CA2193208C - Stable beverage fountain syrups containing oil phase and method of stabilizing fountain syrup oil phase - Google Patents
Stable beverage fountain syrups containing oil phase and method of stabilizing fountain syrup oil phase Download PDFInfo
- Publication number
- CA2193208C CA2193208C CA002193208A CA2193208A CA2193208C CA 2193208 C CA2193208 C CA 2193208C CA 002193208 A CA002193208 A CA 002193208A CA 2193208 A CA2193208 A CA 2193208A CA 2193208 C CA2193208 C CA 2193208C
- Authority
- CA
- Canada
- Prior art keywords
- syrup
- oil
- beverage
- oil phase
- fountain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/62—Clouding agents; Agents to improve the cloud-stability
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/70—Clarifying or fining of non-alcoholic beverages; Removing unwanted matter
- A23L2/78—Clarifying or fining of non-alcoholic beverages; Removing unwanted matter by ion-exchange
Abstract
The present invention relates to a method for stabilizing beverage fountain syrups having a dispersed oil phase consisting essentially of incorporating into said syrups from about 0.02 % to about 0.3 % of a stabilizer which is xanthan gum. The present invention further relates to beverage fountain syrup compositions, preferably dilute juice beverage fountain syrup compositions, comprising: a) from about 0.02 % to about 0.3 % of a stabilizer which is xanthan gum; b) from about 0.2 % to about 3 % oil; c) from about 0.2 % to about 10 % of an emulsifier which is a modified food starch; d) an effective amount of a flavor component; e) an effective amount of sweetener; and f) from about 30 % to about 70 % water; wherein said syrup has a Brix value of from about 30~ to about 70~; and a modified food starch to oil ratio of from about 0.1 to about 4.
Description
2 ~ 93~ O8 STABLE BEVERAGE FOUNTAIN SYRUPS
CONTAll~IING OIL PHASE AND METHOD
s OF STABILIZING FOUNTAIN SYRUP OIL PHASE
FIELD OF INVENTION
The invention relates to beverage fountain syrup compositions and a method for to stabilizing beverage fountain syrups having a dispersed oil phase and a high Brix value.
BACKGROUND OF THE INVENTION
Beverage fountain syrups are concentrated forms of beverages which can be diluted with water or carbonated water to form a single strength, ready-to-serve beverage. Beverage fountain syrups are typically utilized by fast food and restaurant 15 retail establishments. The public is most familiar with the carbonated cola beverages that are dispensed via "soda" fountains.
Currently health consciousness or awareness by the public has increased the demand for the availability of fruit and botanical juice beverages.
Particularly, parents prefer juice beverages over carbonated cola beverages for their children.
2o Juice beverages, such as the dilute juice beverage SUNNY DELIGIaT''M, heretofore have not been readily available in fast food ~ and restaurant retail establishments except in bottled or canned ready to drink forms. There is a need for juice beverages and particularly dilute juice beverages to be supplied in a beverage fountain syrup form which can be readily utilized in fountain machines.
25 Generally, single strength dilute juice beverages comprise a dispersed oil phase (sometimes referred to as an oil cloud). In single strength beverages which comprise an oil phase, thickener combinations, such as the combination of carboxymethylcellulose and xanthan gum, have been used to stabilize the oil phase, i.e., to keep the oil form separating. PCT Application No. 9308704, Burger et al., published May 13, 1993, so discloses a beverage thickener system comprising propylene glycol alginate, xanthan gum and guar gum. The thickener system provides for stable oil-in-water emulsions in beverages.
It has been discovered that in fountain syrups of dilute juice beverages having from 0.29% to about, high Brix value (generally from about 30° to about 70°), and no 35 thickener, oil will separate from the syrup and rise to the top within a few days.
Fountain syrups of dilute juice beverages having only carboxymethylcellulose or guar gum as the thickener show poor stability and separation of the oil phase occurs generally within about 35 days. Surprisingly, thickener systems that have been used for single strength beverages, and particularly dilute juice beverages, such as carboxymethyl cellulose/xanthan gum or propylene glycol alginate/guar gum/xanthan gum have also shown poor stability such that separation of the oil begins visible separation generally within from about 24 to about 70 days at 70°F (21 °C). In addition to providing poor stability of the oil phases, these conventional thickener systems can cause significant increases in the viscosities of the beverage fountain syrups which can hinder to the ability of the fountain syrups to be pumped through a typical fountain machine resulting in a viscosity of greater than about 250 centipoise at 51 sec' shear rate.
It is an aspect of an object of the present invention to provide for a method for stabilizing the oil phase of beverage fountain syrups, particularly dilute juice beverage fountain syrups, having a high Brix value.
It is an aspect of an object of the present invention to provide for beverage fountain syrups, particularly dilute juice beverage fountain syrups, which exhibit stability of the oil phase, i.e. no visible separation of the oil phase, for at least about 90 days, preferably at least about 120 days and must 2o preferably equal to or greater than about 140 days at about 21°C.
Further, it is an aspect of an object that the beverage fountain syrups, particularly dilute juice beverage fountain syrups, have good pumpability.
SUMMARY OF THE INVENTION
The present invention relates to a method for stabilizing beverage fountain syrups having a dispersed oil phase consisting essentially of incorporating into said syrups from about 0.02°/° to about 0.3°/° of a stabilizer which is xanthan gum.
The present invention further relates to a method for stabilizing 3o beverage fountain syrup compositions having from about 0.2°/°
to about 3%
of a dispersed oil phase and a Brix value of from about 30° to about 70°
B
' 21 93208 2a consisting essentially of incorporating into the syrup compositions from about 0.02% to about 0.3°/° of a stabilizer which is xanthan gum and from about s 0.2°I°-0.10°/° of an emulsifier which is a modified food starch, wherein the ratio of modified food starch to oil is from about 0.1 to about 0.4.
The present invention further relates to beverage fountain syrup compositions comprising:
a) from about 0.02°I° to about 0.3°/°, by weight, of a stabilizer to which is xanthan gum;
b) from about 0.2°/° to about 3°/°, by weight, oil;
c) from about 0.2°/° to about 10°/°, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of a flavor component;
15 e) an effective amount of sweetener; and f) from about 30°/° to about 70°I°, by weight, water;
wherein the syrup has a Brix value of from about 30° to about 70° and a modified food starch to oil ratio of from about 0.1 to about 4.
The present invention further relates to a beverage fountain syrup 2o composition comprising:
a) from about 0.05°I° to about 0.2°/°, by weight, of a stabilizer which is xanthan gum;
b) from about 0.3°I° to about 2°I°, by weight, oil;
c) from about 0.1 °I° to about 4°I°, by weight, of an emulsifier which is a 25 modified food starch;
d) an effective amount of flavor component;
e) an effective amount of sweetener; and f) from about 35°/° to about 60°/°, by weight, water;
wherein the beverage fountain syrup composition has a Brix value of from 3o about 40° to about 65° and a modified food starch to oil ratio of from about 0.2 to about 2.
~1932~~
WO 96100510 PCTIUS95l07770 DETAILED DESCRIPTION OF THE INVENTION
Definitions:
As used herein, the term "comprising" means various unnamed 75 components can be conjointly employed in the compositions of this invention Accordingly, the terms "consisting essentially of" and "consisting of" are embodied in the term comprising.
As used herein the term "fruit flavors" refers to those flavors derived from the edible reproductive part of the seed plant, especially one having a sweet pulp so associated with the seed, for example, apples, oranges, lemon, limes, etc.
Also included within the term fruit flavor are synthetically prepared flavors made to simulate fruit flavors derived from natural sources. Particularly preferred fruit flavors are the citrus flavors including orange, tangerine, lemon, lime and grapefruit flavors. A variety of other fruit flavors can be used such as apple, s5 grape, cherry, pineapple, coconut and the like. These fruit flavors can be derived from natural sources such as fruit juices and flavor oils or synthetically prepared.
If desired, fruit juices, including orange, lemon, tangerine, lime, apple and grape can be used in a flavor component.
As used herein, the term "botanical flavor" refers to flavors derived from 9o parts of the plant other than the fruit. As such, botanical flavors can include those flavors derived from nuts, bark, roots and leaves. Also included within this term are synthetically prepared flavors made to simulate botanical flavors derived from natural sources. Examples of botanical flavors include cola flavors, tea flavors, coffee and the like. These botanical flavors can be derived from natural sources 95 such as essential oils and extracts or be synthetically prepared. Coffee, black tea, and herbal tea extracts can be used as the flavorant herein.
As used herein 'single strength" refers to a single strength beverage, i.e. a ready-to-serve or consume beverage that does not require additional components such as water before consumption.
loo As used herein, the term "fruit juice" refers to citrus and non-citrus juices including vegetable juices. The fruit juice can be provided as juice made from apple, passion fruit, cranberry, pear, peach, plum, apricot, nectarine, grape, cherry, currant, raspberry, gooseberry, blackberry, blueberry, strawberry, lemon, lime, mandarin, tangerine, orange, grapefruit, potato, tomato, lettuce, celery, l05 spinach, cabbage, watercress, dandelion, rhubarb, carrot, beet, cucumber, pineapple, coconut, pomegranate, lawi, mango, papaya, banana, watermelon and cantaloupe. The term "fruit juice' also refers to water extracted soluble solids, fruit juice concxntrates, oomminutes and purees.
,,",, WO 96100510 PCTIL,'S95'07',"0 As used herein, the term "nutritionally-supplemental amount' is meant that llo the mineral and vitamin sources used in the practice of this invention provide a nourishing amount of minerals and vitamins. This is supplemental or in addition to the amount found in the average diet. This supplemental amount will provide from about 1096 to about 20096 of the Recommended Dietary Allowance (~A)_ The RDA for vitamins and minerals is as defined in the United States of America 115 (see Recommended Daily Dietary Allowance-Food and Nutrition Board, National Academy of Sciences-National Research Council).
As used herein the term 'dilute juice beverage' means a single strength, ready-to-serve beverage comprising from 096 to about SO~o, preferably from about 3 % to about 35 96 and most preferably from about 5 96 to about 10 %
fruit 120 j uice.
As used herein the term 'syrup', 'fountain syrup' or 'beverage fountain syrup' refers to a composition which when diluted with an appropriate amount of water forms a single strength beverage. Syrups as described herein are prepared at generally about five to six fold such that the syrup is diluted with four to five 12s parts water by volume to form a single strength beverage. Most people are familiar with this syrup in relation to a dispenxr that produces beverages from a mixture of syrup and watrcer such as at a convenience store.
All percentages herein are by weight unless otherwix specified.
~s~NTIAL GOMPONEN'15 OF FOUNTAIN SYRLIp Xanthan gum is an exocellular heteropolysaxharide produced by a fermentation proxss using the bacteria Xanthomonas c~nparris. Xanthan gum is a polymer with five sugar residues, two glucox units, two mannox units, and one gluctuonic acid. The backbone of the unit is a 1, 4 Iinlcrd ~i-d-glucose. This 13s backbone is identical in structure to cellulox. A reference for Xanthan structures, properties, and uses, is 'Xanthan Gum, Natural Biogum for Scientific Water Control', dth edition from Kelco, Division of Mack & Co., Inc.
Xanthan is available in a variety of particle sizes, including 80-mesh and 200-mesh, preferably 200 mesh is used. Xanthan loo gums are available from many commercial sources including Kelco, a Division of Merck Company (California) and TIC Gums. A preferred commercial product is Keltrol F from Kelco.
Xanthan gum is utilized as a stabilizer of the dispersed oil in the syrup compositions. Xanthan gum is used at levels of from about 0.02 96 to about 0.3 96 , las and preferably from about 0.0596 to about 0.296 of the syrup compositions.
* = Trade-mark .... WO 96100510 _ PC.LIZ;g9c~07' ~0 Oil is utilized in the syrup compositions to provide opacity or cloud to the single strength beverages made from the syrups. The oil produces a juice, hike appearance in the single strength dilute juice beverage. Suitable oils for use are iso oils such as vegetable oils, animal oils, synthetic oils, and mixtures thereof.
Preferred for use are vegetable oils. Preferred unhydrogenated oils arc soybean, sunflower, high oleic sunflower, safflower, cottonseed, corn, peanut, and canola oils. Partially hydrogenated oils can be used for oils requiring improved flavor stability.
is5 The oil is utilized at a level of from about 0.2 96 to about 3 % , preferably from about 0.3 % to about 2 % of the syrup composition.
The oil is typically incorporated into the composition as an oil-in-water emulsion which utilizes a modified food starch as an emulsifier. Thex are octenyl succinate modified starchy ('OSAN-starch') which arc also commonly referred to ibo as Iipophilic starches. They arc typically made by treatment with from about 296 to about 396 1-octeayl succinate anhydride. Sec 'Modified Food Starches:
Properties and Uses' Chaptu 9, O.B. Wurzburg, editor, (1986) CRC Press, Boca Baton, Florida Purity Gum BE
(National Starch) is a suitable modified food starch derived from waxy maize 16s which is commonly used as an emulsifier for beverage emulsions. Generally, the starch is utilized at from about 0.0296 to about 1096, preferably from about 0.196 to about 496, of the syrup composition. The amount of starch used depends on the particular starch utilized and the amount of oil utilized. Typically, the modified starch to oil ratio is from about 0.1 to about 4 and preferably from about 0.2 to 17o about 2.
Brominated vegetable oils and rrsin esters, in particular the ester gums, and other weighting agents are not preferred for use in the compositions. Most preferably, the syrup compositions are substantially frte of weighting agents, typically this is less than about 0.05 96 and preferably less than about 0.0196 of 175 the syrup COmpOS1t10I1.
The turbidiry of diluted beverages prepared from the syrup compositions of the present invention will generally be grt~ta~ than 200 NTU's. The range is typically from about 1000 to about 15000 NTU's as a result of the disperxd oil phase. Preferably, the turbidiry is from about 1500 to about 10000 NTU's and iso most preferably from about 2000 to about 5000 NTU's. Ttubidiry is a measure of the cloudiness or opacity of a beverage. One way of measuring turbidity is by determining how much light is scaaerai by a sample of the beverage. See 'The a ,.".. V1~'O 96100510 PCTIL; S9510?", 0 Ratio Turbidimettr', Technical Information Series - Booklet No. 10, Hach Company, Loveland Colorado. A useful instrument for doing this is the DRT
iss 100B Turbidimeter (HF Instruments, a Division of Shaban Mfg., Inc. Ft.
Myers, Florida). The measured turbidity is reported in NTU's (nephelomerric turbidiry unit. A higher number indicates a higher degree of turbidiry or cloudiness.
See "Relationship Betwetn Sensory Clarity and Turbidity Values of Apple Juice", L.
J. Malcolmson and L. Jeffrey, 1989 Can. Inst. Food Sci. Txhnol. J. 22(2); 129 Flaoor Com~ionent The particular amount of the flavor component effective for imparting flavor characteristics to the syrup compositions depends upon the flavors) selected, the flavor impression desired and the form of the flavor.
19s The flavoring system can comprise a fruit juice, a fruit flavor, a botanical flavor or mixtures thereof. In particular the combination of tea flavors, preferably green tea or black tea flavors, together with fruit juices have an appealing taste Preferred fruit juices and flail flavors are apple, pear, lemon, lime, mandarin, grapefruit, cranberry, orange, strawberry, grape, kiwi, pineapple, tangerine, 20o passion fruit, mango, guava, raspberry, and cherry. Citrus flavors and juices, preferably grapefruit, orange, lemon, lime, mandarin, tangerine and juices of mango, passion Exult, and guava, or mixtures thereof are most preferred.
The fruit flavors can be derived from nanual sources such as fruit juices and flavor oils, or else be synthetically prepared.
Zos The flavor compoaent can also comprise a blend of various flavors, e.g.
lemon and lime flavors, citrus flavors and selected spices (the typical cola soft drink flavor). Mixttuzs of flavors and juices can be used.
The syrup compositions of the present invention are preferably formulated such that upon dilution a dilute juice beverage is formed which comprises from 210 096 to about 5096, preferably from about 396 to about 3596, and most preferably from about 596 to about 1096 fruit juice. For example, a preferred syrup composition which will provide 596 orange juice in the diluted beverage can comprise fmm about 4 96 to about 5 96 orange juice concentrate having a Brit of 60° or from about 2096 to about 2596 orange juice. One skilled in the art is Zls familiar and able of determining the requisite amount of juice, cancentrate or puree needed in the syrup to achieve a particular targeted dilute beverage concentration.
Syrup compositions of the present invention which are substantially free of fruit juice typically comprise flavor components which are no more than about 219 3 ?__ ~ 8 PCTIUS95I07770 220 15 % of the syrup, preferably such flavor component comprises at least 0.004 % of the beverage, and typically from about 0.04 % to about 10 ~o , and preferably from about 0.1 % to about 0.4 ~'o of the beverage.
Sweetener The syrup compositions of the present invention contain a sweetener in an 225 amount sufficient to provide the desired flavor and texture. The syrup composition preferably comprises a carbohydrate sweetener.
The carbohydrate sweetener is preferably a mono- and or disaccharide sugar such as maltose, lactose, galactose, sucrose, glucose, fructose, invert sugars and mixtures thereof. Especially preferred is fructose. All of these sugars are 2so typically incorporated into the syrup compositions as "syrups" (sugar dissolved or slurried in water), but they can likewise be incorporated in other forms, e.g.
solid form. These sugars are also provided to some extent by other added materials in the compositions such as fruit juice, optional flavorants, and the Iike.
Fructose for use in the beverage product can be provided as liquid fructose, 2s5 high fructose corn syrup, dry fructose or fructose syrup; it is preferably provided as high fructose corn syrup wherein at least about 42 % by weight of the solids in the syrup are fructose. Preferred fructose sources are high fructose corn syrups wherein 42 % of the solids in the syrup are fructose (HFCS 42), high fructose corn syrup wherein 55 % of the solids in the syrup are fructose (HFCS 55), and liquid 2ao fructose (contains 99 % fructose solids), all of which are available from A.E.
Staley Manufacturing, Decatur, Illinois.
Sugar alcohols can also be used in the syrup compositions of the present invention. These sugar alcohols include sorbitol, mannitol, and xylitol.
Usually, however, these materials are not used as the sole sweetener because in the levels 2as required to sweeten beverages, they have a side effect of flatulence or related gastrointestinal related problems.
For diet syrup compositions, non-caloric sweeteners can be used as long as the Brix is not lowered below about 30 ° . Thus, mixtures of non-caloric and caloric sweeteners are preferred. Mixtures of carbohydrates, low calorie 2so sweeteners and artificial sweeteners can also be used in the present invention, i.e., a mixture of aspartame and sucrose or high fructose corn syrup can be used.
Examples of such sweeteners . include aspartame, saccharine, cyclamates, acetosulfam-K, L-aspariyl-L-phenylalanine lower alkyl ester sweeteners, L-a.spartyl-D-alanine amides as disclosed in U.S. patent 4,411,925 to Brennan, et al 255. (1983), L-aspartyl-D-serine amides disclosed in U.S. 4,399,163 to Brennan et al (1983), L-aspartyl-hydroxymethylalkane amide sweeteners disclosed in U.S.
WO 96/00510 2 l 9 3 2 ~ ~ PCT/US95107770 4,338,346 issued to Brand (1982), L-aspartyl-1-hydroayethylalkane amide sweeteners disclosed in U.S. 4,423,029 to Rizzi (1983), glycerins, synthetic alkoxy aromatics, etc. Lo Han Guo juice which contains a natural sweetener can 26o also be used as a sweetener.
The amount of sweetener effective in the syrups of the present invention depends upon the particular sweeteners used and the sweetness intensity desired.
Preferred syrup compositions comprise from about 30 W to about 70 % by weight sugar. In determining the amount of sugar of the present invention, any sugar or 2s5 other sweetener present in the flavor component, such as fruit juice, is also included.
For carbohydrates or sugars, the amount of sweetener can be from about 30 % to about 70 % , and preferably from about 40 9~ to about 65 % by weight for the syrup compositions. The amount for artificial sweeteners generally ranges 27o from about 0.001 % to about 29~, preferably from about 0.019b to about 0.1 ~.
Syrup compositions of the present invention have a Brio value of from about 30° to about ?0°, preferably from about 40° to about 65° and most preferably from about SO° to about 60°.
Added Water 275 Sufficient water is utilized to achieve the desired syrup concentration and Brix value. Water comprises from about 30 % to about 70 % , preferably from about 35 % to about 60 % and most preferably from about 40 ~% to about 50 % , of the syrup compositions. Water as used herein includes water from all sources, e.g., juice and sweetener.
2so Acidi The syrup compositions of the present invention have a pH of from about 2.5 to about 4.5, preferably from about 2.7 to about 3.5. Calcium fortified syrup compositions typically have higher pH levels of from about 2.5 to about 4.5 and preferably from about 3 to about 4. This pH range is typical for non-carbonated 285 dilute juice beverage products. The acidity can be adjusted to and maintained within the requisite range by known and conventional methods, e.g., the use of food grade acid buffers. Generally, citric, malic, phosphoric, fumaric, lactic and acetic acids are added and/or their salts, e.g., sodium citrate and potassium citrate. For non-carbonated beverages, citric acid is preferred. For calcium fortified beverages, citric 29o and malic acids are preferred. Typically, the acidity within the above recited ranges is a balance between maximum acidity for microbial inhibition and optimum acidity for the desired beverage flavor and sourness impression.
~~- 21 ~3~08 WO 96100510 PCTlUS95/07770 OPTIONAL COMPON
The syrup composition can additionally comprise from 0f~ to about 1109 295 of the U.S. RDA of vitamins and minerals such that the vitamins and minerals are chemically and physically compatible with the essential elements of the beverage composition. Especially preferred are Vitamin A, and provitamins thereof (beta carotene), Vitamins C, D, E, B1, B6, B12, niacin, pantothenic acid, folic acid biotin, thiamin, calcium, magnesium, potassium, sodium, iron, zinc and mixtures 30o thereof. Other optional ingredients are preservatives such as benzoic acid, sorbic acid and salts thereof, and natural and synthetic colors.
Viscosi The viscosities of the syrup compositions will generally be no more than about 250 centipoise, more preferably no more than about 200 centipoise and most 305 preferably no more than about 150 centipoise, at 70°F(21°C) and at a shear rate of 51 sec -1 as measured with a Brookfield viscometer Model DV-III with coaxial cylinders such as spindle #31 or #34 and chamber 13R
Method of Stabilizing Oil in Syrun Compositions The present invention also relates to a method for providing stability of the oil 31o phase in beverage fountain syrups by the addition of xanthan gum without the use of other stabilizerslthickeners, such as carboxymethylcellulose, guar gum, propylene glycol alginate, or mixtures thereof. Typically, this method provides for stability from separation of the oil phase from beverage fountain syrups comprising from about 0.2% to about 3%, preferably from about 0.3% to about 2%, oil and having a 315 Brix value of from about 30° about 70°, preferably from about 40° to about 65° and most preferably from about 50° to about 60°. The method consists essentially of incorporating into said syrups from about 0.02% to about 0.3%, preferably from about 0.05% to about 0.2%, of a stabilizer which is xanthan gum.
The method provides for syrup compositions which exhibit stability of the 32o dispersed oil phase, i.e., no visible separation of the oil phase, for at least about 90 days, preferably at least about 120 days and most preferably equal to or greater than about 140 days at about 21°C.
The syrup compositions preferably have a modified food starch to oil ratio of from about 0.1 to about 4 and preferably from about 0.2 to about 2.
325 Svruo Composition Preparation The syrup compositions of the present invention can be prepared by conventional formulation techniques.
A method for preparing the beverage fountain syrup compositions herein is described as follows: 1. Added to water are the starch emulsifier and the oil to form WO 96100510 PC'T/Z;S95%07','0 1° 2193208 33o a water-in-oil emulsion. The emulsion is homogenized for a sui~cient period of time to form the emulsion. 2. Added to water with mixing are the stabilizer, sweetener, and flavor component as well as any optional components such as preservatives.
3.
The emulsion of 1 is then add to the slurry of 2 with mixing.
Calcium fortified beverage fountain syrups can be made and are encompassed 335 by the present invention. Methods for making natural and manufarnued calcium containing beverages, for example are described in U.S. 4,737,375 to Nakel et.
al., U.S. 4,830,862 to Braun et al. and U.S. 4,722,847 to Heckert et. al.
The key aspect of the process of the present invention is mixing the requisite 34o materials, in the requisite amounts, to achieve the beverage fountain syrup compositions of the present invention. Other well known and conventional variations of the above described formulation technique can, therefore, be used herein.
The following examples are given to illustrate the invention and are not intended to Limit it in any way.
3a5 EXAMPLES
A syrup composition of the present invention is prepared as follows:
Example 1 Wt-°~~
Watt 27 350 Xanthan Gum 0.1 ~~
Citric Acid 3 Sodium Citrate 0.5 Vegetable Oil 1 355 Purity Gum BE 1. l 0.5 Preservatives, 9avon, colon, vitamins 3~ 100 Method of Preparation 1. Starch and oil are added to about one fourth of the water to form an oil-in wuer emulsion. The emulsion is homogenized with a Gaulin homogenizer 365 (Model M 3).
2. Xanthan gum is dispersed and hydrated in the remaining water with good WO 96100510 219 3 ~ 0 8 PCT/US95/07770 agitation. The high fructose corn syrup is then added and mixed. The other ingredients are then added with mixing. The emulsion is then added with mixing.
37o Example 2 A syrup composition of the present invention is prepared as follows:
In i nt Wt-'/o Water 27 Xanthan Gum 0.1 Citric Acid 2.2 Sodium Citrate 0.5 Juice Concentrate 5 Vegetable Oil 0.6 3so Purity Gum BE 0.6 IVGsc.In edients 0.5 Preservatives, flavors, colors, vitamins Method of Preparation 1. Starch and oil are added to about one fourth of the water to form an oil-in-water emulsion. The emulsion is homogenized with a Gaulin homogenizer (Model M-3).
390 2. Xanthan gum is dispersed and hydrated in the remaining water with good agitation. The high fiuctose corn syrup is then added and mixed. The other ingredients are then added with mixing. The emulsion is then added with mixing.
~amPle 3 395 A syrup composition of the present invention is prepared as follows:
~3 Water 25 Xanthan Gum 0.1 40o Citric Acid 2.2 Malic Acid 1.1 Calcium Hydroxide 0.6 Juice Concentrate 5 WO 96!00510 ~ ~ 9 3 2 ~ 8 PCT/OS95/07770 Vegetable Oil 0.6 405 Purity Gum BE 0.6 Misc. Ineredients 0.5 Preservatives, flavors, colors, vitamins 1. Starch and oil are added to about one fourth of the water to form an oil-in-water emulsion. The emulsion is homogenized with a Gaulin homogenizer (Model M-3).
2. Xanthan gum is dispersed and hydrated in about one half of the water with 415 good agitation. The high fructose corn syrup is then added and mixed. The juice concentrate and miscellaneous ingredients are added and mixed.
3. Citric and malic acids are added to the remaining one fourth of the water and mixed until dissolved. The calcium hydroxide is then added and mixed until 42o dissolved. This solution is then added to the mixture from step 2 and mixed.
The emulsion is then added with mixing.
WHAT IS CLAIMED IS:
CONTAll~IING OIL PHASE AND METHOD
s OF STABILIZING FOUNTAIN SYRUP OIL PHASE
FIELD OF INVENTION
The invention relates to beverage fountain syrup compositions and a method for to stabilizing beverage fountain syrups having a dispersed oil phase and a high Brix value.
BACKGROUND OF THE INVENTION
Beverage fountain syrups are concentrated forms of beverages which can be diluted with water or carbonated water to form a single strength, ready-to-serve beverage. Beverage fountain syrups are typically utilized by fast food and restaurant 15 retail establishments. The public is most familiar with the carbonated cola beverages that are dispensed via "soda" fountains.
Currently health consciousness or awareness by the public has increased the demand for the availability of fruit and botanical juice beverages.
Particularly, parents prefer juice beverages over carbonated cola beverages for their children.
2o Juice beverages, such as the dilute juice beverage SUNNY DELIGIaT''M, heretofore have not been readily available in fast food ~ and restaurant retail establishments except in bottled or canned ready to drink forms. There is a need for juice beverages and particularly dilute juice beverages to be supplied in a beverage fountain syrup form which can be readily utilized in fountain machines.
25 Generally, single strength dilute juice beverages comprise a dispersed oil phase (sometimes referred to as an oil cloud). In single strength beverages which comprise an oil phase, thickener combinations, such as the combination of carboxymethylcellulose and xanthan gum, have been used to stabilize the oil phase, i.e., to keep the oil form separating. PCT Application No. 9308704, Burger et al., published May 13, 1993, so discloses a beverage thickener system comprising propylene glycol alginate, xanthan gum and guar gum. The thickener system provides for stable oil-in-water emulsions in beverages.
It has been discovered that in fountain syrups of dilute juice beverages having from 0.29% to about, high Brix value (generally from about 30° to about 70°), and no 35 thickener, oil will separate from the syrup and rise to the top within a few days.
Fountain syrups of dilute juice beverages having only carboxymethylcellulose or guar gum as the thickener show poor stability and separation of the oil phase occurs generally within about 35 days. Surprisingly, thickener systems that have been used for single strength beverages, and particularly dilute juice beverages, such as carboxymethyl cellulose/xanthan gum or propylene glycol alginate/guar gum/xanthan gum have also shown poor stability such that separation of the oil begins visible separation generally within from about 24 to about 70 days at 70°F (21 °C). In addition to providing poor stability of the oil phases, these conventional thickener systems can cause significant increases in the viscosities of the beverage fountain syrups which can hinder to the ability of the fountain syrups to be pumped through a typical fountain machine resulting in a viscosity of greater than about 250 centipoise at 51 sec' shear rate.
It is an aspect of an object of the present invention to provide for a method for stabilizing the oil phase of beverage fountain syrups, particularly dilute juice beverage fountain syrups, having a high Brix value.
It is an aspect of an object of the present invention to provide for beverage fountain syrups, particularly dilute juice beverage fountain syrups, which exhibit stability of the oil phase, i.e. no visible separation of the oil phase, for at least about 90 days, preferably at least about 120 days and must 2o preferably equal to or greater than about 140 days at about 21°C.
Further, it is an aspect of an object that the beverage fountain syrups, particularly dilute juice beverage fountain syrups, have good pumpability.
SUMMARY OF THE INVENTION
The present invention relates to a method for stabilizing beverage fountain syrups having a dispersed oil phase consisting essentially of incorporating into said syrups from about 0.02°/° to about 0.3°/° of a stabilizer which is xanthan gum.
The present invention further relates to a method for stabilizing 3o beverage fountain syrup compositions having from about 0.2°/°
to about 3%
of a dispersed oil phase and a Brix value of from about 30° to about 70°
B
' 21 93208 2a consisting essentially of incorporating into the syrup compositions from about 0.02% to about 0.3°/° of a stabilizer which is xanthan gum and from about s 0.2°I°-0.10°/° of an emulsifier which is a modified food starch, wherein the ratio of modified food starch to oil is from about 0.1 to about 0.4.
The present invention further relates to beverage fountain syrup compositions comprising:
a) from about 0.02°I° to about 0.3°/°, by weight, of a stabilizer to which is xanthan gum;
b) from about 0.2°/° to about 3°/°, by weight, oil;
c) from about 0.2°/° to about 10°/°, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of a flavor component;
15 e) an effective amount of sweetener; and f) from about 30°/° to about 70°I°, by weight, water;
wherein the syrup has a Brix value of from about 30° to about 70° and a modified food starch to oil ratio of from about 0.1 to about 4.
The present invention further relates to a beverage fountain syrup 2o composition comprising:
a) from about 0.05°I° to about 0.2°/°, by weight, of a stabilizer which is xanthan gum;
b) from about 0.3°I° to about 2°I°, by weight, oil;
c) from about 0.1 °I° to about 4°I°, by weight, of an emulsifier which is a 25 modified food starch;
d) an effective amount of flavor component;
e) an effective amount of sweetener; and f) from about 35°/° to about 60°/°, by weight, water;
wherein the beverage fountain syrup composition has a Brix value of from 3o about 40° to about 65° and a modified food starch to oil ratio of from about 0.2 to about 2.
~1932~~
WO 96100510 PCTIUS95l07770 DETAILED DESCRIPTION OF THE INVENTION
Definitions:
As used herein, the term "comprising" means various unnamed 75 components can be conjointly employed in the compositions of this invention Accordingly, the terms "consisting essentially of" and "consisting of" are embodied in the term comprising.
As used herein the term "fruit flavors" refers to those flavors derived from the edible reproductive part of the seed plant, especially one having a sweet pulp so associated with the seed, for example, apples, oranges, lemon, limes, etc.
Also included within the term fruit flavor are synthetically prepared flavors made to simulate fruit flavors derived from natural sources. Particularly preferred fruit flavors are the citrus flavors including orange, tangerine, lemon, lime and grapefruit flavors. A variety of other fruit flavors can be used such as apple, s5 grape, cherry, pineapple, coconut and the like. These fruit flavors can be derived from natural sources such as fruit juices and flavor oils or synthetically prepared.
If desired, fruit juices, including orange, lemon, tangerine, lime, apple and grape can be used in a flavor component.
As used herein, the term "botanical flavor" refers to flavors derived from 9o parts of the plant other than the fruit. As such, botanical flavors can include those flavors derived from nuts, bark, roots and leaves. Also included within this term are synthetically prepared flavors made to simulate botanical flavors derived from natural sources. Examples of botanical flavors include cola flavors, tea flavors, coffee and the like. These botanical flavors can be derived from natural sources 95 such as essential oils and extracts or be synthetically prepared. Coffee, black tea, and herbal tea extracts can be used as the flavorant herein.
As used herein 'single strength" refers to a single strength beverage, i.e. a ready-to-serve or consume beverage that does not require additional components such as water before consumption.
loo As used herein, the term "fruit juice" refers to citrus and non-citrus juices including vegetable juices. The fruit juice can be provided as juice made from apple, passion fruit, cranberry, pear, peach, plum, apricot, nectarine, grape, cherry, currant, raspberry, gooseberry, blackberry, blueberry, strawberry, lemon, lime, mandarin, tangerine, orange, grapefruit, potato, tomato, lettuce, celery, l05 spinach, cabbage, watercress, dandelion, rhubarb, carrot, beet, cucumber, pineapple, coconut, pomegranate, lawi, mango, papaya, banana, watermelon and cantaloupe. The term "fruit juice' also refers to water extracted soluble solids, fruit juice concxntrates, oomminutes and purees.
,,",, WO 96100510 PCTIL,'S95'07',"0 As used herein, the term "nutritionally-supplemental amount' is meant that llo the mineral and vitamin sources used in the practice of this invention provide a nourishing amount of minerals and vitamins. This is supplemental or in addition to the amount found in the average diet. This supplemental amount will provide from about 1096 to about 20096 of the Recommended Dietary Allowance (~A)_ The RDA for vitamins and minerals is as defined in the United States of America 115 (see Recommended Daily Dietary Allowance-Food and Nutrition Board, National Academy of Sciences-National Research Council).
As used herein the term 'dilute juice beverage' means a single strength, ready-to-serve beverage comprising from 096 to about SO~o, preferably from about 3 % to about 35 96 and most preferably from about 5 96 to about 10 %
fruit 120 j uice.
As used herein the term 'syrup', 'fountain syrup' or 'beverage fountain syrup' refers to a composition which when diluted with an appropriate amount of water forms a single strength beverage. Syrups as described herein are prepared at generally about five to six fold such that the syrup is diluted with four to five 12s parts water by volume to form a single strength beverage. Most people are familiar with this syrup in relation to a dispenxr that produces beverages from a mixture of syrup and watrcer such as at a convenience store.
All percentages herein are by weight unless otherwix specified.
~s~NTIAL GOMPONEN'15 OF FOUNTAIN SYRLIp Xanthan gum is an exocellular heteropolysaxharide produced by a fermentation proxss using the bacteria Xanthomonas c~nparris. Xanthan gum is a polymer with five sugar residues, two glucox units, two mannox units, and one gluctuonic acid. The backbone of the unit is a 1, 4 Iinlcrd ~i-d-glucose. This 13s backbone is identical in structure to cellulox. A reference for Xanthan structures, properties, and uses, is 'Xanthan Gum, Natural Biogum for Scientific Water Control', dth edition from Kelco, Division of Mack & Co., Inc.
Xanthan is available in a variety of particle sizes, including 80-mesh and 200-mesh, preferably 200 mesh is used. Xanthan loo gums are available from many commercial sources including Kelco, a Division of Merck Company (California) and TIC Gums. A preferred commercial product is Keltrol F from Kelco.
Xanthan gum is utilized as a stabilizer of the dispersed oil in the syrup compositions. Xanthan gum is used at levels of from about 0.02 96 to about 0.3 96 , las and preferably from about 0.0596 to about 0.296 of the syrup compositions.
* = Trade-mark .... WO 96100510 _ PC.LIZ;g9c~07' ~0 Oil is utilized in the syrup compositions to provide opacity or cloud to the single strength beverages made from the syrups. The oil produces a juice, hike appearance in the single strength dilute juice beverage. Suitable oils for use are iso oils such as vegetable oils, animal oils, synthetic oils, and mixtures thereof.
Preferred for use are vegetable oils. Preferred unhydrogenated oils arc soybean, sunflower, high oleic sunflower, safflower, cottonseed, corn, peanut, and canola oils. Partially hydrogenated oils can be used for oils requiring improved flavor stability.
is5 The oil is utilized at a level of from about 0.2 96 to about 3 % , preferably from about 0.3 % to about 2 % of the syrup composition.
The oil is typically incorporated into the composition as an oil-in-water emulsion which utilizes a modified food starch as an emulsifier. Thex are octenyl succinate modified starchy ('OSAN-starch') which arc also commonly referred to ibo as Iipophilic starches. They arc typically made by treatment with from about 296 to about 396 1-octeayl succinate anhydride. Sec 'Modified Food Starches:
Properties and Uses' Chaptu 9, O.B. Wurzburg, editor, (1986) CRC Press, Boca Baton, Florida Purity Gum BE
(National Starch) is a suitable modified food starch derived from waxy maize 16s which is commonly used as an emulsifier for beverage emulsions. Generally, the starch is utilized at from about 0.0296 to about 1096, preferably from about 0.196 to about 496, of the syrup composition. The amount of starch used depends on the particular starch utilized and the amount of oil utilized. Typically, the modified starch to oil ratio is from about 0.1 to about 4 and preferably from about 0.2 to 17o about 2.
Brominated vegetable oils and rrsin esters, in particular the ester gums, and other weighting agents are not preferred for use in the compositions. Most preferably, the syrup compositions are substantially frte of weighting agents, typically this is less than about 0.05 96 and preferably less than about 0.0196 of 175 the syrup COmpOS1t10I1.
The turbidiry of diluted beverages prepared from the syrup compositions of the present invention will generally be grt~ta~ than 200 NTU's. The range is typically from about 1000 to about 15000 NTU's as a result of the disperxd oil phase. Preferably, the turbidiry is from about 1500 to about 10000 NTU's and iso most preferably from about 2000 to about 5000 NTU's. Ttubidiry is a measure of the cloudiness or opacity of a beverage. One way of measuring turbidity is by determining how much light is scaaerai by a sample of the beverage. See 'The a ,.".. V1~'O 96100510 PCTIL; S9510?", 0 Ratio Turbidimettr', Technical Information Series - Booklet No. 10, Hach Company, Loveland Colorado. A useful instrument for doing this is the DRT
iss 100B Turbidimeter (HF Instruments, a Division of Shaban Mfg., Inc. Ft.
Myers, Florida). The measured turbidity is reported in NTU's (nephelomerric turbidiry unit. A higher number indicates a higher degree of turbidiry or cloudiness.
See "Relationship Betwetn Sensory Clarity and Turbidity Values of Apple Juice", L.
J. Malcolmson and L. Jeffrey, 1989 Can. Inst. Food Sci. Txhnol. J. 22(2); 129 Flaoor Com~ionent The particular amount of the flavor component effective for imparting flavor characteristics to the syrup compositions depends upon the flavors) selected, the flavor impression desired and the form of the flavor.
19s The flavoring system can comprise a fruit juice, a fruit flavor, a botanical flavor or mixtures thereof. In particular the combination of tea flavors, preferably green tea or black tea flavors, together with fruit juices have an appealing taste Preferred fruit juices and flail flavors are apple, pear, lemon, lime, mandarin, grapefruit, cranberry, orange, strawberry, grape, kiwi, pineapple, tangerine, 20o passion fruit, mango, guava, raspberry, and cherry. Citrus flavors and juices, preferably grapefruit, orange, lemon, lime, mandarin, tangerine and juices of mango, passion Exult, and guava, or mixtures thereof are most preferred.
The fruit flavors can be derived from nanual sources such as fruit juices and flavor oils, or else be synthetically prepared.
Zos The flavor compoaent can also comprise a blend of various flavors, e.g.
lemon and lime flavors, citrus flavors and selected spices (the typical cola soft drink flavor). Mixttuzs of flavors and juices can be used.
The syrup compositions of the present invention are preferably formulated such that upon dilution a dilute juice beverage is formed which comprises from 210 096 to about 5096, preferably from about 396 to about 3596, and most preferably from about 596 to about 1096 fruit juice. For example, a preferred syrup composition which will provide 596 orange juice in the diluted beverage can comprise fmm about 4 96 to about 5 96 orange juice concentrate having a Brit of 60° or from about 2096 to about 2596 orange juice. One skilled in the art is Zls familiar and able of determining the requisite amount of juice, cancentrate or puree needed in the syrup to achieve a particular targeted dilute beverage concentration.
Syrup compositions of the present invention which are substantially free of fruit juice typically comprise flavor components which are no more than about 219 3 ?__ ~ 8 PCTIUS95I07770 220 15 % of the syrup, preferably such flavor component comprises at least 0.004 % of the beverage, and typically from about 0.04 % to about 10 ~o , and preferably from about 0.1 % to about 0.4 ~'o of the beverage.
Sweetener The syrup compositions of the present invention contain a sweetener in an 225 amount sufficient to provide the desired flavor and texture. The syrup composition preferably comprises a carbohydrate sweetener.
The carbohydrate sweetener is preferably a mono- and or disaccharide sugar such as maltose, lactose, galactose, sucrose, glucose, fructose, invert sugars and mixtures thereof. Especially preferred is fructose. All of these sugars are 2so typically incorporated into the syrup compositions as "syrups" (sugar dissolved or slurried in water), but they can likewise be incorporated in other forms, e.g.
solid form. These sugars are also provided to some extent by other added materials in the compositions such as fruit juice, optional flavorants, and the Iike.
Fructose for use in the beverage product can be provided as liquid fructose, 2s5 high fructose corn syrup, dry fructose or fructose syrup; it is preferably provided as high fructose corn syrup wherein at least about 42 % by weight of the solids in the syrup are fructose. Preferred fructose sources are high fructose corn syrups wherein 42 % of the solids in the syrup are fructose (HFCS 42), high fructose corn syrup wherein 55 % of the solids in the syrup are fructose (HFCS 55), and liquid 2ao fructose (contains 99 % fructose solids), all of which are available from A.E.
Staley Manufacturing, Decatur, Illinois.
Sugar alcohols can also be used in the syrup compositions of the present invention. These sugar alcohols include sorbitol, mannitol, and xylitol.
Usually, however, these materials are not used as the sole sweetener because in the levels 2as required to sweeten beverages, they have a side effect of flatulence or related gastrointestinal related problems.
For diet syrup compositions, non-caloric sweeteners can be used as long as the Brix is not lowered below about 30 ° . Thus, mixtures of non-caloric and caloric sweeteners are preferred. Mixtures of carbohydrates, low calorie 2so sweeteners and artificial sweeteners can also be used in the present invention, i.e., a mixture of aspartame and sucrose or high fructose corn syrup can be used.
Examples of such sweeteners . include aspartame, saccharine, cyclamates, acetosulfam-K, L-aspariyl-L-phenylalanine lower alkyl ester sweeteners, L-a.spartyl-D-alanine amides as disclosed in U.S. patent 4,411,925 to Brennan, et al 255. (1983), L-aspartyl-D-serine amides disclosed in U.S. 4,399,163 to Brennan et al (1983), L-aspartyl-hydroxymethylalkane amide sweeteners disclosed in U.S.
WO 96/00510 2 l 9 3 2 ~ ~ PCT/US95107770 4,338,346 issued to Brand (1982), L-aspartyl-1-hydroayethylalkane amide sweeteners disclosed in U.S. 4,423,029 to Rizzi (1983), glycerins, synthetic alkoxy aromatics, etc. Lo Han Guo juice which contains a natural sweetener can 26o also be used as a sweetener.
The amount of sweetener effective in the syrups of the present invention depends upon the particular sweeteners used and the sweetness intensity desired.
Preferred syrup compositions comprise from about 30 W to about 70 % by weight sugar. In determining the amount of sugar of the present invention, any sugar or 2s5 other sweetener present in the flavor component, such as fruit juice, is also included.
For carbohydrates or sugars, the amount of sweetener can be from about 30 % to about 70 % , and preferably from about 40 9~ to about 65 % by weight for the syrup compositions. The amount for artificial sweeteners generally ranges 27o from about 0.001 % to about 29~, preferably from about 0.019b to about 0.1 ~.
Syrup compositions of the present invention have a Brio value of from about 30° to about ?0°, preferably from about 40° to about 65° and most preferably from about SO° to about 60°.
Added Water 275 Sufficient water is utilized to achieve the desired syrup concentration and Brix value. Water comprises from about 30 % to about 70 % , preferably from about 35 % to about 60 % and most preferably from about 40 ~% to about 50 % , of the syrup compositions. Water as used herein includes water from all sources, e.g., juice and sweetener.
2so Acidi The syrup compositions of the present invention have a pH of from about 2.5 to about 4.5, preferably from about 2.7 to about 3.5. Calcium fortified syrup compositions typically have higher pH levels of from about 2.5 to about 4.5 and preferably from about 3 to about 4. This pH range is typical for non-carbonated 285 dilute juice beverage products. The acidity can be adjusted to and maintained within the requisite range by known and conventional methods, e.g., the use of food grade acid buffers. Generally, citric, malic, phosphoric, fumaric, lactic and acetic acids are added and/or their salts, e.g., sodium citrate and potassium citrate. For non-carbonated beverages, citric acid is preferred. For calcium fortified beverages, citric 29o and malic acids are preferred. Typically, the acidity within the above recited ranges is a balance between maximum acidity for microbial inhibition and optimum acidity for the desired beverage flavor and sourness impression.
~~- 21 ~3~08 WO 96100510 PCTlUS95/07770 OPTIONAL COMPON
The syrup composition can additionally comprise from 0f~ to about 1109 295 of the U.S. RDA of vitamins and minerals such that the vitamins and minerals are chemically and physically compatible with the essential elements of the beverage composition. Especially preferred are Vitamin A, and provitamins thereof (beta carotene), Vitamins C, D, E, B1, B6, B12, niacin, pantothenic acid, folic acid biotin, thiamin, calcium, magnesium, potassium, sodium, iron, zinc and mixtures 30o thereof. Other optional ingredients are preservatives such as benzoic acid, sorbic acid and salts thereof, and natural and synthetic colors.
Viscosi The viscosities of the syrup compositions will generally be no more than about 250 centipoise, more preferably no more than about 200 centipoise and most 305 preferably no more than about 150 centipoise, at 70°F(21°C) and at a shear rate of 51 sec -1 as measured with a Brookfield viscometer Model DV-III with coaxial cylinders such as spindle #31 or #34 and chamber 13R
Method of Stabilizing Oil in Syrun Compositions The present invention also relates to a method for providing stability of the oil 31o phase in beverage fountain syrups by the addition of xanthan gum without the use of other stabilizerslthickeners, such as carboxymethylcellulose, guar gum, propylene glycol alginate, or mixtures thereof. Typically, this method provides for stability from separation of the oil phase from beverage fountain syrups comprising from about 0.2% to about 3%, preferably from about 0.3% to about 2%, oil and having a 315 Brix value of from about 30° about 70°, preferably from about 40° to about 65° and most preferably from about 50° to about 60°. The method consists essentially of incorporating into said syrups from about 0.02% to about 0.3%, preferably from about 0.05% to about 0.2%, of a stabilizer which is xanthan gum.
The method provides for syrup compositions which exhibit stability of the 32o dispersed oil phase, i.e., no visible separation of the oil phase, for at least about 90 days, preferably at least about 120 days and most preferably equal to or greater than about 140 days at about 21°C.
The syrup compositions preferably have a modified food starch to oil ratio of from about 0.1 to about 4 and preferably from about 0.2 to about 2.
325 Svruo Composition Preparation The syrup compositions of the present invention can be prepared by conventional formulation techniques.
A method for preparing the beverage fountain syrup compositions herein is described as follows: 1. Added to water are the starch emulsifier and the oil to form WO 96100510 PC'T/Z;S95%07','0 1° 2193208 33o a water-in-oil emulsion. The emulsion is homogenized for a sui~cient period of time to form the emulsion. 2. Added to water with mixing are the stabilizer, sweetener, and flavor component as well as any optional components such as preservatives.
3.
The emulsion of 1 is then add to the slurry of 2 with mixing.
Calcium fortified beverage fountain syrups can be made and are encompassed 335 by the present invention. Methods for making natural and manufarnued calcium containing beverages, for example are described in U.S. 4,737,375 to Nakel et.
al., U.S. 4,830,862 to Braun et al. and U.S. 4,722,847 to Heckert et. al.
The key aspect of the process of the present invention is mixing the requisite 34o materials, in the requisite amounts, to achieve the beverage fountain syrup compositions of the present invention. Other well known and conventional variations of the above described formulation technique can, therefore, be used herein.
The following examples are given to illustrate the invention and are not intended to Limit it in any way.
3a5 EXAMPLES
A syrup composition of the present invention is prepared as follows:
Example 1 Wt-°~~
Watt 27 350 Xanthan Gum 0.1 ~~
Citric Acid 3 Sodium Citrate 0.5 Vegetable Oil 1 355 Purity Gum BE 1. l 0.5 Preservatives, 9avon, colon, vitamins 3~ 100 Method of Preparation 1. Starch and oil are added to about one fourth of the water to form an oil-in wuer emulsion. The emulsion is homogenized with a Gaulin homogenizer 365 (Model M 3).
2. Xanthan gum is dispersed and hydrated in the remaining water with good WO 96100510 219 3 ~ 0 8 PCT/US95/07770 agitation. The high fructose corn syrup is then added and mixed. The other ingredients are then added with mixing. The emulsion is then added with mixing.
37o Example 2 A syrup composition of the present invention is prepared as follows:
In i nt Wt-'/o Water 27 Xanthan Gum 0.1 Citric Acid 2.2 Sodium Citrate 0.5 Juice Concentrate 5 Vegetable Oil 0.6 3so Purity Gum BE 0.6 IVGsc.In edients 0.5 Preservatives, flavors, colors, vitamins Method of Preparation 1. Starch and oil are added to about one fourth of the water to form an oil-in-water emulsion. The emulsion is homogenized with a Gaulin homogenizer (Model M-3).
390 2. Xanthan gum is dispersed and hydrated in the remaining water with good agitation. The high fiuctose corn syrup is then added and mixed. The other ingredients are then added with mixing. The emulsion is then added with mixing.
~amPle 3 395 A syrup composition of the present invention is prepared as follows:
~3 Water 25 Xanthan Gum 0.1 40o Citric Acid 2.2 Malic Acid 1.1 Calcium Hydroxide 0.6 Juice Concentrate 5 WO 96!00510 ~ ~ 9 3 2 ~ 8 PCT/OS95/07770 Vegetable Oil 0.6 405 Purity Gum BE 0.6 Misc. Ineredients 0.5 Preservatives, flavors, colors, vitamins 1. Starch and oil are added to about one fourth of the water to form an oil-in-water emulsion. The emulsion is homogenized with a Gaulin homogenizer (Model M-3).
2. Xanthan gum is dispersed and hydrated in about one half of the water with 415 good agitation. The high fructose corn syrup is then added and mixed. The juice concentrate and miscellaneous ingredients are added and mixed.
3. Citric and malic acids are added to the remaining one fourth of the water and mixed until dissolved. The calcium hydroxide is then added and mixed until 42o dissolved. This solution is then added to the mixture from step 2 and mixed.
The emulsion is then added with mixing.
WHAT IS CLAIMED IS:
Claims (9)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A method for stabilizing beverage fountain syrup compositions having from about 0.2% to about 3% of a dispersed oil phase and a Brix value of from about 30° to about 70° consisting essentially of incorporating into said syrup compositions from about 0.02% to about 0.3% of a stabilizer which is xanthan gum and from about 0.2%-0.10% of an emulsifier which is a modified food starch, wherein the ratio of modified food starch to oil is from about 0.1 to about 0.4.
2. The method of claim 1 wherein the syrup composition comprises a modified food starch and has a modified food starch to oil ratio of from about 0.2 to about 2.
3. The method of claim 2 whereby the method provides for syrup compositions which exhibit stability of the oil phase for at least about 90 days.
4. A beverage fountain syrup composition comprising:
a) from about 0.02% to about 0.3%, by weight, of a stabilizer which is xanthan gum;
b) from about 0.2% to about 3%, by weight, oil;
c) from about 0.02% to about 10%, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of a flavor component;
e) an effective amount of sweetener; and f) from about 30% to about 70%, by weight, water;
wherein said beverage fountain syrup composition has a Brix value of from about 30° to about 70° and a modified food starch to oil ratio of from about 0.1 to about 4.
a) from about 0.02% to about 0.3%, by weight, of a stabilizer which is xanthan gum;
b) from about 0.2% to about 3%, by weight, oil;
c) from about 0.02% to about 10%, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of a flavor component;
e) an effective amount of sweetener; and f) from about 30% to about 70%, by weight, water;
wherein said beverage fountain syrup composition has a Brix value of from about 30° to about 70° and a modified food starch to oil ratio of from about 0.1 to about 4.
5. A composition according to claim 4 wherein said beverage fountain syrup composition has a pH of from about 2.5 to about 4.5.
6. A composition according to claim 4 wherein said beverage fountain syrup composition exhibits stability of the oil phase for at least about 90 days.
7. A composition according to claim 6 wherein said beverage fountain syrup composition has a viscosity of no more than about 250 centipoise.
8. A beverage fountain syrup composition comprising:
a) from about 0.05% to about 0.2%, by weight, of a stabilizer which is xanthan gum;
b) from about 0.3% to about 2%, by weight, oil;
c) from about 0.1% to about 4%, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of flavor component;
e) an effective amount of sweetener; and f) from about 35% to about 60%, by weight, water;
wherein said beverage fountain syrup composition has a Brix value of from about 40° to about 65° and a modified food starch to oil ratio of from about 0.2 to about 2.
a) from about 0.05% to about 0.2%, by weight, of a stabilizer which is xanthan gum;
b) from about 0.3% to about 2%, by weight, oil;
c) from about 0.1% to about 4%, by weight, of an emulsifier which is a modified food starch;
d) an effective amount of flavor component;
e) an effective amount of sweetener; and f) from about 35% to about 60%, by weight, water;
wherein said beverage fountain syrup composition has a Brix value of from about 40° to about 65° and a modified food starch to oil ratio of from about 0.2 to about 2.
9. A composition according to claim 8 wherein said beverage fountain syrup composition exhibits stability of the oil phase for at least about 120 days.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26809694A | 1994-06-28 | 1994-06-28 | |
| US08/268,096 | 1994-06-28 | ||
| PCT/US1995/007770 WO1996000510A1 (en) | 1994-06-28 | 1995-06-19 | Stable beverage fountain syrups containing oil phase and method of stabilizing fountain syrup oil phase |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2193208A1 CA2193208A1 (en) | 1996-01-11 |
| CA2193208C true CA2193208C (en) | 2000-02-29 |
Family
ID=23021455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002193208A Expired - Lifetime CA2193208C (en) | 1994-06-28 | 1995-06-19 | Stable beverage fountain syrups containing oil phase and method of stabilizing fountain syrup oil phase |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5624698A (en) |
| EP (1) | EP0767613B1 (en) |
| JP (1) | JP3534767B2 (en) |
| CN (1) | CN1075716C (en) |
| AT (1) | ATE178762T1 (en) |
| AU (1) | AU2866295A (en) |
| CA (1) | CA2193208C (en) |
| DE (1) | DE69509090T2 (en) |
| MX (1) | MX9606680A (en) |
| WO (1) | WO1996000510A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5126158A (en) * | 1990-08-07 | 1992-06-30 | Pepsico Inc. | Beverage compositions comprising a dipetide sweetener, saccharin salt and hydrocolloidal polysaccharide |
| US5855948A (en) * | 1995-03-02 | 1999-01-05 | Robinsons Soft Drinks Limited | Drink compositions utilizing gelatinised starch and method of making |
| CN1086282C (en) * | 1995-12-15 | 2002-06-19 | 普罗克特和甘保尔公司 | Beverages having stable flavor/cloud emulsions in presence of polyphosphates-contg. preservative systems and low levels of xanthan gum |
| AT2501U1 (en) * | 1997-08-18 | 1998-12-28 | Atb & G Frenkenberger | METHOD FOR PRODUCING A FRUIT JUICE BASED BEVERAGE |
| US6387418B1 (en) | 1999-04-19 | 2002-05-14 | Stewart And Lynda Resnick Revocable Trust | Pomegranate extracts and methods of using thereof |
| US6641850B1 (en) | 1999-04-19 | 2003-11-04 | Stewart And Lynda Resnick Revocable Trust | Methods of using pomegranate extracts for causing regression in lesions due to arteriosclerosis in humans |
| US7727563B2 (en) | 1999-04-19 | 2010-06-01 | Pom Wonderful, Llc | Methods of using pomegranate extracts for treating diabetes related atherosclerotic complications in humans |
| US8372454B2 (en) * | 1999-04-19 | 2013-02-12 | Pom Wonderful Llc | Methods of making pomegranate compounds for the treatment of erectile dysfunction |
| WO2001037848A1 (en) * | 1999-11-29 | 2001-05-31 | Rimonest Ltd. | Mixture of pomegranate seed oil and juice products |
| EP1155043A1 (en) * | 1999-12-23 | 2001-11-21 | Cerestar Holding B.V. | Stabilized cyclodextrin complexes |
| JP4132691B2 (en) * | 2001-02-19 | 2008-08-13 | サントリー株式会社 | Mango juice processed products and beverages using the same |
| ES2312543T3 (en) * | 2001-02-27 | 2009-03-01 | San-Ei Gen F.F.I., Inc. | CARBON DRINKS. |
| US20040062845A1 (en) * | 2001-11-30 | 2004-04-01 | Krawczyk Gregory R. | Beverage emulsion stabilizer |
| JP2006516995A (en) * | 2003-01-31 | 2006-07-13 | シンプリー スィック，リミティド ライアビリティー カンパニー | Improved thickening beverage for dysphagia |
| US8153180B2 (en) | 2005-09-06 | 2012-04-10 | Pepsico, Inc. | Method and apparatus for making beverages |
| US20080058418A1 (en) * | 2006-09-06 | 2008-03-06 | The Coca-Cola Company | Stable polyunsaturated fatty acid emulsions and methods for inhibiting, suppressing, or reducing degradation of polyunsaturated fatty acids in an emulsion |
| US20090018186A1 (en) * | 2006-09-06 | 2009-01-15 | The Coca-Cola Company | Stable beverage products comprising polyunsaturated fatty acid emulsions |
| EP2005845A1 (en) * | 2007-06-22 | 2008-12-24 | Döhler GmbH | Disperse base material |
| US8263140B1 (en) | 2008-04-16 | 2012-09-11 | Pom Wonderful, Llc | Pomegranate based skin protectant and topical application |
| CN102366132A (en) * | 2010-12-22 | 2012-03-07 | 东莞市百味佳食品有限公司 | Concentrated orange juice and manufacturing method thereof |
| US8623433B1 (en) | 2011-01-07 | 2014-01-07 | Innovitamin Organics, Llc | Safflower oil emulsion as dietary supplement and preparation thereof |
| US20140178535A1 (en) * | 2012-12-20 | 2014-06-26 | Tate & Lyle Ingredients Americas Llc | Coating compositions for consumable articles |
| US9907325B2 (en) | 2015-03-06 | 2018-03-06 | Kraft Foods Group Brands Llc | Encapsulated weighting agents for beverage emulsions |
| JP7129193B2 (en) * | 2018-03-29 | 2022-09-01 | アサヒ飲料株式会社 | Beverage, method for producing beverage, and method for improving dispersion stability of essential oil in beverage |
| US20220387436A1 (en) * | 2018-08-30 | 2022-12-08 | Techmix, Inc. | Bovine supplement for neonatal calves |
| US11298357B2 (en) * | 2018-08-30 | 2022-04-12 | Techmix, Llc | Bovine supplement for neonatal calves |
| EP4075989A1 (en) * | 2019-12-19 | 2022-10-26 | Purac Biochem B.V. | Method of preparing a preserved fruit composition |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4163807A (en) * | 1978-03-15 | 1979-08-07 | Merck & Co., Inc. | Citrus fruit juice and drink |
| US4216243A (en) * | 1978-10-12 | 1980-08-05 | Kraft, Inc. | Yogurt beverage and method for manufacture thereof |
| US4235936A (en) * | 1979-03-26 | 1980-11-25 | Rich Products Corporation | Soft intermediate-moisture frozen beverage concentrates |
| US4332824A (en) * | 1979-03-26 | 1982-06-01 | Rich Products Corporation | Intermediate-moisture frozen foods |
| US4433000A (en) * | 1980-11-19 | 1984-02-21 | Coca Cola Company | Method for preventing separation in fruit juice-containing products |
| US4528205A (en) * | 1984-01-09 | 1985-07-09 | Lever Brothers Company | Low calorie syrup |
| FR2581515B1 (en) * | 1985-05-07 | 1991-01-18 | Polive Wuhrlin Sa Laboratoires | PROCESS FOR INCORPORATING A LOW-WATER-SOLUBLE HYGROSCOPIC SUBSTANCE, IN PARTICULAR ASPARTAME, IN A SUGAR-BASED FOOD PRODUCT |
| US4705691A (en) * | 1985-11-18 | 1987-11-10 | The Procter & Gamble Co. | Beverage opacifier |
| US4722847A (en) * | 1986-05-07 | 1988-02-02 | The Procter & Gamble Company | Fruit juice beverages and juice concentrates nutritionally supplemented with calcium |
| GB8820811D0 (en) * | 1988-09-05 | 1988-10-05 | Cerestar Holding Bv | Flavour compositions |
| US4986994A (en) * | 1989-04-21 | 1991-01-22 | The Southland Corporation | Process for making a low calorie beverage |
| US5069924A (en) * | 1989-04-21 | 1991-12-03 | The Southland Corporation | Low calorie beverage |
| JPH0724560B2 (en) * | 1990-06-01 | 1995-03-22 | 株式会社ヤクルト本社 | Beverage containing plant extract |
| CH681343A5 (en) * | 1990-10-26 | 1993-03-15 | Nestle Sa | |
| EP0610341B1 (en) * | 1991-10-28 | 1996-09-18 | The Procter & Gamble Company | Beverage thickener/emulsifier system |
-
1995
- 1995-06-19 MX MX9606680A patent/MX9606680A/en unknown
- 1995-06-19 WO PCT/US1995/007770 patent/WO1996000510A1/en active IP Right Grant
- 1995-06-19 AU AU28662/95A patent/AU2866295A/en not_active Abandoned
- 1995-06-19 CA CA002193208A patent/CA2193208C/en not_active Expired - Lifetime
- 1995-06-19 DE DE69509090T patent/DE69509090T2/en not_active Expired - Lifetime
- 1995-06-19 CN CN95194135A patent/CN1075716C/en not_active Expired - Lifetime
- 1995-06-19 JP JP50327296A patent/JP3534767B2/en not_active Expired - Lifetime
- 1995-06-19 AT AT95923974T patent/ATE178762T1/en not_active IP Right Cessation
- 1995-06-19 EP EP95923974A patent/EP0767613B1/en not_active Expired - Lifetime
- 1995-12-12 US US08/587,597 patent/US5624698A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0767613A1 (en) | 1997-04-16 |
| DE69509090D1 (en) | 1999-05-20 |
| AU2866295A (en) | 1996-01-25 |
| WO1996000510A1 (en) | 1996-01-11 |
| EP0767613B1 (en) | 1999-04-14 |
| CA2193208A1 (en) | 1996-01-11 |
| MX9606680A (en) | 1997-03-29 |
| JPH10501988A (en) | 1998-02-24 |
| CN1075716C (en) | 2001-12-05 |
| CN1152859A (en) | 1997-06-25 |
| US5624698A (en) | 1997-04-29 |
| JP3534767B2 (en) | 2004-06-07 |
| ATE178762T1 (en) | 1999-04-15 |
| DE69509090T2 (en) | 1999-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2193208C (en) | Stable beverage fountain syrups containing oil phase and method of stabilizing fountain syrup oil phase | |
| US20200236976A1 (en) | Preparation and Incorporation of Co-Products into Beverages to Enhance Nutrition and Sensory Attributes | |
| AU730121B2 (en) | Vitamin preparations for beverage applications | |
| US4988530A (en) | Soluble dietary fiber fortified beverage | |
| JP3311350B2 (en) | Beverage thickener / emulsifier system | |
| US4612205A (en) | Carbonated juice beverage with cola taste | |
| CA2779122C (en) | Thick juice beverages | |
| US20170119024A1 (en) | Preparation and incorporation of co-products into beverages to achieve metabolic and gut health benefits | |
| WO2018132260A1 (en) | Preparation and incorporation of co-products into beverages to achieve metabolic and gut health benefits | |
| CA1298135C (en) | Carbonated juice beverage with cola taste | |
| MXPA98004779A (en) | Drinks which have stable flavor emulsions / turbies in the presence of conservative systems containing polyphosphate and low rubber levels of xant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20150619 |