 parts styrene/isoprene/styrene block copolymer (Kraton 1107~ Shell Chemical Co.) plus 40 parts WINGT~CX PLUS~ (Goodyear Chemical .
Co . ) Z5 = microwave susc~ptor adhesive (NoO 24848~, Swift Adhesives, Downers Grove, IL) The blend was Xnife coated on the vapor coated side of 0.96 mil (24.4 micrometer) biaxially oriented poly(ethylene terephthalate) substrate bearing vapor-deposited aluminum having a thickness affording - approximately 50% optical transmission. After drying as in Examples 1-30, the dry coating weights were 3O8 mg/cm2.
The microwave performance of the tapes is given in Table 5. The data generally shows that as the concentration of radiation curable poly(~-olefin) polymer in the blend increases, the microwave performance of uncured PSA ~ilms generally i-proves.
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Various modifica~ions and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention, and it should be understood that this invention is not to be unduly limited to the illustrative embodiments set forth herein.
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Claims (24)
1. A microwave-active tape comprising a layer of pressure sensitive adhesive (PSA), wherein said PSA comprises a polymeric .alpha.-olefin that has been cured.
2. A microwave-active tape comprising layers of:
(a) backing material, (b) microwave active material, and (c) a pressure sensitive adhesive, wherein the pressure sensitive adhesive comprises a polymeric .alpha.-olefin that has been cured.
(a) backing material, (b) microwave active material, and (c) a pressure sensitive adhesive, wherein the pressure sensitive adhesive comprises a polymeric .alpha.-olefin that has been cured.
3. The microwave-active tape as described in Claim 2, wherein said backing material is an oriented heat-resistant polymeric substrate and said pressure sensitive adhesive has a "Peel" value of at least 5 N/dni and a "Shrink Back" value of 220°C of less than 5%.
4. The microwave-active tape as described in Claim 3, wherein said polymeric .alpha.-olefin is selected from a group consisting of radiation curable poly(.alpha.-olefin), thermally-curable hydrosiloxane poly(.alpha.-olefin), radiation-curable hydrosiloxane poly(.alpha.-olefin), and moisture-curable poly(.alpha.-olefin).
5. The microwave active tape as described in Claim 4, wherein the radiation curable poly(.alpha.-olefin) has an inherent viscosity in the range of 4.0 to 900 dl/g.
6. The microwave active tape as described in Claim 4, wherein the moisture curable poly(.alpha.-olefin) has an inherent viscosity in the range of 4.0 to 9.0 dl/g.
7. The microwave-active tape as described in Claim 4, wherein said poly(.alpha.-olefin) is blended with at least one thermoplastic polymer.
8. The microwave-active tape as described in Claim 2, wherein said microwave active material and pressure-sensitive adhesive are in separate, adjacent layers.
9. The microwave-active tape as described in Claim 2, wherein said backing comprises a low-adhesion carrier web, which can be stripped off after the pressure-sensitive adhesive layer has been applied to a microwave food package.
10. The microwave-active tape as described in Claim 2, wherein said backing comprises a heat-resistant polymeric substrate.
11. The microwave-active tape as described in Claim 10, wherein said heat-resistant polymeric substrate is biaxially-oriented polypropylene.
12. The microwave-active tape as described in Claim 10, wherein said heat-resistant polymeric substrate is biaxially-oriented poly(ethylene terephthalate).
13. The microwave-active tape as described in Claim 10, wherein said heat-resistant polymeric substrate is poly(4-methylpent-1-ene).
14. The microwave active tape as described in Claim 2, wherein said microwave active material converts a portion of the incident microwave energy into sensible heat.
15. The microwave-active tape as described in Claim 14, wherein said microwave active material comprises at least one of (a) a thin metallized polymeric substrate, (b) a thin coating of conductive paint of a polymeric substrate, wherein said conductive paint comprises graphite, carbon black, or metallic particles or flakes, and (c) conductive particles in an organic binder, wherein said particles are carbon black or graphite.
16. The microwave active tape as described in Claim 2, wherein said microwave active material reflects a portion of the incident microwave energy.
17. The microwave active tape as described in Claim 16, wherein said microwave active material comprises at least one of a metal foil having a thickness greater than 1 micrometer, and a metal mesh having openings greater than 2 mm in diameter.
18. A food package comprising a piece of a microwave-active tape comprising layers of (a) an oriented backing material, (b) a microwave-active material, and (c) a pressure-sensitive adhesive, wherein said pressure sensitive adhesive comprises a polymeric .alpha.-olefin that has been cured and has "Peel" value of at least 5 N/dm and a "Shrink Back" value at 200°C of less than 5%.
19. The food package as described in Claim 18, wherein said microwave active tape provides automatic venting.
20. A method of selectively heating and browning food comprising the steps of (1) positioning a first piece of microwave-active tape comprising layers of (a) an oriented backing material, (b) a microwave-active material, and (c) a pressure-sensitive adhesive, wherein said pressure sensitive adhesive comprises a polymeric .alpha.-olefin that has been cured and has a "Peel" value of at least 5 N/dni and a "Shrink Back" value at 200°C of less than 5% adjacent to a first portion of food requiring browning and (2) positioning a second piece of microwave-active tape adjacent to a second portion of food requiring less cooking time than said first portion of food, wherein said first piece of microwave-active tape is a microwave susceptor and said second piece of microwave active tape is a microwave shield.
21. A method of steam venting a food containing comprising a piece of microwave active tape on the outside surface of an air-tight polymer food container, wherein the microwave active tape is a susceptor and comprises layers of (a) an oriented backing material, (b) a microwave-active material, and (c) a pressure-sensitive adhesive, wherein said pressure sensitive adhesive comprises a polymeric .alpha.-olefin that has been cured and has a "Peel" value of at least 5 N/dni and a "Shrink Back" value at 200°C of less than 5%.
22. The microwave active tape as described in Claim 4, wherein the pressure sensitive adhesive is hot melt coatable when the inherent viscosity of the radiation curable poly .alpha.-olefin is in the range of 1.5 to 4.0 dl/g.
23. The microwave active tape as described in Claim 4, wherein the pressure-sensitive adhesive is hot melt coatable when the inherent viscosity of the moisture curable poly .alpha.-olefin is in the range of 1.5 to 4.0 dl/g.
24. The microwave active tape as described in Claim 4, wherein the thermally curable poly .alpha.-olefin is in the range of 1.5 to 9.0 dl/g.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/652,018 | 1991-02-07 | ||
US07/652,018 US5298708A (en) | 1991-02-07 | 1991-02-07 | Microwave-active tape having a cured polyolefin pressure-sensitive adhesive layer |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2100165A1 true CA2100165A1 (en) | 1992-08-08 |
Family
ID=24615189
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002100165A Abandoned CA2100165A1 (en) | 1991-02-07 | 1991-12-19 | Microwave-active tape having a cured polyolefin pressure-sensitive adhesive layer |
Country Status (7)
Country | Link |
---|---|
US (2) | US5298708A (en) |
EP (1) | EP0570512B1 (en) |
JP (1) | JPH06506009A (en) |
AU (1) | AU643586B2 (en) |
CA (1) | CA2100165A1 (en) |
DE (1) | DE69116896T2 (en) |
WO (1) | WO1992013923A1 (en) |
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-
1991
- 1991-02-07 US US07/652,018 patent/US5298708A/en not_active Expired - Fee Related
- 1991-12-19 EP EP92906756A patent/EP0570512B1/en not_active Expired - Lifetime
- 1991-12-19 WO PCT/US1991/008810 patent/WO1992013923A1/en active IP Right Grant
- 1991-12-19 JP JP4506430A patent/JPH06506009A/en active Pending
- 1991-12-19 DE DE69116896T patent/DE69116896T2/en not_active Expired - Fee Related
- 1991-12-19 CA CA002100165A patent/CA2100165A1/en not_active Abandoned
-
1992
- 1992-01-17 AU AU10316/92A patent/AU643586B2/en not_active Ceased
-
1993
- 1993-12-07 US US08/163,680 patent/US5428209A/en not_active Expired - Lifetime
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AU643586B2 (en) | 1993-11-18 |
DE69116896T2 (en) | 1996-09-05 |
US5298708A (en) | 1994-03-29 |
US5428209A (en) | 1995-06-27 |
JPH06506009A (en) | 1994-07-07 |
EP0570512A1 (en) | 1993-11-24 |
AU1031692A (en) | 1992-08-13 |
EP0570512B1 (en) | 1996-01-31 |
WO1992013923A1 (en) | 1992-08-20 |
DE69116896D1 (en) | 1996-03-14 |
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Legal Events
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FZDE | Discontinued |