CA2250717A1 - Methods for molding hinged starch-bound articles - Google Patents

Abstract

Method and systems for forming hinged starch-bound matrices. Starch-based compositions are molded between heated molds in order to form a cellular matrix and also to remove water from the starch-based compositions in order to form a binding matrix of solidified starch. The molding apparatus is configured to form one or more creases (230) within the hinge structure (200) in order to define one or more lines upon which the hinge will bend. The molding apparatus is also configured such that the region of the mold corresponding to the inner surface of the hinge area will transfer heat more slowly to the interior skin portion (224) of the inner hinge surface, resulting in reduced thickness of the skin of the inner hinge. This increases the collapsibility, or ability of the inner surface of the hinge to fold or buckle, during the bending action. This in turn reduces the bending radius of the hinge such that the hinging action exerts less strain on the outer surface of the hinge. The inner surface of the hinge may optionally by treated with glycerine or other polyol to soften the inner surface. The exterior skin portion (226) of the hinge may optionally be coated with an elastomeric material, such as polyvinyl alcohol, in order to strengthen the outer surface and reduce its tendency to fracture during the hinging action.

Description

~UC~ 9~ T~E 09 36 ~M ~ORKMAN NYDEGGER ~SEELEY F~X NO. 180132~ ' ~ P.

METI~ODS FOR MOLDIN(~ AR'rICLES W~IICl~ INCLUDE
A HINGF,D STARC~-BOU~D CELLULAR MATXlX
13ACK(~RO~ND OF THI.;', J~VF.NT~OI~I
1. Tlle Field of thc ~nv~tior S The ~resc~1t invcntion relates to thc manufacturc of starch-bound articlcs havinl a lightwcight ccllular matrix. ~orc particularly, thc prcsent invcntion relates to starch-boun~l articles that include a hin~e structure that is intcgra11y moldcd ~ithin thc articlc, as well as methods and apparatus ror fo~nin~ such hinL~ed articles.

2. The Rc1cv~t Technoloev Duc to political and othcr pre~s~s stcm ming from the aw~incss of the nc~,ativc cnvif~"~ impsct of using papcr, lhLm~Gplastics, polyslyrcnc, or melals for a variety of sin~ use, mail~y ~ p~s~l~1e allicles such as c~n~in~rs und other P~r~cir~g materials, ~hcr~
has been an acutc need (long since rccognized by those skilled in the art) to find subslitutc pae~in~ materials that arc moro cnviror~m~ ly sound. Some havc a~temytcd to m~ml~rt1-rc articles from slarch-co~t~in~g cVl~po~;l;nnc bet~ ~ s~arch is a nalural~
plentiful, and renewable resou~c¢. One ~,parc.ltly simple method that has been uscd to m~luf:~rSl~re starch-based fflcles involves the gclation of starch in ~ater, followed by neating in ordcr to dry uut the starch to form a solidified materil throu~h what has bccn charactcrized ~c a "retro~radalion' proccss. Another, less succeccful method involves mclting ~nt thcn cooling the starch like a thcrmoplastic material to forrn a solidificd material.
In the gelation/~ uL,~dation process, 3 starch-c~r~t~inin~ mixturc is ~ypically sha~e~l illto ~n ap~,.v~,.,ate article betweel1 hcatet molds for a periot of time s~fl;cicnt to first ~c]alc the starch-based binder ant then remove a s~bs(~nti~l portion of thc water by evapor.ltion to form a solidified or semi-hardcnct material. The starch-conlainin~ mixture typically includes ~ gel5~tini~P~i starch ~ran~ s togethcr ~tl~ option~l admixtures, such as inorg3nic mineral fillcrs and fiben, together with su~lcient water to form a ~nixturc havinu a dcsirc~l rheolo~y. Depcnting on the c~,~.c~l.Ll~ion of the various components, bo~h in the starch-conS~ in~ mLlCtUre and the final molded starcl~-bound cellular matrix, thc starch-bound ~rticles molded from such cornpositiosls can havc a ~ridc ratlge of densities and slrcngth ~ro~.tics. Because such articlcs arc lar~ely starch-bound, ar d to not includc apr~reciablc amounts of artificial plastics or otber compon~ntC thcy a~e readily biote~radahle.

AM~NDE3 SHEET

~UG-11-98 TUE 09:36 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 p ~ 9 7 /'1 0 1 ~
~ ~ IPE~ 29,~1AY 1998-~h~ ar-:h-cont~inin~ mixlllrc is rcadily moldable into a variety of different sllapcs to rOnn a number of arlicles and containcrs, Thcsc includc platcs, bowls, cups> and "clam~
shell'' style sand~Yich containcr~. Thc clarn sllell sandwich conl~ er is an cxamplc of a two-pieco arlicle lhat is prefcrably hin~ed in order for il to havc ~c ~rcatcst casc orusc by thc S restautas~t owller or consumer during pa~ ein~ and consumption of thc sandwich or othcr componenl within thc clam shell cont~ r.
U~S, r~ter.t No. 5,316,230 to Ticfenhacher et al. shows one prior art attempt atfc~rrnin~ a l~inge in a clam shell s~yle c~r.t~inr1r. SpCcifirslly~ r~f,.~.,cc to l;i~ures 14 show~
that Ihe hingc structurc that holds the two container halves or bowls 1 and 2 together comrri~cs "a strip hinge 7 which is re~eive~l in lecesses 5, 6 and which corcictc of a shcct m~teriSIl such as a s1~ip, which has bccn baked with the container bowls which cor.,lilulc thc ~ody." Col. 17, lincs 38-42. T~efenb~cher et al. fuIther sets rorth examples of the types of _~ sheet material used to forrn the hinsc. PY~rlc 7 utilizcs a wood frcc papcr; Examplc 8 -_ utilizcs a non-wovcn textilc fabric of cotton/celluloso pre-olded in lhe longitudinal dircction;
Ex~1mplo 9 utilizcs a ~n ~ V3Vcl~ fabrie of elass fibers prefolded in the lo~it~ 1 d~rcetion.
~Vhile the fore6oin6 strip hinge m~t--n~ls can be atvantageously used t~ join the el3m shell eont~in r halves together, their use greatly eomplicates the molting proeedure used to rnS-nllf~~ture Iha clarn shell eC~toin~r. Speeifieally, reference to tho ~ise~lssion beginninr at col 17, line 42 through eol 18, line 6, rcveals that the strip hin~,e materials must be carcf;~lly molded into the Cu~ bowls during the melding process "Ctlo prevent a displ~cemenl of he two eont~inrr bowls when they have been folded together." "Sheet materials which ~re not centTally inserted with res~eet to the feeding of the balcing comrosition into the succ~eding evolution of water vapor w~ll be .ti~pl~red and will not be bonded at a pr~del'ined loeation." Col. 17, lines 62-66. Henee, ~reat care must be taken in properly inserting the sheet m~terials inlo the starch-based comrosition dunng the molding process in order to prevent ~rregularities in plaeement and subsequent use. The fore~ oing precautions ~,reatly ~nerease the diffieulty, allt çspeci~lly thc eost, of mar7~s-prorlu~-;ng clam shell style sandwich cont~iners from starch-based CO...pGSitiOnS.
Many are f~mili~r with elam shell eontainers m~nnf~rtured frorn plastie materials, such as polystyrene foa~n, which include a hinge integrally molded within the foarned rolystyr~ne sl~ucture. R~or~l~ee polystyrene foam is ad~lu,3tely flexible and durable, simrl~
m~lding a crease into the hinge area definin~ the junction between the t~o clarn shell halves is adequate ~o forTn a reasonably durable hin~e between the two polys-yrene el~n shell ,-~;v~,r~ L'L~ iC~.

AUG~ 9a TUE 09:37 AM WORKMAN NYDEGGER ~SEELEY F~X NO. 180132817~7h,~ ~ ~ 7 P. 1~ 1 6 ~
IPEA/iJS 2 3 MAY 1998 hAIves. ln comparison to rolyslyrene, s~arch-bo~d cellular matric~s are typically morc ligid ~nd brittlc. I~or tllis reason, l'iefenbacher e~ al spccifically tcachcs and clai~s a mandatory "condi-ioning" step in which thc ncwly dcmolded s~rch-bount artic]es must be ~laced in a high humidity chamber in order to for Ihe A~ticlc to rcabsorb watcr iA ordcr to so~tcn and S plastici7c tl-e olllerwisc stiff, rctrograded starch binden Col~ 15, lines 36-59 claim I .
Articles manufactured accotding to 7~efenbacher ct al. arc conditioncd to hAvc ~water conLent ~v~thin a ccrtain range, the range having a lower limi~ of about 6% by wei~ht watcr and an upper limit of 22% by weight water. Tiefenbacf2-!~ el ~1. teachcs lhat ~l-is ~,on~ inninB step is nrC~csry in ortcr to obtain the ncco,~ r toughness arld deformability whilo m, nin~illing mAch~'lir~l stability. Notwith~s~ g the conditionin~ step, l~cfenbacher ef a~. spccifi~ ly teaches the use of hinge strips, such as paper or non-woven fiabrics, in order to fo~m a hinge be~ween t~vo halves of a clam shcll typc cnnt~in~~~. One of ordinasy sklll in tlle art would conclude ~at the ~ tLntO~:~ in Tfefenbacher e~ al. were unable to m~mlf~ ~lrc - slarch-based articlcs havin~ an integrally fo~net hingo as with polystyrcne-based articlcs.
The problem u~as likely due to ~c inability to obtaill a starch-bolmd ma~rix that ~ras simultancously stiffenough to avoit meel~nnic~ form~1;on or warpinl3 of the container halves (which can happen if the starch matrix is over-conditioned to ineludc too much water), and yet flexible enough to avoid Ld~ i or r~pture of the hingo upon opening and closing the cl~m shell cont~in~t.
In li~ht of the foregoing, wha~ are needed are 1l ~e~l.o~s ant systems for rrl~nl~f~ctllri nE~
integra~ly I'olsned hinges within starch-bount cellular matriccs.
It vvould be a flu rther improvement in ~e ~t to provide melhof~ and systems forformin~ a hin~e witllin st~rch-bound matrices during the m~nllfa~: ~re of thc cntire anicle such lhat the arlicle and hinge are m~nl-f~tl~ed in a single step.
It would be an additional improvcment ~ the an if the integrally ~ormed hin~e c~limin~t~d thc need to introduce forei~n materials such as paper strips thaL need to be inser~e~l into lhe mol~l;ng appalatus during the mo~ ng of starch-based compo~ition~ into the desired articles.
It would yet bc an atvance in the art to provide methods ~nd sy~tems for m~nnfar1~ltin~ inte~rally fo~med hin~es in starch-bound ar~icles lhal woult allow the articlcs to be opened and closed repP~tP~ly withoul: subst~ntial rupture of the starch-bound ma~rix.

~UG~ 9~ TUE 09:37 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 180132~1707 P. 13 iPEAllJS ~ 98 Such mc~hods and syst~ms for forming an integral hingc within starch-~ound ccllul~r nlalricCs arc disclosed and claime~l herein, as are thc hinged s~rch-boun~l articles fonne~i thereby.
~;;UMMARY
S Thc prcscnt invenl.ion involvcs thc form~tirn of durable hin~es within article~ havin~
a st~rch-bound cellu~ar matrix. Such articlcs are manu-.aclured from starch-based mixLures which are moldcd using heated molds that are spccially confi~ured to form a creasc in thc moldcd article. The crease provitcs a hin6e area for loc~li7~ folding or bendin6. which causes lhe inncr surface or skin of the hinge to CG~ SS, whilc causing thc outcr surfacc or skin of the hinge to elongatr, The specially configured rnold also results in a hin~ e thal is more easily bent and more rcsilicDt as a result of optimi7;nE~ thc thiclfn~s of the inncr and outer skins or surfaces in tho are~ of the hing~.
In ~crl~ the starch-bound ccllular matrix includes a rclatively tense outer surface or skin surrounding a relatively porous interior portion. The skin forms as a result of a process that uses p~ired male and female molds that arc hcatet to "~alce" tl~e starch-bascd c~mrositior and thereby remove water from the starch-based mixture by evaporation. The heatcd molts are preferably made from metal, which is a good conductor of hcat and which h c relatively high specific hcat. Dryin~ out thc starch binder causes it to solitify and form Ihe binding, matrix. Becausc the tr~nsfer of heat firom the molds to the starch-based nnixture occurs only at tlle surface interfacc bctwccn thc molds and the mixture, thc skin is dricd out more quickly Ihan thc intcrior portion. This allo~vs the intcrior portion to under~o f~rther expansion and cell forrnation for a period of timc aftcr initial skin formation. Hence, ~hc intcrior portion is more porous ~d has a reduced derlsity.
P~ecause me~l is such a good conductor of hcat, hcat inputs a~e qu~ckly eqllil ibr~ed throughout thc molds such that the mold t~ LIJ~G is csC~n~ ly uniform throughout cach half of the mold pair. l'his in turn results in almosl: unifiorrn transfer of heat from thc molds to the starch-bascd mixturc. Por this reason thc skin has bccn obsctvcd to have a rem~rkably constant Ihi~t~n~cs throut~hout and on both sides of thc molded articles. Ncvelthelcss, allering ~he ra~e of heat transfet dur~ng the molding process can chan~e the thickncss of thc skin. In some cases it may be desirable to optimize the skin t~ir~n~-5s sincc incrcased skin thic~ ss results in a~ticles having more surface stren~h. Howcvcr, skins of increased thickness ar~ also gencrally morc rigid and more likely to ~acture if mechanically dcformcd.

~t~ EI~ SHEET

~UG~ 9~ TUE 09 37 ~M ~ORKM~N NYDEGGER &SEELEY F~X NO.180132B1707 P. Iq 9 7 1 1 0 1~
IP ~ 2 ., MAY 1998-s In 6cneral, thc skin thir~ ss is directly proportional to th~ rate of hel ~r3.nsl'cr ~rom Lh~ molds to ~hc starch-bascd mixture Incrc3sin~ tho rate of llcat tr~nsrer ~,cnctally incl eases the skin thickness; rcducing thc rate of heat tr~nsfcr ~,enerall~ rcduccs the skin thickncss In li~e fashion, the rale of hcat transfcr from the molds to the .s~arch-b~scd mixture is dircc~ly S proportional ~o the ~ pe~,lturc of tho molds. Increasing thc mold tcmper~Lutc incrc~ses thc rate of he~t transfer, ~hilc reducing thc mold te.llp~.~t~l~ r~duces thc ratc of hcat ~ransrer, llcnce, incrcasing Ihe mold te,..pel~t~rc gcnerally rcsults i~ increased s~;in tl7iekness, while r~in~in~ the mold t~.l.~.~turc ~encrally results in de~reased skin thickness Howcvcr, it is virlua11y impossiblc to heat diI~crcnt pasts of an inte~rally formed mctal mold to dirrercnt tcmperalurcs in orter to altcr the skin thi~ n~cs throughout the molded articlc.Accordin~ly, in order to molt the articlc such that intcrior sL;in portion of thc hinge area has reduced thir~ ss~ the prescnt invention preferably ut~ s specially dcsigned molds ~ in which the portion of the mold surface CO~ Ohd~lg to the intcrior s~in portion of the Jhin6e transfers less heat per unit of time Cc~ ~C~ to the rest of the mold rn a p.. ,fL~Icd e~ho~liment, the molt arca CO~ pQn~in~ to the intenor skin portion of thc hin~,e corn~rises a material having lo~cr hcat diffusivity, such as polycthcr cther ke~one ("Pl~l~K") Nevertheless, ~ny material that is heat r~si~Ant, durablo, and ~ill rcsult in an intenor skin portion of thc hinge having reduced Ih rL ~ ss is w~thin thc scope of the prcscnt invcn~ion Othcr matcrials include silicone rubbcr, Al2O3, glass-fibcr-reinforced Tcflon, porcclain, and other cerarnics Moreover, any mold co~ u-~ti~.n that is able to rctucc thc rate of hcat f~ow to the illterior skin portion of the hingc area w~thin the moldcd aIticle such that thc interior skin portion has reducet thickness co r ~,d to the s3cin thi~Lnt~s~ in other portions of thc article is unthin the scopc of the prcsent invention A broad range of dirfcrent mold materi~ls and configurations that rcsult in thc invelltive hinge Y~ .,s will be disc~ssed hcrcinaftcr Refcrring to the hin~c s~cture, it will now bc explained morc prccisely what is meant by thc "interior skirl" portion and thc "exterior skin" portion of the hinge arca Assuming that thc two halves of thc ~ticlc are initially oriented with an initial anglc bctwccn them, the "intcrior skin" is located on the side of the ~ticle toward which thc two halves will be brou~ht tosettler dlmng closure of tho two halvcs Aceordingly, the "~utcr skin" is located on thc si~le of the articlc opposite tho "interior skin" Thus, the "interior skin" is on the side of the article in which the initial an~le between the ~wo halves is decrea~ed during closure, while the "extcrior skin" is on ~he side in which the initia~ angle is incrcascd durin~
closurc Because the angle ben ~een the two halves of the a~icle decrca~cs durin~ closurc, ~UG-11-98 TUE 09 38 ~M WORKM~N NYDEGGER &SEELEY F~X N0. 18013281107 P 15 ~ J i lA~ ~9B

~h~ interior skin is subjecl to comrression, collapse, ~ld b~ kling, whilc thc outcr skin i~
s~lbjcct to strain and elongation. Dcfotmation Or Ihc interior skin portion of the llingc by compression, and of the exterior ~kin r~ortion of the extcrior s:_n porlion by clon~,aliol1 or stretcllin~, can cnuse disruption, cvcs~ fracturc, of thc starch-t~olmt matrix in ~he hinyc ~ca.
S Accordin~ly, the prosent inven~ion involves ~ varicty of stratcsics for incrc~sin~ ~hc tcndency of the interior skin portion of the hinge to collapse or buckle wl~en con~presscd during closure and also its ability to rc-extend during opening witho~lt substantlal fraclure.
l'hc most important feature of the hingc for provitin6 this rcsult is the aforcmcntioned moldin~ method in which tho interi~r skin ponion of the hin~c has a rcducct thickness coll-pa~et to thc thirL~n~c~ of the exterior skill portion. The ~ ced ~hi~L n~Ss of the inlerior skin portion result~i in thc intcrior skin portion bcin~ Icss rigid ~nt more flexiblc, such as what of'ten occur~ when scmi-rigid materials ~re made thinnel. In addilion, the crcase thal . ~ protrutcs in~lvardly along tllc length ofth~ inl:erior sldn por~ion ofthe hinge provides a clean . Iine upon which the hinge will bend and the interior skin will eo!l~rsc or bucklc durin~
closure of the articlc. '~hc cc~ p~iibility, re~ r~r~. ~d durability of thc interior skin po~tion of the hinge can fi~rther bc irnproved by trealing the intcrior skin portion with glyccrin, ~
mixlure of glyccrin and water, or any othcr similar polyalcohol that can be abso, ~ into and soften the starch-bount rnatrix. As will bc diec~1qs~c~ k ,~ An ,~, glycerin and other polyols act as plasticizcrs ant hl1m~et~nt~c for moldcd starch.
S~n~ilarly, the present invention involvcs cu.. pl~ .1i.. y stratcaics for reducing thc amount of strain or elon~ation of the exterior skin portion of the hin~e. and also the ability of the exterior skin portion to rcmain mtact aftcr bcin6 straincd and clongatcd in ordcr to improve lhe ll~lcibi1ity, durability, and rrcil;rnrr of t'hc hingc. Molding the extcnor skin portion of thc hinge to have a thicker skin rel~tive to the thickncss of the interior skin portion results in grea~er strength and resistance to tensile ~act~lre. In rnost cases, the e~terior skin portion of thc hingc will havc a thi~L n~ss that is sirnilar or identical to the thickne~s of the articlc skin in general. ln addition, the cre~ce on thc interior skin side suhst~nti~lly redl~ces thc ben~;ng radius of thc hingc, which su~cl~n~ y reduccs the strain on tl~e extcrior skin portion of the hingc dur~ng closl~re o~the article by a ~ ,o.~ional arnount. lncorporating a 3 0 more e~ collapsible interior skin portion has also be~n found to further reduce thc bon-~i ng radius of the hinge c~-n~a.ed to a crea_ed hinge having equal skin thir~n~sc~c on bo~h sides.
Coatin~ the exterior skin portion of the hingc with an elastomeric coating (e.g, polyvinyl alcoho1) greatly incrcascs the strength and endurance of the cxterior skin porlion. The ~UG-11-98 TUE 09:38 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 180132~1707 P. 16 P~jT'J~ 9 7 /1l p ,1 6 ~

cxtclior skin portion may also inclute a tjny crease or groove op~osite the nlain crcasc on tll~ intcrior skin si~e which acts ~s a bcnding initialor to ensure that thc cxtcrior skin por~ion elon~ales unirorrnly during Ihe bendi~g action and in thc san. scncral arca as the collapsc or bucklin~ of the interior skin ~ortion.
S ~nothcr way to rcducc thc mcc~a~lical stresses on thc hin~c is to simply employ mult~plc l~illges or hin6e units ill order to recluce lhe overall bending an~lc of each individual hingc or hinge unil. Using mul iple hinges greatly increases the bending endurancc of thc hingc by distributin~ thc m-~ch~ni~l stresses ovcr a widcr arca of thc intcrior and cxlerior skins orthe hinge area~ Each hinge unit only cxperienccs a fraction of the overall bend. I~or inqt~nr-- PSsl~ming thc two halves of the article will be bent 180~ dunng closure or hinging action, a single hinge will itself be bent around the enlire 180~. However, if a tol~ble hin~c is used, then each hingc unit will only havc to bcnd about 90~, assuming even distribution of the hinE~in~ action bctwccn the two hinge units. If a triplc hinge is employcd, cach unit will have to bond about 60~; if a quadruple hinge is use, about 45~ each, and so on Molding a multiple hinge only rcquires that thc mold ~ypm. ~q bc confi6urcd so that it forrns as many crcascs within thc intcrior skin portion of thc h~gc arca as the nurnbcr of desired hinge urlits A double hingc will rcqu~rc two parallel creases, a triple hin~e, three, and so on. For every crease on the intcriOr slcin portion therc can optionally be rr.oldcd a co--esl,ol.ding bending initiation crease on the exterior skin ponion.
Bl~lFF ]~F~eC~IPT101~ OF T~h' DE~AWIN('.~
Jn order t~lat the rnanner in which ~he above-recited ant othcr advantagcs ~d objecls of the il~vention are obt~in~rl a more particular tcscription of the invention briefly descriW
above will be rendered b~ reference to a specific embo~liment thereaf which is illuslrate~l in thc appended trawin~s. Und~ ;nc that thcsc drawing depict only a typical embodimcnt ' ' 25 of thc invention and 3re not therefore to be consitered to be limiting of ils scope, ~lle invention will be dcscribed and cxrl~inl~d w~th addilional specificity and detail through Ihe usc of the acco t,a.aying drawings listed hereinaftcr.
Figure 1 is a p~ c~t;re view of a molf~in~ apparalus for m~ss production of hing~tl articles.
Figure 2 is a pcrspectivc ~ricw of a mold in the fillin~ position in the moldingapparatus shown in lii~urc 1 AMENDED SHEET

~UG~ 98 TUE 09 38 ~M WORKM~N NYDEGGER ~SEELEY F~X ~O, 180132~1707 P; 17 ~ ~' lPE~2~ 7MA~ ~B6 ' Ul'C 3 iS a cross-sectional view of a mold depicted in Figure 2 showin~ a mixlurc bcing molded to llave a hinge wi~ a secl:ion of intcrior skin that is lhilmcr than tlle OppOSillg exlerior skil1.
l;i~urc 4 is a pcrsycctive view oran o~en clum-sl1ell cQn~Ainrr havin~ a touble hingc.
S Fi~urc S is a p~ c~ive view of thc double-hinged clarn-shell conlainrr afler bcin~
closed so ~ha~ the hingc has been folded.
F~i~,uro 6 is an cnlarged view of a schematic ~,r~S3 se~tit~n~l and L~e,.;,l,c~,tive vicw of the unfoldcd l1in~c depictcd in ~igurc 4.
Figure 7 is an enlarged view of a srh~ tic cross-section and p~a~ c vicw orthe foldcd hin~e depic~e~l in Figure 5.
Figure g is a sca~ nin~ clc~ on ~ucrograph image of a cross-scction of an unfolded hin~c formcd from a starch-bascd mixture.
~~ Figure 9 is a sc~nin~ clc.,tron micrograph irnage of a cross-section of thc hingc _ rl shown in ~'igurc 8 after ~eing rolded.
Figure 10 is a sC~nnin~ elc~ n rnictogl~h image of a cross-scction of an articlemoldct in an all-min--m mold baving a SiliCone mcmbcr.
F}gure I I is a s~ng elcc~on mic.o~.sph image of a cross-section of a hingc willa thick interior skin.
I; i~urc 12 is a higher tn~gnifir~tion of tlle ima~e ~hown in Figwe I 1 with a white line outlining a rou~h trace of the intcrior skin to highlight the folding pattern.
Pigure 13 is a scanning clc~tlul~ rni~,u~aph image of a cross-section of a hinge with a thick intcrior skin and two parallel indcnta~ons for loc~ d fo1ding.
Figure 14 is a sch~2rnq~ic depiction of the image in Fi~urel3.
Figuro 15 is a SC~nnine clcct~on micrograph ima~e of a cross-scction o~ lhe hinge shown in I:igurcs 13 ant 14 after beinL~ bent.
Figu2e 16 shows a 5~ tic ~ ram of an apparatus used ~o ~est thc bcndabiliLy of starch-bound matrix samples.
~igurc 17 is a graph showin~ the ef~ect of usin~ vaIying arnounts of glycerin and varying the relative humidity on the maximum allowable bend anglc bcÇore frac~urc of Ihe starch-bound cellular matrix.
Figule 18 is a graph co.~a, ;ng the cffcct of using va~ying amounts of glycerin on Ihc compression side of a hingc verses thc elongatcd side mcasured at 40% rclative 1~umidity.

A',~lE~ D S~EET

~UG-11-98 TUE 09:39 ~M ~ORKM~N NYDEGGER &SEELEY F~X NO.180132~1707 P. 18 7 7 ~ O 1 I~E~ MAY 1998-l i6urc 19 is a graph sllowin6 th~ avera6c bcnd angle at railure for tllc l~o pair~i vcrsus the lo~al amount of polyvinyl alcohol coating applicd urc 20 is a ~raph showin6 thc same tah prcscnted in Fi~urc 19 as a func~iol~ o1 th~ glycerin contcnt in the coaLings S I~ETAll~F,ll I)l; ~CRlPTl(~N ()~ T~lF, PI~FFF~T~F,l~ ~,MBODIM~ 'l S
1. ~k;~E~AL DISClJ~SION.
A. ~troductioll.
Thc prcscnt invcntion is directed to hinged s~arcl -bound articles and systcms alld methods for such Pficles Morc particularly, the prcscnt invention cnco,.,passes mclhod~
1~ and systcms for man~factl~rinr hin~cs having in~ d rc~ilience and durability Such hinges arc particularly uscful in the m~nl~6r~ e of rlose~ble cont~inpn~ such E~ "cl3rn shell"
sandwich con~s-;nPrs, which have a bottom ~d a lid connr~t~d togetller by a hinge s~ructurc is elimin9tes the neet for introducing ~oreign m~teri91~ into the starch-bound cellular matrix in order to forrn a hinE~c. Sucll foreign hingc materials, like paper or plastic strips -._ used in thc prior art, ~ill generally not decolllyosc or dc~;.~e as fast as thc starch-bound cellular matrix once thc article has been discarded, They arc also not readily rccyclable Articles formet from starch-basct wmpnsitions ha~-e a porous interior scction surrounded by a skin that i5 denser and less porou~ thall thc interior In ~,encral, the thickcr the skin, the more rigid the skin and the article in the area of incrcased skin thickncss Additionally, thc thickcr the skin the Frcater thc stren~th of the skin and the articlc Conversely, the thinner the skin, the rnorc flexible and ea~,ily bent is the rticlc or r~orlion thereof The present invention u~ilizes a crease coupled with decrcaset skin thickncss within tlle intcrior skin portion of the hinge to increase the bendability of lhe hin~,c As discusscd more rully below, tlw pre_ent invention talc~s advantagc or thc fact that lowering the rate of heat transfer to a parlicular area of the ~rticlc during the molding process will r~s~llt in a loc31i7ed area of red~lced skin thirL n ~c5, In gcneral, starch-bascd cornpositions can be molded to yicld a wide v~ricty of articlcs, includinF, containers, plates, cups, "clam shell" santwich containcrs, plattcrs, cartons, boxes an~ other types of co~t~in~S ar,d articlcs having mcchanical properties that are substantially similar or evcn superior to articles rn~nu~t~red using convcntional materi~ls, such as paper, polystyreno foarn, plastic, metal and ~lass Starch-bound articlcs can usually be made at a fraction of the cost of using conventional mat~rials bccause of thc ~UG-11-98 TUE 09:39 ~M ~ORKM~N NYDEGGER ~SEELEY F~X NO. 18013281707 P. 19 IP~ ~ 9 ~/A~ 1998 - ~cnerally lower cost cf the materials inputs and also because of lowcr ovarall ~ncr~y rcquircmcnts.
The manufacturing proccsscs ~nd resultin6 aniclcs are less harmful to ~hc environment comparcd to conventional ,~naterisls and processes. Thcorctically all of thc wastc Ac~oci~ted with tlle manufacturin~, process can bc dircctly recycled back inlo ~l~c yroduction linc as a filler material. Ollce the gcncrally disposable articlcs h~ve fulfillcd lhclr intended usc, thc starch-bound articles are easily rccycled into other articles or similar matcrials wilh minimum proces~in~ lf discarded into the cnvironment, the starch-based binder ~t othcr or~anic co-~ .po~ c of the articlcs are in a sl~te which malces them quiclcly dissolvc and/or ~iodc,~c.ade in the pfcsencc of moislure, whilc tne inorE~anic filler is alrc~dy largely co~n~cltiblc with thc earth into which it may be disposcd. Thc invcntivc articles are of ~cnerally low mass.
B. Uefinitions.
~hc terrns C'starch-based cC~ osit;nn~ or "rnolrlin~ cornposition", as uscd in the lS specifi~tion and thc appcnded claims, refers to starch-cor~tainin~ cc ~ ositions of ap~rol,.iate rhcology that can be molted within heatod molds to forrn articles having a starch-bound cellular matrix. Such compositions typically include a thi~r~lin~ ag,cnt, such as gel~tini7~d starch, an w~l~2elatinized starch col..ponc"l thst is ~clatini~et upon molding the c~mrosition usin~ hcated molds, s~ st~nti~lly ., .i r. ., . ~ ly di spersed fibcrs, ~rater. an inorganic fillcr, and, optior~11y, ~ mold-rele~e agcnt, gurns, org~Lic fillers, dispersants, cross-linkers, placti~ s, h~ nt~, and integral coating matcrials.
The terrn ~ el ~ ini7~yl starch", as uscd m the specification and tl~e AE~pçndl~d claims, refers to nativc or othe~wise ungel~tini7~d starch or starch derivativcs that can be addcd ~o the molding cc,.,l~o~ition but which ~vill not becomc gelatinizcd until the mixturc has been heated to abovc thc ~elation t~ rc of the un~elatinized ~tarch dur~ng the molding proccss. The "total starch" in the starGh-based composition comprises the combination of pre~ ni7~d starch ~nd ungel~tini7~d starch, which together constitute the "starch binder"
upon thc removal of p~rt or s~hs~ 11y all of the ~'ree (or unbound) watcr from the moldin~
co,..~-osition.
As uscd in thc specification and the a~ d claims, the tc~n "total solids" includes thc actual solids togcther with any aLll~Lixlul~es that may bc adted to the starch-base~l co..lposition that are initially dissolved into the "fluid fraction" but which ~vill form ~ ~olid upon ~e rem<~val of water by evaporation during or afler the molding proccss nle "fluid AMEI~IDED SI IEET

~UG-11-98 TUE 09:39 ~M WORKM~N NYDEGGER &SEELEY F~X NO, 1801~281707 P. 20 ~ Ip~s 29~7~/A~ ~J998~ ~

l1 fraction" iS thc portion of the composition compnsing the wa.ter and any liqui~ls or solids ~h~t arc dissolved within the water (c.g., prc~,clalini~ct starch, m~gn~sium stearatc, clc.). Tl-c "solid fractios~" is the portion of the composition that inc'- des thc solids ll~a~ arc no dissolved in ~he water (c.g., fibcrs, inorganic fillers, ctc.) Ille lemls "fiber-reinforccd ccllular matrix", "starch-bound cellular matrix" or"starch-1oound matrix7', as ~Iset in the specification and th~a appended claims, shall r~fer ~o thc substantially hartencd structure of thc arlicles manuf~ctured hercin.
The terms "l~aldenin~" or "trjing", as used in this spcçiflc ~ion ~nd thc app~nded claims, refers to the proccss of removing water from thc molding mixture, p3rticul~rly fi om the starch-bascd gel, to producc a form-stablc articl~. The term "harten~ng", howevcr, is not limited by the extent of gel~tior~ o~the un~el~tinizrd starch cornponcnt or the amount of water actually removet.
l'hc term "fom~-stable", as used in tl~ spc~,.llciulion and thc appended claims, re~ers to the statc in which thc starch-bound matrix of the ncwly demolded articlc has sufficient strength and structural integrity that it c~n be rcmovcd firom the mold, supporl its own wcight against Ihe forcc of ~ravity, rcsist destructive watcr vapor expansion, and rcsist significant defo~mation when e~o;~ to subsequent processing a~d h~T~,rlling,.
The terms "moldct article", "starch-bound artic1e", or "articlc of manufacturc", as uscd in thc specification alld thc ay~ ~ 1 claims, are it-t~ to include any articlc that can be fomled usil g tlle t~ i crlns~i co~ lions and ~roc c 53~ S Cor-t~inrrs ant other articlcs that can be forrned usin6 thc c~n~po~;lions and processes o~ the invention include, but arc not liniited to, tlle following: cartons, boxes, sandwich cort~in~ hinget or two-part "cla~
shell" c~.nt~ln-ors, dry cereal boxcs, frozen foot boxcs, milk cartons, fruit juice containcrs, carriers for bcvcragc containcr~, ice cream ca~tons, cups (includin~, but not limitcd ~o, disposablo drin3cing cups and cone cups), frcnch fry scoops, rast-food carry out boxcs, packa~in~, support trays (for supporting products such as cookies and candy bars), cans, yo~hun c~rlt~in~rs, sleeves, cigar boxcs, confrrt~ ry boxcs, boxes for cosmetics, platcs, vcnding plates, pie platcs, trays, bal;in~ t~ays, bowls, brcakfas~ ~latcs, micro~aveablc dinn~r tl~ys, 'CTV" dinnor trays, c~ cartons, mcat p~ p;ng platten, ~i~pos~blc single use lincrs which can be utiliwd with containers such as cups or food co. tA;"~Is~ cushionin~ malerials (i e., "peanuts"), bottles, jars, cases, crates, dishcs, lids, s~raws, partition.~, liners, anchor pads, corner braces, corner protcctors, clearance pads, hinged shcets, trays, furm~ls, cushioning -~.3~3 SHE~f, ~UG~ 98 TUE 09 40 ~M WORKM~N NYDEGGER &SEELEY F~X N0. 180132B1707 p zl "s~ ~ 7, ~
IPEAI~ S 2 S MAY 1998-materials, al~d other objects uscd in p~ ine, storing, shippin~, portioning, servin~, or dispcnsin~ an object within a conLainer, and ~n endless variety of other objects.
The tenns "hin~e7'. "hin~c arca", or "hinge structurc" r~fcr to thc spccific s~mctur~
mamlfact~red accordin~ to Ihe present invenlion th~t includes, at a minimuln, a crcasc alld S ~n inlerior skin portion havin~ rcduced thic~rl~5~ comE)ared to the thirl~n~ ss of thc rcst ol' ~he .~rticlc. A "hin~e" may include a unilary hinge or multiple hinge portions. The hin~c c3.n bc dcsign~d to b~ ~olded up to anglcs of 360~. I'hc hin~c area may optionally bc trcated wi~h a softenin6 a6cnt (¢.~ Iycerin) and/or srl elactomeric coating to increase the flexibility and durabi1i~y o~ the hingc.
~1. .eTARCH-PfASF.l) CQMPO~TIONS.
The following is a ~cneral ~lisc~C~ion of thc idr-~ 3, I,ro~ les, and prcfcrred yrupu-lions of each ofthe co~ ~pO.~ tc ~hat may bc added to the molting CG~IyGSiliOlLs~ alon~
with how each CO~ ûl~C~t is ~nterrelated with the ~ .cecci~ p~,._t~ , pfo~elties of Ihe _J m~ ble co.. ~i~os;tion~ and properties of the final ~tanh-bound articles.
A. ~;tarch.
'l'he moltin~ ~osillo.~ used to rn~nllf:~r~ro starch-bound articles include starch as Lhe primary bindcr, which acts ai a binder throu~h the formation of a starch gcl and subsequent rcmoval oI' water by evaporation from the starch gel. St~rch is a natural carbohydrato chain comprisin~ prim~rily con~3en~e~l ~luco9e molecules storcd in planLs in granular form.
In general, sta~ch granules arc insoluble in cold watcr and are g~laLiniY,ed by raisin~
the water t~ atu C to a~ove the g~latin t~ t~lro of the starch ~ranulcs. Wllcn Lhc starch ~,ranulcs arc cxposcd to hot watcr, thc ~ranulc walls soften, swell, and then burst to releas~ th~ slarch chains, ~vhich result in th~ gelation of the liquid fraction of thc mixture.
l~he exact tcmperaturc at which a particular starch 6ranulc swells and gelaLes depends on thc type of starch it is. Com starch, for example, gclatcs at a higher tempcrature than potato starch. ~Jnmodifict starch ~ranules can bc ~clatcd Ul cold watcr if the ouler membranc has becn broken by, e.~ rinding thc starch gr~nules. Alternati~ely, starch can bc chcmically modified sû that it will ~o1ate in cold water. Gclatcd arKi hardcned st~rch binds thc 3û indiviclual filler particles and fibers within the colnrosition that has been molded into thc tesired shape of the article.
Although starch is produced h many plants, an i~l~pUI L.-,t sourcc arc secds of cereal grains (e.g, com, waxy corn, whe~t, sor~hum. rlcc, and waxy ricc). ~nother i~r~ortnnt ~UG~ 8 TUE 09:40 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 18013Z81707 P. 22 ~ -- PCTUS 97 /101 68 source inchldes tubers such as potatoes, roots such as tapioca (~.e., cassava ~d manioc), swcct polato, ~nd arrowroot, and thc pith orthe sagc palm.
Thc tcrrn "starch" inclu-les both unrnodificd and modified starchcs 13y "motitled,"
it is mcanl lhat Ihe starch can be derivatizcd or modirlet by typical processes hlown in Il1e ~rt such as, e g, substitution7 eslerificatioll, etherification, oxiclalion, acid hydrolysis, cross-linkillg, and cnzyme conversion. Typical modified slarchcs includc esters, such ac the acctato and the half esters of dicarboxylic acids/anhydritcs, particul~rly the alkcnylsuccinic ~cids/anhydrides; ethers, such as the hydroxyethyl and hydroxypropyl starchcs; oxidi~.et starches, such as those oxidi~ed with hyporhlnrit~; ~t~cl.es reactcd with cross-linlcin~ agents, s~ch as phosphorus oxychlorite, epichlorohydrin, hydrophobic cationic cpoxi~les, all~
phnsphqte deriv:~tives p.~ t by rcaction with sotium or potassiurn orthophosphatc or tripolyphosphate, and combinqti~n~ thereof. Modifiet starches also include scagel, lon~7-chain alkylstarchcs, dextrins, amine ~ hcs, ant tialdehytc starchcs.
A smaller portion of thc starc~ within the molding cc...~l.ç~ on is prel~rably gçl~tini7rd in ordcr to ait the dispersion of thc cQ~"~>Qr.~ throuc~n~t the composition, par~icularly the fibers. ~n ~d~itinn~ the gel~1ini7P~ ~ch ~action keeps tl~e solid colnpo.~
from settling within thc co. . ~rosition. The starch can be gela1ini7~ed by hcating unmodificd starch in thc ~ e of water, or by adting a modifiet starch to the aqueous composition Ncvertheless, thc llnm~iti~A starch CV~ O~ 1 will generally CO~lYJ~;3e thc majority of total starch within the ~olcling c, ~ o:~; l jnn In its ~ morlifi. A granlll r state, unrnodified starches will not gelate in cold water and to not apprcciably affect tllc rheology of thc liquid fraction of the molding compo~itinn Hence, unm9~ifi~l Slarcll can bc included insi~nificantly lar~e Mnounts without ~reatly arrecting thc rheolo~y of the moldin~
composilion since their primary ef~ect on systcm rhcolog~ is negli~ible until the composition J 25 is heated durinE~ the mnlt~ing process. Oncc thc starch-based composition }~s been propcrly positionet within the heated molts, the im,-easc~ viscosity and grecn streng h impartcd by the ncwly gelated unmo~ifird starch component is ad~anta~eous.
From E~ cost standpoint, it is ~dvS~t~er~u~ that the majonty of total starch co1nprises unmodified starch granules, which are typically far less expensivc compared to modified stn~ches. In ract, ~mmodifict starch granules terivcd Srom potato starch are vcry i~lc,.~.lsivc allt ~rc often treated ~s uscless wastc products. In some colmlries it is discarted or fcd ~o c~ttle as a cheap feed material. Hence, thc use of ~ n~if ~A starches provides a trcmendous AMEhlDED SHEET

~UG~ 9~ TUE 09:41 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 18013281707 P. 23 IPE411J~ ~ MAY 1998-economic advantagc over olher matcrials and also provides a uscful outlel l'ot such previo-lsly c~iscarded matcrials.
A pre~'errcd starch is pot~to starcll, which ~luickly ~elales and reaches ;~ maximum vi5coSil~ and yielt slress at about 65~C. lhc viscosiLy and yield slress of a mixlur-!
S contaillin~ gelatini7~d pota~o starch and w~ler then decreases as thc tcmpcraturc is raiscd 1urthcr until walcr is cvapor~ted, aftcr which tl-e viscosity a~ld yield strcss increase }~recipitously. Waxy corn starch acls in a sirrular fashion and is also prererred. Potato anll waxy corn st3rch are also ~Icfc,.~id bcca~se they swcll and gelale casily in a singlc stcp;
howcvcr. ~lly slarch that has similar swellin~ characteristics will be pr~lerrcd to thosc thal swell in Iwo or more stages.
B. Water.
Watcr is an important component wi~hin starch-based compositions used to mold ~ ~ st rch-bound articles. Waler aids in the tispersion Or thc fibrous compo~ent throughout Ihe starch-baset ct~mrosition. Waler is impo~ant for ov~rall molding com~o~i~ion rhcolo~y in ordct to obtain ~ col~lposition that can be readily mixed. transported, and injectet inlo 111C
molding apparanls. Water is important in lubricalin~ thc solid parlicles, solva~ the ~issolvable or gelatable components and in achicvin~ the propt~r viscosity and yiel-l slres!i of the composition. l he waler acts as a ~clating agenl Ihat gc13tcs the un~elalini~cd slarch granules during thc hcatet molding proccss. lhe subsequcnt rcmov31 of w~Ler by evaporation from Ihe slarch causcs it to solidir~ and bind the solid componcnts to~cthcr witllin the moldcd article. Finally, thc watcr aids in f~rTnin~ Ihc cellular structLlr~.
~t a millimum, a sufficient amount of water should bc addcd to dispersc and uniforn~ly gel~te Ihe starch withill the moldct starch-based composition. l'he water conl~nl should also be sufficienl to functioll with th~ particular pluccs~ g equi~mcnt bcillg employecl.
Increasing lhc watcr content inc-ea~es lhc number ar~d si7~: orlhe cclls or voids in Lhe structural matrix and lowcrs thc density ofthe resulling article. In theory, ~he morc watcr in a mixture, thc mûrc vapor that is produced, snd thus, the more cclls in the interior and tho rnore pinholcs in the su~ace lhat arc formcd. In conlrast, usin~ less water yields a motc dellse pro~lucl hz~ing smaller c~lls.
~'he amoun~ ol water that is added to thc rnolding c- mrositionc use-l lo manufacturc starch-bound articlcs will preferab]y be in a r~ ,c frûm about 15% to about 80~fu by ~,veight of the rnixtur~, and more preferably frorn about 30% to about 70% by ~ci6ht. In genel al, tl~c ~UG-11-98 TUE 09:41 ~M WORKM~N NYDEGGER ~SEELEY F~X N0. 18013281707 P. 24 IP~ ~ ~ I tA3Y 199~

~mount of water will bc detemlincd by the desircd rhcolo~y of ~hc composilion as wcll as thc dcsirell porosity and ~lensity of thc final product C. Fibers.
The tcrrns "fibers" and "fibrous materials" includc both inorganic fibcrs alld or~anic S fibers. Thc use of filbers has been rount to provide a numbel of userul bcncfits. Fibers scrvc to rcinforce Ihe structural n~ rUc of the moldcd articles. Morc spccifically, ~hey scrvc to increase thc collesion ofthe partially hz~rdened E~ticles, givinE~ them increascd form stabilily;
they AISO increasc the elo~galior, deflection, ton6hn~sc, fracturc cnergy, flexural strcngth, and tcnsile strength of thc articles. Fibcrs also aid retsining small amounts of residual w~ter w~thin the newly molded articles by preventin~ collapse or ovcr exp~cior of thc ccllular structural Inatrix tue to thc softening ef~cct of the ~vater. In the prior art~ articlcs h~d to be ovcr dried in order to be surcecsfully demoldet, then conditioncd to r~h~ t moisturc and ~~ reduce brittl~ .~rc~, It has bcen fount that thc greatest bcncfit occurs when fibers preferably havinglength grealer than about 1 5 mrn arc used and/or fibcrs baving an aspcct ratio of at leas~
about ZS:l. More prefcrably, tho fibers will havc a length ~rcater than about 2 mrn. Most pret'er~bly, thc fibers will l~ave a len~th grcater than about 3.5 mm and ~ aspcct ratio of al least about 100:1. Of equal or ~reater in~O~l~ce is the level of ~ p~ion of the fibcrs.
More homogenous dispers~on of the fibcrs results in far grcater strength and tol~ghnp~s of the final product. On the other hand, poorly ~ .scd or clumped fibers often result in a decrease in strength u,l"~a.ed to cc~..po,itions in whieh no fibers are used. l'he use of signirlcant quantities of pregolPJini7~l starch in the moldin~ eomposition ai~s in Ihc homo~enous ~i~pt~rsion of fibers throughout the co...po~;lion by transrerring shear from the mixing apparatus d~wn to the fiber level.
J 25 Fibers that may be used preferably includ~ naturally occ~rring organic fibers, such as cellulosic fibers extraeted from hemp, cotton, pl~t lea~es, sisal, abaea, b~ca~se, wood (both hardwood ~r sof~wood, examples of whieh include southern hardwood and southcrn pine, respectivcly), or stems, husks, shells, ant fruits, or inor~anic fibers made from ~l ss, graphite, siliea, ceramic, or metal matorials. Any equivalent fiber which imparls streng,th and flexibilily is also within the seope of the present invention. Recycled paper fibers c ~n be used but a,ro somewhat less desirable becal~e of the fiber disru~tion that occurs durin6 thc original paper manufacturin~ process.

~UG~ 98 TUE 09:41 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 180132~1707 P. 25 IPEA/I.S 2~ MAY 1998 - The amount of fibers addcd to the molting composition will vary deI~cndin~ u~on thc desired properties of the final moldcd article The flcxur~l slrcn~th tou~hncss Ilexibility, and cost arc principle critcria for determining the amount of fiber to be addcd to Ihe composition llle concen~ration of fibers will prcferably be in a ra~lgc from ahout 1 ~o to about 40~~ by wci~ht orthe molding ~o.~ ositinn moro prefcr3bly from about 2% to about 20% by weight, and most pr~ferably from about 3% to about 10% by wci6ht D. ~ Iid Fillerq.
Thc tcrm fillers l, as uset in ~se spccifi~tion and the a~ d claims, includcs both inorganic and incrt or~nic filler particles but does not typically includc fibers, exccpl rlbrous 10 m~t~ri~l~ having ve~y low aspect ratio and which impart litt!c or no strenglheninE ef~cct In general, fillers to not strengthen ~be stn~ctural matrix but merely add mass ant reducc the starch require.l,c..t~ IIowever, inor~anic mineral fillers gener~lly incrcasc the stil~1ness o~' ~he articles which is advantagcous where a stiffer ar~iclc is desired Mineral fillcrs also help the aIticle resist mecb~nic~l dcf~ ation whcn e.~l G;~d to changcs in ambient moi~turc.
Inorganic materials cci.. only used in Ihe paper industry, as wcll as more fincly ground filler matcrials used in the concretc industry, may bc used in the moldin6 CCS~ G~ ti-~nc Ex~unples of useful i~JI~ iC fillers include perlitc, vermiculite1 sand, gravcl, rock, lir~ onP., s~ cts~n~, glagg beads, aerogcl, xerogcls, seagel, mica~ clay, synthctic clay, alun~a, 9ilica, fly ash, fused silica, :~PolitL~s, tabular ~ 3rnins~, kaolin, mi~ l,l,e.es, hollow glass sphcres. porous ccramic spheres, gypsum (calciuTTl sulfate dihydratc), calciun~
c~l,onale, calciurn aluminatc, li~htweight polylners, xonotlite (a crystalline calcium silicate gcl), li~htwcight exp~n~1ed clay~, hydrated or ul hyd-~lLd hydraulic ccment panicles, pumice, cxfoliated rock, and other geologic materials~
A dry-milled calcium carbona~e is a p.~r~ t inorg~nic aggre~atc, sincc it can bcobta~ined at one-third the cost of calcium carbonate obtaincd through wet-milling, ~
prcfcrred calcium carbonate is R040, which has a particlc si~ range from about 10 to 150 microns, with an average particle size of about 42 microns, allt a low specific surfacc arca.
13Otll clay and gypsum are particularly i,~po.~ a~g~ate materials bccausc of their rcady availability, extreme low cost, workability, ease of formation, ant becql~se they c~n also provide a degrcc of binding and strcn~th if atted iT~ high enough amountj (in the case of gypsum hemihydrate).
Exarnple~ of fillcrs which can add a lightwcight characteristic ant higher insulation to thc moldet articles hclute pcrlitc, verrniculite, ~lass bca~, hollow glass spheres, syn-AMENDED SHEET

~UG-II-9~ TUE 09:42 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 1~0132~1707 P~ 26 US~J~ q7Y'~

thehc materials(e.~., porolLs cc:rarnic spherc~, tabular alurnina, ctc.), cork, purnicc, and li61~t-wci~;ht e~panded clays, sand, gravcl, rock, limestonc, s~ld~lone, and othcr ~el~lo~ic~l materials.
The inorgaslic filler is prcfcrably includcd in an am~unt in a rango fiom about 20%
S to about 80% by weighl of solids in the starchbased con.position, preferabl~ in a raJ~c from about 30% to about 70%, ancl morc prcfcrably in a ran~e from about 40% to aboul 60% by wci~ht. ~f includct, inert organic fillers ~i11 prcfcrably be inclutcd in an amount in a rango Irom about 5% to about 60% by wci~ht of the total solits. If included, li~htwci~ht fillers, defincd a~ those hav~n6 a density lowcr than about 1 glcm3~ are preferably includcd in an amount in a ran~e from aboùt 5% to about 85% by weight of the inorePrric~lly ~ ed moldin~
CQmrRitinn~ more ~ f_~ly from about 15% to about 65%, ant most preferably from about 25% to about 55% by weight.
- E. Mold~ A~ A~ont~, _; To ~ssist in dcmolding the newly forrned articles, a mold-r.,leasing agenl can bc added to the moldable c~mposition, Medium- ant long-chain fatty acits, their salts, and their acid denvative~ can be wet as mold-relc~ain~ agcnts. Plcfc. . ed molt-rcl~air-~ agents fior L~se in the prcscnt invcntion include stearates, which have hydrophobic properties 3nd arc not solubtc in ~atcr. Stearate are salts of stearic acid ant ha~c tho general formula of CH3(CHz)16COO-Xt, whese X~ can bo an ion of Al, Mg, Na, ~, or Ca. ~hlm;nll~n stearate i3 one pre~err~t mold release agcnt that has bcen approvcd by the Unitet Slates Food and Drug Adrr~inicttation Silicones can also be used i~c mold rrlr~in~ a~ents. r,ecilhin, which is a mixture of phos}~hatidcs ant glyce~ides, c~n contribute to les~ning of the stirl~in~ ss of the molding compositio~, proviting molt rçle~in~ plope.l;cs, and can improve the flexibility of thc fomled articles. Various waxes such as paraffin and ~ces WBX, and Tenon-based matcrials can also bo uscd ~ moIt-~elFA~ agcnts. To fi~rther assist in relc~iing ~c articles from thc molds, he molds can be polished, chromc p1atcd, or coated with, e g, nickel, Tellon, or any other material that limits the tendency of the articlcs to stick to thc molts.
F. Ol~ti~ln~I Admi~turr~ ~ rost~Formatior ~reatments.
Thc starch-based ~ ion may optionally include other admixtur~is to changc thc rheology of the mixture and/or to improve thc ".rrl~ l p~ ies of the final molded product. F,xamples of uscful rhcology-modifying agents ~ncludc pol~ .cch~idc gums, such as alginic acid, phycocolloits, agsr, gum arabic, ~uar ~wn, locust bean ~um, gum kar~ya, D SHEET

~UG-11-98 TUE 09:42 ~M ~ORKM~N NYDEGGER &SEELEY F~X NO. 1~0132~1707 P. 27 18 IPEA~S ~ AY 19~8 ~mll Lra~acanlh, ~nd IrLixtures thcrcof. A prcfelTed gun is guar gum, ~hich ~ids in prcvenling se~re~alion of the fibers from tlle mixturc; it also acts as a pumpin~ aicl by prevcntin~ aggrc~ation or blockage of thc fibers within the purnp apparatus.
Othcr admixtur~s includc humectanls, plastici7.ers, cross-linking a~cnts, wa~er-S proofillg agents, additional binding agcnts, allt the likc.
Thc molded articles can bc treated in a variety of tiffercnt ways to improvc thcmerh~nicSIl and/or chemical ~ro~..lics of thc articles. ~or e,c~mrle, the surfacc of the starch-l~ound ccllular matrix can be Ireatcd witll ~ polyol, such as glyccrin, preferably aqueous glyccrin ror incrcased peneh~lJility. Glycerin acts as a plP~tiei7Rr, a hurncct~nt, and a stabilizer for reclucing w rping whcn ambient hnrniAity changes. Thc surface can also bc trcated with a coating malerial for increasin~ resistanc~ of t~c article to moisturc and/or for strengthening the article, particularly to prcvent or reducc the e~ects of fracturinK during bending of the slarch-bound cellular matrix, lII. Pl~FPA12~N~'. A~n MO~-l)lNG 'rl~ ~TAl~cH-R ~ ~F,n CnMposITloN~;~
Starch-bound articles of manufaclure are typically produced tilrough a multi-stcp proccss, which includes preparin~ the mixture and then ~olt~ng the composition ~t an elevatct t~ Lure into the desired articles. ~ ition~l optional proccs~in~ steps may include, I'or e~ , printing, co~tin~ cor~itil~ninc~ and p:~r~a~.jne of the ~nal articlcs, in ~ltition to the post-fiorn~tiorl i~,L-~ t with 61ycerin ~nd/or l~li7~ d or general ~.lactnm~-ric coatin~.
A. Prcparin~ e Mixture.
There a~c a number of diffcrent mixing apl,&~us ant mixing sequenccs that can beused to yield the co . .r o~il in~c of ~e prcscnt invention. The only criterion is tl~at tl~c mixing means be able to yield a starch-based conJ~osition in which all of thc components, p~ticularly the fibrous material, are subst~nti~lly ho,.. og~neously mixcd throughout the c.,...l,GsiL;on. Both high shear and low sl~ear rnixing appalaL~s are ~ ,~.,ed depen~ine on thc sta6c of the mix~n~ process. Typically, the fo~nation of a pregel mix and also thc dispcrsion of fibers is carried out usin~ a high shear mixing apparatus. Howcvcr, when mixin~ in the atditional llngel~tini7~d starch CO~ rnt and also fragile inorganic fillcrs 3 0 ~vhich arc morc easily brokcn, it will generally be prcferable to use a low shcar mixer in or~cr to protect thc starch granules from prematurely gel~tini~inE~ and also to prcvent ~he fiagile a~g,rc~ate fillers from breaking, ~UG-11-98 TUE 09:42 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013231707 P. 28 , P~:T,~IS 9 7 / 1 0 1 ~ 8 ~P'F~ S ~; MAY 1998-~n a ~.refe.,~.;d embodimenL, a portion of the wa~er and starch are blcnded to~lher ~Qth thc fibers and, optionally, thc inorganic fillcr, in ~rt~r ~o Çvrm ~ preblcnd mixturc. I'his is ~onc at higll sllear. Gums such as guar gwn arc ~cnerally a~3dcd to tbe prcblend mixturc~
111creafler, thc rcmainder of the water and the ul-gelq~ini7rd starch asc added to the preblcnt mixlurc and mixed at low shear to blend thc starcll without causing it to prcmatulely gclPti~ e Thc mold relcasc a~ent is typically a~lded durirl~ this second mixin6 phase~
Weaker. Ii~,ht vei~ht a~grcgate fillers should also be combined using low shear mixin~
Examplcs of high shcar mixors include the TMN turbo batter mixers that are available from Franz ~I~as W~ff~ h.nen Intustriegesellschaft M.B.I~. of Vienna, Austria. ~ltemative high shear n~xer~ are rli~closc~l ant clain~ed in U.S. Patent ~o.

4,225,Z47 entitled "Mixing and Agitating Devicc"; U.S. Patent No. 4,552,463 entittcd "Mcthot and ~ppar~tus for Producing a l'olloir~Rl Mixt~ure"; U.S. Patent No. 4,889,428 entitled "Rotary Mill", U.S. Patent No. 4,944,S95 enlitled "~pparatus for Plod~ C Cemel~t Builting ~aterialQ"; and U.S. Patent No. 5,061,319 entitled "Proccss for Prod~cir~g Cen~ent Builting MateAal". }~or purposes of disclosure, the fo ing patents are ~ICGllJGratCd herein by specifir r~fe.ci. Ice. ~Itematively, a variable speed mlxcr can be used to providc both hi~h ant low shear m.ixin~. Variable speed mixers include the F,irich Rv-l 1. An examplc of a low shcar mixer is a Hobart M~xer.
Once the co...~on- "t~ have been atequ~tely dispcrsed throughout the starch-based co~ osilion, thc starch-based ec~ ,,ilion is ready for molding. It may bc desirable at lhis st~gc to increase the watcr content ~n ordcr to adjust the viscosity of the molding composition to ~ d~sircd level.
B. Forminp the M~ rc i~Q~ho n~ ed Article.
Once the rrol~lin~ apparatus ha-~ been ~,1e~ atcd, it is preferably romled into thc J 25 desired shapc of the article throu~h the US8 of heatcd molds. A detailed dcscriptioll of thc ty~e of molding app~..lus that may be used to mold the arLicles of thc present invention ;Q
set fo~h in Scrial No. 08/353,543, 1~f,.~,l.ced above. Scri31 No. 08/353,543 also scts forth a delailed dcscription of ~1ef~cd m.-thn~lc for generally moldin~ starch-baced composition5 usin~ the disclosed app~l,tus.
nle molding ~rP~ should be heated to a temp._~tule that is suff ~ içntly hi~h tocause the rapid cxpansion of a starch-baced co~l.yci:~ition within thc molting d~pat atus and also in ordcr to drive o~ a substantial portion of the watcr by evaporation. Preferably, thc molding appdlut~s should be hcated to a t~ ure gre~tcr than about 145~ C, more hiv;ci~3t~ SHEET

~UG-11-98 TUE 09:43 ~M ~ORKM~N NYDEGGER &SEELEY FAX NO. 1~01 281707 P. 29 îP~ ~7C~ 9~88 prcferably grcatcr than about 175~ C, and most prc~crably grcat~r ~llan about 195~ C. 1 hc ~cmperalure st-ould not be so grcat, however, so as to eause buming, scorchin~ or calmclizAtion of the starch binder. This genctal~y occurs at ~emlleraturcs greatcr Ihan abou 250~ C. In most cases, it w~ll bc prcferable to maintain olle mold componcnt at a 5 temperalUre that is sligl)llSf holtcr than the other half, such a_ 5~ or 10~ C hottcr. ~t h~s becn fo~d Ihat thc n~old~d .~iclc will be more easily rcleased from the mold component ker~ al thc hotter tc~ ,.aturc, thereby .~Psien~ting the mold co,..l~nc~rlt from which the articl-: will be removed last.
Thc molds are preÇerably matc of metals such as steel, br~ss, and ~l~minllrr) Polished metals, including chromc and nickel, along with Teflon coatings, make it easicr to removc the srticles from the molds and create a qrnoot~ finish. Thc material of the molds must be able to withstand the tcmperaturcs and pressures enco~tered dLlring thc ~nllfP~ rillg process.
The molds can be heated by a vanety of heating means. FY~ples of lleating means for hcatin~ at least the surfaccs of the molds jnrl~ extcmal heating el ements, such as gas bu ners, ir~ared li~ht, and el~ heahn~ elements, which can be ~n~ or directed ~tthc molds. Other alternative exarnples of heatin~ mcans are hcaled liguids, such ~s oils or heated gases, such as steam, ~at c~ be piped through the molds to hcat them. Various types of heating can also be used to va~y ~o t~ e~ e of thc molds along thc length Or Ihc molds in order to vary the properties ofthe hardcnc~ matrix vithin the molded articlc. It is also possible to heat ~e mixtures without heating the molds. For examplc, thc molds can bc madc out of cerarnic and microwaves be appliet to heat the mixture.
By varying tho ~ernp~rat~e and p~o~c,~ing time it i~ ~ossible lo a~fect Ihc density, porosity, and thic~nes~ of the surface layer, or skin. Gcncrally, in order to yield a molted articlc having a thinner but rno~ dcnsc surface laycr, the molding ~emperature is lower, thc molds have fewer vents, and the moldablc ~ h~ has a higher viscosit~. Thc viscosity of he mixturc can bc increasct b~ adding a rhcology-modifyin~ a~ent, such as Tyloscq~, including less watcr, or by using an aggrcgate material having a hi~hcr spccific surfacc arca.
Figure I tepicls a pL~ jlJC-,LiVC ViCW of one embodiment of a mol~ling appdralus for mass production of molded starch-bound articlcs, which is cornrncrcially availablc as tlle BIO~AT 32 sl~ch foarn cYpAn~ion wlit from Walten~erk Kiel GmbH. & Co. KG, loca~ed in Kiel, Gcrmany. As shown in Figure 1, moldin~ apparatus 10 fimctions in a continuous - ~v; ~-'cC~ cT

~UG-11-98 TUE 09:43 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P. 30 21 IP ~ S '~ h A ~ 1~9 rrocess to m~ss producc desired anicl~ 20 which in this embodimcnt are hingecl "clam-shell" containcrs.
Articles 20 ~rc folmed in scveral st~ges that arc simultaneously bcin~ pcrformc~l ~y difFerent co-nrollents o~molding apparstus 10. Molding appara~s 10 has a formin~ statiol~
S ~0 attached to and communicAtill~ with a hcalin6 station or heatin~ apparatus 40, I Jealing app .ratus 40 includes ~n insulation wall 42 that del;nes a llcating chanlber 44. I Icating apparatus 40 further compriscs heating elemcnts 46 which are positioned within hea~inE~
ch~nber 44 for providing heat therein. Heating appa~atus 40, and more particularly thc ~mpor~ t of hcatinE~ appara~us 40 which in~ rs insulation wall 42, hcatin6 chamber 44 and heating cl~ 46 arc an exars-plc of a hcating means for heating tllo rnolds or at Icast onc mold, whcrein the heating means is in thcrmal cQ~-municatio~ with at least one rnold.
A traclc systcm 50 cxtends throu6h both fomling station 30 and heating chambcr 44 in ~ col~tin~n~, circular fi~ehinn Track system 50 includes an upper track 52 ant a low~ar tsack 54. Riting on traclc system 50 via wheels 56 are a plurality of intc.conllected heatcd molds 60.
~s best sllo~rn in ~'i6ure 2, each mold has two co,.,l.one..ts includin~ a top plate 62 ant a bottom plate 64 Top plate 62 ~nd bottom plate 64 include a male mold 66 and a female mold 68, ~ ely. Top plate 62 ~nd bottom plate 64 are connected togethcr at onc cnd by a hingc 70. Male mold 6~i and femalo mold 68 are configured to cnable malc mold 66 and female mold 68 to be coupled togethcr at an offset dis-ance sulrlcicntly closc to molt a cc ..,E,os;iion into an a~ticle. In ~e eml~o~ rlt shown in Figures 1-2, top platc 62 and male mold 66 arc integrally cnnnr~,ted as are bottom platc 64 and female mold 68.
Hin~e 70 is an ex~mple of a movement means for incrc~ing and decreaçing Ihc of rsct distance betwccn male mold 66 and fcmale mold 68 by moving top platc 62 and bottom plate 64 togetheT and apart. Hinge 70 cnablcs male mold 66 ant female mold 68 to bo brought into suffi~ nlly closc p~UXi~lliIy w~th each olher that a composition placed betweetl male mold 66 and fcmale mold 68 can be moldcd into an articlc of manufacture, and ~hcrcby the articlo can be removcd by then increasin~ the ~ n~e between malc mold 66 and female mold 68.
Refcrrin~ to l~igure 2, in the firsl stagc, hcated molds 60 are open and positiolled to receive a moldable mixture 80 ~rom filling spout 82. Moldable mixh~re 80 is puml~ed S~rom a mixer (rlOt shown) via an exttudcr Ihrough a ~icp~ cin~ pipc 84 to filling spout 82. I~iling spout 82, ~icp~ rlcing pipc 84 and ~n extmder or the equivalent are an cxamplc of mcans for ~UG-II-9~ ~UE 09:43 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 180132~1707 P. 31 lP~WS 2997~A~ 99~6 8 dclivering 3 moldable rr~ixture to heaLed Molds G0 Heatcd mold~ 60 arc opcncd bysepar~tin~ upper track 52 and lower ~rack 54 on which top plate 62 and bottom plale G4 ndc, rcspcctively Filling spout 82 is llscd to disch~rge a selected q~ qntity of moldablc mixturc 80 into fcmale mold 68, although this systcm can be modifict to ~ccomrnodate com~ositions having ~rcatly valying rhcologies For examplc, hichly viscous or high yicld mixturcs can bc extruded to fonn a discrete volurne of nlalerial, which is Ihcn separated and droppcd illtO
Ihe mold by a cuttin~ means Once female mold 68 i9 filled, healed molds 60 advance and arc closed as a result of uppcr track 52 ant lower track 54 closing to~etller Convcntional locking ..~cch~.isms can be used to lock the mold halvcs togethcr as long as they arc able to withstand the l~rc; ,u cs produccd by the heatcd r ~ixture5 ~vhich is up to about 5 Bars Referril~g to Figure 1, he~ed molts 60 travcl the length of heating ap~aratus 40, ~otatc to an invcr,tet positinn~ and then travcl back to forming station 30 ~IeaLing ,.~ cl~ c.lt~ 46 are posi~inn~d w~thin heating cll~m~rr 44 fo~ heatin~ heated molds 60 as they travel ~II~Gt~huugh The speed at which heatet molds 60 travel through hcating app~ratus 40 is in part limitcd by the required time it takes to fill heated molds 60 Tho fi~ling timc is, of course, A~.~"~A~ on tho sizc ofthe ~rticle bcing moldet The forrning lime and tc~ t~lre are ~lccted so that whcn hcated molds 60 return to forming station 30, the fo~mcd articl~s can be removet from the molds in a forrn-stable c~n~litior, Once thc molts relurn to fonning station 30, hea~ed molds 60 are a~ ain opened by S~,F " 3 upper Irack 52 ant lower t~ck 54 A scraper blade 88 is thcn passed over fcmale molt 68 to rcmovc excess material that may have cxitet through vent holes d~lrin~ the heating process l~le formed articles are removcd from fernale mold 68 by a m~ans for removin~ the formed articles from a mold ~n cxample Or a rcmovin~ mean~ is shown in ~i~ure I and compnscs a rotating dmm 90 wilh a plurality of rotating a~ns 92 Arms 92 are ~ff l~-hrd to f~n~l Pd to the rotating dmm 90 or the axle of thc rotating drum 90 anci follow the rotalion~l speed of the axlc of t~m 90 Rotating arm~ 92 arc att~ d to vacuum suction cups 94 conh~ured to removc formed articles 20 from female mold 68 Vacuum suction cups 94 arc made of silicone rubber and are heat resisl~nt up to about 250~C Movcmcnt of drum 90 is controllet by traclc systcm 50, with drum 90 positioned wi~hin lower track 54 As drum 90 rotatcs, arms 92 bend in towart the open~t hcated mold to pick up formcd products 20 ~i~h suction cups 94 Amls 92 then bcnd oulward from drurn 90 and a convcycr bclt 98 is used to catch ant transfer forrncd protucts 20 ~o~ subsc~ucnt pro~çss~ng such as applyin~ a ~UG-11-9B TUE 09:44 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 180132B1707 P. 32 '- ~ PGLJ~97/1016 iP~A~ 2 ~ MAY 199~

eoatin~ thereto. With fomlet products 20 remo~cd form l~ealed molts 60, thc mo~ds rctum tt~ rlllin~ spout 82 and the proccss is repcated.
In all alterna~ivc process for forming articles of the invention usin~ molLli~
apparat~ls 10, a moldable mixture 80 is ~ ,cued using a Hobart mixer, Eirich mixcr, or similar mixer havin an 80 ~allon c~pacity. Such a mixer providcs cnough matcrial for the produc~ion of at least abou~ 3000 articles per hour, up to about 14,000 pcr ho~r. Tho moldablo mixturc is then transfcrred to a vacuum hoppcr ant pumped using a rnonopump havin~ one auger through a dispcnsin~ pipc 84 to fillin~ spou 82, Tha monopum~ in combination with ~;cp~ncing pipe B4 and filling spout 82 providc another examplc of mc~s for dclivering a moldable mi~turc to heatcd molds 60. The monopurnp pushes the malerial under pressurc at a rate of about 6 kg/min. A guillotirle m~rh~ni5m is used to open and shut fillling spout 82 for a spccific time, ~.efe.ably for about 0.3 sc~onAs This allows about 30 ms of thc moldablc m~xture to be r~ in~o female mold 68. The filled molds thcn B~ througl~ heat~ng apparalus 40 at a ralc of 3 5 cm per second and are heaLed for about 30-3 5 secor~1s The forrncd articles ~re thcn rcmoved from the molds by v~cuum suction cups 94 as described abovc arld are placed on conveyer 98. No subscq~lent conditioning o~ the formed articlcs of thc invention is Ic.luir~t be~ore bcing sui1~hle for usc~
By using the co~ bsi~ionq and ~elh~ q tiiqrl~s~t herc~n, a wite var~ety of diffcrcnt articles can be molded that will havc adcquate stren~th and stmctural inte~rity to be dcmolted and thcn shipped to the de~ired ~le~in~tion without ~e rleed for a. subscqucnt lengthy conditioninE~ step. The ability to Ir~n~lfr~~l~re articles without a conditionill~ step, or simply a very short conditioning slep, is a significant improvemen- over the prior alt. It fllso within thc scope of the invcntion to r~lrther treat the molded articlcs to enl ance their llexibility alld durability.
C. Sl~ir Thickness.
In general, thc starch-bound ccllular matrix includcs a relatively dense outcr surface or skin surrounding a rclatively porous intcrior portion. Thc skin forms as a result or a process th~t uscs paired male and female moids that are heated to "bake" thc starch-bascd cnmrosition E~nd thereby r~:move water fi~om the starch-b~set mixturc by evaporalion. The hcated molds arc prcferably made from metal, ~hich is a good con~-c'nr of heat and WhiCIl h~s relativcly high spccific heat. Dryin~ out thc starch binder causcs it to solidify and rorTn the bindin~ matri~c. Re~ cc thc transfer of hcat &om the molds to the slarch-basccl mixturc occurs only at the surface Llt..rL~ between ~e mold~ and the mixturo, the skin is dricd out ~UG~ 9~ ~UE 09:44 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 1~013281707 P. 33 h~Y~998'-' more quickly thall the intcrior portion. This allows thc interior portion ~o ullder~o ~urlhcr expansioll and c~ll formation for a period of time after initi~l skil- formation. Hellce, thc interior portion is more porous and has a reduced dcnsity.
Becausc mctal is such a good conductor of heal, hcat inputs ~re quickly equilibr,~L~l lhroughout the molds such that thc mold t~"lpe.~lture is essentially unifonn throughout cach half of the mold pair. This 1n turn results in almost uniform transfer o~ heat from thc mol~s to the slarch-based rnixture. For this rcason the skin has been obser~ed to have a remarkably constant thickncss throughout ant on both sidcs of the moltet articlcs. Neve~thelcss, altering the rate of heat transfer du~ng the molding proccss can change thc thir~nesS of lhe skin. In somc cases it may be desirable to optimi7~ the s~in thirl~nesC, slnce increaset skin 1hi~ n.-5s results h~ articles havi~g more surface strength. However, skins of incrcased thickness arc also generally morc ngid and more likely to ~acture if rnc~lrs-~ir~lly dch"".cd.
In general, the skin tl~i' L n~ss is directly ~.upoltional to thc rate of heat trans~er from the molds to the st~rch-ba~d rnixture. Increasing tho rate of hcat transfer generally inLI~ascs the skin thickness; red~lrin.g thc ratc of heat transfcr generally reduces thc skin thickness, In likc fashion, the rate of hcat L~ ar~.~ from the molds to thc starch-based mixtllre is dircctly proportional to the t~ e~ ; of the molds. InL~ the mold tc ~~r~ re increases Ihcrate of hcat trans~er, while rcd~e;~g the molt ~. .IIE~.~e rctuces the rate of heat ~ransfcr.
Hcnce, increasing the molt t~ ul~ generslly results in increased skin thir~n~ ss~ while reducing the mold tL.. ~p~.ature generally results in tc.,leased skin thir~n~ cs However, it is virtually imI~ossible to heat diffcrent parts of an lnte~rally fomlcd me-al mold to differcnt ~empcratures in order to alter the skin thirL-nPq5 throughout thc molded article.
D. ~nlll ~paratu,~ ~or For~ina Tl~i"ner ~nteri~lr ~ l Portion.
Tn ordcr to mold the articlc such that inLerior skin portion of the hinge ~rca has reduccd thich~oss, the prcsent inven~ion prefcrably utili~.es spccially dcsigncd molds in which the portion of the mold surface cul~onding to thc interior skin portion o~ Ihe hin~c transfcrs lcss lleat p~r unit of time cGInp&red to the rest of lhe mold. In a preferred cmbotirnent, thc mold area corr(~spor.~;nc to thc intenor skin portion of the hinge compri~cs A material having a hcat diffilsivity Ihat is lcss than the heat dirrusivity of the surroundin~
mold.
Hcatct molts 60 are prcferably formed from matcrials, such as metals, that enable heat to be rclatively rapidly tl~sf~ d. Ex~lnples o~suitablc materials include, but are not l~mited to, all~n-inl~n steel, and cast iron. Thc portion of the mold surface cor~s},ondin~ to AMENDED SHEET

~UG~ 9~ TUE 09:45 ~M WORKM~N NYDEGGER &SEELEY F~X N0. 18013281707 P. 34 IPEP~ oS 97~q~gg8 - lhe intcrior skin portion of the hin~e is preferably formcd from a hiE,h ~cmp~ra~ur~ pl~lic or cerarnic that transfers hcat less rapidly than the surrounding mvld. ~ hc mold portion is also preferat~ly formcd from ~ matcrial tl~at is machineablc and durable. Examplcs of suit~lblc m~tcrials for tr~lsferring less h~at than thc surrouuding mold includc, l~ut aro not limitcd to, S poly~lhcr cther ke~onc (PI~EK), Al~Ol, glass-fiber-reinforced T~flon, porcclain, silicol)e, rubbcr, or ceramics Nevcrtheless, any combination of materials is within thc scope to the cxtcnt that the matcrials resul~ in _n interior skin por~ion of thc hin~e llaving reduced thicknes~.
An exarnple of a mold confi~5~..L;on rln~ l to form a hingc having ~1 interior skin portion of re~lucct thi.~ c is shown in ~igurc ~ and is best vicwed in Fi~urc 3 which is a cross-sectin~lAI view of onc of thc molds 60 shown in Figurc 2 a~cr male mold 66 and female mold 68 havc bee~ coupled to molt mixturc 80 into an article 20. A moldir~g s~rip 100 having lower heat dif~sivity i5 shown in contact with and adjacent to malc mold 66. More particularly, molding strip 100 is conn~- t~ ~i to arld extends firom malc mold 66.
Moldin~ strip 100 has a bottom poltion ~,chor~d within male mold 66 and a top portion extcnding fiom ~It ~cyont the surfacc of male molt 66. The top ponion comprises ~o subst~nti~lly parallcl protrusions or ridges lOZa ant 102b which exteml outward lowards ~malc mold G8. Extc~ion~ 102a ant 102b arc tc~min~trd at tips 104a an~l 104b respeclively. Tips 104~ ant 104b alig with two small substantially parallel projections or nibs 108a and 108b that cxtend fiom female mold ~8. Tips 104a and 104b do not t~uch nibs 1 08a and I O~b whcn thc mold is in thc closcd position as shown, as they are offsct from cach other at a sct dist~nce.
Molding strip 100 is shaped or configurcd to cause an impression (o be rormed in an article molded be~wecn malc mold 66 and female mold 68. Moldin~ strip 100 has a thcnnal ~5 di~rusivity that is Icss than the the~mal diffilsivity of male mold 66 thereby enabling an article to be formet with a crcase and at least one sec1:ion of thin skin at thc crcasc, thc thin skin seclion bein6 a section of skin that is thirmer than the skin Oll the opposing side of the arlicle or sections adj~cent to thc thin section. Thc slower heat transfer along moldin~ strip 100 enablcs thc starch-baset mix~ure to foml morc slowly yielding a thimler skin in the articlc at thc arca of the articlc formed oppositc molting strip lO0.
Male molt 66 and remale molt 68 are prcfcrably formed from thc same material, ~hile moldin6 strip 100 is pIeferably forsned ~om a matcrial havin~ a lowcr hcat diffusivity or conductivity Ihan malc mold 66 or female molt 68, such 8s polyethcr elher ketone ~M~iDCD Sh~~T

~UG~ 98 ~UE 09:45 ~M ~ORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P 35 26 IPI~S~SI 2 ~ MA~ 1998 (PrrK), Al20~, glass-fibcr-reinlorccd Teflon, ~orcelain, silicone, rubbcr, or a cer~mic Tl c h~cr thc material, the more easily it can be machined to form the desircd ~roovc hrmin~
rid~e wilhin lhc molding strip 100 and Ihe more durable it ~ill bc whcn uscd lo mokl arlicles Moldin~, strip 100 is .~n cxample of a mcans for fonning a thin skin by LransÇerring lcss hc.lL
to the r,larch-bascd mixlure than either of mal~ mold G6 an~/or icmalc mold 68 In many cascs, it will be }~rcfcrrcd to spray thc moldin~ strip 100 with a silicone or olher adhcsion re~ rin~ liquid tunng thc mnl~ing process in ortcr to reduce s~ nc of the molded s,tarch-based article to thc molding strip 100 ~cverthelexs, any mold con~lguration that is able lo r~ducc the rate of heal llow or lransfer to the interior skin portion of the hinge within thc molded arliclc such that thc in~erior skin portion hss retuced thi~ n~ss compared to thc skin thi~l~n~c~ in other portions of thc &rticle is ~vithin the scope of thc prcsent invenlion For cx~rnrle, another way to reduc~ thc flow of heat lo thc interior skin portion of the hinge is to inco-l,o-ak witl)in a mold app~ralus of llnifnr-Tl material a molding s~rip 100 having reducet thirll n~ss. Bccausc lhe specific hea1 and heat diffi~sivily of the molt apparalus rnatcrisl is ur~iform Ihroughout the mol~l, the molting strip 100 will havc a lower hc~t capacity tuc lo its reduccd thickncss Because of this, the molding strip 1 on will have a lower reservoir of heat such that il wil I
transfer less hcat during tho inidal slcin formation stage comparcd to the thicker portions of thc mold The practic~l effect would be that molding strip 100 would cool town mlore quickly as a result of thc evaporation of water cG~p~d to ~c rést of Ihe mold Anothcr way to reduce thc flow of heat to Ihe interior skin portion of the hin6e area would bc to coat or l~min:3t~ the molding slnp 10~ with a material that has lower hea~
di~sivily or heat conductance such that thc aow of heat is impeded Such co~tin~C includc, b~lt ~rc not lirnited to, Nedox (Tcflon i~-lplcigr~-l~ ~ilh nickcl) md l'uf~n (aluminum oxitc infilLraled with l cflon) Yet another way to rcduce thc flow of heat to the intelior skin por~ion ol' lhc hin~c area would be tO thrrrnAIIy isolate the molting strip 100 from thc rest of the mold al-d thell providc sep~ate healing means for selectively healing the molding strip 100 to a Icsscr dc~ree than the rest of thc mold IV. nF~I~N.q AN~ FEAT~J~F~ O~ ~NVl~NTlV~ H~NGF~.
Thc tcsi~n of hinged ar~iclcs within the scopo of the prosent in~en~ion involvossel ~ction of a pa~ticular mix~urc of thc above materials in combination with ~he selcction Or a hingc dcsi~n based on the dcsircd final ~ ,p~.lics ~he tcsired final propcrties are ~UG-II-9~ TUE 09:45 ~M WORKM~N NYDEGGER &SEELEY FAX NO, 180132~1707 P. 36 -- IP~ AQr ~g9&

~l~lcrmincd primarily ba~ed on thc intended use of the articlc. 'l'hc hingc can compri~
sin~le hillge or a multiple llin~e dcpcllding on thc clcsired bendin~ and pcrformancc clitcria of tllc particular article. ~ sin61e hin~e will expericncc stress c er the enlirc bcnding an~lc of (he hin~e. ~n a double hinge, each hin~c unit will only be bent about half tllc distance ol' S thc overall brn~in~ anL~le o~thc hin~c, while each hinge ~mit in a triple hin~e will only h-:
bcnt ~bout one-third of thc distance of the overall bcnt~in~ an~le of the hinge. For a clam-sllell c~ taine~l~ which is required to bcnd about 180~, it is presently ~ f .~cd to usc a doul lc hingc such that each hingc unit is require~l to bend about 90~, or half of the overall bcnding angle or t1ict~nt~c of tho hinge.
The less a hingc or hin e component must bond during the bcnding action thc Icssstress is applicd to the hinge, pPrticularly in compressing thc intcrior skin porlion ol' lho hin6c ant in elongi~in~ the exterior skin portion tusing the b~n~ing action. In gcncral, multiplc hin6es are more durablc than single hinges sincc cach unit will only be requircd lo bend o~er a fraction of thc overall bendin~ anglo. In this way, thc mt~h~nical strcsses are distribute~ over a lar~er area of the hinge. ~ltcr~n~ the mold apparatus to manu~cturc articlcs having multiple hinges is sirnply a mat,tcr of incluting onc or more additional mold structures that will forrn one or more ~ itinn~l crcascs within the hinge structllre.
S~lectin~ the desiret multiple of hin~e units is a matter of having enough hin~,c units to distribute the mechanical ~tresses ~cso~ w~th the b~n~in~ action, while not having so many hinge units that the hinge beco .~e clumsy or in which the bend angle is so uncvcnly distribu~ed bel~veen thc hin6e unit_ that one or morc of the hinge units docs not funclion or sc vc any purpose. The dcsign and intrl-~cd use of the hin~ed ar~iclc is ~ factor in sclcctin~
a p~rticular dcsi~n. Most hinged conl iners must bc at Icast sufficiently durable to rell-ain closcd without failure after bcin~ closed. While a hinge Ihat can only bo closcd oncc is sLl~rlcicntly durablo for cenain uscs, hin~,es preferably are sufficiently durahle to b~
rcpea~edly opcncd and closed.
Figures 4-7 dcpict one embodimcnt of the present inverltion, ~vhich is a containcr havin~ a hin~e structure with two crcascs. l;i~ure 4 is a p~ ,Live view of an open clam-shcll cor~ rr dcpictin6 a double crea~ied hinge s~ruclure. Figurc S is a pcrspcc~ivc vicw of the clam-shell containcr in Fi~ure 4 in a closet position. Article 20 o~ Figures l -S is a clarn-shell containcr 20, which is an eY~n~rle of a hingcd cont~in-~r that must bc at IC3St sufficiently durablc to rcmain closcd without failure after being closed once and lhat c~n preferably be opened at lcast once without failurc. I-Iowcvcr, this ant other containcrs ~UG~ 9~ TUE 09:46 ~M WORKM~N NYDEGGER ~SEELEY F~X NO, 18013281707 P. 37 3C - ~ S 97 /1 01 68 IP ~AI JS . 3 MAY 1998 disclose~l her~in ~re r1refcrably suft~cicntly durablc so that thcy may be openc~l and clo~d sevcral timcs.
Tlle clan~-sll~ll container 20 h~ a hingc structurc or unit 200. Hinge Str~lCt~lrC 200 compnscs thrcc intcgral segment.s includin~ A flexible bendin~ region 202 betwccn a top arm 204 and a bol~om arm 206. Top arm 204 and bottom 3lm 20G are more ri~,id than ~lc~<iblc bendin~ rcE~ion 202. Top ~rm 204 is also an in~gral scgmcnt of a top 214 of container 2,0 alld bollom arrn is also an integral se~ .erlt of bottom 216. Accordingly, top 214 of containcr 20 and bottom 2l6 of cont~nr~ 20 are inlegrally conncctcd by hinge structure 200. This hin~e structure is an cxample of ~ hinging mcans for opening E~d closing thc containcr by pi~otin~ thc top ~t bottom relative to each other a~ the hingc mcans ovcr a bending anL~le.
Figuro 6 is an cnlarget schematic dr~ictit~n of a cross-section o~ hin~e structurc 200 shown in Figur~ 4 in an opcn position. Figure 7 is an cnlar~et sch~rn~tic depiction of a cross-scction of l~inge structurc 200 after bein~ folded into a closcd position as shown in I;i~ute 2.
Thc cross 9~itiU!~ iews shown ~ Fi~urcs 6 and 7 depict thc starch-bound cellularmatrix of hillgc stn-cture tO. lhc starch-bound cellular matrix has an irmcr cellular core 220 betwesn an interior skin portion 224 and an cxtcrior skin portion 226. ~nner cellular cor~ 220 is distinguishable from interior skin portio~ 224 and extcrior skin portion 226 since imler ccllular core 220 has a porosity th~at is s~lbst~ntiPlly greater than thc porosity of intcrior ski~
portion 224 and extenor skin portion 226. Conscquently, in~erior skin porlion 224 ~nd exterior skin portion 226 are substantially denser than inner cellular core 220 Two substantially parallel dcprcssions or creascs 230a and 230b are located wilhin hin e structure 200 Crcascs 230a~nd 230b are fomled into thc starch-bound ccllular matrix on thc sarne side of the hinge structure 2~)0 ss thc intcrior skin port~on 224 I lence, cr~ases 230a and 230b arc tisposet directly within inLerior skin portion 224 Crcascs 230a ~nd 230b provide clean b~n~in~ lines upon which hinge 200 will bend and in~erior skin 224 ~vill collapsc or buckle turing closure of contauncr 20.
Creases 230a and 230b ~re spaccd apa~t by a sw~ll 232, which is also within inlerior skin portion 224 Creases 230a and 230b and ~h~ area of hinge structure 2û0 surrnunding cress~s 230a and 230b, such ~c swell 232, define bendin~ region 202 The intcrior skin portion 224 has a thickness at ancl around creases 230a and 230b th.~t is less ~hsn thc thirl~n~ ss of exterior skin portion 226, ~;~rticul.~rly the section of e~terior skin 226 that is opposite crease 230a ant 30b ~n general, the thickness of intcrior skin AMENDED SHEET

~UG~ 98 TUE 09:46 ~M WORKM~N NYDEGGER &SEELEY F~X NO. IaO132al707 P. 3a IP~ 7 /~~199~8 portioll 224 wi~hin ~he cntirc bending re~ion 202 will be le~s than tlle ~hickncss of cxtcrior skin r~orlion 226 in thc bending rc~ion 202.
Eacll ~;r~ie also includes a basc point. The base points of cre~ses 230~ and 23ûb ~rc idel tificd as 234a and 234b. Opposite basc point 234a and 2341~ are two subsl mlially parallel slldllow ~,roovcs 236a and 236b within extcrior skin porlion 226, which arc lllUCh rnorc shallow comparcd to creases 230a and 230b. The ~rooves 236a and Z36b act 3S
bending ir~itiators during thc bcnding ac~ion b~ providing elongalion distribution in a de~ired localized area of cxtcrior skin portion 226 .
~c bendabilily of hin~c structure 200 is bcst vicwcd in Figurc 7 which gr.l~ rn~ tically depicls a cross-section of hingc structure 200 af~er bcin~ foldct into a closcd position. A
substqntinl I~ortion of bcnding region 202 cxpcriences eilher compression or elor.g3tirn as hinge slruct~rc 200 is hlded by pivoting anns 204 and 206 towards each othcr.
Althou~h most of b~rlAin~ r~g~on 202 moves during folding, thc ~reatcst mov~mcnt-J is cxpelicnced at or _round the respectivc rcgions in bctween basc points 234a and 234b and ~ooves 236a and 236b which _rc necks 240a ant 240b. Moro sp~cifir~qlly~ thc mostsubstantial col.lprcs~ion of thc inlerior skin portion 224 nd çlor Gqtion of tbe exterior skin porlion 226 is expenenccd in the area of necks 240a and 240b. The tl-irL-nf ss of necl;s 240a ant 240b is preferably optimized based oll lhe mixturc and hinge de~ign to cnablc inner cellular core 220 to co~ r~ss during foldin~ of the hingc and exterior skin 226 to elonga~c ~ hout mpturing. To minimi7~ the compression and strcss experienced in bRn~inJ7 rc~ion 2û2, necks 24ûa and 240b are ~referably sicnific~ntly thinner than adiacent sections such as ~rrns 2û4 or 206 or swcll 232.
~I he relative Ihickncss of necks 240a and 240b is bcst describet by r eference lo Ibo thickness of hmer cellular corc 220 at nccks 240a and 24ûb conlpdfcd thc thickncss of imlcr ccllular coro 22û in othcr sections of hinge structure 10, such as arms 2û4 and 20fi Thc tl~ickness of inncr cellular core 2ZO at nccks 24ûa and 240b is signillcantly Ic~ than thc ~hiclcncss of inner cellular corc 220 at arms 204 and 206 and is also gencrally Icss than in other areas af bcntin~ region 202 Any ralio Or the thi~l~n~ ss of imler cellular core 220 in arms 204 alld 2û6 to Ihc thi~ n~-ss of inner cellul~ core 220 in nccks 240a ant 240b is within the scope of thc prcsent invention; howevcr, it is prcfcrably in a range from about I, I û to about 1: 1 5, more prcferably about 1,4 to abou~ I :2 and is most prcfcrably about I :3.
As shown in Figurcs 6 ant 7, the bending radius experienced by thc extcrior skinporlion 226 is ~reatly reduced by virtuc of thc creases 230a .~nd 230b. The bentillg r ldius ED ~r~F~T, ~UG~ 98 TUE 09 46 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 180132~1707 P. 39 -- ~ ~ 7 Md~,Olgg~ ~

is ~Iso furthcr rcduccd ~q ~ result of Lhe reduced lhic~nrss of tlle inlerior skin portioll 224 at l~ndin~ region 202 compared ~o crcaset hinges in which thc int~rior skin porlion ~locs not havc reduce~l Ihickncss compLIred to the cxterior sl~in r~ortion 226. Re~lcin~ lhc bcndin~
radius ofthe hinge reduccs thc ovcrall slrain or clon~ation exl~encnccd by the ext~rior skin S ~Onion 226. The rcduccd thickness of the interior ~kin I ortion 224 at bending re~,ion 2()2, more spccifically L~t cre~es 230a and 230b, ~nh:~n~5 the ~bility of thc intcrio~ skin portion 224 to comprcss, which in tum rcduccs the slrain on thc exterior skin porlion 226 whcn thc hin~~e structure is bcnt.
In gcncral, tlle ra~lius of b~ ng of the hingc stn~cture will prelerably bc in a ra~l~c rrom about 0.005" to about 0.050", rr~orc prcfcrably in a range firom about 0.010" to abou 0.035", and most prcferably in a rangc from aout 0.015" to about 0.025".
The gcncral shape orhingo structure 10 results f~om the shape of thc mold utilizcd ~ o form hinge stluclure 10, while the thirL-nr~: of the skin results from utili7illg a mold that ~J removeS watcr more slo~ly in the area where it i9 dcsirct to l-ave a thinner skin, such as thc interior side of a hinge.
In addition to utili.7ing al least two s~b~ parallcl creases as shown in Fi~urcs4-7, a sin~le crease or s~ liti~ tFIl creases can also be utilized. A hingc having onc crcase or multiple creases dcfines ~ flexure linc or a vertex of a br~ ~inc an~le when viewing thc movcmcnt of top 214 of cr~n~in~r 20 relativc to the movement of bottom 216 of cont~ . 20. Thc location of lhe vcrtcx ~3epclt~s on the particular dcsi~,n and the num~er ol' crcases utili~.ed. Whcn multiple creases arc utilized then the IOCaliOn o~thc flcxurc linc or vertcx is rclated to t11e location of at leA~t two pivot point areas since the arms cal~ pivol at two loca~ions. Figures 6 and 7 del ict for example two pivol roint arcas 242a and 242b which arc located in each respcctive neck and arount the basc of each r~e.tive crease ~t which the anns pivot.
A hingc StrL~ctllrC formct with three creases to havc a similar desiE~n as hillgc slmcturc 200 woult have an additional swell 234 to provide a spaccr bctwccn cach crcasc and would have three pi~ot point arcas. lt is also within the scop~ of the present invcntion to fom~ a hingc structure with mL~ltiple crea~cs and without a swell between pairs of crea~L;cs by positioning the creascs in an abutting posilion.

E J, ~UG~98 ~UE 09:47 ~M WORKM~N NYDEGGER ~SEELEY F~X NO. 1~0132~1707 p, 40 31 Ip ~ A$ 1~8 - V. rO~ST-FOl~MATIOl~'rRl;'.~TMli,NTS.
A. Trc~in~ tl-c Intcrior Skin Porti-)n ~lf Hin~e Area witl~ cc~crin n~;)thor Poly-)ls to Imnrovc C~nl~ ;ihility.
'I'he interior skin prcfcrably includes softeslin~ means for enllancin~ c abilily ortllc S inlerior skin to comprcss, collapse, or buckle. An examplc of a sofl:enill~ mcans is a polyol in contact wilh the intcrior skin. Accordingly, Ihe inlerior skin porlion of Ll hin~ c is pre~rabl~ ~rcatcd with a polyol, including potyol solutions such as aqucous ~,lyccrhl. A
presently prcfcrrcd polyol is ~Iycerin due to its effcctivcncss, low cost, solubility in w3tcr, alld ease of applicallon. Neverthclcss, any other polyol thst can act lo sollen Ihe inlerior S~iill portion of thc hin~c is within the scope of the present invcntion. Othcr USCflll polyols include, but arc not limitcd to, polyethylene glycols, propylene glycol, polypropylcnc ~~1ycols, 3nt sorbitol. U~ elhylene plycol woult also bc eA[~c~t~ ~ lo work, it shoul-l not bc usccl _~ in containcrs that will come into conlact with food or ~ ,cs duc to its toxicity.
-~,J Polyols such as glycerin act to soften and plasticize the interior skin portion, or any olher treated portion, which e~lh~nççs the abilily of the intcrior skin to co.~.prcss, fold, or collapse. The softening and pl~cti~;7inE~ cffect of thc polyol t~ .C.lt iS pemlanell~ if nonvolatile polyols are used, even if the cQnt:~inrr is latcr CA~OSCd to widc variations in :lmhi~rlt rclativc humidity. }~nh~nccd cola~rcssion and collapsc of thc intcrior skin portion of the hingo makcs it morc resilient and durable such that the interior skin portion can be repeatedly collapscd or buckled and then re~A~ ded witho~t fraclure Or the interior ~kin portion.
Moreover, making a morc casily r~ psi~lc intcrior skin pOrtiOIl bcncfits thc cxtcrior skin portion by reducing the elongalion o~ the exterior skin, sincc ~ more casily collapsct intcrior skin portion results in a shor~er bending radius ror the e~terior skin l~or~ion. Tllis reduccs thc strain on the extelior skin portion, which decreases the tendellcy for frachlrc of ~he c~tenor skin porlion and increases thc lifc of thc hin~c.
Polyols ~rc gcncrally hygroscopic and function as humcctants by rcE~llatin~ thc moisb~ro content wilhin he starch aRer a starch-based article is lrealed. More specirlcally, thc polyol enables the starch-based article to absorb andJor retain a desircd amount of moisturc undcr ambient conditions depentin~ or~ the amount of polyol uscd to trcat thc a~ticle. ln ~eneral, ally polyol will enable the starch-based articlc, morc pArticularly lhc skin of lhe starch-bound ccllular matrix, to rctain morc moisture under amhient condilions tllan articles not trea~e~l wilh a polyol.

AMENDED SHEET

~UG-11-98 TUE 09:47 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 18013281707 P. 41 32 ~ - IP ~ S ~9-7~A~ 99~86 8 rOIyols also act ~o stabili7.e thc structurc of the ~t~rch-l~ound ccllular matl ix. ~ftcr a starch-boulld aliicle has bccn trealed with a polyol it will tend ~o morc rclinbly tCSi9t warpinU or othcr dimcnsional chan~cs if fulther subjec~ed ~o surfacc moisturc, SUc]l as ~lcam ~r liquid watcr. ~ùrther exposurc to surrace moislurc may rcsult fiom high relalive humi contact witll food or bcverages, or thn~ugh IlIC application of water-based coating,s.
~Vhile it is within 111~ scopc of the prescnt imention to usc 100% glyccrin or otllel polyol, the glyce~n is preferably dilLIled by water, which ~nhances the abil~ty of thc polyalcohol to r~,.ellaîc into the starch-based arliclc. In ~encral, optin~l penelralion occurs when the viscosity of the glyce~in solution is retuced ~o below about 10 cps by means of dilutin~ the glycerin with water. In ad~lilion, the water is i~m~ tely available to incrcasc tl~ mois~ure content of the slarch bound matrix. Accordingly, a prefcrred aqucous glyc--rill Cnmrositiorl compr~ses at least about 15% glycerin by wei~ht of thc aqueous sol~lion, and more prcfcrably at least about 25% 61yccrill by weighl of the aqucous solution. As lon~ as the glycerin i9 includet in an anlount of ~t least about 15%, the articlc will bc stabilizcd a~ainst thc tendency of thc water to cause w~rping of thc article.
Any coating t~ niq!~P known in the art is within the sco~e of the prcscnt invcntion ~nd may be used to apply glyecrin or other polyols lo the slareh-based artieles, particularly the illterior skin portion of the hinge. The glyeerin may be ~Fplied, for example, by spruyi or p:~intin~~ glyeerin onto the surface or dippin~ the article inlo a vat containin~ ~Iycerin.
In gencral, the arnount of glycerin applicd to the surface of the molded sLarch-bollnd artieles, partieul3r the interior skin portion of the hinge, will be within a range from about 1 x 10 ' ~/cn~2 to about 4.S x lO'l ~/cm2, more preferably in a range frorn about 1 5 x 10'4 ~tcm2 to abo~lt 2.5 x 10~ g/eml ~eeordingly, for a clam shell container used to serv~
harnbur~ers, it is presently p..:f~ ;d to apply about 0.05 X of a 50/50 mixture of g,lycenn and water to the interior s~;in portion Or the hinge sueh that it is treated with about 0.025 ~
81YCcrin net~
Glycerin is most econnmi~lly applied as a liquit at ambient conditiolls; h~wever, it can also be applied at elevated te.s~pc~ res. In one ~mboAim~nt of the prcscnt invcntion, the ~Iyce~in is applied to a starch-bascd article at a~ .u.~il,Jately the same temper~ture at which the article is forrned. It is also wi~hin the scope of the present invention to rcheat lhC
starch-based arlicles that have been for ned and allowed to cool to aunbiellt conditions. For starch-based A~ticles formed using the plcfc.led compositions and methods set forth above, pcr.~,tlution of the ~Iycerin ie op~imized whcn ~he articlc has a tel"~c,aturc in a ran~c from A,~,E~ 'FT

~UG~ 9~ TUE 09:47 ~M WOKKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P. 42 ~Cp~Jj~ 7 1~1 ~A~Y q~8 about ~0~ C to about 90~ C and when thc glyccrin is hcated to a temperat~lrc in a ran~c froln ~bout ~0~ C to about 90~ C.
In L~eneral, thc trcated articlcs arc rcady for use or may bc fi~rthcr trc~ted immc~ cly ol ~hortly ~ftcr treatment with ~lycerin. However, if aqueous solutinns includin~ hi~,hcr S conccntratiolls of waler arc used, it m~y ~e dcsirablc to subject the :~rliclc to fu~thcr drying prior to furlher trealmr~lt or use, B. ~ lic~tion of l~ ct~mcric Co~tinc~ to ~trcn~ eo thc F~terior ~kin I~Qrl;~n nf ~in~e Struct lr~.
The exterior sk~n portion of thc hin~e preferably includcs stren~thenin~ mean.s for enhancin6 the ability of thc cxterior skin to clon~,ate with rracture. An cxample of a strcDgtllening mcans is an ~ o ~ ric coatin6 on the exterior skin portion of the hinge, such as polyvinyl alcohol. Polymeric coatings provide reinforccment to reduce tho tendency of -~ the hinge to l~racturc due to strain and clon~ation of the starch-bound ccllular matrix. This -- incrc~ses the life ol the hin~e. Elastomeric co~inC~ also servo to hokl the extcrior skin portion of thc hin e togelhel if rminor fractures do actually occur ill the starch-bourld coll ul~r matrix. The e~ t"mrric CQ'~ g~ can bc appliet using any coating app~atus or mcans kno~n in the ~t.
Additionally, polymcric co~tin~S block the entry of moisture illtO the exterior skin portion, thereby provin_ structural and surface protection fi~om derormation, collapsc, or n~pture as a result of dcstructive levels of moisturc to which the hinget article ma~ bo exposcd. The ela~lu.,.e.ic coatin~ further holps to r~la~n moisturc within the starch-bound malrix in ordcr to maintain a desircd lcvcl of wnll~,ss and durabili~y such that thc hillgc docs not becom~ o~er dricd and brittle over time.
Thc cl~stomeric coatings arc prcferably water-based and ~;omprise ei~her a synthctic or natural polyrner. n~c clastomeric co~ting is preferably nontoxic if uscd in contaillcrs ~nd ~ck3~,in~ matcrials that ~.vill come into contact with food or bever3~es. Exa~nples of elastomeric coating m3tcrials within the scope of thc prcscnt invcntiou includc polyvinyl alcohol, I-olylactic acid, natural latox, and rnixlures thereof. Thc clastomeric coatin~ is prcfcrably water-solublo or a water-bornc cmulsion such that~it can be applied by means of an aqucous solution or emulsion. The ~~vater-bascd clastomcric coating matcrial may optionally include a polyol such ~c glycelin for increasct stabili7,ation of tho starch-bound matrix to which the çl~ tic coatin~ is applicd. It is also within the scope of the prescllt invention to inc!ude inor~,anic fillcrs, such as kaolin, silica fium~, calcium carbonate, or talc r.LF~

~UG~ 98 TUE 09:48 ~M WOR~MAN NYDEGGER &SEELEY F~X NO. 18013281707 P. 43 to ~lecrcRsc thc glossinr~c of tho co~ting~ If includeLI, Ille silic~ rumc prcfcrably hns 3 concentration in ~ ran~e fir~ m about 0.25 lo about 3~O by wci~ht of the coa~inL~ comro~ ioll, mor~ r~r~ler~bly in a ran~e from about 0 Sn/O to about 1 5% by wcighl For a clarn shcll container used to sctvc harnbur~ers, il is presenlly l~rcfcrrcd to llsc S ~n aqueous polyvinyl alcohol coatin~ malerial that includcs G0~/u polyvinyl ~lcohvl, 2n~/l~
I)lasLicizcr (sucll as urea), and 20% watcr such thal about 0 2 ~ to about 1 8 ~ of coating matcrials is applied to thc articlc, more ~refer21bly in R ranre from about 0,3 g to about 1 2 g, and mo~t prcrcr3bly in a range from about 0 4 g to about 0 8 g. Prcscntly, it i~ prcferrcd to usc a proprietar~ poly~inyl alcohol coaling matcrial that includts an unknown plaslici~er oblaincd from Planet I'olymer llle coating material iY prefcrably dilutcd with a~out 20%
water V~. EXAMPI,l~ THF P~E~'l;,RRF,I) F,MBODIM~I~TS.
Outlined below arc examplcs of the ~rescnt invcntion and comparative exanlF~lcs sctting fortll the results of ~A~ b involving ~ticles with a slarch-bound cellular ma~rix having a hin~e or a fle~ible region. Thc CAa~ JICg includc tcsts of dirr .~i~t physical confi~uralions as wcll as thc impact of post-fo~rn~tior ~ al~ such as glycerin ttealmcnt cf tl~e interior skh portion of the hinge or Rppl1e~tion of a polymeric coating lo the exterior skin portion of the hin~c n~le 1 A hing~ was formcd by molting a starch-bascd mixture in an aluminum two-piece mold l~lc two-piece mold includcd an al~in ~n male mold wilh a polyether ethcr kctonc molding strip colresl)onAi ~ ~ to the interior surÇace of thc hin~c stn~cturc l hc molclin~ strip hAd two 90~ "V"-shaped cxtcnsions or a "W"-sl)al~ed eYtt~niion Thc "W"-shapcd cxtcnsion w~s ~-sser ti~lly t~vo parallel ridgcs Thc all~min ~m fernale molà ha~ t-~vo small projeclions that alisnet ~ith the tips of thc "W" but dit not touch the tips when the mold wa~ closcd ~ st :~nnin~ electron micrograph image of a cross-scction of the hin~c fortncd from thc starcll-based mixture is shown in I~i~urc 8 The hinge is shown in a strai~ht position befiore bein~ foldcd The top surf~ce orthe hinge in Fig-lre 8, which is thc interior skin Or tho hinge, is forrned by thc "W"-shapet l-olyetl er ether ke~one rYtpncion~ Due lo the low he~t conductivity or hi~,h insulation propenies of the polyether e~her ketone compare~l lo Ihe 31uminum surfaccs of the mold, the interior skin portion of the hin~e is thinner thall the cxtcrior skin portion of the hin~e i~ ure 8 ~UG~ 9~ TUE 09:48 ~M WORKM~N NYDEGGER &SEELEY F~X NO, 1~0132~1707 P. 44 jp~ AY 19~8~

A her thc hin~se was formcd, tlle exterior skin of the hingc was coatcd witl~ in l~ycr of polyvinyl alcohol. A sm~ll amolmt of glycerin was al~plied ~o ~hc intcrior skin of tl~c hinge. 'l ~c hhlgc was thcn bent as shown in ~i~urc 9, Whicll iS scanning eleclron microgr~rl a~ Or a cross-scc ion of thc bcnt hinge. Figure 9 has dottcd lines roughly delineatilt~ c S scgmcnt 300 of the articlc Ihat cxpcriences the most comr~re~sion and clongation as Illc hingc is foldcd. rorlion 300 rou~hly corl~s~onds lo bcnding rcgion 202.
Thc configuration Or lhe bcnt hingc in ~i~ure 9 sho~s that the interior skin in sc~nent 300 is able to compress without substanlial fracturc ant that thc exterior skin does not rupturc as it elollg~les. Thc glyccrin ~p~ lly acLc ~s a pl~ctici7~r or soJtencr to furlher enh~nce Ihc ability of the thin interior sldn to CGlll~l~.S~ while the poly~inyl alcohol enhances thc ability of the exterior skin to ~Ic)n~e without rupt-Jre. The hingc was opcncd and closcd several times without failure, lhus d,e.~o~ .,ling that the hinge is sufficiently d~rable for repefltcd usc. Accordin~cly, thc tcst deterrnined that problems ~scoci~1e~1 with forrning a - hinL~ed starch-b3scd article in a metal mold were ove,~,c",c by varyine thc rate of heat transfcr in the mold to create a portion ofthe hin~e ha~ing a thinner skin, and then rnh~3ncins the ben~hi 1 ity of the lIinge by treaLinl; thc mtcrior skin ~nth glycerin and coating the exterior sliin with ~ pol~vinyl alcohol coating, Fxa~uple ~
A s~arch-bascd mixturc was molded in a mold formct ~om alll~in~rn with a roundcdsegmcnt made frorn 5ili~0nP rubbcr to idcntify thc result Oll skin thicklless of molding a mixture in a mold havin~ two tifferent surface m~ C. A scA~in~ clcctron micro~raph ima~e of a cross-section of thc article formet in the mold is 5hown in Figure 10 Tllc Ihickncss of thc skin 310 of the article in contact with thc al~minllm was ~ncasurcd and ~ound to be S~bout 250 ~m Thc thic~nrc~ of the skin 312 o~the a~icle in contact with the silicone ~~ 25 was mcasurcd and found to be about 10~ ~lm Thc position of thc cil jt~on~ nl~rnhcr durin~
molting is i~3~n~ifiP~1 by numeral 314 Tl-e e,~p~ ".t indic~ted that the tirr ~e, ce in tllc thcrmal conductivity of the aluminl~m and silicon~ rubbcr yields a wall ~ickncss ratio o~
about 2 5 :1.
mp~ ive F~ e l ~n cxpcriment was contucted on a strir or sheet having a s~rch-bound cellular n~atrix ~nt having an interior skin that was approxirnately as thicl; as thc cxtcrior skin to obscrvc the bentability of hinge in the sLrip a~ter thc interior skin ~~vas coated wilh glyceril-The in~crior skin and the exterior skill of tho strip hat c~ blo thi~ ~noss as the strip was AMENDED SHEET

~UG-11-98 TUE 09:48 ~M ~ORKM~N NYDEGGER &SEELEY F~X NO. IaO13281707 P. 45 ~ ~P~S 9 ~

formcd in a molt having only an aluminuln surface and without ~ny structure for formin6 ind~ntations or ~,roovcs. I he glycerin was blushed onlo thc intcrior sl~in of thc sl~rch-b~scd sLrip and allowed lo soak in for about ~n hour to enl-~n~ e the ~LbiliLy of thc intcrior skhl Or lhc to buckle.
S After the inlerior skin of ll~e strip was tleatcd w~lh ~lyccrin it was bent as sllown in Fi~urc 1 1. I i~ure I 1 is a sC:~nnin~ ~lecLron micrograph ima8e Or a cross-scction of thc bull strip. Figure 11 has dotted lincs rou~hly telin~ing the portion 320 of ~h~ ~tnp th~t experienced thc most co,np.es ,;on ant elongation as thc strip was folded, Whilc thc 61yccrin enhanced thc buckiing, it was found th~t the amount of glycentl necessary to causc sufficient buc~linL tue lo thc thi~'Ln~Cs o~the intcrior skin eventually col~ict~d with the funclionalily df the hin~c as the hinge bccame ~x~cs~i~rely 50g6y, particularly whcn microwaved.
Figurc 12 is a higher m~ifir~tion of the imagc shown in Figure 11, ~arlicul~rly thc interior skin o~ the hingc, with a whitc linc ou~ g a ro~lgh trace of the intcrior skin to hi~zhlight the excessive folding that occurred. l~i6ure 12 shows Ihat thc bc~Ain~ is not loe~ and tends to wanter, thereby eausin~ regional inoQnqiqterl~ie5 Accortin~ly, il can be concluded that the need for glyeerin can be avoidcd, or at le ~st minimi~ed, by reduein~
the thicknes~ of ~e interior skin. It can also be concl.~do~ lhat the b~ n~lin~ is not sufficiently controlled without a focal or pivot point formed by an intentation in the hin~e. Co..,p.~ ~ti~e F.xAmnle 2 An experiment wa~ conducted on a hinge in a co~lt;~ e. ~ ignPIi to have a localized bending point and having an intcrior slcin that was ~pprnYin~t~ ly a5 thick as the exterior si;in of thc hin~,e to observe the bendability of hinge after the exterior skiD was coated wilh polyvinyl alcohol Tlle localized bcndin~ point was ob~ained by rorming two parallcl indel~t~tions in the interior skin~ The in~erior skin and the exterior skin of tho hinge or~he J~ 25 container had co.,-parzlble thirl~n~s5 as the article was formed in a mold havin~ an all alllminl~ln surface. Poly~inyl alcohol was coated onto the exterior skin of the statch-bascd hin~e ure 13 is a sr~nnine electron microgr~ph imag~ of a cros~-sec~ion of Ihc hinge befiore being bent. Figure 14 is a srh~m~tic depictiol~ of the image in Figurol3 whelein tho illterior skin 224 or a portion thereof is clcarly as thick or nearly as thick as exterior skin 22G
of hinge 200. Figure 13 also shows that inner c~llular core 220 is relatively tllin at ~e nccks under bases 234a and 234b. Figure 15 is ~ sc~nning elect~on micro~raph image of a cross-scction of the l~ ge ~fter bein~ bcnt.

~v~ ED SHEEr, ~UG-Il-9~ TUE 09:49 ~M WORKM~N NYDEGGER &SEELEY F~X NO~ la013281707 P. 46 - IP~ 9~

Fi~,urc 15 shows th~t the folding was loc~ Led; howev~r the hin~e hl~l roor pcrforn1ance~ A rrRcturc 380 occurr~d in lhe exteri~r skin as shown il1 Figurc 15 ~ e rracturc most lil;ely occu~cd duc to the l~lativc thich~ess ol'th intcrior skin which yicklcd a larf~e bending ~n~le thcreby causing cxccssivc strain on the exterior skin Tl1c c~cccssivc S strain m~y also have resulled in lhe firacturc duc to the ina~ilily ol'thc cclhlhar core 220 at ~lndcr onc or bolh of lhc bascs of tlle creaces to comprcss sincc thc ccllul~r corc was rclatively thin or dcnse un~ler Ihe bases thcrcby limitin~ itS ability ~o compress~
It can b~ concludcd that a thick inlerior skin reduccs thc b~ndability of a hil1ge since it is difficult to collapse. Ad~it-nn~lly it can be concluded ~at thc ability of a hin6c to fold is e~ re~l by crcatin~ a point for locali7.ed folding whcn thc ~olting point does not form a neck that is so thin ~1d dense that thc ability of the cellu]ar core to co...prcss is impaircd.
F,Y .~PIO 3 A bcnt angle tcst was devclopcd to qu~ultify thc cffect of glycerin on thc llcxibility -~ of lhe slarch-bascd hingos. Figure 16 is a srl~rm~ti~ dia6ram of the test ~pparaluj utili~ed to l~lC~u~ ~e llexibility of starchbased hinges. The test involvcd utili7inr- a clamp 400 to hold astarch-basedstrip4120fafoamcdstarchshcet~toneend41~andthenb~ din~strip 412 around a pin 416 by the apE-lir~tion of rnoment ~t thc other cnd 418 of strip 412 by a sliding pin 420 in a circular track 422 Circular track 422 has ~raduations for meaiurernent of thc bcnding angle. The bendin~ anglo over which the strips were bent before a crack w as visually obscrvcd 011 tho tensile face or the o~lter surfacc of the hin~ed portion of cach sh iy was then manually noted.
The strips were exciscd from thc base of a two-plece Clan1 shell wntainer havinf~ ~
slarch-bound m3b:iX. The dimensions of lhc strips wcrc 15 mm x 80 mm. 'rhc strips wcrc sprayed at four levels of ~lycerin-water solu~on and allowed to equilibrate at Ihree dirlerenl rclativc humidity contitions. The strips had 0 0.3 g 0.6 ~ and 0.8 ~ of solution and wcrc col1~litioned at 15% 40% ant 80~/~ relativc humitity. Tho samplei were teslecl wilh tl~t:
coated side in con,~c.ssion which WAS the insidc surface ~LS the strips were bcnt.
l hc results of the tesl are shown ~n the tablc ~pictcd in Figurc 17. ~t was fowld ~hal the llexibility of thc strips was enh~necd by glycerin at all relative humidity levels. It was also found that 0.45 g o~ glycerin pcr part was suffcicnt to impart cxtrcmc flcxibility to thc stnps even at only 15% relative humitity con-lilicne After the strips were treated with 0 4S g Or glycerin pcr part the strips were bent to the m~ximum allowablc an&lc 135~
wilhout railure.

~UG~ 98 TUE 09:49 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P. 47 IP~jS 2IMAY 1998 Thc moistur~ content incrcasc due to tllc glyccrin was ~pparcntly not thc only faclor ~ausing an increase in the nexibilily. Alth~ugh ~he absorption of moi~ture ~t lligher rclativc In~midity lcvcls duc to ~Iycerin furthcr incl~ascd thc flcxibilily of thc strips, lhcrc w~ greaLly enhanced Ilexibility even at very low rela~ive humidity levels, Jt can therefore bc conchldcd S that thc ~lyccrin aids in improvin~ thc propcrtics of thc foarn hin~c in ways olher tllall jus by humidific~tion. The glycerin apparenlly acls as a plaslici~er or softcner by its own ri~
Additionally, the testing determined that problems ~ccoc~:lt~d with thc viscosi~y of purc ~lyccrin wcrc avoided by utili7in~ an aqueous solution comprisin~ 600/o by wci~ht of glycerin, ~s it ~as adequate for pen~tratine the pores of the skin of the starch-based hinues.
Fxaml~le 4 Thc tcst apparatus depicted in I~igure 16 was utilized to comparc the rcsult of trcating ~e inncr surface or coJ~ cssion sidc of ~ hin$~c in a strip wit'h the outer surface or tension sidc of the hinge in a strip having a starch-based matrix. Tl~e strips wcrc spraycd at diff~rcnt J levels of glycerin-waler solulion And allowed to equilibrate a~ approximately 40% relative 1 5 hum~dity.
Thc results of the tesling are shown in ~he table d~pi~le~ in Figure 18. n~e flexibility of thc strips trcatcd on the inner surface ~reatly increased aftcr bein~, trcatcd with morc than about 0.2 g of glycerm per part as thc stnps ~ere bent to the ma~ um a]lowablc an61e, 13~S~, without failurc. Ihe flcxibility was not ncarly as ~jgnific~ntly irnprovcd fior the same slnps whcn thc tcnsion sidc was trcatcd and thcn placcd in tension. The bend any,le for t~e strips tlcated on their tension sitc was only about 80~. It was also found that thc dcpcn~lencc or flcxibility on which surfacc was trcatcd was most apparenl ror lower ~Iyccrin coatin~
weighls,, Henc~, treal:ing Ihe inner sur~ace is much more ef~cctivc cvcn at lowcr lcvcrs of glycerin compared to treatillF thc outer su.~acc of thc sasnc hingc.
J 25 Ex:ltnple S
The increase in nexibility resulting fro~n coatinE~ starch-baset arlicl~s witl1 elastomeric co~ti"E~ was quantified by tcstin6 thc bcnt angle of coaled starch-bascd alticlcs wi~h the test apparatus depicled in Figure 16. Two-picce hingcd clarnshell containers wei~hinF about 20 ~rarns cach wcrc formcd in ~n alwninum mold havin6 a polycthcr c~her ketone strip and wcrc thcn coatcd with compo.si~ions rangin~ in wci6ht from ~bout 1.5 gri~rns to about 3.5 gr rns. lhe coaling~ were a rlanct Polymcr polyvinyl alcohol (PV~) forn~ ion ~hich is 1~% polyvinyl alcohol, 28% ~,lyccrin, and 5~% water. l'he coa~inL~s were ap~ l usin~ a Nordson hot melt system and a liner slide. Th~ coatinF compositions AMENDED SHEET

~UG-11-98 TUE 09:50 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P. 4~
- ~' P~ 7 1J1 ~,~,q~98 wer~ ~prlied ~t pot and gunlhoso temper3turcs of 90~C and 150~C, resl ccli~ely Oncc co~lcd, thc clamshcll containers werc Illowcd lo ~lry aL ambi~nl conditiolls for scvcral days.
StriTls werc cxciset from the base of Lhc two-~7iece clam shcll containcrs havillg a st3r~h-l ound matrix. Thc ~imrn~ions of the strips wcre 7 cm x 2 cm willl a lhickncss Or S ~bout 2.5 nun. 'l'he strips were equilibriatcd .It 3bout 30% rclative humid-y for about ~ hours in ~ h~lmidity chamber. The s(rips wcrc rcmovcd from the chamber and immedialcly bent using tlle ben~ lcsl app~tus d~pictcd in Figure 16. Two o~the strips had becn coalcd will thc ~'VA contin~ on the side placed in comprcssion, whicll was the inside surface, and two of ~hc strips had been coated with the PVA coating on thc sidc placcd in tcn~ion, which was Ihe oulside surfacc. ~'a~lure was manually noted as Ihe point at which thcre was clcar cvidence of crack forrnation.
The re~ulls of thc tcst are shown in thc t~lc dopicted ;n Figure 19. Figure 19 shows _~ the averagc bcnd angle at failuro for the ~wo pairs versus thc total amount of coatin~ applicd.
;i~urc 20 shows the same data as a function of only the ~Iyccrin content in the coating. Thc 1~ ~end 3ngle at failurc illcreased with increasing amounls of coat~ng and Ihe bcnd anglc WAS
always highcr whcn thc side coated with PVA w~s in compression. This is most likely due to thc softenin~ ant plaslic~zing cffcct of thc ~,lycerin (ant watcr) which al!ows thc material to strain under comprcssion, thereby collapsing the ma(erial on the com~ ssion si~o o~ the bend point and minimiz~ng thc rcsultant str~ss on the side in t~inn The bend an~le at 20 failurc for all ~mples tested wi~ the rVA side in cu,y~ession were higher than 55~, which was angle obser~ed for a conditioncd, llnro~tod sarnple.
From tl1e foregoing, it may bc conrlnArt3 that applyin6 an clastomcric coatin~ to lhc outer surface of the hinge is most offeclive in slreng~ening Ihe hing~. Coaling lhe inncr surrace Or the hingc had a much lcss trarnatic cffcct on hin~c durabilily and rcsilicnc~.
Vll. SUMMAl~Y.
In view of the foregoing, the present invention provides methods and systems form.~nuf:-cturjng intc~rally formcd hinE~cs within st3rch-bound ccllular matriccs.The prcsent invcntion furthcr providcs mcthods and syslems for forrnin).3 a hin~c ~ in starch-botlnd m~lrjt~,s dunng the rn~hllr~.~t~-r~ of the er~tire article such that thc arliclc fmd hinge are manuractured in a single ster.
In addition, thc present invention providos methods and systems that climinalc ll-e nccd to introducc forei~n materials such as papcr strips that nced to be insened in~o ~he mol~ing apparatus dur~ng the molding of starch-bascd cornr~ ti~n~ into the desired articlcs ED ~rlEET, ~UG-11-98 TUE 09:50 ~M WORKM~N NYDEGGER &SEELEY F~X NO. 1~013281707 P. 49 ~~P~ hi~

l llc pres~nl invenlion also providcs methods and systcms for manuract~rin~
inlegrally formcd hin6cs in starch-bound articlcs IhElt ~llow tlle articlcs lo bc opclled and closecl rcpcaledly wilhout substantial rupture of the starch-bound maLri~;.
~ccordingly, tl~c prcsellt invcntion discloscs how to increase ~llc collapsibility or S ability of the illtcrior skin porLion of Ihe hingc to buckle wilhout del ilit~tin~ rraClurc durin~
closurc of the arlicle halvcs, ant the ability of Ihe interior skin portion lo thell rc-cxtcn~l dunng opening of thc articlc halves without tebilitatin~, fract~lre.
Similarly, Llle present invcntion di~closes llow to rcducc thc strain, and incrcasc ll~c s~rength of the exterior skin pot~ion when subjcctod to tensile stress, during closure of thc articlc halvcs s~lch that the exterior skin portion does not suffcr dcbilitatin~ fracturc.
The present invention further provides mcthods and sys~ems for ~ faclllrillg a hin~: structure that in~ Rs multiplc hin~cs or hiinge portions that distribute ~he mrc]-qnical strcsscs and deformation over a wite area of the hin~e arca and result in a more durablc llin~e.
Tho present invelltion may be embodicd in other specific forms wilhouL depar~
from its spirit or essenlial cll~ ,rt- .istic~. The described embo-~im~nlc are to bc considcred in all respecls only as illustratcd and not restrictive. Ihc scope of the invcntion is, thereforc, indicaled by tlle appcndcd claims rathcr than by the fore~oinE~ dcscription. All chan~cs which comc withicl the meaning and ran6c of equivalcncy of the claims ~Lre to bc embraced within their scope -AMENDED SHEET

Claims (100)

What is claimed is:

1. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising:
molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixturec by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article, wherein the hinge structure comprises an interior skin portion, an exterior skinportion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step resulting in the interior skin portion of the hinge structure having a thickness that is less than the thickness of the exterior skin portion of the hinge structure; and demolding the article after the article has achieved form stability.

2. A method for manufacturing an article as defined in claim 1, wherein the molding step imparts less heat per unit time to the interior skin portion of the hinge structure than to the exterior skin portion of the hinge structure such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion.

3. A method for manufacturing an article as defined in claim 1, wherein the molding step is carried out using a heated mold apparatus.

4. A method for manufacturing an article as defined in claim 3, wherein the heated mold apparatus includes a molding strip corresponding to the interior skin portion of the hinge structure and having reduced heat diffusivity compared to the rest of the mold apparatus.

5. A method for manufacturing an article as defined in claim 1, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion of the hinge structure.

6. A method for manufacturing an article as defined in claim 1, wherein the molding step results in the exterior skin portion of the hinge structure having at least one bending initiation groove.

7. A method for manufacturing an article as defined in claim 1, further including the step of treating the interior skin portion of the hinge structure with a polyol.

8. A method for manufacturing an article as defined in claim 7, wherein the polyol is applied by means of an aqueous polyol solution.

9. A method for mmanufacturing an article as defined in claim 7, wherein the polyol comprises glycerin.

10. A method for manufacturing an article as defined in claim 7, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.

11. A method for manufacturing an article as defined in claim 1, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure.

12. A method for manufacturing an article as defined in claim 11, wherein the elastomeric coating comprises polyvinyl alcohol.

13. A method for manufacturing an article as defined in claim 11, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex.
derivatives of the foregoing, and mixtures of the foregoing.

14. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising:
molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article, wherein the hinge structure comprises an interior skin portion, an exterior skinportion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step imparting less heat per unit time to the interior skin portion of the hinge structure than to the exterior skin portion of the hinge structure such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.

15. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion of the hinge structure.

16. A method for manufacturing an article as defined in claim 14, wherein the molding step results in the exterior skin portion of the hinge structure having at least one bending initiation groove.

17. A method for manufacturing an article as defined in claim 14, further including the step of treating the interior skin portion of the hinge structure with a polyol.

18. A method for manufacturing an article as defined in claim 17, wherein the polyol is applied by means of an aqueous polyol solution.

19. A method for manufacturing an article as defined in claim 17, wherein the polyol comprises glycerin.

20. A method for manufacturing an article as defined in claim 17, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.

21. A method for manufacturing an article as defined in claim 14, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure.

22. A method for manufacturing an article as defined in claim 21, wherein the elastomeric coating comprises polyvinyl alcohol.

23. A method for manufacturing an article as defined in claim 21, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.

24. A method for manufacturing an article as defined in claim 14, further including the step of applying a wax-based coating material to the article.

25. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a clam shell container.

26. A method for manufacturing an article having a starch-bound cellular matrix,the method comprising:
molding an aqueous starch-based mixture within a heated mold apparatus into a desired shaped of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the heated mold forming a hinge structure within the article, wherein the hinge structure comprises an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the heated mold being configured such that it imparts less heat per unit time to the interior skin portion of the hinge structure than to the exterior skin portion of the hinge structure such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.

27. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion of the hinge structure.

28. A method for manufacturing an article as defined in claim 26, wherein the molding step results in the exterior skin portion of the hinge structure having at least one bending initiation groove.

29. A method for manufacturing an article as defined in claim 26, further including the step of treating the interior skin portion of the hinge structure with a polyol.

30. A method for manufacturing an article as defined in claim 29, wherein the polyol is applied by means of an aqueous polyol solution.

31. A method for manufacturing an article as defined in claim 29, wherein the polyol comprises glycerin.

32. A method for manufacturing an article as defined in claim 29, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.

33. A method for manufacturing an article as defined in claim 26, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure.

34. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating comprises polyvinyl alcohol.

35. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.

36. A method for manufacturing an article as defined in claim 26, further including the step of applying a wax-based coating material to the article.

37. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a clam shell container,

38. A method for manufacturing an article having a starch-bound cellular matrix,the method comprising:
molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation and thereby form the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article, the hinge structure comprising an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the interior cellular core having a density less than the densities of the interior and exterior skin portions;
and demolding the article after the article has achieved form stability.

39. A method for manufacturing an article as defined in claim 38, wherein the molding step includes forming at least one depression in the interior skin portion of the hinge structure,

40. A method for manufacturing an article as defined in claim 38, wherein the molding step results in the interior skin portion having a thickness that is less than the thickness of the exterior skin portion.

41. A method for manufacturing an article as defined in claim 38, wherein the molding step imparts less heat per unit time to the interior skin portion of the hinge structure than to the exterior skin portion of the hinge structure such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion.

42. A method for treating a starch-based article comprising the steps of:

providing a starch-based which which includes a quantity of a starch binder such that the starch-based article is dimensionally unstable when exposed to fluctuations in ambient moisture; and applying an aqueous liquid including water, a polyalcohol and a water-borne coating material to at least a portion of the starch-based article in order to treat the portion of the starch-based article.

43. An article of manufacture including a hinge structure, the hinge structure having a starch-bound cellular matrix and comprising an interior skin portion separated from an exterior skin portion by an intermediate cellular core, the interior skin portion including a crease such that the hinge structure has a reduced cross-section at the crease, the exterior skin portion having a thickness and the interior skin portion having a thickness that is less than the thickness of the exterior skin portion.

44. An article of manufacture as defined in claim 43, wherein the interior skin portion has been treated with a softening agent for imparting to the interior skin portion increased bendability or collapsibility during bending of the hinge structure.

45. An article of manufacture as defined in claim 44, wherein the softening agent comprises a polyol.

46. An article of manufacture as defined in claim 45, wherein the polyol comprises glycerin.

47. An article of manufacture as defined in claim 45, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.

48. An article of manufacture as defined in claim 43, wherein the exterior skin portion has been treated with an clastomeric coating for imparting increased resistance against fracture due to elongation of the exterior skin portion during bending of the hinge structure.

49. An article of manufacture as defined in claim 48, wherein the elastomeric coating comprises polyvinyl alcohol.

50. An article of manufacture as defined in claim 48, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing,

51. An article of manufacture as defined in claim 43, wherein the reduced cross section at the crease reduces the bending angle of the hinge such that strain on the exterior skin portion is reduced during bending of the hinge structure.

52. An article of manufacture as defined in claim 43, wherein the hinge structure further includes one or more additional creases substantially parallel to the crease to form a multiple hinge structure.

53. An article of manufacture as defined in claim 52, wherein the hinge structure further includes a swell between the crease and the one or more additional creases.

54. An article of manufacture as defined in claim 43, wherein the interior skin and the exterior skin have respective densities that are substantially similar.

55. An article of manufacture as defined in claim 43, wherein the article includes two main structural elements integrally connected to either side of the hinge structure.

56. An article of manufacture as defined in claim 43, wherein the article comprises a clam shell container.

57. An article of manufacture comprising a hinge structure having a starch-boundcellular matrix, the hinge structure including an intermediate cellular core disposed between an interior skin portion and an exterior skin portion, the hinge structure including a bending region at or near a depression in the interior skin portion, the exterior skin having a thickness at the bending region, the interior skin portion having a thickness at the bending region that is less than the thickness of the exterior skin portion at the bending region.

58. An article of manufacture as defined in claim 57, wherein the article comprises a clam shell container.

59. An article of manufacture as defined in claim 58, wherein the clam shell container further includes a coating material.

60. An article of manufacture as defined in claim 59, wherein the coating material comprises polyvinyl alcohol.

61. An article of manufacture as defined in claim 59, wherein the coating material increases the strength of the exterior skin portion of the hinge.

62. An article of manufacture defined in claim 57, wherein the interior skin portion of the hinge has been treated with a polyol.

63. An article of manufacture as defined in claim 62, wherein the polyol comprises glycerin.

64. An article of manufacture comprising a multiple hinge structure having a starch-bound cellular matrix the multiple hinge structure comprising an interior skin portion separated from an exterior skin portion by an intermediate cellular core, the multiple hinge structure also including at least two depressions that are substantially parallel to each other in the interior skin portion of the hinge structure the interior skin portion having a thickness that is less than the thickness of the exterior skin portion.

65. An article of manufacture as defined in claim 64, wherein the article comprises a clam shell container.

66. An article of manufacture as defined in claim 65, wherein the clam shell container further includes a coating material.

67. An article of manufacture as defined in claim 66, wherein the coating material comprises polyvinyl alcohol.

68. An article of manufacture as defined in claim 66, wherein the coating material increases the strength of the exterior skin portion of the hinge.

69. An article of manufacture as defined in claim 64, wherein the interior skin portion of the hinge has been treated with a polyol.

70. An article of manufacture as defined in claim 69, wherein the polyol comprises glycerin.

71. An article of manufacture having a starch-bound cellular matrix and comprising first and second halves and a hinge structure disposed between the first and second halves, the first half being connected to the hinge structure by a first arm and the second half being connected to the hinge by a second arm, the hinge structure including an interior skin portion, an exterior skin portion, an intermediate cellular core disposed between the interior skin portion between the first and second arms defining a bending region of reduced cross section, the exterior skin portion having a thickness at the bending region, the interior skin portion having a thickness at the bending region that is less than the thickness of the exterior skin portion at the bending region.

72. An article of manufacture as defined in claim 71, wherein the article comprises a clam shell container.

73. An article of manufacture as defined in claim 72, wherein the clam shell container includes an interior side that has been treated with a wax coating to render the interior side more resistant to moisture.

74. An article of manufacture as defined in claim 71, wherein the interior skin portion has been treated with a polyol.

75. An article of manufacture as defined in claim 71, wherein the exterior skin portion has been treated with an elastomeric coating.

76. An article of manufacture as defined in claim 71, wherein the elastomeric coating comprises polyvinyl alcohol.

77. An article of manufacture an integrally molded article having a starch-bound cellular matrix, the article including a first half connected to a second half by means of a hinge structure that is integrally molded with the first and second halves and which also comprises the starch-bound cellular matrix, the hinge structure providing means for pivoting the first and second halves relative to each other at the hinge structure, said hinge structure comprises an interior skin portion separated from an exterior skin portion by an intermediate cellular core, the interior skin portion having a depression such that the hinge structure has a reduced cross-section at the depression.

78. An article of manufacture as defined in claim 77, wherein the integrally molded article comprises a clam shell container.

79. An article of manufacture as defined in claim 77, wherein the exterior skin portion having a thickness and the interior skin portion having a thickness that is less than the thickness of the exterior skin portion.

80. An article of manufacture as defined in claim 79, wherein the hinge structure includes at least one bending initiation groove in the exterior skin portion.

81. An article of manufacture as defined in claim 77, wherein the interior skin portion having a plurality of depressions such that the hinge structure is a multiple hinge structure and has reduced cross-section at each of the plurality of depressions, the exterior skin portion having a thickness and the interior skin portion having a thickness that is less than the thickness of the exterior skin portion.

82. A system for manufacturing an article having a starch-bound cellular matrix,the system comprising:

a mold apparatus comprising a material having a heat diffusivity and being configured such that the mold apparatus can mold an aqueous starch-based composition into a molded article having a desired shape, said mold apparatus including means for venting water produced during molding of the aqueous starch-based composition;
heating means for heating the mold apparatus to a temperature sufficient to remove a substantial quantity of water from the aqueous starch-based composition by evaporation;
hinge forming means disposed within the mold apparatus for forming a hinge structure within the molded article such that the hinge structure includes at least one depression on an interior side of the hinge structure; and heat reducing means disposed within the hinge forming means for reducing heat transfer from the hinge forming means to the interior side of the hinge structure.

83. A system for manufacturing an article as defined in claim 82, wherein the heat reducing means causes the hinge forming means to impart less heat per unit time to the interior side of the hinge structure.

84. A system for manufacturing an article as defined in claim 82, wherein the hinge forming means comprises a material having a lower heat diffusivity compared to the heat diffusivity of the rest of the mold apparatus, the lower heat diffusivity material thereby comprising the heat reducing means.

85. A system for manufacturing an article as defined in claim 84, wherein the material having the lower heat diffusivity comprises polyether ether ketone.

86. A system for manufacturing an article as defined in claim 84, wherein the material having the lower heat diffusivity is selected from the group consisting of silicone rubber, Al2O3, glass-fiber-reinforced polytetrafluoroethylene, porcelain, and ceramics.

87. A system for manufacturing an article as defined in claim 82, wherein the hinge forming means has a thickness that is substantially lower compared to the rest of the mold apparatus such that the hinge forming means has substantially lower heat capacity per unit of surface area compared to the rest of the mold apparatus, the hinge forming means thereby comprising the heat reducing means.

88. A system for manufacturing an article as defined in claim 82, wherein the heat reducing means comprises a coating material on a surface of the hinge forming means that has a substantially lower heat diffusivity than the mold apparatus, the coating material thereby comprising the heat reducing means.

89. A system for manufacturing an article as defined in claim 88, wherein the coating material is selected from the group consisting of polytetrafluoroethylene impregnated with nickel and aluminum oxide infiltrated with polytetrafluoroethylene.

90. A system for manufacturing an article as defined in claim 82, wherein the hinge forming means is substantially thermally isolated from the rest of the mold apparatus, wherein the heat reducing means comprises means for imparting less heat to the hinge forming means comparerd to the rest of the mold apparatus.

91. A system for manufacturing an article as defined in claim 82, wherein the hinge forming means yields an article having at least two depressions in the interior side of the hinge structure.

92. A system for manufacturing an article as defined in claim 82, wherein the hinge forming means yields an article having at least one bending initiation groove.

93. A system for manufacturing an article as defined in claim 82, further including means for treating the interior surface of the hinge structure with a polyol.

94. A system for manufacturing an article as defined in claim 82, further including means for treating the interior surface of the hinge structure with an aqueous polyol solution.

95. A system for manufacturing an article as defined in claim 82, further including means for treating the interior surface of the hinge structure with glycerin.

96. A system for manufacturing an article as defined in claim 82, further including means for coating the article with an elastomeric coating.

97. A system for manufacturing an article as defined in claim 82, further including means for coating the article with polyvinyl alcohol.

98. A system for manufacturing an article as defined in claim 82, wherein the system is configured so as to yield a hinged clam shell container.

99. A system for manufacturing an article having a starch-bound cellular matrix the system comprising:
a mold apparatus a first mold half and a second mold half, the first and second mold halves comprising a melt having a heat diffusivity and being configured such the mold apparatus can mold an aqueous starch-based composition into a molded article having a desired shape and such that the mold apparatus includes means for venting water vapor produced during molding of the aqueous starch-based composition;
heating means thermally communicating with the first and second mold halves for heating the first and second mold halves to a temperature sufficient to remove a substantial quantity of water from the aqueous starch-based compositionby evaporation;
a molding strip disposed within the first mold half and having at least one substantially linear protrusions for forming a hinge structure within the molded article having at least one depression on one side of the hinge structure; and heat reducing means disposed within the molding strip for reducing heat transfer from the molding strip to the one side of the hinge structure.

100. A mold apparatus for manufacturing a hinged container having a starch-boundcellular matrix, the mold apparatus comprising;
a mold apparatus including a first mold half and a second mold half, the first and second mold halves comprising a metal having a heat diffusivity and being configured such the mold halves can mold an aqueous starch-based composition into a molded container having a desired shape and a hinge connecting two halvesof the container together and such that the mold includes means for venting water vapor produced during molting of the aqueous starch-based compositions;
heating means thermally communicating with the first and second mold halves for heating the first and second molt halves to a temperature sufficient to remove a substantial quantity of water from the aqueous starch-based compositionby evaporation; and a molding strip disposed within the first mold half and having at least two substantially linear and substantially parallel protrusions for forming a hinge structure within the molded container having at least two substantially parallel depressions on one side of the hinge structure, the molding strip comprising a material that has a heat diffusivity that is substantially lower than the heat diffusivity of the first and second mold halves.