CA2122534A1 - Tri-carbamate-functional crosslinking agents - Google Patents

Tri-carbamate-functional crosslinking agents

Info

Publication number
CA2122534A1
CA2122534A1 CA002122534A CA2122534A CA2122534A1 CA 2122534 A1 CA2122534 A1 CA 2122534A1 CA 002122534 A CA002122534 A CA 002122534A CA 2122534 A CA2122534 A CA 2122534A CA 2122534 A1 CA2122534 A1 CA 2122534A1
Authority
CA
Canada
Prior art keywords
crosslinking agents
carbamate
tri
functional crosslinking
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002122534A
Other languages
French (fr)
Other versions
CA2122534C (en
Inventor
John W. Rehfuss
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of CA2122534A1 publication Critical patent/CA2122534A1/en
Application granted granted Critical
Publication of CA2122534C publication Critical patent/CA2122534C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3831Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing urethane groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40Chemically modified polycondensates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3851Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
    • C08G18/3853Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring containing cyanurate and/or isocyanurate groups
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31942Of aldehyde or ketone condensation product

Abstract

Compounds are described having the formula:
(See formula I), wherein Z represents a cyanuric ring nucleus or the residue of a polyol, L1, L2, and L3 each independently represents a divalent linking group or a covalent bond, and R1, R2, and R3 each independently represents H, alkyl, cycloalkyl, or aryl.
These compounds are useful as crosslinking agents for curable compositions such as coating compositions.
CA 2122534 1993-04-30 1994-04-29 Tri-carbamate-functional crosslinking agents Expired - Lifetime CA2122534C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/056,514 1993-04-30
US08/056,514 US5336566A (en) 1993-04-30 1993-04-30 Tri-carbamate-functional crosslinking agents

Publications (2)

Publication Number Publication Date
CA2122534A1 true CA2122534A1 (en) 1994-10-31
CA2122534C CA2122534C (en) 2003-03-11

Family

ID=22004909

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2122534 Expired - Lifetime CA2122534C (en) 1993-04-30 1994-04-29 Tri-carbamate-functional crosslinking agents

Country Status (10)

Country Link
US (1) US5336566A (en)
EP (1) EP0622387B1 (en)
JP (1) JP3506764B2 (en)
KR (1) KR100326622B1 (en)
CN (1) CN1064054C (en)
AU (1) AU683046B2 (en)
BR (1) BR9401645A (en)
CA (1) CA2122534C (en)
DE (1) DE69411221T2 (en)
ES (1) ES2120535T3 (en)

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US5827930A (en) * 1995-10-06 1998-10-27 Basf Corporation Curable coating composition
US6165618A (en) * 1994-11-03 2000-12-26 Basf Corporation Curable coating compositions containing carbamate resin and additives
US6423788B1 (en) * 1995-10-06 2002-07-23 Basf Corporation Curable coating composition
US5792810A (en) * 1995-10-06 1998-08-11 Basf Corporation Curable coating composition including compound having carbamate and hydroxyl functionality
US5756213A (en) * 1995-10-06 1998-05-26 Basf Corporation Curable coating composition having carbonate-containing component
US5854385A (en) * 1995-10-06 1998-12-29 Basf Corporation Coating compositions with low molecular weight carbamate or urea component
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US5976701A (en) * 1994-04-29 1999-11-02 Ppg Industries Ohio, Inc. Flexible aminoplast-curable film-forming compositions and composite coating
US5709950A (en) * 1994-04-29 1998-01-20 Ppg Industries, Inc. Color-plus-clear composite coatings that contain polymers having carbamate functionality
US5532061A (en) * 1994-12-21 1996-07-02 Basf Corporation Carbamate-functional polyester polymer or oligomer having pendant carbomate groups
US5451656A (en) * 1994-12-21 1995-09-19 Basf Corporation Carbamate-functional polyester polymer or oligomer and coating composition
US6498266B1 (en) 1995-10-06 2002-12-24 Basf Corporation Method of preparing a carbamate- or urea-functional compound
US5766769A (en) * 1995-10-06 1998-06-16 Basf Corporation Curable composition for coatings
US5593733A (en) * 1995-11-21 1997-01-14 Ppg Industries, Inc. Coating composition containing polyester polymers with terminal carbamate groups and polymeric polyol derived from ethylenically unsaturated monomers
US5959040A (en) * 1996-09-04 1999-09-28 Ppg Industries Ohio, Inc. Film-forming composition suitable for use as a monocoat
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US6150465A (en) 1998-10-01 2000-11-21 Basf Corporation Powder slurry compositions with solid particulate carbamate resin component dispersed in liquid aminoplast resin carrier
BR9914138A (en) * 1998-12-14 2001-06-19 Basf Corp Powder composition of slurry containing particulate compounds with carbamate function
AU2027300A (en) * 1998-12-14 2000-07-03 Basf Corporation Particulate carbamate functional compounds and powder coatings comprising the same
JP2002532607A (en) * 1998-12-14 2002-10-02 ビー・エイ・エス・エフ、コーポレーション Granular carbamate-functional compound and powder coating containing said compound
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US6635314B1 (en) 1999-03-17 2003-10-21 E. I. Du Pont De Nemours And Company High solids clear coating composition
DE60001162T3 (en) 1999-03-17 2007-02-15 E.I. Dupont De Nemours And Co., Wilmington SCRATCH-RESISTANT AND ACID-CORROSION-RESISTANT CLEAR LACQUER COMPOSITION WITH HIGH SOLIDS CONTENT
KR20020007330A (en) 1999-03-17 2002-01-26 메리 이. 보울러 High solids acid etch resistant clear coating composition
US6855779B1 (en) 1999-03-17 2005-02-15 E. I. Du Pont De Nemours And Company High solid epoxy, melamine and isocyanate compositions
US6624275B2 (en) 2001-11-02 2003-09-23 Basf Corporation Water- and organic-soluble carbamate material
US6624279B2 (en) 1999-05-21 2003-09-23 Basf Corporation Water-soluble carbamate materials
US6624241B2 (en) 1999-05-21 2003-09-23 Basf Corporation Waterborne coating compositions containing materials dispersed with water-soluble carbamate materials
US6362285B1 (en) 1999-12-15 2002-03-26 Basf Corporation Curable coating compositions containing carbamate functional reactive additives
US6303690B1 (en) 1999-12-15 2001-10-16 Basf Corporation Cathodic electrocoat having a carbamate functional resin and a carbamate functional reactive additive
US6380323B1 (en) 1999-12-15 2002-04-30 Basf Corporation Electrocoat resin compositions containing carbamate functional resins having one or more quaternary ammonium groups and at least one carbamate functional reactive additive
US6391968B1 (en) 1999-12-15 2002-05-21 Basf Corporation Curable coating compositions containing carbamate functional polymers and carbamate functional reactive additives
WO2001049658A1 (en) * 1999-12-30 2001-07-12 Eastman Chemical Company Beta-hydroxy butenyl carbamate, functional oligomers and coatings therefrom
US6541577B2 (en) * 2000-12-06 2003-04-01 Basf Corporation Carbamate functional polymers and oligomers
US20030050388A1 (en) * 2001-09-06 2003-03-13 Strickland Debra S. Aqueous coating composition
EP1456311B1 (en) * 2001-12-17 2012-09-26 BASF Coatings GmbH Urethane polymers that reduce the effect of polylactone linkages
DE60225328T2 (en) * 2001-12-17 2009-02-26 Basf Corp., Southfield ASYMMETRIC DIISOCYANATE MONOMERS IN URETANOLPOLYMERS AND OLIGOMERS FOR CRYSTALLINE INITIALIZATION LIGHTING
US6927271B2 (en) * 2002-01-10 2005-08-09 Basf Corporation Hydroxyl and carbamate functional resins
US6716953B2 (en) * 2002-05-16 2004-04-06 Ppg Industries Ohio, Inc. Etherified carbamate crosslinking agents and their use in curable compositions, particularly film-forming compositions
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US8686090B2 (en) * 2003-12-10 2014-04-01 Basf Coatings Gmbh Use of urea crystals for non-polymeric coatings
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US7858190B2 (en) * 2005-09-15 2010-12-28 Basf Coatings Gmbh Thermosetting coating compositions with multiple cure mechanisms
US20080124532A1 (en) * 2006-11-29 2008-05-29 Basf Corporation Materials and oligomers in low voc coatings
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US20090053420A1 (en) * 2007-08-20 2009-02-26 Basf Corporation Thermosetting coating compositions with multiple cure mechanisms
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Also Published As

Publication number Publication date
DE69411221T2 (en) 1999-02-18
AU6072994A (en) 1994-11-03
EP0622387B1 (en) 1998-06-24
KR100326622B1 (en) 2002-09-05
JPH0726059A (en) 1995-01-27
EP0622387A1 (en) 1994-11-02
AU683046B2 (en) 1997-10-30
ES2120535T3 (en) 1998-11-01
DE69411221D1 (en) 1998-07-30
BR9401645A (en) 1995-03-07
US5336566A (en) 1994-08-09
JP3506764B2 (en) 2004-03-15
CN1064054C (en) 2001-04-04
CA2122534C (en) 2003-03-11
CN1112148A (en) 1995-11-22

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Effective date: 20140429