CA2126222A1 - Phosphonic acid based ion exchange resins - Google Patents

Phosphonic acid based ion exchange resins

Info

Publication number
CA2126222A1
CA2126222A1 CA002126222A CA2126222A CA2126222A1 CA 2126222 A1 CA2126222 A1 CA 2126222A1 CA 002126222 A CA002126222 A CA 002126222A CA 2126222 A CA2126222 A CA 2126222A CA 2126222 A1 CA2126222 A1 CA 2126222A1
Authority
CA
Canada
Prior art keywords
ion exchange
phosphonic acid
exchange resins
acid based
based ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002126222A
Other languages
French (fr)
Other versions
CA2126222C (en
Inventor
E. Philip Horwitz
Spiro D. Alexandratos
Renato Chiarizia
Ralph C. Gatrone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arch Development Corp
University of Tennessee Research Foundation
Original Assignee
E. Philip Horwitz
Spiro D. Alexandratos
Renato Chiarizia
Ralph C. Gatrone
Arch Development Corp.
The University Of Tennessee Research Corporation
Arch Development Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E. Philip Horwitz, Spiro D. Alexandratos, Renato Chiarizia, Ralph C. Gatrone, Arch Development Corp., The University Of Tennessee Research Corporation, Arch Development Corporation filed Critical E. Philip Horwitz
Publication of CA2126222A1 publication Critical patent/CA2126222A1/en
Application granted granted Critical
Publication of CA2126222C publication Critical patent/CA2126222C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/12—Compounds containing phosphorus

Abstract

An ion exchange resin for extracting metal ions from a liquid waste stream. An ion excahnge resin is prepared by copolymerizing a vinylidene disphosphonic acid with styrene, acrylonitrile and divinylbenzene.
CA002126222A 1991-12-20 1992-12-18 Phosphonic acid based ion exchange resins Expired - Lifetime CA2126222C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/811,098 1991-12-20
US07/811,098 US5281631A (en) 1991-12-20 1991-12-20 Phosphonic acid based ion exchange resins
PCT/US1992/011105 WO1993012882A1 (en) 1991-12-20 1992-12-18 Phosphonic acid based ion exchange resins

Publications (2)

Publication Number Publication Date
CA2126222A1 true CA2126222A1 (en) 1993-07-08
CA2126222C CA2126222C (en) 2003-01-28

Family

ID=25205548

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002126222A Expired - Lifetime CA2126222C (en) 1991-12-20 1992-12-18 Phosphonic acid based ion exchange resins

Country Status (7)

Country Link
US (3) US5281631A (en)
EP (1) EP0618843B1 (en)
JP (1) JP3345008B2 (en)
AT (1) ATE214303T1 (en)
CA (1) CA2126222C (en)
DE (1) DE69232489T2 (en)
WO (1) WO1993012882A1 (en)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5281631A (en) * 1991-12-20 1994-01-25 Arch Development Corp. Phosphonic acid based ion exchange resins
CA2130248A1 (en) * 1994-08-16 1996-02-17 Harald D. H. Stover Method of forming polymer microspheres
US5618851A (en) * 1995-02-06 1997-04-08 Arch Development Corp. Grafted methylenediphosphonate ion exchange resins
US5491048A (en) * 1995-02-21 1996-02-13 Eastman Kodak Company Removal of tin from seasoned photographic color developers
US5531899A (en) * 1995-06-06 1996-07-02 Millipore Investment Holdings Limited Ion exchange polyethylene membrane and process
US5651883A (en) * 1995-06-06 1997-07-29 Argonne National Laboratory/University Of Chicago Development Corp. Method for the chromatographic separation of cations from aqueous samples
WO1996041145A1 (en) * 1995-06-07 1996-12-19 Eichrom Industries, Inc. Process and apparatus for separating tritiated water
DE19533688A1 (en) * 1995-09-12 1997-03-13 Bayer Ag Process for the recovery of catalysts in the production of adipic acid
US5582737A (en) * 1995-11-07 1996-12-10 Eichrom Industries, Inc. Ion exchange and regeneration process for separation and removal of iron (III) ions from aqueous sulfuric acid metal ion-containing solutions
EP0780406A3 (en) * 1995-12-21 1997-08-20 Albright & Wilson Uk Ltd Phosphonic acid polymers
US5759716A (en) 1996-04-08 1998-06-02 Ensci Inc Battery element containing metal inhibiting additives
US6350541B1 (en) 1996-07-02 2002-02-26 Ensci Inc. Battery element containing efficiency improving additives
US6268081B1 (en) 1996-07-02 2001-07-31 Ensci Inc Battery element containing efficiency improving additives
US6168886B1 (en) * 1996-07-02 2001-01-02 Ensci Inc Battery element containing metal macroporous additives
US5854968A (en) * 1997-06-09 1998-12-29 Arch Development Corporation Process and apparatus for the production of BI-213 cations
US5948264A (en) * 1998-02-06 1999-09-07 Eichrom Industries, Inc. Ion exchange and regeneration process for separation and removal of iron (III) ions from aqueous sulfuric acid metal ion-containing solutions
US6511775B2 (en) 1998-03-20 2003-01-28 Ensci Inc. Separator containing efficiency improving additives for a lead acid batteries
US5945342A (en) * 1998-05-18 1999-08-31 Westinghouse Savannah River Company Method for digesting spent ion exchange resins and recovering actinides therefrom using microwave radiation
WO2000001458A1 (en) 1998-07-02 2000-01-13 Arch Development Corporation Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same
US6232353B1 (en) * 1998-07-02 2001-05-15 Arch Development Corporation Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same
DE19829827C2 (en) * 1998-07-03 2001-05-31 Fraunhofer Ges Forschung Process for heavy metal separation
FR2794991B1 (en) * 1999-06-15 2002-03-15 Rhone Poulenc Fibres PROCESS FOR SEPARATING IRON FROM OTHER METAL IONS, AND PROCESS FOR RECYCLING CATALYSTS IN OXIDATION REACTIONS OF CARBOXYLIC ACID
WO2001049389A1 (en) * 2000-01-03 2001-07-12 Hydromatix, Inc. Method and apparatus for metal removal by ion exchange
US6597723B1 (en) * 2000-03-21 2003-07-22 Interdigital Technology Corporation Weighted open loop power control in a time division duplex communication system
US6514414B1 (en) 2000-09-08 2003-02-04 Clariant Finance (Bvi) Limited Process for separation and removal of iron ions from basic zinc solution
US6852296B2 (en) * 2001-06-22 2005-02-08 Pg Research Foundation Production of ultrapure bismuth-213 for use in therapeutic nuclear medicine
US6616846B2 (en) 2001-08-28 2003-09-09 Mds (Canada) Inc. Extraction of phosphonates
US6998052B2 (en) * 2002-04-12 2006-02-14 Pg Research Foundation Multicolumn selectivity inversion generator for production of ultrapure radionuclides
WO2003101724A1 (en) * 2002-05-31 2003-12-11 Sun Drilling Products Corp. Low density polymer beads
US7429394B2 (en) * 2004-03-30 2008-09-30 Relypsa, Inc. Ion binding compositions
US8192758B2 (en) * 2004-03-30 2012-06-05 Relypsa, Inc. Ion binding compositions
CA2558029C (en) * 2004-03-30 2013-05-07 Ilypsa, Inc. Ion binding polymers and uses thereof
US7854924B2 (en) * 2004-03-30 2010-12-21 Relypsa, Inc. Methods and compositions for treatment of ion imbalances
US8282960B2 (en) * 2004-03-30 2012-10-09 Relypsa, Inc. Ion binding compositions
US7556799B2 (en) * 2004-03-30 2009-07-07 Relypsa, Inc. Ion binding polymers and uses thereof
US8076432B2 (en) * 2004-07-07 2011-12-13 Unichem Technologies, Inc. Phosphonic compounds and methods of use thereof
GB0417344D0 (en) 2004-08-04 2004-09-08 Phosphonics Ltd Substituted organopolysiloxanes and use thereof
KR100668339B1 (en) 2005-06-18 2007-01-12 삼성전자주식회사 Ion exchangeable mixture and method of producing the same
US20070009409A1 (en) * 2005-07-11 2007-01-11 Hariprasad Gali 212Bi or 213Bi Generator from supported parent isotope
WO2007041569A1 (en) 2005-09-30 2007-04-12 Ilypsa, Inc. Methods and compositions for selectively removing potassium ion from the gastrointestinal tract of a mammal
AU2006294455B2 (en) * 2005-09-30 2013-06-20 Relypsa, Inc. Methods for preparing core-shell composites having cross-linked shells and core-shell composites resulting therefrom
US7291273B2 (en) * 2005-12-12 2007-11-06 General Electric Company Methods for removing metals from plating operation
US7723114B1 (en) 2006-01-11 2010-05-25 Clemson University Methods and systems for detection of radionuclides
CN101535400A (en) * 2006-09-21 2009-09-16 清洁技术有限公司 An ion exchange resin and a process for the use thereof
DE102007041361A1 (en) 2007-08-30 2009-03-05 Lanxess Deutschland Gmbh Adsorption of radionuclides
DE102007060790A1 (en) * 2007-12-18 2009-06-25 Lanxess Deutschland Gmbh Process for the preparation of cation exchangers
US8133740B1 (en) 2008-08-19 2012-03-13 Clemson University Research Foundation Colorimetric detection of uranium in water
WO2010022380A2 (en) 2008-08-22 2010-02-25 Relypsa, Inc. Linear polyol stabilized polyfluoroacrylate compositions
DE112009002063T5 (en) * 2008-08-22 2012-01-12 Relypsa, Inc. Crosslinked cation exchange polymers, compositions and use for treating hyperkalemia
US20100104527A1 (en) * 2008-08-22 2010-04-29 Relypsa, Inc. Treating hyperkalemia with crosslinked cation exchange polymers of improved physical properties
CZ303585B6 (en) * 2008-12-15 2012-12-27 Ústav makromolekulární chemie, AV CR, v. v. i. Polymeric aliphatic ion-exchange materials and methods of using the same
US8101700B2 (en) * 2008-12-31 2012-01-24 Unichem Technologies, Inc. Phosphonic polymers having a phosphinate backbone and methods of making and using thereof
WO2010082990A1 (en) * 2009-01-15 2010-07-22 Dow Global Technologies Inc. Ion exchange resins comprising interpenetrating polymer networks and their use in chromium removal
RU2462297C2 (en) * 2010-09-21 2012-09-27 Учреждение Российской академии наук Ордена Ленина и Ордена Октябрьской Революции Институт геохимии и аналитической химии им. В.И. Вернадского РАН (ГЕОХИ РАН) Method of producing sorption materials based on carbon nanotubes
RU2489353C2 (en) * 2011-01-25 2013-08-10 Закрытое акционерное общество "Инновации ленинградских институтов и предприятий" (ЗАО ИЛИП) Method of purifying aluminium salts from iron
US8507284B2 (en) 2011-07-14 2013-08-13 Uchicago Argonne, Llc Method and apparatus for extraction of strontium from urine
RU2560361C2 (en) * 2012-07-29 2015-08-20 Закрытое Акционерное Общество "Аксион-Редкие И Драгоценные Металлы" Method for producing complex-forming sorbent for selective recovery of indium
JP6475624B2 (en) 2012-10-08 2019-02-27 レリプサ， インコーポレイテッド Potassium binding agents for the treatment of hypertension and hyperkalemia
RU2531916C1 (en) 2013-04-26 2014-10-27 Закрытое Акционерное Общество "Аксион-Редкие И Драгоценные Металлы" Method of producing sorbent for selective extraction of scandium ions
US9074162B1 (en) 2014-02-07 2015-07-07 Ecolab Usa Inc. Detergent compositions comprising vinylidene diphosphonic acid polymers
US10641751B2 (en) * 2015-06-19 2020-05-05 Dionex Corporation Ion exchange chromatography column, method, and system thereof
US20170065731A1 (en) * 2015-09-06 2017-03-09 Medical Theranostics Inc. Method, Apparatus, and System for Radiation Therapy
US10379090B2 (en) 2016-06-17 2019-08-13 Dionex Corporation Charge reversible ion exchange resins, chromatography column, method, and system thereof
KR102646311B1 (en) * 2019-02-08 2024-03-13 엔테그리스, 아이엔씨. Ligand-Modified Filters and Methods for Reducing Metals from Liquid Compositions
GB202311428D0 (en) 2023-07-25 2023-09-06 Phosphonics Ltd Organopolysiloxanes and use thereof

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2764563A (en) * 1956-09-25 Cation exchange resins containing phos-
DE1106963B (en) * 1959-11-11 1961-05-18 Hoechst Ag Process for the production of polyvinylphosphonic acid
US3062792A (en) * 1960-03-01 1962-11-06 Eastman Kodak Co Polymers derived from tetraalkyl vinylidenediphosphonates
US3544509A (en) * 1967-05-08 1970-12-01 Monsanto Co Diphosphonic acids and salts thereof as flame retardants
US3489706A (en) * 1967-05-16 1970-01-13 Goodrich Co B F Bis(beta-chloroethyl)vinyl phosphonate copolymer compositions
US3686290A (en) * 1969-05-29 1972-08-22 Robert L Carroll Processes for preparing olefinic organo-phosphorus compounds
US3993715A (en) * 1974-04-01 1976-11-23 Stauffer Chemical Company Process for forming fire retardant polymers of bis (hydrocarbyl) vinylphosphonate
US3928192A (en) * 1974-06-06 1975-12-23 Aerojet General Co Buffered, weak ion-exchange water demineralization process
US4362659A (en) * 1978-03-09 1982-12-07 Pedro B. Macedo Fixation of radioactive materials in a glass matrix
BE879880A (en) * 1978-11-09 1980-05-07 Macedo Pedro B FIXING BY ION EXCHANGE OF TOXIC MATERIALS IN A GLASS MATRIX
US4376706A (en) * 1979-04-02 1983-03-15 Petro-Metals Recovery Systems Limited Chromium and zinc removal and recovery by ion exchange
FR2489711A1 (en) * 1980-04-21 1982-03-12 Minemet Rech Sa EXCHANGE COMPOSITIONS OF METAL CATIONS
JPS58222095A (en) * 1982-06-16 1983-12-23 Lion Corp Salt of 1-methacryloxyethane-1,1-diphosphonic acid
DE3314569A1 (en) * 1983-04-22 1984-10-25 Cassella Ag, 6000 Frankfurt NETWORKED HYDROPHILE COPOLYMERISATE, THEIR PRODUCTION AND USE
US4758635A (en) * 1984-07-02 1988-07-19 The Dow Chemical Company Polyamindoamine based metal ion control compound
US4939284A (en) * 1985-11-04 1990-07-03 The Procter & Gamble Company Process for the manufacture of tetraalkyl ethenylidenebisphosphonate esters
DE3704307A1 (en) * 1987-02-12 1988-08-25 Dow Chemical Gmbh COMPLEX-FORMING RESIN OF THE GELTYPS AND ITS USE TO REDUCE THE CONCENTRATION OF MULTI-VALUE EARTH ALKALI AND / OR HEAVY METAL IONS IN SOLUTIONS
DE3707149A1 (en) * 1987-03-06 1988-09-15 Hoechst Ag METHOD FOR THE PRODUCTION OF VINYLPHOSPHONESEUREDIALKYLESTER
US4902426A (en) * 1987-06-30 1990-02-20 Pedro B. Macedo Ion exchange compositions
US4830837A (en) * 1987-08-03 1989-05-16 Olin Corporation Process for removing aluminum from concentrated alkali metal halide brines
EP0461822B1 (en) * 1990-06-07 1996-05-08 Korea Research Institute Of Chemical Technology Phosphoric acid-type chelate resin as uranyl ion adsorbent
US5091491A (en) * 1990-11-01 1992-02-25 W. R. Grace & Co.-Conn. Water-soluble allylphosphonate copolymers
US5281631A (en) * 1991-12-20 1994-01-25 Arch Development Corp. Phosphonic acid based ion exchange resins

Also Published As

Publication number Publication date
ATE214303T1 (en) 2002-03-15
US5281631A (en) 1994-01-25
EP0618843A1 (en) 1994-10-12
JPH07508452A (en) 1995-09-21
EP0618843A4 (en) 1995-04-12
WO1993012882A1 (en) 1993-07-08
JP3345008B2 (en) 2002-11-18
DE69232489T2 (en) 2002-09-26
US5449462A (en) 1995-09-12
EP0618843B1 (en) 2002-03-13
CA2126222C (en) 2003-01-28
DE69232489D1 (en) 2002-04-18
US5539003A (en) 1996-07-23

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Effective date: 20121218