CA2186419C

CA2186419C - Solid lubricants & friction modifiers for heavy loads and rail applications

Info

Publication number: CA2186419C
Application number: CA002186419A
Authority: CA
Inventors: Kelvin Spencer Chiddick
Original assignee: Kelsan Technologies Corp
Current assignee: Kelsan Technologies Corp
Priority date: 1996-09-25
Filing date: 1996-09-25
Publication date: 2003-12-30
Anticipated expiration: 2016-09-25
Also published as: WO1998013445A1; EP0946693A1; PL332418A1; KR20000048631A; JP4642944B2; JP2001501994A; KR100494878B1; BR9711553A; ATE310070T1; TR199900682T2; CZ297890B6; EP0946693B1; ES2253783T3; DE69734671D1; US6136757A; AU4196097A; DE69734671T2; AU736427B2; CA2186419A1; BR9711553B1

Abstract

The present invention relates to novel lubricant and friction modifier compositions optionally comprising a solid lubricant and a banding agent in water medium suitable for lubricating steel-steel interfaces such as tractor-trailer couplings, rail-wheel systems and other heavy duty applications.
The invention also relates to compositions described above which include friction modifiers with high or very high and positive coefficients of friction such that the coefficient of friction is considerably higher than the solid lubricant. The invention further relates to compositions comprising a binding agent and a friction modifier with a very high and positive coefficient of friction in a water medium.

Description

X1$6419 SOLID LUBRICANTS & FRICTION MODIFIERS FOR HEAVY LOADS
AND RAIL APPLICATIONS
FIELD OF THE INVENTION
The present invention relates to novel lubricant and friction modifier compositions comprising a solid lubricant, or a friction modifier, or both along with a binding agent in water medium suitable foz- lubricating steel-steel interfaces such as tractor-trailer couplings, rail-wheel systems and other heavy duty applications.
The invention also relates to compositions described above which include friction modifiers with high or very high and positive coefficients of friction such that the coefficient of friction is considerably higher than the solid lubricant.
The invention further relates to compositions comprising a binding agent and a friction modifier with a very high and positive coefficient of friction in a water medium.
BACKGROUND OF THE INVENTION
A conventiona:L lubricant for tractor-trailer couplings, rail-wheel systems ;end other heavy duty applications is grease.
However, grease has serious limitations for operation and for environmental contamination. Following mating of the coupling components after an application of grease, a large portion of the A

grease is immediately lost due to difficulties of the grease adhering to the coupling or rail. The lost grease falls on parts of the vehicle piping and on the ground as a non-biodegradable contaminant. Further, grease dissipates during use causing its lubricating performance to deteriorate to potentially hazardous conditions. This known dissipation thereby encourages users to apply excessive arr.ounts of grease to compensate. Moreover, exposed couplings, rails or wheels can become contaminated with dust and grit thereby forming a grinding compound which causes rapid wear to the bearing plates unless they are cleaned and regreased before use.
Typically, grease is reapplied every week or two. Its removal prior to re:greasing is accomplished with high pressure steam causing it to be flushed into the water supply.
Alternatively, stranger solvents may be used to remove grease which are even more unacceptable from an environmental standpoint.
Lubricant compositions comprising, inter alia, solid lubricants and pol~~mer media have been used as alternatives to grease and these lubricants have the advantage of forming a film on the metal surface:, and accordingly, better adhesion. However, as the lubricant dissipates, the polymer medium may still contaminate the environment.

X1$6419 Aqueous lubricant compositions have been suggested but discarded as impractical. in Swiss patent specification CH 669,207 A5, wherein a method of using an aqueous graphite dispersion for coating or paintinct sides of rails was discussed and discarded as the aqueous dispersion is apparently easily removed. The solution of CH 669,207 A5 is a composition which includes, inter olio, a polymer resin which has the same drawbacks as other polymer media as discussed above.
It is recogni~;ed i.n U.S. Patents 5,173,204 and 5,308,516, that when the co-efficient of friction increases with speed, it is known as having a negative friction characteristic. The origin of much noised emission in steel rail-wheel transportation systems can be directly attributed to the fact the negative friction characteri;~tic that under certain conditions arising in use, the wheels of :such systems do not always roll over the rails but sometimes slide: relative to them. This is most pronounced on curves. An efi=ecti.ve way to eliminate the squeaking and chattering is by changing the friction characteristic from a negative one to a positive one. Hereinafter, the term "positive friction" means that the coefficient of friction increases with speed of sliding and a 'rh:igh" coefficient of friction is greater than 0.10.
Apart from reduced fz°iction (and noise) and wheel-rail wear, Si. .~

use of a friction m~~dif_Ler can prevent the initiation and growth of short pitch corrugation by preventing or eliminating the oscillatory motions, commonly known as roll-stick oscillations, which are excited i:n the rail/wheel interface by the presence of negative friction.
U.S. Patents 5,173,204 and 5,308,516, teach that in a rail-wheel system, the l,abrica:nt composition should be applied to 25%
of all the wheels of a _rail-wheel system. Considering that the effect is most pronounced on curves, a lot of lubricant, time and effort is required in order to ensure that there is sufficient lubricant.
SZJMMARY OF THE INVENTION
The present invention provides water-based lubricant and friction modifier ~~ompositions for heavy duty use with metal applications such as tractor-trailer couplings or rail-wheel systems that has improved adhesion characteristics. The inclusion of a binding agent, defined below, in the lubricant, or lubricant and friction modifier, composition helps to bind the lubricant and friction modifier to the coupling, rail or other surface. Therefore, the composition need not be applied as frequently or in them same quantity and accordingly there will be less lubricant and :Erict:ion modifier lost and less environmental contamination.
In another aspE~ct, the invention also provides a water-based lubricant composition which includes a wetting agent. The inclusion of a wetting agent also helps to ensure that there is better adhesion of the solid lubricant to the coupling, rail or other surface and thus the solid lubricant may be better applied.
This invention is also directed to water based friction modifier compositions that include a wetting agent.
In another aspE;ct, the invention also provides a water-based lubricant compositi~~n which may be applied to a rail at precise areas ideri~ified a:~ problem areas such as curves or inclines.
Due to this specific application at identified spots, the subsequent transfer from rail to wheel means that the lubricant will be spread alone the :rail by movement of the wheels over the rail but principally far the identified spots. The advantages of such precision a~~plication are that less lubricant, time and effort are required in order to achieve the same results of improved noise control, traction and reduced short pitch corrugation.
In yet a further aspect, the invention provides a lubricant composition which i;~ easier to apply than previous compositions.
The lubricant composition is water-based which makes it easier to apply as the binding agent absorbs the water present in the A

composition and thus allows for quick adhesion to the metal surface .
In one aspect ~~f this invention, the composition comprises:
(a) at least about 24% by weight water medium;
(b) about 8% by weight binding agent; and (c) at least about 2% by weight solid lubricant.
In another as~~ect the lubricant composition additionally includes a friction modifier which exhibits improved high and positive or very high and positive friction characteristics. The composition allows for i~he solution to the steel-steel rolling-sliding situation described above with respect to the prior patents U.S. Patents 5,173,204 and 5,308,516 but with the added benefit of the precision application, described above, namely, that less lubricant, time and effort will be required to achieve the same result set out i.n those patents.
Accordingly, i:n a further aspect, the invention provides a lubricant composition comprising a water medium, solid lubricant, binding agent and a friction modifier present such that the coefficient of friction produced between steel bodies in rolling-sliding motion lubricated using the said composition is greater than 0.10 and wherein said coefficient of friction increases with an increase in the relative speed of sliding movement between the bodies.
A

1$~41~.

According to a further aspect of the invention there is provided a composition comprising:
(a) at least 60% by weight water;
(b) at least 5°-<s by weight binding agent; and (c) at least 3~ by weight friction modifier;
wherein the composition has the characteristics of very high and positive friction, with. a coefficient of friction ranging from 0.45 at 2.5% creep up to 0.72 at 30% creep. This product is used mainly to enhance traction of the locomotion wheels.
Further, according to the present invention, there is a method of reducing noise in a steel rail-wheel system by applying said lubricant, or lubricant and friction modifier, composition to the surface of t:he rail whereby the lubricant composition is effective to change the negative friction characteristics between the rail and the wheel to a positive friction characteristic.
The present invention also provides compositions which are capable of effectively reducing short pitch corrugation. This is achieved by compositions having a high coefficient of friction and positive friction characteristics.
The above compositions have the advantage of being relatively non-pol7_utir~g and economical in that the dispersal means allows for isolated application of compositions to surfaces which are targeted as problem areas.
A

DETAILED DESCRIPTIOZJ OF THE SPECIFIC EMBODIMENTS OF THE INVENTION
Generally the lubricant and friction modifier compositions are water-based compositions consisting of water, a solid lubricant, as required, a binding agent and, in some embodiments, a friction modifier and/or a wetting agent.
The lubricant and f-_riction modifier compositions can be formulated by selecting one or more solid lubricants and friction modifiers as requirE:d. Examples of solid lubricants and friction modifiers can be found from, but are not limited to, the following lists.
Solid Lubricants molybdenum disuphide graphite aluminum stearate zinc stearate carbon compounds (coal dust, carbon fibres, etc.) The preferred ;solid lubricants are molybdenum disulphide and graphite.
Friction Modifiers calcium carbonate magnesium. carbonate magnesium. silicate barium sulphate calcium sulphate asbestos A

aluminum silicate silica amorphous. silica naturally occuz°ring silica slate powder diatomaceous earth ground quartz silica flour white lead basic lead carbonate zinc oxide antimony oxide dolomite calcium sulphite napthalen.e syne:mite polyethylene mica The friction modi.f:ier, if any, preferably comprises a powderised mineral. The friction modifier for a high and positive friction lubricant composition may have a particle size in the range of about 0.5 microns to about 5 microns, and preferably has a particle size in the range of about 1 micron to about 2 microns. A very high and positive friction modifier composition may have a particle size of 10 microns.
The friction m~~difier should have a coefficient of friction which is considerably higher than the coefficient of friction of the solid lubricant:. The coefficient of friction values given are those produced between steel bodies in rolling-sliding contact. High anal positive friction modifier compositions produce a coefficient of friction which is greater than 0.10 and wherein the said coefficient of friction increases with an increase in the relatives speed of sliding movement between steel bodies. For very high and positive friction, the steel to steel coefficient of friction for the lubricant composition according to the invention should :increase from about 0.45 to about 0.72 as creepage increases from about 2.5% to about 30%. Particular compositions contain friction modifiers but not solid lubricants to create very high. and positive friction characteristics.
The term binding agent herein is defined to mean a hydrophilic agent which absorbs water causing it to swell out physically into pai.°ticl.es of a shape capable of adhering to a rail. The binding agent: creates a continuous phase matrix which is capable of binding so:Lid lubricants, friction modifiers and other compounds to a metallic surface by dispersing the solid lubricant or holding said solid lubricant in a discontinuous phase matrix. The binding agent has rigidity such that when the composition is placed on t:he metal surface, it has some structure and will maintain :its .integrity after the wheel goes over the composition. Examples of binding agents include but are not limited to clays su~~h as bentonite (sodium montmorillonite) and caslne.
Also optionally arE~ included preservatives, wetting agents and additives to al:Low f=or mixing of the composition with grease already on rai:1 or coup:Ling. Preservatives such as ammonia are a ~~~~419 used for preserving the lubricant composition. Alcohols such as butoxyethanol may also be used.
The term wetting agent used herein is defined to mean a flow agent which permits the solid lubricant particles to be surrounded by water wit.h:in the matrix of the binding agent and the solid lubricant. The wetting agent helps to reduce surface tension and allows 'the solid lubricant to get into the cracks of the rails or other sur:Eaces and also emulsifies the grease to permit a good adhesion. An example of a wetting agent includes but is not limited to nonyl phenoxypolyol.
Method of Preparation Embodiments of the lubricant and friction modifier compositions may be prepared according to the following method.
Under a high speed mixer slowly add to 35% of the water in a mixing drum at room temperature, the binding agent (ie. Bentonite (sodium montmorillonitE~)) and the wetting agent (ie. nonyl phenoxypolyol). These components should be mixed well until thick gel is formed.. Continue to mix then add the balance of ingredients in the following order: water (the remaining 65%), ammonia, ether E.B. (if a:ny), any other liquids, solid lubricant (ie. molybdenum)as required, and any other solids. These components should be mixed thoroughly until smooth to ensure that A

~18641g the solid lubricant. is well dispersed.
The resulting composition is a thick, thixotropic liquid which is jelly-like when standing but upon stirring or pumping the viscosity decreases. The composition is a matrix whose continuous phase is the binding agent and which also contains a discontinuous phase, the solid lubricant.
The above compositions may be applied to the coupling or rail surfaces or the like by means of which will be recognized by one in the art such as pump or brush. The composition is applied so that a film of the composition is evenly spread on the rail. Said film i:~ preferably a bead approximately one-eighth of an inch in diameter.
The binding agent works by absorbing the water in the composition. Over time, the composition dehydrates to leave a solid bead and thereby enhances adhesion of the lubricant and friction modifier t:o the rail over previously used greases or polymer lubricant c~~mpositions. The binding agent additionally keeps the lubricant. and friction modifier dispersed even after the wheel runs over thf~ rail and also reduces reabsorption of water. Therefore, t:he composition is not easily removed by rain.
The desired coef=ficient of friction level for the compositions of this invention are obtained by proportionately mixing appropriate quantities of the friction modifier with a A

1$641 high coefficient of friction and the solid lubricant with a very low coefficient 0i= fricaion. The solid lubricant and the friction modifier are preferably present in the composition in about equal amounts for the high and positive friction compositions but mayy be present in differing amounts or with no solid lubricant in. order to achieve very high and positive friction characteristics.
The following, given by way of example only and not intended to be construed in a limitative manner, illustrate the compositions according tc> embodiments of the invention.

A water-based, high and positive friction lubricant composition comprises:
(a) 80.193% by weight water;
(b) 8.940% by weight sodium montmorillonite;
(c) 0.0040 by weight ammonia;
(d) 0.0020 by weight nonyl phenoxypolyol;
(e) 4.9300 by weight molybdenum disulphide; and (f) 4.93% by weight magnesium silicate;
and is prepared as described above.
A North American heavy haul railroad tested the above composition and it was found that noise levels were reduced by A

20 decibels at the top of. the rail and at the gage face.
Similar lubricant compositions can be formulated by selecting one or more alternative lubricants and friction modifiers as disclosed above.

A water-based, very high and positive friction composition (with no added lubricani~) was prepared as described above using the following compcnents:
(a) 85.254% by weight water;
(b) 9.4500 by weight sodium montmorillonite;
(c) 0.004% by weight ammonia;
(d) 0.002% by weight nonyl phenoxypolyol;
(e) 5.200 by weight anydrous aluminum silicate; and (f) 0.090 by weight black iron oxide (as a colorant).
The composition was tested and found to produce a positive steel to steel frici~ion characteristic in the range of 0 to 0.45 as the relative speed of sliding (creepage) increased from zero to about 2.5%, rising to about 0.72 as creepage increased to about 300. These coefficient of friction levels are substantially above: steel to steel friction coefficient levels obtained with conventional lubricants and above those of the lubricant composition disclosed in U.S. Patents 5,173,204 and 5,308,516.
A

~18G41g A water-based 5th wheel lubricant composition was prepared as described above using the following components:
(a) 58.994% by weight water;
(b) 8% by weight sodium montmorillonite;
(c) 0.0040 by weight ammonia;
(d) 0.002% by weight nonyl phenoxypolyol;
(e) 3% by weigYit butoxyethanol; and (f) 300 by weight molybdenum disulphide.
When the lubr~_cant: 'was applied to the surface of a wheel tread, the composition illustrated a marked improvement with respect to adhesion of the lubricant. Tests have shown that the fifth wheel composition lasts substantially longer or for substantially more miles, in the order of 5-10 times longer than conventional lubricants.

A water-based .Low coefficient friction lubricant composition was prepared as des~ribE~d above using the following components:
(a) 79.502% by weight water;
(b) 12.621% by weight sodium montmorillonite;
(c) 0.004% by weight ammonia;
(d) 0.0020 by weight nonyl phenoxypolyol;
(e) 3% by weight butoxyethanol; and A

'~~6419 (f) 4.871% by weight molybdenum disulphide.
Similar testing was done to that described in example 1 and with similar results being recorded.
It is understood that the invention has been disclosed herein in connection with certain examples and embodiments.
However, such chances, modifications or equivalents as can be used by those skil=led .in the art are intended to be included.
Accordingly, the disclosure is to be construed as exemplary, rather than limitin~~, and such changes within the principles of the invention as are obvious to one skilled in the art are intended to be included within the scope of the claims.
A

Claims

1. A water-based lubricant composition for lubricating steel-to-steel interfaces consisting of:
(a) from about 24% to about 88% by weight water;
(b) about 3% to about 15% by weight binding agent;
(c) from about 2% to about 60% by weight solid lubricant; and (d) a wetting agent.

2. The composition according to claim 1, wherein the solid lubricant is molybdenum disulphide, graphite, or a combination thereof.

3. The composition according to claim 1, wherein the binding agent is sodium montmorillonite.

4. The composition according to claim 1, wherein the wetting agent is nonyl phenoxypolyol.

5. The composition of claim 1 for the use of lubricating steel surfaces.

6. A water-based lubricant composition for lubricating steel-to-steel interfaces consisting of:
(a) from about 60% to about 90% by weight water;
(b) from about 5% to about 18% by weight binding agent;
(c) from about 3% to about 24% by weight solid lubricant; and (d) from about 3% to about 32% by weight friction modifier, wherein said composition is characterized in producing a coefficient of friction of at least 0.1 which increases with increased creepage levels between steel bodies in rolling-sliding contact.

7. The water based lubricant composition of claim 6 further consisting of a wetting agent.

8. The composition according to claim 6, wherein the solid lubricant is molybdenum disulphide, graphite, or a combination thereof.

9. The composition according to claim 6, wherein the friction modifier has a particle size in the range of 0.5 to 5 microns.

10. The composition according to claim 6, wherein the friction modifier has a particle size in the range of 1 to 2 microns.

11. The composition according to claim 6, wherein the binding agent is sodium montmorillonite.

12. The composition according to claim 7, wherein the wetting agent is nonyl phenoxypolyol.

13. The composition of claim 6 for the use of lubricating steel surfaces.

14. A water-based friction modifier composition consisting of:
(a) from about 60% to about 90% by weight water;
(b) from about 5% to about 18% by weight binding agent; and (c) from about 3% to about 32% by weight friction modifier, wherein said composition is characterized in producing a coefficient of friction of at least 0.1 which increases with increased creepage levels between steel bodies in rolling-sliding contact.

15. The water based lubricant composition of claim 14 further consisting of a wetting agent.

16. The composition according to claim 14 wherein the coefficient of friction increases to about 0.45 at creepage levels of up to 2.5%.

17. The composition according to claim 14 wherein the coefficient of friction increases from about 0.45 to about 0.72 as creepage increases from about 2.5% to about 30%.

18. The composition according to claim 14, wherein the friction modifier has a particle size of 10 microns.

19. A water based lubricant composition comprising:
(a) 24-88% by weight water;
(b) 3-15% by sodium montmorillonite;
(c) 2-60% by weight molybdenum disulphide; and (d) (d) 0.002-2% by weight nonyl phenoxypolyol.

20. The water-based lubricant composition of claim 19 comprising:
(a) 55-88% by weight water;
(b) 5-8% by weight sodium montmorillonite;
(c) 2-18% by weight molybdenum disulphide; and (d) 0.002-2% by weight nonyl phenoxypolyol.

21. A water-based lubricant composition comprising:
(a) 60-90% by weight water;
(b) 5-18% by weight sodium montmorillonite;
(c) 3-24% by weight molybdenum disulphide;
(d) 3-24% by weight magnesium silicate; and (e) 0.002-2% by weight nonyl phenoxypolyol wherein said molybdenum disulphide and magnesium silicate are present in a ratio of 1:1 such that the resulting coefficient of friction of the said composition ranges from about 0.17 to about 0.35 as creepage levels increase from about 2.5% to about 30% between steel bodies in rolling-sliding contact.

22. A water-based composition comprising:
(a) 60-90% by weight water;
(b) 5-18% by weight sodium montmorillonite;
(c) 3-32% by weight anhydrous aluminum silicate; and (d) 0.002-2% by weight nonyl phenoxypolyol wherein the resulting coefficient of friction of the said composition ranges from about 0.45 to about 0.72 as creepage levels increase from about 2.5% to about 30%
between steel bodies in rolling-sliding contact.

23. The composition according to claim 14, wherein the binding agent is sodium montmorillonite.

24. The composition according to claim 15, wherein the wetting agent is nonyl phenoxypolyol.

25. The composition of claim 14 for the use of lubricating steel surfaces.

26. A method for lubricating a metallic surface to reduce friction and wear, using a lubricant composition according to claim 1 comprising depositing a bead of the lubricant composition onto the metallic surface and allowing the water to evaporate.

27. A method for lubricating a metallic surface to reduce friction and wear, using a lubricant composition according to claim 6 comprising depositing a bead of the lubricant composition onto the metallic surface and allowing the water to evaporate.

28. A method for lubricating a metallic surface to reduce friction and wear, using a lubricant composition according to claim 14 comprising depositing a bead of the lubricant composition onto the metallic surface and allowing the water to evaporate.