CA2222166A1 - Catalyst, processes and polymer products therefrom - Google Patents
Catalyst, processes and polymer products therefrom Download PDFInfo
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- CA2222166A1 CA2222166A1 CA002222166A CA2222166A CA2222166A1 CA 2222166 A1 CA2222166 A1 CA 2222166A1 CA 002222166 A CA002222166 A CA 002222166A CA 2222166 A CA2222166 A CA 2222166A CA 2222166 A1 CA2222166 A1 CA 2222166A1
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- Prior art keywords
- aluminum
- cobalt
- catalyst
- polymer
- ethylene glycol
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Abstract
A cobalt/aluminum catalyst for the polymerization of polyesters of terephthalic acid and an ethylene glycol, a process for the preparation of such catalysts, a process for the polymerization of terephthalic acid and an ethylene glycol, a process of spinning fibers of such polyesters where reduced spinneret wiping is achieved, and fibers of such polyesters containing catalyst residues of cobalt/aluminum, and films or bottles of said polyesters.
Description
CA 02222166 1997-11-2~
W O 96/41828 PCT~U536/08q84 TIT~E
Catalyst, Processes and Polymer Products Therefrom This invention relates to a catalyst useful for the preparation of high molecular weight polyester polymers of terephthalic acid and ethylene glycol, to the process for the production of such high molecular weight polyester polymers, to such high molecular weight polyester polymers made by the process using the catalyst, and to products made from such polyester high molecular weight polymers such as fibers, films, and bottles.
Many commercial processes for the production of high molecular weight polyester polymers of terephthalic acid and ethylene glycol employ an antimony catalyst. The use of an antimony catalyst presents some problems when the polymer is melt spun into fibers, i.e., the antimony catalyst residues form deposits around spinneret holes. These deposits must be wiped off from time to time or the filaments will be defective. It is believed that the antimony deposits form because antimony is present in the polymer as antimony glycollate, which boils at about the temperature of the spinneret. The antimony glycollate vaporizes, and then hydrolyzes, leaving a non-volatile antimony containing deposit at the spinneret. A non-antimony containing catalyst is, therefore, a desirable goal.
High molecular weight polyester polymers of terephthalic acid and ethylene glycol are usually produced by one of three different processes, namely, (1) the direct esterification and then polymerization of pure terephthalic acid and ethylene glycol. (This direct polymerization process is satisfactory only if the ingredients are of high purity.) (2) Transesterification of dimethylterephthalate (DMT) and CA 02222166 1997-ll-2~
W O96/41828 PCT~US96/08484 ethylene glycol to form, what is called in the art, "DMT monomer." The transesterification usually takes place in the presence of a manganese, zinc, or lithium catalyst. The DMT monomer is a mixture of ester products (low molecular weight polymer) in which most of the end groups are glycoxyl, and the mixture contains molecules with a degree of polymerization that is 1, 2, or 3. The DMT monomer is then further polymerized to high molecular weight polymer often with an antimony catalyst. The manganese catalyst used in the transesterification reaction tends to cause undesirable color in the final product unless it is sequestered; so phosphorus compounds, for example, H3PO4, are often added before the DMT monomer is polymerized to sequester the manganese catalyst residue. (3) Reaction of medium purity (polymer grade) terephthalic acid and ethylene glycol to form, what is called in the art, "oligomer." The oligomer mixture contains color forming catalyst residues from the manufacture of terephthalic acid. These catalyst residues include manganese, iron, and molybdenum.
These catalyst residues are then sequestered by the addition of a phosphoric compound, for example, H3PO4, and then polymerized (polycondensed) to form high molecular weight polymer. The oligomer has a degree of polymerization of about 7, has 500 to 1000 carboxyl end groups per 10 to the 6th power grams of oligomer. Some cyclic materials are present in the oligomer. (This third process does not require the highly purified starting materials necessary for the first process described above.) The catalyst of the invention is useful in all three of these processes. In the first process described, the catalyst of the invention may be added at the direct esterification step or at the beginning of the polymerization; in the second process described, the catalyst will be added after the DMT
monomer is formed and after the manganese catalyst is sequestered (deactivated); and in the third process the CA 02222166 1997-11-2~
W O 96/41828 PCTrUS96/08484 catalyst will be added after the color-forming metal impurities in the oligomer are deactivated.
Combinations of metals compounds have been employed in the prior art as catalyst for the preparation of high molecular weight polymers of terephthalic acid and ethylene glycols: see, for example, Nichols U.S. Patent 5,116,311; Engle-Bader et al. U.S. Patent 5,166,938; and Kosky et al. U.S. Patent 4,590,259.
The present invention is a polymerization catalyst useful for the preparation of high molecular weight polymers of terephthalic acid and ethylene glycol comprising a cobalt salt and an aluminum compound selected from the group consisting of aluminum chloride, aluminum hydroxide, aluminum acetate, and aluminum hydroxychloride dissolved in ethylene glycol, where the mole ratio of aluminum to cobalt is 0.25 to 1 to 16 to 1, and where the mole ratio of chlorine to aluminum is in the range of 0 (no chlorine) to 3 to 1.
The present invention is also a process for the production of ethylene terephthalate polyester polymer, which comprises combining a polymerization catalyst formed by combining a cobalt salt that is soluble in ethylene glycol and aluminum compound selected from aluminum chloride, aluminum hydroxide, aluminum acetate, and aluminum hydroxychloride in ethylene glycol, where the mole ratio of aluminum to cobalt is 0.25 to 1 to 16 to 1 and a chlorine to aluminum ratio in the range of 0.25 to 3 with (a) terephthalic acid and ethylene glycol, or (b) low molecular weight ethylene terephthalate polymer (also called DMT monomer), or (c) oligomer, where the concentration of cobalt in the thus formed mixture is in the range of about 10 to 100 parts per million parts of the mixture, and polymerizing the mixture. The aluminum to cobalt mole ratio may be in the range of 1 to 1 to 16 to 1 in some circumstances. The optimum W O 96/41828 PCT~US96/08484 aluminum to'cobalt mol ratio for good polymerization and color is about 0.67.
Useful cobalt salts include cobaltous'acetate tetrahydrate, cobaltous nitrate, cobaltous chloride, cobalt acetylacetonate, cobalt napthenate, cobalt hydroxide, and cobalt salicyl salicylate. The preferred cobalt salts are soluble in ethylene glycol in the 100-10,000 parts per million cobalt range.
- This invention is also a process for the preparation of a catalyst for the preparation of ethylene terephthalate polyester polymer, which comprises heating a cobalt salt and aluminum compound selected from the group consisting of aluminum chloride, aluminum hydroxide, aluminum acetate, and al-~minllm hydroxychloride in ethylene glycol to a temperature in the range of about 40,to 180 degrees C
where the aluminum to cobalt mole ratio is in the range of 0.25 to 1 to 16 to 1. A temperature range of about 40 to 180 degrees C is satisfactory: lower temperatures lead to less corrosion of equipment when chloride is present with the aluminum or cobalt salts.
This invention is also an ethylene terephthalate polyester polymer having a NLRV of at least 12 and containing catalyst residues of cobalt and aluminum; in other words derived from cobalt salt(s) and from aluminum chloride and/or aluminum hydroxychloride. The polymer can be in the form of a fiber or film or bottle.
This invention is also a process for the production of ethylene terephthalate polyester polymer fiber in which there is a reduced need to wipe antimony deposits from the spinneret face which comprises melt spinning a molten mixture of ethylene terephthalate polyester polymer containing catalyst residue of cobalt salt and an aluminum compound selected from the group consistingof aluminum chloride and aluminum hydroxychloride.
CA 02222166 1997-11-2~
De~;le~ Descript; nn When the catalyst of the present invention is used to prepare polyester polymer from polymer grade terephthalic acid or high purity terephthalic acid, the terephthalic acid (TPA) and ethylene glycol will be fed into a reactor. The reaction to form oligomer will proceed without catalyst and is usually conducted at a temperature of about 240 to about 300 degrees C
and at a pressure of about 0 to 50 pounds per square inch (0 to 3.5 Kg/sq cm). Usually, the reactor will be fed more than an stoichiometric amount of the ethylene glycol, and the excess glycol separated by distillation. To the oligomer stream may then be added coloring agents such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide that are used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide is added to the oligomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. Since polymer grade TPA and plant grade ethylene glycol contain various amount of metals, for example, iron, titanium, molybdenum, cobalt, and manganese, that tend to give color to the final product, a phosphorus compound, such as orthophosphoric acid, is often added to TPA/glycol slurry that feeds the direct esterfier or to the oligomer line and mixed to sequester these color forming metal impurities.
Then the catalyst of the present invention is added to the oligomer stream, and the oligomer is then subjected to polycondensation in the usual manner.
CA 02222166 1997-11-2~
W O 96/41828 PCTrUS96/08484 When the catalyst of the present invention is used to prepare polyester polymer from dimethylterephthalate (DMT), the DMT and ethylene glycol will be fed into a reactor aIong with a transesterification catalyst, for example, manganese, zinc, or lithium acetates, or glycollates. The reaction that forms DMT monomer is usually conducted at a temperature of about 190 to about 260 degrees C and at a pressure of about 0 to 10 pounds per square inch (0 to 0.7 Kg/ sq cm). Sodium or other metal dimethyl isophthalate-5-sulfonate may be added with the catalyzed glycol to make a copolymer. Methanol will be separated by distillation. To the DMT monomer stream may then be added fillers, coloring agents, such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide (TiO2) is added to the DMT monomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. A phosphorus compound such as orthophosphoric acid is then added at this point to (deactivate) sequester the ester exchange catalyst, for example, manganese compound. Then the catalyst of the present invention is added to the stream, and the DMT monomer subjected to polycondensation in the usual manner.
When the catalyst of the present invention is used to prepare polyester polymer from pure terephthalic acid, the terephthalic acid (TPA) and ethylene glycol will be fed into a reactor. The CA 02222166 1997-11-2~
W O 96/41828 PCT~US96/08484 reaction to form oligomer will proceed without catalyst and is usually conducted at a temperature of about 240 to about 300 degrees C and at a pressure of about 0 to 50 pounds per square inch gauge (0 to 3.5 Kg/sq cm).
Usually, the reactor will be fed more than a stoichiometric amount of the ethylene glycol, and the excess glycol separated by distillation. To the oligomer stream may then be added coloring agents, such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid, and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide is added to the oligomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. Then the catalyst of the present invention is added to the oligomer stream, and the oligomer subjected to polycondensation in the usual manner.
In order to be a viable replacement for the traditional antimony catalyst used to polymerize terephthalic acid/ethylene glycol polymers, the desired catalyst should meet the following criteria: 1. It is preferably soluble in ethylene glycol, but some catalyst may be in slurry form, such as the reaction product of aluminum hydroxide and cobalt hydroxide. 2.
It should produce a polymer which, when formed into a yarn, has a color, dyeability, and durability about as good as the yarn made with antimony catalyst. 3. It should be capable of being used in the same equipment that is presently used for antimony catalyst. 4. It should have a reactivity as good as the antimony CA 02222166 1997-11-2~
WO 96/41828 PCTAUS9~,'08484 catalyst. 5. It should not deposit on the spinnerets.
6. It should cost about the same as an antimony catalyst. 7. The catalyst residues should be not be toxic. The catalyst of the invention meets these criteria.
The catalyst of the invention may be prepared as follows:
1. To a 500 cc agitated flasks with reflux condenser add:
0.64 grams of Cobalt diacetate. 4H2O
dissolved in about 209 grams of ethylene glycol at room temperature.
10.39 grams of Nalco 8676 (aluminum hydroxychloride) is then added with mixing. (Nalco lS 8676 has an aluminum to chlorine mole ratio of about 0.5. Nalco 8676 is a colloidal suspension in water of aluminum hydroxychloride particles. It is a 10~
solution (based on Al2O3) of 20 nanometer particles.) 2. Heat 110 to 160 degrees C and hold about 30 minutes. In ethylene glycol the solution turns from a pink to a deep purple. Then cool the catalyst solution. Analyses of the catalyst (Item 3 in the table below) indicated that the chlorine to aluminum mole ratio was about 0.5, and the aluminum to cobalt mole ratio about 8 to 1.
Other catalysts were prepared by the above procedure and tabulated below.
CA 02222166 1997-11-2~
WO 96/41828 PCT~US96/08484 TART.~ OF POT~YY~RT~TTON CATAT~ysT SOT~UTIONS
SAMPLE MOLS Al GR~MS GR~MS GRAMS OF
NO. ------ CoAc2.4H20 NALCO 8676 ETHYLENE
MOLS Co GLYCOL
1 2 .64 2.57 216.8 2 4 .64 5.14 214.2 3 8 .64 10.3 209 4 16 .64 20.6 198.8 GRAMS OF
NALCO 8187*
4 .64 2.6 216.8 6 8 .64 5.2 214 GRAMS OF
AlC13 7 2 .64 .686 218.7 8 4 .64 1.372 218 9 8 .64 2.744 216.6 16 .64 5.489 213.9 *Nalco 8187 is aluminum hydroxychloride solution in water having an aluminum content measured as A1203 of 22~ by weight.
(Nalco 8676 and 8187 were analyzed. The percent solids was determined by drying at 110 degrees C. Nalco 8676 was 21.9 +/- 1.6~ solid, and Nalco 8187 was 46.2 +/- 0.39~ solid. When calcined at 900 degrees C, Nalco 8676 was 9. 75 +/- 0.23~ solid, and Nalco 8187 was 22.6 +/- 0. 05~ solid. The aluminum content of Nalco 8676 was 5.68~ by weight, and the chlorine content was 3.77~. The aluminum content of Nalco 8187 was 12.4%, and the chlorine content was 9. 3~.) To make polymer in a 1 liter resin kettle, add 400 grams of catalyst-free TPA oligomer. Add 8.6 grams of the catalyst solutions made per above table to the oligomer with ethylene glycol to make a 2/1 mole ratio of ethylene glycol/terephthalate. The total ethylene glycol and catalyst solution is 129 grams.
CA 02222166 1997-11-2~
It is common commercial practice to vary the composition of polyester fibers by including, in the mixture to be, polymerized monomers that improve the dyeability of fibers made from the polymer. Sodium isophthalic acid-5-sulfonate glycol ester or trimellitic acid glycol ester groups have often been incorporated in the polyester chains to improve dyeability. The catalyst of the present invention is compatible with making such copolymers.
The invention is further illustrated in the following polymerization Examples, all parts and percentages being by weight, except as indicated. NLRV
and LRV are measures of relative viscosity, being the ratio at 25 degrees C of the flow times in a capillary viscometer for a solution and for the solvent. The solution is 4.75 wt. percent of polymer in solvent.
The solvent for NLRV is hexafluoroisopropanol. The solvent for LRV is hexafluoroisopropanol containing 100 parts per million H2SO4.
ExamDles Example 1 Lab Resin Kettle Example Four hundred grams catalyst-free oligomer that was made from pure terephthalic acid and ethylene glycol was combined with 120.4 grams of ethylene glycol and 8.6 grams of ethylene glycol containing the cobalt/all~min-~m catalyst (#3 in the above table).
The amount of catalyst was such that the final polymer contained 14.8 parts per million cobalt, and 54 parts per million aluminum. The mixture was stirred at 60 revolutions per minute, heated to 265 degrees C for 30 minutes, to dissolve and remelt the oligomer into the glycol mixture, and then heated to 275 degrees C at a pressure of 120 millimeters of mercury and held at this condition for 20 minutes. The temperature was then CA 02222166 1997-11-2~
W O 96/41828 PCT~US96/08484 raised to 280 degrees C, and the vacuum adjusted to 30 millimeters of mercury and held at this condition for 20 minutes. Then the temperature was raised to 285 degrees, and the pressure lowered to about one (+/-0.5) millimeters of mercury and held until the agitatortorque reached 4 pounds per inch (71 Kg/meter) at 60 revolutions per minute. Then the agitator speed was lowered to 40 revolutions per minute, and the torque allowed to rise back to 4 pounds per inch. At this point, the polymer was cast in 1/2" (13 mm) wide strips in a pan of cold water. The polymer was then dried and crystallized at 90 degrees for one hour in a vacuum oven and then ground to pass through a 4 millimeters screen, and then the properties of the polymer determined. The polymer had an NLRV of 24.19, 26.5 COOH ends per 106 grams of polymer, 1.208~ DEG
(diethylene glycol), and a color on the Hunter scale L = 74.3, a = -0.5, and b = 6.8. The polymerization rate was about the same as that obtained with 200 part per million antimony; the color was close to that obtained from 200 part per million antimony, and the amount of diethylene glycol was somewhat higher than that obtained using 200 parts per million antimony, but still acceptable.
Similar Examples with other catalysts prepared, as shown in the "Table of Polymerization Catalyst Solutions," give similar results to this Example 1.
Example 2 and Control Examples Semi-Works Example Control (~nt;~y Cat~ly~t) Dimethyl terephthalate (DMT) is fed at 84 pounds (38 Kg) per hour to plate 15 of a 20 plate ester exchange distillation column. Catalyzed glycol was made by dissolving 590 grams of manganese acetate with 4 waters of hydration, 115 grams of sodium acetate, CA 02222l66 l997-ll-2~
and 853 grams of antimony glycollate at about 50 degrees C in 1200 pounds (545 Kg) of ethylene glycol.
This catalyst solution was fed at 210 milliliters/minute to plate 17 of the ester exchange column. Virgin glycol was fed to the calandria reboiler at about 70 milliliters/minutes to control the calandria temperature at 237+/-2 degrees C. Glycol boil up in the column was provided by Dowtherm~ heat to the c-alandria's heat exchanger. Methanol was removed from the top of the column, and methanol reflux was provided to condense the glycol vapor. The monomer produced in the calandria was then pumped and filtered through a monomer line to the flasher. 13.8 milliliters/minute of 1~ H3PO4 in glycol was added to the monomer line and mixed with the monomer to deactivate the ester exchange manganese catalyst. Then 9.5 milliliters/minute of 596 TiO2 in glycol was injected into the monomer line and mixed with the monomer. The monomer was then prepolymerized in a Dowtherm~-heated flashing vessel operated at 245 degrees C and 90 millimeters of mercury pressure. The discharge from the flasher was fed to a Dowtherm~
heated, agitated prepolymerization vessel operated at 275 degrees C and 30 millimeters of mercury pressure.
The prepolymer from the prepolymerization vessel was then fed to a horizontal screen/wire filming agitated finishing vessel. This vessel was run at 285 degrees C
and a pressure to produce 19. 7 +/- 0. 6 LRV. The polymer produced was pumped to a spinning machine where yarn was spun at 290 degrees C, quenched, and steam drawn to produce a 70 denier (78 dtex) 34 filament trilobal cross section yarn. This process and product properties will be compared with product made by use of the catalyst of the invention.
Dowtherm6) is a registered trademark of the Dow Chemical Co.
CA 02222166 1997-ll-2~
r~~ yBt of the Tnv~-nt; tln W; th No T~ner The same process used to prepare the control yarn was used except, instead of dissolving antimony glycollate in the catalyzed glycol fed to the exchanger, the cobalt/aluminum catalyst was prepared separately. 250 grams of cobalt acetate with 4 waters of hydration were dissolved in 180 pounds (82 Kg) of ethylene glycol. 4061 grams of Nalco 8676 was added, and the mixture was heated to 160 degrees C to form a clear purple solution. This catalyst solution was injected into the monomer line at 24 milliliters/minute after the 11.4 milliliters/minute of 1% H3PO4 solution in glycol was added to deactivate the manganese catalyst.
~ y8t of t-h~ Tnv~nt; nn W; l-h Tnn~r The catalyst was run the same way as described in the prior paragraph except 2 parts per million on a polymer basis of carboxyl violet was added with the TiO2 to change the hue color of the fiber.
CA 02222166 1997-11-2~
W O 96/41828 PC~rrUS96/08484 TABLE: results of the control and invention catalyst runs.
Without Control Toner With Toner Finisher pressure, mm Hg 2.96 2.88 3.02 %DEG, analyzed 0.9 0.83 0.87 %TiO2, analyzed 0.096 0.097 0.093 Sb analyzed, ppm 240 Cobalt added, ppm 0 24 24 Mn, added, ppm 98 98 98 Toner added, ppm 0 0 2 Tenacity, gpd (g/dtex) 3.95(3.6) 3.9(3.5) 3.95(3.6) Elongation at break, % 32 33.4 33.4 Boil off shrinkage, % 8 7.7 7.9 Draw tension, grams 105 104 103 (1.2X Draw ratio, 185~C, 150 ypm-= 137 mpm) Glf dye 109 108 103 Tube color, Hunter lab L 84.7 83.3 82.3 b 1.2 2.5 1.15 Color cards, Hunter lab L 89.4 87.4 87 a -.62 -.38 -.13 b .74 2.10 .76 No visual difference could be seen between control and invention catalyst run with toner.
There was no significant change in spinning filter pack pressure rise rate.
Invention and control yarns were judged equal in physical properties.
Invention yarn without toner was less white.
CA 02222166 1997-11-2~
Example 3 Semi-Works Draw Textured Feed Yarn Example Made with TPA Process Control Example Oligomer, with about 7 average degrees of polymerization, was made in a commercial direct esterfier reactor. A side stream was pumped to the semi-works' flashing vessel, prepolymerizer, and finishing vessels at 110 pounds (50 Kg) per hour. One item was made with no H3PO4, and one item was made with 14 milliliters/minute of 0.1~ H3PO4 that was injected into the oligomer line and mixed with a static mixer to deactivate color forming metal residues. Then 18.8 milliliters/minute of 1~ antimony solution in ethylene glycol as the polymerization catalyst and 23 milliliters/minute of 10~ TiO2, as the delustrant, was then added to the oligomer line and mixed with a static mixer. The polymer was spun through a filtration pack and spinneret to produce a 265 denier (294 dtex) 34 filament draw textured feed yarn, known as partially oriented yarn (POY). This yarn was textured at 700 meters/minute on a Barmag FK-6-900 texturing machine.
Invention Example The invention yarn was made in the same equipment, except that, instead of the antimony catalyst, 16 milliliters/minute of a cobalt aluminum catalyst solution was added to the oligomer line after the H3PO4 was injected. This catalyst was made by dissolving 250 grams of cobalt acetate with 4 waters of hydration in 180 pounds (82 Kg) of ethylene glycol. Then 4061 grams of Nalco 8676 was added. The mixture was then heated with agitation to 170 degrees C
to produce a deep blue solution. The solution's theoretical cobalt level is 0.0725~ and aluminum level is 0.263~.
CA 02222166 1997-11-2~
Results comparing cont-~~l and in.enti3n product.
Control With Invention Without H3PO4 H3PO4 With H3PO4 Finisher pressure mm Hg 3.86 2.28 4.94 Sb ppm 228 217 39(note 1) Tio2~ 0.31 0.28 0.30 P ppm 4(from TiO2) 3.5 10.1 COOH ends/106g 25 26 34 DEG% 1.15 1.12 1.31 Yarn properties Draw tension, g 109.5 109 115 (185 degrees C, 1.71Xx draw ratio, 185 ypm = 169 mpm) Note: 9 parts per million antimony comes from the antimony in TiO2. About 30 parts per million antimony is in the supply of oligomer.
Color on tubes Hunterlab L 84.9 85.7 83.7 a '-0.3 -0.3 0.4 b 1.9 1.14 0.9 W 62.8 67.8 65.9 color on cards L 91.0 91.9 90.0 a -1.0 -0.85 -0.2 b 2.55 1.6 1.1 W 69.5 76.1 75.3 ~-Tenacity, gpd 2.47(2.2) 2.44(2.2) 2.43(2.2) (g/dtex) Elongation, % 123.1 121.7 126.8 Colors of Control and Invention with H3PO4 were judged equivalent by visual examination.
~EN~ ~ .
CA 02222166 1997-11-2~
The textured yarn results show:
Control With Without H3PO4 H3PO4 Invention Tenacity, gpd 4.37(3.9) 4.19(3.8) 4.21(3.8) (g/dtex) Elongation % 22.38 21.06 21.17 Leesona shrinkage 18.2 20.0 17.9 (180 degrees F (82~C) in water,~
~ dye vs. std (100~) 101.1 103.1 102.1 Broken filaments 0.18(0.40) 0.38 (0.84) 0 per pound (per Kg) Additional Examples Similar polymerization experiments for the preparation of poly(ethylene terephthalate) polymer were carried out in which 0.83 mmoles of cobalt and 0.56 mmoles of aluminum were added to the mixture to be polymerized, using catalyst formed from cobalt diacetate and aluminum hydroxide, using catalyst formed from cobalt diacetate and aluminum triacetate and using catalyst formed from cobalt dihydroxide and aluminum hydroxide, and using catalyst formed from cobalt dihydroxide and aluminum triacetate in which 0.83 mmoles of cobalt and 0.28 mmoles of aluminum were added to the mixture to be polymerized, and using catalyst formed from cobalt diacetate and Nalco 8187 in which 0.84 mmoles of cobalt and 0.58 mmoles of aluminum were added to the mixture to be polymerized. The results were all highly satisfactory.
W O 96/41828 PCT~U536/08q84 TIT~E
Catalyst, Processes and Polymer Products Therefrom This invention relates to a catalyst useful for the preparation of high molecular weight polyester polymers of terephthalic acid and ethylene glycol, to the process for the production of such high molecular weight polyester polymers, to such high molecular weight polyester polymers made by the process using the catalyst, and to products made from such polyester high molecular weight polymers such as fibers, films, and bottles.
Many commercial processes for the production of high molecular weight polyester polymers of terephthalic acid and ethylene glycol employ an antimony catalyst. The use of an antimony catalyst presents some problems when the polymer is melt spun into fibers, i.e., the antimony catalyst residues form deposits around spinneret holes. These deposits must be wiped off from time to time or the filaments will be defective. It is believed that the antimony deposits form because antimony is present in the polymer as antimony glycollate, which boils at about the temperature of the spinneret. The antimony glycollate vaporizes, and then hydrolyzes, leaving a non-volatile antimony containing deposit at the spinneret. A non-antimony containing catalyst is, therefore, a desirable goal.
High molecular weight polyester polymers of terephthalic acid and ethylene glycol are usually produced by one of three different processes, namely, (1) the direct esterification and then polymerization of pure terephthalic acid and ethylene glycol. (This direct polymerization process is satisfactory only if the ingredients are of high purity.) (2) Transesterification of dimethylterephthalate (DMT) and CA 02222166 1997-ll-2~
W O96/41828 PCT~US96/08484 ethylene glycol to form, what is called in the art, "DMT monomer." The transesterification usually takes place in the presence of a manganese, zinc, or lithium catalyst. The DMT monomer is a mixture of ester products (low molecular weight polymer) in which most of the end groups are glycoxyl, and the mixture contains molecules with a degree of polymerization that is 1, 2, or 3. The DMT monomer is then further polymerized to high molecular weight polymer often with an antimony catalyst. The manganese catalyst used in the transesterification reaction tends to cause undesirable color in the final product unless it is sequestered; so phosphorus compounds, for example, H3PO4, are often added before the DMT monomer is polymerized to sequester the manganese catalyst residue. (3) Reaction of medium purity (polymer grade) terephthalic acid and ethylene glycol to form, what is called in the art, "oligomer." The oligomer mixture contains color forming catalyst residues from the manufacture of terephthalic acid. These catalyst residues include manganese, iron, and molybdenum.
These catalyst residues are then sequestered by the addition of a phosphoric compound, for example, H3PO4, and then polymerized (polycondensed) to form high molecular weight polymer. The oligomer has a degree of polymerization of about 7, has 500 to 1000 carboxyl end groups per 10 to the 6th power grams of oligomer. Some cyclic materials are present in the oligomer. (This third process does not require the highly purified starting materials necessary for the first process described above.) The catalyst of the invention is useful in all three of these processes. In the first process described, the catalyst of the invention may be added at the direct esterification step or at the beginning of the polymerization; in the second process described, the catalyst will be added after the DMT
monomer is formed and after the manganese catalyst is sequestered (deactivated); and in the third process the CA 02222166 1997-11-2~
W O 96/41828 PCTrUS96/08484 catalyst will be added after the color-forming metal impurities in the oligomer are deactivated.
Combinations of metals compounds have been employed in the prior art as catalyst for the preparation of high molecular weight polymers of terephthalic acid and ethylene glycols: see, for example, Nichols U.S. Patent 5,116,311; Engle-Bader et al. U.S. Patent 5,166,938; and Kosky et al. U.S. Patent 4,590,259.
The present invention is a polymerization catalyst useful for the preparation of high molecular weight polymers of terephthalic acid and ethylene glycol comprising a cobalt salt and an aluminum compound selected from the group consisting of aluminum chloride, aluminum hydroxide, aluminum acetate, and aluminum hydroxychloride dissolved in ethylene glycol, where the mole ratio of aluminum to cobalt is 0.25 to 1 to 16 to 1, and where the mole ratio of chlorine to aluminum is in the range of 0 (no chlorine) to 3 to 1.
The present invention is also a process for the production of ethylene terephthalate polyester polymer, which comprises combining a polymerization catalyst formed by combining a cobalt salt that is soluble in ethylene glycol and aluminum compound selected from aluminum chloride, aluminum hydroxide, aluminum acetate, and aluminum hydroxychloride in ethylene glycol, where the mole ratio of aluminum to cobalt is 0.25 to 1 to 16 to 1 and a chlorine to aluminum ratio in the range of 0.25 to 3 with (a) terephthalic acid and ethylene glycol, or (b) low molecular weight ethylene terephthalate polymer (also called DMT monomer), or (c) oligomer, where the concentration of cobalt in the thus formed mixture is in the range of about 10 to 100 parts per million parts of the mixture, and polymerizing the mixture. The aluminum to cobalt mole ratio may be in the range of 1 to 1 to 16 to 1 in some circumstances. The optimum W O 96/41828 PCT~US96/08484 aluminum to'cobalt mol ratio for good polymerization and color is about 0.67.
Useful cobalt salts include cobaltous'acetate tetrahydrate, cobaltous nitrate, cobaltous chloride, cobalt acetylacetonate, cobalt napthenate, cobalt hydroxide, and cobalt salicyl salicylate. The preferred cobalt salts are soluble in ethylene glycol in the 100-10,000 parts per million cobalt range.
- This invention is also a process for the preparation of a catalyst for the preparation of ethylene terephthalate polyester polymer, which comprises heating a cobalt salt and aluminum compound selected from the group consisting of aluminum chloride, aluminum hydroxide, aluminum acetate, and al-~minllm hydroxychloride in ethylene glycol to a temperature in the range of about 40,to 180 degrees C
where the aluminum to cobalt mole ratio is in the range of 0.25 to 1 to 16 to 1. A temperature range of about 40 to 180 degrees C is satisfactory: lower temperatures lead to less corrosion of equipment when chloride is present with the aluminum or cobalt salts.
This invention is also an ethylene terephthalate polyester polymer having a NLRV of at least 12 and containing catalyst residues of cobalt and aluminum; in other words derived from cobalt salt(s) and from aluminum chloride and/or aluminum hydroxychloride. The polymer can be in the form of a fiber or film or bottle.
This invention is also a process for the production of ethylene terephthalate polyester polymer fiber in which there is a reduced need to wipe antimony deposits from the spinneret face which comprises melt spinning a molten mixture of ethylene terephthalate polyester polymer containing catalyst residue of cobalt salt and an aluminum compound selected from the group consistingof aluminum chloride and aluminum hydroxychloride.
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De~;le~ Descript; nn When the catalyst of the present invention is used to prepare polyester polymer from polymer grade terephthalic acid or high purity terephthalic acid, the terephthalic acid (TPA) and ethylene glycol will be fed into a reactor. The reaction to form oligomer will proceed without catalyst and is usually conducted at a temperature of about 240 to about 300 degrees C
and at a pressure of about 0 to 50 pounds per square inch (0 to 3.5 Kg/sq cm). Usually, the reactor will be fed more than an stoichiometric amount of the ethylene glycol, and the excess glycol separated by distillation. To the oligomer stream may then be added coloring agents such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide that are used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide is added to the oligomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. Since polymer grade TPA and plant grade ethylene glycol contain various amount of metals, for example, iron, titanium, molybdenum, cobalt, and manganese, that tend to give color to the final product, a phosphorus compound, such as orthophosphoric acid, is often added to TPA/glycol slurry that feeds the direct esterfier or to the oligomer line and mixed to sequester these color forming metal impurities.
Then the catalyst of the present invention is added to the oligomer stream, and the oligomer is then subjected to polycondensation in the usual manner.
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W O 96/41828 PCTrUS96/08484 When the catalyst of the present invention is used to prepare polyester polymer from dimethylterephthalate (DMT), the DMT and ethylene glycol will be fed into a reactor aIong with a transesterification catalyst, for example, manganese, zinc, or lithium acetates, or glycollates. The reaction that forms DMT monomer is usually conducted at a temperature of about 190 to about 260 degrees C and at a pressure of about 0 to 10 pounds per square inch (0 to 0.7 Kg/ sq cm). Sodium or other metal dimethyl isophthalate-5-sulfonate may be added with the catalyzed glycol to make a copolymer. Methanol will be separated by distillation. To the DMT monomer stream may then be added fillers, coloring agents, such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide (TiO2) is added to the DMT monomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. A phosphorus compound such as orthophosphoric acid is then added at this point to (deactivate) sequester the ester exchange catalyst, for example, manganese compound. Then the catalyst of the present invention is added to the stream, and the DMT monomer subjected to polycondensation in the usual manner.
When the catalyst of the present invention is used to prepare polyester polymer from pure terephthalic acid, the terephthalic acid (TPA) and ethylene glycol will be fed into a reactor. The CA 02222166 1997-11-2~
W O 96/41828 PCT~US96/08484 reaction to form oligomer will proceed without catalyst and is usually conducted at a temperature of about 240 to about 300 degrees C and at a pressure of about 0 to 50 pounds per square inch gauge (0 to 3.5 Kg/sq cm).
Usually, the reactor will be fed more than a stoichiometric amount of the ethylene glycol, and the excess glycol separated by distillation. To the oligomer stream may then be added coloring agents, such as carbon black, delustrants, opaquing agents, color, and thermal stabilizers, copolymerization additives such as glycol esters of sodium or other metal dimethyl isophthalate-5-sulfonate, isophthalic acid, trimellitic acid, and the like. Titanium dioxide is a conventional additive; it serves as a whitening agent and a delustrant. Most commercial grades of titanium dioxide used in polyester fiber contain antimony compounds which serve as thermal and ultraviolet light stabilizers; so if titanium dioxide is added to the oligomer, the final product will still contain some antimony, and antimony will show up in the analysis of the polymer. The antimony in the TiO2 is chemically bound in the TiO2 crystal. Then the catalyst of the present invention is added to the oligomer stream, and the oligomer subjected to polycondensation in the usual manner.
In order to be a viable replacement for the traditional antimony catalyst used to polymerize terephthalic acid/ethylene glycol polymers, the desired catalyst should meet the following criteria: 1. It is preferably soluble in ethylene glycol, but some catalyst may be in slurry form, such as the reaction product of aluminum hydroxide and cobalt hydroxide. 2.
It should produce a polymer which, when formed into a yarn, has a color, dyeability, and durability about as good as the yarn made with antimony catalyst. 3. It should be capable of being used in the same equipment that is presently used for antimony catalyst. 4. It should have a reactivity as good as the antimony CA 02222166 1997-11-2~
WO 96/41828 PCTAUS9~,'08484 catalyst. 5. It should not deposit on the spinnerets.
6. It should cost about the same as an antimony catalyst. 7. The catalyst residues should be not be toxic. The catalyst of the invention meets these criteria.
The catalyst of the invention may be prepared as follows:
1. To a 500 cc agitated flasks with reflux condenser add:
0.64 grams of Cobalt diacetate. 4H2O
dissolved in about 209 grams of ethylene glycol at room temperature.
10.39 grams of Nalco 8676 (aluminum hydroxychloride) is then added with mixing. (Nalco lS 8676 has an aluminum to chlorine mole ratio of about 0.5. Nalco 8676 is a colloidal suspension in water of aluminum hydroxychloride particles. It is a 10~
solution (based on Al2O3) of 20 nanometer particles.) 2. Heat 110 to 160 degrees C and hold about 30 minutes. In ethylene glycol the solution turns from a pink to a deep purple. Then cool the catalyst solution. Analyses of the catalyst (Item 3 in the table below) indicated that the chlorine to aluminum mole ratio was about 0.5, and the aluminum to cobalt mole ratio about 8 to 1.
Other catalysts were prepared by the above procedure and tabulated below.
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WO 96/41828 PCT~US96/08484 TART.~ OF POT~YY~RT~TTON CATAT~ysT SOT~UTIONS
SAMPLE MOLS Al GR~MS GR~MS GRAMS OF
NO. ------ CoAc2.4H20 NALCO 8676 ETHYLENE
MOLS Co GLYCOL
1 2 .64 2.57 216.8 2 4 .64 5.14 214.2 3 8 .64 10.3 209 4 16 .64 20.6 198.8 GRAMS OF
NALCO 8187*
4 .64 2.6 216.8 6 8 .64 5.2 214 GRAMS OF
AlC13 7 2 .64 .686 218.7 8 4 .64 1.372 218 9 8 .64 2.744 216.6 16 .64 5.489 213.9 *Nalco 8187 is aluminum hydroxychloride solution in water having an aluminum content measured as A1203 of 22~ by weight.
(Nalco 8676 and 8187 were analyzed. The percent solids was determined by drying at 110 degrees C. Nalco 8676 was 21.9 +/- 1.6~ solid, and Nalco 8187 was 46.2 +/- 0.39~ solid. When calcined at 900 degrees C, Nalco 8676 was 9. 75 +/- 0.23~ solid, and Nalco 8187 was 22.6 +/- 0. 05~ solid. The aluminum content of Nalco 8676 was 5.68~ by weight, and the chlorine content was 3.77~. The aluminum content of Nalco 8187 was 12.4%, and the chlorine content was 9. 3~.) To make polymer in a 1 liter resin kettle, add 400 grams of catalyst-free TPA oligomer. Add 8.6 grams of the catalyst solutions made per above table to the oligomer with ethylene glycol to make a 2/1 mole ratio of ethylene glycol/terephthalate. The total ethylene glycol and catalyst solution is 129 grams.
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It is common commercial practice to vary the composition of polyester fibers by including, in the mixture to be, polymerized monomers that improve the dyeability of fibers made from the polymer. Sodium isophthalic acid-5-sulfonate glycol ester or trimellitic acid glycol ester groups have often been incorporated in the polyester chains to improve dyeability. The catalyst of the present invention is compatible with making such copolymers.
The invention is further illustrated in the following polymerization Examples, all parts and percentages being by weight, except as indicated. NLRV
and LRV are measures of relative viscosity, being the ratio at 25 degrees C of the flow times in a capillary viscometer for a solution and for the solvent. The solution is 4.75 wt. percent of polymer in solvent.
The solvent for NLRV is hexafluoroisopropanol. The solvent for LRV is hexafluoroisopropanol containing 100 parts per million H2SO4.
ExamDles Example 1 Lab Resin Kettle Example Four hundred grams catalyst-free oligomer that was made from pure terephthalic acid and ethylene glycol was combined with 120.4 grams of ethylene glycol and 8.6 grams of ethylene glycol containing the cobalt/all~min-~m catalyst (#3 in the above table).
The amount of catalyst was such that the final polymer contained 14.8 parts per million cobalt, and 54 parts per million aluminum. The mixture was stirred at 60 revolutions per minute, heated to 265 degrees C for 30 minutes, to dissolve and remelt the oligomer into the glycol mixture, and then heated to 275 degrees C at a pressure of 120 millimeters of mercury and held at this condition for 20 minutes. The temperature was then CA 02222166 1997-11-2~
W O 96/41828 PCT~US96/08484 raised to 280 degrees C, and the vacuum adjusted to 30 millimeters of mercury and held at this condition for 20 minutes. Then the temperature was raised to 285 degrees, and the pressure lowered to about one (+/-0.5) millimeters of mercury and held until the agitatortorque reached 4 pounds per inch (71 Kg/meter) at 60 revolutions per minute. Then the agitator speed was lowered to 40 revolutions per minute, and the torque allowed to rise back to 4 pounds per inch. At this point, the polymer was cast in 1/2" (13 mm) wide strips in a pan of cold water. The polymer was then dried and crystallized at 90 degrees for one hour in a vacuum oven and then ground to pass through a 4 millimeters screen, and then the properties of the polymer determined. The polymer had an NLRV of 24.19, 26.5 COOH ends per 106 grams of polymer, 1.208~ DEG
(diethylene glycol), and a color on the Hunter scale L = 74.3, a = -0.5, and b = 6.8. The polymerization rate was about the same as that obtained with 200 part per million antimony; the color was close to that obtained from 200 part per million antimony, and the amount of diethylene glycol was somewhat higher than that obtained using 200 parts per million antimony, but still acceptable.
Similar Examples with other catalysts prepared, as shown in the "Table of Polymerization Catalyst Solutions," give similar results to this Example 1.
Example 2 and Control Examples Semi-Works Example Control (~nt;~y Cat~ly~t) Dimethyl terephthalate (DMT) is fed at 84 pounds (38 Kg) per hour to plate 15 of a 20 plate ester exchange distillation column. Catalyzed glycol was made by dissolving 590 grams of manganese acetate with 4 waters of hydration, 115 grams of sodium acetate, CA 02222l66 l997-ll-2~
and 853 grams of antimony glycollate at about 50 degrees C in 1200 pounds (545 Kg) of ethylene glycol.
This catalyst solution was fed at 210 milliliters/minute to plate 17 of the ester exchange column. Virgin glycol was fed to the calandria reboiler at about 70 milliliters/minutes to control the calandria temperature at 237+/-2 degrees C. Glycol boil up in the column was provided by Dowtherm~ heat to the c-alandria's heat exchanger. Methanol was removed from the top of the column, and methanol reflux was provided to condense the glycol vapor. The monomer produced in the calandria was then pumped and filtered through a monomer line to the flasher. 13.8 milliliters/minute of 1~ H3PO4 in glycol was added to the monomer line and mixed with the monomer to deactivate the ester exchange manganese catalyst. Then 9.5 milliliters/minute of 596 TiO2 in glycol was injected into the monomer line and mixed with the monomer. The monomer was then prepolymerized in a Dowtherm~-heated flashing vessel operated at 245 degrees C and 90 millimeters of mercury pressure. The discharge from the flasher was fed to a Dowtherm~
heated, agitated prepolymerization vessel operated at 275 degrees C and 30 millimeters of mercury pressure.
The prepolymer from the prepolymerization vessel was then fed to a horizontal screen/wire filming agitated finishing vessel. This vessel was run at 285 degrees C
and a pressure to produce 19. 7 +/- 0. 6 LRV. The polymer produced was pumped to a spinning machine where yarn was spun at 290 degrees C, quenched, and steam drawn to produce a 70 denier (78 dtex) 34 filament trilobal cross section yarn. This process and product properties will be compared with product made by use of the catalyst of the invention.
Dowtherm6) is a registered trademark of the Dow Chemical Co.
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r~~ yBt of the Tnv~-nt; tln W; th No T~ner The same process used to prepare the control yarn was used except, instead of dissolving antimony glycollate in the catalyzed glycol fed to the exchanger, the cobalt/aluminum catalyst was prepared separately. 250 grams of cobalt acetate with 4 waters of hydration were dissolved in 180 pounds (82 Kg) of ethylene glycol. 4061 grams of Nalco 8676 was added, and the mixture was heated to 160 degrees C to form a clear purple solution. This catalyst solution was injected into the monomer line at 24 milliliters/minute after the 11.4 milliliters/minute of 1% H3PO4 solution in glycol was added to deactivate the manganese catalyst.
~ y8t of t-h~ Tnv~nt; nn W; l-h Tnn~r The catalyst was run the same way as described in the prior paragraph except 2 parts per million on a polymer basis of carboxyl violet was added with the TiO2 to change the hue color of the fiber.
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W O 96/41828 PC~rrUS96/08484 TABLE: results of the control and invention catalyst runs.
Without Control Toner With Toner Finisher pressure, mm Hg 2.96 2.88 3.02 %DEG, analyzed 0.9 0.83 0.87 %TiO2, analyzed 0.096 0.097 0.093 Sb analyzed, ppm 240 Cobalt added, ppm 0 24 24 Mn, added, ppm 98 98 98 Toner added, ppm 0 0 2 Tenacity, gpd (g/dtex) 3.95(3.6) 3.9(3.5) 3.95(3.6) Elongation at break, % 32 33.4 33.4 Boil off shrinkage, % 8 7.7 7.9 Draw tension, grams 105 104 103 (1.2X Draw ratio, 185~C, 150 ypm-= 137 mpm) Glf dye 109 108 103 Tube color, Hunter lab L 84.7 83.3 82.3 b 1.2 2.5 1.15 Color cards, Hunter lab L 89.4 87.4 87 a -.62 -.38 -.13 b .74 2.10 .76 No visual difference could be seen between control and invention catalyst run with toner.
There was no significant change in spinning filter pack pressure rise rate.
Invention and control yarns were judged equal in physical properties.
Invention yarn without toner was less white.
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Example 3 Semi-Works Draw Textured Feed Yarn Example Made with TPA Process Control Example Oligomer, with about 7 average degrees of polymerization, was made in a commercial direct esterfier reactor. A side stream was pumped to the semi-works' flashing vessel, prepolymerizer, and finishing vessels at 110 pounds (50 Kg) per hour. One item was made with no H3PO4, and one item was made with 14 milliliters/minute of 0.1~ H3PO4 that was injected into the oligomer line and mixed with a static mixer to deactivate color forming metal residues. Then 18.8 milliliters/minute of 1~ antimony solution in ethylene glycol as the polymerization catalyst and 23 milliliters/minute of 10~ TiO2, as the delustrant, was then added to the oligomer line and mixed with a static mixer. The polymer was spun through a filtration pack and spinneret to produce a 265 denier (294 dtex) 34 filament draw textured feed yarn, known as partially oriented yarn (POY). This yarn was textured at 700 meters/minute on a Barmag FK-6-900 texturing machine.
Invention Example The invention yarn was made in the same equipment, except that, instead of the antimony catalyst, 16 milliliters/minute of a cobalt aluminum catalyst solution was added to the oligomer line after the H3PO4 was injected. This catalyst was made by dissolving 250 grams of cobalt acetate with 4 waters of hydration in 180 pounds (82 Kg) of ethylene glycol. Then 4061 grams of Nalco 8676 was added. The mixture was then heated with agitation to 170 degrees C
to produce a deep blue solution. The solution's theoretical cobalt level is 0.0725~ and aluminum level is 0.263~.
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Results comparing cont-~~l and in.enti3n product.
Control With Invention Without H3PO4 H3PO4 With H3PO4 Finisher pressure mm Hg 3.86 2.28 4.94 Sb ppm 228 217 39(note 1) Tio2~ 0.31 0.28 0.30 P ppm 4(from TiO2) 3.5 10.1 COOH ends/106g 25 26 34 DEG% 1.15 1.12 1.31 Yarn properties Draw tension, g 109.5 109 115 (185 degrees C, 1.71Xx draw ratio, 185 ypm = 169 mpm) Note: 9 parts per million antimony comes from the antimony in TiO2. About 30 parts per million antimony is in the supply of oligomer.
Color on tubes Hunterlab L 84.9 85.7 83.7 a '-0.3 -0.3 0.4 b 1.9 1.14 0.9 W 62.8 67.8 65.9 color on cards L 91.0 91.9 90.0 a -1.0 -0.85 -0.2 b 2.55 1.6 1.1 W 69.5 76.1 75.3 ~-Tenacity, gpd 2.47(2.2) 2.44(2.2) 2.43(2.2) (g/dtex) Elongation, % 123.1 121.7 126.8 Colors of Control and Invention with H3PO4 were judged equivalent by visual examination.
~EN~ ~ .
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The textured yarn results show:
Control With Without H3PO4 H3PO4 Invention Tenacity, gpd 4.37(3.9) 4.19(3.8) 4.21(3.8) (g/dtex) Elongation % 22.38 21.06 21.17 Leesona shrinkage 18.2 20.0 17.9 (180 degrees F (82~C) in water,~
~ dye vs. std (100~) 101.1 103.1 102.1 Broken filaments 0.18(0.40) 0.38 (0.84) 0 per pound (per Kg) Additional Examples Similar polymerization experiments for the preparation of poly(ethylene terephthalate) polymer were carried out in which 0.83 mmoles of cobalt and 0.56 mmoles of aluminum were added to the mixture to be polymerized, using catalyst formed from cobalt diacetate and aluminum hydroxide, using catalyst formed from cobalt diacetate and aluminum triacetate and using catalyst formed from cobalt dihydroxide and aluminum hydroxide, and using catalyst formed from cobalt dihydroxide and aluminum triacetate in which 0.83 mmoles of cobalt and 0.28 mmoles of aluminum were added to the mixture to be polymerized, and using catalyst formed from cobalt diacetate and Nalco 8187 in which 0.84 mmoles of cobalt and 0.58 mmoles of aluminum were added to the mixture to be polymerized. The results were all highly satisfactory.
Claims (11)
1. An antimony-free Co/Al polymerization catalyst that is formed from (1) a cobalt compound that is cobalt hydroxide or a cobalt salt and (2) from an aluminum compound that is aluminum chloride, aluminum hydroxide, aluminum acetate, and/or aluminum hydroxychloride, said catalyst being in ethylene glycol, wherein the mole ratio of aluminum to cobalt is in the range of 0.25 to 1 to 16 to 1, and where the mole ratio of any chlorine to aluminum is in the range from 0 to 3:1.
2. A process for the preparation of a catalyst for the preparation of ethylene terephthalate polyester polymer, which comprises heating (1) a cobalt compound that is cobalt hydroxide or a cobalt salt with (2) an aluminum compound that is aluminum chloride, aluminum hydroxide, aluminum acetate, and/or aluminum hydroxychloride in ethylene glycol to a temperature in the range of 40 to 180 degrees C, where the aluminum to cobalt mole ratio is in the range of 0.25 to 1 to 16 to 1, and where the mole ratio of any chlorine to aluminum is in the range from 0 to 3:1.
3. A process for the production of ethylene terephthalate polyester polymer which comprises combining (a) a polymerization catalyst, formed by combining in ethylene glycol (1) a cobalt compound that is cobalt hydroxide or a cobalt salt that is soluble in ethylene glycol with (2) an aluminum compound, that is aluminum chloride, aluminum hydroxide, aluminum acetate, and/or aluminum hydroxychloride, where the mole ratio of aluminum to cobalt is 0.25:1 to 16:1, and where the mole ratio of any chlorine to aluminum is in the range from 0 to 3:1, with (b) terephthalic acid and ethylene glycol, or with low molecular weight ethylene terephthalate polymer or oligomer, where the concentration of cobalt in the thus-formed mixture is in the range of about 10 to 100 parts per million parts of the mixture and polymerizing the mixture.
4. A process according to Claim 3; in which the cobalt compound is cobaltous acetate tetrahydrate, cobaltous nitrate, cobaltous chloride, or cobalt hydroxide.
5. A process according to Claim 3 or 4, wherein sodium isophthalic acid-5-sulfonate glycol ester or trimellitic acid glycol ester is in the mixture to be polymerized.
6. An ethylene terephtnalate polyester polymer having a NLRV of at least 12 and containing catalyst residues of aluminum and cobalt in molar amount in the range of 0.25 to 1 to 16 to 1 aluminum to cobalt.
7. A polymer according to Claim 6 in the form of a fiber.
8. A fiber according to Claim 7, that contains titanium dioxide and/or carbon black.
9. A fiber according to Claim 7 or 8 that contains, chemically incorporated into the polyester polymer molecule, sodium isophthalic-5-sulfonate, and/or residues of a trimellitic acid glycol ester chain brancher.
10. A polymer according to Claim 6 in the form of a film.
11. A polymer according to Claim 6 in the form of a bottle.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/487,767 | 1995-06-08 | ||
| US08/487,767 US5512340A (en) | 1995-06-08 | 1995-06-08 | Catalyst and process for producing polyester |
| US56904495A | 1995-12-07 | 1995-12-07 | |
| US08/569,044 | 1995-12-07 | ||
| US08/620,821 | 1996-03-25 | ||
| US08/620,821 US5596069A (en) | 1995-06-08 | 1996-03-25 | Catalyst and process for producing catalyst |
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| CA2222166A1 true CA2222166A1 (en) | 1996-12-27 |
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| CA002222166A Abandoned CA2222166A1 (en) | 1995-06-08 | 1996-06-04 | Catalyst, processes and polymer products therefrom |
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| US (3) | US5596069A (en) |
| EP (1) | EP0830408B1 (en) |
| JP (1) | JP3459261B2 (en) |
| CN (1) | CN1076359C (en) |
| CA (1) | CA2222166A1 (en) |
| DE (1) | DE69624917T2 (en) |
| ES (1) | ES2184872T3 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO1998042769A1 (en) * | 1997-03-25 | 1998-10-01 | Toray Industries, Inc. | Catalyst for producing polyester, process for producing the same, and process for producing polyester by using the same |
| US6066714A (en) * | 1998-04-17 | 2000-05-23 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
| CN1177882C (en) | 1998-10-23 | 2004-12-01 | 东洋纺织株式会社 | Polymerization catalyst for polyester production, polyester and process for producing polyester |
| US6281158B1 (en) * | 1999-02-15 | 2001-08-28 | Shell Oil Company | Preparation of a co-containing hydrotreating catalyst precursor and catalyst |
| US6034203A (en) * | 1999-04-08 | 2000-03-07 | E. I. Du Pont De Nemours And Company | Catalysis with titanium oxides |
| ES2230142T3 (en) | 1999-08-24 | 2005-05-01 | Toyo Boseki Kabushiki Kaisha | POLYMERIZATION CATALYSTS FOR POLYESTERS, POLYESTERS PRODUCED WITH THE SAME, AND A POLYESTER PRODUCTION PROCESS. |
| US6828272B2 (en) * | 1999-12-10 | 2004-12-07 | Equipolymers Gmbh | Catalyst systems for polycondensation reactions |
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| US7745368B2 (en) | 2006-07-28 | 2010-06-29 | Eastman Chemical Company | Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids |
| KR101338846B1 (en) * | 2006-09-05 | 2013-12-06 | 주식회사 효성 | Polyester polymer and manufacturing method thereof |
| US8563677B2 (en) | 2006-12-08 | 2013-10-22 | Grupo Petrotemex, S.A. De C.V. | Non-precipitating alkali/alkaline earth metal and aluminum solutions made with diols having at least two primary hydroxyl groups |
| US8791225B2 (en) * | 2008-06-06 | 2014-07-29 | Dak Americas Mississippi Inc. | Titanium-nitride catalyzed polyester |
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| CN101967225A (en) * | 2010-10-11 | 2011-02-09 | 苏州瀚海化学有限公司 | Method for preparing water-soluble sulfo-copolyester |
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|---|---|---|---|---|
| DE1545039A1 (en) * | 1963-10-21 | 1969-11-20 | Toyo Rayon Co Ltd | Process for the production of polyesters |
| FR1426192A (en) * | 1963-10-21 | 1966-01-28 | Toyo Rayon Co Ltd | Process for the preparation of polyesters |
| US3533973A (en) * | 1968-11-04 | 1970-10-13 | Fmc Corp | Polyester polycondensation in the presence of a catalytic amount of a trivalent aluminum salt |
| US4590259A (en) * | 1984-11-30 | 1986-05-20 | General Electric Company | High molecular weight linear polyesters and method for their preparation |
| CA1303771C (en) * | 1986-02-25 | 1992-06-16 | Jerold C. Rosenfeld | Preparation of gray to blue aromatic polyesters by incorporation of cobalt into the catalyst system |
| US5166311A (en) * | 1989-05-22 | 1992-11-24 | Hoechst Celanese Corporation | Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate |
| US4959449A (en) * | 1989-05-25 | 1990-09-25 | Hoechst Celanese Corporation | Process for preparing low color polyarylates |
| US5116938A (en) * | 1989-10-23 | 1992-05-26 | Hoechst Celanese Corporation | Process for producing the polyester polyethylene terephthalate (PET) from a lower dialkyl ester of a dicarboxylic acid and a glycol using a specific catalyst system |
-
1996
- 1996-03-25 US US08/620,821 patent/US5596069A/en not_active Expired - Fee Related
- 1996-06-04 EP EP96919042A patent/EP0830408B1/en not_active Expired - Lifetime
- 1996-06-04 WO PCT/US1996/008484 patent/WO1996041828A1/en active IP Right Grant
- 1996-06-04 DE DE69624917T patent/DE69624917T2/en not_active Expired - Lifetime
- 1996-06-04 ES ES96919042T patent/ES2184872T3/en not_active Expired - Lifetime
- 1996-06-04 CN CN96196132A patent/CN1076359C/en not_active Expired - Fee Related
- 1996-06-04 CA CA002222166A patent/CA2222166A1/en not_active Abandoned
- 1996-06-04 PT PT96919042T patent/PT830408E/en unknown
- 1996-06-04 JP JP50311297A patent/JP3459261B2/en not_active Expired - Fee Related
- 1996-08-14 US US08/702,419 patent/US5652033A/en not_active Expired - Fee Related
- 1996-08-14 US US08/702,418 patent/US5674801A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5596069A (en) | 1997-01-21 |
| DE69624917T2 (en) | 2003-07-31 |
| DE69624917D1 (en) | 2003-01-02 |
| CN1192758A (en) | 1998-09-09 |
| PT830408E (en) | 2003-02-28 |
| WO1996041828A1 (en) | 1996-12-27 |
| JP3459261B2 (en) | 2003-10-20 |
| US5652033A (en) | 1997-07-29 |
| US5674801A (en) | 1997-10-07 |
| JPH11507694A (en) | 1999-07-06 |
| EP0830408B1 (en) | 2002-11-20 |
| ES2184872T3 (en) | 2003-04-16 |
| EP0830408A1 (en) | 1998-03-25 |
| CN1076359C (en) | 2001-12-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |