CA2150379C

CA2150379C - Exhaust emission control catalyst and process for producing the same

Info

Publication number: CA2150379C
Application number: CA002150379A
Authority: CA
Inventors: Kazuhide Terada; Takeshi Narishige; Naohiro Satoh; Yoshikazu Fujisawa; Yoshiyuki Nakanishi
Original assignee: Honda Motor Co Ltd
Current assignee: Honda Motor Co Ltd
Priority date: 1993-09-29
Filing date: 1994-09-29
Publication date: 1998-12-01
Anticipated expiration: 2014-09-29
Also published as: EP0671211A1; WO1995009048A1; DE69421796T2; US6008155A; EP0671211B1; DE69421796D1; EP0671211A4; CA2150379A1

Abstract

An exhaust emission control catalyst having superior NOx cleaning capability has .theta. and .alpha. phases and is constituted by modified alumina having an alpha ratio R represented by 0.5 % <= R <= 95 % and a catalytic metal carried on the modified alumina such as platinum Pt. In addition, a catalyst constituted by the above catalyst as a catalytic element and aluminosilicate or CeO2 also has a superior NOx cleaning capability.

Description

, ,. 21S'q37,~

EXHAUST EMISSION CONTROL CATALYST AND
PROCESS FOR PRODUCING THE SAME

BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
The present invention relates to an exhaust emission control catalyst, and particularly, to such a catalyst including an alumina and a catalytic metal carried in the alumina, and a catalyst including: cerium oxide (CeO2) having a catalyst material as the former catalyst; or a solid acidic aluminosilicate which includes a molecular sieves property and a catalyst material as the former catalyst; and the present invention also relates to a process for producing the exhaust emission control catalyst.
DESCRIPTION OF THE PRIOR ART
An active alumina having a r-phase and/or a ~-phase has been conventionally used as the above-described alumina, and platinum has been used as the catalytic metal. The aluminosilicate has a function as a support and a hydrocarbon (HC) adsorbing capability (for example, see Japanese Patent Publication No.27295/1981). The cerium oxide (CeO2) has a function as a support and a nitrogen oxide (NOx) adsorbing capability. Inthiscase,platinum(Pt)isusedasthecatalytic metal (for example, see Japanese Patent Application Laid-open No.184876/1993).

However, the prior art catalyst suffers from a following problem: If platinum (Pt) or palladium is carried in the active alumina, the platinum (Pt) or palladium (Pd) is dispersed, becauseitismulti-porousandhasalargespecificsurfacearea.
Therefore, the hydrocarbon (HC) adsorbing capability and nitrogen oxide (NOx) adsorbing capability provided by the platinum (Pt) or palladium (Pd) are enhanced, but in an atmosphere containing an excessive amount of air (e.g., an air-fuelratioA/F-. 24), acompleteoxidizationof hydrocarbon (HC), namely, a oxidizing reaction represented by HC -~ C~2 +

H20 advances, so that the amount of active aldehyde ( CHO) produced,whichisaproductofpartialoxidationofhydrocarbon (HC) and has a NOx reducing capability, is insufficient, and a reduction-impeding effect by oxygen adsorbed on the surface of platinum (Pt) or the like is liable to be produced. For this reason, the reducing conversion of NOx cannot be sufficiently performed, and the range of temperature for conversion of NOx is narrowed.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an exhaust emission control catalyst of the above-described type, and a process for producing the same, wherein the partial oxidation of hydrocarbon can occur in a wider range of temperature of an exhaust gas by using an alumina having a specific surface area smaller than that of an active alumina, 21~0379 thereby increasing the NOx percent conversion even in an atmosphere containing an excessive amount of oxygen.
To achieve the above object, according to the present invention, there is provided an exhaust emission control catalyst comprising an alumina, and a catalytic metal carried in the alumina, the catalytic metal being at least one element selected fromtheplatinum group,whereinthealuminacomprises a modified alumina which has a ~-phase and an ~-phase and has an ~-conversion rate R in a range of 0.5 % < R < 95 %.

There is also provided a process for producing an exhaust emission control catalyst, comprising the steps of subjecting an active alumina to a thermal treatment at a heating temperature T set in a range of 800~C _ T < 1,100~C to phase-convertthe active aluminaintoa modifiedaluminahaving a ~-phase and an ~-phase and having an ~-conversion rate R

in a range of 0.5 % _ R < 95 %, and carrying at least one catalyticmetalselectedfromtheplatinumgroupinthemodified alumina.
In addition, there is provided a process for producing an exhaust emission control catalyst, including the steps of carryingatleastonecatalyticmetalselectedfromtheplatinum group in a modified alumina, and subjecting the active alumina with the catalytic metal carried therein to a thermal treatment at a heating temperature set in a range of 800~C _ T < l,100~C

215037~

to phase-convert the active alumina into a modified alumina having a ~-phase and an ~-phase and having an C~-conversion rate R in a range of 0.5 % < R _ 95 %.

For example, if boehmite represented by a structural formula 4 [AlO(OH)] is heated, a phase conversion represented by boehmite phase ~ r-phase ~ 77-phase ~ ~-phase ~ c~-phase occurs with an increase in temperature, wherein the specific surface area of the r-phase < the specific surface area of the 71-phase < the specific surface area of the ~-phase < the specific surface area of the cY-phase.

In the catalyst, the specific surface area of the modified alumina is smaller than that of the active alumina having the r -phase or the like, because it has the ~- and c~-phases.

Therefore, if the catalytic metal is carried in the modified alumina, the dispersion of the metal is suppressed, as compared with the case where the catalytic metal is carried in the active alumina and hence, the catalyst exhibits a relatively weak oxidizing capability to hydrocarbon (HC).
Thus, the hydrocarbon is partially oxidized to produce an active aldehyde (CHO) having a reducing capability. The production of the active aldehyde is performed in a wider range of temperature of an exhaust gas and hence, nitrogen oxide (NOx) is reduced and converted by the active aldehyde (CHO), and the range of temperature for such conversion is widened.

215037~

The NOx converting capability of the catalyst is higher in a lower range of temperature of the exhaust gas. Therefore, if this catalyst is combined with a catalyst capable of exhibiting a higher NOx convertingcapability in a higher range of temperature, e.g., a catalyst including a zeolite and cerium oxide (CeO2) carried therein, the range of temperature for conversion of NOx can be further widened.
Further, because the modified alumina has the ~-phase which is a metastable phase and the a-phase which is a stable phase, the closing of fine pores resulting from the phase conversionoftheactivealumina,theembeddingofthecatalytic metal due to this closing and the like are difficult to occur and therefore, the catalyst has an excellent heat resistance, and the catalytic capability is less degraded.
However, if the ~-conversion rate R of the modified alumina is smaller than 0.5 %, the modified alumina has a specific surface area decreased at a small degree and hence, it is impossible to achieve an intended purpose. On the other hand, if the ~-conversion rate R of the modified alumina is larger than 95 %, the modified alumina has a too-decreased specific surface area, resulting in a reduced function of the catalytic metal.
With this producing process, it is possible to easily produce a catalyst having characteristics as described above.

However, if the heating temperature T in the thermal treatment is lower than 800 ~C, it is failed to smoothly advance the phase conversion. On the other hand, if T > l,100~C, it is difficult to control the upper limit value (R = 95 %) of the ~-conversion rate R.
It isa furtherobject ofthe present inventiontoprovide an exhaust emission control catalyst of the above-described type and a process for producing the same, wherein an alumina havingaspecificsurface areadecreasedto avalue smallerthan that of-the active alumina is used, and a particular amount of catalytic metal is carried in the alumina, so that a partial oxidization of hydrocarbon (HC) can occur at a wider range of temperature of an exhaust gas; and a particular amount of aluminosilicate is also used, so that the adsorption and desorption of an active aldehyde (CHO) can be performed by the aluminosilicate,therebyincreasingtheNOxpercentconversion can be increased even in an atmosphere containing an excessive amount of oxygen.
To achieve the above object, according to the present invention, there is provided an exhaust emission control catalyst including a catalyst material and a solid acidic aluminosilicate having a molecular sieves property, the catalyst material being formed of an alumina and a catalytic metal carried in the alumina, wherein the alumina is a modified 21~0379 alumina having an ~-conversion rate R set in a range of 0.1 %
_ R < 95 %; the weight percent Al (= {A/(A + B)} x 100) of the catalyst material is set in a range of 11 % by weight _ Al <

95 % by weight, wherein A represents an amount of catalyst material incorporated, and B represents an amount of aluminosilicate incorporated, and the catalytic metal is at least one element selected from the platinum group, the weight percent al of the catalyst metal being set in a range of 0.1 by weight < al_ 5 % by weight.

There is also provided a process for producing an exhaust emission control catalyst, including the steps of subjecting an active alumina to a thermal treatment at a heating temperature set in a range 800 ~C _ T _ 1,100~C to produce a modified alumina having an ~-conversion rate R in a range of 0.1 % < R _ 95 % from the active alumina; carrying at least one element selected from the platinum group in the modified alumina to fabricate a catalyst material, the weight percent al of the catalytic metal in the catalyst material being set in a range of 0.1 % by weight < al _ 5 % by weight; and mixing the catalyst material with a solid acidic aluminosilicate having a molecular sieves property, the weight percent Al (=
{A/(A + B)} x 100) of the catalyst material being set in a range of 11 % by weight < Al < 95 % by weight, wherein A represents 215037g an amount of catalyst material incorporated, and B represents an amount of aluminosilicate incorporated.
If the ~-conversion rate is set in the above-described range, the specific surface area of the modified alumina is smaller than that of the active alumina having the ~-phase or the like, because it has the ~ -phase. Therefore, if a particular amount of the catalytic metal is carried in the modified alumina, the dispersion of the metal is suppressed, as compared with the case where the catalytic metal is carried in the active alumina and hence, the catalyst exhibits a relatively weak oxidizing capability to hydrocarbon (HC).
Thus, the hydrocarbon is partially oxidized to produce an active aldehyde (CHO) having a NOx reducing capability. The production of the active aldehyde (CHO) is performed in a wider range of temperature of an exhaust gas, and the aluminosilicate adsorbs a portion of the active aldehyde (CHO) to store it therein and desorbs such portion to supply it. Thus, nitrogen oxide (NOx) is reduced and converted by the active aldehyde (CHO) which is free from the beginning and the active aldehyde which has become free as a result of desorption thereof, and the range of converting temperature is widened.

The NOx converting capability of the catalyst is higher at a lower temperature of the exhaust gas and hence, if this catalyst is combined with a catalyst capable of exhibiting a higher NOxconvertingcapabilityat ahighertemperature, e.g., a catalyst including an aluminosilicate andcerium oxide (CeO2) carried therein, the range of temperature for conversion of nitrogen oxide (NOx) can be further widened.
Further, because the modified alumina has the ~-phase which is a stable phase, the closing of fine pores in the active alumina resulting from the phase conversion, the embedding of the catalytic metal due to this closing and the like are difficult to occur. Therefore, the catalyst has an excellent heat resistance, and the catalytic capability is less degraded at a higher temperature.
However, if the ~-conversion rate R of the modified alumina is smaller than 0.1 %, the modified alumina has a specific surface area decreased at a small degree and hence, it is impossible to achieve an intended purpose. On the other hand, if the ~-conversion rate R of the modified alumina is larger than 95 %, the fine pores are closed with an excessive advancement of the ~-conversion rate, so that the specific surface area of the modified alumina is substantially reduced.
As a result, the dispersion of the catalytic metal is extremely degraded to remarkably decrease the NOx adsorbing capability.
If the weight percent Al of the catalyst material is smaller than 11 % by weight, the NOx percent conversion is lowered due to a decrease in catalytic capability. On the other hand, if Al > 95 % by weight, the adsorbing and desorbing actions by the aluminosilicate are reduced and hence, the NOx percent conversion is likewise lowered.
Further, if the weight percent alof the catalytic metal is equal to or smaller than 0.1 % by weight, the NOx percent conversionisloweredduetoadecreaseincatalyticcapability.
On the other hand, even ifthe weight percent alofthe catalytic metal is set at a value smaller than 5 % by weight, a NOx converting effect corresponding to an increase in amount of catalytic metal carried is not obtained.
This producing process makes it possible to easily mass-produce a catalyst having characteristics as described above. However, if the heating temperature T in the thermal treatment is lower than 800 ~C, it is failed to smoothly advance the phase conversion of the ~-phase and/or the ~-phase into the ~-phase. On the other hand, if T > 1,100 ~C, it is difficult to control the upper limit value (R = 95 %) of the ~-conversion rate R.
It is a yet further object of the present invention to provide an exhaust emission control catalyst of the above-described type and a process for producing the same, wherein analuminahavingadecreasedspecificsurfaceareasmallerthan that of an active alumina is used, and a catalytic metal is carried in the alumina, so that a partial oxidization of hydrocarbon(HC)occurs;andaparticularamountofceriumoxide (CeO2) is also used, so that a NOx adsorbing capability can be exhibited by the cerium oxide, thereby increasing the NOx percent conversion even in an atmosphere containing an excessive amount of oxygen.
To achieve the above object, according to the present invention, there is provided an exhaust emission control catalyst including acatalyst material formed of an alumina and acatalyticmetalcarriedinthealumina,andceriumoxide(CeO2), wherein the alumina is a modified alumina having an ~ -conversion rate R set in a range of 0.1 % _ R < 98 %, and the weight percent Al(= {A/(A + E)} x 100) of the catalyst material is set in a range of 20 % by weight < Al< 88 % by weight, wherein A represents an amount of catalyst material incorporated, and E represents an amount of cerium oxide (CeO2) incorporated.
According to the present invention, there is also provided a process for producing an exhaust emission control catalyst, including the steps of subjecting an active alumina to a thermal treatment at a heating temperature T set in a range of 800~C _ T _ 1,100~C to produce a modified alumina having an ~-conversion rate R in a range of 0.1 % _ R < 98 %; carrying at least one catalytic metal selected from the platinum group in the modified alumina to fabricate a catalyst material; and mixing the catalyst material with cerium oxide (CeO2), the 21~0379 weight percent A1 (= {A/(A + E)} x l00) of catalyst material incorporated being set in a range of 20 % by weight < A1 < 88 %
by weight, wherein A represents an amount of catalyst material incorporated, and E represents an amount of cerium oxide incorporated.
If the ~-conversion rate R is set in the above-described range, the specific surface area of the modified alumina is smaller than that of the active alumina having the y-phase or the like, because it has the ~ -phase. Therefore, if the catalytic metal is carried in the modified alumina, the dispersionofthemetalissuppressed, as comparedwiththecase where the catalytic metal is carried in the active alumina, and hence, the catalyst material exhibits a relatively weak oxidizing capability to hydrocarbon (HC).
Thus, the hydrocarbon is partially oxidized to produce an active aldehyde (CHO) having a NOx reducing capability. The production of the active aldehyde (CHO) is performed in a wider range of temperature of an exhaust gas. On the other hand, the cerium oxide (CeO2) exhibits a NOx adsorbing capability even in an atmosphere containing an excessive amount of oxygen and hence, the active aldehyde (CHO)is adsorbedontheceriumoxide (CeO2)toreduce activated nitrogenoxide (NOx)toformnitrogen gas (N2), carbon dioxide gas (CO2) and water, thereby achieving the conversion of the nitrogen oxide (NOx). In this case, the 21~0379 active aldehyde (CHO) is more easily produced from an unsaturated hydrocarbon than from a saturated hydrocarbon, and free nitrogen oxide (NOx) is lower in activity than the adsorbed nitrogen oxide (NOx).
The production of the active aldehyde (CHO) by the partial oxidization of the hydrocarbon, the adsorption of the nitrogen oxide (NOx) and the reduction of the nitrogen oxide (NOx) by the active aldehyde (CHO) as described above occur at a temperature from a lower range of temperature to a higher range of temperature of an exhaust gas and hence, the range of temperature for purifying by the catalyst is widened.
Further, because the modified alumina has the ~ -phase which is a stable phase, the closing of fine pores in the active alumina resulting from the phase conversion, the embedding of the catalytic metal due to this closing and the like are difficult to occur and hence, the catalyst has an excellent heat resistance, and the catalytic capability is less degraded at a higher temperature.
However, if the ~-conversion rate R of the modified alumina is smaller than 0.1 %, the modified alumina has a specific surface area decreased at a small degree and hence, it is impossible to achieve an intended purpose. On the other hand, if R _ 95 %, the fine pores are closed with an excessive advancement of the ~x-conversion rate, so that the specific surface area is substantially reduced, and as a result, the dispersion of the catalytic metal is extremely degraded to remarkably decrease the NOx adsorbing capability.
If the weight percent A1 of the catalyst material is equal to or smaller than 20 % by weight, the NOx percent conversion is lowered due to a decrease in catalytic capability provided by the catalyst material. On the other hand, if Al -- 88 % by weight, the NOx adsorbing capability of the cerium oxide (CeO2) is decreased and hence, the NOx percent conversion is likewise lowered.
This producing process makes it possible to mass-produce a catalyst having characteristics as described above. However, if the heating temperature T in the thermal treatment is lower than 800~C, it is failed to smoothly advance the phase conversion of the r-phase and/or the 7~-phase into the ~-phase. On the other hand, if T > 1,100 ~C, it is difficult to control the upper limit value (R = 98 %) of the CY-conversion rate R.

BRIEF DESCRIPTION OF THE DRAWINGS
Fig.l is a graph illustrating the relationship between the weight percent of an c~-alumina and the X-ray reflection intensity rate;
Fig.2 is a powder X-ray diffraction pattern for an active alumina;
Fig.3 is a powder X-ray diffraction pattern for one 215~379 example of a modified alumina;
Fig.4 is a powder X-ray diffraction pattern for another example of a modified alumina;
Fig.5 is a graph illustrating the relationship between the gas temperature and the NO percent conversion;
Fig.6 is a graph illustrating the relationship between the ~-conversion rate R and the maximum NO percent conversion;
Fig.7 is a graph illustrating the relationship between the ~-conversion rate R of a modified alumina and the maximum NO conversion rate r;
Fig.8 is a graph illustrating the relationship between the weight percent A1 of a catalyst material and the maximum NO conversion rate r;
Fig.9 is a diagram illustrating cerium oxide (CeO2);
Fig.10 is a graph illustrating the relationship between the ~-conversion rate R of a modified alumina and the maximum NO conversion rate r;
Fig.11 is a graph illustrating the relationship between the weight percent Al of a catalyst material and the m~x; mllm NO conversion rate r; and Fig.12 is a graph illustrating the relationship between the average crystal grain size D of cerium oxide (CeO2) and the m~x; mllm NO conversion rate r.
DESCRIPTION OF THE PREFERRED EMBODIMENTS

1. First exhaust emission control catalyst This catalyst is formed from a modified alumina and a catalytic metal carried in the mixed-phase alumina.
The modified alumina has a ~ phase and an ~ phase, wherein the ~-conversion rate R is set in a range of 0.5 % <
R _ 95 %. The catalytic metal which may be used is at least one element selected from the platinum group, i.e., Ru, Rh, Pd, Ir and Pt. In this embodiment, Pt is used.
The measurement of the ~-conversion rate R was carried out in a following manner.
(a) Commercially available ~-alumina and r -alumina (active alumina) were mixed at a predetermined ratio by weight, and the mixture was blended while being pulverized for 30 minutes in a mortar. Table 1 shows the composition of each of the mixtures (1) to (5).
Table 1 Mixture No. Composition (% by weight) ~-alumina r-alumina (1) 0 100 (2) 25 75 (3) 50 50 (4) 75 25 100 ~

(b) Each of the mixtures (2) to (5) were subjected to a powder X-ray diffraction to measure an intensity of X-ray reflected from a {113} face of the ~-alumina appearing at 2 ~ = 43.4 +
0.2 in a CuK ~ line.

(c) A percent intensity of X-ray reflected for each of the mixtures (2) to (4) was determined based on the intensity of X-ray reflected for the mixture (5) defined at 100 %, thereby determining the relationship between the weight percent (the weight rate) of the a-alumina and the percent intensity of X-ray reflected to provide results shown in Fig.1.
As apparent from Fig.1, the weight percent of the ~-alumina and the percent intensity of X-ray reflected are in a direct proportional relation to each other. Therefore, in determining the ~-conversion rate R of the modified alumina with the weight percent of the ~-alumina defined as the ~-conversion rate R, the intensity of X-ray reflected from the {113} faceofthe ~-alumina inthe modified aluminais measured to determine a percent intensity of X-ray reflected from the intensity of X-ray reflected for the mixture (5), and the ~

-conversion rate Ris determined based on the percent intensity of X-ray reflected in Fig.1.
In producing the catalyst, the following two processes may be used. A first process includes a step of subjecting an 2I~03 79 active alumina such as ~ - and ~-alumina to a thermal treatment with a heating temperature T set in a range of 800~C
_ T _ 1100 ~C, preferably, 900 ~C _ T < 1050 ~C, a step of phase-converting the active alumina into a modified alumina having an ~-conversion rate R in a range of 0.5 % _ R - 95 %, and a step of carrying a catalytic metal Pt onto the modified alumina.
A second process includes a step of carrying a catalytic metal Pt onto an active alumina basically similar to the above-described active alumina, and a step of subjecting the active alumina havingPt carried thereonto a thermal treatment with a heating temperature T set in a range of 800 ~C _ T _ 1100 ~C, preferably, 900 ~C _ T _ 1050 ~C tophase-convertthe active alumina into a modified alumina having a ~-phase and an ~-phase with an ~-conversion rate R in a range of 0.5 % <

R < 95 %.

In the step of carrying Pt in each of the first and second processes, the concentration of Pt in a chloroplatinic acid solution is adjusted, so that the amount of Pt carried is in a range of 0.5 + 0.2 % by weight.

Particular embodiments of the catalyst and the process for producing the same will be described below.
First embodiment (a) An active alumina (r-alumina) was subjected to a thermal treatment with a heating temperature T set at 1000 ~C and with a heating time t set at 2 hours using an electric furnace to form a modified alumina by a phase-conversion of the active alumina.
(b) The modified alumina was subjected to a wet pulverizing treatment using a ball mill to provide a slurry of the modified alumina.
(c) The modified alumina slurry was evaporated to dryness at 150 ~C and then to a firing at 600 ~C for one hour using an electric furnace to provide a massive modified alumina.
(d)Themassivemodifiedaluminawassubjectedtoapulverizing treatment and then to a screening to provide a pellet-shaped modified alumina having a particle size of 1.4 to 3.4 mm.
(e) The pellet-shaped modified alumina was immersed into 37.3 g of a chloroplatinic acid solution (having a Pt concentration of 0.70 %) for 12 hours.
(f) The pellet-shaped modified alumina was filtered, and the resulting modified alumina was subjected to a drying at 80~C
for 5 hours and then to a firing at 600~C for one hour using an electric furnace to decompose the chloroplatinic acid, thereby producing a catalyst with Pt carried on the modified alumina. ThiS catalyst is called an example 1.
Second embodiment An active alumina was subjected to a thermal treatment with a heating temperature T set at 1000~C and with a heating time t set at 5 hours using an electric furnace to provide a modified alumina by a phase conversion of the active alumina, as in the first embodiment. Thereafter, the steps (b) to (f) described in the first embodiment were carried out to produce a catalyst with Pt carried in the modified alumina. This catalyst is called an example 2.
Third embodiment (a) An active alumina was subjected to a wet pulverizing treatment using ball mill to provide an active alumina slurry, as in the first embodiment.
(b) The active alumina was evaporated to dryness at 150~C and then to a firing at 600~C for one hour using an electric furnace to provide a massive active alumina.
(c) The massive alumina was subjected to a pulverizing treatment and then to a screening to provide a pellet-shaped active alumina having a particle size of 1.4 to 3.4 mm.
(d) 25 g of the pellet-shaped active alumina was immersed in 37.3 g of a chloroplatinic acid solution (having a Pt concentration of 0.70 %) for 12 hours.
(e) The pellet-shaped active alumina was filtered, and the resulting active alumina was subjected to a drying at 80~C for 5 hours and then to a firing at 600~C for one hour using an electric furnace to decompose the chloroplatinic acid, thereby producing a catalyst material with Pt carried in the active alumina.
(f) The catalyst material was subjected to a thermal treatment with a heating temperature T set at 1000~C and with a heating time t set at 2 hours using an electric furnace to phase-convert the active alumina into a modified alumina, thereby producing a catalyst with Pt carried in the modified alumina. This catalyst is called an example 3.
Comparative Example I
(a) The steps (a) to (c) described in the third embodiment were carried out to provide a pellet-shaped active alumina.
(b) The pellet-shaped active alumina was immersed in an amount of 25 g into 39.0 g of a chloroplatinic acid solution (having a Pt concentration of 0.45 %) for 12 hours.
(c) The pellet-shaped active alumina was filtered, and the resulting active alumina was subjected to a drying at 80~C for 5 hours and then to a firing at 600~C for one hour using an electric furnace to decompose the chloroplatinic acid, thereby producing a catalyst with Pt carried in the active alumina. This catalyst was called an example la.
Fig.2 shows a result of the powder X-ray diffraction for the active alumina used in the first to third embodiments and the comparative example I. In Fig.2, a peak indicative of a ~

21~0379 -phase is observed.
Figs.3 and 4 show results of the powder X-ray diffraction for the modified alumina in the first and second embodiments.
In Figs.3 and 4, peaks indicative of ~- and ~-phases are observed. The intensity of X-ray reflected for the ~-phase in Fig.4 is higher than that in Fig.3. This is due to the fact that an ~-conversion has advanced, because the heating time in the thermal treatment in the second embodiment is longer than that in the first embodiment.
Table 2 shows the ~-conversion rate R of the modified alumina or the active alumina, the BET specific surface area and the amount of Pt carried in the examples 1 to 3 and la of the catalysts.
Table 2 Catalyst Modified, active alumina Amount of Pt carried ~-conversion BET specific (% by weight) rate R (%) surface area (m2/g) Example 1 0.5 136 0.42 Example 2 5.3 97 0.65 Example 3 7 89 0.63 Example la 0 277 0.68 In order to carry out an NO conversion test for the examples 1 to 3 and la of the catalysts, a gas including 10 %

2lso379 of H2O, 1200 ppm of C3H6, 1000 ppm of CO, 1200 ppm of NO, 500 ppm of H2, 10 % of CO2. 10 % ~f ~2~ all by weight and the balance of N2 was prepared as a test gas.
The NOconversiontest wascarried out by forcingthetest gas to flow at a flow rate of 10000 ml/min through an ambient-pressurefixed-bedreactionpipewith20gofacatalyst packed therein, and rising the temperature of the test gas from ambient temperature to 400 ~C at 15~C/min, a measuring the NO

conversion rate during that time.
Fig.5 shows results of the NO conversion test. It can be seen from Fig.5 that the examples 1 to 3 of the catalysts show ahighNOconversionandhaveanextendedconvertingtemperature range, as compared with the example la. Particularly, the examples 1 and 2 have their NO converting capabilities shifted toward a lower gas-temperature side, as compared with the example la.
If the examples 1 and 2 of the catalysts are compared with each other, the example 2 using the modified alumina having a higher ~-conversion rate R shows a higher NO conversion than the example 1, and its m~x;mllm value is shifted toward a lower temperature side.
In the case of the example 3 of the catalyst, the NO
conversionisdecreased,ascomparedwiththeexamplel,because Pt is highly dispersed, as compared with the example 1, due to the fact that the phase conversion of the active alumina is carried out after carrying of Pt.
Fourth embodiment Using an active alumina similar to that in the first embodiment, various catalysts were produced in the same manner as in the first embodiment, except that the heating time t in the thermal treatment was varied. However, the ~-conversion rate R of the modified alumina is increased with an increase in heating time t and for this reason, when the chloroplatinic acid solution of the same Pt concentration is used, the amount of Pt carried is decreased. Therefore, in order to maintain the amountofPtcarriedatO.5 + 0.2%byweight,theconcentration of Pt in the chloroplatinic acid solution was increased with an increase in ~-conversion of the modified alumina.
Table 3 shows the heating temperature T and the heating time t in the thermal treatment, the ~-conversion rate R and the BET specific surface area of the modified alumina, and the amount of Pt carried in the modified alumina. It was confirmed in the powder X-ray diffraction for determining the ~ -conversion rate R that each modified alumina had ~- and ~-phases.

Table 3 Thermal treatment ~_ BET Amount of Catalyst conditions convertion specific Pt No. Heating Heating rate R( % ) surface carried temperature time (hr) area (% by (~C) (m2/h) weight) Example 4 1000 10 25 74 0.57 Example 5 1000 20 45 59 0.63 Example 6 1000 30 75 44 0.58 Example 7 1000 50 90 37 0.51 Second comparative example (a) A commercially available ~-alumina and an active alumina similar to that inExample 1 were mixed at apredetermined ratio to produce various alumina.
Table 4 shows compositions of the alumina mixtures (1) to (6).
Table 4 Alumina mixture Composition (% by weight) ~-aluminaActive alumina (1) 20 80 (2) 35 65 (3) 50 50 (4) 70 30 (5) 90 10 (6) 100 0 hereafter, the steps (b) to (f) described in the first embodiment were carried out to produce various catalysts with Pt carried in the alumina mixtures. However, in carrying Pt, the concentration ofPt in the chloroplatinic acid solution was adjusted as in the fourth embodiment. These catalysts called examples 2a to 7a in correspondence to the mixtures (1) to (6).
The ~-conversion rates R in the examples 2a to 7a are regarded as being 20, 35, 50, 70, 90 and 100 % in correspondence to the amount of ~-alumina, respectively.

The NO conversion test similar to that described above was carried out for the examples 4 to 7 and the examples 2a to 7a of the catalysts to determine the relationship between the ~-conversion rates R and the mAximllm NO conversion for the modified alumina and the like, thereby providing results given in Table 5. The m~x; mllm NO conversions for the examples 1 to 3 and la of the catalysts are also given in Table 5.

Table 5 Catalyst No. ~-conversion rate R (%) M~; NO conversion rate Example 1 0.5 46.2 Example 2 5.3 54 Example 3 7 50 Example 4 25 53.4 Example 5 45 54.6 Example 6 75 54.1 Example 7 90 51 Example la 0 39 Example 2a 20 40.2 Example 3a 35 41.4 Example 4a 50 40.8 Example 5a 70 40.8 Example 6a 90 37.2 Example 7a 100 24 Fig.6 is a graph illustrating the relationship between the CY-conversion R and the mAx;mllm NO conversion given in Table 5. In Fig.5, points 1 to 7 and la to 7a correspond to the examples 1 to 7 and la to 7a, respectively.
As apparent from Table 5 and Fig.6, each of the examples 1 to 7 of the catalysts according to the embodiment of the present invention exhibits a high m~x; mllm NO conversion, as compared 215037~

with the examples la to 7a in Comparative Example II. This is due tothe factthatthe modified aluminaineachoftheexamples 1 to 7 has the ~- and ~-phases, and the ~-conversion rate R
in each of the examples 1 to 7 is set in a range of 0.5 % _ R < 95 %. In each of the examples la to 6a, the mAx;mllm NO
conversion is low due to the use of the active alumina having a ~-phase is used, and the same is true in the example 7a due to the fact that it includes only the ~-alumina.

II. Second exhaust emission control catalyst This catalyst is a mixture of a catalyst material and a solidacidicaluminosilicatehavingamolecularsievesproperty.
The catalyst material includes an alumina and a catalytic metal carried in the alumina.
Thealuminausedisamodifiedaluminahavingan ~-phase, and the catalytic metal used is at least one element selected from the platinum group, i.e., Ru, Rh, Pd, Ir and Pt. In this embodiment, Pt is used. Further, the aluminosilicate used is a modified ZSM-5 zeolite produced by the dealuminization of an unmodified zeolite, e.g., an unmodified ZSM-5 zeolite in this embodiment.
The ~-conversion rate R of the modified alumina is set in a range of 0.1 % _ R < 95 %, preferably, in range of 45 %
< R < 90 %. The measurement of the ~-conversion rate R was carried out in the same manner as that described in the item I. The modified alumina was made in the same manner as that described in the item I.
If the ~-conversion rate R is set in the above range, the specific surface area of the modified alumina is small, because it has the ~-phase, as compared with that of the active alumina having the ~-phase or the like. Therefore, if Pt is carried in this modified alumina, the dispersion of Pt is suppressed, as compared with the case where Pt is carried in the active alumina, and hence, the resulting catalyst exhibits a relatively weak oxidizing capability to a hydrocarbon (HC).
Thus, the hydrocarbon is partially oxidized to produce an active aldehyde (CHO) having an NOx reducingcapability. The production of the aldehyde (CHO) is performed in a wider range oftemperatureofanexhaust gas, andthe modifiedZSM-5 zeolite adsorbs a portion of the active aldehyde to store it therein, and desorbs the portion of the active aldehyde to supply it.
Therefore, NOx is reduced and converted by the active aldehyde, and the converting temperature range is widened.
Further, the modified alumina has the ~-phase which is a stablephaseandhence,theclosingoffineporesinthe active alumina resulting from the phase conversion, the embedding of Pt duetothisclosingandthe likeare difficulttooccur.Thus, the modified alumina has an excellent heat resistance and is less in degree of degradation of the catalytic capability at a high temperature.
For the dealuminization of the unmodified ZSM-5 zeolite, at least one of an acid treatment, a steaming treatment and a boiling treatment may be utilized.
The acid treatment employs a process which involves heating a 0. 5 to 5 N hydrochloric acid solution to 70 to 90~C

and throwing the modified ZSM-5 zeolite into the hydrochloric acidsolutiontoagitatetheresultingmixtureforlto 20 hours.
The boiling treatment employs a process which involves subjecting the unmodified ZSM-5 zeolite to a hydrating, rising the temperature of the atmosphere around the modified ZSM-5 zeolite in the hydrated state to 550 to 600~C, and maintaining the unmodified ZSM-5 zeolite in the risen-temperature atmosphere for about 4 hours.
The steaming treatment employs a process which involves maintaining the unmodified ZSM-5 zeolite in an atmosphere containing about 10 % of water and having a temperature of 750 to 900~C for 10 to 20 hours.

The acid, boilingandsteamingtreatments maybeutilized aloneorincombinationoftwoormorethereof,andifnecessary, each of the treatments may be repeated. In this manner, a modified ZSM-5 zeolite is produced, and the molar ratio of SiO2/Al2O3 thereof may be in a range of 25 to 800.

21~0379 Such a modified ZSM-5 zeolite has a hydrophobic nature increased depending upon the type of the dealuminization, and an increased adsorbing capability which is a characteristic, because it has a basic skeleton structure similar to that possessed by the unmodified ZSM-5 zeolite and moreover, has a specificsurfaceareaincreasedbytheremovalofaluminum.Thus, the modified ZSM-5 zeoliteexhibits agood adsorbingcapability to the hydrocarbon (HC) and the active aldehyde (CHO) even in the presence of water.
Further, the modified ZSM-5 zeolite has a crystallizability enhanced by the dealuminization, and the generation of nucleus of a pyrolysis product is inhibited.
Therefore,theheat-resistingtemperatureofthemodified ZSM-5 zeolite is increased to about l,000~C.
Inordertoenhancetheconversion ofNOxbythecatalyst, the weight percent Al (= {A/(A + B)} x 100) of the catalyst materialissetinarangeofll%byweight < Al< 95 % byweight, wherein A represents the weight of catalyst material incorporated, and B represents the weight of modified ZSM-5 zeolite incorporated.
Likewise, in order to enhance the conversion of NOx by the catalyst, the weight percent al (= {a/(a + b)} x 100) of Pt is set in a range of 0.1 % by weight c al < 5 % by weight, wherein a represents the weight of Pt incorporated, and b 21~0379 represents the weight of modified alumina incorporated.
Inproducingthecatalyst,basically,followingstepsare carriedoutsequentially:astepofsubjectinganactivealumina such as a ~-alummina to a thermal treatment with a heating temperature T set in a range of 800 ~C _ T < 1 , 100 ~C, preferably 900~C < T _ 1,050~C to produce a modified alumina having an ~-phase and having an ~-conversion rate R in a range of 0.1 % < R < 95 % from the active alumina, a step carrying platinum (Pt) into the modified alumina to provide a catalyst material, and a step of mixing the catalyst material with a modified ZSM-5 zeolite.
In this case, after the platinum has been carried in the modifiedzeolite, athermaltreatment similartothatdescribed above may be carried out to produce a modified alumina from the active alumina. The form of the catalyst is not limited to the mixture, and may be formed into a laminated structure having a layer formed of the catalyst material, and a layer formed of the modified ZSM-5 zeolite.
The carrying of Pt in the modified alumina or the active alumina is performed by immersing the modified alumina Ir the like into a hexachloroplatinic acid (H2PtC16) solution. Inthis case, the concentration of Pt in the hexachloro platinic acid solution is adjusted so that the weight percent a1 of Pt is in a range of 0.1 % by weight < al < 5 % by weight. The platinum 21~037~

compoundswhichmaybeused are variousPt-containingcompounds including Pt(NH3) 2 ( N~2 ) 2 and the like.
Particular embodiments will be described below.
Production of modified alumina A commercially available active alumina (y-alumina having ~-conversion rate of O %) was subjected to a thermal treatment at varied heating temperatures T for varied heating times t in the atmosphere to produce various modified alumina having different ~-conversion rates.
Table 6 shows the thermal treatment conditions and the ~-conversion rates R for examples 1 to 11 of the modified alumina.

Table 6 Thermal treatment conditions Modified Heating Heating time ~-conversion alumina temperature (hr) rate R (%) ( ~C ) Example 1 900 3 0.1 Example 2 900 10 0.2 Example 3 1000 4 3 Example 4 1000 7 5 Example 5 1000 10 7 Example 6 1000 20 29 Example 7 1000 25 51 Example 8 1000 30 64 Example 9 1000 70 81 Example 10 1000 100 89 Example 11 1000 150 95 Production of modified ZSM-5 zeolite (a) An Na-type unmodified ZSM-5 zeolite having a molar ratio of SiO2/Al2O3equal to 33.7 was placed in an amount of 500 g into a 5N hydrochloric acid solution of 90 (~C) and then, the mixture was agitated for 20 hours to provide a slurry.
(b) Solids were filtered off from the slurry and washed with a 20-times amount of pure water.
(c) The solids were dried in the atmosphere at 100 ~C for 5 hours and then, the dried solids were subjected to a firing in -the atmosphere at 400 ~C for 12 hours to produce a massive modified ZSM-5 zeolite.
(d) The massive modified ZSM-5 zeolite was subjected to a pulverization to provide a powdered modified ZSM-5 zeolite.
This modified ZSM-5 zeolite had a molar ratio of SiO2/Al2O3 of 41.3andhence,itcanbeseenthatthedealuminizationoccurred.
the heat-resisting temperature of the modified ZSM-5 zeolite was of l,000~C.

First embodiment Production of catalyst (a) The example 9 in Table 6, i.e., a modified alumina having an ~-conversion rate R of 81 % was placed in an amount of 98.5 g into 21.4 g of a hexachloro platinic acid solution (having a Pt concentration of 7.0 %), and the resulting mixture was blended sufficiently. Then, solids were filtered off and subjected to a drying at 120 ~C for one hour and then to a firing in the atmosphere at 600 ~C for one hour to produce a catalyst materialhavingaweightpercentalofPtequaltol. 5% byweight.
(b) 90 g of the catalyst material, 90 g of a modified ZSM-5 zeolite, 100 g of 20 % silica sol, 240 g of ethanol and alumina balls were thrown into a pot. The resulting mixture was subjected to a wet pulverization for 12 hours to prepare a slurry-like catalyst. In this case, the weight percent Al of the catalyst material was equal to 50 % by weight.

A cordierite honeycomb support having a diameter of 25.5 mm and a length of 60 mm and having 3Q0 cells of 10.5 mil was immersed into the slurry-like catalyst and then picked up from the slurry-like catalyst. An excessive amount of the catalyst was removed from the honeycomb support by injection of air.
Thereafter, the honeycomb support was maintained under heating at 120~C to dry the slurry-like catalyst, and further subjected to a firing in the atmosphere at 600~C for one hour to retain the catalyst in the honeycomb support. In this case, the amount ofcatalystcarriedinthe honeycombsupport wasof 150 g/liter.
This catalyst is called an example 1.
For comparison, a slurry-like catalyst was prepared in the same manner, except that a commercially available active alumina similar to that described above was used as an alumina.
This slurry-like catalyst and a honeycomb support similar to that described above were used, and the catalyst was retained in the honeycomb support in the same manner as described above.
In this case, the amount of catalyst retained in the honeycomb support was equal to the above-described amount and is called a comparative example 1.
Exhaust gas-assumed purifying test Assuming an exhaust gas corresponding to a theoretic air-fuel ratio A/F of 14.6 and an air-fuel ratio A/F of 24.3 in an atmosphere containing an excessive amount of air, two types of first and second test gases having compositions shown in Table 7 were prepared.

Table 7 Constituent First test gas (A/F = Second test gas (A/F =
14.6) (% by volume) 24.3) (% by volume) CO2 14.0 10.0 H2 0.17 0.05 C3H6 0.12 0.24 NO 0.05 0.12 CO 0.05 0.10 ~2 0.5 10.0 H20 10.0 10.0 N2 balance balance In the purifying test, first, the catalyst of the example 1 was placed in a fixed-bed flow type reactor apparatus. Then, the first test gas was supplied to flow through the apparatus at a space velocity S.V. of 5 x 104 h-1, wherein the temperature ofthe firsttest gaswasrisenfrom ambienttemperature at20 ~C

/min, and the percent conversions of hydrocarbon (HC), carbon monoxide (CO) and nitrogen monoxide (NO) were measured at a predetermined temperature. The second test gas was also used to measure the conversion of hydrocarbon (HC) and the like in the same manner. Further, a similar purifying test was carried out even with the catalyst of the comparative example 1.
Table 8 shows conditions for and results of the measurement.

Table 8 ~-conversionAir-fuel Measuring Conversion rate (%) Catalyst rate R of ratio A/F temperature modified alumina (%) of gas (~C) HCCO NO
Example 1 81 14.6 450 97 98 91 Comparative 0 98 98 64 example 1 Example 1 81 24.3 300 99 97 27 Comparative 0 98 95 14 example 1 C~

~150379 As apparent from Table 8, the catalyst of the example 1 exhibitsahigherpercentconversionofhydrocarbonandthelike.
Particularly, the percent conversion of nitrogen monoxide in the atmosphere containing an excessive amount of air with an air-fuelratioA/Fequalto24.3isabouttwotimesthatprovided in the comparative example 1. This is due to a difference in physical properties between the modified alumina having the ~
-conversion rate equal to 81 % and the active alumina having the ~-conversion rate equal to 0.

Second embodiment Various catalysts were produced in the same manner as in the firstembodiment.Inthiscase,thetotal amount ofcatalyst materialandmodifiedZSM-5zeoliteincorporatedwasdetermined at 180 g as in the first embodiment.
Table 9 shows the ~-conversion rate R of the modified alumina, the composition, the m~x;mllm NO conversion rate r and the gas temperature at which such percent conversion r was obtained, for the catalysts of examples 1 to 6 and comparative examples 1 and 2.
In these catalysts, the weight percent a1 of Pt is equal to 1.5 % by weight (constant); the weight percent Al of the catalyst material is equal to 25 % by weight (constant); and the ~-conversion rate R of the modified alumina is varied.

The purifying test was carried out in the same manner as in the first embodiment, using a second test gas (A/F = 24.3) 2~50379 similar to that used in the first embodiment. The same is true of other catalyst which will be described hereinafter.

Table 9 Catalyst ~-conversion Weight percent Weight percent Maximum NO Gas temperature rate R a1of Pt (% by Alof catalyst conversion rate of modified weight) material (% by r (%) alumina (%) weight) Example 1 0.1 1.5 25 25 260 Example 2 3 1.5 25 28 270 Example 3 29 1.5 25 32 320 Example 4 51 1.5 25 50 270 Example 5 64 1.5 25 54 260 Example 6 81 1.5 25 55 270 Comparative 0 1.5 25 22 270 example 1 Comparative 100 1.5 25 13 270 example 2 o 41 ~

Table 10 shows the ~-conversion rate R of the modified alumina, the composition, the maximum NO conversion rate r, and the gas temperature at which such maximum NO conversion rate r was obtained, for the catalysts of examples 7 to 14 and comparative examples 3 and 4.
In these catalysts, the weight percent al of Pt is equal to 1.5 % by weight (constant); the weight percent Al of the catalyst material is equal to 50 % by weight (constant); and the ~-conversion rate R of the modified alumina is varied.

Table 10 Catalyst ~-conversion Weight percent Weight percent Maximum NO Gas temperature rate R a1of Pt (% by Alof catalyst conversion rate of modified weight) material (% by r (%) alumina (%) weight) Example 7 0.2 1.5 50 26 270 Example 8 7 1.5 50 25 270 Example 9 29 1.5 50 26 270 Example 10 51 1.5 50 39 270 Example 11 64 1.5 50 42 260 Example 12 81 1.5 50 44 250 Example 13 89 1.5 50 37 260 Example 14 95 1.5 50 28 260 Comparative O 1. 5 50 22 280 example 3 Comparative 100 1. 5 50 13 340 example 4 C~

21~0379 Table 11 shows the ~-conversion rate R of the modified alumina, the composition, the m~x;mllm NO conversion rate r, and the gas temperature at which such m~; mllm NO conversion rate r was obtained, for the catalysts of examples 15 to 19 and comparative examples 5 and 6.
In these catalysts, the weight percent al of Pt is equal to 1.5 % by weight (constant); the weight percent Al of the catalyst material is equal to 75 % by weight (constant); and the ~-conversion rate R of the modified alumina is varied.

Table 11 Catalyst ~-conversion Weight percent Weight percent M~;mllm NO Gas temperature rate R a1of Pt (% by A,of catalyst conversion rate of modified weight) material (% by r (%) alumina (%) weight) Example 15 5 1.5 75 23 250 Example 16 29 1.5 75 25 260 Example 17 51 1.5 75 35 260 Example 18 64 1.5 75 38 260 Example 19 81 1.5 75 38 250 Comparative 0 1.5 75 19 270 example 5 Comparative 100 1.5 75 13 350 example 6 ca 215037g Fig.7 is a graph which illustrates the relationship between the a-conversion rate R and the maximum NO percent convertion r based on Tables 9 to 11. In Fig.7, points 1 to 19 correspond to the examples 1 to 19, respectively, and points (1) to (6) correspond to the comparative examples 1 to 6, respectively.
As apparent from Fig.7 and Tables 9 to 11, the alumina in each of the catalysts of the comparative examples 1, 3 and 5 is an active alumina having an a-conversion rate R of O %.
The aluminaineachofthecatalystsofthecomparativeexamples 2, 4 and 6 is an ~-alumina having an a-conversion rate R of 100 %. In this case, the highest value of the maximum NO
conversion rate r is 22 % with the catalysts of the comparative examples 1 and 3. Therefore, it is possible to increase the m~x; mllm NO conversion rate r to a value greater than 22 % in an atmosphere containing an excessive amount of air by setting the a-conversion rate R of the modified alumina in a range of 0.1 % < R _ 95 %, if the weight percent A1 of the catalyst material is in a range of 11 % by weight _ A1 < 95 % by weight and the weight percent alof Pt is in a range of 0.1 % by weight < al _ 5 % by weight, as in the catalysts of the examples 1 to 19. It can be seen from Fig.7 that if the a-conversion rate R of the modified alumina is set in a range of 45 % _ R - 90 %, the m~x; mllm NO conversion rate r can be further increased to a level in a range of 32 % _ r _ 55 % and therefore, the preferable range of the ~-conversion rate R of the modified alumina is of 45 _ R < 90 %.
Table 12 shows the ~-conversion rate R of the modified alumina, the composition, the maximumNO conversion rate r, and the gas temperature at which such maximum NO conversion rate r was obtained, for the catalysts of examples 20 to 25 and comparative examples 7 and 8.
In these catalysts, the ~ -conversion rate R of the modifiedaluminaisequalto81 %(constant); theweight percent a1 of Pt is equal to 1.5 % by weight (constant); and the Weight percent Al of the catalyst material is varied.

Table 1 2 Catalyst ~-conversion Weight percent Weight percent Maximum NO Gas temperature rate R alof Pt (% by Alof catalyst converslon rate(oC) alumina (%) weight) material (96 by r (96) 280 Example 20 81 1.5 Example 21 81 1.5 15 48 260 Example 22 81 1.5 35 51 270 Example 23 81 1.5 60 40.5 260 Example 24 81 1.5 80 36 260 Example 25 81 1.5 90 29 250 Comparative 81 1.5 10 19 320 Comparative 81 1.5 95 22 250 example 8 Fig.8 is a graph which illustrates, based on Tables 9 to 12, the relationship between the weight percent Al of the catalyst material and the m~x;mllm NO conversion rate r with the ~-conversion rate R of the modified alumina equal to 81 % and with the weight percent al of Pt equal to 1.5 % by weight. In Fig.8, points 6, 12, 19, and 20 to 25 correspond to the examples 6, 12, 19, and 20 to 25, respectively, and point (7) and (8) correspond to the comparative examples 7 and 8.
As apparent from Fig.8 and Table 12, the weight percent Al of the catalyst material in the catalyst of the comparative example 7 is equal to 10 % by weight, and the weight percent Al of the catalyst material in the catalyst of the comparative example 8 is equal to 95 % by weight. In this case, the highest value of the m~;mllm NO conversion rate r is 22 %. Therefore, it is possible to increase the mA~;mllm NO conversion rate r to a value greater than 22 % in an atmosphere containing an excessive amount of air by setting the weight percent Alof the catalyst material in a range of 11 % by weight _ A1 < 95 % by weight, if the ~-conversion rate R is in a range of 0.1 % _ R _ 95 % and the weight percent al of Pt is in a range of 0.1 %
< al _ 5 % by weight, as in the catalysts of the examples 6, 12, 19 and 20 to 25. It can be seen from Fig.8 that if the weight percent Al of the catalyst material is set in a range of 12 %
_ Al _ 80 % by weight, the m~;mllm NO conversion rate r can be increased to a level equal to or greater than 36 % and therefore, the preferable range of weight percent of the catalyst material is of 12 %_ Al _ 80 % by weight.

Table 13 shows the ~-conversion rate R of the modified alumina, and the composition, the maximum NO conversion rate r, and the gas temperature at which such maximum NO conversion rate r was obtained, for the catalysts of examples 26 and 27 and a comparative example 9.
In these catalysts, the ~ -conversion rate R of the modified aluminaisequalto81 %(constant); the Weightpercent A1ofthecatalystmaterialisequalto50%byweight(constant);
and the weight percent al of Pt is varied.

Table 13 Catalyst ~-conversion Weight percent Weight percent Maximum NO Gas temperature rate R alof Pt (% by A,of catalyst conversion rate of modified weight) material (% by r (%) alumina (%) weight) Example 26 81 0.5 50 37 270 Example 27 81 3.0 50 39 270 Comparative 81 0.1 50 22 320 example 9 o As apparent from Table 13, the weight percent a1 of Pt in the catalyst of the comparative example 9 is equal to 0.1 %
by weight. In this case, the highest value of the m~x;mllm NO
conversion rate r is 22 %. Therefore, it is possible to increase the m~x;mllm NO conversion rate r to a value greater than 22 %
in an atmosphere containing an excessive amount of air by setting the weight percent alof Pt in a range of 0.1 % by weight < a1 _ 5 % by weight, if the ~-conversion rate Rofthe modified alumina is in arangeofO.1 % _ R _ 95 % andthe weight percent a1 of the catalyst material is in a range of 11 % by weight _ Al < 95 % by weight, as in the catalysts of the examples 26 and 27.
III. Third exhaust emission control catalyst This catalyst is a mixture of a catalyst material and a CeO2 powder. The catalyst material is formed of an alumina and a catalytic metal carried in the alumina.
Thealuminausedisamodifiedaluminahavingan ~-phase.

The catalytic metal used is at least one element selected from the platinumgroup, i.e., Ru, Rh,Pd, Ir andPt.In anatmosphere containing an excessive amount of oxygen (for example, an air-fuel ratio A/F -. 24), Pt is preferred.
The ~-conversion rate R of the modified alumina is set in a range of 1 % _ R < 98 %, preferably, 30 % < R < 95 %. The measurement of the ~-conversion rate R was carried out in the same manner as described in the item I. The modified alumina was produced in the same manner as described in the item I.
Table 14 shows the thermal treatment conditions and the ~ -conversion rate R for examples 1 to 11 of the modified alumina.
Table 14 Modified Thermal treatment conditions ~-conversion alumina Heating Heating time rate R(%) temperature (~C)(hr) Example 1 900 3 0.1 Example 2 1000 4 3 Example 3 1000 7 5 Example 4 1000 10 7 Example 5 1000 20 29 Example 6 1000 25 51 Example 7 1000 30 64 Example 8 1000 70 81 Example 9 1000 100 89 Example 10 1000 150 95 Example 11 1000 200 98 In Fig.9, reference character 1 designates CeO2 having an NOx adsorbing capability. The CeO2 is in the form of a polycrystalline grain aggregate including a plurality of crystals 2. The average grain size D of the crystals is preferably set in a range of D < 500 A.
In producing cerium oxide (CeO2), any of various cerium salts such as cerium carbonates, oxlates, nitrates and the like is heated in the presence of oxygen. If it is desired to provide pure cerium oxide (CeO2) free of any of rare earth elements, the cerium oxide obtained after heating is cleaned with nitric acid.
The control of the average crystal grain size D is carried out by adjusting the heating temperature in the producing course.
For obtaining cerium oxide (CeO2) having an average crystal grain size D, for example, equal to 78 A, cerium nitrate is heated to 180 ~C. The average crystal grain size D can also be controlled by subjecting the produced cerium oxide to a thermal treatment. For example, when cerium oxide (CeO2) having an average crystal grain size D of 78 A is subjected to a thermal treatment at 700 ~C for 10 hours, ceriumoxide having an average crystal grain size D of 123 A.
In calculating the average grain size D(hkl~, Scherrer expression~ D(hk1~ = 0-9 A / (,G 1/2 ~ COs ~ ) was used, wherein hkl is a Miller index; A is a wavelength (A) of a characteristic X-ray; ,G 1/2 is a half width (radian)of a (hkl) face; and ~ is an X-ray reflection angle. Therefore, the average crystal grain size D is determined from a grain size D(lll~ of each of crystals 21S037~

calculated by measuring the half width ,G 1/2 of a face (111) from an X-ray diffraction pattern for cerium oxide (CeO2).
In the catalyst, the weight percent A1 (= {A/(A + E)} x 100) of the catalyst material is set in a range of 20 % by weight < A1 < 88 % by weight in order to the increase the NOx percent conversion, wherein A represents the weight of catalyst material incorporated, and E represents the weight of CeO2 incorporated.
Likewise, the weight percent al (= {a/(a + b)} x 100) of the catalytic metal in the catalyst is set in a range of 0.1 %
by weight < al < 5 % by weight in order to the increase the NOx percent conversion, wherein a represents the weight of catalytic metal incorporated, and b represents the weight of modified incorporated. In this case, if the weight percent al is equal to less than 0.1 % by weight, the NOx percent conversion is decreased by a reduction in catalytic capability. On the other hand, even if the weight percent al is set at a value greater than 5 % by weight, a NOx converting effect corresponding to an increase in amount of catalytic metal carried is not obtained.
In the production of the catalyst, a process is employed which involves carrying a catalytic metal in a modified alumina to produce a catalyst material and then mixing the catalyst material and cerium oxide (ceo2).

Inthiscase,acatalytic metalmaybecarriedinanactive alumina and then, the resulting catalyst material may be subjectedtoathermaltreatmentsimilartothatdescribedabove, thereby producing a modified alumina from the active alumina.
The form of the catalyst is not limited to the above-described mixture, and the catalyst may be formed into a laminated structure having a layer formed of a catalytic material and a layer formed of cerium oxide (CeO2).
In carrying, for example, platinum (Pt) in the modified or active alumina, the modified or active alumina is immersed in a hexachloro platinic acid (H2PtCl6) solution. In this case, the concentration of Pt in the hexachloro platinic acid is adjusted, so that the weight percent al of Pt is in a range of 1 % by weight < a1 _ 5 % by weight. Platinum compounds which can be utilized are various Pt-containing compounds such as Pt(NH3)2(NO2)2. In carrying paradium (Pd), a paradium nitrate solution is used. In carrying iridium (Ir), a ammonium hexacholo-iridate solution ((NH4)2IrCl6) is used. Further, in carrying rhodium, a rhodium nitrate (Rh(NO3)3) is used.
First embodiment Production of Catalyst (a)Theexample8inTable 14,i.e.,themodifiedaluminahaving an ~-conversion rate R of 81 % was placed in an amount of 98.5 into 21.4 g of a hexachloro platinic acid solution (having a Pt concentration of 7.0 %) and sufficiently mixed. Then, water 215037~

in the resulting mixture was removed using a rotary evaporator and thereafter, obtained solids were subjected to a drying at 120 ~C for 4 hours and further to a firing in the atmosphere at 600 ~C for 1 hour to provide a catalyst material having a Pt weight percent al equal to 1.5 % by weight.
(b) Then, 90 g of the catalyst material, 90 g of a cerium oxide powder having an average crystal grain size D of 78 A, 100 g of 20 % silica sol, 240 g of pure water and alumina balls were thrown into a pot, and the resulting mixture was subjected to a wet pulverization to prepare a slurry-like catalyst. In this case, the weight percent Al of the catalyst material is equal to 50 % by weight.
A cordierite honeycomb support having a diameter of 25.5 mm and a length of 60 mm and having 300 cells of 10.5 mil was immersed into the slurry-like catalyst and then picked up from the slurry-like catalyst. An excessive amount of the catalyst was removed from the honeycomb support by injection of air.
Thereafter, the honeycomb support was maintained under heating at 120~C to dry the slurry-like catalyst, and further subjected to a firing in the atmosphere at 600~C for one hour to retain the catalyst in the honeycomb support. In this case, the amount ofcatalystretainedinthehoneycombsupportwasof150g/liter.
This catalyst is called an example 1.
For comparison, a slurry-like catalyst was prepared in 215037~

the same manner, except that a commercially available active alumina ( r - alumina having an ~-conversion rate R of 0 %) was used as an alumina. This slurry-like catalyst and a honeycomb support similar to that described above were used, and the catalyst was retained in the honeycomb support in the same manner as described above. In this case, the amount of catalyst retained ln the honeycomb support was equal to the above-described amount and is called a comparative example 1.
Exhaust gas-assumed purifying test Assuming an exhaust gas corresponding to a theoretic air-fuel ratio A/F of 14.6 and an air-fuel ratio A/F of 24.3 in an atmosphere containing an excessive amount of oxygen, two types of first and second test gases having compositions shown in Table 15 were prepared.
Table 15 Constituent First test gas (A/F = Second test gas (A/F =
14.6) (% by volume)24.3) (% by volume) CO2 14.0 10.0 H2 0.17 0.05 C3H6 0.12 0.08 NO 0.05 0.08 CO 0.05 0.10 ~2 0.5 10.0 H20 10.0 10.0 N2 balance balance 21~0379 In a purifying test, first, the catalyst of the example 1 was placed in a fixed-bed flow type reactor apparatus. Then, the first test gas was supplied to flow through the apparatus at a space velocity S.V. of 5 x 104 h-l, wherein the temperature ofthe first test gaswas risenfromambienttemperature at20 ~C

/min, and the percent conversions of hydrocarbon (HC), carbon monoxide (CO) and nitrogen monoxide (NO) (which corresponds to NOx) were measured at a predetermined temperature. The second test gas was also used to measure the percent conversion of hydrocarbon (HC) and the like in the same manner. Further, a similar purifying test was carried out even with the catalyst of the comparative example 1.
Table 16 shows conditions for and results of the measurement.

Table 16 a -conversionAir-fuel Measuring Conversion rate (%) Catalyst rate R of ratio A/F temperature modified of gas (~C) alumina (%) HC CO NO
Example 1 81 14.6 450 97 98 92 Comparative 0 98 98 70 example 1 Example 1 81 24.3 250 98 90 59 Comparative 0 99 92 20 example 1 o ~~

~150379 As apparent from Table 16, the catalyst of the example lexhibitsahighpercentconversionofhydrocarbonandthelike.
Particularly, the percent conversion of nitrogen monoxide (NO) in the atmosphere containing an excessive amount of air with an air-fuel ratio A/F equal to 24.3 is about three times of that provided in the comparative example 1. This is due to a difference in physical properties between the modified alumina having the ~-conversion rate equal to 81 % and the active alumina having the ~-conversion rate equal to 0.

Second embodiment Various catalysts were produced in the same manner as in the firstembodiment.Inthiscase,thetotal amountofcatalyst material and cerium oxide (CeO2) incorporated was determined at 180 g as in the first embodiment.
Table 17 shows the ~-conversion rate R of the modified alumina, the average crystal grain size D of cerium oxide, the composition, the maximum NO conversion rate r and the gas temperature at which such percent conversion r was obtained, for the catalysts of examples 1 to 7 and comparative examples 1, 11 and 2.
In these catalysts, the average crystal grain size D of the cerium oxide is equal to 78 A; the weight percent al of Pt is equal to 1.5 % by weight (constant); the weight percent A
of the catalyst material is equal to 50 % by weight (constant), 21~0379 and the CY-conversion rate R of the modified alumina is varied.

The comparative example 1 is the same as the comparative example in the first embodiment.
The purifying test was carried out in the same manner as in the first embodiment, using a second test gas tA/F = 24.3) prepared to assume the atmosphere containing the excessive amount of air in the first embodiment. The same is true of other catalyst which will be described hereinafter.

Table 1 7 Catalyst ~-conversionAverage grainWeight Weight Maximum NO Gas rate R of size D of percent a1 ofpercent Al ofconversion temperature modified CeO2 (A) Pt (% by catalyst rate r (%) (~C) alumina (%) weight) material (%
by weight) Example 1 0.1 78 1.5 50 31 250 Example 2 7 78 1.5 50 34 250 Example 3 29 78 1.5 50 38 255 Example 4 51 78 1.5 50 48 250 Example 5 64 78 1.5 50 52 260 Example 6 89 78 1.5 50 53 255 Example 7 95 78 1.5 50 37 260 Comparative 0 78 1.5 50 22 245 example 1 Comparative98 78 1.5 50 22 265 example 1, Comparative100 78 1.5 50 15 265 example 2 21~0379 Table 18 shows the ~x-conversion rate R of the modified alumina, the average crystal grain size D of ceriumoxide (CeO2), the composition, the maximum NO conversion rate r and the gas temperature at which such percent conversion r was obtained, for the catalysts of examples 8 to 12.
In these catalysts, the cY-conversion rate R of the modified alumina is equal to 81 % (constant); the weight percent a1 of Pt is equal to 1.5 % by weight (constant); the weight percent A1 of the catalyst material is equal to 50 % by weight (constant);
and the average crystal grain size D of cerium oxide is varied.

Table 18 Catalyst ~-conversion AveragegrainWeight Weight Maximum NO Gas rate R of size D of CeO2percent alofpercent Alofconversion temperature modified (A) Pt (% by catalyst rate r (%) (~C) alumina (%) weight) material (%
by weight) Example 8 81 123 1.5 50 61 255 Example 9 81 205 1.5 50 59 255 Example 10 81 316 1.5 50 58 260 Example 11 81 542 1.5 50 37 265 Example 12 81 702 1.5 50 29 260 c~

n37~

Table 19 shows the ~-conversion rate R of the modified alumina, the average crystal grain size D of ceriumoxide (CeO2), the composition, the mAx;mllm NO conversion rate r and the gas temperature at which such percent conversion r was obtained, for the catalysts of examples 13 to 16 and comparative examples 3 to 6. The catalyst of the example 14 has the same structure as the catalyst of the example 1. The catalyst of the comparative example 6 includes a modified alumina and platinum (Pt) carried in the modified alumina. A catalyst of a comparative example 7 including cerium oxide (CeO2) and platinum carried in the cerium oxide is also shown in Table 7.
In the catalysts of the examples 13 to 16 and the comparative examples 3 to 5, the c~-conversion rate R is equal to 81 % (constant); the average crystal grain size D of the cerium oxide (CeO2) is equal to 78 A (constant); the weight percent al of Pt is equal to 1.5 % by weight (constant); and the weight percent Al of the catalyst material is varied.

Table 19 Catalyst ~-conversion AveragegrainWeight Weight Maximum NO Gas rate R of size of D ofpercent al ofpercent A1ofconversion temperature modifiedCeO2 (A) Pt (% by catalystrate r (%) (~C) alumina (%) weight)material (%
by weight) Example 13 81 78 1.5 25 46 265 Example 14 81 78 1.5 50 60 260 Example 15 81 78 1.5 75 49 250 Example 16 81 78 1.5 85 27 250 Comparative 81 78 1.5 15 8 290 example 3 Comparative 81 78 1.5 20 22 270 example 4 Comparative 81 78 1.5 88 22 250 example 5 Comparative 81 - 1.5 100 18 245 example 6 Comparative - 78 1.5 0 0 example 7 cn o c~.

Fig.10 is a graph illustrating the relationship between the ~-conversionrateRofthe modified alumina andthem~x;mllm NO percent conversion and taken from Tables 17 to 19. In Fig.7.
Points 1 to 16 correspond to the examples 1 to 16, and points (1) and (11) to (7) correspond to the comparative examples 1 and 11 to 7, respectively.
As apparent from Fig.10 and Tables 17 to 19, the highest value of the mAx;mllm NO percent conversions r provided by the catalysts of the comparative examples 1 and 11 to 7 is 22 %.
Therefore, it is possible to increase the maximum NO conversion rate r to a value greater than 22 % in an atmosphere containing an excessive amount of air by setting the ~-conversion rate R of the modified alumina in a range of 0.1 % _ R < 98 %, if the weight percent A1 of the catalyst material is in a range of 22 % by weight < A1 < 88 % by weight, as in the catalysts of the examples 1 to 16. In this case, the weight percent a of platinum (Pt) satisfies a range of 0.1 % by weight < a1 _ 5 % by weight. It can be seen from Fig.10 that if the ~ -conversion rate R of the modified alumina is set in a range of 30 % _ R _ 95 %, the m~x; mllm NO conversion rate r can be increasedto alevelequaltoor greaterthan39% andtherefore, the preferablerange ofthe ~-conversionrate Rofthe modified alumina is of 30 _ R _ 95 %.

21~037!~

Fig.11 is a graph illustrating the relationship between the weight percent Al of the catalyst material and the m~x;ml~m NO percent conversion taken from Tables 17 to 19. In Fig.11, points 1 to 16 correspond to the examples 1 to 16, and points (1) and (11) to (7) correspond to the comparative examples 1 and 11 to 7, respectively.
As apparent from Fig.ll and Tables 17 to 19, the highest value of the m~x;mllm NO percent conversions r provided by the catalysts of the comparative examples 1 and llto 7 is likewise 22 %. Therefore, it is possible to increase the m~;mllm NO
conversion rate r to a value greater than 22 % in an atmosphere containing an excessive amount of air by setting the weight percent Alof the catalyst material in a range of 20 % by weight < Al< 88 % by weight, if the ~-conversion rate of the modified alumina is in a range of 0.1 % _ R < 98 %, as in the catalysts of the examples 1 to 16. In this case, the weight percent a of platinum (Pt) satisfies a range of 0.1 % by weight < al <
5 % by weight. It can be seen from Fig.ll that if the weight percent of the catalyst material is set in a range of 23 % _ A1 < 81 % by weight, the m~x; mllm NO conversion rate r can be increasedto alevelequaltoor greaterthan39% andtherefore, the preferable range of the weight percent of the catalyst material is of 23 % _ Al _ 81 % by weight.
Fig.12 is a graph illustrating the relationship between 21~037~) the average crystal grain size D and the mAx;mllm NO percent conversion for examples 8 to 12 and 14 and taken from Tables 17 to 19. In Fig.12, points 8 to 12 and 14 correspond to the examples 8 to 12 and 14, respectively.
As apparent from Fig.12 and Tables 18 and 19, the maximum NOpercentconversionisincreased,astheaveragecrystalgrain size D of the cerium oxide (CeO2) is decreased. It can be seen from Fig.12 that the average crystal grain size D of the cerium oxide(CeO2)ispreferablyinarangeofD<500A,andtheoptimal range is of D _ 320 A.

If the average crystal grain size D of the cerium oxide (CeO2) issetintheabove-described range,the specificsurface area of the cerium oxide (CeO2) can be enlarged, and the fine pores can also be enlarged. Therefore, it is possible to increase the probability of contact of the cerium oxide with nitrogen oxide (NOx) to increase the NOx percent adsorption per unitweighteveninanatmospherecontaininganexcessiveamount of air.
Third Embodiment Various catalysts were produced in the same manner as in the first embodiment, except that 21.4 g of a palladium nitrate solutionwasusedtocarrypalladium(pd)in amodifiedalumina;
14.2 g of an ammonium hexachloro-iridate solution (having an Ir concentration of 3.5 %) was used to carry iridium in an modified alumina; and 14.2 g of a rhodium nitrate solution (having a Rh concentration of 3.5 %) was used to carry rhodium inamodifiedalumina.Inthiscase,thetotalamountofcatalyst material and cerium oxide (CeO2) incorporated was likewise set at 180 g.
Table 20 shows the ~-conversion rate R of the modified alumina, the average crystal grain size D of the cerium oxide, the composition, the mAx;mllm NO conversion rate r and the gas temperature at which such mAx;ml~m NO conversion rate r was obtained, for examples 1 to 3 and comparative examples 1 to 3.
A purifying test was carried out in the same manner as in the first embodiment, using a second test gas (A/F = 24.3) assuming the atmosphere containing the excessive amount of air in the first e-mbodiment.

Table 20 Catalyst ~-conversion AveragegrainWeight Weight Maximum NO Gas rate R of size D of CeO2percent al ofpercent A,ofconversion temperature modified (A) Pd, Ir, Rh (%catalyst rate r (%) (~C) alumina (%) by material (%
weight) by weight) Example 1 81 78 Pd:1.5 50 36 240 Comparative 0 78 Pd:1.5 50 12 230 example 1 Example 2 81 78 Ir:0.5 50 39 290 Comparative 0 78 Ir:0.5 50 12 285 example 2 Example 3 81 78 Rh:0.5 50 36 310 Comparative 0 78 Rh:0.5 50 9 305 example 3 21 5~379 It can be seen from Table 20 that the m~;ml~m NO percent conversion provided by the catalysts of the examples 1 to 3 in the atmosphere containing the excessive amount of air was increased to a level three times of those provided when the active alumina (~-alumina) was used, as in the catalysts of the comparative examples 1 to 3, because the modified alumina having the a-conversion rate R equal to 81 % was used in the examples 1 to 3.

~lSG379 Effect of the Invention According to the present invention, it is possible to provide an exhaust emission control catalyst wherein the NOx percent conversion can be increased in a wider range of temperature of an exhaust gas by using the modified alumina specified as described above.
According to the present invention, it is possible to provide an exhaust emission control catalyst which exhibits a high NOx percent conversion even in an atmosphere containing an excessive amount of air by specifying the ~-conversion R

of the modified alumina, the weight percent A1 of the catalyst material and the weight percent al of the catalyst material as described above.
According to the present invention, it is possible to provide an exhaust emission control catalyst which includes a catalyst material formed of an alumina and a catalytic metal carried in the alumina, and cerium oxide (CeO2), and which exhibits a high NOx percent conversion even in an atmosphere containing an excessive amount of air by specifying the ~-conversion R of the modified alumina, the weight percent A1 ofthe catalyst material as described above.
Further, according to the present invention, it is possible to provide a process for easily mass-producing an exhaust emission control catalyst having excellent characteristics as described above.

Claims

WHAT IS CLAIMED IS

1. An exhaust emission control catalyst comprising an alumina, and a catalytic metal carried in the alumina, the catalytic metal being at least one element selected from the platinum group, wherein said alumina comprises a modified alumina which has a .theta.
-phase and an .alpha.-phase and has an .alpha.-conversion rate R in a range of 0.5 % < R < 95 %.

2. An exhaust emission control catalyst comprising a catalyst material and a solid acidic aluminosilicate having a molecular sieves property, the catalyst material being formed of an alumina and a catalytic metal carried in the alumina, wherein said alumina is a modified alumina having an .alpha. -conversion rate R set in a range of 0.1 % < R < 95 %;
the weight percent A1 (={A/(A+B)}x100) of said catalyst material is set in a range of 11 % by weight< A1 < 95 % by weight, wherein A represents an amount of catalyst material incorporated, and B represents an amount of aluminosilicate incorporated; and said catalytic metal is at least one element selected from the platinum group, the weight percent a1 of the catalyst metal being set in a range of 0.1 by weight < a1 < 5 % by weight.

3. An exhaust emission control catalyst according to claim 2, wherein said aluminosilicate is a modified zeolite which is obtained by subjecting an unmodified zeolite to a dealuminization.

4. An exhaust emission control catalyst according to claim 2 or 3, wherein said catalytic metal is platinum (Pt).

5. An exhaust emission control catalyst comprising cerium oxide (CeO2), and a catalyst material formed of an alumina and a catalytic metal carried in the alumina, wherein said alumina is a modified alumina having an .alpha. -conversion rate R set in a range of 0.1 % < R < 98 %, and the weight percent A1 (={A/(A + E)} x 100) of said catalyst material is set in a range of 20 % by weight < A1 < 88 % by weight, wherein A represents an amount of catalyst material incorporated, and E represents an amount of cerium oxide (CeO2) incorporated.

6. An exhaust emission control catalyst according to claim 5, wherein said catalytic metal is at least one metal selected from the platinum group, the weight percent a1 of said catalytic metal in said catalyst material being set in a range of 0.1 % by weight < a1 < 5 % by weight.

7. An exhaust emission control catalyst according to claim 5 or 6, wherein said catalytic metal is platinum (Pt).

8. An exhaust emission control catalyst according to claim 5, 6 or 7, wherein the average crystal gain size D of the cerium oxide (CeO2) is smaller than 500 .ANG..

9.A process for producing an exhaust emission control catalyst, comprising the steps of:
subjecting an active alumina to a thermal treatment at a heating temperature T set in a range of 800 °C < T < 1,100°C
to phase-convert the active alumina into a modified alumina having a .theta.-phase and an .alpha.-phase and having an .alpha.-conversion rate R in a range of 0.5 % < R < 95 %; and carrying, in said modified alumina, at least one catalytic metal selected from the platinum group.

10.A process for producing an exhaust emission control catalyst, comprising the steps of:
carrying, in a modified alumina, at least one catalytic metal selected from the platinum group; and subjecting said active alumina with said catalytic metal carried therein to a thermal treatment at a heating temperature T set in a range of 800 °C < T < 1,100°C to phase-convert said active alumina into a modified alumina having a .theta.-phase and an .alpha.-phase and having an .alpha.-conversion rate R in a range of 0.5%
< R < 95 %.

11.A process for producing an exhaust emission control catalyst, comprising the steps of:
subjecting an active alumina to a thermal treatment at a heating temperature T set in a range 800°C ~ T ~ 1,100°C to produce a modified alumina having an .alpha.-conversion rate R in a range of 0.1 % ~ R ~ 95 % from said active alumina;
carrying, in said modified alumina, at least one element selected from the platinum group to fabricate a catalyst material, the weight percent a1 of said catalytic metal in said catalyst material being set in a range of 0.1 % by weight < a1 ~ 5 % by weight; and mixing said catalyst material with a solid acidic aluminosilicate having a molecular sieves property, the weight percent A1(= {A/(A + B)} x 100) of said catalyst material being set in a range of 11 % by weight ~ A1 < 95 % by weight, wherein A represents an amount of catalyst material incorporated, and B represents an amount of aluminosilicate incorporated.

12. A process for producing an exhaust emission control catalyst, comprising the steps of:
subjecting an active alumina to a thermal treatment at a heating temperature T set in a range of 800 °C ~ T ~ 1,100°C
to produce a modified alumina having an .alpha.-conversion rate R
in a range of 0.1 % ~ R < 98 %;
carrying, in said modified alumina, at least one catalytic metal selected from the platinum group to fabricate a catalyst material; and mixing said catalyst material with cerium oxide (CeO2), the weight percent A1 (= {A/(A + E)} x 100) of catalyst material being set in a range of 20 % by weight < A1 < 88 % by weight, wherein A represents an amount of catalyst material incorporated, and E represents an amount of cerium oxide incorporated.