CA2183270A1 - Polyolefins having terminal aldehyde or hydroxyl substituents and derivatives thereof - Google Patents

Polyolefins having terminal aldehyde or hydroxyl substituents and derivatives thereof

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Publication number
CA2183270A1
CA2183270A1 CA002183270A CA2183270A CA2183270A1 CA 2183270 A1 CA2183270 A1 CA 2183270A1 CA 002183270 A CA002183270 A CA 002183270A CA 2183270 A CA2183270 A CA 2183270A CA 2183270 A1 CA2183270 A1 CA 2183270A1
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CA
Canada
Prior art keywords
polymer
polyolefins
terminal aldehyde
derivatives
derived
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002183270A
Other languages
French (fr)
Other versions
CA2183270C (en
Inventor
Jacob Emert
Istvan T. Horvath
Richard H. Schlosberg
Warren A. Thaler
David A. Young
Stephen Zushma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Jacob Emert
Istvan T. Horvath
Richard H. Schlosberg
Warren A. Thaler
David A. Young
Stephen Zushma
Exxon Chemical Patents, Inc.
Exxonmobil Chemical Patents Inc.
Exxon Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jacob Emert, Istvan T. Horvath, Richard H. Schlosberg, Warren A. Thaler, David A. Young, Stephen Zushma, Exxon Chemical Patents, Inc., Exxonmobil Chemical Patents Inc., Exxon Chemical Patents Inc. filed Critical Jacob Emert
Publication of CA2183270A1 publication Critical patent/CA2183270A1/en
Application granted granted Critical
Publication of CA2183270C publication Critical patent/CA2183270C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/58—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/54—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound

Abstract

A polymer having a terminal aldehyde or hydroxyl substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula: H2C=CHR4, wherein R4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin preferably has at least about 30 % terminal vinylidene unsaturation. Particularly desirable also are alkylamino derivatives formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process in the preferred polyolefins. Polyene(diene)-containing copolymers and terpolymers may also be used to prepare the polymer.
CA002183270A 1994-03-07 1995-03-01 Polyolefins having terminal aldehyde or hydroxyl substituents and derivatives thereof Expired - Fee Related CA2183270C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US20699394A 1994-03-07 1994-03-07
US206,993 1994-03-07
US08/391,845 US5674950A (en) 1994-03-07 1995-02-27 Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof
US391,845 1995-02-27

Publications (2)

Publication Number Publication Date
CA2183270A1 true CA2183270A1 (en) 1995-09-14
CA2183270C CA2183270C (en) 2006-07-25

Family

ID=26901864

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002183270A Expired - Fee Related CA2183270C (en) 1994-03-07 1995-03-01 Polyolefins having terminal aldehyde or hydroxyl substituents and derivatives thereof

Country Status (8)

Country Link
US (3) US5674950A (en)
EP (1) EP0750643B1 (en)
JP (1) JPH09510241A (en)
AU (1) AU1973895A (en)
BR (1) BR9507050A (en)
CA (1) CA2183270C (en)
DE (1) DE69509760T2 (en)
WO (1) WO1995024431A1 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2251599A1 (en) * 1996-05-16 1997-11-20 Exxon Chemical Patents Inc. Ethylene/alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
CA2034759C (en) * 1988-08-01 2003-06-03 Won R. Song Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives
US5759967A (en) * 1988-08-01 1998-06-02 Exxon Chemical Patents Inc Ethylene α-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
DE19548145A1 (en) * 1995-12-21 1997-06-26 Basf Ag Fuel or lubricant compositions containing secondary polyisobutenamines
DE19622061A1 (en) * 1996-05-31 1997-12-04 Basf Ag Process for the hydroformylation of ethylenically unsaturated polymers in aqueous dispersion
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5773567A (en) * 1996-06-17 1998-06-30 Exxon Chemical Patents Inc Carboxylic amide-containing polymers for use as fuel or lubricating oil additives and processes for their preparation
US5811379A (en) 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
DE10045056A1 (en) 2000-09-12 2002-03-21 Basf Ag Process for the continuous hydroformylation of polyalkenes with 30 to 700 carbon atoms
US20030122104A1 (en) * 2001-02-12 2003-07-03 Dober Chemical Corporation Liquid replacement systems
AU2002241114A1 (en) * 2001-03-26 2002-10-08 Octel America Inc Composition
AU2002310898A1 (en) * 2001-03-28 2002-10-28 Shell Internationale Research Maatschappij B.V. Process for the preparation of a polymer-amine
JP2005502449A (en) * 2001-08-24 2005-01-27 ドーバー ケミカル コーポレイション Controlled release of additives in fluid systems.
US6827750B2 (en) 2001-08-24 2004-12-07 Dober Chemical Corp Controlled release additives in fuel systems
US6835218B1 (en) 2001-08-24 2004-12-28 Dober Chemical Corp. Fuel additive compositions
WO2003019065A1 (en) * 2001-08-24 2003-03-06 Dober Chemical Corporation Controlled release of additives in cooling system
US7938277B2 (en) 2001-08-24 2011-05-10 Dober Chemical Corporation Controlled release of microbiocides
JP2006131707A (en) * 2004-11-04 2006-05-25 Mitsui Chemicals Inc Carbonyl group containing polymer and its derivative
US7563368B2 (en) 2006-12-12 2009-07-21 Cummins Filtration Ip Inc. Filtration device with releasable additive
US8591747B2 (en) 2008-05-27 2013-11-26 Dober Chemical Corp. Devices and methods for controlled release of additive compositions
US7883638B2 (en) 2008-05-27 2011-02-08 Dober Chemical Corporation Controlled release cooling additive compositions
US8702995B2 (en) 2008-05-27 2014-04-22 Dober Chemical Corp. Controlled release of microbiocides
US20090304868A1 (en) * 2008-05-27 2009-12-10 Dober Chemical Corporation Controlled release cooling additive composition
US8273414B2 (en) * 2009-03-05 2012-09-25 Wacker Chemical Corporation Phosphate-containing binders for nonwoven goods
CN106536694A (en) * 2014-05-19 2017-03-22 路博润公司 Hydroxy functionalized ashless additive
WO2019236418A1 (en) * 2018-06-05 2019-12-12 Exxonmobil Chemical Patents Inc. Alcohol-polyalphaolefins and methods thereof
CN114008182A (en) 2019-06-20 2022-02-01 埃克森美孚化学专利公司 Amphiphilic reaction products from vinylidene olefins and process for making same
WO2020256852A1 (en) 2019-06-20 2020-12-24 Exxonmobil Chemical Patents Inc. Amphiphilic reaction products from lightly branched olefins and methods for production thereof

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2644844A (en) * 1950-01-25 1953-07-07 Du Pont Process of preparing alcohols from olefins
US3011984A (en) * 1957-06-14 1961-12-05 Exxon Research Engineering Co Oxonation of butyl rubber and covulcanization products of same with natural rubber or butadiene-styrene copolymer
US3310576A (en) * 1963-02-05 1967-03-21 Exxon Research Engineering Co Hydroformylation catalyst and process relating thereto
US3311598A (en) * 1963-02-05 1967-03-28 Exxon Research Engineering Co Process for hydroformylating an unsaturated hydrocarbon polymer
US3334076A (en) * 1963-06-19 1967-08-01 Exxon Research Engineering Co Inhibiting gelation of hydroformylated polymers
US3383426A (en) * 1963-09-09 1968-05-14 Exxon Research Engineering Co Hydroformylation process for polymers
US3330875A (en) * 1963-12-19 1967-07-11 Exxon Research Engineering Co Decobalting hydroxylated polymers with concentrated phosphoric acid
US3278437A (en) * 1964-01-27 1966-10-11 Shell Oil Co Lubricating oil compositions
US3314911A (en) * 1964-06-24 1967-04-18 Exxon Research Engineering Co Colloidal silica containing latices of hydroformylated polymers of conjugated dienes
US3346664A (en) * 1964-11-03 1967-10-10 Exxon Research Engineering Co Coating compositions containing hydroxylated diolefin polymer and silicone resin
US3409648A (en) * 1965-07-16 1968-11-05 Exxon Research Engineering Co Process for preparing carboxylic acids from olefins
US3432512A (en) * 1965-07-22 1969-03-11 Borden Co Cyanoalkylated hydroxyalkylated polyvinyl alcohol and derivatives
US3574576A (en) * 1965-08-23 1971-04-13 Chevron Res Distillate fuel compositions having a hydrocarbon substituted alkylene polyamine
US3513310A (en) * 1967-03-10 1970-05-19 Industrial Nucleonics Corp High-speed nucleonic measuring system
US3776981A (en) * 1971-02-03 1973-12-04 Shell Oil Co Hydroformylated block copolymers
US4271088A (en) * 1978-06-16 1981-06-02 Suntech, Inc. High selectivity cyanoalkylation process
US4234435A (en) * 1979-02-23 1980-11-18 The Lubrizol Corporation Novel carboxylic acid acylating agents, derivatives thereof, concentrate and lubricant compositions containing the same, and processes for their preparation
US4526936A (en) * 1983-03-18 1985-07-02 W. R. Grace & Co. Process for the preparation of polymeric amine containing products
US4558101A (en) * 1983-03-18 1985-12-10 W. R. Grace & Co. Process for the preparation of polymeric amine containing products
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JPS61151202A (en) * 1984-12-26 1986-07-09 Toa Nenryo Kogyo Kk Production of propylene polymer
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US4665208A (en) * 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4657984A (en) * 1985-10-16 1987-04-14 Texaco Inc. Process for formation of dialkylaminomethylated internal olefin polymers
DE3611230A1 (en) * 1986-04-04 1987-10-08 Basf Ag POLYBUTYL AND POLYISOBUTYLAMINE, METHOD FOR THE PRODUCTION THEREOF AND THE FUEL AND LUBRICANT COMPOSITIONS CONTAINING THE SAME
US4739120A (en) * 1986-08-21 1988-04-19 The Dow Chemical Company Process for the hydrogenation of nitriles to primary amines
DE3635490A1 (en) * 1986-10-18 1988-04-21 Basf Ag USE OF POLYCARBONIC ACID ESTERS IN FULL OR PART SYNTHETIC LUBRICANTS AND LUBRICANTS CONTAINING THESE ESTERS
DE3772331D1 (en) * 1986-11-13 1991-09-26 Idemitsu Kosan Co METHOD FOR OLIGOMERIZING PROPEN.
DE3700363A1 (en) * 1987-01-08 1988-07-21 Basf Ag FUEL OR LUBRICANT COMPOSITION AND USE OF POLYBUTYL OR POLYISOBUTYL DERIVATIVES IN THE SAME
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
GB8724108D0 (en) * 1987-10-14 1987-11-18 Shell Int Research Preparation of functionalized polymers
JPH0757774B2 (en) * 1987-11-18 1995-06-21 三井石油化学工業株式会社 Liquid hydroxylated modified .ALPHA.-olefin polymer, its production and use
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5229478A (en) * 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5017299A (en) * 1988-08-01 1991-05-21 Exxon Chemical Patents, Inc. Novel ethylene alpha-olefin copolymer substituted Mannich base lubricant dispersant additives
US5075507A (en) * 1988-08-01 1991-12-24 Air Products And Chemicals, Inc. Process for the preparation of bis(aminopropyl)aliphatic glycols
DE3826797A1 (en) * 1988-08-06 1990-02-08 Basf Ag FUEL COMPOSITIONS CONTAINING POLYCARBONIC ACIDIC LOW-CHAIN ALCOHOLS
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
AU4502989A (en) * 1988-11-14 1990-06-12 Amoco Corporation 1-hydroxymethyl polyolefin via hydroformylation
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
GB9002134D0 (en) * 1990-01-31 1990-03-28 Exxon Chemical Patents Inc Fuel oil compositions and additives
US5046491A (en) * 1990-03-27 1991-09-10 Derrick Steven J Apparatus and method for respired gas collection and analysis
KR0123370B1 (en) * 1990-06-22 1997-11-12 벤 씨, 카덴헤드 Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
WO1992001477A1 (en) * 1990-07-26 1992-02-06 G.D. Searle & Co. Polymeric drug delivery system
JP3176386B2 (en) * 1991-04-30 2001-06-18 三菱化学株式会社 Amino group-containing polymer
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
EP0563365B1 (en) * 1991-10-15 1997-11-05 The Dow Chemical Company Preparation of metal coordination complex
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
DE69208023T2 (en) * 1991-11-07 1996-07-11 Shell Int Research Process for the production of secondary amines
US5277440A (en) * 1992-08-07 1994-01-11 Jackson Jr Thomas S Air bag retention device
US5340881A (en) * 1992-11-16 1994-08-23 The University Of Akron Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform

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US5880219A (en) 1999-03-09
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US5674950A (en) 1997-10-07
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EP0750643B1 (en) 1999-05-19
BR9507050A (en) 1997-09-02
EP0750643A1 (en) 1997-01-02
DE69509760D1 (en) 1999-06-24
JPH09510241A (en) 1997-10-14
WO1995024431A1 (en) 1995-09-14
US5919869A (en) 1999-07-06

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