CA2176767A1 - Ethylene Polymers Having Enhanced Processability - Google Patents
Ethylene Polymers Having Enhanced ProcessabilityInfo
- Publication number
- CA2176767A1 CA2176767A1 CA2176767A CA2176767A CA2176767A1 CA 2176767 A1 CA2176767 A1 CA 2176767A1 CA 2176767 A CA2176767 A CA 2176767A CA 2176767 A CA2176767 A CA 2176767A CA 2176767 A1 CA2176767 A1 CA 2176767A1
- Authority
- CA
- Canada
- Prior art keywords
- index
- ethylene polymers
- rsi
- high pressure
- ethylene polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Abstract
An ethylene polymer having a Polydispersity Index of at least about 3.0, a melt index, MI, and a Relaxation Spectrum Index, RSI, such that (RSI)(MI) is greater than about 26 when is about 0.7, and a Crystallizable Chain Length Distribution Index, LW/Ln, less than about 3 is provided. Such ethylene polymer has processability equivalent or superior to even conventional high pressure polyethylene at similar melt index, yet need not be made under high pressure reaction conditions.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44245395A | 1995-05-16 | 1995-05-16 | |
US08/442,453 | 1995-05-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2176767A1 true CA2176767A1 (en) | 1996-11-17 |
CA2176767C CA2176767C (en) | 2001-01-02 |
Family
ID=23756840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002176767A Expired - Fee Related CA2176767C (en) | 1995-05-16 | 1996-05-16 | Ethylene polymers having enhanced processability |
Country Status (26)
Country | Link |
---|---|
US (1) | US5798427A (en) |
EP (1) | EP0743327B1 (en) |
JP (1) | JP3073929B2 (en) |
KR (1) | KR100267629B1 (en) |
CN (1) | CN1141306A (en) |
AR (1) | AR001953A1 (en) |
AT (1) | ATE200497T1 (en) |
AU (1) | AU713324B2 (en) |
BR (1) | BR9602284A (en) |
CA (1) | CA2176767C (en) |
CZ (1) | CZ291412B6 (en) |
DE (1) | DE69612424T2 (en) |
ES (1) | ES2158246T3 (en) |
GR (1) | GR3035742T3 (en) |
HU (1) | HUP9601322A3 (en) |
ID (1) | ID16439A (en) |
MX (1) | MX9601812A (en) |
MY (1) | MY115806A (en) |
PL (1) | PL187966B1 (en) |
PT (1) | PT743327E (en) |
RU (1) | RU2162858C2 (en) |
SK (1) | SK63796A3 (en) |
TR (1) | TR199600395A1 (en) |
TW (1) | TW426690B (en) |
UA (1) | UA47394C2 (en) |
ZA (1) | ZA963917B (en) |
Families Citing this family (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6025448A (en) | 1989-08-31 | 2000-02-15 | The Dow Chemical Company | Gas phase polymerization of olefins |
US6538080B1 (en) | 1990-07-03 | 2003-03-25 | Bp Chemicals Limited | Gas phase polymerization of olefins |
US5525695A (en) * | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
IT1270253B (en) | 1994-06-20 | 1997-04-29 | Spherilene Srl | ETHYLENE COPOLYMERS AND PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS |
SE504455C2 (en) * | 1995-07-10 | 1997-02-17 | Borealis Polymers Oy | Cable sheath composition, its use and methods for its manufacture |
US6165387A (en) * | 1997-02-04 | 2000-12-26 | Borealis A/S | Composition for electric cables |
SE9703798D0 (en) | 1997-10-20 | 1997-10-20 | Borealis As | Electric cable and a method of composition for the production thereof |
SE513362C2 (en) | 1997-11-18 | 2000-09-04 | Borealis As | Procedure for reducing reactor fouling |
US5998558A (en) * | 1997-12-29 | 1999-12-07 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene polymers having enhanced processing ease |
GB9800245D0 (en) * | 1998-01-07 | 1998-03-04 | Bp Chem Int Ltd | Novel polymers |
AU2738599A (en) * | 1998-03-12 | 1999-09-27 | Bp Chemicals Limited | Polymerisation catalysts |
US6207606B1 (en) * | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
SE9802087D0 (en) | 1998-06-12 | 1998-06-12 | Borealis Polymers Oy | An insulating composition for communication cables |
TW460485B (en) | 1998-06-19 | 2001-10-21 | Japan Polyolefins Co Ltd | Ethylene.Α-olefin copolymer, and combinations, films and use thereof |
SE9802386D0 (en) | 1998-07-03 | 1998-07-03 | Borealis As | Composition for electric cables |
ES2280674T3 (en) * | 1998-11-25 | 2007-09-16 | Basell Polyolefine Gmbh | METALOCENE MONOHALOGENURES. |
SE9804407D0 (en) | 1998-12-18 | 1998-12-18 | Borealis Polymers Oy | A multimodal polymer composition |
US6818585B2 (en) | 1998-12-30 | 2004-11-16 | Univation Technologies, Llc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
US6281316B1 (en) * | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
US6339134B1 (en) | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
US6271325B1 (en) | 1999-05-17 | 2001-08-07 | Univation Technologies, Llc | Method of polymerization |
AU777107B2 (en) * | 1999-09-29 | 2004-09-30 | E.I. Du Pont De Nemours And Company | Improved processing polyethylenes |
US6624107B2 (en) | 1999-10-22 | 2003-09-23 | Univation Technologies, Llc | Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof |
US6300439B1 (en) | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6417304B1 (en) | 1999-11-18 | 2002-07-09 | Univation Technologies, Llc | Method of polymerization and polymer produced therefrom |
US6265505B1 (en) | 1999-11-18 | 2001-07-24 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
US6271323B1 (en) | 1999-10-28 | 2001-08-07 | Univation Technologies, Llc | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6380328B1 (en) | 1999-12-10 | 2002-04-30 | Univation Technologies, Llc | Catalyst systems and their use in a polymerization process |
US6281306B1 (en) * | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
US20080281063A9 (en) * | 1999-12-30 | 2008-11-13 | Sukhadia Ashish M | Ethylene polymers and copolymers with high optical opacity and methods of making the same |
EP1138702A1 (en) * | 2000-03-30 | 2001-10-04 | Fina Research S.A. | Metallocene-produced polyethylene for glossy plastic containers |
US6455638B2 (en) | 2000-05-11 | 2002-09-24 | Dupont Dow Elastomers L.L.C. | Ethylene/α-olefin polymer blends comprising components with differing ethylene contents |
US6403717B1 (en) * | 2000-07-12 | 2002-06-11 | Univation Technologies, Llc | Ethylene inter-polymer blends |
EP1428841A1 (en) * | 2002-12-12 | 2004-06-16 | ATOFINA Research | Rotomoulded articles with dimensional stability |
EP1540669B1 (en) * | 2002-09-10 | 2007-12-05 | Union Carbide Chemicals & Plastics Technology Corporation | Polypropylene cable jacket compositions with enhanced melt strength and physical properties |
US7208559B2 (en) | 2002-12-27 | 2007-04-24 | Mitsui Chemicals, Inc. | Ethylened polymer and molded object obtained therefrom |
JP4903357B2 (en) * | 2003-03-28 | 2012-03-28 | 住友化学株式会社 | Ethylene polymer |
US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US20050182210A1 (en) | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
US7094857B2 (en) * | 2004-03-10 | 2006-08-22 | Chevron Phillips Chemical Company, L.P. | Ethylene polymers and copolymers with high optical opacity |
DE602004014718D1 (en) * | 2004-03-12 | 2008-08-14 | Borealis Tech Oy | Crosslinked pressure tube made of polyethylene and process for its preparation |
DE102004020524A1 (en) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylene for film, e.g. stretch film, used in carrier bags, contains ethylene homopolymers and/or copolymers of ethylene with 1-alkenes |
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CN102786619B (en) * | 2006-05-17 | 2015-01-07 | 陶氏环球技术有限责任公司 | Ethylene/ alpha-olefin/ diene solution polymerization process |
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KR20080101791A (en) | 2007-05-16 | 2008-11-21 | 주식회사 엘지화학 | Long chain-branched ethylene-alpha olefin copolymer |
TW200932762A (en) * | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
TW200932770A (en) * | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Metallocene catalysts and their use in polymerization processes |
EP2112175A1 (en) | 2008-04-16 | 2009-10-28 | ExxonMobil Chemical Patents Inc. | Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane |
WO2011087520A1 (en) | 2009-12-22 | 2011-07-21 | Univation Technologies, Llc | Catalyst systems having a tailored hydrogen response |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
US8110262B2 (en) * | 2008-11-10 | 2012-02-07 | Chevron Phillips Chemical Company Lp | Polymer compositions containing a polymer processing aid and a hindered amine light stabilizer |
US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
EP2430053A1 (en) | 2009-05-14 | 2012-03-21 | Univation Technologies, LLC | Mixed metal catalyst systems having a tailored hydrogen response |
WO2010137740A1 (en) * | 2009-05-29 | 2010-12-02 | 住友化学株式会社 | Ethylene/α-olefin copolymer and moldings |
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BR112012017676B1 (en) | 2010-01-19 | 2020-01-14 | Dow Global Technologies Llc | method for improving the bubble stability of a polyethylene composition suitable for expanded film extrusion process |
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KR101309389B1 (en) | 2011-06-28 | 2013-09-17 | 삼성토탈 주식회사 | Polyethylene resin composition for Heat shrinkage film and Heat shrinkage film |
CN104024326B (en) | 2011-12-28 | 2016-11-23 | 三井化学株式会社 | Ethylene polymer composition and formed body therefrom |
US9284415B2 (en) | 2012-03-15 | 2016-03-15 | Exxonmobil Chemical Patents Inc. | Oxygen tailoring of polyethylene |
JP6096535B2 (en) * | 2013-02-28 | 2017-03-15 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | Transparent and tough rubber composition and method for producing the same |
KR101791810B1 (en) | 2014-03-21 | 2017-10-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Process to produce ethylene propylene copolymers |
WO2017048392A1 (en) | 2015-09-17 | 2017-03-23 | Exxonmobil Chemical Patents Inc. | Polyethylene polymers and articles made therefrom |
KR102427756B1 (en) * | 2018-12-10 | 2022-08-01 | 주식회사 엘지화학 | Polyethylene and its chlorinated polyethylene |
KR102427755B1 (en) | 2018-12-10 | 2022-08-01 | 주식회사 엘지화학 | Polyethylene and its chlorinated polyethylene |
US20210395411A1 (en) * | 2018-12-21 | 2021-12-23 | Lg Chem, Ltd. | Polyolefin |
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EP4317215A1 (en) | 2021-03-31 | 2024-02-07 | Mitsui Chemicals, Inc. | Ethylene resin composition and molded body |
WO2022210844A1 (en) | 2021-03-31 | 2022-10-06 | 三井化学株式会社 | ETHYLENE-α-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, AND FILM |
EP4316833A1 (en) | 2021-03-31 | 2024-02-07 | Mitsui Chemicals, Inc. | ETHYLENE-a-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, FILM, AND LAMINATE |
Family Cites Families (21)
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---|---|---|---|---|
US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
DE3836059A1 (en) * | 1988-10-22 | 1990-05-03 | Hoechst Ag | METHOD FOR PRODUCING AN ETHYLENE PROPYLENE COPOLYMER |
DE3916555A1 (en) * | 1989-05-20 | 1990-11-22 | Hoechst Ag | PROCESS FOR THE PRODUCTION OF ETHYLENE POLYMERS |
MY107639A (en) * | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
DE4015254A1 (en) * | 1990-05-12 | 1991-11-14 | Hoechst Ag | METHOD FOR PRODUCING A POLYOLEFIN |
US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
DE59209897D1 (en) * | 1991-05-27 | 2001-04-26 | Targor Gmbh | Process for the production of polyolefins with a broad molar mass distribution |
TW300901B (en) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
DE59210001D1 (en) * | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Process for the preparation of an olefin polymer using metallocenes with specifically substituted indenyl ligands |
US5395471A (en) * | 1991-10-15 | 1995-03-07 | The Dow Chemical Company | High drawdown extrusion process with greater resistance to draw resonance |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5459217A (en) * | 1993-04-09 | 1995-10-17 | Mitsui Petrochemical Industries, Ltd. | Ethylene/alpha-olefin copolymer |
WO1993025591A1 (en) * | 1992-06-18 | 1993-12-23 | Spherilene S.R.L. | Process for preparing an ethylenic polymer |
ES2128371T3 (en) * | 1992-08-15 | 1999-05-16 | Targor Gmbh | PROCEDURE FOR OBTAINING POLYOLEFINS. |
WO1994007930A1 (en) * | 1992-09-29 | 1994-04-14 | Exxon Chemical Patents Inc. | Long chain branched polymers and a process to make long chain branched polymers |
US5420220A (en) * | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
DE69430910T2 (en) * | 1993-02-22 | 2002-12-12 | Idemitsu Kosan Co | ETHYLENE COPOLYMER, THERMOPLASTIC RESIN COMPOSITION CONTAINING IT AND METHOD FOR THE PRODUCTION THEREOF |
WO1994028034A1 (en) * | 1993-05-25 | 1994-12-08 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
AU697056B2 (en) * | 1993-12-21 | 1998-09-24 | Univation Technologies Llc | Production of polyolefins containing long chain branches by a gas phase process |
IT1270253B (en) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | ETHYLENE COPOLYMERS AND PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS |
-
1996
- 1996-05-07 UA UA96051806A patent/UA47394C2/en unknown
- 1996-05-13 KR KR1019960015713A patent/KR100267629B1/en not_active IP Right Cessation
- 1996-05-14 TR TR96/00395A patent/TR199600395A1/en unknown
- 1996-05-15 JP JP08143480A patent/JP3073929B2/en not_active Expired - Lifetime
- 1996-05-15 ID IDP961293A patent/ID16439A/en unknown
- 1996-05-15 PL PL31426096A patent/PL187966B1/en not_active IP Right Cessation
- 1996-05-15 MX MX9601812A patent/MX9601812A/en unknown
- 1996-05-15 RU RU96109205/04A patent/RU2162858C2/en active
- 1996-05-16 DE DE69612424T patent/DE69612424T2/en not_active Expired - Lifetime
- 1996-05-16 AT AT96303474T patent/ATE200497T1/en not_active IP Right Cessation
- 1996-05-16 CN CN96110711A patent/CN1141306A/en active Pending
- 1996-05-16 ES ES96303474T patent/ES2158246T3/en not_active Expired - Lifetime
- 1996-05-16 MY MYPI96001861A patent/MY115806A/en unknown
- 1996-05-16 CA CA002176767A patent/CA2176767C/en not_active Expired - Fee Related
- 1996-05-16 HU HU9601322A patent/HUP9601322A3/en unknown
- 1996-05-16 TW TW085105800A patent/TW426690B/en not_active IP Right Cessation
- 1996-05-16 CZ CZ19961424A patent/CZ291412B6/en not_active IP Right Cessation
- 1996-05-16 ZA ZA963917A patent/ZA963917B/en unknown
- 1996-05-16 PT PT96303474T patent/PT743327E/en unknown
- 1996-05-16 AU AU52295/96A patent/AU713324B2/en not_active Ceased
- 1996-05-16 BR BR9602284A patent/BR9602284A/en not_active IP Right Cessation
- 1996-05-16 AR AR33652996A patent/AR001953A1/en active IP Right Grant
- 1996-05-16 SK SK637-96A patent/SK63796A3/en unknown
- 1996-05-16 EP EP96303474A patent/EP0743327B1/en not_active Expired - Lifetime
- 1996-10-10 US US08/728,848 patent/US5798427A/en not_active Expired - Lifetime
-
2001
- 2001-04-12 GR GR20010400238T patent/GR3035742T3/en unknown
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