CA2208689A1 - Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same - Google Patents

Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same

Info

Publication number
CA2208689A1
CA2208689A1 CA002208689A CA2208689A CA2208689A1 CA 2208689 A1 CA2208689 A1 CA 2208689A1 CA 002208689 A CA002208689 A CA 002208689A CA 2208689 A CA2208689 A CA 2208689A CA 2208689 A1 CA2208689 A1 CA 2208689A1
Authority
CA
Canada
Prior art keywords
ethylene copolymer
norbornene compound
unsaturated ethylene
mol
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002208689A
Other languages
French (fr)
Other versions
CA2208689C (en
Inventor
Hidenari Nakahama
Tatsuyoshi Ishida
Masaaki Yasuda
Toshiyuki Tsutsui
Toshihiro Sagane
Masaaki Kawasaki
Noriaki Kihara
Hitoshi Onishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Hidenari Nakahama
Tatsuyoshi Ishida
Masaaki Yasuda
Toshiyuki Tsutsui
Toshihiro Sagane
Masaaki Kawasaki
Noriaki Kihara
Mitsui Petrochemical Industries, Ltd.
Hitoshi Onishi
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP7528895A external-priority patent/JPH08268928A/en
Application filed by Hidenari Nakahama, Tatsuyoshi Ishida, Masaaki Yasuda, Toshiyuki Tsutsui, Toshihiro Sagane, Masaaki Kawasaki, Noriaki Kihara, Mitsui Petrochemical Industries, Ltd., Hitoshi Onishi, Mitsui Chemicals, Inc. filed Critical Hidenari Nakahama
Publication of CA2208689A1 publication Critical patent/CA2208689A1/en
Application granted granted Critical
Publication of CA2208689C publication Critical patent/CA2208689C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/39—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms
    • C07C13/42—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms with a bicycloheptene ring structure
    • C07C13/43—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms with a bicycloheptene ring structure substituted by unsaturated acyclic hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Abstract

The chain polyene-group containing norbornene compound of the invention is represented by the formula [I]:

... [I]
wherein n is an integer of 1 to 5, R1 is an alkyl group of 1 to 5 carbon atoms, and R2 and R3 are each independently a hydrogen atom or an alkyl group of 1 to 5 carbon atoms.
The unsaturated ethylene copolymer of the invention is a random copolymer of 30 to 92 % by mol of (i) ethylene units, 6 to 70 % by mol of (ii) specific .alpha.-olefin units and 0.1 to 30 % by mol of (iii) units derived from the norbornene compound [I], where the molar ratio of (i)/(ii) is in the range of 40/60 to 92/8 and the unit (iii) is represented by the specific formula, and has an intrinsic viscosity [.pi.] of 0.05 to 10 dl/g.

The novel unsaturated ethylene copolymer is excellent in weathering resistance, heat resistance and ozone resistance and has a high vulcanizing rate.
CA002208689A 1994-12-26 1995-12-25 Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same Expired - Fee Related CA2208689C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP322099/1994 1994-12-26
JP32209994 1994-12-26
JP7528895A JPH08268928A (en) 1995-03-31 1995-03-31 Chain-like polyene group-containing norbornene compound and its production
JP75288/1995 1995-03-31
JP126535/1995 1995-05-25
JP12653595 1995-05-25
PCT/JP1995/002655 WO1996020150A1 (en) 1994-12-26 1995-12-25 Norbornene compounds having chain polyene groups and unsaturated ethylenic copolymer produced with the use of the same

Publications (2)

Publication Number Publication Date
CA2208689A1 true CA2208689A1 (en) 1996-07-04
CA2208689C CA2208689C (en) 2002-02-05

Family

ID=27301761

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002208689A Expired - Fee Related CA2208689C (en) 1994-12-26 1995-12-25 Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same

Country Status (7)

Country Link
US (1) US6040407A (en)
EP (1) EP0801047B1 (en)
KR (1) KR100252074B1 (en)
CN (2) CN1171097A (en)
CA (1) CA2208689C (en)
DE (1) DE69516180T2 (en)
WO (1) WO1996020150A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI102473B (en) * 1996-03-13 1998-12-15 Optatech Oy Process for the preparation of norbornene and substituted norbornene derivatives
AU736721B2 (en) 1997-01-21 2001-08-02 Mitsui Chemicals, Inc. Tire rubber composition
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
ATE354540T1 (en) 2000-01-21 2007-03-15 United States Borax Inc NONBORATE COMPOSITION AND PRODUCTION THEREOF
WO2001098407A1 (en) 2000-06-20 2001-12-27 Mitsui Chemicals, Inc. Crosslinkable rubber compositions and use thereof
EP1548035A4 (en) * 2002-09-11 2006-08-09 Japan Polypropylene Corp CATALYST FOR POLYMERIZING a-OLEFIN AND PRODUCTION METHOD OF a-OLEFIN POLYMER USING THE SAME
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
AU2003302033A1 (en) 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
KR100807766B1 (en) * 2004-04-28 2008-02-28 미쓰이 가가쿠 가부시키가이샤 Rubber composition and use thereof
KR101149755B1 (en) * 2009-01-06 2012-06-01 에스케이종합화학 주식회사 The Manufacture of Ethylene-Propylene-Diene Copolymer
KR101973344B1 (en) 2010-09-02 2019-04-26 메르크 파텐트 게엠베하 Interlayer for electronic devices
US9109065B2 (en) * 2011-10-13 2015-08-18 Mitsui Chemicals, Inc. Ethylene copolymer, composition including the copolymer, and shaped article and film or sheet formed from the ethylene copolymer or the composition
KR102112890B1 (en) * 2012-09-21 2020-05-19 메르크 파텐트 게엠베하 Organic semiconductor formulations

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3678018A (en) * 1968-02-20 1972-07-18 Sumitomo Chemical Co Sulfur-curable olefinic copolymers and method for producing the same
US3674755A (en) * 1968-07-30 1972-07-04 Sumitomo Chemical Co Process for copolymerizing alpha-monoolefins with or without a polyene,using catalyst comprising organoaluminum compound and vanadyl compound containing cyclic hydrocarbon group
CA977375A (en) * 1970-01-22 1975-11-04 Sergio Arrighetti Polyene hydrocarbons containing at least two conjugated double bonds and process for obtaining same
US4200722A (en) * 1971-09-24 1980-04-29 Stamicarbon, B.V. Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack
JPS4931757B2 (en) * 1972-02-28 1974-08-24
TW383314B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer

Also Published As

Publication number Publication date
WO1996020150A1 (en) 1996-07-04
KR100252074B1 (en) 2000-04-15
DE69516180T2 (en) 2000-09-14
CN1259529A (en) 2000-07-12
CN1125835C (en) 2003-10-29
EP0801047B1 (en) 2000-04-05
KR980700944A (en) 1998-04-30
CA2208689C (en) 2002-02-05
CN1171097A (en) 1998-01-21
DE69516180D1 (en) 2000-05-11
US6040407A (en) 2000-03-21
EP0801047A4 (en) 1998-03-04
EP0801047A1 (en) 1997-10-15

Similar Documents

Publication Publication Date Title
CA2208689A1 (en) Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same
AU621474B2 (en) Styrenic copolymer and production thereof
TW327178B (en) Polyvinyl ether compound
TW372239B (en) N-oxycarbonyl substituted 5'-deoxy-5-fluorcytidines
MX9804475A (en) Monomeric units useful for reducing the modulus of low water polymeric silicone compositions.
HK1001731A1 (en) Cycloolefin type random copolymer compositions and uses thereof
EP0694558A4 (en) Novel sphingoglycolipid and use thereof
TW331569B (en) Unsaturated copolymer based on olefin and production and use
CA2223905A1 (en) Plastic articles for medical use
CA2076426A1 (en) Cationic polymer flocculating agents
CA2061003A1 (en) Process for isomerizing endo-form of aromatic group-containing norbornenes to exo-form thereof, isomer mixture of aromatic group-containing norbornenes and process for preparing same, and ethylene/aromatic group-contain ng norbornene copolymer and process for preparing same
CA2528290A1 (en) Bis[urea-urethane] compounds
TW337985B (en) "N-(B-branched alkyl)-1, 2-benzisothiolin, 3ones, their preparation and their use as industrial biocides"
CA2070663A1 (en) Sulfonating agent and process
AU1960092A (en) Spicamycin derivatives and the use thereof
EP0947856A3 (en) Ocular lens material
CA2051268A1 (en) Organocyclosiloxane and method for its preparation
CA2065978A1 (en) Organosilicon compounds containing (meth)acryloxy groups, their preparation and use
CA2023168A1 (en) Resin composition for use as paint
DK1826214T3 (en) Composition comprising ferrocene derivatives and fuel composition comprising such derivatives
CA2171914A1 (en) Modifier composition and a modified polymer
TW334451B (en) Composition which can be crosslinked by light
CA2037618A1 (en) Polyethylene and process of production thereof
AU6694290A (en) Synthesis of perfluoroalkyl bromides
CA2059389A1 (en) Thermoplastic resin composition

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed