CA2163734A1 - Siloxane Modified Polyolefin Copolymers - Google Patents

Siloxane Modified Polyolefin Copolymers

Info

Publication number
CA2163734A1
CA2163734A1 CA2163734A CA2163734A CA2163734A1 CA 2163734 A1 CA2163734 A1 CA 2163734A1 CA 2163734 A CA2163734 A CA 2163734A CA 2163734 A CA2163734 A CA 2163734A CA 2163734 A1 CA2163734 A1 CA 2163734A1
Authority
CA
Canada
Prior art keywords
siloxane modified
alkylphenyl
carbons
phenyl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2163734A
Other languages
French (fr)
Other versions
CA2163734C (en
Inventor
Steven Daryl Smith
Andrew Julian Wnuk
Margaret Sue Gerber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Steven Daryl Smith
Andrew Julian Wnuk
Margaret Sue Gerber
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Steven Daryl Smith, Andrew Julian Wnuk, Margaret Sue Gerber, The Procter & Gamble Company filed Critical Steven Daryl Smith
Publication of CA2163734A1 publication Critical patent/CA2163734A1/en
Application granted granted Critical
Publication of CA2163734C publication Critical patent/CA2163734C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1386—Natural or synthetic rubber or rubber-like compound containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product

Abstract

A siloxane modified copolymer with the following general formula: <IMAGE> wherein: x=1 to 1000; m=2 to 100; n=0 to 1000; z=0 to 2; y=1 to 3; (z+y)=3; and p=1 to 200; wherein R and R1 are independently selected from the group consisting of hydrogen, alkyl groups having 1 to 6 carbons, phenyl, benzyl or alkylphenyl having from 6 to 12 carbons; R2 is selected from the group consisting of C1 to C6 alkyl, phenyl, benzyl or alkylphenyl having from 6 to 12 carbons; R3 is methyl, ethyl or propyl; and Z is O, S, NH or NR' wherein R' is phenyl, C1 to C4 alkyl or C1 to C3 alkylphenyl. A process for obtaining siloxane modified copolymer comprising: reactively extruding organosiloxanes having reactive terminal groups with polyolefins having reactive groups, the molar ratio of the functional groups being from about 1:1 to about 1:100,000 in a substantially solvent-free environment at a temperature from about 150 DEG C. to about 350 DEG C. for not more than 1 hour at 50 to 350 rpm.
CA 2163734 1993-06-24 1994-06-03 Siloxane modified polyolefin copolymers Expired - Fee Related CA2163734C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/082,685 US5476901A (en) 1993-06-24 1993-06-24 Siloxane modified polyolefin copolymers
US08/082,685 1993-06-24
PCT/US1994/006236 WO1995000578A1 (en) 1993-06-24 1994-06-03 Siloxane modified polyolefin copolymers

Publications (2)

Publication Number Publication Date
CA2163734A1 true CA2163734A1 (en) 1995-01-05
CA2163734C CA2163734C (en) 2000-10-31

Family

ID=22172756

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2163734 Expired - Fee Related CA2163734C (en) 1993-06-24 1994-06-03 Siloxane modified polyolefin copolymers

Country Status (10)

Country Link
US (2) US5476901A (en)
EP (1) EP0705297B1 (en)
JP (1) JPH08511825A (en)
KR (1) KR100329900B1 (en)
AT (1) ATE184295T1 (en)
AU (2) AU6963494A (en)
CA (1) CA2163734C (en)
DE (1) DE69420560T2 (en)
ES (1) ES2135584T3 (en)
WO (1) WO1995000578A1 (en)

Families Citing this family (202)

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