CA2114547A1 - A Method of Presulfurizing a Catalyst - Google Patents

A Method of Presulfurizing a Catalyst

Info

Publication number
CA2114547A1
CA2114547A1 CA2114547A CA2114547A CA2114547A1 CA 2114547 A1 CA2114547 A1 CA 2114547A1 CA 2114547 A CA2114547 A CA 2114547A CA 2114547 A CA2114547 A CA 2114547A CA 2114547 A1 CA2114547 A1 CA 2114547A1
Authority
CA
Canada
Prior art keywords
catalyst
presulfurizing
sulfidable
elemental sulfur
sulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2114547A
Other languages
French (fr)
Other versions
CA2114547C (en
Inventor
James Dallas Seamans
Charles Terrell Adams
Wendy Beth Dominguez
Andrew An-Ju Chen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CRI International Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2114547A1 publication Critical patent/CA2114547A1/en
Application granted granted Critical
Publication of CA2114547C publication Critical patent/CA2114547C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/06—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof

Abstract

The invention relates to an improved method of presulfurizing a sulfidable metal or metal oxide-containing catalyst which sulfur stripping upon start-up of a reactor and improves catalyst activity. The method comprises contacting porous particles of the sulfidable catalyst with elemental sulfur at a temperature such that said elemental sulfur is incorporated in the pores of said catalyst by sublimation and/or melting and at the same time or subsequently heating the catalyst particles in the presence of a liquid olefinic hydrocarbon at a temperature greater than 150 °C.
CA002114547A 1991-07-30 1992-07-28 A method of presulfurizing a catalyst Expired - Lifetime CA2114547C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/737,630 US5215954A (en) 1991-07-30 1991-07-30 Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst
US737,630 1991-07-30

Publications (2)

Publication Number Publication Date
CA2114547A1 true CA2114547A1 (en) 1993-02-18
CA2114547C CA2114547C (en) 1998-09-22

Family

ID=24964643

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002114547A Expired - Lifetime CA2114547C (en) 1991-07-30 1992-07-28 A method of presulfurizing a catalyst

Country Status (8)

Country Link
US (4) US5215954A (en)
EP (1) EP0598004B1 (en)
JP (1) JP3412764B2 (en)
CA (1) CA2114547C (en)
DE (1) DE69215877T2 (en)
SA (1) SA92130034B1 (en)
SG (1) SG52259A1 (en)
WO (1) WO1993002793A1 (en)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5215954A (en) * 1991-07-30 1993-06-01 Cri International, Inc. Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst
FR2689420B1 (en) * 1992-04-01 1994-06-17 Eurecat Europ Retrait Catalys PROCESS FOR PRESULFURIZING A HYDROCARBON PROCESSING CATALYST.
ZA942966B (en) * 1993-05-04 1995-01-19 Cri Int Inc A method of treating spontaneously combustible catalysts.
US6093309A (en) * 1993-05-04 2000-07-25 Cri International, Inc. Method of treating spontaneously combustible catalysts
US5360779A (en) * 1993-10-14 1994-11-01 Phillips Petroleum Company Preparation of supported sulfur compositions
FR2725381B1 (en) * 1994-10-07 1996-12-13 Eurecat Europ Retrait Catalys OFF-SITE PRETREATMENT PROCESS FOR A HYDROCARBON TREATMENT CATALYST
JPH08129007A (en) * 1994-10-31 1996-05-21 Sekiyu Sangyo Kasseika Center Analysis of sulfur
FR2743512B1 (en) 1996-01-17 1998-03-13 Eurecat Europ Retrait Catalys METHOD FOR INCORPORATING SULFUR IN THE POROSITY OF A HYDROCARBON PROCESSING CATALYST
US5821191A (en) * 1996-06-17 1998-10-13 Shell Oil Company Process for presulfiding hydrocarbon processing catalysts
US5786293A (en) * 1996-06-17 1998-07-28 Shell Oil Company Process for presulfiding hydrocarbon processing catalysts
FR2755379B1 (en) * 1996-11-07 1999-01-08 Inst Francais Du Petrole METHOD FOR SULFURIZING CATALYSTS COMPRISING AT LEAST ONE GROUP VI METAL AND / OR AT LEAST ONE GROUP VIII METAL
FR2758478B1 (en) 1997-01-21 1999-02-26 Elf Aquitaine PROCESS FOR THE PRESULFURIZATION OF CATALYSTS
US5958816A (en) * 1997-02-28 1999-09-28 Tricat, Inc. Method of presulfiding and passivating a hydrocarbon conversion catalyst
DE19745191A1 (en) * 1997-10-13 1999-04-15 Ftu Gmbh Forschung Und Tech En Material for purifying gas to remove mercury and other pollutants
US6444865B1 (en) 1997-12-01 2002-09-03 Shell Oil Company Process wherein a hydrocarbon feedstock is contacted with a catalyst
US6315890B1 (en) * 1998-05-05 2001-11-13 Exxonmobil Chemical Patents Inc. Naphtha cracking and hydroprocessing process for low emissions, high octane fuels
US6803494B1 (en) 1998-05-05 2004-10-12 Exxonmobil Chemical Patents Inc. Process for selectively producing propylene in a fluid catalytic cracking process
US6602403B1 (en) 1998-05-05 2003-08-05 Exxonmobil Chemical Patents Inc. Process for selectively producing high octane naphtha
US6455750B1 (en) 1998-05-05 2002-09-24 Exxonmobil Chemical Patents Inc. Process for selectively producing light olefins
FR2780303B1 (en) * 1998-06-25 2000-07-28 Inst Francais Du Petrole PROCESS FOR SULFURIZING CATALYSTS IN A REDUCING MEDIUM AND USE OF THE SULFURED CATALYST IN REFINING OR HYDROCONVERSION REACTIONS
US6562752B2 (en) * 1998-06-25 2003-05-13 Institut Francais Du Petrole Metallic sulphide catalysts, processes for synthesising said catalysts and use thereof
FR2780314B1 (en) * 1998-06-25 2000-08-11 Inst Francais Du Petrole PROCESS FOR THE SULPHIDATION OF CATALYSTS IN THE PRESENCE OF CARBON AND ELEMENTAL SULFUR
FR2784312B1 (en) * 1998-10-12 2000-11-10 Eurecat Europ Retrait Catalys OFF-SITE PRESULFURIZATION IN THE PRESENCE OF HYDROCARBON MOLECULE
US6291391B1 (en) 1998-11-12 2001-09-18 Ifp North America, Inc. Method for presulfiding and preconditioning of residuum hydroconversion catalyst
CN1107707C (en) * 1999-01-25 2003-05-07 中国石油化工集团公司 Process for presulfurizing hydrocatalyst
US6365542B1 (en) * 1999-01-25 2002-04-02 China Petrochemical Corporation And Research Institute Of Petroleum Processing Presulfurization method of hydrogenation catalyst
US6218333B1 (en) * 1999-02-15 2001-04-17 Shell Oil Company Preparation of a hydrotreating catalyst
US6281158B1 (en) 1999-02-15 2001-08-28 Shell Oil Company Preparation of a co-containing hydrotreating catalyst precursor and catalyst
JP2004500445A (en) 1999-05-28 2004-01-08 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Manufacturing method of lubricating base oil
JP4898069B2 (en) * 2000-06-19 2012-03-14 アンスティテュ フランセ デュ ペトロール Presulfidation and preconditioning method of residual oil hydroconversion catalyst
RU2278147C2 (en) 2001-04-19 2006-06-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method of production of the base oil with the high content of the saturated hydrocarbons
US6929067B2 (en) 2001-04-24 2005-08-16 Shell Oil Company Heat sources with conductive material for in situ thermal processing of an oil shale formation
WO2003033630A1 (en) 2001-10-16 2003-04-24 Shell Internationale Research Maatschappij B.V. Upgrading of pre-processed used oils
CA2463110C (en) 2001-10-24 2010-11-30 Shell Canada Limited In situ recovery from a hydrocarbon containing formation using barriers
US7173160B2 (en) * 2002-07-18 2007-02-06 Chevron U.S.A. Inc. Processes for concentrating higher diamondoids
US20050085378A1 (en) * 2003-09-11 2005-04-21 Peter Birke Particulate catalyst comprising pyrophoric metal and stabilized by wax
US7959796B2 (en) 2003-12-19 2011-06-14 Shell Oil Company Systems, methods, and catalysts for producing a crude product
BRPI0405843B1 (en) 2003-12-19 2014-09-09 Shell Int Research Methods of producing a crude oil product.
US7413646B2 (en) 2003-12-19 2008-08-19 Shell Oil Company Systems and methods of producing a crude product
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
DK1737571T3 (en) * 2004-01-20 2016-10-03 Shell Int Research PROCESS FOR RECOVERY OF CATALYTIC ACTIVITY OF A SPENT hydroprocessing catalyst.
RU2372143C2 (en) * 2004-01-20 2009-11-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method of regenerating catalytic activity of spent water treatment catalyst, spent water treatment catalyst with regenerated catalytic activity, and water treatment method
US7678731B2 (en) * 2004-09-10 2010-03-16 Chevron Usa Inc. Hydroprocessing bulk catalyst and uses thereof
US20060234876A1 (en) * 2005-04-11 2006-10-19 Bhan Opinder K Systems, methods, and catalysts for producing a crude product
CN101166808B (en) 2005-04-11 2013-03-27 国际壳牌研究有限公司 Method and catalyst for producing a crude product having a reduced MCR content
WO2006110556A1 (en) 2005-04-11 2006-10-19 Shell International Research Maatschappij B.V. Method and catalyst for producing a crude product having a reduced nitroge content
US8507404B2 (en) * 2005-07-12 2013-08-13 Exxonmobil Research And Engineering Company Regenerable sulfur traps for on-board vehicle applications
NZ567415A (en) 2005-10-24 2010-12-24 Shell Int Research Solution mining systems and methods for treating hyrdocarbon containing formations
US7793722B2 (en) 2006-04-21 2010-09-14 Shell Oil Company Non-ferromagnetic overburden casing
JP5086344B2 (en) 2006-07-21 2012-11-28 中國石油化工股▲フン▼有限公司 Hydrogenation catalyst composition and method for its preparation and use thereof
US7749374B2 (en) 2006-10-06 2010-07-06 Shell Oil Company Methods for producing a crude product
WO2008051822A2 (en) 2006-10-20 2008-05-02 Shell Oil Company Heating tar sands formations to visbreaking temperatures
AU2008242797B2 (en) 2007-04-20 2011-07-14 Shell Internationale Research Maatschappij B.V. In situ recovery from residually heated sections in a hydrocarbon containing formation
RU2496067C2 (en) 2007-10-19 2013-10-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Cryogenic treatment of gas
CN101418236B (en) * 2007-10-26 2012-09-05 中国石油化工股份有限公司 Hydrocarbons hydrogenation method
US8262905B2 (en) 2009-03-19 2012-09-11 Shell Oil Company Oil and polar additive impregnated composition useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst
CN101665745B (en) * 2009-09-16 2012-02-22 长春惠工净化工业有限公司 Ex-situ presulfiding method of hyrorefining catalysts
US9132421B2 (en) * 2009-11-09 2015-09-15 Shell Oil Company Composition useful in the hydroprocessing of a hydrocarbon feedstock
US8268251B2 (en) * 2010-03-29 2012-09-18 International Business Machines Corporation Early warning sulfur detection based on change in fluorescence intensity of polymer-bound phosphine compound
CN103805235B (en) * 2012-11-03 2015-07-22 中国石油化工股份有限公司 Wet-process starting method of hydrogenation device, low-energy-consumption hydrogenation technology and hydrogenation equipment
US9266056B2 (en) 2013-05-07 2016-02-23 Uop Llc Process for initiating operations of a separation apparatus
EP2944367A1 (en) 2014-05-16 2015-11-18 Shell International Research Maatschappij B.V. Process for reducing the total sulphur content of a gas stream
CN106147842B (en) * 2015-05-14 2018-08-10 中国石油天然气股份有限公司 A kind of passivation start-up method of the gasoline hydrogenation modifying catalyst containing molecular sieve
CN106140320B (en) * 2015-05-14 2018-09-04 中国石油天然气股份有限公司 The passivating method of low boiling point sulfide heaviness catalyst
CN106147829B (en) * 2015-05-14 2018-08-10 中国石油天然气股份有限公司 The start-up method of the gasoline hydrogenation modifying catalyst containing molecular sieve
CN106147828B (en) * 2015-05-14 2018-10-16 中国石油天然气股份有限公司 A kind of start-up method of the sulfide of low boiling point containing molecular sieve heaviness catalyst
CN108026450B (en) 2015-09-07 2020-11-27 国际壳牌研究有限公司 Conversion of biomass to liquid hydrocarbon material
WO2018064990A1 (en) * 2016-10-03 2018-04-12 Ecopetrol S.A. A method for manufacturing catalysts from deactivated hydrotreatment catalysts and the application thereof in a dispersed-bed hydrocracking process

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA759938A (en) * 1967-05-30 D. Holmes Peter Catalysts and reactors containing said catalysts
US2038599A (en) * 1931-01-30 1936-04-28 Standard Ig Co Carrying out catalytic reactions
US3383301A (en) * 1966-01-20 1968-05-14 Gulf Research Development Co Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes
BE794334A (en) * 1972-01-20 1973-07-19 Unilever Nv METAL SULPHIDE CATALYST DEPOSITED ON A SUPPORT
US4089930A (en) * 1976-02-12 1978-05-16 New England Power Service Company Process for the catalytic reduction of nitric oxide
US4177136B1 (en) * 1978-01-03 1994-05-03 Standard Oil Co Ohio Hydrotreating process utilizing elemental sulfur for presulfiding the catalyst
FR2503733B1 (en) * 1981-04-09 1985-09-06 Inst Francais Du Petrole PROCESS FOR HYDROTREATING A HYDROCARBON CHARGE IN THE PRESENCE OF A CATALYST SUBJECT TO PRESULFURATION
US4368141A (en) * 1981-06-24 1983-01-11 Phillips Petroleum Company Olefin disproportionation and catalyst therefor
US4431747A (en) * 1982-07-20 1984-02-14 Exxon Research And Engineering Co. Supported carbon-containing molybdenum and tungsten sulfide catalysts, their preparation and use
FR2548205B1 (en) * 1983-06-30 1985-11-29 Eurecat Europ Retrait Catalys PROCESS FOR PRESULFURIZING A HYDROCARBON PROCESSING CATALYST
US4548920A (en) * 1984-03-26 1985-10-22 Shell Oil Company Hydrodenitrification catalyst
US4672049A (en) * 1984-10-25 1987-06-09 Mobil Oil Corporation Hydroprocessing catalyst
US4934547A (en) * 1987-02-10 1990-06-19 Helena Laboratories Corporation Specimen collection container and non-removable cover
US5051389A (en) * 1987-09-16 1991-09-24 Exxon Research And Engineering Company Catalyst composition prepared by vapor depositing onto a carbon support
US4943547A (en) * 1988-09-13 1990-07-24 Seamans James D Method of presulfiding a hydrotreating catalyst
US5041404A (en) * 1988-09-13 1991-08-20 Cri Ventures, Inc. Method of presulfiding a hydrotreating, hydrocracking or tail gas treating catalyst
US5053376A (en) * 1990-06-04 1991-10-01 Exxon Research & Engineering Company Method of preparing a sulfided molybdenum catalyst concentrate
US5215954A (en) * 1991-07-30 1993-06-01 Cri International, Inc. Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst

Also Published As

Publication number Publication date
WO1993002793A1 (en) 1993-02-18
JPH06509278A (en) 1994-10-20
DE69215877D1 (en) 1997-01-23
JP3412764B2 (en) 2003-06-03
US5292702A (en) 1994-03-08
EP0598004B1 (en) 1996-12-11
CA2114547C (en) 1998-09-22
US5468372A (en) 1995-11-21
SA92130034B1 (en) 2005-11-15
EP0598004A1 (en) 1994-05-25
US5688736A (en) 1997-11-18
SG52259A1 (en) 1998-09-28
DE69215877T2 (en) 1997-07-10
US5215954A (en) 1993-06-01

Similar Documents

Publication Publication Date Title
CA2114547A1 (en) A Method of Presulfurizing a Catalyst
CA2021527A1 (en) Catalyst for the selective oxidation of sulphur compounds to elemental sulphur, process for preparing such a catalyst and method for the selective oxidation of sulphur compounds to elemental sulphur
DE69012450T2 (en) Process for the preparation of metal oxide oxidation catalysts containing iron phosphorus and antimony.
FR2584732B1 (en) PROCESS AND DEVICE FOR THE CATALYTIC CRACKING OF HYDROCARBON CHARGES, WITH CONTROL OF THE REACTION TEMPERATURE
DE69023437D1 (en) Process for the catalytic reduction of nitrogen oxides from exhaust gases.
GB9210629D0 (en) Novel multimetallic sulfide catalysts containing noble metals and hydrodenitrogenation process using same
DE69416507T2 (en) EXOTHERMAL PROCESS WITH POROUS AGENT FOR REGULATING THE REACTION SPEED AND EXOTHERMAL HEAT
AU8983882A (en) Removing metal contaminants from catalyst
EP0361385A3 (en) Deodorizing method and deodorizing catalyst
ZA79629B (en) Reactor for the continuous thermal treatment of solids particularly carbonaceous adsorbents and process of operating the same
DE3160347D1 (en) Catalysts preparation process based on molybden and/or tungsten oxides and oxides of other metals
DE3764521D1 (en) AGENT FOR PREVENTING DEPOSITS IN THERMAL CRACKING PROCESSES.
DE3886991T2 (en) Anti-rust agent, anti-rust coating composition and coating method for the corrosion prevention of metal surfaces.
JPS57119839A (en) Carrying catalyst containing copper and alkali metal and its use for manufacturing 1,2-dichlorethane
HUP9903474A2 (en) A process for presulphiding hydrocarbon conversion catalysts
EP0252761A3 (en) Hydrocarbon cracking catalysts and processes utilizing the same
CA2153748A1 (en) Alumina-Based Catalyst for the Treatment of Gases Containing Sulphur Compounds, Use of These Catalysts for the Treatment and Processes for Treatment of the Said Gases
CA2030278A1 (en) Removal of metallic contaminants from a hydrocarbonaceous liquid
DE3375805D1 (en) Method of carrying out metallurgical or chemical processes, and a low-shaft furnace
JPS56100636A (en) Method of recovering and reusing heavy metal oxidation catalyst from wittenndmttmethod
GB8722458D0 (en) Closures
AU546291B2 (en) Catalysts containing one or more metals and co2 treated support
ZA927956B (en) Catalyst and process for the catalytic partial oxidation of hydrocarbons.
IL66397A0 (en) Liquid-phase process for the oxidation of tetralin
JPS5433503A (en) Treatment of heavy oil

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry