CA2156607A1 - Production of attrition-resistant catalyst binders through use of delaminated clay - Google Patents

Production of attrition-resistant catalyst binders through use of delaminated clay

Info

Publication number
CA2156607A1
CA2156607A1 CA2156607A CA2156607A CA2156607A1 CA 2156607 A1 CA2156607 A1 CA 2156607A1 CA 2156607 A CA2156607 A CA 2156607A CA 2156607 A CA2156607 A CA 2156607A CA 2156607 A1 CA2156607 A1 CA 2156607A1
Authority
CA
Canada
Prior art keywords
attrition
production
resistant catalyst
delaminated clay
catalyst binders
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2156607A
Other languages
French (fr)
Other versions
CA2156607C (en
Inventor
Edward J. Demmel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey Process Technologies Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2156607A1 publication Critical patent/CA2156607A1/en
Application granted granted Critical
Publication of CA2156607C publication Critical patent/CA2156607C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr

Abstract

Attrition-resistant binders can be pre-pared by a process wherein a slurry of delam-inated and calcined clay particles is brought to either a low pH level (e.g., 1.0 to 3.0) or to a high pH level (e.g., 14.0 to 10.0) and mixed with a phostate-containing compound in a concentration of from about 2.0 to about 20.0 weight percent. Preferably, the resulting slurry is spray dried and the particulate prod-ucts of the spray drying are then calcined to produce attrition-resistant binder particles.
CA002156607A 1993-03-01 1994-02-07 Production of attrition-resistant catalyst binders through use of delaminated clay Expired - Fee Related CA2156607C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/024,688 US5288739A (en) 1992-06-04 1993-03-01 Production of attrition-resistant catalyst binders through use of delaminated clay
US024,688 1993-03-01

Publications (2)

Publication Number Publication Date
CA2156607A1 true CA2156607A1 (en) 1994-09-15
CA2156607C CA2156607C (en) 1998-09-01

Family

ID=21821880

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002156607A Expired - Fee Related CA2156607C (en) 1993-03-01 1994-02-07 Production of attrition-resistant catalyst binders through use of delaminated clay

Country Status (7)

Country Link
US (1) US5288739A (en)
EP (1) EP0687202B1 (en)
AU (1) AU676018B2 (en)
CA (1) CA2156607C (en)
DE (1) DE69425650T2 (en)
DK (1) DK0687202T3 (en)
WO (1) WO1994020211A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3135748A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. A composition and a process for preparation of attrition resistant cracking catalyst suitable for enhancing light olefins
EP3135373A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. Preparation and composition of a fluid catalytic cracking catalyst additive with lower phosphate content for enhanced lpg yield

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US5472922A (en) * 1993-10-25 1995-12-05 Mobil Oil Corporation Manufacture of improved catalyst
JP2816098B2 (en) * 1994-08-02 1998-10-27 日本碍子株式会社 Honeycomb structure and manufacturing method thereof
US5521133A (en) * 1994-11-29 1996-05-28 Engelhard Corporation Phosphorus bound porous microspheres
US5786031A (en) * 1995-06-07 1998-07-28 Engelhard Corporation Barrier for a metal substrate
US5584925A (en) * 1995-06-26 1996-12-17 Thiele Kaolin Company Chemically aggregated kaolin clay pigment and process for making the same by phosphate bonding
WO1997012011A1 (en) * 1995-09-25 1997-04-03 Intercat, Inc. Bottoms cracking catalysts
US5958818A (en) * 1997-04-14 1999-09-28 Bulldog Technologies U.S.A., Inc. Alkaline phosphate-activated clay/zeolite catalysts
US6103949A (en) * 1997-04-14 2000-08-15 Bulldog Technologies U.S.A., Inc. Alkaline phosphate-activated clay/zeolite catalysts
JP3927704B2 (en) * 1997-10-15 2007-06-13 中国石油化工集団公司 Catalyst for catalytic pyrolysis process for the production of light olefins and its preparation
DE19829747A1 (en) * 1998-07-03 2000-01-05 Huels Infracor Gmbh Dealuminated catalyst support, process for the preparation of the catalyst support and process for hydrating C2 or C3 olefins with water in the presence of a catalyst consisting of this catalyst support impregnated with acid
US7259286B2 (en) * 2000-08-28 2007-08-21 Research Triangle Institute Attrition resistant bulk iron catalysts and processes for preparing and using same
EP1786559A2 (en) * 2004-08-27 2007-05-23 Albemarle Netherlands B.V. Hydrocarbon conversion process using nanosized particles
US20060277819A1 (en) * 2005-06-13 2006-12-14 Puri Suresh K Synergistic deposit control additive composition for diesel fuel and process thereof
US8222180B2 (en) * 2005-08-01 2012-07-17 Indian Oil Corporation Limited Adsorbent composition for removal of refractory sulphur compounds from refinery streams and process thereof
US7517827B2 (en) * 2006-02-27 2009-04-14 Indian Oil Company Ltd Process for preparation of liquefied petroleum gas selective cracking catalyst
CN101590432B (en) * 2008-05-28 2011-04-20 中国石油天然气股份有限公司 Modified clay and preparation method thereof
BR112013021991A8 (en) * 2011-03-10 2018-07-10 Kior Inc Phyllosilicate-based compositions and methods of manufacture thereof for catalytic pyrolysis of biomass
BR112013026166A2 (en) * 2011-04-13 2019-09-24 Kior Inc improved catalyst for thermocatalytic conversion of biomass to liquid fuels and chemicals
US9518229B2 (en) 2012-07-20 2016-12-13 Inaeris Technologies, Llc Catalysts for thermo-catalytic conversion of biomass, and methods of making and using
US9522392B2 (en) 2013-03-15 2016-12-20 Inaeris Technologies, Llc Phosphorous promotion of zeolite-containing catalysts
EP3071325B1 (en) * 2013-11-18 2021-03-03 Indian Oil Corporation Limited Process of preparing a catalyst for enhancing liquid yield in thermal coking process
US10245581B2 (en) 2015-11-30 2019-04-02 Indian Oil Corporation Limited Composition and process for preparation of attrition resistant additive suitable for cracking hydrocarbon feed

Family Cites Families (16)

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US2377093A (en) * 1940-10-19 1945-05-29 Universal Oil Prod Co Conversion of hydrocarbon oils
US2531427A (en) * 1946-05-03 1950-11-28 Ernst A Hauser Modified gel-forming clay and process of producing same
US2848423A (en) * 1954-07-20 1958-08-19 Houdry Process Corp Preparation of kaolin catalysts
US2921018A (en) * 1956-11-30 1960-01-12 Phillips Petroleum Co Method for improving used cracking catalysts
US3044954A (en) * 1958-04-11 1962-07-17 Sun Oil Co Siliceous cracking catalyst with a discontinuous surface glaze
BE582883A (en) * 1958-10-28
US4471070A (en) * 1982-11-29 1984-09-11 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels
US4594332A (en) * 1983-10-20 1986-06-10 Basf Aktiengesellschaft Preparation of hard, fracture-resistant catalysts from zeolite powder
US4728635A (en) * 1986-04-07 1988-03-01 Katalistiks International Inc. Alkaline earth metal spinels and processes for making
US4873211A (en) * 1987-07-02 1989-10-10 Phillips Petroleum Company Cracking catalyst and process
EP0358261B1 (en) * 1988-09-06 1994-04-13 Petroleo Brasileiro S.A. - Petrobras Kaolin containing fluid cracking catalyst
US5173463A (en) * 1988-09-06 1992-12-22 Petroleo Brasileiro, S.A.-Petrobras Kaolin containing fluid cracking catalyst
US5126298A (en) * 1991-03-12 1992-06-30 Mobil Oil Corp. Cracking catalysts comprising clays with different particle sizes, and method of preparing and using the same
US5231064A (en) * 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5110776A (en) * 1991-03-12 1992-05-05 Mobil Oil Corp. Cracking catalysts containing phosphate treated zeolites, and method of preparing the same
US5190902A (en) * 1992-06-04 1993-03-02 Demmel Edward J Method for producing attrition-resistant catalyst binders

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3135748A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. A composition and a process for preparation of attrition resistant cracking catalyst suitable for enhancing light olefins
EP3135373A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. Preparation and composition of a fluid catalytic cracking catalyst additive with lower phosphate content for enhanced lpg yield
US10252249B2 (en) 2015-08-24 2019-04-09 Indian Oil Corporation Limited Composition and a process for preparation of attrition resistant cracking catalyst suitable for enhancing light olefins
US10449524B2 (en) 2015-08-24 2019-10-22 Indian Oil Corporation Limited Process and composition for preparation of cracking catalyst suitable for enhancing LPG

Also Published As

Publication number Publication date
AU676018B2 (en) 1997-02-27
EP0687202B1 (en) 2000-08-23
EP0687202A1 (en) 1995-12-20
DE69425650D1 (en) 2000-09-28
DE69425650T2 (en) 2001-05-23
AU6101694A (en) 1994-09-26
EP0687202A4 (en) 1997-07-09
US5288739A (en) 1994-02-22
DK0687202T3 (en) 2000-12-27
WO1994020211A1 (en) 1994-09-15
CA2156607C (en) 1998-09-01

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