CA2211043A1 - Hydrocarbon treatment and catalyst therefor - Google Patents

Hydrocarbon treatment and catalyst therefor

Info

Publication number
CA2211043A1
CA2211043A1 CA002211043A CA2211043A CA2211043A1 CA 2211043 A1 CA2211043 A1 CA 2211043A1 CA 002211043 A CA002211043 A CA 002211043A CA 2211043 A CA2211043 A CA 2211043A CA 2211043 A1 CA2211043 A1 CA 2211043A1
Authority
CA
Canada
Prior art keywords
hydrocarbon treatment
catalyst therefor
core
outer layer
therefor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002211043A
Other languages
French (fr)
Other versions
CA2211043C (en
Inventor
Wim Herman Verrelst
Luc Roger Marc Martens
Johannes Petrus Verduijn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents, Inc.
Wim Herman Verrelst
Luc Roger Marc Martens
Johannes Petrus Verduijn
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents, Inc., Wim Herman Verrelst, Luc Roger Marc Martens, Johannes Petrus Verduijn, Exxonmobil Chemical Patents Inc. filed Critical Exxon Chemical Patents, Inc.
Publication of CA2211043A1 publication Critical patent/CA2211043A1/en
Application granted granted Critical
Publication of CA2211043C publication Critical patent/CA2211043C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/12Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80Mixtures of different zeolites

Abstract

A crystalline molecular sieve, especially a zeolite, each crystallite having a core and an outer layer of the same structure, the Si:Al molar ratio in the core being greater than that in the outer layer, gives lower branching in olefin oligomerization products.
CA002211043A 1995-02-07 1996-01-29 Hydrocarbon treatment and catalyst therefor Expired - Fee Related CA2211043C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9502342.0 1995-02-07
GBGB9502342.0A GB9502342D0 (en) 1995-02-07 1995-02-07 Hydrocarbon treatment and catalyst therefor
PCT/EP1996/000395 WO1996024567A1 (en) 1995-02-07 1996-01-29 Hydrocarbon treatment and catalyst therefor

Publications (2)

Publication Number Publication Date
CA2211043A1 true CA2211043A1 (en) 1996-08-15
CA2211043C CA2211043C (en) 2001-03-20

Family

ID=10769201

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002211043A Expired - Fee Related CA2211043C (en) 1995-02-07 1996-01-29 Hydrocarbon treatment and catalyst therefor

Country Status (13)

Country Link
US (2) US6013851A (en)
EP (1) EP0808298B1 (en)
JP (1) JP3937241B2 (en)
KR (1) KR100360734B1 (en)
CN (2) CN1072187C (en)
AT (1) ATE171155T1 (en)
AU (1) AU697790B2 (en)
CA (1) CA2211043C (en)
DE (1) DE69600667T2 (en)
ES (1) ES2122782T3 (en)
GB (1) GB9502342D0 (en)
WO (1) WO1996024567A1 (en)
ZA (1) ZA96891B (en)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999028031A1 (en) 1997-12-03 1999-06-10 Exxon Chemical Patents Inc. Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion
US6177381B1 (en) 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
WO2001074970A2 (en) 2000-04-03 2001-10-11 Chevron U.S.A. Inc. Improved conversion of syngas to distillate fuels
GB0010433D0 (en) * 2000-04-28 2000-06-14 Exxon Chemical Patents Inc Alkene oligomerization process
US7112711B2 (en) 2000-04-28 2006-09-26 Exxonmobil Chemical Patents Inc. Alkene oligomerization process
US6521198B2 (en) * 2000-05-17 2003-02-18 The Regents Of The University Of California Metal surfaces coated with molecular sieve for corrosion resistance
US6515033B2 (en) 2001-05-11 2003-02-04 Chevron U.S.A. Inc. Methods for optimizing fischer-tropsch synthesis hydrocarbons in the distillate fuel range
AU2003218439A1 (en) * 2002-03-29 2003-10-13 Exxonmobil Chemical Patents Inc. Process for olefin oligomerization
AU2003222120A1 (en) * 2002-03-29 2003-10-13 Exxonmobil Chemical Patents Inc. Oxon process
EP1494983A1 (en) * 2002-03-29 2005-01-12 ExxonMobil Chemical Patents, Inc. a Corporation of the State of Delaware Oligomerization of olefins
US7081553B2 (en) * 2002-03-29 2006-07-25 Exxonmobil Chemical Patents Inc. Cobalt flash process
FR2843049B1 (en) * 2002-08-01 2005-03-25 Inst Francais Du Petrole NON-HOMOGENEOUS ADSORBENT AND ITS USE IN DIFFUSIONS SEPARATION PROCESSES
EP1697287B1 (en) 2003-12-18 2015-08-26 ExxonMobil Chemical Patents Inc. Improvements in or relating to hydrogenation
WO2005058787A1 (en) 2003-12-18 2005-06-30 Exxonmobil Chemical Patents Inc. Improvements in or relating to hydroformylation
ATE517074T1 (en) * 2003-12-18 2011-08-15 Exxonmobil Chem Patents Inc IMPROVEMENTS IN OR RELATING TO CATALYTIZED REACTIONS
US7442365B1 (en) 2004-06-14 2008-10-28 Uop Llc Process for preparing molecular sieve beads
US7320782B1 (en) * 2004-06-14 2008-01-22 Uop Llc Process for preparing a layered molecular sieve composition
PL1616839T3 (en) * 2004-07-16 2014-03-31 Uop Llc Process for synthesizing molecular sieves
GB0512377D0 (en) 2005-06-17 2005-07-27 Exxonmobil Chem Patents Inc Oligomerisation of olefins with zeolite catalyst
US8278235B2 (en) * 2007-06-20 2012-10-02 Basf Corporation Structurally enhanced cracking catalysts
US9108181B2 (en) * 2007-06-20 2015-08-18 Basf Corporation Structurally enhanced cracking catalysts
EP2067528A1 (en) 2007-11-29 2009-06-10 Uop Llc Process for preparing a layered molecular sieve composition
US8193402B2 (en) 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
EP2225351A4 (en) 2007-12-03 2016-11-09 Gevo Inc Renewable compositions
CN101314135B (en) * 2008-06-27 2011-05-11 吉林大学 Method for preparing double-catalysis center molecular sieve nucleocapsid material with hydrothermal/solvent-thermal system
US8476350B2 (en) * 2008-12-24 2013-07-02 Exxonmobil Research And Engineering Company Triglyceride plasticizer and process of making
EP2513153A1 (en) 2009-12-15 2012-10-24 ExxonMobil Chemical Patents Inc. Temperature control of an oligomerisation process and reactor
US8771815B2 (en) 2009-12-17 2014-07-08 Exxonmobil Research And Engineering Company Process for making triglyceride plasticizer
SG182407A1 (en) 2010-01-08 2012-08-30 Gevo Inc Integrated methods of preparing renewable chemicals
WO2011140560A1 (en) 2010-05-07 2011-11-10 Gevo, Inc. Renewable jet fuel blendstock from isobutanol
WO2012033562A1 (en) 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudates including zeolite catalysts and their use in oligomerization processes
US8742187B2 (en) 2011-04-19 2014-06-03 Gevo, Inc. Variations on prins-like chemistry to produce 2,5-dimethylhexadiene from isobutanol
US9505685B2 (en) 2011-07-25 2016-11-29 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013886A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
US9573861B2 (en) 2011-07-25 2017-02-21 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013884A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Process for nitrile removal from hydrocarbon feeds
WO2013013885A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
KR20130017165A (en) * 2011-08-10 2013-02-20 서강대학교산학협력단 Zeolite core/silica zeolite shell composites, method of prefaring the same and catalystic use the same
EP2797854B9 (en) 2011-12-30 2017-08-30 K+S KALI GmbH Composition of a magnesium sulphate urea compound
CA3092028C (en) 2012-01-13 2022-08-30 Lummus Technology Llc Process for separating hydrocarbon compounds
US9670113B2 (en) 2012-07-09 2017-06-06 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
DE102012025141A1 (en) 2012-12-21 2014-06-26 K+S Aktiengesellschaft Composition of a magnesium-urea compound
US10047020B2 (en) 2013-11-27 2018-08-14 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA3123783A1 (en) 2014-01-08 2015-07-16 Lummus Technology Llc Ethylene-to-liquids systems and methods
CA3225180A1 (en) 2014-01-09 2015-07-16 Lummus Technology Llc Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
RU2017131237A (en) 2015-03-20 2019-04-22 Эксонмобил Кемикэл Пейтентс Инк. METHOD FOR TURNING THE CONTAINING OLEFIN HYDROCARBON RAW MATERIALS INTO PRODUCT OF OLIGOMERIZATION REACTION OR HYDRAULIC PRODUCT OF OLIGOMERIZATION REACTION
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US20160312134A1 (en) * 2015-04-24 2016-10-27 Uop Llc Process for the production of jet-range hydrocarbons
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
EP3786138A1 (en) 2015-10-16 2021-03-03 Lummus Technology LLC Oxidative coupling of methane
WO2017180910A1 (en) 2016-04-13 2017-10-19 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
WO2018118105A1 (en) 2016-12-19 2018-06-28 Siluria Technologies, Inc. Methods and systems for performing chemical separations
DE102017104877A1 (en) 2017-03-08 2018-09-13 K+S Aktiengesellschaft Magnesium sulfate granules based on synthetic magnesium sulfate
DE102017104876A1 (en) 2017-03-08 2018-09-13 K+S Aktiengesellschaft Use of magnesium sulfate granules
ES2960342T3 (en) 2017-05-23 2024-03-04 Lummus Technology Inc Integration of oxidative methane coupling procedures
EP3649097A4 (en) 2017-07-07 2021-03-24 Lummus Technology LLC Systems and methods for the oxidative coupling of methane
CN109908944B (en) * 2019-04-12 2020-09-15 西南化工研究设计院有限公司 Catalyst for preparing nonene and dodecene by oligomerization of propylene and preparation method thereof

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4203869A (en) * 1976-09-24 1980-05-20 Mobil Oil Corporation ZSM-5 Containing aluminum-free shells on its surface
US4394362A (en) * 1981-04-28 1983-07-19 Chevron Research Company Crystalline silicate particle having an aluminum-containing outer shell
EP0118632A1 (en) * 1983-03-14 1984-09-19 Mobil Oil Corporation Crystalline materials and process for their manufacture
US4975401A (en) 1983-05-02 1990-12-04 Mobil Oil Corporation ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes
US4575416A (en) 1984-07-16 1986-03-11 Mobil Oil Corporation Hydrodewaxing with mixed zeolite catalysts
FR2600557B1 (en) * 1986-06-24 1993-03-19 Elf France BINARY ZEOLITIC SYSTEMS, THEIR SYNTHESIS AND THEIR USE
AU613954B2 (en) 1987-10-07 1991-08-15 Mobil Oil Corporation Olefin oligomerization
US4788374A (en) * 1987-12-23 1988-11-29 Mobil Oil Corporation Zeolite catalysis
DE3914817C2 (en) 1989-05-05 1995-09-07 Huels Chemische Werke Ag Process for oligomerizing olefins
GB9114390D0 (en) 1991-07-03 1991-08-21 Shell Int Research Hydrocarbon conversion process and catalyst composition
JP2800499B2 (en) * 1991-09-18 1998-09-21 日産自動車株式会社 Hydrocarbon adsorbent
US5250484A (en) 1991-11-26 1993-10-05 Mobil Oil Corporation Surface modified porous acidic crystalline catalyst
AU671463B2 (en) 1992-06-05 1996-08-29 Exxon Chemical Patents Inc. ZSM-22 zeolite
US5284989A (en) 1992-11-04 1994-02-08 Mobil Oil Corporation Olefin oligomerization with surface modified zeolite catalyst
SG48109A1 (en) * 1993-04-23 1998-04-17 Exxon Chemical Ltd Molecular sieve layers and processes for their manufacture
CA2182994A1 (en) * 1994-02-22 1995-08-24 Exxonmobil Chemical Patents, Inc. Oligomerization and catalysts therefor
DE19619138C2 (en) * 1996-05-11 2002-04-18 Degussa Process for the production of vinylated organic silicon compounds

Also Published As

Publication number Publication date
CN1173858A (en) 1998-02-18
DE69600667T2 (en) 1999-04-08
JPH10513459A (en) 1998-12-22
US6013851A (en) 2000-01-11
CA2211043C (en) 2001-03-20
DE69600667D1 (en) 1998-10-22
EP0808298B1 (en) 1998-09-16
US6300536B1 (en) 2001-10-09
ATE171155T1 (en) 1998-10-15
GB9502342D0 (en) 1995-03-29
JP3937241B2 (en) 2007-06-27
EP0808298A1 (en) 1997-11-26
CN1277951A (en) 2000-12-27
AU4539596A (en) 1996-08-27
AU697790B2 (en) 1998-10-15
CN1072187C (en) 2001-10-03
WO1996024567A1 (en) 1996-08-15
KR19980701991A (en) 1998-06-25
KR100360734B1 (en) 2003-02-07
ES2122782T3 (en) 1998-12-16
ZA96891B (en) 1996-07-16

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