CA2128430A1 - Production of Hydrogen Peroxide - Google Patents

Production of Hydrogen Peroxide

Info

Publication number
CA2128430A1
CA2128430A1 CA 2128430 CA2128430A CA2128430A1 CA 2128430 A1 CA2128430 A1 CA 2128430A1 CA 2128430 CA2128430 CA 2128430 CA 2128430 A CA2128430 A CA 2128430A CA 2128430 A1 CA2128430 A1 CA 2128430A1
Authority
CA
Canada
Prior art keywords
hydrogen peroxide
catalyst
source
production
fluorinated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2128430
Other languages
French (fr)
Other versions
CA2128430C (en
Inventor
Karl T. Chuang
Bing Zhou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nouryon Pulp and Performance Chemicals AB
Original Assignee
Karl T. Chuang
Bing Zhou
Eka Nobel Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Karl T. Chuang, Bing Zhou, Eka Nobel Ab filed Critical Karl T. Chuang
Publication of CA2128430A1 publication Critical patent/CA2128430A1/en
Application granted granted Critical
Publication of CA2128430C publication Critical patent/CA2128430C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/029—Preparation from hydrogen and oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B01J35/23—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension

Abstract

The invention a relates to hydrogen peroxide manufacture, and catalyst therefor, by direct oxidation of hydrogen with oxygen in an acidic aqueous medium. The catalyst includes a Group VIII metal on a partially hydrophobic, partially hydrophilic support, such as Pd on fluorinated carbon. Improvements in H2O2 selectivity and catalyst stability are achieved by adding a source of sodium and chloride ions to the reaction medium and, in the case of a fluorinated carbon support, adding a source of fluoride ions.
CA002128430A 1992-01-21 1993-01-21 Production of hydrogen peroxide Expired - Fee Related CA2128430C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/823,688 US5338531A (en) 1992-01-21 1992-01-21 Production of hydrogen peroxide
US07/823,688 1992-01-21

Publications (2)

Publication Number Publication Date
CA2128430A1 true CA2128430A1 (en) 1993-07-22
CA2128430C CA2128430C (en) 1998-10-27

Family

ID=25239423

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002128430A Expired - Fee Related CA2128430C (en) 1992-01-21 1993-01-21 Production of hydrogen peroxide

Country Status (16)

Country Link
US (3) US5338531A (en)
EP (1) EP0623095A1 (en)
JP (1) JP3375628B2 (en)
KR (2) KR940703780A (en)
AU (1) AU670058B2 (en)
BR (1) BR9305762A (en)
CA (1) CA2128430C (en)
CZ (1) CZ173794A3 (en)
FI (1) FI111708B (en)
HU (1) HU215565B (en)
NO (1) NO313091B1 (en)
NZ (1) NZ246548A (en)
RO (1) RO111175B1 (en)
SK (1) SK281953B6 (en)
UA (1) UA26158C2 (en)
WO (1) WO1993014025A1 (en)

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US5338531A (en) * 1992-01-21 1994-08-16 Chuang Karl T Production of hydrogen peroxide
CA2122881A1 (en) * 1993-05-06 1994-11-07 Michiya Kawakami Process for producing hydrogen peroxide
SE9600884L (en) * 1996-03-07 1997-09-08 Bengtsson Erik Process Design Process for the preparation of hydrogen peroxide by direct synthesis between hydrogen and oxygen in contact with a catalyst in a solvent
SE9600885L (en) * 1996-03-07 1997-09-08 Bengtsson Erik Process Design Process for producing hydrogen peroxide by direct synthesis between hydrogen and oxygen in contact with catalyst
SE9602484D0 (en) * 1996-06-24 1996-06-24 Eka Chemicals Ab Method of producing a chemical compound
DE19642770A1 (en) * 1996-10-16 1998-04-23 Basf Ag Process for the production of hydrogen peroxide
CN1116223C (en) 1997-12-22 2003-07-30 阿克佐诺贝尔公司 Process for production of hydragen peroxide
US6576214B2 (en) * 2000-12-08 2003-06-10 Hydrocarbon Technologies, Inc. Catalytic direct production of hydrogen peroxide from hydrogen and oxygen feeds
US6168775B1 (en) * 1998-08-26 2001-01-02 Hydrocarbon Technologies, Inc. Catalyst and process for direct catalystic production of hydrogen peroxide, (H2O2)
US6346228B1 (en) * 1999-02-19 2002-02-12 Council Of Scientific And Industrial Research Hydrophobic multicomponent catalyst useful for direct oxidation of hydrogen to hydrogen peroxide
IT1318550B1 (en) 2000-06-01 2003-08-27 Eni Spa CATALYST AND PROCESS FOR DIRECT SYNTHESIS OF OXYGEN WATER.
US6448199B1 (en) 2000-09-05 2002-09-10 Council Of Scientific & Industrial Research Hydrophobic composite Pd-membrane catalyst useful for non-hazardous direct oxidation of hydrogen by oxygen to hydrogen peroxide and method of its preparation
US6432376B1 (en) 2000-09-05 2002-08-13 Council Of Scientific & Industrial Research Membrane process for the production of hydrogen peroxide by non-hazardous direct oxidation of hydrogen by oxygen using a novel hydrophobic composite Pd-membrane catalyst
DE10048844A1 (en) * 2000-10-02 2002-04-11 Basf Ag Process for the production of platinum metal catalysts
KR100383218B1 (en) * 2000-10-26 2003-05-12 한국화학연구원 Direct manufacturing method of hydrogen peroxide
US6534440B2 (en) * 2000-11-29 2003-03-18 Council Of Scientific And Industrial Research Process for the activation of a metallic palladium based catalyst useful for the direct oxidation of hydrogen to hydrogen peroxide
US7115192B1 (en) 2001-05-07 2006-10-03 Uop Llc Apparatus and process for the synthesis of hydrogen peroxide directly from hydrogen and oxygen
US20060131161A1 (en) * 2001-05-07 2006-06-22 Towler Gavin P Air sanitation with hydrogen peroxide
JP2003050068A (en) * 2001-05-30 2003-02-21 Permelec Electrode Ltd Ice composition containing hydrogen peroxide, and method of preserving perishable food
US6768013B1 (en) 2001-06-15 2004-07-27 Uop Llc Intrinsically safe oxidation process
DE10153546A1 (en) * 2001-10-30 2003-05-22 Degussa Direct synthesis of hydrogen peroxide and its integration in oxidation processes
EP1344747B1 (en) * 2002-03-14 2012-02-08 Repsol Quimica S.A. Process to obtain hydrogen peroxide
ATE453603T1 (en) * 2003-02-03 2010-01-15 Repsol Quimica Sa INTEGRATED PROCESS FOR THE SELECTIVE OXYDATION OF ORGANIC COMPOUNDS
US20060102492A1 (en) * 2003-02-19 2006-05-18 Corradi Jason T In situ generation of hydrogen peroxide
US7067103B2 (en) * 2003-03-28 2006-06-27 Headwaters Nanokinetix, Inc. Direct hydrogen peroxide production using staged hydrogen addition
US7192562B1 (en) 2003-04-17 2007-03-20 Uop Llc Hydrogen-oxygen mixer-sparger
US7442350B1 (en) * 2003-04-17 2008-10-28 Uop Llc Plate design for mixer sparger
US7569508B2 (en) * 2004-11-17 2009-08-04 Headwaters Technology Innovation, Llc Reforming nanocatalysts and method of making and using such catalysts
US7045479B2 (en) * 2003-07-14 2006-05-16 Headwaters Nanokinetix, Inc. Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions
US7655137B2 (en) 2003-07-14 2010-02-02 Headwaters Technology Innovation, Llc Reforming catalysts having a controlled coordination structure and methods for preparing such compositions
US7011807B2 (en) * 2003-07-14 2006-03-14 Headwaters Nanokinetix, Inc. Supported catalysts having a controlled coordination structure and methods for preparing such catalysts
US7144565B2 (en) * 2003-07-29 2006-12-05 Headwaters Nanokinetix, Inc. Process for direct catalytic hydrogen peroxide production
US20050201925A1 (en) * 2004-03-09 2005-09-15 Bi Le-Khac Process for making hydrogen peroxide
US7632775B2 (en) * 2004-11-17 2009-12-15 Headwaters Technology Innovation, Llc Multicomponent nanoparticles formed using a dispersing agent
US7449423B2 (en) * 2005-01-14 2008-11-11 Headwaters Technology Innovation, Llc Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method
US7803201B2 (en) * 2005-02-09 2010-09-28 Headwaters Technology Innovation, Llc Organically complexed nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
US7856992B2 (en) 2005-02-09 2010-12-28 Headwaters Technology Innovation, Llc Tobacco catalyst and methods for reducing the amount of undesirable small molecules in tobacco smoke
US7045481B1 (en) 2005-04-12 2006-05-16 Headwaters Nanokinetix, Inc. Nanocatalyst anchored onto acid functionalized solid support and methods of making and using same
US7357903B2 (en) * 2005-04-12 2008-04-15 Headwaters Heavy Oil, Llc Method for reducing NOx during combustion of coal in a burner
US7326399B2 (en) * 2005-04-15 2008-02-05 Headwaters Technology Innovation, Llc Titanium dioxide nanoparticles and nanoparticle suspensions and methods of making the same
US20060258875A1 (en) * 2005-05-10 2006-11-16 Clementine Reyes Methods for manufacturing supported nanocatalysts and methods for using supported nanocatalysts
US7396795B2 (en) * 2005-08-31 2008-07-08 Headwaters Technology Innovation, Llc Low temperature preparation of supported nanoparticle catalysts having increased dispersion
US7288500B2 (en) 2005-08-31 2007-10-30 Headwaters Technology Innovation, Llc Selective hydrogenation of nitro groups of halonitro aromatic compounds
US7892299B2 (en) * 2005-09-15 2011-02-22 Headwaters Technology Innovation, Llc Methods of manufacturing fuel cell electrodes incorporating highly dispersed nanoparticle catalysts
US7935652B2 (en) * 2005-09-15 2011-05-03 Headwaters Technology Innovation, Llc. Supported nanoparticle catalysts manufactured using caged catalyst atoms
JP4709954B2 (en) * 2005-09-21 2011-06-29 田中貴金属工業株式会社 Direct synthesis of hydrogen peroxide
US7718158B2 (en) * 2005-10-13 2010-05-18 Lyondell Chemical Technology, L.P. Polymer-encapsulated ion-exchange resin
US7528269B2 (en) * 2005-12-20 2009-05-05 Lyondell Chemical Technology, L.P. Process for oxidizing organic compounds
US7758660B2 (en) * 2006-02-09 2010-07-20 Headwaters Technology Innovation, Llc Crystalline nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
US7718710B2 (en) * 2006-03-17 2010-05-18 Headwaters Technology Innovation, Llc Stable concentrated metal colloids and methods of making same
US7514476B2 (en) * 2006-03-17 2009-04-07 Headwaters Technology Innovation, Llc Stable concentrated metal colloids and methods of making same
US7632774B2 (en) * 2006-03-30 2009-12-15 Headwaters Technology Innovation, Llc Method for manufacturing supported nanocatalysts having an acid-functionalized support
US7541309B2 (en) * 2006-05-16 2009-06-02 Headwaters Technology Innovation, Llc Reforming nanocatalysts and methods of making and using such catalysts
US7604719B2 (en) * 2006-05-25 2009-10-20 Uop Llc In situ generation of hydrogen peroxide
US7357909B2 (en) * 2006-06-28 2008-04-15 Lyondell Chemical Technology, L.P. Process for producing hydrogen peroxide
US7563742B2 (en) 2006-09-22 2009-07-21 Headwaters Technology Innovation, Llc Supported nickel catalysts having high nickel loading and high metal dispersion and methods of making same
US7601668B2 (en) 2006-09-29 2009-10-13 Headwaters Technology Innovation, Llc Methods for manufacturing bi-metallic catalysts having a controlled crystal face exposure
US7534741B2 (en) * 2007-02-09 2009-05-19 Headwaters Technology Innovation, Llc Supported nanocatalyst particles manufactured by heating complexed catalyst atoms
EP2000205A1 (en) * 2007-06-01 2008-12-10 Repsol Ypf S.A. Process to obtain hydrogen peroxide
US7501532B1 (en) 2007-11-20 2009-03-10 Lyondell Chemical Technology, L.P. Process for producing hydrogen peroxide
CN101850272B (en) * 2010-06-22 2011-12-14 中国工程物理研究院核物理与化学研究所 Method for preparing hydrophobic catalyst by freezing molding
US9610573B2 (en) 2011-07-15 2017-04-04 Solvay Sa Process to obtain hydrogen peroxide, and catalyst supports for the same process
WO2015124533A1 (en) * 2014-02-21 2015-08-27 Solvay Sa Process to obtain hydrogen peroxide, and catalyst and catalysts supports for said process
SI25590A (en) 2018-01-15 2019-07-31 Univerza V Ljubljani Process for preparation of isotope labeled hydrogen peroxide
WO2020138800A1 (en) * 2018-12-26 2020-07-02 코오롱인더스트리 주식회사 Catalyst, method for producing same, electrode comprising same, membrane-electrode assembly comprising same, and fuel cell comprising same

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US4681751A (en) * 1983-06-22 1987-07-21 E. I. Du Pont De Nemours And Company Catalytic process for making H2 O2 from hydrogen and oxygen
EP0132294B1 (en) * 1983-06-22 1987-03-11 E.I. Du Pont De Nemours And Company Catalytic process for making h2o2 from hydrogen and oxygen
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Also Published As

Publication number Publication date
EP0623095A1 (en) 1994-11-09
BR9305762A (en) 1997-01-28
HUT69291A (en) 1995-09-28
WO1993014025A1 (en) 1993-07-22
SK88294A3 (en) 1995-01-12
FI943377A (en) 1994-07-15
CA2128430C (en) 1998-10-27
FI943377A0 (en) 1994-07-15
NO942714L (en) 1994-07-20
HU9402151D0 (en) 1994-09-28
NZ246548A (en) 1995-09-26
US5925588A (en) 1999-07-20
KR940703780A (en) 1994-12-12
AU670058B2 (en) 1996-07-04
SK281953B6 (en) 2001-09-11
FI111708B (en) 2003-09-15
JPH07503447A (en) 1995-04-13
US5846898A (en) 1998-12-08
US5338531A (en) 1994-08-16
NO313091B1 (en) 2002-08-12
JP3375628B2 (en) 2003-02-10
AU3342393A (en) 1993-08-03
KR0118992B1 (en) 1997-09-30
HU215565B (en) 1999-01-28
UA26158C2 (en) 1999-06-07
CZ173794A3 (en) 1995-08-16
NO942714D0 (en) 1994-07-20
RO111175B1 (en) 1996-07-30

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