CA2144685A1 - Apparatus and method for water purification using ozone generated by ultraviolet radiaton - Google Patents

Apparatus and method for water purification using ozone generated by ultraviolet radiaton

Info

Publication number
CA2144685A1
CA2144685A1 CA002144685A CA2144685A CA2144685A1 CA 2144685 A1 CA2144685 A1 CA 2144685A1 CA 002144685 A CA002144685 A CA 002144685A CA 2144685 A CA2144685 A CA 2144685A CA 2144685 A1 CA2144685 A1 CA 2144685A1
Authority
CA
Canada
Prior art keywords
water
ultraviolet
gas
ozone
ozone generating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002144685A
Other languages
French (fr)
Inventor
Dennis E. Pelster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2144685A1 publication Critical patent/CA2144685A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/123Ultra-violet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/78Details relating to ozone treatment devices
    • C02F2201/782Ozone generators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/40Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ozonisation

Abstract

The present invention provides a method and apparatus for the purification of water using a continuous filament ultraviolet light bulb source to produce radiation resulting in ozone production in gases containing oxygen.
This gas containing the ozone is then injected into water where many undesirable bacteria, viruses, and organic and inorganic compounds are destroyed.

Description

as APPARATUS AND METHOD FOR WATER PURIFICATION USING OZONE GENERATED
BY ULTRAVIOLET RADIATION

BACKGROUND OF THE INVENTION
1. Field of the Invention The present invention is generally directed to the purification of water by injecting ozone into water. An oxygen containing gas is directed by confined flow past a continuous filament bulb that produces ultraviolet radiation resulting in changing some of the oxygen into ozone. The ozone and remaining gas are then injected into water where ozone destroys many undesirable bacteria, viruses and other organic and inorganic compounds.
2. Description of the Prior Art The use of ozone, having a chemical formula of 03, to purify water has been known since the early 1 900's. Ozone molecules readily oxidize many types of bacteria, viruses or organic contaminates contained in water to make them ineffective and thereby increase the purity of water.
Ozone is produced by subjecting oxygen, 2, to electrostatic discharge.
Ozone is also less efficiently produced by oxygen containing gas absorbing ultraviolet radiation. The efficiency of ultraviolet radiation production of ozone relates to the design of the ultraviolet light producing device, the amount of energy applied to the light source, the oxygen content of the gas, and temperature and pressure of the oxygen containing gas.
The most common ozone generators for water purification involving ultraviolet wave lengths relate to fluorescent devices having two electrodes ~4~8~

separated by a glass tube containing a gas that will be bombarded by electrons passing between the electrodes. This ultraviolet light produced by this electron bombarded gas converts oxygen into ozone. These devices are described in U.S. Patents 4,214,962, 4,273,660, 4,504,445, and 4,990,311.
Electromagnetic fields are sometimes used in addition to these fluorescent tubes to enhance their efficiency.
In the 1930's single and connected continuous filament bulbs for the production of ultraviolet radiation were invented for therapeutic and hygienic purposes and for reduction of odors in refrigerators. These include U.S.
Patents 1,845,376, 2,042,963, and 2,088,544. These bulbs were designed for 110 - 120 Volts AC operation. In recent years these devices continued to be manufactured in only small batch quantities. One example is depicted on Spectronics drawing P-82173 that uses a capacitor or ballast. However, these bulbs offer no protection against possible viewer eye damage when inserted in standard outlets so remain relatively unused.
The power source for all existing ultraviolet ozone producing devices is electricity. Therefore, simply constructed devices that produce the most ozone for the least electric power are the most desired for water purification.
The present invention provides a water purification apparatus and method for an improved production of ozone requiring less power with a simple design using a continuous filament bulb configuration.

SUMMARY OF THE INVENTION:
The present invention provides an efficient method and apparatus for the purification of water using a continuous filament ultraviolet light bulb source to produce radiation resulting in ozone production from gases containing 21~q~

oxygen. This gas containing the ozone is then injected into water where many undesirable bacteria, viruses, and organic and inorganic compounds are destroyed .
In the broadly described apparatus, a gas containing oxygen is introduced into a chamber containing an ultraviolet light producing bulb having a continuous filament. The continuous filament provides a single electrical circuit inside the bulb. Ultraviolet light emitting rays of proper wave length converts some of the oxygen into ozone.
After the ozone is produced in the chamber, the gaseous mixture containing the ozone is injected into the water for mixing with the water and reacting with impurities contained in the water. This is accomplished by using well known restrictive water flow devices to increase water flow velocities, resulting in a low pressure at the restriction for gas injection andeliminating the need for pressurized gas containers, gas compressors or pumps. However, these positive pressure gas devices may also be used to move the oxygen containing gas through the ozone chamber of the present invention and to be forcibly injected into the water.
The present invention can be used to purify water for drinking purposes, spas, swimming pools, esthetic water pools and water falls for example as well as other uses where water needs purification.
Accordingly, one object of the invention is to provide an efficient and simple method of generating ozone for water purification.
Another object of the invention is to use a continuous filament ultraviolet light bulb source for generation of ozone for water purification.

2 1 ~

Another object of the invention is to eliminate the ballast or capacitor in the electrical circuit for the continuous filament ultraviolet light source used for water purification.
Another object of the invention is to provide protection against possible visual damage from ultraviolet light when using continuous filament bulbs for generation of ozone for water purification.

BRIEF DESCRIPTION OF THE DRAWINGS:
Figure 1 is a flow chart of the present invention where a gas containing oxygen flows into a ozone generator device and the ozone containing gas is then injected into water for purification of the water.
Figure 2 is a perspective view of the ozone generator device with the cover removed to show the components.
Figure 3 is a view of a plurality of single filament ultraviolet bulbs in the ozone generator chamber.

DETAILED DESCRIPTION OF THE ~t~tRRED EMBODIMENTS:
As indicated in figure 1, a gas containing oxygen 10 is introduced into an enclosed ozone generator device 1 1. This gas may be air, pure oxygen, or any combination of gasses containing oxygen. Higher percentages of oxygen in the gas increase the efficiency of the conversion of oxygen molecules of 2 into ozone, 03 Optional gas dryers may be used to dry the gas prior to the ozone generator and thereby promote increased ozone production. The gas may be introduced into the ozone generator by reduced pressure techniques produced by well known methods where water 1 2 flowing through a restriction 13 increases in velocity and decreases in pressure, providing a 2l.s~a~
-reduced pressure at the high velocity area for injection of ozone containing gas. These devices include but are not limited to venturi tubes, orifices, flow control valves, and jet valves. Introducing environmental air by this method for partial conversion into ozone produces a convenient process.
Pressure systems 14 such as, but not limited to, pressure tanks, compressors, pumps, blowers, and similar methods may be used to inject the gas containing oxygen into the ozone generator device thereby forcing the gas containing ozone 15 to mix into the water 12 for water purification. The gas pressure as a minimum amount should be greater than atmospheric pressure.
With a pressure system for gas injection, ozone containing gas distribution in the water is readily accomplished by but not limited to known techniques such as nozzles, porous sintered metal, ceramic, or plastic distribution devices 1 6 immersed in water promoting small, injected gas bubbles to distribute the ozone in water. A check valve 2 2 may be inserted in the ozone containing gas line to prevent any water back flow into the ozone generating device 11.
After the gas enters the ozone generating device 1 1, shown with cover removed in perspective view of figure 2, the gas containing oxygen 10 flows into the device housing 17 through inlet 23, and around a voltage reducing means such as a transformer 18. Electric power 25 connected to the transformer is used for high voltage power supplies and includes but is not limited to 110 - 120 volts AC or 200-240 volts AC. The transformer reduces the source voltage to lower voltages for powering the ultraviolet light bulb when lower voltages are desired. A ballast or capacitor may also be used in place of the transformer. Although continuous filament bulbs at the higher line voltages may be used, the lower voltage bulbs are preferred. Passing the gas containing oxygen around the transformer, ballast or capacitor cools the 214~6~5 i component for longer life and excites the gas 1 0 by warming the gas to a greater energy level for more efficient oxygen reaction into ozone.
The gas enters the ultraviolet light bulb chamber 19 through an angled entrance 20 that does not allow direct light passage out of the bulb chamber.
This entrance could be for example but not limited to a 90 elbow, slanted hole, or any labyrinth design.
The gas 1 0 flows around an ultraviolet light bulb 21 that emits ultraviolet light producing ozone. This light bulb has a continuous filament and preferably uses low voltage. The continuous filament provides a single electrical circuit inside the bulb. Spectronics Corporation in Westbury, N.Y.
part 4254G/OP is preferred. Other continuous filament bulbs producing ultraviolet wave lengths for ozone production having higher or lower alternating or direct current voltages may also be used. Although the bulb manufacturer states that ballast or capacitor should be used, excellent results were obtained with only a transformer for low voltage operation.
The ozone generating device housing and the ultraviolet light bulb chamber should be sealed for more efficient ozone production but the unit will operate without tight seals. The housing means 17 may be designed to eliminate direct visual contact by people when opened by not allowing power to the ultraviolet bulb when the device is opened. However, the housing may have a small ultraviolet translucent window to indicate light bulb operation.
Construction materials for the ozone generating housing may be metal, plastic, or a combination of these materials.
The gas, having passed around the ultraviolet bulb, contains ozone and exits the ozone generating device through connection 24. The ozone containing gas is then injected into water for purification purposes.

~-4g~8~

-For higher demands of ozone, a plurality of continuous filament bulbs may be used in the ozone generating chamber 1 9 as shown in figure 3. For some applications, this plurality of bulbs in one chamber produces more ozone while other applications may require a plurality of ozone generating devices each having continuous filament ultraviolet light producing bulbs.
Example 1. The present invention using an ozone generating apparatus having a continuous filament ultraviolet light bulb made by Spectronics Corporporation, Corporation, Westbury, N.Y., part 4254G/OP, was evaluated in the engineering department of a local university. A transformer was used to reduce 110 volts AC to 12 volts AC. Pressurized air at 74F. was introduced into the ozone generating device. The amount of ozone produced by the device was measured to be 1.28 grams of ozone per hour. Measured voltage was 12 volts AC and measured AC current was 0.35 amperes for the bulb during ozone production. The ozone generation rate was independent of air flow rates except at very low, inadequate air flows.
Comparison of this test is made to Gas Purification Systems Inc., Denver Colorado, Model 5V consuming 0.50 amperes, 110 volts AC and producing 0.550 grams ozone per hour. This unit uses two separated electrodes and a fluorescent tube design similar to many other current models in the referenced patents.
Comparing the results of the above present invention example to present ozone generating models using separated electrodes indicates unanticipated and surprising improvements. Ozone production more than doubled for the apparatus using continuous filament ultraviolet source with less input of power.

Claims (20)

1. A water purification apparatus comprising:
(a) a means for introducing a gas containing oxygen into an ultraviolet ozone generating device, (b) a light bulb means in said ultraviolet ozone generating device for producing ultraviolet light at wave lengths for changing said oxygen into ozone gas, (c) said light bulb means having a continuous filament and, (d) a means for introducing said ozone gas into water.
2. The water purification apparatus according to claim 1 wherein said ultraviolet ozone generating device contains a means for lowering voltages to said light bulb means.
3. The water purification apparatus to claim 1 wherein said means for introducing said gas containing oxygen into said ultraviolet ozone generating device is low pressure formed by water flow through a restricted flow area.
4. The water purification apparatus according to claim 1 wherein said means for introducing said gas containing oxygen into said ultraviolet ozone generating device is a high gas pressure source.
5. The water purification apparatus according to claim 1 wherein said gas containing oxygen is introduced around said light bulb means through an angled entrance.
6. The water purification apparatus according to claim 1 wherein said light bulb means operates using alternating current electricity.
7. The water purification apparatus according to claim 1 wherein said gas containing oxygen is air.
8. The water purification apparatus according to claim 1 wherein said means for injecting said ozone gas into water is a porous means for producing small gas bubbles.
9. The water purification apparatus according to claim 1 wherein a plurality of said light bulbs means for producing ultraviolet light are used in said ultraviolet ozone generating device.
10. The water purification apparatus according to claim 1 wherein a plurality of said ultraviolet ozone generating devices are used in said water purification apparatus.
11. A method of purifying water comprising the steps of:
(a) introducing a gas containing oxygen into an ultraviolet ozone generating device, (b) providing in said ozone generating device a light bulb means with a continuous filament for producing ultraviolet light at wave lengths for changing said oxygen into ozone gas and, c) introducing said ozone gas into water.
12. The method of purifying water according to claim 11 wherein said ultraviolet ozone generating device contains a means for lowering voltages to said light bulb means.
13. The method of purifying water according to claim 11 wherein said means for introducing said gas containing oxygen into said ultraviolet ozone generating device is low pressure formed by water flow through a restricted flow area.
14. The method of purifying water according to claim 11 wherein said means for introducing said gas containing oxygen into said ultraviolet ozone generating device is a high pressure source.
15. The method of purifying water according to claim 11 wherein said gas containing oxygen is introduced around said light bulb means through an angled entrance.
16. The method of purifying water according to claim 11 wherein said light bulb means operates with alternating current.
17. The method of purifying water according to claim 11 wherein said gas containing oxygen is air.
18. The method of purifying water according to claim 11 wherein said light bulb means operates using alternating current electricity.
19. The method of purifying water according to claim 11 wherein a plurality of said light bulbs means for producing said ultraviolet light are used in said ultraviolet ozone generating device.
20. The method of purifying water according to claim 11 wherein a plurality of said ultraviolet ozone generating devices are used.
CA002144685A 1994-03-25 1995-03-15 Apparatus and method for water purification using ozone generated by ultraviolet radiaton Abandoned CA2144685A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US218,268 1994-03-25
US08/218,268 US5387400A (en) 1994-03-25 1994-03-25 Apparatus and method for water purification using ozone generated by ultraviolet radiation with a continuous filament bulb

Publications (1)

Publication Number Publication Date
CA2144685A1 true CA2144685A1 (en) 1995-09-26

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CA (1) CA2144685A1 (en)

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US5614151A (en) * 1995-06-07 1997-03-25 R Squared Holding, Inc. Electrodeless sterilizer using ultraviolet and/or ozone
US6022456A (en) * 1997-02-20 2000-02-08 Valdosta State University Apparatus and method for generating ozone
US6485685B1 (en) * 1997-04-04 2002-11-26 Toyota Jidosha Kabushiki Kaisha Purifying agent, apparatus and method for forming purifying agent, and purifying method using the agent
US6589490B1 (en) * 2000-10-20 2003-07-08 Jorge M. Parra UV water treatment apparatus
KR20030046621A (en) * 2001-12-16 2003-06-18 한국전자통신연구원 Method for seting communication environment of smart card and mobile entity using layered protocol stack with selective multiple transmission protocols
US6888324B1 (en) 2002-05-16 2005-05-03 Balboa Instruments, Inc. Ozone generator having a mercury lamp with a filament temperature detective circuit
US7329997B1 (en) 2002-05-16 2008-02-12 Balboa Instruments, Inc. System including an electronic ballast for use with a spa
WO2005000365A1 (en) * 2003-06-06 2005-01-06 Inventive Holdings Llc Lighting apparatus and system for decontamination
US8211374B2 (en) 2003-07-18 2012-07-03 David Richard Hallam Air cleaning device
US7837951B2 (en) * 2005-01-05 2010-11-23 Gsg Holdings, Inc. Modular ozone generator with an air diffuser
US20080213129A1 (en) * 2007-01-25 2008-09-04 Koninklijke Philips Electronics, N.V. Non-linear uv light sources for disinfection
US20130284422A1 (en) * 2009-08-04 2013-10-31 William O. Irvine Integrated fluid filtration and recirculation system and method
US20110220371A1 (en) * 2010-03-11 2011-09-15 Halliburton Energy Services, Inc. System and method for fluid treatment
US9038725B2 (en) 2012-07-10 2015-05-26 Halliburton Energy Services, Inc. Method and system for servicing a wellbore

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FZDE Discontinued