CA2206765A1 - Shape memory alloy treatment - Google Patents

Shape memory alloy treatment

Info

Publication number
CA2206765A1
CA2206765A1 CA002206765A CA2206765A CA2206765A1 CA 2206765 A1 CA2206765 A1 CA 2206765A1 CA 002206765 A CA002206765 A CA 002206765A CA 2206765 A CA2206765 A CA 2206765A CA 2206765 A1 CA2206765 A1 CA 2206765A1
Authority
CA
Canada
Prior art keywords
component
shape memory
temperature
memory alloy
alloy treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002206765A
Other languages
French (fr)
Other versions
CA2206765C (en
Inventor
Alan Pelton
Thomas Duerig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Confluent Medical Technologies Inc
Original Assignee
Nitinol Devices and Components Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitinol Devices and Components Inc filed Critical Nitinol Devices and Components Inc
Publication of CA2206765A1 publication Critical patent/CA2206765A1/en
Application granted granted Critical
Publication of CA2206765C publication Critical patent/CA2206765C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/006—Resulting in heat recoverable alloys with a memory effect
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
    • A61F2/82—Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Media Introduction/Drainage Providing Device (AREA)
  • Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
  • Materials For Medical Uses (AREA)

Abstract

A method of treating a component formed from a Ni-Ti based shape memory alloy, so that the component exhibits super-elasticity, comprises cold working the component, annealing the alloy while the component is restrained in the configuration resulting from the cold working step, and exposing the component to a temperature that is less than the solvus temperature of the alloy and greater than the temperature to which it is exposed in the annealing step to cause the A f temperature to be reduced.
CA002206765A 1996-06-13 1997-06-03 Shape memory alloy treatment Expired - Lifetime CA2206765C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/661,305 1996-06-13
US08/661,305 US5843244A (en) 1996-06-13 1996-06-13 Shape memory alloy treatment

Publications (2)

Publication Number Publication Date
CA2206765A1 true CA2206765A1 (en) 1997-12-13
CA2206765C CA2206765C (en) 2007-01-23

Family

ID=24653050

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002206765A Expired - Lifetime CA2206765C (en) 1996-06-13 1997-06-03 Shape memory alloy treatment

Country Status (5)

Country Link
US (1) US5843244A (en)
EP (1) EP0812928B1 (en)
JP (1) JP3949228B2 (en)
CA (1) CA2206765C (en)
DE (1) DE69700723T2 (en)

Families Citing this family (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030069522A1 (en) 1995-12-07 2003-04-10 Jacobsen Stephen J. Slotted medical device
US5827321A (en) * 1997-02-07 1998-10-27 Cornerstone Devices, Inc. Non-Foreshortening intraluminal prosthesis
US20040267350A1 (en) * 2002-10-30 2004-12-30 Roubin Gary S. Non-foreshortening intraluminal prosthesis
US6190332B1 (en) * 1998-02-19 2001-02-20 Percusurge, Inc. Core wire with shapeable tip
US6312455B2 (en) * 1997-04-25 2001-11-06 Nitinol Devices & Components Stent
US6057498A (en) 1999-01-28 2000-05-02 Barney; Jonathan A. Vibratory string for musical instrument
US6375458B1 (en) * 1999-05-17 2002-04-23 Memry Corporation Medical instruments and devices and parts thereof using shape memory alloys
US6485507B1 (en) * 1999-07-28 2002-11-26 Scimed Life Systems Multi-property nitinol by heat treatment
WO2001015832A1 (en) 1999-08-30 2001-03-08 Michael Abel Barbed endodontic instrument
WO2001039695A2 (en) * 1999-12-01 2001-06-07 Advanced Cardiovascular Systems, Inc. Nitinol alloy composition for vascular stents
US6706053B1 (en) * 2000-04-28 2004-03-16 Advanced Cardiovascular Systems, Inc. Nitinol alloy design for sheath deployable and re-sheathable vascular devices
US6554848B2 (en) 2000-06-02 2003-04-29 Advanced Cardiovascular Systems, Inc. Marker device for rotationally orienting a stent delivery system prior to deploying a curved self-expanding stent
US6572646B1 (en) 2000-06-02 2003-06-03 Advanced Cardiovascular Systems, Inc. Curved nitinol stent for extremely tortuous anatomy
US20050043757A1 (en) * 2000-06-12 2005-02-24 Michael Arad Medical devices formed from shape memory alloys displaying a stress-retained martensitic state and method for use thereof
US6602272B2 (en) 2000-11-02 2003-08-05 Advanced Cardiovascular Systems, Inc. Devices configured from heat shaped, strain hardened nickel-titanium
US7976648B1 (en) 2000-11-02 2011-07-12 Abbott Cardiovascular Systems Inc. Heat treatment for cold worked nitinol to impart a shape setting capability without eventually developing stress-induced martensite
US6749376B2 (en) * 2000-12-11 2004-06-15 Command Tooling Systems, Llc Binary machine tool holder
US20060086440A1 (en) * 2000-12-27 2006-04-27 Boylan John F Nitinol alloy design for improved mechanical stability and broader superelastic operating window
US7128757B2 (en) * 2000-12-27 2006-10-31 Advanced Cardiovascular, Inc. Radiopaque and MRI compatible nitinol alloys for medical devices
US6855161B2 (en) * 2000-12-27 2005-02-15 Advanced Cardiovascular Systems, Inc. Radiopaque nitinol alloys for medical devices
US6569194B1 (en) 2000-12-28 2003-05-27 Advanced Cardiovascular Systems, Inc. Thermoelastic and superelastic Ni-Ti-W alloy
US20050021123A1 (en) 2001-04-30 2005-01-27 Jurgen Dorn Variable speed self-expanding stent delivery system and luer locking connector
US20040176837A1 (en) * 2001-05-17 2004-09-09 Atladottir Svava Maria Self-expanding stent and catheter assembly and method for treating bifurcations
US8337540B2 (en) 2001-05-17 2012-12-25 Advanced Cardiovascular Systems, Inc. Stent for treating bifurcations and method of use
US6824560B2 (en) * 2001-06-13 2004-11-30 Advanced Cardiovascular Systems, Inc. Double-butted superelastic nitinol tubing
US6551341B2 (en) 2001-06-14 2003-04-22 Advanced Cardiovascular Systems, Inc. Devices configured from strain hardened Ni Ti tubing
EP1401526B1 (en) 2001-07-05 2006-12-06 Precision Vascular Systems, Inc. Troqueable soft tip medical device and method for shaping it
US7175655B1 (en) * 2001-09-17 2007-02-13 Endovascular Technologies, Inc. Avoiding stress-induced martensitic transformation in nickel titanium alloys used in medical devices
US6699015B2 (en) 2002-02-19 2004-03-02 The Boeing Company Blades having coolant channels lined with a shape memory alloy and an associated fabrication method
US7018205B2 (en) * 2002-05-10 2006-03-28 Abelity, Llc Barbed endodontic instrument
US7914467B2 (en) 2002-07-25 2011-03-29 Boston Scientific Scimed, Inc. Tubular member having tapered transition for use in a medical device
WO2004011076A2 (en) 2002-07-25 2004-02-05 Boston Scientific Limited Medical device for navigation through anatomy and method of making same
US20040045645A1 (en) 2002-09-10 2004-03-11 Scimed Life Systems, Inc. Shaped reinforcing member for medical device and method for making the same
US8377035B2 (en) 2003-01-17 2013-02-19 Boston Scientific Scimed, Inc. Unbalanced reinforcement members for medical device
WO2004071343A2 (en) 2003-02-11 2004-08-26 Cook, Inc. Removable vena cava filter
US7169118B2 (en) 2003-02-26 2007-01-30 Scimed Life Systems, Inc. Elongate medical device with distal cap
US7163550B2 (en) 2003-03-26 2007-01-16 Scimed Life Systems, Inc. Method for manufacturing medical devices from linear elastic materials while maintaining linear elastic properties
US7001369B2 (en) 2003-03-27 2006-02-21 Scimed Life Systems, Inc. Medical device
ATE419879T1 (en) * 2003-03-31 2009-01-15 Memry Corp MEDICAL DEVICES WITH MEDICINAL ELUTION PROPERTIES AND PRODUCTION PROCESSES THEREOF
US7192496B2 (en) 2003-05-01 2007-03-20 Ati Properties, Inc. Methods of processing nickel-titanium alloys
US7942892B2 (en) 2003-05-01 2011-05-17 Abbott Cardiovascular Systems Inc. Radiopaque nitinol embolic protection frame
US7789979B2 (en) 2003-05-02 2010-09-07 Gore Enterprise Holdings, Inc. Shape memory alloy articles with improved fatigue performance and methods therefor
US20090198096A1 (en) * 2003-10-27 2009-08-06 Paracor Medical, Inc. Long fatigue life cardiac harness
US7455738B2 (en) * 2003-10-27 2008-11-25 Paracor Medical, Inc. Long fatigue life nitinol
US7824345B2 (en) 2003-12-22 2010-11-02 Boston Scientific Scimed, Inc. Medical device with push force limiter
ITTO20040135A1 (en) 2004-03-03 2004-06-03 Sorin Biomedica Cardio Spa CARDIAC VALVE PROSTHESIS
US7699867B2 (en) 2004-04-16 2010-04-20 Cook Incorporated Removable vena cava filter for reduced trauma in collapsed configuration
AU2005234753B2 (en) 2004-04-16 2010-12-02 Cook, Inc. Removable vena cava filter having inwardly positioned anchoring hooks in collapsed configuration
WO2005102212A1 (en) 2004-04-16 2005-11-03 Cook, Inc. Removable vena cava filter with anchoring feature for reduced trauma
US7625390B2 (en) 2004-04-16 2009-12-01 Cook Incorporated Removable vena cava filter
EP2158874A1 (en) 2004-04-16 2010-03-03 Cook Incorporated Removable vena cava filter having improved centering capabilities
US20050273151A1 (en) * 2004-06-04 2005-12-08 John Fulkerson Stent delivery system
US8062033B2 (en) 2004-06-08 2011-11-22 Gold Standard Instruments, LLC Dental and medical instruments comprising titanium
US8167901B2 (en) 2004-09-27 2012-05-01 Cook Medical Technologies Llc Removable vena cava filter comprising struts having axial bends
US20100241120A1 (en) * 2004-10-04 2010-09-23 Saint Louis University Intramedullary nail device and method for repairing long bone
US7632242B2 (en) 2004-12-09 2009-12-15 Boston Scientific Scimed, Inc. Catheter including a compliant balloon
ITTO20050074A1 (en) 2005-02-10 2006-08-11 Sorin Biomedica Cardio Srl CARDIAC VALVE PROSTHESIS
US20060247679A1 (en) * 2005-04-29 2006-11-02 Sdgi Holdings, Inc. Compression device and method for shape memory alloy implants
EP2179709B1 (en) 2005-08-17 2011-10-05 C. R. Bard, Inc. Variable speed stent delivery system
US9445784B2 (en) 2005-09-22 2016-09-20 Boston Scientific Scimed, Inc Intravascular ultrasound catheter
US7850623B2 (en) 2005-10-27 2010-12-14 Boston Scientific Scimed, Inc. Elongate medical device with continuous reinforcement member
US20070131317A1 (en) * 2005-12-12 2007-06-14 Accellent Nickel-titanium alloy with a non-alloyed dispersion and methods of making same
CA2936205C (en) 2006-01-13 2018-08-21 C.R. Bard, Inc. Stent delivery system
US11026822B2 (en) 2006-01-13 2021-06-08 C. R. Bard, Inc. Stent delivery system
CA2885593C (en) 2006-05-17 2018-03-06 G & H Technologies Llc Wear resistant coating
GB0615658D0 (en) 2006-08-07 2006-09-13 Angiomed Ag Hand-held actuator device
US8551020B2 (en) 2006-09-13 2013-10-08 Boston Scientific Scimed, Inc. Crossing guidewire
US8556914B2 (en) 2006-12-15 2013-10-15 Boston Scientific Scimed, Inc. Medical device including structure for crossing an occlusion in a vessel
US8500787B2 (en) * 2007-05-15 2013-08-06 Abbott Laboratories Radiopaque markers and medical devices comprising binary alloys of titanium
US8500786B2 (en) 2007-05-15 2013-08-06 Abbott Laboratories Radiopaque markers comprising binary alloys of titanium
GB0713497D0 (en) 2007-07-11 2007-08-22 Angiomed Ag Device for catheter sheath retraction
US8409114B2 (en) 2007-08-02 2013-04-02 Boston Scientific Scimed, Inc. Composite elongate medical device including distal tubular member
US8105246B2 (en) 2007-08-03 2012-01-31 Boston Scientific Scimed, Inc. Elongate medical device having enhanced torque and methods thereof
US8821477B2 (en) 2007-08-06 2014-09-02 Boston Scientific Scimed, Inc. Alternative micromachined structures
US9808595B2 (en) 2007-08-07 2017-11-07 Boston Scientific Scimed, Inc Microfabricated catheter with improved bonding structure
US8192351B2 (en) 2007-08-13 2012-06-05 Paracor Medical, Inc. Medical device delivery system having integrated introducer
US9848981B2 (en) 2007-10-12 2017-12-26 Mayo Foundation For Medical Education And Research Expandable valve prosthesis with sealing mechanism
US7841994B2 (en) 2007-11-02 2010-11-30 Boston Scientific Scimed, Inc. Medical device for crossing an occlusion in a vessel
US8246672B2 (en) 2007-12-27 2012-08-21 Cook Medical Technologies Llc Endovascular graft with separately positionable and removable frame units
US8376961B2 (en) 2008-04-07 2013-02-19 Boston Scientific Scimed, Inc. Micromachined composite guidewire structure with anisotropic bending properties
US8840661B2 (en) * 2008-05-16 2014-09-23 Sorin Group Italia S.R.L. Atraumatic prosthetic heart valve prosthesis
US8535243B2 (en) 2008-09-10 2013-09-17 Boston Scientific Scimed, Inc. Medical devices and tapered tubular members for use in medical devices
US8840735B2 (en) * 2008-09-19 2014-09-23 Fort Wayne Metals Research Products Corp Fatigue damage resistant wire and method of production thereof
JP2010092330A (en) * 2008-10-09 2010-04-22 Seiko Epson Corp Operation sequence creating apparatus, method for controlling the same, and program
US8246648B2 (en) 2008-11-10 2012-08-21 Cook Medical Technologies Llc Removable vena cava filter with improved leg
US8795254B2 (en) 2008-12-10 2014-08-05 Boston Scientific Scimed, Inc. Medical devices with a slotted tubular member having improved stress distribution
ES2551694T3 (en) 2008-12-23 2015-11-23 Sorin Group Italia S.R.L. Expandable prosthetic valve with anchoring appendages
EP2628465A1 (en) 2009-04-27 2013-08-21 Sorin Group Italia S.r.l. Prosthetic vascular conduit
US8808369B2 (en) 2009-10-05 2014-08-19 Mayo Foundation For Medical Education And Research Minimally invasive aortic valve replacement
US8137293B2 (en) 2009-11-17 2012-03-20 Boston Scientific Scimed, Inc. Guidewires including a porous nickel-titanium alloy
US10196713B2 (en) 2009-11-20 2019-02-05 Dentsply Sirona Inc. Medical instrument with modified memory and flexibility properties and method
US8911573B2 (en) 2009-11-20 2014-12-16 D & S Dental, Llc Medical instrument with modified memory and flexibility properties and method
US9005377B2 (en) 2009-11-20 2015-04-14 D & S Dental, Llc Method of modifying a physical property of an endodontic instrument
EP2552530A1 (en) 2010-03-31 2013-02-06 Boston Scientific Scimed, Inc. Guidewire with a flexural rigidity profile
US8216398B2 (en) * 2010-05-17 2012-07-10 Saint Louis University Method for controlling phase transformation temperature in metal alloy of a device
IT1400327B1 (en) 2010-05-21 2013-05-24 Sorin Biomedica Cardio Srl SUPPORT DEVICE FOR VALVULAR PROSTHESIS AND CORRESPONDING CORRESPONDENT.
US8475711B2 (en) 2010-08-12 2013-07-02 Ati Properties, Inc. Processing of nickel-titanium alloys
GB201017834D0 (en) 2010-10-21 2010-12-01 Angiomed Ag System to deliver a bodily implant
US10022212B2 (en) 2011-01-13 2018-07-17 Cook Medical Technologies Llc Temporary venous filter with anti-coagulant delivery method
US8795202B2 (en) 2011-02-04 2014-08-05 Boston Scientific Scimed, Inc. Guidewires and methods for making and using the same
EP2486893B1 (en) 2011-02-14 2017-07-05 Sorin Group Italia S.r.l. Sutureless anchoring device for cardiac valve prostheses
EP2486894B1 (en) 2011-02-14 2021-06-09 Sorin Group Italia S.r.l. Sutureless anchoring device for cardiac valve prostheses
US9072874B2 (en) 2011-05-13 2015-07-07 Boston Scientific Scimed, Inc. Medical devices with a heat transfer region and a heat sink region and methods for manufacturing medical devices
EP2842517A1 (en) 2011-12-29 2015-03-04 Sorin Group Italia S.r.l. A kit for implanting prosthetic vascular conduits
US10364483B1 (en) 2013-03-01 2019-07-30 The United States Of America As Represented By The Administrator Of National Aeronautics And Space Administration High hardness, high elasticity intermetallic compounds for mechanical components
US9279171B2 (en) 2013-03-15 2016-03-08 Ati Properties, Inc. Thermo-mechanical processing of nickel-titanium alloys
US9901706B2 (en) 2014-04-11 2018-02-27 Boston Scientific Scimed, Inc. Catheters and catheter shafts
US11351048B2 (en) 2015-11-16 2022-06-07 Boston Scientific Scimed, Inc. Stent delivery systems with a reinforced deployment sheath
WO2017196745A1 (en) * 2016-05-09 2017-11-16 Boston Scientific Scimed, Inc. Closure device with fixed jaw hook
WO2019224577A1 (en) 2018-05-23 2019-11-28 Sorin Group Italia S.R.L. A cardiac valve prosthesis
CN110453164B (en) * 2019-08-14 2020-12-22 河北工业大学 Processing method for enhancing oxidation resistance of forged Ni-Cr-Co-based alloy
DE102020214587A1 (en) * 2020-11-19 2022-05-19 Dirk Wiechmann Method of programming an orthodontic component made of a shape memory material
EP4277676A1 (en) 2021-01-17 2023-11-22 Inspire M.D Ltd Shunts with blood-flow indicators
CN113235028B (en) * 2021-04-06 2022-06-14 华南理工大学 Training method of nickel-titanium shape memory alloy with high martensitic transformation temperature

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4533411A (en) * 1983-11-15 1985-08-06 Raychem Corporation Method of processing nickel-titanium-base shape-memory alloys and structure
US4502896A (en) * 1984-04-04 1985-03-05 Raychem Corporation Method of processing beta-phase nickel/titanium-base alloys and articles produced therefrom
JPS6260851A (en) * 1985-09-11 1987-03-17 Sumitomo Metal Mining Co Ltd Manufacture of shape memory ni-ti alloy
JPS62284047A (en) * 1986-06-02 1987-12-09 Hitachi Metals Ltd Manufacture of shape memory alloy
US4935068A (en) * 1989-01-23 1990-06-19 Raychem Corporation Method of treating a sample of an alloy
JPH0885855A (en) * 1994-09-20 1996-04-02 Nippon Tungsten Co Ltd Production of titanium-nickel superelastic material

Also Published As

Publication number Publication date
CA2206765C (en) 2007-01-23
US5843244A (en) 1998-12-01
JPH10147851A (en) 1998-06-02
DE69700723T2 (en) 2000-06-08
DE69700723D1 (en) 1999-12-09
JP3949228B2 (en) 2007-07-25
EP0812928A1 (en) 1997-12-17
EP0812928B1 (en) 1999-11-03

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