CA2194238A1

CA2194238A1 - Wettable polyolefin fiber compositions and method

Info

Publication number: CA2194238A1
Application number: CA002194238A
Authority: CA
Inventors: Paresh J. Sheth
Original assignee: Individual
Current assignee: Lyondell Chemical Co
Priority date: 1994-07-12
Filing date: 1995-06-13
Publication date: 1996-01-25
Also published as: US5614574A; AU2827295A; AU695499B2; EP0770152A4; CN1157642A; BR9508277A; JPH10502687A; EP0770152A1; WO1996001916A1

Abstract

Compositions of polyolefin, a polar group material and a hydrophilic modifier are provided. The polyolefin is preferably isotactic polypropylene. The polar group material is acrylic acid or maleic anhydride or an ethylene/alkyl acrylate copolymer. The hydrophilic modifier comprises a monoglyceride and a salt of a linear alkyl phosphate. The compositions provide highly wettable, spinnable fibers for diaper coverstock, personal hygiene pads, battery separators, filters and tea bag pouches.

Description

WO9C/01916 21 94238 PCIIUS95107~22 WETTABLE POLYOLEFIN F~BER COM:POSmONS AND METEIOD

Field of the Invention The present invention relates to a formulation and method for i-,-pa,ling both wetting and spreading characteristics to polyolefin containing fibers and nonwoven m~teri~l~. More particularly, the invention is directed to a fiber co-l.l)o~i~ion 5 comprising polypropylene, a polar m~t~ri~l such as an ethylene copolymer, and a hydrophilic modifier compri~in~ a monoglyceride and long chain hyd~oc~luon with a hydrophilic group.

Background of the Invention The manufacture and various uses of polyolefin-based fibers and corresponding 10 nonwoven materials are well known in the textile art. Attempts to apply such knowledge to produce products in the area of personal hygiene, such as cover stocks for c~t~meni~l devices, disposable diapers, and incontinence pads, have met withIimited success. Such products must have a fluid-absorbent core, usually comprising one or more layers of fluid absorbent material such as wood pulp, gauze, or tissue 15 and, in some cases, synthetic hydrophilic material, such as hydrophilic polyurethane foam.
The fluid-absorbing material is typically provided in the form of a thermally bonded pad. To protect the clothing or areas around the user from being stained or wetted by fluids absorbed by the pad, the pad may be backed by a fluid impervious 20 barrier sheet. The absorbent product is typically positioned against the body with the hydrophilic material facing and contacting the body and the fluid impervious barrier layer facing the outside. To enhance a sense of comfort, such absorbent products also generally employ a facing or cover stock material which covers the body-facing surface of the product. The facing or cover stock must be very pervious to fluids on 25 the side of the product that is placed against the body, and yet be essentially nonabsorbent. Such material should also feel smooth and soft to the touch. In addition, certain additional characteristics are also sometimes desired, such as visual opacity, specific coloring, and luster on the outer surfaces.
In order to obtain many of above-listed characteristics, a cover stock utilizing30 essentially hydrophobic polymeric material, such as polyolefin fiber or film, may be 21 ~4233 WO 96/01916 PCI/llS9StO7522 -made at least temporarily hydrophilic yet have the continuin~ ability to pass aqueous fluids through. This is particularly impo~tant in the case of diaper cover stock so as to avoid lateral liquid migration and side leakage without interfering with fabric bonding steps or wet strength of the final product.
Based on the t~ching in the paper-making art, it is known that short term llydlophilicity can be illlpa.led to hyd~o~hobic polymers such as polyolefin fiber by using flash evaporation techniques and treating the resulting fiber or fil~m~nt with hydrophilizing agents such as polyvinyl alcohol or various nitrogen-cont~ining water-soluble polymers. Efforts to incorporate an alkoxylated alkylphenols or corresponding polyoxyalkylenes into spun melt fiber compositions are disclosed in U.S. Patent No. 4,578,414.
U.S. Patent No. 5,033,172 discloses that the hydrophilicity and liquid strike through properties of fiber can be retained for an e~tended period by incorporating into the polyolefin composition an effective amount of a modifier composition. In U.S. Patent No. 4,853,290, a blend of ethylene-acrylic acid copolymer and ethylene-methylacrylate copolymer is coextruded onto a polypropylene film. U.S.
Patent Nos. 3,373,222 and 3,373,223 disclose polymeric blends comprising a polyolefin resin, a polyamide resin, and either a carboxylated polyethylene, an ethylene-acrylic or a methacrylic acid copolymer. U.S. Patent No. 5,033,172 discloses a hydrophobic polyolefin con~ining nonwoven m~tP~l which may contain up to 60% by weight of a particular modifier composition.
U.S. Patent Nos. 4,540,414 and 4,550,725 disclose a nonwoven polypropylene fabric designed for removal of moisture from the skin of a human being covered by the fabric. U.S. Patent Nos. 4,372,310, 4,892,532 and 4,892,534 disclose particular arrangements of liquid absorbing fabrics and fabric layers suitable for forming a diaper material. U.S. Patent No. 4,804,378 discloses a material suitable for forming a sheet having a hydrophilic surface and a hydrophobic inside. European Patent Publication Nos. 0307116 and 0192965 disclose both porous films and absorbent layers for various sanitary articles.
The prior art does not disclose compositions for forming a highly wettable polyolefin, and particularly a highly wettable polypropylene. Substantially increased acceptance of polypropylene as a suitable nonwoven fabric for various incontinent ~ WO96/01916 21 q4238 P~ ss~ 2 products ~ uil~ s increased wettability of the polypropylene. Moreover, the pol.~ lene co~ osilion should be easily formed as a fiber which is spinnable, and ideally may be formed into a fabric sheet including nonwoven fibers.

Summary of the Invention A novel polyolefin fiber comprises about 98 to 70% by weight of a polyolefin and a selected amount of a polar group material, such as an ethylene copolymer, a maleic anhydride, or an acrylic acid, and a hydrophilic modifier comprising a monoglyceride and a salt of a linear alkyl. The ethylene copolymer may comprise about 70 to 82% by weight ethylene and about 30 to 18% by weight of an alkyl acrylate relative to the sum of the polypropylene and ethylene copolymer, wherein the alkyl has one to four carbon atoms, said alkyl acrylate present in an amount 0.2 to 3.0% by weight. The hydrophilic modifier may comprise a fused combination of a monoglyceride and a linear alkyl phosphate. This modifier is present in an amount of less than 2% by weight, and preferably between 0.1% and 2.0% by weigpt, the sum of the polypropylene and ethylene copolymer.
A novel process for forming fibers based on polypropylene comprises combining isotactic polypropylene with a polar group material and a selected hydrophilic modifier. The polar group material may be ethylene copolymer of about 70 to 82% by weight ethylene and about 30 to 18% by weight of an ethylene alkyl acrylate wherein the alkyl group has one to four carbon atoms. Alternatively, the polar group material may be a maleic anhydride or an acrylic acid. The hydrophilic modifier may be present in an amount between 0.1% and 2.0% by weight, and preferably between 0.4% and 1.0% by weight, the sum of the polypropylene and ethylene copolymer. The composition may be extruded into a fiber which are commercially spinnable.
The polyolefin in these compositions and processes preferably is isotactic polypropylene. In the processes, the composition may be a blend or one in which at least a portion of the ethylene copolymer is grafted onto said polyolefin. The ethylene copolymer in the compositions include ethylene methyl acrylate, ethylene ethyl acrylate, and ethylene butyl acrylate.

WO 96/01916 2 1 9 4 2 3 8 PCT~S9s/07s22 -It is an object of the present invention to provide an improved inert hydrophobic polyolefin-co~t~inin~ nonwoven composition with desired wettability char~rteri.cties .
It is a further object of the present invention to provide an improved S polyolefin-cont~ining web comrrise~ of fibers, or a nonwoven or fibr~ ted film suitable as cover stock for various sanitary products.
Still another ob.iect is to obtain and retain high hydrophilicity and liquid str;ke-through p-o~ ies in a strong well bonded nonwoven hydrophobic m~t~ri~l, inclu~ing continl'ous and/or staple fibers utili7ing polyolefin components.
It is a significant feature of this invention that the polypropylene- based m~teri~l may be used to form fibers having applications for either woven m~teri~ls or nonwoven m~teri~l.c, and that the fibers are spinnable at commercially acceptable rates.
Yet another feature of the invention is that a polypropylene-based material may 15 be efficiently modified to form a material having a wettability contact angle of less than about 80~.
An advantage of the invention is that the wettable polyolefin m~t~.ri~l acc~rding to this invention is more easily dyeable than prior art polyolefin fiber m~ter~ls.

20 Brief Description of the Drawings Figure 1 is a sch~-m~tic ,~l~senL~tion of a liquid drop at an equilibrium state on a solid surface.
Figure 2 illustrates in cross-section a portion of a diaper which includes nonwoveri web material having a polyolefin composition according to the present 25 invention. The diaper also includes an absorbent material core, a facing sheet, and a backing sheet.
Figure 3 illustrates a cross-sectional view of a web m~t~.n~l for forming a filter including a polyolefin composition according to the present invention.

WO96/01916 21 94238 P~ 5S/v7522 -_ 5 _ Detailed Desoliplion of the Invention Polyolefins useable in accordance with this process are crystalline polyethylene, polypropylene, or copolymers thereof, having melt indices in the range from about 0.1 to about 80 g/10 min. The most important polyolefin for use in S formation of fibers at this time is isotactic polypropylene, which is commercially avaiIable from many sources. The polypropylene can contain the usual thermal, oxidative and ultraviolet light stabilizers.
The fiber forming cG.~position may comprise polypropylene and a copolymer of ethylene and an alkyl acrylate having 2 to 30% by weight, suitably 2 to 15%, 10 preferably 4 to 10%, most preferably about 7%. Alternatively, and in accol~allce with this invention, the copolymer of ethylene and an alkyl acrylate is grafted onto the polypropylene, and the composition may include both grafted and blended ethylene alkyl acrylate copolymer. An advantage of the ethylene alkyl acrylate copolymer is that it is both thermoplastic and compatible with polypropylene so that 15 ~rucessing difficulties are minimi7~d or prevented. By the term compatible is meant that the copolymer does not se~a,dte into discrete particles in the polypropylene composition which are observable under an optical microscope at a m~nification of times 250 - 500.
The ethylene copolymer comprising ethylene and an alkyl acrylate in the 20 compositions used in this invention include ethylene methyl acrylate, ethylene ethyl acrylate, and ethylene butyl acrylate. Ethylene methyl acrylate copolymer ("EMA") alone or in blends has been used in film, extrusion coating, sheet, molding, tubing, profile extrusion and coextrusion areas. Compared to low density polyethylene homopolymer, it has a lower softening ~.,-~-dture (138~F), a reduced flexural 25 modulus, and improved environmental stress crack resistance. It is thermally stable and can be processed at extrusion coating temperatures of 600~F to 630~F. Ethylene copolymer has been disclosed for use as a blending component with low density polyethylene, polypropylene, polyester, and polycarbonate to improve impact strength and toughness, to increase heat seal response and promote adhesion, to reduce 30 stiffness, and to increase the surface coefficient of friction. Modern Plestics, Mid-October Encyclopedia Issue, 1991, pp. 71-72.

WO96/01916 2 ! 9 4 2 3 8 pCT~S95/07s22 -Ethylene ethyl acrylate copolymer (nEEAn) resins are tough, flexible copolymers that have found application in profile extrusion specialty hose and tubing appli~tionc, ~ck~in~, and bumpers; film appli~ationc include disposable ey~min~tion gloves for doctors and den~istc, balloons, etc. EEA has been used for hot melt adhesives. As the ethylacrylate content of EEA increases, the copolymers become more flexible, tougher, and more re-silipnt The polarity of high ethylacrylate resins is said to enh~nce surface acceptance of inks and provide adhesive l~lope Lies.
Modern Plastics, Mid-October Encyclopedia Issue, 1991, pp. 71-72.
Ethylene butyl acrylate ("EBA") is used for low melt-index films. It produces a tough film at low telllpel~tures and is employed mainly in the p~ck~gin~ of frozen foods. Modern Plastics, Mid-October Encyclopedia Issue, 1991, p. 68.
Particularly pl~r~lled copolymers are the ethylene methyl acrylate random copolymers of ethylene and methylacrylate and the ethylene ethyl acrylate randomcopolymers of ethylene and ethylacrylate. The EMA copolymers preferably contain about 20% to 24% and preferably about 20% by weight of methylacrylate. The EEA
copolymers preferably contain about 15% to 30% by weight of the ethylacrylate mo,iety. These copolymers have a melt index of 1 to 20, preferably about 18; andhave a thermal stability such that when the temperature is raised at 10~ C/min., under flowing nitrogen, less than 0.75% of the copolymer weight is lost at 300~ C.
It is a critical feature of the present invention that the amount of alkyl acrylate in the polypropylene ethylene alkyl acrylate copolymer be present in an amount between 0.2% to 3.0% by weight, and preferably between 0.5% and 2.0% by weight, in order to produce a textile fiber having commercially acceptable proceccing characteristics. If the amount of alkyl acrylate component is increased above 3.0%, a textile fiber produced therefrom loses its ne~çcc~ry polypropylene characteric~il s, degrades during high-speed fiber processing and produces a final fiber with lln~cceptably low tenacity (less than about 1.5 grams/denier) and excessive elongation and with significantly different melt characteristics to be commercially unacceptable.
For example, carpet made from fibers having an alkyl acrylate component between 3.0% and 5.0%, melts excessively upon exposure to flame as compared to conventional polypropylene carpet to the point that it dramatically fails a standard "pill test" for flame resistance while standard polypropylene passes. Further at an WO96/01916 2 1 ~4238 P~ s9s~07522 alkyl acrylate content above 2.0% the fiber fuses together on the heated drawing rolls and is basically unspinnable on modern commercial scale e(lui~ nt. These subde, yet commercially critical, limit~tions were completely unexpected.
An alkyl acrylate coll,l)ollellL of less than 0.2 % produces a fiber with 5 incllfficient polarity pelr~ ance character to impart a desired wettability feature.
Accordingly, the maximum amount of alkyl acrylate component is l,r~rell~d subject to acceptable fiber production and ~c.rol,l,ance character. The more plerelled alkyl acrylate col,.l)onent is between 0.5% to 1.7% by weight, with 1.0 to 1.5% being most prefe~ d.
It is understood that polymer additives, such as thermal, oxidative and ultraviolet light stabilizers, which are typically found in fiber-forrning polymer co...l,osilions may be added without departing from the present invention. The percent by weight values given in this application are e~lessed as a percent by weight of the composition which includes a polyolefin, such as polypropylene, and 15 a polar material, such as an alkyl acrylate copolymer, and preferably a particu~ar type of hydrophilic modifier. The combined percent values for these materials should uniformly be 100%. Other additives may be included to dilute the polyolefin composition. If such additives are included in the composition, the ratio of thepolyolefin, the polar material, and the hydrophilic modifier would remain as 20 provided. The total percent values of all materials, including additives, would then exceed 100%. For example, if nylon were added to the polypropylene/alkyl acrylate copolymer ll~ix~ule, the ratio of the polypropylene and alkyl acrylate copolymer would not be affected since the "base" ."i~lu~ has not changed. Such additives are commonly included in a polypropylene/copolymer composition to dilute the polymer25 composition.
It has been found very desirable in some applications to blend a polyamide, such as nylon 6 or nylon 6,6, into a first composition (a polypropylene and ethylene copolymer composition)to further enhance the first composition without sacrificing the desired spinning or dyeing properties of the fiber. The addition of polyamide 30 forms a second composition (e.g., a polypropylene/copolymer/nylon 6 composition) with improved fl~mm~bility, improved tenacity and improved resiliency con-par~d to the first composition, even to a point that the modified fiber is more resilient than -polypropylene alone. The added polyamide is by weight about 1% to 20%, and preferably 5% to 15%, the weight of the first co-nl)o~ition. When a nylon component is added it may substitute for a part of the ethylene copolymer as long as the alkyl acrylate component doesn't drop below an amount sufficient to keep the otherwiseS immicrihle polypropylene and polyamide from sep~ling (usually about 0.5%). Aplef~lled composition when polyamide is included is about 1.4% alkyl acrylate com~nPnt (appro~im~tely 7% ethylene copolymer) and 15% nylon 6 with the remainder (approxim~t~ly 93%) polypropylene. For this one preferred composition,the ~ltern~tively e~ressed phr valves are 100 phr polypropylene, 7.5 phr ethylene copolymer, and 16.1 phr nylon.
As ~liccllssçd~ the ethylene copolymers utilized in the present invention - cor~ s at least 70% ethylene with the alkyl acrylate component present between 2%
to 30%, typically between 18% to 24% depending upon the selected alkyl acrylate.Depen~ing upon the amount of alkyl acrylate component present in the ethylene copolymer, the ratio of ethylene copolymer to polypropylene can be easily adjusted to maintain the proper amount of alkyl acrylate in the final product. It is alsoimportant that the amount of ethylene contributed by the ethylene copolymer be m~in~inçd below 10%. Accordingly, it is preferred that the higher the percentageof alkyl acrylate in the copolymer, the easier it is to obtain the proper balance of components. By way of example, a mixture of 93% polypropylene and 7% ethylene methyl acrylate having a 20% methyl acrylate component produces a polypropylene/ethylene methyl acrylate copolymer composition having a methyl acrylate component of about 1.4%. Similarly, a 3% ~d~ition of the same ethylene methyl acrylate copolymer produces a methyl acrylate component of 0.6%.
In using a composition of the polypropylene and ethylene alkyl acrylate copolymer, it is inll)olLant that the polypropylene and ethylene alkyl acrylate copolymer be uniformly incorporated prior to forming the composition into a shaped article. The combination may be only a uniform blend, but preferably, and in accordance with this invention, it is a composition in which at least a portion of the ethylene alkyl acrylate is grafted onto the polypropylene. Whether by blending and/or grafting can be accomplished in a separate step prior to forming, or the blending and/or grafting and extrusion can be carried out in the same operation if the W 0 96/Oi916 2 1 94238 P~ 5s~07522 '_ g extruder has a suitable mixing section. Poor blending and/or grafting can result in uneven dyeing even if the lG."~ in~ steps of dyeing procedure are ~ elly conducted.
The grafting of ethylene alkyl acrylate copolymer to polyolefin polymer, 5 preferably isotactic polypropylene, for use in this invention is accomplished by subjecting the ethylene alkyl acrylate copolymer to co-graft polym~-ri7~tion in the presence of the polyolefin polymer. The graft polymerization method is not critical and the graft poly-lle,izalion can be effected according to conventional methodsemploying organic free radical iniliatol~. The polymerization conditions may be those 10 known to the art. The organic radical-generating agent used in this invention incllldes:
2,5-dimethyl-2,5-di(t-butylperoxy)hexene-3, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 1 ,3-bis(t-butylperoxyisoplopyl)benzene, 2,2-bis(t-bulyl~ro,~y)-p-diisopropylbenzene, ,, dicumyl peroxide, di-t-butyl peroxide,t-butyl benzoate, 1, l-bis(t-bulylpelu~y)-3,3,5-trimethylcyclohexane, 2,4-dichlorobenzoyl peroxide, benzoyl peroxide, azobisisobutyronitrile and the like.
Preferred are:
2 ,5-dimethyl-2 ,5-di(t-butylperoxy)hexane, 1,3-bis(t-butylperoxyisopropyl)benzene and 2,2-bis-(t-Butylpelo~y)-p-diisopropylbenzene.

The thermoplastic resin composition of this invention can be obtained by adding 0.01-0.3 parts by weight, preferably 0.05-0.2 parts by weight, of an organic radical-generating agent to 100 parts by weight of a mixture consisting of 98-70% by weight, preferably 96-90% by weight of polypropylene, and 2-30 % by weight, and 30 preferably 4-10% by weight, of an ethylene alkyl acrylate copolymer, and thensubjecting the resulting mixture to thermal treatment in a mixer (e.g., a Banbury WO96/01916 21 q~8 Pcr/US95/07522 mixer, a knP~-lçr) or an extruder at 170~ to 300~C., preferably 180~ to 250~C., for 0.2 to 30 minlltes, preferably 0.5 to 20 minl~tes.
The uniform combination of polypropylene and ethylene-alkyl acrylate copolymer is formed into the desired shaped article by any of the known techniques 5 such as melt spinning in the case of fibers, casting or other known methods offilm-m~kin~, extrusion or injection mol~ling. The present invention is particularly useful with fibers, and particularly dyed fibers. Fibers of various deniers can be adequately wetted both in the form of fibers or nonwoven webs made from these fibers. When a degree of orient~tion is increased, at a given melt flow rate, for example, by a times 3 co~ ed to a times 1.5 draw ratio, a significant increase in uptake of the dyestuff is observed. An increased degree of orientation is the result of the degree of higher draw ratios. Generally, the fibers are from 1 to 1500 denier and can be in the form of round or lobed fibers, tape or fibrillated film. Round or lobed fibers are for apparel, upholstery and carpet face yarn uses and can have a denier of about 1 to 60 without encount~rinE dyeing problems by the present technique. These fibers can also be used in production of other articles, such as dec,orated ribbons or nonwoven textiles. The tape fibers are generally used for carpet backing and are of heavier denier, i.e., about 500 to 1500 denier. Fibrillated film fibers are used for cordage carpet face yarn or upholstery.
Sizing is a procedure by which warp yarn is prepared for weaving by coating it with a sizing agent, such as PVA. In effect, sizing reduces the metal to fiber friction, thereby protecting the yarn from abrasion. It is important for the yarn to be sized so that it perform well on the weaving machines without being abraded and cause processing problems.
For fibers to be fully penetrated by dye, the spinning and drawing processes should be conducted in a manner to produce a fiber with a uniform structure through its cross-section, i.e., minim~l sheath/core structural differences. On the other hand, greater economy of dye use in dyeable carpet backing made from woven tapes can be obtained if such tapes do possess a sheath/core structure. In these sheath/core structures, the sheath is dyeable, while the core exhibits very little dye pick-up.
Thus, less dye is used to dye a backing which is made up from such fibers.

wo96/01916 2 1 9 4 2 3 8 ~ ?s~2 After spinning of the fibers, but before drawing, a sp;n finish can be applied to the fibers. If such a m,2teri,21 is used, it may be anionic, but preferably is nonionic in nature. Nonionic spin finishes are commercially available and a pl~r~ d one is "Dispersol VLn. Suitably useable is "Nopcostat" 2152P, which is thought to S be a modified coconut fatty acid ester. Finishes coi~ ;nin~ mineral oil act as a plasticizer and can increase dye uptake rate at the fiber surface. A water-dispersible or water-soluble finish such as the "Dispersol VL" is l,refell~d.
Fini~hin~ operations can optionally be pelÇo"l,ed on the fibers before dyeing.
For example, the fibers can be ~ ulized by mechanically crimping or forming suchas described in Textile Fibers, Dyes, Finishes, and Processes: A Concise Guide, by Howard L. Needles, Noyes Publications, 1986, pp. 17-20.
A Lawson Hemphill CTT-YAT (Constant Tension Transport-Yarn Abrasion Tester) single end tester was used to test the fibers described herein. The instrument abrades a yarn over a "standard" copper wire or some other wire in the same location until the wire breaks or is incised. The yardage of yarn that is passed before such a failure is indicative of the frictiona', p,opel~ies of the yarn. In this experiment, however, a continuous but same loop of yarn was run against the wire, until suchtime as the yarn failed. The number of cycles to failure for the 2 meter length of looped yarn was used as a basis for ~sessing the frictional properties. The fiber as disclosed above withstood 207 cycles, whereas regular polypropylene fiber withstood 182 cycles, thereby illustrating that this modified polypropylene fiber was morereadily sizable than regular polypropylene and therefore should better withstandtortuous weaving conditions.
Through use of the AATCC test method for shrinkage from home 1~2lnder2ng, it was determined that this modified polypropylene fiber had similar shnnk~e characteristics as regular polypropylene. A vertical flammability test commonly used in the textile industry was also performed on this modified polypropylene fiber.There was no significant difference between flammability test results for this fiber and for conventional polypropylene fibers.
This invention specifically deals with the synergistic phenomena between polyolefin and ethylene methylacrylate or ma eic anhydride or acrylic acid in combination with a hydrophilic modifier preferably comprising a monoglyceride and 21 9423~
WO 96/01916 PCT/I~S95/07522 a salt of a linear alkyl. Polyolefin type polymers are the most ch~llPn~in~ fibers to wet using conventional fiber production techniques. Polypropylene practically is a nonpolar polyolefin polymer with a very low surface energy. It has been reportedthat the surface energy of polypropylene is a 28.7 dynes/cm with 26.0 and 2.7 5 dynes/cm dispersive and polar fractions, respectively.
Polypropylene can be modified with EMA at a certain level to enable the polyolefin fibers to be reliably dyed with dispersed dyes. However, the introduction of polar groups does not impart any "wettable" characteristics. Similarly, both acrylic acid and maleic anhydride m~lified products also do not yield a wettable10 polymer or fiber. Commercial m~teri~lc, such as the PolybondrM material from Uniroyal Chemical Company, Inc., combine functional monomers such as acrylic acid or maleic anhydride with polyolefin, and thereby form chemiç~lly grafted polyolefin copolymers. This ch~mic~lly grafted polyolefin copolymer, when combined with polypropylene, similarly does not produce a wettable fiber.
Hydrophilic modifiers including long chain hydrocarbons with a hydrophilic group, when incorporated into a polyolefins matrix, also do not offer any appreciable wettability. However, when a preferred hydrophilic modifier such as disclosed herein is used in conjunction with polar substrates, such as EMA or Polybond, the wettability of the polyolefin improves dramatically, as measured by contact angle.
20 This wettability can be further improved if a polyamide (either nylon 6 or 66) at a level between 2% to 20% is also incorporated.
A suitable hydrophilic modifier consists of a compound including a monoglyceride and a long chain hydrocarbon with a hydrophilic group, e.g., a potassium or sodium salt of a linear alkyl phosph~te. A pl~fe~led monoglyceride is 25 glycerol monosterate. While a hydrocarbon group cont~ining from 12 to 22 carbon atoms may be used, a C,4 to Clg hydrocarbon chain length is preferred. Typical hydrophilic groups are the carboxylates, sulfates, sulfonates, phosphates, phosphonates, quaternary ammonium salts, and polyoxyethylene groups, which may each be referred to as a salt of a linear alkyl. The adsorption of these compounds is 30 caused by putting the long chain hydrocarbons on a polyolefin backbone.
The hydrophilic group alone, though polar in nature, does not migrate very well to the surface. Since the wettability characteristic is generally regarded as a Wo 96/01916 2 1 9 4 2 3 8 p~ s~07s22 surface phenomenon, it is illlpol~nt that these co"lponents be present at the surface rather than in the bulk region. The push to migrate or exude towards the surfacecomes from the highly l~iCtillçd (> 90%) monoglyceride, which by itself does notimpart the surface wettability. Accordingly, it is beneficial to melt/fuse the S monoglycelide with the long chain hydl~c~luons having the hydrophilic group coll.ponent so as to realize the significant impact on surface wettability. Thismelt/fuse operation may be pelrolmed by a prilling process or a p~ctilli7ing process so that heat transfer takes place in a manner that will not degrade the monoglyceride.
Due to surface grafting of polyolefins with the polar material, the additional increase 10 in surface energy imparts the wettability that is nececc~ry for applications involving fibers, fabric, sheet and film.
There is a lt;lll~k~ble difference in polarity between the long chain hydrocarbon molecules and the hydrophilic group. According to this invention, wettability is enh~nced without sacrificing any inherent characteristics of polyolefins, 15 e.g., moisture and stain resistance. As discussed above, polypropylene is practically a nonpolar polymer where the surface energy contribution is derived from the dispersive forces (almost up to 905~) and a very low (10%) level of polar forces.
While polarity is introduced through the grafting process, wettability is not subst~nti~lly increased as evidenced by the contact angle measurement. When the 20 selected hydrophilic modifier is incorporated with the polar material, a synergistic effect is demonstrated by achieving not only a low contact angle, but also with an increase in spreading factor values.
A l,lerelled hydrophilic modifier is Product No. 5808 available from G. R.
Goulston and Company in Monroe, North Carolina. This compound (hereaher "5808 25 Modifier'i) consists of a ",i~u,~ of a food grade emulsifier, such as mono and diglycerides of edible fats and oils, and a salt of a linear alkyl phosphate. The raw material for the long chain hydrocarbon group may be an oil or fat (e.g., fatty acids, fatty alcohols or their derivatives), or a petroleum or petrochemical (e.g., n-paraffin, naphthenic acid, x-olefin, alkyl benzene, alkyl phenol, synthetic alcohol, synthetic 30 fatty acid, polyoxyalkylene glycol or polysiloxanes). The hydrophilic group may be anionic (e.g., carboxylate, sulfonate, sulfate, phosphate or phosphonate), cationic (e.g., amine salts, quaternary ammonium salts, pyrridium salts, sulfonium salts, WO 9C/019lG PCI/US95/07522 pho~oniu,ll salts, arnino acid, amino sulfate, betaine or sulrob,;~ine), or noniQni~
(e.g., polyhydric alcohol, glycerine, glucose, sorbitol, sucrose, ~mino~lcohol, polyethylene glycol, ~mineoxide~ sulfoxide or ~min~imitle).
The p,efelied modifier is a combination of nonionic and anionic structures.
The nonionic structure may be a monoglyceride with a melting point approximately66~C and a boiling point of approxim~t~ly 260~C. GMS, or glycerol monos~-rate~
is the presently pl~îelled monoglyceride. This nonionic structure is highly dictilled with a monoglyceride content in excess of 95 % by weight. The minor colllponent has an anionic structure, and is a potassium salt linear alkyl (C,6 to C,8) phosph~t~. The plefe~l~d ratio of these two col~-ponents varies depenf~ing on the applic~tiQ~, although the nonionic structure preferably is from 50% to 90% by weight of the mo lifisr. A
80:20 ratio by weight of the nonionic and anionic structure is prerelled. Other plefel~d hydrophilic modifiers are polypropylene glycol polyoxyethylates and fatty alcohol polyoxyethylates. Other hydrophilic modifiers may include alkyl phenol polyoxyethylates, fatty acid polyoxyethylates, and fatty acid amide polyoxyethylates.
The invention can be further understood by referring to the following examples in which parts and percentages are by weight unless otherwise indicated.

Example 1 A polypropylene alloy composition cont~inin~ 93 % by weight of a commercial fiber grade of isotactic polypropylene having a melt flow rate of 18 (ASTM
D-1238-89, 230~C, 2.16 lbs) and Cont~ining thermal, oxidative and ultraviolet light stabilizers and 7% by weight of a copolymer of ethylene methylacrylate along with 5808 Modifier (0.5% by weight) is prepared by first dry mixing the polymers and then melt blending the mix in a 40 mm Berstorff extruder at 246~C. The ethylene copolymer contains 20% by weight of the methylacrylate comonomer, and has a meltindex of 18 (ASTM D-1238-89, 190~C, 2.16 lbs). The resulting homogeneous, compatible polymer blend is cut into nibs after water-quenching, which are then fed to a melt spinning apparatus and 50-60 denier per filament fiber is spun at 230-245~C. A mineral-oil based finish containing anionic surfactants is applied to the fiber bundle after spinning, but before drawing. The fibers are drawn three times to give a final denier of 18-20 per filament. The physical properties of specimens of WO 96101916 2 1 9 4 2 ~ 8 PCI'tUS95/07522 the fibers so prepared are tested, and the test results are set forth in Table I.
S~ c of the fibers are knitted on a knitting m~hine to produce a tubularknit fabric. Samples of the fibers were tested for wetting characteristics.

Example 2 A polypropylene graft colllpGsition cont~ining 93 ~ by weight of a commercial fiber grade of isotactic polypropylene having a melt flow rate of 4 (ASTM
D-1238-89, 230~C, 2.16 lbs) and 7% by weight of a grafted copolymet of ethylene methylacrylate (and co~ ining thermal, oxidative and ultraviolet light stabilizers) is ~leya,ed by first dry mixing the polymers along with 0.5% by weight of the 5808 Modif1er, and then melt blending the mix in a 40 mm Berstorff extruder at 246~C in the presence of sufficient free radical initia,or peroxide, specifically, 2,5-dimethyl-2,5-di(tertiary-butyl peroxy)hexane, to visbreak the composition to a product melt flow rate of 18. The ethylene copolymer contains 20% by weight of the methylacrylate comonomer, and has a melt index of 18 (ASTM D-1238-89, 190~C, 2.16 lbs). The resulting homogeneous, compatible polymer blend is cut into nibs after water-quenching, which are then fed to a melt spinning appa~dtlls and 50-60 denier per filament fiber is spun at 230 - 245~C. A mineral-oil based finish conlailling anionic surfactants is applied to the fiber bundle after spinning, but before drawing. The fibers are drawn three times to give a final denier of 18-20 per filament. The physical properties of specimens of the fibers so prepared are tested, and the test results are set forth in Table I. Specimens of the fibers are knitted on a knitting machine to produce a tubular knit fabric. Samples of the fibers were tested for wetting characteristics.

W O 96/01916 ~ 1 942 38 P~r~US95/07~22 TABLE I
Example I Example II
Physical(Unmodified (Alloy (Grafted Propertieshomopolymer)Modified PP) Modified PP) Denier 1,450 1,480 1,460 (gms/9000 meters) Tensile (gms/den) 2.5 2.5 2.3 Fl~ n ~ ti~n (%) 39.0 44.0 48.0 Tou~hness(gms/den) 0.69 0.75 0.80 Energy at Break 3,980 4,420 4,675 (gms - inch) Young Modulus 17.0 12.0 10.5 (gms/den) Example 3 A polypropylene combination alloy and graft composition cont~inin,~ 93 % by weight of a commercial fiber grade of isotactic polypropylene having a melt index in tlle range of 8-12 (ASTM D-1238-89, 230~C, 2.16 lbs) (and cont~ining thermal, oxidative and ultraviolet light stabilizers) and 7 % by weight of an alloyed and grafted copolymer of ethylene methylacrylate is prepared by first dry mixing the polymers along with a 5808 Modifier (0.5% by weight), and then melt blending the mix in a40 mm Berstorff extruder at 246~C in the presence of sufficient free radical initiator peroxide, specific~lly 2,5-dimethyl-2,5-di(tertiary-butyl peroxy)hexane, to visbreak the composition to a product melt flow rate of 18. The ethylene copolymer c~nt~ins 20% by weight of the methylacrylate comonomer, and has a melt index of 18 (ASTM
D-1238-89, 190~C, 2.16 lbs). The resulting homogeneous, compatible polymer blendis cut into ribs after water-quenching, which are then fed to a melt spinning apparatus and 50 - 60 denier per filament fiber is spun at 230~ - 245~C. A mineral-oil based finish co~t~ining anionic surfactants is applied to the fiber bundle after spinning, but before drawing. The fibers are drawn three times to give a final denier of 18-20 per fil~m~nt The physical properties of specimens of the fibers so prepared are tested, SUBSTITUTE SHEET (RULE 26) Wo 96/01916 2 1 9 4 2 3 8 P~ 51O7522 and the test results are about the same as those obtained with the fibers of Example 2. Sper-im~n~ of the fibers are hlitted on a kllitting m~hine to produce a tubular knit fabric. Samples of the fibers were tested for wetting characteristics.
The theoretical bac~gl.~und of wetting phenomena may be understood by 5 reference to Fig. 1. The typical example of the wetting process is a drop of liquid, D, wetting a solid surface, S. As shown in Fig. 1, the contact angle ~3 is the angle between the liquid-vapor and liquid-solid interface measured in the liquid phase at the three-phase interface where liquid contacts the solid. This contact angle ~3 on a smooth surface is related to the energies of the solid-liquid, YSL~ solid-vapor YsV, and 10 liquid-vapor YLV interfaces by the Young - Dupre Equation as follows:
YSV YSL = YLV COS ~3 The same phenomena in slightly different terms may be e~cplessed as follows:

YS = YSL + YL COS ~ t and WSL = YL [ 1 ~ COS ~ ]
The Ys~ YL and YSL are the free energies per square centimeter, e.g., dynes/cm of the solid, liquid and solid-liquid interfaces, i.e., their surface tensions. WSL is the 20 work of adhesion, or the work required to separate the liquid from the solid. ~ is the contact angle formed at the solid-liquid interface.
The core of the physical phenomena expressed by the above equations may be described as follows. When the adhesion between solid and liquid is less than the self cohesion (or surface tension) of the liquid, there is a contact angle. The larger the 25 angle, the smaller the adhesion. When the adhesion is equal to or greater than the cohesion, the angle is zero and a complete wetting occurs. The approach mentioned above simplistically describes only the conditions of pure thermodynamic equilibrium, and its application to dynamic processes may be questionable.
Using Young's Equation, it is possible to use the contact angle as the criteria 30 for wetting. It is logical to assume that if ~ = 0~, one has complete wetting; if 0 ( 9 ~ 90~, one has partial wetting; if 9 ) 90~, one has non-wetting. Polyolefins generally have contact angles greater than 90~. As a practical matter, one does not 21. 94238 WO 96/01916 PCI/11Sg5107522 have generally s~ti~f~ctory wetting, at least with respect to the wetting of polyolefin m~n~ls, if the contact angle is not less than about 80~.
Another characteristic of a polyolefin m~teri~l iS its spreading factor, which may be defined as ~he ratio of the length L of a liquid drop D on a surface S as a 5 function of time. Accordingly, Lo may be the measured length of a drop D 30 se~on-~s after being deposited on surface S, and L, may be the length of the same drop D on surface S S minlltes after being deposited (4.5 minlltes subsequent to the time b is measured). In this case, the spreading factor SF may be ~ essed as follows:
SF = L, - Lo L~
The spreading factor was measured by the difference in drop length relative to that of the original drop length over S continuous minlltes. Generally, if this spreading 15 factor is < 1.0, then the resultant composition and fiber/fabric is considered not wettable. An ideal wettable polymer therefore will have both contact angle <80~
and a spreading factor > 1Ø

TABLE II
WETTING OF SPREADING CHARACTERISTICS OF
POLYOLEFIN BASED FILAMENTS

Sample IDContact Spreading Angle Factor After 30 After 5 Seconds Minutes Polypropylene (pp) 105 100 < < < 1 pp + nonIonic modifier 98 90 < <1 pp + anionic modifier 96 90 < <1 pp + Ethylene Copolymer 98 90 < < 1 pp + Ethylene Copolymer + nonionic modifier (0.5%) 65 52 <1 pp + Ethylene Copolymer + nonionic modifier (1 %) 45 38 -1.0 pp + Ethylene Copolymer + anionic modifier (0.5%) 59 51 > 1 pp + Ethylene Copolymer wo 96/olsl6 2 1 9 4 2 3 8 Pcr~ussslo7~22 ~ - 19 -+ anionic modifier (1.0%) 62 51 > 1 pp + Ethylene Copolymer + nylon 6(6%) + anionic modifier (0.5%) 47 31 >1 pp + Ethylene Copolymer + nylon 6(6~o) + anionic modifier (1.0%) 50 31 > 1 pp + Ethylene Copolymer + nylon 6(10%) + anionic modifier (1.0%) 26 23 > > 1 pp + Ethylene Copolymer + nylon 6(15%) + anionic modifier (1.0%) 59 41 > > 1 10 pp + Ethylene Copolymer + nylon 6(6%) + anionic mo iifier (1.0%) 50 31 > > 1 Based on the data ~u.n~ ed above, it may be concluded that it is possible to achieve the wetting of polypropylene by incorporating both the modification through grafting technique utili7.ing either EMA or maleic anhydride (or possibly acrylic acid), and a suitable hydrophilic modifier. Either of these by itself will not impart the wettability. This polypropylene/polar group material/hydrophilic modifier material combination may be used for various applications wherein reasonabl~ or high wettability is desired (i.e., a contact angle of less than about 80~ and spreading factor > 1), such as diapers, pads, filters, tea bags, or battery separators formed of woven or nonwoven fibers. The wettability and spreadability can further be enhanced byincorporating another polyamide, i.e., either nylon 6 or 66, into the above material.
~rom the above examples, it may be understood that the addition of both polar group m~teri~l and the hydrophilic modifier to a polypropylene based material will result in a material which is hydrophilic and thus "wettable". The polar group material may be an EMA m~teri~l as described above, or may be either an acrylic acid comprising about 0.1% to 2% by weight of the polypropylene composition, or a maleic anhydride comprising about 0.1% to 10%, and preferably 0.1% to 2%, by weight of the polypropylene composition. The hydrophilic modifier may be either a nonionic or anionic material, and may be used in compositions wherein the hydrophilic modifier is present in the amount of between 0.1% and 2~, and preferably between 0.4% and 1.0%, of the weight of the polypropylene and polar group material composition.
While it is not desired to be bound by any particular theory as to why the above composition becomes so much more wettable compared to similar polypropylene-based m~t~ri~lc, it is specu~ d that the colllbinalion of increased dispersive and polar filnrtionc far exceeds the surface energy that is very critical for adequate wetting to occur on polyolefin surfaces. Neither a polar m~tPri~l nor ahydrophilic mo-~ifier on its own is capable of imparting such highly desired 5 characteristic that produces good spreading and even dyeing. The above material can be colllpaldtively easy to dye compared to some modified polypropylene m~tPri~lc, and may be either acid dyeable, base dyeable, or disperse dyeable.
In order to channel a fluid to a target or acquisition zone, current practice would involve the use of a surfactant-treated polypropylene nonwoven web in diaper 10 product lines. A polypropylene nonwoven web generally has to go through an extra step to be slightly hydrophilic. This tre~tmPnt unfortunately is not believed to be permanent in its nature, and tends to leak out.
The wettable polymers as described above thus have significantly improved hydrophilic characteristics which enable the polymers to be formed into fibers suitable 15 for fabrics or into injection molded films. These polymers provide improved dyeability, and particularly make the polymer dyeable with a broad range of disperse dyes. This increased dyeability feature is of great importance be~ause certain disperse dye molecules are to large to diffuse into the fiber core of prior art polyp;~opylene fibers, but these same molecules may penetrate into the improved 20 polypropylene fibers of this invention. Dye selection therefore becomes less complex, and the final shade of the dyed product is brighter, deeper and sharper than prior art compositions. This wettability ch~racteristic also should provide ~oYctollçnt eYh~lstion for the dyed products, since the dye molecules once in place in a fiber should tend to stay in place. Improved w~chf~ctness and crockfastness results may 25 thus be éxpected, and the product should be both wettable and dyeable for various applications. It is expected that various polyamide compositions would be dyeable with either acid or disperse dyes.
A hydrophilic or wettable polymer provides highly desirable m~tPri~l features, such as permanently, wickability, and extra comfort. These attributes are highly30 desired in product applications such as diapers, adult incontinence products and sanitary napkins, where a nonwoven web comes in contact with the body or entry point for any fluid penetration. Referring to Fig. 2, the cross-section of a suitable wo 96101916 2 1 9 4 2 3 8 Pcrlussslo7522 diaper according to the present invention is depicted. The diaper 10 comprises afacing sheet 12, absGll,ellt core 14, nonwoven fabric sheet 16, an absorbent sheet 18, a second nonwoven fabric sheet 20, and a bac-k-ing sheet 22. The polypropylene fibers of the present invention are particularly well suited for forming the nonwoven fabric sheets 16 and 20, and may also be used for forming the facing sheet 12.
Further details with respect to construction of a suitable diaper are disclosed in U.S.
Patent No. 4,540,414.
The utility of this col--position is not limited to absorbent products as described above, and the invention has utility also in pack~ging and consumer goods. Tea bag pouches formed from a nonwoven web may thus be made of this polypropylene material. By having a wettable polypropylene nonwoven web, an increased immersion of tea leaves in hot or cold water is expected to result in a final product with improved aroma, taste and efficiency. Moreover, the improved nonwoven web will not produce any ~ignifi~ nt detrimental effect, such as leaching out a coll-ponent which may affect taste. t In industrial products, nonwoven mats made out of polypropylene are increasingly used. The present invention is accordingly expected to significantly enhance the performance of mats or fabric sheets containing nonwoven fibers. Forexample, filter cartridges made out of polypropylene will have tremendous affects on pres~u~e drop, since the initial resistance will be reduced and internal wicking will promote a high flow rate. The life time of the filter will be increased while also increasing the flow rate characteristics of the filter. From a commercializationstandpoint, the "duMbility" feature could have numerous application in both absorbent products and nonabsorbent products. Referring to Fig. 3, the cross-section of a suitable filter sheet for filtering particulate from the gas steam is disclosed. Filter 30 as shown in Fig. 3 may conclude subst~nti~lly planar mat 32 having polypropylenefibers as disclosed herein. Those skilled in the art will further appreciate that the mat may be formed to have a plurality of generally V-shaped bends 34 and 36 commonlyused in filters for increasing the cross-sectional flow area through the filter medium while decreasing the overall size of the filter.
In addition to being used as a diaper cover stock or a filtration media, the fabric sheet including nonwoven fibers according to the present invention may be used 21. 94238 as a carpet component, and wipes and roll towels, coated or l~min~t~d fabrics embe~lin~ another home furnishing fabrics, and surgical caps and gowns, and durable papers and p~e~ in~, and in interlinings and interfaoings. Information regarding m~nllf~ctllre of nonwoven fabrics, the performance of these m~teri~ls, and S the market for nonwoven fabrics is dicrlosed in a brochure entitled "Guide To Nonwoven Fabrics" by ~csoçi~tion of the Nonwoven Fabrics Industry.
While the techniques of the present invention are particularly well suited for increasing the wettability char~cterictics of polypropylene, it should be understood that the selected polar group material, such as an ethylene copolymer inrllldin~ alkyl acrylate as described above, in combination with a hydrophilic modifier as described above, may be used to substantially increase the wettability characteristics of other polyolefin m~Pri~lc, such as polyester, nylon, and ace~te, all of which may be used to form fibers. Those skilled in the art will also appreciate that fibers made of a polyolefin m~t~ l as disclosed herein may be used for various woven or nonwoven applirationc to form either fabrics or mats. The fibers may also be combined with other common stock materials, such as pulp or paper stock, to form a desired wettable and breathable fabric or mat. As previously explained, the concept of the present invention may also be used for form m~teri~l.c such as fibrillated films which did not include fibers.
Various modifications to the modified polypropylene fibers and to the techniques described herein for forming and dyeing such fibers should be apparent from the above description of those preferred embodiments. Although the invention ha thus been described in detail for these embodiments, it should be understood that this explanation is for illustration and that the invention is not limited to these embo~im.ontc Alternative fibers and forming and dyeing techniques will thus be apparent to those skilled in the art in view of this disclosure, and such alternative fibers and techniques may be performed without departing from the spirit of the invention, which is defined by the claims.

Claims

What is claimed is:

1. A process of forming a wettable polyolefin composition, comprising:
forming a composition of about 98 to 70% by weight of a polyolefin, an ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to18% by weight of an alkyl acrylate wherein the alkyl has one to four carbon atoms, said alkyl acrylate present in the composition in an amount between 0.2 to 3.0% by weight, and a hydrophilic modifier in an amount of about 0. 1% to 2 % by weight and comprising a long chain hydrocarbon with a hydrophilic group and a monoglyceride.

2. The process of Claim 1, wherein the alkyl acrylate is present in an amount between 0.5% to 1.7% by weight.

3. The process of Claim 1, wherein the hydrophilic modifier is present in an amount by weight of about 0.4% to 1.0% by weight.

4. The process of Claim 1, wherein the ethylene from said ethylene copolymer is in an amount less than 10% by weight.

5. The process of Claim 1, wherein the polyolefin is polypropylene and at least a portion of the ethylene copolymer is grated onto the polypropylene.

6. The process of Claim 1, wherein the ethylene copolymer is ethylene methyl acrylate.

7. The process of Claim 1, wherein the ethylene copolymer is ethylene ethyl acrylate.

8. The process of Claim 1, wherein the ethylene copolymer is ethylene butyl acrylate.

9. The process of Claim 1, wherein the polyolefin is polypropylene and the composition further includes a polyamide blended therein in an amount by weight of from 1% to 20% of the polypropylene.

10. The process of Claim 1, wherein the hydrophilic modifier comprises a monoglyceride and a long chain hydrocarbon with a hydrophilic group.

11. A process for forming a polypropylene fiber, comprising:
(a) combining polypropylene with an ethylene copolymer, the ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to 18% by weight of an ethylene alkyl acrylate wherein the alkyl group has one to four carbon atoms, said alkyl acrylate comprising less than 3.0% by weight, and a selected amount of a hydrophilic modifier comprising a long chain hydrocarbon with a hydrophilic group and a monoglyceride sufficient to result in a wetting contact angle of less than about 80°; and (b) forming the composition into fibers.

12. The process of Claim 11, wherein at least a portion of the ethylene copolymer is grafted onto said polypropylene.

13. The process of Claim 11, wherein ethylene alkyl acrylate copolymer is ethylene methyl acrylate.

14. The process of Claim 11, wherein the hydrophilic modifier is present in an amount of about 0.4% to 1.0% by weight.

15. The process of Claim 11, wherein the ethylene copolymer comprises from 0.5% to 1.7% by weight.

16. The process of Claim 11, wherein the ethylene from the ethylene copolymer is present in an amount less than 10% by weight.

17. The process of Claim 11, wherein the composition further includes a polyamide blended therein in an amount by weight of from 1% to 20% of the polypropylene.

18. A polyolefin composition, comprising:
(a) about 98 to 70% by weight of a polyolefin;
(b) an ethylene copolymer comprising 70 to 82% and about 30 to 18% by weight of an alkyl acrylate wherein the alkyl acrylate has one to four carbon atoms, said alkyl acrylate being present in an amount between 0.2% to 3.0% by weight; and (c) a hydrophilic modifier in an amount by weight of from 0.1% to 2.0% by weight and comprising a long chain hydrocarbon with a hydrophilic group and a monoglyceride.

19. The composition of Claim 18, wherein the ethylene copolymer is ethylene methyl acrylate.

20. The composition of Claim 18, wherein the alkyl acrylate is present in an amount of 0.5% to 1.7% by weight.

21. The composition of Claim 18, wherein the hydrophilic modifier is present in an amount by weight of about 0.4% to 1.0% by weight.

22. The composition of Claim 18, wherein the ethylene from said ethylene copolymer is in an amount less than 10% by weight.

23. The composition of Claim 18, wherein the composition further includes a polyamide blended therein in an amount of from 1% to 20% by weight.

24. The polypropylene based fiber, comprising:
about 98 to 70% by weight of a polypropylene, an ethylene copolymer incorporated into the polypropylene to form an alloy, said ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to 16% by weight of an alkyl acrylate wherein the alkyl acrylate has one to four carbon atoms, said alkyl component present in an amount between 0.2% to 3.0% by weight, and a hydrophilicmodifier in an amount of from 0.1% to 2% by weight and comprising a long chain hydrocarbon with a hydrophilic group and a monoglyceride.

25. The fiber of Claim 24, wherein the ethylene copolymer is ethylene methyl acrylate.

26. The fiber of Claim 24, wherein the alkyl acrylate is present in an amount of 0.5 to 1.7% by weight.

27. The fiber of Claim 24, wherein the hydrophilic modifier is present in an amount of about 0.4% to 1.0% by weight.

28. The fiber of Claim 24, wherein the ethylene from said ethylene copolymer is in an amount less than 10% by weight.

29. The fiber of Claim 24, wherein the composition further includes a polyamide blended therein in an amount of from 1% to 20% by weight of the polypropylene.

30. A process for forming a wettable polyolefin composition, comprising:
forming a composition of about 98 to 70% by weight of a polyolefin, a selected amount of a polar group material, and a hydrophilic modifier comprising a long chain hydrocarbon with a hydrophilic group and at least 50% by weight a monoglyceride,the hydrophilic modifier being in an amount by weight of about 0.1 % to 2 % the sum of the polyolefin and polar group material, the polar group material selected from a group consisting of (1) an ethylene copolymer, the ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to 18% by weight of an alkyl acrylate wherein the alkyl has one to four carbon atoms, said alkyl acrylate present in the composition in an amount between 0.2 to 3.0% by weight of the sum of the polyolefin and ethylene copolymer, (2) a maleic anhydride comprising about 0.1 % to 10% by weight of the polyolefin, and (3) an acrylic acid comprising about 0.1% to 2.0% by weight of the polyolefin.

31. The process of Claim 30, wherein the long chain hydrocarbon with hydrophilic group comprises a salt of a linear alkyl phosphate.

32. The process of Claim 31, wherein the salt of a linear alkyl phosphate has a hydrocarbon chain length of from 14 to 18 carbons.

33. The process of Claim 31, wherein the monoglyceride and the salt of a linear alkyl phosphate are fused.

34. The process of Claim 30, in which the polar group material is an ethylene copolymer.

35. The process of Claim 34, in which the ethylene copolymer is ethylene methyl acrylate.

36. The process of Claim 30, wherein the polar group material is an ethylene copolymer and the ethylene copolymer is present in an amount between 2 to 15% by weight.

37. The process of Claim 30, wherein the monoglyceride is glycerol monosterate.

38. A process for forming a polypropylene fiber, comprising:
combining polypropylene with a polar group material selected from a group consisting of (1) an ethylene copolymer, the ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to 18% by weight of an ethylene alkyl acrylate wherein the alkyl group has one to four carbon atoms, said alkyl acrylate comprising less than 3.0% by weight of the sum of the polypropylene and ethylenecopolymer, (2) a maleic anhydride, and (3) an acrylic acid, and a hydrophilic modifier comprising a monoglyceride and a long chain hydrocarbon with a hydrophilic group, whereby the polar group material and the hydrophilic modifier result in a wetting contact angle of less than about 80°.

39. The process of Claim 38, wherein the polar group material is an ethylene copolymer, and at least a portion of the ethylene copolymer is grafted onto said polypropylene.

40. The process of Claim 38, wherein the polar group material is an ethylene copolymer, and the ethylene copolymer is ethylene methyl acrylate.

41. The process of Claim 38, wherein the hydrophilic modifier is present in an amount by weight of about 0.4% to 2.0% of the polypropylene and the polar group material.

42. The process of Claim 38, wherein the long chain hydrocarbon with a hydrophilic group is a salt of a linear alkyl phosphate.

43. The process of Claim 38, wherein the long chain hydrocarbon with a hydrophilic group has a hydrocarbon chain length of from 14 to 18 carbons.

44. The process of Claim 38, wherein the monoglyceride and the long chain hydrocarbon with a hydrophilic group are fused.

45. A polyolefin composition, comprising:
(a) about 98 to 70% by weight of a polyolefin;
(b) a selected amount of a polar group material selected from a group consisting of (1) an ethylene copolymer comprising 70 to 82% and about 30 to 18%by weight of an alkyl acrylate wherein the alkyl acrylate has one to four carbon atoms, said alkyl acrylate being present in an amount between 0.2% - 3.0% by weight of the sum of the polyolefin and ethylene copolymer, wherein at least a portion of saidcopolymer is grafted onto said polyolefin, (2) a maleic anhydride comprising about 0.1% to 10% by weight of the polyolefin, and (3) an acrylic acid comprising about 0.1% to 2.0% by weight of the polyolefin; and (c) a hydrophilic modifier in an amount by weight of from 0.1% to 2.0%
of the polyolefin and the polar group material, the hydrophilic modifier comprising a monoglyceride and a long chain hydrocarbon with a hydrophilic group.

46. The composition of Claim 45, in which the polar group material is ethylene copolymer and the alkyl acrylate is present in an amount of 0.5 to 2.0% by weight of the sum of the polyolefin and ethylene copolymer.

47. The composition of Claim 45, wherein the polar group material is an ethylene copolymer and the ethylene copolymer is present in an amount between 2 to 15% by weight.

48. The composition of Claim 45, wherein the hydrophilic modifier comprises a linear alkyl phosphate.

49. The composition of Claim 45, wherein the long chain hydrocarbon with a hydrophilic group has a hydrocarbon chain length of from 14 to 18 carbons.

50. The composition of Claim 45, wherein the monoglyceride and the long chain hydrocarbon with a hydrophilic group are fused.

51. The composition of Claim 45, wherein the monoglyceride is glycerol monosterate.

52. A polypropylene based fiber, comprising:
about 98 to 70% by weight of a polypropylene, a selected amount of a polar group material selected from a group consisting of (1) an ethylene copolymer incorporated into the polypropylene to form an alloy, said ethylene copolymer comprising about 70 to 82% by weight ethylene and about 30 to 16% by weight of an alkyl acrylate wherein the alkyl acrylate has one to four carbon atoms, said alkyl acrylate component present in an amount between 0.2 - 3.0% by weight the sum of the polyplopylene and ethylene copolymer, (2) an acrylic acid, and (3) a maleic anhydride, and a hydrophilic modifier in an amount by weight of from 0.1% to 2%
of the polypropylene and the polar group material, the hydrophilic modifier comprising a long chain hydrocarbon with a hydrophilic group and at least 50% by weight a monoglyceride.

53. The fiber of Claim 52, in which the polar group material is an ethylene copolymer and the ethylene copolymer is ethylene methyl acrylate.

54. The fiber of Claim 52, wherein the long chain hydrocarbon with a hydrophilic group has a hydrocarbon chain length of from 14 to 18 carbons.

55. The fiber of Claim 52, wherein the monoglyceride and the long chain hydrocarbon with a hydrophilic group are fused.

56. The fiber of Claim 52, wherein the monoglyceride is glycerol monosterate.