CA2208689A1 - Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same - Google Patents

Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same

Info

Publication number
CA2208689A1
CA2208689A1 CA002208689A CA2208689A CA2208689A1 CA 2208689 A1 CA2208689 A1 CA 2208689A1 CA 002208689 A CA002208689 A CA 002208689A CA 2208689 A CA2208689 A CA 2208689A CA 2208689 A1 CA2208689 A1 CA 2208689A1
Authority
CA
Canada
Prior art keywords
ethylene copolymer
norbornene compound
unsaturated ethylene
mol
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002208689A
Other languages
French (fr)
Other versions
CA2208689C (en
Inventor
Hidenari Nakahama
Tatsuyoshi Ishida
Masaaki Yasuda
Toshiyuki Tsutsui
Toshihiro Sagane
Masaaki Kawasaki
Noriaki Kihara
Hitoshi Onishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Hidenari Nakahama
Tatsuyoshi Ishida
Masaaki Yasuda
Toshiyuki Tsutsui
Toshihiro Sagane
Masaaki Kawasaki
Noriaki Kihara
Mitsui Petrochemical Industries, Ltd.
Hitoshi Onishi
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP7528895A external-priority patent/JPH08268928A/en
Application filed by Hidenari Nakahama, Tatsuyoshi Ishida, Masaaki Yasuda, Toshiyuki Tsutsui, Toshihiro Sagane, Masaaki Kawasaki, Noriaki Kihara, Mitsui Petrochemical Industries, Ltd., Hitoshi Onishi, Mitsui Chemicals, Inc. filed Critical Hidenari Nakahama
Publication of CA2208689A1 publication Critical patent/CA2208689A1/en
Application granted granted Critical
Publication of CA2208689C publication Critical patent/CA2208689C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/39Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms
    • C07C13/42Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms with a bicycloheptene ring structure
    • C07C13/43Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing seven carbon atoms with a bicycloheptene ring structure substituted by unsaturated acyclic hydrocarbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50Diels-Alder conversion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/36Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Abstract

The chain polyene-group containing norbornene compound of the invention is represented by the formula [I]:

... [I]
wherein n is an integer of 1 to 5, R1 is an alkyl group of 1 to 5 carbon atoms, and R2 and R3 are each independently a hydrogen atom or an alkyl group of 1 to 5 carbon atoms.
The unsaturated ethylene copolymer of the invention is a random copolymer of 30 to 92 % by mol of (i) ethylene units, 6 to 70 % by mol of (ii) specific .alpha.-olefin units and 0.1 to 30 % by mol of (iii) units derived from the norbornene compound [I], where the molar ratio of (i)/(ii) is in the range of 40/60 to 92/8 and the unit (iii) is represented by the specific formula, and has an intrinsic viscosity [.pi.] of 0.05 to 10 dl/g.

The novel unsaturated ethylene copolymer is excellent in weathering resistance, heat resistance and ozone resistance and has a high vulcanizing rate.
CA002208689A 1994-12-26 1995-12-25 Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same Expired - Fee Related CA2208689C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP322099/1994 1994-12-26
JP32209994 1994-12-26
JP7528895A JPH08268928A (en) 1995-03-31 1995-03-31 Chain-like polyene group-containing norbornene compound and its production
JP75288/1995 1995-03-31
JP126535/1995 1995-05-25
JP12653595 1995-05-25
PCT/JP1995/002655 WO1996020150A1 (en) 1994-12-26 1995-12-25 Norbornene compounds having chain polyene groups and unsaturated ethylenic copolymer produced with the use of the same

Publications (2)

Publication Number Publication Date
CA2208689A1 true CA2208689A1 (en) 1996-07-04
CA2208689C CA2208689C (en) 2002-02-05

Family

ID=27301761

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002208689A Expired - Fee Related CA2208689C (en) 1994-12-26 1995-12-25 Chain polyene group-containing norbornene compound and unsaturated ethylene copolymer using the same

Country Status (7)

Country Link
US (1) US6040407A (en)
EP (1) EP0801047B1 (en)
KR (1) KR100252074B1 (en)
CN (2) CN1171097A (en)
CA (1) CA2208689C (en)
DE (1) DE69516180T2 (en)
WO (1) WO1996020150A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI102473B (en) * 1996-03-13 1998-12-15 Optatech Oy Process for the preparation of norbornene and substituted norbornene derivatives
WO1998031745A1 (en) 1997-01-21 1998-07-23 Mitsui Chemicals, Inc. Rubber compositions for tires
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6919036B2 (en) 2000-01-21 2005-07-19 U.S. Borax Inc. Nonaborate compositions and their preparation
KR100767334B1 (en) 2000-06-20 2007-10-17 미쓰이 가가쿠 가부시키가이샤 Crosslinkable rubber composition and use thereof
WO2004024783A1 (en) * 2002-09-11 2004-03-25 Japan Polypropylene Corporation POLYMERIZATION CATALYST FOR α-OLEFINS AND PROCESS FOR PRODUCTION OF α-OLEFIN POLYMERS THEREWITH
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
ES2394304T3 (en) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Multiple catalyst system for the polymerization of olefins and polymers produced from them
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
WO2005105913A1 (en) * 2004-04-28 2005-11-10 Mitsui Chemicals, Inc. Rubber composition and use thereof
KR101149755B1 (en) 2009-01-06 2012-06-01 에스케이종합화학 주식회사 The Manufacture of Ethylene-Propylene-Diene Copolymer
EP2611842B1 (en) 2010-09-02 2015-11-04 Merck Patent GmbH Interlayer for electronic devices
EP2767551B1 (en) * 2011-10-13 2016-05-25 Mitsui Chemicals, Inc. Ethylene-based copolymer, composition containing the copolymer, and molded article and film or sheet formed of the copolymer or the composition
US9425417B2 (en) 2012-09-21 2016-08-23 Merck Patent Gmbh Polycycloolefinic polymer formulation for an organic semiconductor

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3678018A (en) * 1968-02-20 1972-07-18 Sumitomo Chemical Co Sulfur-curable olefinic copolymers and method for producing the same
US3674755A (en) * 1968-07-30 1972-07-04 Sumitomo Chemical Co Process for copolymerizing alpha-monoolefins with or without a polyene,using catalyst comprising organoaluminum compound and vanadyl compound containing cyclic hydrocarbon group
CA977375A (en) * 1970-01-22 1975-11-04 Sergio Arrighetti Polyene hydrocarbons containing at least two conjugated double bonds and process for obtaining same
US4200722A (en) * 1971-09-24 1980-04-29 Stamicarbon, B.V. Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack
JPS4931757B2 (en) * 1972-02-28 1974-08-24
TW383314B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer

Also Published As

Publication number Publication date
KR100252074B1 (en) 2000-04-15
EP0801047A4 (en) 1998-03-04
US6040407A (en) 2000-03-21
EP0801047B1 (en) 2000-04-05
EP0801047A1 (en) 1997-10-15
CN1125835C (en) 2003-10-29
CA2208689C (en) 2002-02-05
CN1171097A (en) 1998-01-21
CN1259529A (en) 2000-07-12
WO1996020150A1 (en) 1996-07-04
DE69516180D1 (en) 2000-05-11
KR980700944A (en) 1998-04-30
DE69516180T2 (en) 2000-09-14

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