CA2172636A1 - Flexible cube-corner retroreflective sheeting - Google Patents

Flexible cube-corner retroreflective sheeting

Info

Publication number
CA2172636A1
CA2172636A1 CA002172636A CA2172636A CA2172636A1 CA 2172636 A1 CA2172636 A1 CA 2172636A1 CA 002172636 A CA002172636 A CA 002172636A CA 2172636 A CA2172636 A CA 2172636A CA 2172636 A1 CA2172636 A1 CA 2172636A1
Authority
CA
Canada
Prior art keywords
cube
retroreflective sheeting
body portion
corner retroreflective
flexible cube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002172636A
Other languages
French (fr)
Other versions
CA2172636C (en
Inventor
Kenneth L. Smith
Tzu-Li J. Huang
James C. Coderre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Kenneth L. Smith
Tzu-Li J. Huang
James C. Coderre
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kenneth L. Smith, Tzu-Li J. Huang, James C. Coderre, Minnesota Mining And Manufacturing Company filed Critical Kenneth L. Smith
Publication of CA2172636A1 publication Critical patent/CA2172636A1/en
Application granted granted Critical
Publication of CA2172636C publication Critical patent/CA2172636C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/14Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of indefinite length
    • B29C39/148Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of indefinite length characterised by the shape of the surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S359/00Optical: systems and elements
    • Y10S359/90Methods
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24521Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness with component conforming to contour of nonplanar surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material

Abstract

A retroreflective article (10) has a body portion (14) and a multiple of cube-corner elements (12) that project from a rear side (20) of the body portion (14). The body portion (14) includes a body layer (18) that contains a light-transmissible polymeric material having an elastic modulus less than 7 x 108 pascals. The cube-corner elements (12) contain a light transmissible polymeric material having an elastic modulus greater than 16 x 108 pascals. A
retroreflective article of this construction can be highly flexed while maintaining good retroreflective performance.
CA002172636A 1993-10-20 1994-10-20 Flexible cube-corner retroreflective sheeting Expired - Lifetime CA2172636C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/139,433 US5450235A (en) 1993-10-20 1993-10-20 Flexible cube-corner retroreflective sheeting
US08/139433 1993-10-20
PCT/US1994/011943 WO1995011466A1 (en) 1993-10-20 1994-10-20 Flexible cube-corner retroreflective sheeting

Publications (2)

Publication Number Publication Date
CA2172636A1 true CA2172636A1 (en) 1995-04-27
CA2172636C CA2172636C (en) 2006-01-24

Family

ID=22486629

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002172636A Expired - Lifetime CA2172636C (en) 1993-10-20 1994-10-20 Flexible cube-corner retroreflective sheeting

Country Status (11)

Country Link
US (5) US5450235A (en)
EP (1) EP0724731B1 (en)
JP (1) JP3623506B2 (en)
CN (1) CN1040694C (en)
AT (1) ATE189316T1 (en)
AU (1) AU676619B2 (en)
CA (1) CA2172636C (en)
DE (1) DE69422823T2 (en)
DK (1) DK0724731T3 (en)
ES (1) ES2141264T3 (en)
WO (1) WO1995011466A1 (en)

Families Citing this family (234)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6318867B1 (en) 1993-10-20 2001-11-20 3M Innovative Properties Company Conformable cube corner retroreflective sheeting
US5600484A (en) 1993-10-20 1997-02-04 Minnesota Mining And Manufacturing Company Machining techniques for retroreflective cube corner article and method of manufacture
EP0724738B1 (en) * 1993-10-20 2000-05-10 Minnesota Mining And Manufacturing Company Asymetric cube corner article and method of manufacture
US5450235A (en) * 1993-10-20 1995-09-12 Minnesota Mining And Manufacturing Company Flexible cube-corner retroreflective sheeting
US5691846A (en) * 1993-10-20 1997-11-25 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture
EP0724737B1 (en) * 1993-10-20 1998-07-22 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture
US5658670A (en) * 1994-08-19 1997-08-19 Minnesota Mining And Manufactury Company Multi-layer compositions having a fluoropolymer layer
US6206525B1 (en) 1994-09-28 2001-03-27 Reflexite Corporation Miniature micro prism retroreflector
US6599597B1 (en) * 1995-06-07 2003-07-29 Nike, Inc. Barrier membranes including a barrier layer employing aliphatic thermoplastic urethanes
AU700594B2 (en) * 1995-06-09 1999-01-07 Minnesota Mining And Manufacturing Company Tiled retroreflective sheeting
JP3717938B2 (en) * 1995-06-29 2005-11-16 ミネソタ マイニング アンド マニュファクチャリング カンパニー Wet retroreflective marker material
US6451408B1 (en) 1995-06-29 2002-09-17 3M Innovative Properties Company Retroreflective article
US6703108B1 (en) 1995-06-29 2004-03-09 3M Innovative Properties Company Wet retroreflective marking material
CN1198790A (en) * 1995-10-05 1998-11-11 美国3M公司 Flexible raised pavement marker, mounting device and method
AU7724196A (en) * 1995-11-02 1997-05-22 Minnesota Mining And Manufacturing Company Microstructured articles with backing and methods of manufacture
US20030170426A1 (en) * 1995-12-01 2003-09-11 W. Scott Thielman Cellular retroreflective sheeting
US5706132A (en) * 1996-01-19 1998-01-06 Minnesota Mining And Manufacturing Company Dual orientation retroreflective sheeting
USD383312S (en) * 1996-01-19 1997-09-09 Minnesota Mining And Manufacturing Company Seal pattern on retroreflective sheeting
US5905826A (en) * 1996-01-24 1999-05-18 Minnesota Mining And Manufacturing Co. Conspicuity marking system including light guide and retroreflective structure
JPH09212115A (en) * 1996-02-02 1997-08-15 Minnesota Mining & Mfg Co <3M> Retroreflection sheet and article having retroreflection performance
US5882796A (en) * 1996-04-01 1999-03-16 Minnesota Mining And Manufacturing Company Bonded structured retroreflective sheeting
US5910858A (en) * 1996-04-01 1999-06-08 Minnesota Mining And Manufacturing Company Retroreflective sheeting with coated back surface
US5784197A (en) * 1996-04-01 1998-07-21 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective sheeting with coated back surface
US5754338A (en) * 1996-04-01 1998-05-19 Minnesota Mining And Manufacturing Company Structured retroreflective sheeting having a rivet-like connection
US5805338A (en) * 1996-04-10 1998-09-08 Minnesota Minning And Manufacturing Company Pillowed flexible cube-corner sheeting and methods of manufacture
US5948488A (en) * 1996-04-30 1999-09-07 3M Innovative Properties Company Glittering cube-corner article
US5763049A (en) * 1996-04-30 1998-06-09 Minnesota Mining And Manufacturing Company Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same
US5814355A (en) * 1996-04-30 1998-09-29 Minnesota Mining And Manufacturing Company Mold for producing glittering cube-corner retroreflective sheeting
US5840405A (en) * 1996-04-30 1998-11-24 Minnesota Mining And Manufacturing Company Glittering cube-corner retroreflective sheeting
US5770124A (en) * 1996-04-30 1998-06-23 Minnesota Mining And Manufacturing Company Method of making glittering cube-corner retroreflective sheeting
US6015214A (en) 1996-05-30 2000-01-18 Stimsonite Corporation Retroreflective articles having microcubes, and tools and methods for forming microcubes
US6303058B1 (en) 1996-06-27 2001-10-16 3M Innovative Properties Company Method of making profiled retroreflective marking material
US5855977A (en) * 1996-08-26 1999-01-05 Minnesota Mining And Manufacturing Company Multi-layer compositions comprising a fluoropolymer
JP3974959B2 (en) * 1996-09-30 2007-09-12 スリーエム カンパニー Method for manufacturing retroreflective information display sheet
US6083607A (en) * 1996-10-18 2000-07-04 Nippon Carbide Kogyo Kabushiki Kaisha Triangular pyramidal cube corner type retroreflective sheet
CN1091409C (en) 1996-10-23 2002-09-25 美国3M公司 Article comprising flexible retroreflective sheeting
US6021559A (en) * 1996-11-01 2000-02-08 3M Innovative Properties Company Methods of making a cube corner article master mold
US5734501A (en) * 1996-11-01 1998-03-31 Minnesota Mining And Manufacturing Company Highly canted retroreflective cube corner article
US6861141B2 (en) 1996-12-04 2005-03-01 Gina M. Buccellato Pavement marking article and raised pavement marker that uses pressure sensitive adhesive
US5922238A (en) * 1997-02-14 1999-07-13 Physical Optics Corporation Method of making replicas and compositions for use therewith
US6156436A (en) * 1997-04-04 2000-12-05 3M Innovative Properties Company Use of a crystalline bead bond layer in a retroreflective article
US6656566B1 (en) 1997-04-15 2003-12-02 3M Innovative Properties Company Retroreflective luminescent articles
DE29707066U1 (en) * 1997-04-21 1997-08-14 Imos Gubela Gmbh Microretroflector
US5959793A (en) * 1997-06-06 1999-09-28 Globe-Amerada Glass Co. Laminated safety mirror with reflective coating adjacent the bonding layer
US6197393B1 (en) 1997-06-27 2001-03-06 3M Innovative Properties Company Multi-layer compositions comprising a fluoropolymer
US6117508A (en) 1997-06-27 2000-09-12 Dyneon Llc Composite articles including a fluoropolymer blend
US5889615A (en) * 1997-06-27 1999-03-30 Minnesota Mining And Manufacturing Company Dual axis retroreflective articles
CN1105637C (en) 1997-07-02 2003-04-16 美国3M公司 Cube corner sheeting mold and its mfg. method
US5898523A (en) * 1997-07-02 1999-04-27 Minnesota Mining & Manufacturing Company Tiled retroreflective sheeting composed of highly canted cube corner elements
KR100574610B1 (en) 1997-07-02 2006-04-28 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 Retroreflective cube corner sheeting, molds therefor, and methods of making the same
US6253442B1 (en) * 1997-07-02 2001-07-03 3M Innovative Properties Company Retroreflective cube corner sheeting mold and method for making the same
US5981032A (en) * 1997-07-02 1999-11-09 3M Innovative Properties Company Retroreflective cube corner sheeting mold and sheeting formed therefrom
US6420622B1 (en) 1997-08-01 2002-07-16 3M Innovative Properties Company Medical article having fluid control film
US6375871B1 (en) 1998-06-18 2002-04-23 3M Innovative Properties Company Methods of manufacturing microfluidic articles
US6524488B1 (en) 1998-06-18 2003-02-25 3M Innovative Properties Company Method of filtering certain particles from a fluid using a depth loading filtration media
US6290685B1 (en) 1998-06-18 2001-09-18 3M Innovative Properties Company Microchanneled active fluid transport devices
US6080243A (en) * 1998-06-18 2000-06-27 3M Innovative Properties Company Fluid guide device having an open structure surface for attachement to a fluid transport source
US6907921B2 (en) 1998-06-18 2005-06-21 3M Innovative Properties Company Microchanneled active fluid heat exchanger
US6431695B1 (en) 1998-06-18 2002-08-13 3M Innovative Properties Company Microstructure liquid dispenser
US6110566A (en) * 1997-10-23 2000-08-29 3M Innovative Properties Company Stabilization of fluorescent dyes in vinyl articles using hindered amine light stabilizers
US5940212A (en) * 1997-10-30 1999-08-17 3M Innovative Properties Company Cube corner article with altered inactive areas and method of making same
JP3580999B2 (en) 1997-11-17 2004-10-27 日本カーバイド工業株式会社 Triangular pyramidal cube corner retroreflective sheet
US6036322A (en) 1997-12-01 2000-03-14 Reflexite Corporation Multi-orientation retroreflective structure
US6282026B1 (en) 1998-02-05 2001-08-28 3M Innovative Properties Company Retroreflectors having two optical surfaces and varying retroreflectivity
US6045230A (en) * 1998-02-05 2000-04-04 3M Innovative Properties Company Modulating retroreflective article
US5985444A (en) 1998-04-03 1999-11-16 3M Innovative Properties Company Amide functional ultraviolet light absorbers for fluoropolymers
US6096428A (en) * 1998-04-09 2000-08-01 3M Innovative Properties Company Multi-layer compositions comprising a fluoropolymer
US6156400A (en) 1998-04-09 2000-12-05 3M Innovative Properties Company Multi-layer compositions comprising a fluoropolymer
EP1089880B1 (en) 1998-04-29 2004-02-11 3M Innovative Properties Company Receptor sheet for inkjet printing having an embossed surface
US6470610B1 (en) * 1998-05-29 2002-10-29 3M Innovative Properties Company Prefabricated retroreflective sign
US6103152A (en) 1998-07-31 2000-08-15 3M Innovative Properties Co. Articles that include a polymer foam and method for preparing same
US6322652B1 (en) 1998-09-04 2001-11-27 3M Innovative Properties Company Method of making a patterned surface articles
US6253477B1 (en) * 1998-09-23 2001-07-03 Hallmark Technologies, Inc. Retro-reflective sign
US6050691A (en) * 1998-10-19 2000-04-18 3M Innovative Properties Company Method of making randomly oriented cube-corner articles
US6287670B1 (en) 1999-01-11 2001-09-11 3M Innovative Properties Company Cube corner cavity based retroreflectors and methods for making same
US6055108A (en) * 1999-02-11 2000-04-25 Minnesota Mining And Manufacturing Company Imaging articles and methods using dual-axis retroreflective elements
US6172810B1 (en) 1999-02-26 2001-01-09 3M Innovative Properties Company Retroreflective articles having polymer multilayer reflective coatings
DE60007850T2 (en) 1999-03-02 2004-11-04 3M Innovative Properties Co., St. Paul COMPOSITIONS FOR JOINING FLUORINE POLYMERS WITH NON-FLUORINE POLYMERS
EP2264490B1 (en) 1999-04-07 2014-02-26 3M Innovative Properties Company Manufacturing method for cube corner retroreflective article
US6540367B1 (en) 1999-04-07 2003-04-01 3M Innovative Properties Company Structured surface articles containing geometric structures with compound faces and methods for making same
US6224792B1 (en) 1999-04-13 2001-05-01 3M Innovative Properties Company Cutting and edge sealing cellular retroreflective sheeting
AU5175500A (en) 1999-06-01 2000-12-18 3M Innovative Properties Company Optically transmissive microembossed receptor media
WO2000073082A1 (en) 1999-06-01 2000-12-07 3M Innovative Properties Company Random microembossed receptor media
US6440334B2 (en) 1999-06-11 2002-08-27 3M Innovative Properties Company Method of making a retroreflective article
US6548164B1 (en) 1999-06-30 2003-04-15 3M Innovative Properties Company Removable sheeting
US7223364B1 (en) 1999-07-07 2007-05-29 3M Innovative Properties Company Detection article having fluid control film
US6677028B1 (en) 1999-09-10 2004-01-13 3M Innovative Properties Company Retroreflective articles having multilayer films and methods of manufacturing same
KR100373209B1 (en) * 1999-09-11 2003-02-25 주식회사 엘지화학 Retroreflective article
CA2384709A1 (en) 1999-10-04 2001-04-12 3M Innovative Properties Company Improved continuous process for making glittering cube corner sheeting
US6454839B1 (en) 1999-10-19 2002-09-24 3M Innovative Properties Company Electrofiltration apparatus
US6656307B2 (en) 1999-11-24 2003-12-02 3M Innovative Properties Company Method of making signs having metalized cube corner sheeting
JP3975039B2 (en) 1999-12-13 2007-09-12 日本カーバイド工業株式会社 Triangular pyramid cube corner retroreflective element
US6958179B2 (en) * 1999-12-30 2005-10-25 3M Innovative Properties Company Segmented sheeting and methods of making and using same
US6517664B1 (en) 2000-01-10 2003-02-11 Process Resources Corporation Techniques for labeling of plastic, glass or metal containers or surfaces with polymeric labels
US6375776B1 (en) 2000-01-24 2002-04-23 Avery Dennison Corporation Method for forming multi-layer laminates with microstructures
AU2706901A (en) * 2000-01-31 2001-08-14 Nippon Carbide Kogyo Kk Triangular pyramidal cube corner retroreflection element
US6533961B2 (en) * 2000-02-22 2003-03-18 3M Innovative Properties Company Durable fluorescent organic pigments and methods of making
US8728610B2 (en) * 2000-02-25 2014-05-20 3M Innovative Properties Company Compound mold and structured surface articles containing geometric structures with compound faces and method of making same
JP3468418B2 (en) * 2000-03-15 2003-11-17 日本カーバイド工業株式会社 Triangular pyramidal cube corner retroreflective sheet
JP4028155B2 (en) 2000-04-11 2007-12-26 日本カーバイド工業株式会社 Fluorescent retroreflective sheet
US6741523B1 (en) 2000-05-15 2004-05-25 3M Innovative Properties Company Microstructured time dependent indicators
US6656319B1 (en) 2000-10-25 2003-12-02 3M Innovative Properties Company Fluid-activatable adhesive articles and methods
US6531212B2 (en) 2001-02-14 2003-03-11 3M Innovative Properties Company Retroreflective article and method
US6592967B2 (en) * 2001-02-14 2003-07-15 Avery Dennison Corporation Microprism reflective sheeting with improved retention of reflectivity
US7141303B2 (en) 2001-03-06 2006-11-28 3M Innovative Properties Company Protective articles
EP1903481B1 (en) * 2001-06-19 2009-10-28 Nippon Carbide Kogyo Kabushiki Kaisha Integrated circuit enclosed retroreflective product
WO2003014779A1 (en) * 2001-08-09 2003-02-20 Nippon Carbide Kogyo Kabushiki Kaisha Retroreflection device
US6589317B2 (en) 2001-08-10 2003-07-08 3M Innovative Properties Company Structured surface filtration media array
US6894615B2 (en) * 2001-10-09 2005-05-17 3M Innovative Properties Company Article with retroreflective and radio frequency-responsive features
EP1459239B1 (en) 2001-12-24 2012-04-04 L-1 Secure Credentialing, Inc. Covert variable information on id documents and methods of making same
AU2002364036A1 (en) 2001-12-24 2003-07-15 Digimarc Id Systems, Llc Laser etched security features for identification documents and methods of making same
US7694887B2 (en) 2001-12-24 2010-04-13 L-1 Secure Credentialing, Inc. Optically variable personalized indicia for identification documents
EP1459246B1 (en) 2001-12-24 2012-05-02 L-1 Secure Credentialing, Inc. Method for full color laser marking of id documents
ATE434781T1 (en) * 2002-04-03 2009-07-15 3M Innovative Properties Co PRODUCTS FOR DISPLAYING TIME OR TIME-TEMPERATURE
AU2003221894A1 (en) 2002-04-09 2003-10-27 Digimarc Id Systems, Llc Image processing techniques for printing identification cards and documents
US7048989B2 (en) * 2002-04-18 2006-05-23 3M Innovative Properties Company Retroreflective article comprising water-borne acrylic topcoats
US7824029B2 (en) 2002-05-10 2010-11-02 L-1 Secure Credentialing, Inc. Identification card printer-assembler for over the counter card issuing
US20030235677A1 (en) * 2002-06-25 2003-12-25 3M Innovative Properties Company Complex microstructure film
US20040029044A1 (en) * 2002-08-08 2004-02-12 3M Innovative Properties Company Photocurable composition
US6818276B2 (en) * 2002-10-24 2004-11-16 Eastman Kodak Company Light management film with colorant receiving layer
US7804982B2 (en) 2002-11-26 2010-09-28 L-1 Secure Credentialing, Inc. Systems and methods for managing and detecting fraud in image databases used with identification documents
US7102522B2 (en) * 2002-12-24 2006-09-05 3M Innovative Properties Company Tamper-indicating radio frequency identification antenna and sticker, a radio frequency identification antenna, and methods of using the same
US20040146677A1 (en) 2003-01-24 2004-07-29 3M Innovative Properties Company Flexible reflective sleeve
EP1443344A1 (en) * 2003-01-29 2004-08-04 Heptagon Oy Manufacturing micro-structured elements
US6816125B2 (en) * 2003-03-01 2004-11-09 3M Innovative Properties Company Forming electromagnetic communication circuit components using densified metal powder
US6884371B2 (en) * 2003-03-06 2005-04-26 3M Innovative Properties Company Method of making retroreflective sheeting and articles
US7152983B2 (en) 2003-03-06 2006-12-26 3M Innovative Properties Company Lamina comprising cube corner elements and retroreflective sheeting
ATE491190T1 (en) 2003-04-16 2010-12-15 L 1 Secure Credentialing Inc THREE-DIMENSIONAL DATA STORAGE
US20070006493A1 (en) * 2003-05-12 2007-01-11 Arnold Eberwein Illuminated license plate for vehicles and vehicle provided with the same
US7678443B2 (en) * 2003-05-16 2010-03-16 3M Innovative Properties Company Complex microstructure film
US6833391B1 (en) * 2003-05-27 2004-12-21 General Electric Company Curable (meth)acrylate compositions
US7271283B2 (en) * 2003-08-29 2007-09-18 General Electric Company High refractive index, UV-curable monomers and coating compositions prepared therefrom
US20070031641A1 (en) * 2003-09-05 2007-02-08 3M Innovative Properties Company License plate for back illumination and method for making same
US7364085B2 (en) * 2003-09-30 2008-04-29 Digimarc Corporation Identification document with printing that creates moving and three dimensional image effects with pulsed illumination
US20050079324A1 (en) 2003-10-13 2005-04-14 Haunschild Dale H. Method of making retroreflective material
US7327466B2 (en) * 2003-11-03 2008-02-05 Zygo Corporation Multi-corner retroreflector
DE112004001974T5 (en) * 2003-11-11 2006-08-24 Tae Ii Kim Advertising film with retroreflective microprism film and method of making the same
US20050151021A1 (en) * 2003-12-17 2005-07-14 Hamilton Douglas C. Heat dissipating, light-reflecting plates for radiator systems of spacecraft and methods for fabricating the same
US20050132626A1 (en) * 2003-12-22 2005-06-23 Ahmadi William Y. Multi-layered sign with enhanced reflecting layer
US20050154098A1 (en) * 2004-01-09 2005-07-14 Reflexite Corporation Fade-resistant fluorescent retroreflective articles
CA2553801A1 (en) 2004-01-21 2005-08-11 3M Innovative Properties Company Retroreflective elements and articles
US7329447B2 (en) * 2004-04-01 2008-02-12 3M Innovative Properties Company Retroreflective sheeting with controlled cap-Y
PL1584518T3 (en) * 2004-04-07 2008-03-31 3M Innovative Properties Co License plate assembly comprising light source and backlit license plate
US7252396B2 (en) * 2004-11-16 2007-08-07 3M Innovative Properties Company Retroreflective article having at least one valve and method of making same
CN100526917C (en) * 2004-12-28 2009-08-12 3M创新有限公司 Prismatic retroreflective article with fluorine- or silicon-containing prisms
US7195360B2 (en) * 2004-12-28 2007-03-27 3M Innovative Properties Company Prismatic retroreflective article and method
BRPI0500848A (en) * 2005-01-10 2006-09-05 Avery Dennison Do Brasil Ltda film, substrate and film use
US8353995B2 (en) * 2005-07-15 2013-01-15 3M Innovative Properties Company Automobile panel repair laminate
BRPI0616423B8 (en) * 2005-09-26 2018-09-04 Avery Dennison Corp retro-reflective laminated material
GB2433637A (en) * 2005-12-21 2007-06-27 3M Innovative Properties Co Semi-transparent retroreflective material
GB0602105D0 (en) * 2006-02-02 2006-03-15 3M Innovative Properties Co License plate assembly
US20070218258A1 (en) * 2006-03-20 2007-09-20 3M Innovative Properties Company Articles and methods including patterned substrates formed from densified, adhered metal powders
US7611251B2 (en) 2006-04-18 2009-11-03 3M Innovative Properties Company Retroreflective articles comprising olefinic seal films
MX2008013229A (en) * 2006-04-18 2008-10-21 3M Innovative Properties Co Microstructured articles comprising nitrogen containing ingredient.
GB2438203A (en) * 2006-05-18 2007-11-21 Ind Rubber Plc Depressible insert for a road stud
WO2008006245A1 (en) * 2006-07-06 2008-01-17 Hungchen Lee Retroreflecting belt structure
RU2443003C2 (en) * 2006-07-17 2012-02-20 Эйвери Деннисон Корпорейшн Method of manufacturing a distorted optical components array
US7842374B2 (en) * 2006-07-28 2010-11-30 3M Innovative Properties Company Retroreflective article comprising a copolyester ether composition layer and method of making same
US20080032096A1 (en) * 2006-08-07 2008-02-07 Eastman Kodak Company Microstructured film containing polysulfone polymer
US7674515B2 (en) * 2006-10-23 2010-03-09 Avery Dennison Corporation Fluorescent polycarbonate articles
US20080145545A1 (en) * 2006-12-15 2008-06-19 Bret Ja Chisholm Metal oxide and sulfur-containing coating compositions, methods of use, and articles prepared therefrom
US20080143519A1 (en) * 2006-12-19 2008-06-19 3M Innovative Properties Company Tamper-indicating radio frequency identification tag and methods of indicating tampering of a radio frequency identification tag
DE102007052325A1 (en) * 2007-03-29 2009-05-07 Erk Eckrohrkessel Gmbh Method for the sliding temperature control of chemical substances with defined inlet and outlet temperatures in a heater and device for carrying out the method
WO2009002225A2 (en) * 2007-06-25 2008-12-31 Closed Company 'molecular-Medicine Technologies' Multifunctional diagnosis device and a method for testing biological objects
US7547105B2 (en) * 2007-07-16 2009-06-16 3M Innovative Properties Company Prismatic retroreflective article with cross-linked image layer and method of making same
US20090027775A1 (en) * 2007-07-26 2009-01-29 Nilsen Robert B Multiple layer reflective tag
CN101971064B (en) * 2008-01-14 2015-07-29 艾利丹尼森公司 For the retrodirective reflector of touch-screen applications and position sensing
EP2103972B1 (en) 2008-03-20 2014-04-23 3M Innovative Properties Company Light device comprising light guide
US20090286049A1 (en) * 2008-05-15 2009-11-19 3M Innovative Properties Company Methods of applying uv-curable inks to retroreflective sheeting
EP2307914A4 (en) 2008-07-10 2014-03-19 3M Innovative Properties Co Retroreflective articles and devices having viscoelastic lightguide
TW201007647A (en) 2008-07-10 2010-02-16 3M Innovative Properties Co Retroreflective articles and devices having viscoelastic lightguide
EP2313800A4 (en) 2008-07-10 2014-03-19 3M Innovative Properties Co Viscoelastic lightguide
CN102171593A (en) 2008-08-08 2011-08-31 3M创新有限公司 Lightguide having a viscoelastic layer for managing light
EP2350710B1 (en) * 2008-10-22 2020-09-16 3M Innovative Properties Company Retroreflective sheeting
EP2368147A4 (en) * 2008-12-08 2018-01-24 3M Innovative Properties Company Protective overlay bearing a graphic and retroreflective articles comprising the overlay
EP2361396A4 (en) 2008-12-08 2018-01-24 3M Innovative Properties Company Prismatic retroreflective article bearing a graphic and method of making same
US8865293B2 (en) 2008-12-15 2014-10-21 3M Innovative Properties Company Optically active materials and articles and systems in which they may be used
BRPI1006654A2 (en) 2009-04-15 2016-02-10 3M Innovative Properties Co retroreflective optical constructions and optical films
US9291752B2 (en) 2013-08-19 2016-03-22 3M Innovative Properties Company Retroreflecting optical construction
TWI605276B (en) 2009-04-15 2017-11-11 3M新設資產公司 Optical construction and display system incorporating same
EP2419475B1 (en) 2009-04-15 2017-01-25 3M Innovative Properties Company Process and apparatus for manufacturing a nanovoided article
US9464179B2 (en) 2009-04-15 2016-10-11 3M Innovative Properties Company Process and apparatus for a nanovoided article
KR101758933B1 (en) 2009-04-15 2017-07-17 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Optical film
CN102460244B (en) 2009-04-15 2014-11-19 3M创新有限公司 Lightguide with optical film containing voids and blacklight for display system
WO2010120871A1 (en) 2009-04-15 2010-10-21 3M Innovative Properties Company Optical film for preventing optical coupling
US9200775B2 (en) 2009-04-24 2015-12-01 3M Innovative Properties Company Light assembly
EP2292972B1 (en) 2009-09-02 2013-03-27 3M Innovative Properties Company Light device and vehicle including light device
JP5671047B2 (en) 2009-10-16 2015-02-18 スリーエム イノベイティブ プロパティズ カンパニー A prismatic retroreflective sheet with reduced infrared retroreflectivity
EP2491445B1 (en) 2009-10-24 2018-01-03 3M Innovative Properties Company Light source and display system incorporating same
JP5869494B2 (en) 2009-12-08 2016-02-24 スリーエム イノベイティブ プロパティズ カンパニー Optical structure incorporating light guide and low refractive index film
PL2510424T3 (en) 2009-12-11 2017-06-30 Avery Dennison Corporation Position sensing systems for use in touch screens and prismatic film used therein
EP2517053A1 (en) 2009-12-21 2012-10-31 3M Innovative Properties Company Transflective articles and light assemblies
EP2343198A1 (en) 2010-01-12 2011-07-13 3M Innovative Properties Company Security laminate, method of making a security laminate, and article comprising a security laminate
JP2011180449A (en) * 2010-03-02 2011-09-15 Sony Corp Optical body and method for manufacturing the same, window material, and method for sticking optical body
JP5586300B2 (en) * 2010-03-31 2014-09-10 デクセリアルズ株式会社 Functional laminate and functional structure
KR101954456B1 (en) 2010-04-15 2019-03-05 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Retroreflective articles including optically active areas and optically inactive areas
WO2011129831A1 (en) 2010-04-15 2011-10-20 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
EP3495134B1 (en) 2010-04-15 2020-11-25 3M Innovative Properties Co. Retroreflective articles including optically active areas and optically inactive areas
KR101825763B1 (en) 2010-06-01 2018-02-05 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Multi-layer sealing films
JP6010108B2 (en) * 2011-04-01 2016-10-19 スリーエム イノベイティブ プロパティズ カンパニー Film containing triazine UV absorber
KR20140035454A (en) 2011-05-31 2014-03-21 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Method for making microstructured tools having discontinuous topographies, articles produced therefrom
WO2012166448A1 (en) 2011-05-31 2012-12-06 3M Innovative Properties Company Retroreflective articles having composite cube-corners and methods of making
JP5973561B2 (en) 2011-05-31 2016-08-23 スリーエム イノベイティブ プロパティズ カンパニー Method for making microstructured articles that are pattern-cured differently
EP2758813B1 (en) * 2011-09-23 2018-06-06 3M Innovative Properties Company Retroreflective articles including a security mark
JP6017933B2 (en) * 2011-12-22 2016-11-02 信越化学工業株式会社 Composite and production method thereof
JP6576240B2 (en) 2012-03-30 2019-09-18 スリーエム イノベイティブ プロパティズ カンパニー Retroreflective article having machine-readable code
US9529125B2 (en) 2013-01-28 2016-12-27 Aura Optical Systems, Lp Metalized microprismatic retroreflective sheeting with improved observation angularity
US9746591B2 (en) 2013-03-12 2017-08-29 Aura Optical Systems, Lp Multi-layer microprismatic retroreflective sheeting and method of manufacturing the same
KR102030616B1 (en) * 2013-04-22 2019-10-11 미래나노텍 주식회사 Retro-reflection optical sheet
EP3036570A4 (en) 2013-08-19 2017-04-19 3M Innovative Properties Company Retroreflective sheeting including a low elastic modulus layer
WO2015026610A2 (en) 2013-08-19 2015-02-26 3M Innovative Properties Company Retroreflective sheeting including a substantially amorphous polymeric layer
TW201541371A (en) 2014-03-25 2015-11-01 3M Innovative Properties Co Articles capable of use in ALPR systems
WO2016025207A1 (en) 2014-08-13 2016-02-18 3M Innovative Properties Company Optically active articles and systems in which they may be used
JP2016118584A (en) 2014-12-18 2016-06-30 スリーエム イノベイティブ プロパティズ カンパニー Retroreflective sheet, license plate, and manufacturing method therefor
KR102506561B1 (en) * 2014-12-30 2023-03-06 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Vehicle Sign Identification System
US10925268B1 (en) * 2015-03-13 2021-02-23 Ray D. Flasco Inside corner cubic surface reflector fishing lure
WO2017004247A1 (en) 2015-06-30 2017-01-05 3M Innovative Properties Company A barrier element on a microstructured article
US10884163B2 (en) 2015-07-07 2021-01-05 3M Innovative Properties Company Polyurethane layer for a light directing article
CN104991299A (en) * 2015-07-09 2015-10-21 西南科技大学 Method for calculating reflected light intensity of cubic pyramid type retroflection material
US20190008859A1 (en) 2015-08-21 2019-01-10 Acerta Pharma B.V. Therapeutic Combinations of a MEK Inhibitor and a BTK Inhibitor
EP3182327A1 (en) 2015-12-17 2017-06-21 3M Innovative Properties Company A sign identification system for a vehicle
WO2017173017A1 (en) 2016-04-01 2017-10-05 3M Innovative Properties Company Counterfeit detection of traffic materials using images captured under multiple, different lighting conditions
CN109313292B (en) 2016-06-07 2021-07-16 3M创新有限公司 Acrylic polyvinyl acetal films for photo-oriented articles
CN108569000A (en) * 2017-03-11 2018-09-25 昇印光电(昆山)股份有限公司 Decorating film
CN110603146A (en) 2017-05-10 2019-12-20 3M创新有限公司 Fluoropolymer articles and related methods
US20200096683A1 (en) 2017-05-25 2020-03-26 3M Innovative Properties Company Cube corner retroreflective articleswith tailored retroreflectivity and methods of making
WO2020021458A1 (en) 2018-07-24 2020-01-30 3M Innovative Properties Company A patterned wavelength-selective image
US11001979B2 (en) 2018-08-13 2021-05-11 Vergence Automation, Inc. Methods and apparatus for ultrawide entrance angle reflective articles for use with autonomous vehicle machine vision systems
US11762133B1 (en) 2018-09-13 2023-09-19 Vergence Automation, Inc. Retroreflective materials and articles incorporating near-ideal total internal retroreflective elements
EP3977336A1 (en) * 2019-05-24 2022-04-06 3M Innovative Properties Company Radar-optical fusion article and system
JP2022538175A (en) 2019-06-28 2022-08-31 スリーエム イノベイティブ プロパティズ カンパニー Structured surface and optical ferrule containing same
US11675086B1 (en) 2019-08-20 2023-06-13 Scan Systems, Corp. Time-of-flight-based apparatus, systems, and methods for measuring tubular goods
EP4168230A4 (en) 2020-08-27 2023-12-27 Aura Optical Systems, LP Microprismatic retroreflective mold, sheet, and article and methods of manufacture thereof
WO2023223114A1 (en) 2022-05-19 2023-11-23 3M Innovative Properties Company Light shielding articles and electromagnetic receivers and/or emitters including the same

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3190178A (en) 1961-06-29 1965-06-22 Minnesota Mining & Mfg Reflex-reflecting sheeting
US3450459A (en) 1965-10-24 1969-06-17 Walter F Haggerty Retroreflective device
US3924929A (en) * 1966-11-14 1975-12-09 Minnesota Mining & Mfg Retro-reflective sheet material
US3632695A (en) 1970-03-05 1972-01-04 Reflex Corp Canada Ltd Making a combined lens and reflector
US3810804A (en) * 1970-09-29 1974-05-14 Rowland Dev Corp Method of making retroreflective material
US3689346A (en) * 1970-09-29 1972-09-05 Rowland Dev Corp Method for producing retroreflective material
US3684348A (en) * 1970-09-29 1972-08-15 Rowland Dev Corp Retroreflective material
US3700305A (en) 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
US3712706A (en) 1971-01-04 1973-01-23 American Cyanamid Co Retroreflective surface
US3811983A (en) * 1972-06-23 1974-05-21 Rowland Dev Corp Method for producing retroreflective sheeting
US3935359A (en) * 1972-06-23 1976-01-27 Rowland Development Corporation Retroreflective sheeting and method and apparatus for producing same
US3830682A (en) 1972-11-06 1974-08-20 Rowland Dev Corp Retroreflecting signs and the like with novel day-night coloration
DE2317871A1 (en) * 1973-04-10 1974-10-24 Nier Marianne REFLECTIVE OPTICAL GUIDANCE AND WARNING DEVICES
US3926402A (en) 1973-04-24 1975-12-16 Amerace Corp Pin having nonaligned cube axis and pin axis and bundle of such pins
US3992080A (en) * 1975-06-13 1976-11-16 Reflexite Corporation Retroreflective sheet material with controlled stretch and method of making same
US4025159A (en) 1976-02-17 1977-05-24 Minnesota Mining And Manufacturing Company Cellular retroreflective sheeting
US4066098A (en) * 1976-10-08 1978-01-03 Exxon Research & Engineering Co. Marine loading and bunkering arrangement
US4349598A (en) 1976-12-01 1982-09-14 Minnesota Mining And Manufacturing Company High incidence angle retroreflective material
US4202600A (en) 1978-04-24 1980-05-13 Avery International Corporation Diced retroreflective sheeting
US4582885A (en) 1978-07-20 1986-04-15 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4668558A (en) 1978-07-20 1987-05-26 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4243618A (en) 1978-10-23 1981-01-06 Avery International Corporation Method for forming retroreflective sheeting
US4332847A (en) * 1979-09-20 1982-06-01 Relfexite Corporation Method for compression molding of retroreflective sheeting and sheeting produced thereby
US4414316A (en) 1980-09-05 1983-11-08 Rexham Corporation Composite lenticular screen sheet
US4478769A (en) * 1982-09-30 1984-10-23 Amerace Corporation Method for forming an embossing tool with an optically precise pattern
US4601861A (en) * 1982-09-30 1986-07-22 Amerace Corporation Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate
US4486363A (en) 1982-09-30 1984-12-04 Amerace Corporation Method and apparatus for embossing a precision optical pattern in a resinous sheet
US4588258A (en) 1983-09-12 1986-05-13 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles having wide angularity in multiple viewing planes
US4555161A (en) * 1984-02-16 1985-11-26 Reflexite Corporation Encapsulated retroreflective material and method of making same
MX169129B (en) 1984-08-10 1993-06-22 Amerace Corp METHOD FOR PRODUCING CONSTRUCTIONS OF RETRO-REFLECTIVE LAMINATED STRUCTURE SHEET OF THE TYPE OF CUBE CORNERS AND THE PRODUCT OBTAINED WITH THE SAME.
US4637950A (en) * 1985-05-01 1987-01-20 Minnesota Mining And Manufacturing Company Delamination-resistant cellular retroreflective sheeting
CN85106175A (en) * 1985-08-16 1987-03-04 阿麦克公司 Multiple cube corner plate and manufacture method thereof
US4938563A (en) 1986-11-21 1990-07-03 Minnesota Mining And Manufacturing Company High efficiency cube corner retroflective material
US4775219A (en) 1986-11-21 1988-10-04 Minnesota Mining & Manufacturing Company Cube-corner retroreflective articles having tailored divergence profiles
US5066098A (en) 1987-05-15 1991-11-19 Minnesota Mining And Manufacturing Company Cellular encapsulated-lens high whiteness retroreflective sheeting with flexible cover sheet
US4801193A (en) 1988-03-04 1989-01-31 Reflexite Corporation Retroreflective sheet material and method of making same
US4895428A (en) 1988-07-26 1990-01-23 Minnesota Mining And Manufacturing Company High efficiency retroreflective material
US5026447A (en) 1989-02-10 1991-06-25 Phillips Petroleum Company Method for making variable cross section pultruded thermoplastic composite articles
US5175030A (en) * 1989-02-10 1992-12-29 Minnesota Mining And Manufacturing Company Microstructure-bearing composite plastic articles and method of making
US5183597A (en) 1989-02-10 1993-02-02 Minnesota Mining And Manufacturing Company Method of molding microstructure bearing composite plastic articles
US5077117A (en) 1990-04-05 1991-12-31 Minnesota Mining And Manufacturing Company Pavement marking material with rupturing top layer
US5229882A (en) 1990-05-16 1993-07-20 Reflexite Corporation Colored retroreflective sheeting and method of making same
US5264063A (en) * 1990-05-16 1993-11-23 Reflexite Corporation Method for making flexible retroreflective sheet material
US5138488A (en) * 1990-09-10 1992-08-11 Minnesota Mining And Manufacturing Company Retroreflective material with improved angularity
US5117304A (en) 1990-09-21 1992-05-26 Minnesota Mining And Manufacturing Company Retroreflective article
US5236751A (en) * 1991-03-28 1993-08-17 Reflexite Corporation Cone collars with temporary release coating and method for making and assembling same
US5213872A (en) 1991-04-19 1993-05-25 Stimsonite Corporation Preprinted retroreflective highway sign and method for making the sign
WO1994026313A1 (en) 1993-05-06 1994-11-24 The Dow Chemical Company Bicyclopolyazamacrocyclocarboxylic acid complexes, their conjugates, processes for their preparation, and use as contrast agents
US5189553A (en) * 1992-06-08 1993-02-23 Minnesota Mining And Manufacturing Company Optimized construction of retroreflective articles for curved applications
US5272562A (en) 1993-02-05 1993-12-21 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles
US5637173A (en) * 1993-02-17 1997-06-10 Reflexite Corporation Method for forming a retroreflective structure having free-standing prisms
US5376431A (en) 1993-05-12 1994-12-27 Reflexite Corporation Retroreflective microprism sheeting with silver/copper reflecting coating and method of making same
WO1995003558A1 (en) 1993-07-19 1995-02-02 Reflexite Corporation Retroreflective structure
US5648145A (en) * 1993-09-10 1997-07-15 Reflexite Corporation Fire-resistant, retroreflective structure
US5450235A (en) * 1993-10-20 1995-09-12 Minnesota Mining And Manufacturing Company Flexible cube-corner retroreflective sheeting
US5614286A (en) 1993-10-20 1997-03-25 Minnesota Mining And Manufacturing Company Conformable cube corner retroreflective sheeting
US5600484A (en) 1993-10-20 1997-02-04 Minnesota Mining And Manufacturing Company Machining techniques for retroreflective cube corner article and method of manufacture
EP0724737B1 (en) * 1993-10-20 1998-07-22 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture
US5691846A (en) 1993-10-20 1997-11-25 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture
US5585164A (en) 1993-10-20 1996-12-17 Minnesota Mining And Manufacturing Company Dual groove set retroreflective cube corner article and method of manufacture

Also Published As

Publication number Publication date
DE69422823D1 (en) 2000-03-02
US7185993B2 (en) 2007-03-06
AU676619B2 (en) 1997-03-13
DE69422823T2 (en) 2000-06-15
JPH09504622A (en) 1997-05-06
WO1995011466A1 (en) 1995-04-27
EP0724731A1 (en) 1996-08-07
AU7983494A (en) 1995-05-08
DK0724731T3 (en) 2000-04-17
CN1040694C (en) 1998-11-11
US20070014011A1 (en) 2007-01-18
ES2141264T3 (en) 2000-03-16
US7568807B2 (en) 2009-08-04
EP0724731B1 (en) 2000-01-26
US5988820A (en) 1999-11-23
US6350035B1 (en) 2002-02-26
ATE189316T1 (en) 2000-02-15
US20020126382A1 (en) 2002-09-12
JP3623506B2 (en) 2005-02-23
US5450235A (en) 1995-09-12
CA2172636C (en) 2006-01-24
CN1133635A (en) 1996-10-16

Similar Documents

Publication Publication Date Title
CA2172636A1 (en) Flexible cube-corner retroreflective sheeting
AU5504794A (en) Flexible cycloolefin copolymer film
AU5505194A (en) Semi-crystalline cycloolefin copolymer film
AU5504994A (en) Rigid cycloolefin copolymer film
USD375317S (en) Goggle lens
USD399978S (en) Paving element
AU5465396A (en) Biaxially oriented polypropylene film having a high surface modulus
AU7414094A (en) Isoprene-butadiene rubber
AU3195895A (en) Flexible ballistic resistant article having a thermoplastic elastomeric honeycomb panel
CA2250526A1 (en) Ultra-flexible retroreflective sheeting with coated back surface
AU6682396A (en) Retroreflective sheeting with coated back surface
AU1032595A (en) Retroreflective materials
AU5557996A (en) Encapsulated lens retroreflective sheeting having thermoplastic polyur ethane bonding layer
BR8605668A (en) RETRO-REFLECTIVE LAMINATED MATERIAL AND PROCESS OF MANUFACTURING A TRANSPARENT COATING FILM
AU6701094A (en) Antistatic fibers
AU6864596A (en) Retroreflective prism arrays with formed spheres therein
AU9427698A (en) Four component copolymer and the ocular lens made thereof
USD356354S (en) Throw toy
AU6540496A (en) Optically clear antistatic pressure-sensitive adhesive film
USD394094S (en) Tennis racquet
USD363067S (en) Console
USD386819S (en) Flexible finger-mounted razor
USD355663S (en) Optical viewer
USD375320S (en) Goggle body
USD364515S (en) Display case

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20141020