CA2143404A1 - Process for Removal of Heteroatoms Under Reducing Conditions in Supercritical Water - Google Patents

Process for Removal of Heteroatoms Under Reducing Conditions in Supercritical Water

Info

Publication number
CA2143404A1
CA2143404A1 CA2143404A CA2143404A CA2143404A1 CA 2143404 A1 CA2143404 A1 CA 2143404A1 CA 2143404 A CA2143404 A CA 2143404A CA 2143404 A CA2143404 A CA 2143404A CA 2143404 A1 CA2143404 A1 CA 2143404A1
Authority
CA
Canada
Prior art keywords
removal
supercritical water
highly refractory
moiety
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2143404A
Other languages
French (fr)
Other versions
CA2143404C (en
Inventor
Michael Siskin
David T. Ferrughelli
Alan R. Katritzky
William N. Olmstead
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of CA2143404A1 publication Critical patent/CA2143404A1/en
Application granted granted Critical
Publication of CA2143404C publication Critical patent/CA2143404C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/322—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/952—Solid feed treatment under supercritical conditions

Abstract

A process for heteroatom removal-enhancing hydrogenation of highly refractory aromatic ring structures that involves contacting a highly refractory structure having at least one aryl linkage connecting a first heteroaryl moiety and a moiety selected from the group consisting of an aryl moiety and a second heteroaryl moiety with supercritical water having a temperature of from about 400°C to about 600°C in the presence of from about 3.4 MPa to about 18.6 MPa of CO to produce lower molecular weight products having decreased aromatic and heteroatom content. The process has utility for producing more valuable lower molecular weight products having a reduced aromatic heteroatom content from starting materials that are highly refractory and widely considered to be difficult to upgrade such as coals and asphaltenes, and model compounds containing the biaryl linkages.
CA002143404A 1994-03-09 1995-02-24 Process for removal of heteroatoms under reducing conditions in supercritical water Expired - Fee Related CA2143404C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US21260794A 1994-03-09 1994-03-09
US212,607 1994-03-09

Publications (2)

Publication Number Publication Date
CA2143404A1 true CA2143404A1 (en) 1995-09-10
CA2143404C CA2143404C (en) 1999-05-04

Family

ID=22791735

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002143404A Expired - Fee Related CA2143404C (en) 1994-03-09 1995-02-24 Process for removal of heteroatoms under reducing conditions in supercritical water

Country Status (6)

Country Link
US (1) US5611915A (en)
EP (1) EP0671454B1 (en)
JP (1) JP3556722B2 (en)
AU (1) AU696457B2 (en)
CA (1) CA2143404C (en)
DE (1) DE69518680T2 (en)

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US7947165B2 (en) * 2005-09-14 2011-05-24 Yeda Research And Development Co.Ltd Method for extracting and upgrading of heavy and semi-heavy oils and bitumens
US20080099378A1 (en) * 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Process and reactor for upgrading heavy hydrocarbon oils
US20080099374A1 (en) * 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Reactor and process for upgrading heavy hydrocarbon oils
US20080099376A1 (en) * 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Upgrading heavy hydrocarbon oils
US20080099377A1 (en) * 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Process for upgrading heavy hydrocarbon oils
US7842181B2 (en) * 2006-12-06 2010-11-30 Saudi Arabian Oil Company Composition and process for the removal of sulfur from middle distillate fuels
US8142646B2 (en) 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US20090145808A1 (en) * 2007-11-30 2009-06-11 Saudi Arabian Oil Company Catalyst to attain low sulfur diesel
US7862708B2 (en) * 2007-12-13 2011-01-04 Exxonmobil Research And Engineering Company Process for the desulfurization of heavy oils and bitumens
US20090166262A1 (en) * 2007-12-28 2009-07-02 Chevron U.S.A. Inc. Simultaneous metal, sulfur and nitrogen removal using supercritical water
US20090166261A1 (en) * 2007-12-28 2009-07-02 Chevron U.S.A. Inc. Upgrading heavy hydrocarbon oils
US9636662B2 (en) 2008-02-21 2017-05-02 Saudi Arabian Oil Company Catalyst to attain low sulfur gasoline
US9005432B2 (en) 2010-06-29 2015-04-14 Saudi Arabian Oil Company Removal of sulfur compounds from petroleum stream
US8535518B2 (en) 2011-01-19 2013-09-17 Saudi Arabian Oil Company Petroleum upgrading and desulfurizing process
US9926497B2 (en) 2015-10-16 2018-03-27 Saudi Arabian Oil Company Method to remove metals from petroleum
US10106748B2 (en) 2017-01-03 2018-10-23 Saudi Arabian Oil Company Method to remove sulfur and metals from petroleum
US10752847B2 (en) 2017-03-08 2020-08-25 Saudi Arabian Oil Company Integrated hydrothermal process to upgrade heavy oil
US10703999B2 (en) 2017-03-14 2020-07-07 Saudi Arabian Oil Company Integrated supercritical water and steam cracking process
US10526552B1 (en) 2018-10-12 2020-01-07 Saudi Arabian Oil Company Upgrading of heavy oil for steam cracking process

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660269A (en) * 1970-10-14 1972-05-02 Atlantic Richfield Co Coal processing
US3819506A (en) * 1971-09-16 1974-06-25 Sun Research Development Coal dissolving process
US3850738A (en) * 1973-12-06 1974-11-26 Bechtel Int Corp Bituminous coal liquefaction process
GB1461280A (en) * 1974-02-19 1977-01-13 Gulf Oil Corp Refining of carbonaceous fuels
US4005005A (en) * 1974-05-31 1977-01-25 Standard Oil Company (Indiana) Process for recovering and upgrading hydrocarbons from tar sands
US3948754A (en) * 1974-05-31 1976-04-06 Standard Oil Company Process for recovering and upgrading hydrocarbons from oil shale and tar sands
US3960702A (en) * 1974-08-08 1976-06-01 Marathon Oil Company Vapor phase water process for retorting oil shale
GB1489920A (en) * 1974-11-07 1977-10-26 Coal Ind Hydrogenative extraction of coal
GB1490078A (en) * 1974-11-19 1977-10-26 Coal Ind Gas extraction of coal
GB1482690A (en) * 1974-12-19 1977-08-10 Coal Ind Hydrogenation of coal
US4089773A (en) * 1976-12-01 1978-05-16 Mobil Oil Corporation Liquefaction of solid carbonaceous materials
US4166022A (en) * 1978-03-27 1979-08-28 Gulf Research & Development Company Recovery of oil from oil shale
US4298452A (en) * 1980-03-28 1981-11-03 Texaco Inc. Coal liquefaction
US4443321A (en) * 1981-11-17 1984-04-17 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Supercritical solvent coal extraction
GB8513077D0 (en) * 1985-05-23 1985-06-26 British Petroleum Co Plc Obtaining liquid products from solid carbonaceous materials
IT1222812B (en) * 1987-10-02 1990-09-12 Eniricerche Spa PROCEDURE FOR THE LIQUEFACTION OF THE COAL IN A SINGLE STAGE
US5128017A (en) * 1987-10-02 1992-07-07 Eniricerche, S.P.A. Single-step coal liquefaction process
CA2000251A1 (en) * 1989-10-06 1991-04-06 Norbert Berkowitz Method for recovering and partially upgrading bitumen from oil sands, tar sands, oil shales, h eavy oil reservoirs
US5151173A (en) * 1989-12-21 1992-09-29 Exxon Research And Engineering Company Conversion of coal with promoted carbon monoxide pretreatment
US5269947A (en) * 1992-09-17 1993-12-14 Baskis Paul T Thermal depolymerizing reforming process and apparatus

Also Published As

Publication number Publication date
CA2143404C (en) 1999-05-04
JP3556722B2 (en) 2004-08-25
US5611915A (en) 1997-03-18
EP0671454B1 (en) 2000-09-06
DE69518680T2 (en) 2001-05-31
DE69518680D1 (en) 2000-10-12
JPH07258655A (en) 1995-10-09
EP0671454A2 (en) 1995-09-13
EP0671454A3 (en) 1996-08-21
AU696457B2 (en) 1998-09-10
AU1470095A (en) 1995-09-21

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