CA2228889A1 - Hydroconversion process employing a catalyst with specified pore size distribution and no added silica - Google Patents

Hydroconversion process employing a catalyst with specified pore size distribution and no added silica

Info

Publication number
CA2228889A1
CA2228889A1 CA002228889A CA2228889A CA2228889A1 CA 2228889 A1 CA2228889 A1 CA 2228889A1 CA 002228889 A CA002228889 A CA 002228889A CA 2228889 A CA2228889 A CA 2228889A CA 2228889 A1 CA2228889 A1 CA 2228889A1
Authority
CA
Canada
Prior art keywords
ang
catalyst
diameter
tpv
micropores
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002228889A
Other languages
French (fr)
Other versions
CA2228889C (en
Inventor
David Edward Sherwood, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
Texaco Development Corporation
David Edward Sherwood, Jr.
Ifp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corporation, David Edward Sherwood, Jr., Ifp filed Critical Texaco Development Corporation
Publication of CA2228889A1 publication Critical patent/CA2228889A1/en
Application granted granted Critical
Publication of CA2228889C publication Critical patent/CA2228889C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J35/60—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B01J35/615—
    • B01J35/635—
    • B01J35/638—
    • B01J35/647—

Abstract

A process for hydroconverting a hydrocarbon feed containing components boiling above 1000 °F (538 °C), sulphur, metals and carbon residue into product containing decreased levels of components having a boiling point greater than 1000 °F (538 °C), decreased levels of sulphur, particularly decreased sulphur contents in the unconverted 1000 °F+ (538 °C+) boiling point products and reduced sediment, which comprises: contacting said hydrocarbon feed with hydrogen at isothermal hydroprocessing conditions in the presence of, as catalyst, a porous alumina support containing <= 0.5 wt.% of silica, no silicon containing components being intentionally added, and bearing 2.2-6 wt.% of a Group VIII metal oxide, 7-24 wt.% of a Group VIB metal oxide and 0.0-2.0 wt.% of a phosphorus oxide, said catalyst having a Total Surface Area of 195-230 m2/g, a Total Pore Volume (TPV) of 0.82-98 cc/g, and a Pore Diameter Distribution wherein 27.0-34.0 % of the TPV are macropores of diameter > 250 .ANG., 66.0-73.0 % of the TPV
are micropores of diameter 250 .ANG., 55-64.5 % of the Pore Volume in pores with diameters <=.50 .ANG. are micropores of diameter within ~ 25 .ANG. of a pore mode by volume of 110-130 .ANG., and < 0.05 cc/g of micropore volume are micropores with diameters < 80 .ANG..
CA002228889A 1995-08-24 1996-08-22 Hydroconversion process employing a catalyst with specified pore size distribution and no added silica Expired - Lifetime CA2228889C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/518,774 1995-08-24
US08/518,774 US5827421A (en) 1992-04-20 1995-08-24 Hydroconversion process employing catalyst with specified pore size distribution and no added silica
PCT/IB1996/000831 WO1997008274A1 (en) 1995-08-24 1996-08-22 Hydroconversion process employing a catalyst with specified pore size distribution and no added silica

Publications (2)

Publication Number Publication Date
CA2228889A1 true CA2228889A1 (en) 1997-03-06
CA2228889C CA2228889C (en) 2007-11-13

Family

ID=24065449

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002228889A Expired - Lifetime CA2228889C (en) 1995-08-24 1996-08-22 Hydroconversion process employing a catalyst with specified pore size distribution and no added silica

Country Status (9)

Country Link
US (1) US5827421A (en)
EP (1) EP0876443B1 (en)
JP (1) JP2000507992A (en)
AT (1) ATE226238T1 (en)
CA (1) CA2228889C (en)
DE (1) DE69624379D1 (en)
DK (1) DK0876443T3 (en)
PL (1) PL182650B1 (en)
WO (1) WO1997008274A1 (en)

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FR2981659B1 (en) 2011-10-20 2013-11-01 Ifp Energies Now PROCESS FOR CONVERTING PETROLEUM LOADS COMPRISING A BOILING BED HYDROCONVERSION STEP AND A FIXED BED HYDROTREATMENT STEP FOR THE PRODUCTION OF LOW SULFUR CONTENT
FR2983866B1 (en) 2011-12-07 2015-01-16 Ifp Energies Now PROCESS FOR HYDROCONVERSION OF PETROLEUM LOADS IN BEDS FOR THE PRODUCTION OF LOW SULFUR CONTENT FIELDS
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FR3027913A1 (en) 2014-11-04 2016-05-06 Ifp Energies Now METHOD FOR CONVERTING PETROLEUM LOADS COMPRISING A VISCOREDUCTION STEP, A MATURATION STEP AND A SEDIMENT SEPARATION STEP FOR THE PRODUCTION OF LOW SEDIMENT FOLDS
KR102542845B1 (en) * 2015-05-29 2023-06-12 어드벤스드 리파이닝 테크놀로지즈 엘엘씨 High hydrodenitrification selectivity hydrotreating catalyst
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FR3036704B1 (en) 2015-06-01 2017-05-26 Ifp Energies Now METHOD FOR CONVERTING LOADS COMPRISING A VISCOREDUCTION STEP, A PRECIPITATION STEP AND A SEDIMENT SEPARATION STEP FOR FIELD PRODUCTION
FR3050735B1 (en) 2016-04-27 2020-11-06 Ifp Energies Now CONVERSION PROCESS INCLUDING PERMUTABLE HYDRODEMETALLATION GUARD BEDS, A FIXED BED HYDRO-TREATMENT STAGE AND A PERMUTABLE REACTOR HYDRO-CRACKING STAGE
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FR3135090A1 (en) 2022-04-29 2023-11-03 IFP Energies Nouvelles METHOD FOR PROCESSING PLASTICS PYROLYSIS OIL INCLUDING AN H2S RECYCLING STEP

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Also Published As

Publication number Publication date
EP0876443A1 (en) 1998-11-11
ATE226238T1 (en) 2002-11-15
JP2000507992A (en) 2000-06-27
US5827421A (en) 1998-10-27
PL325158A1 (en) 1998-07-06
WO1997008274A1 (en) 1997-03-06
PL182650B1 (en) 2002-02-28
DK0876443T3 (en) 2003-02-24
CA2228889C (en) 2007-11-13
EP0876443B1 (en) 2002-10-16
DE69624379D1 (en) 2002-11-21

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