CA2256668A1 - Elastomers and process for their manufacture - Google Patents
Elastomers and process for their manufactureInfo
- Publication number
- CA2256668A1 CA2256668A1 CA002256668A CA2256668A CA2256668A1 CA 2256668 A1 CA2256668 A1 CA 2256668A1 CA 002256668 A CA002256668 A CA 002256668A CA 2256668 A CA2256668 A CA 2256668A CA 2256668 A1 CA2256668 A1 CA 2256668A1
- Authority
- CA
- Canada
- Prior art keywords
- solvent
- recovery operation
- solvent recovery
- olefin
- anhydrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
Abstract
A process for polymerizing ethylene .alpha.-olefin and optionally diene monomers is disclosed. The process comprises the steps of contacting: (1) ethylene, (2) at least one C3-C20 aliphatic .alpha.-olefin, (3) optionally, at least one C4-C20 diene, (4) a catalyst, the catalyst comprising (a) a metallocene complex, and (b) an activator, and (5) a solvent.
The process can be conducted in a single or multiple reactors, and if in multiple reactors, then the reactors can be configured in series or parallel. Solvent is removed from the polymer stream in an anhydrous, first stage solvent recovery operation such that the solids concentration of the product stream is increased by at least 100 percent.
Additional solvent is removed in an anhydrous, second stage solvent recovery operation from the product of the first stage solvent recovery operation such that the solids concentration of the product stream is in excess of 65 weight percent.
The process can be conducted in a single or multiple reactors, and if in multiple reactors, then the reactors can be configured in series or parallel. Solvent is removed from the polymer stream in an anhydrous, first stage solvent recovery operation such that the solids concentration of the product stream is increased by at least 100 percent.
Additional solvent is removed in an anhydrous, second stage solvent recovery operation from the product of the first stage solvent recovery operation such that the solids concentration of the product stream is in excess of 65 weight percent.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/679,538 US6545088B1 (en) | 1991-12-30 | 1996-07-12 | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
US08/679,538 | 1996-07-12 | ||
PCT/US1997/012294 WO1998002471A1 (en) | 1996-07-12 | 1997-07-09 | Elastomers and process for their manufacture |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2256668A1 true CA2256668A1 (en) | 1998-01-22 |
CA2256668C CA2256668C (en) | 2006-08-22 |
Family
ID=24727319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002256668A Expired - Lifetime CA2256668C (en) | 1996-07-12 | 1997-07-09 | Elastomers and process for their manufacture |
Country Status (19)
Country | Link |
---|---|
US (1) | US6545088B1 (en) |
EP (1) | EP0910593B1 (en) |
JP (1) | JP2000514857A (en) |
KR (1) | KR100496101B1 (en) |
CN (1) | CN1098289C (en) |
AT (1) | ATE200680T1 (en) |
AU (1) | AU718342B2 (en) |
BR (1) | BR9710347A (en) |
CA (1) | CA2256668C (en) |
CZ (1) | CZ9499A3 (en) |
DE (1) | DE69704617T2 (en) |
ES (1) | ES2156001T3 (en) |
HU (1) | HUP9904354A3 (en) |
NO (1) | NO990095L (en) |
NZ (1) | NZ332880A (en) |
PL (1) | PL331038A1 (en) |
TR (1) | TR199900050T2 (en) |
TW (1) | TW341576B (en) |
WO (1) | WO1998002471A1 (en) |
Families Citing this family (180)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6319998B1 (en) * | 1998-03-04 | 2001-11-20 | Exxon Mobil Chemical Patents Inc. | Method for making polymer blends by using series reactors |
WO1999045062A1 (en) | 1998-03-04 | 1999-09-10 | Exxon Chemical Patents Inc. | Product and method for making polyolefin polymer dispersions |
JP4275857B2 (en) | 1998-03-04 | 2009-06-10 | エクソンモービル・ケミカル・パテンツ・インク | Method for enhancing diene conversion in EPDM type polymerization |
ATE495205T1 (en) * | 1998-11-02 | 2011-01-15 | Dow Global Technologies Inc | SHEER-FLUFFILIZABLE ETHYLENE/ALPHA-OLEFIN/DIENE POLYMERS AND THEIR PRODUCTION |
US6369176B1 (en) * | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
JP4566305B2 (en) * | 1999-08-31 | 2010-10-20 | 日本ポリプロ株式会社 | Method for purifying a solvent containing a component derived from a metallocene compound |
EP2267042B1 (en) | 2000-01-26 | 2015-06-10 | Mitsui Chemicals, Inc. | Olefin diblock copolymer of very low polydispersity and process for preparing the same |
KR100769774B1 (en) | 2000-10-25 | 2007-10-23 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Processes and apparatus for continuous solution polymerization |
MXPA03004960A (en) | 2000-12-04 | 2004-04-02 | Exxonmobil Chem Patents Inc | Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions. |
BR0116317A (en) * | 2000-12-20 | 2005-04-05 | Exxonmobil Chem Patents Inc | Olefin polymerization process to produce branched polymer compositions |
SG120869A1 (en) * | 2001-05-31 | 2006-04-26 | Mitsui Chemicals Inc | Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition |
US7022766B2 (en) | 2001-05-31 | 2006-04-04 | Mitsui Chemicals, Inc. | Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition |
AU2002347954A1 (en) | 2001-12-12 | 2003-06-23 | Exxonmobil Chemical Patents Inc. | Compositions suitable for elastomeric membranes |
AU2003216210A1 (en) | 2002-02-08 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Multimodal ethylene, alpha-olefin and diene polymers, processes for making and devices comprising such compositions |
EP1519967B2 (en) | 2002-06-19 | 2013-08-21 | ExxonMobil Chemical Patents Inc. | Method for the polymerisation of ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene and polymers made using such processes |
KR101113341B1 (en) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US20050176890A1 (en) * | 2003-01-23 | 2005-08-11 | Sadahiko Matsuura | Process for producing ethylene /alpha-olefin/unconjugated polyene copolymer, and ethylene/alpha-olefin/unconjugated polyene copolymer |
AU2004247669B2 (en) * | 2003-06-10 | 2010-03-25 | Dow Global Technologies Llc | Film layers made from ethylene polymer blends |
DE602004010412T2 (en) * | 2003-08-19 | 2008-10-16 | Dow Global Technologies, Inc., Midland | MIXING POLYMERISATES AS MELTING ADHESIVE AND METHOD FOR THE PRODUCTION THEREOF |
US7084319B2 (en) | 2003-12-05 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Catalyst fluidization in oxygenate to olefin reaction systems |
EP1727840B1 (en) | 2004-03-17 | 2012-10-24 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
AR048817A1 (en) | 2004-03-17 | 2006-05-31 | Dow Global Technologies Inc | CATALYST COMPOSITION THAT INCLUDES LINK AGENT FOR THE FORMATION OF COPOLYMERS OF MULTIPLE ETHYLENE BLOCKS |
RU2375381C2 (en) | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Catalyst composition, containing shuttle agent, for formation of multi-block-copolymer of higher olefin |
GB0420396D0 (en) | 2004-09-14 | 2004-10-13 | Bp Chem Int Ltd | Polyolefins |
US7947786B2 (en) * | 2004-10-13 | 2011-05-24 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
KR100586922B1 (en) | 2004-11-18 | 2006-06-08 | 금호폴리켐 주식회사 | Preparation Method of EPDM Elastomer and Method of Controlling Productivity of The EPDM |
CA2590871A1 (en) | 2004-12-21 | 2006-06-29 | Dow Global Technologies Inc. | Polypropylene-based adhesive compositions |
EP1674490A1 (en) * | 2004-12-23 | 2006-06-28 | Borealis Technology Oy | Copolymer |
ES2432751T3 (en) * | 2005-01-31 | 2013-12-05 | Exxonmobil Chemical Patents Inc. | Mixtures and globules of polymers, and methods to produce them |
ZA200707871B (en) | 2005-03-17 | 2009-09-30 | Dow Global Technologies Inc | Rheology modification of interpolymers of ethylene/alphaolefins and articles made therefrom |
RU2007138504A (en) * | 2005-03-17 | 2009-04-27 | Дау Глобал Текнолоджиз Инк. (Us) | CATALYST COMPOSITION CONTAINING A SHUTTLE KINETIC TRANSFER AGENT INTENDED FOR OBTAINING A REGIONAL REGULAR MULTI-BLOCK COPOLYMER |
EP3424966B1 (en) | 2005-03-17 | 2020-05-27 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
US7585917B2 (en) | 2005-06-13 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic blend compositions |
KR20080055838A (en) * | 2005-09-15 | 2008-06-19 | 다우 글로벌 테크놀로지스 인크. | Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent |
BRPI0617042B1 (en) | 2005-09-15 | 2018-05-15 | Dow Global Technologies Inc. | PROCESS FOR PREPARING A RAMIFIED POLYMER, PROCESS FOR PREPARING A MULTI-RAMIFIED BLOCK PSEUDO AND RAMIFIED BLOCK POLYMER |
KR101258102B1 (en) * | 2006-03-30 | 2013-04-25 | 토탈 리서치 앤드 테크놀로지 펠루이 | Slurry polymerisation process of ethylene in the presence of low amount of scavenger |
EP2004776A1 (en) | 2006-03-31 | 2008-12-24 | ExxonMobil Chemical Patents Inc. | Product recovery in gas-solids reactors |
US7744746B2 (en) | 2006-03-31 | 2010-06-29 | Exxonmobil Research And Engineering Company | FCC catalyst stripper configuration |
WO2007146875A2 (en) | 2006-06-15 | 2007-12-21 | Dow Global Technologies Inc. | Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same |
US8785531B2 (en) * | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
EP2066744B1 (en) * | 2006-09-11 | 2018-07-11 | Dow Global Technologies LLC | Polyolefin dispersion technology used for resin coated sand |
US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
EP2109641B1 (en) * | 2007-01-17 | 2017-03-01 | AgroFresh Inc. | Delivery of ethylene blocking and/or promoting agents |
EP2170970B1 (en) | 2007-07-16 | 2014-09-03 | Dow Global Technologies LLC | Functionalized polymers and articles prepared therefrom |
US8431096B2 (en) | 2007-08-27 | 2013-04-30 | Nova Chemicals (International) S.A | Process for high temperature solution polymerization |
CA2598957C (en) | 2007-08-27 | 2014-07-15 | Nova Chemicals Corporation | Process for high temperature solution polymerization |
CA2598960C (en) | 2007-08-27 | 2015-04-07 | Nova Chemicals Corporation | High temperature process for solution polymerization |
BRPI0816027B1 (en) * | 2007-09-24 | 2019-05-28 | Dow Global Technologies Inc. | SYNTHETIC LAWN SURFACE |
JP2011501764A (en) * | 2007-09-28 | 2011-01-13 | ダウ グローバル テクノロジーズ インコーポレイティド | Dispersion of high crystallinity olefins |
CN102084053A (en) * | 2007-10-25 | 2011-06-01 | 陶氏环球技术公司 | Polyolefin dispersion technology used for porous substrates |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2231755B1 (en) * | 2007-12-28 | 2011-06-15 | Dow Global Technologies LLC | Pe-based crosslinked elastomeric foam with high filler loadings for making shockpads and articles used in footwear and flooring applications |
FR2934599B1 (en) * | 2008-07-29 | 2012-12-21 | Arkema France | MANUFACTURE OF POLYETHYLENE FROM RENEWABLE MATERIALS, POLYETHYLENE OBTAINED AND USES |
DE102008039218A1 (en) | 2008-08-22 | 2010-02-25 | Woco Industrietechnik Gmbh | Vulcanizable rubber compounds and elastomer molded parts obtainable from these rubber compounds |
JP2012503682A (en) * | 2008-09-23 | 2012-02-09 | ダウ グローバル テクノロジーズ エルエルシー | Radical functionalized olefinic polymers and methods with reduced molecular weight changes |
US8969481B2 (en) | 2008-12-18 | 2015-03-03 | Exxonmobil Chemical Patent Inc. | Peroxide cured TPV |
EP2414410B1 (en) | 2009-03-31 | 2016-03-23 | Dow Global Technologies LLC | Film made from heterogeneous ethylene/alpha-olefin interpolymer |
US20100311927A1 (en) | 2009-06-05 | 2010-12-09 | Dow Global Technologies Inc. | Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene |
US8722817B2 (en) * | 2009-06-05 | 2014-05-13 | Dow Global Technologies Llc | Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene |
SG10201403765WA (en) | 2009-07-01 | 2014-09-26 | Dow Global Technologies Llc | Ethylenic Polymer And Its Use |
US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US8629214B2 (en) | 2009-07-01 | 2014-01-14 | Dow Global Technologies Llc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US8173232B2 (en) | 2009-07-01 | 2012-05-08 | Dow Global Technologies Llc | Stretch hood films |
WO2011002998A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
US8389086B2 (en) | 2009-07-01 | 2013-03-05 | Dow Global Technologies Llc | Composition for stretch hood, method of producing the same, and articles made therefrom |
WO2011109563A2 (en) | 2010-03-02 | 2011-09-09 | Dow Global Technologies Llc | Ethylene-based polymer compositions |
KR101262305B1 (en) | 2009-07-01 | 2013-05-08 | 주식회사 엘지화학 | Process for preparation of elastomeric polymer using transition catalyst |
EP2454318B1 (en) * | 2009-07-15 | 2014-06-25 | Dow Global Technologies LLC | Polymer compositions, methods of making the same, and articles prepared from the same |
ES2858349T3 (en) | 2009-07-29 | 2021-09-30 | Dow Global Technologies Llc | Multi-headed chain transport agents and their use for the preparation of block copolymers |
CN102597029B (en) | 2009-09-14 | 2014-09-17 | 陶氏环球技术有限责任公司 | Polymers comprising units derived from ethylene and poly(alkoxide) |
US8987385B2 (en) | 2009-09-14 | 2015-03-24 | Dow Global Technologies Llc | Interconnected copolymers of ethylene in combination with one other polyalkene |
JP5764561B2 (en) | 2009-09-14 | 2015-08-19 | ダウ グローバル テクノロジーズ エルエルシー | Polymers containing units derived from ethylene and siloxane |
US9546446B2 (en) | 2009-10-23 | 2017-01-17 | Toyo Boseki Kabushiki Kaisha | Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove |
CN101734996B (en) * | 2009-12-29 | 2012-12-19 | 岳阳昌德化工实业有限公司 | Method for recycling and utilizing waste liquor containing 4-vinyl cyclohexene |
US20110172354A1 (en) * | 2010-01-04 | 2011-07-14 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use in fiber applications |
US8653196B2 (en) | 2010-01-11 | 2014-02-18 | Dow Global Technologies, Llc | Method for preparing polyethylene with high melt strength |
US8562915B2 (en) | 2010-01-14 | 2013-10-22 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
WO2011087731A1 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
JP5602249B2 (en) | 2010-01-14 | 2014-10-08 | エクソンモービル・ケミカル・パテンツ・インク | Method and apparatus for continuous solution polymerization |
CA2788086A1 (en) | 2010-01-14 | 2011-07-21 | List Holding Ag | A vacuum devolatilizer |
JP2013528950A (en) | 2010-06-04 | 2013-07-11 | ダウ グローバル テクノロジーズ エルエルシー | Electronic device module comprising homogeneous polyolefin copolymer and adhesion-enhanced graft polymer membrane |
US20130233383A1 (en) | 2010-06-04 | 2013-09-12 | John A. Naumovitz | Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Grafted Silane |
EP2580279B1 (en) | 2010-06-14 | 2019-01-09 | Dow Global Technologies LLC | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
WO2011163025A1 (en) | 2010-06-24 | 2011-12-29 | Dow Global Technologies Llc | Electronic device module comprising heterogeneous polyolefin copolymer and optionally silane |
WO2012024005A2 (en) | 2010-07-09 | 2012-02-23 | Luna Innovations Incorporated | Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates |
US8907034B2 (en) | 2010-09-30 | 2014-12-09 | Dow Global Technologies Llc | Comb architecture olefin block copolymers |
JP5980219B2 (en) | 2010-10-29 | 2016-08-31 | ダウ グローバル テクノロジーズ エルエルシー | Ethylene-based polymer and method thereof |
US20120116034A1 (en) * | 2010-11-08 | 2012-05-10 | Dow Global Technologies, Inc. | Solution polymerization process and procatalyst carrier systems useful therein |
US8877880B2 (en) | 2010-11-17 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Method for controlling polyolefin properties |
CN103339186B (en) | 2010-12-03 | 2016-03-30 | 陶氏环球技术有限责任公司 | Prepare the method based on the polymer composition of ethene |
CA2724943A1 (en) | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
BR112013014809B1 (en) | 2010-12-17 | 2020-10-27 | Dow Global Technologies Llc. | ethylene-based polymer, composition and article |
US10072146B2 (en) | 2010-12-30 | 2018-09-11 | Dow Global Technologies Llc | Compositions, methods of making the same, and articles prepared from the same |
KR102214228B1 (en) | 2011-06-30 | 2021-02-09 | 다우 글로벌 테크놀로지스 엘엘씨 | Multilayered polyolefin-based films having a layer comprising a crystalline block copolymer composite or a block copolymer composite resin |
ES2659153T3 (en) | 2011-07-05 | 2018-03-14 | Dow Global Technologies Llc | Ethylene-based polymers and processes to obtain them |
US20150165652A1 (en) * | 2011-09-14 | 2015-06-18 | Materia, Inc. | Electrolytic cell covers comprising a resin composition polymerized with a group 8 olefin metathesis catalyst |
WO2013048689A2 (en) | 2011-09-30 | 2013-04-04 | Dow Global Technologies Llc | Controlled peel laminate adhesive films |
JP6189325B2 (en) | 2011-12-20 | 2017-08-30 | ダウ グローバル テクノロジーズ エルエルシー | Ethylene / alphaolefin / nonconjugated polyene copolymer and method for forming the same |
MX360854B (en) | 2011-12-22 | 2018-11-20 | Dow Global Technologies Llc | Ethylene-based polymers with improved melt strength and processes for the same. |
US8552117B1 (en) | 2012-06-13 | 2013-10-08 | Teknor Apex Company | Sealing elements and sealing element compositions |
KR102082623B1 (en) | 2012-06-29 | 2020-02-27 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/nonconjugated polyene based compositions for thermoplastic vulcanizates |
EP2885326B1 (en) | 2012-08-16 | 2019-11-27 | ExxonMobil Chemical Patents Inc. | Highly branched compositions and processes for the production thereof |
US8796408B2 (en) * | 2012-08-31 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Plants and processes for forming polymers |
BR112015006803A2 (en) | 2012-09-28 | 2017-07-04 | Dow Global Technologies Llc | composition comprising an ethylene-based polymer and article |
EP2900704B1 (en) | 2012-09-28 | 2020-07-29 | Dow Global Technologies LLC | Ethylene-based polymers and processes to make the same |
KR101391692B1 (en) | 2012-11-14 | 2014-05-07 | 주식회사 엘지화학 | Elastic terpolymer and preparation method thereof |
EP2925797B1 (en) | 2012-11-30 | 2019-01-09 | Dow Global Technologies LLC | Ethylene/alpha-olefin/nonconjugated polyene based compositions and foams formed from the same |
WO2014084893A1 (en) | 2012-11-30 | 2014-06-05 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
ES2719257T3 (en) | 2012-12-28 | 2019-07-09 | Dow Global Technologies Llc | Ethylene-based polymers and processes for preparing them |
KR20140144076A (en) | 2013-06-10 | 2014-12-18 | 주식회사 엘지화학 | Preparation method of elastic terpolymer |
EP2883890A4 (en) | 2013-06-28 | 2016-07-20 | Lg Chemical Ltd | Trinary elastic copolymer comprising diene and method for preparing same |
CN104797610A (en) | 2013-06-28 | 2015-07-22 | 株式会社Lg化学 | Trinary elastic copolymer comprising diene and method for preparing same |
KR101585206B1 (en) | 2013-07-22 | 2016-01-13 | 주식회사 엘지화학 | Elastic diene terpolymer and preparation method thereof |
KR101585204B1 (en) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | Elastic diene terpolymer and preparation method thereof |
IN2015DN02232A (en) | 2013-06-28 | 2015-08-21 | Lg Chemical Ltd | |
US9944733B2 (en) | 2013-12-26 | 2018-04-17 | Dow Global Technologies Llc | Ethylene-based polymers formed using asymmetrical polyenes |
JP6542774B2 (en) | 2013-12-26 | 2019-07-10 | ダウ グローバル テクノロジーズ エルエルシー | Method for forming ethylene-based polymers using asymmetric polyenes |
JP6609254B2 (en) | 2013-12-26 | 2019-11-20 | ダウ グローバル テクノロジーズ エルエルシー | Method for improving reactor stability for the preparation of ethylene-based polymers using asymmetric polyenes |
WO2015142547A1 (en) * | 2014-03-21 | 2015-09-24 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
KR101655392B1 (en) | 2014-04-21 | 2016-09-07 | 주식회사 엘지화학 | Elastic diene terpolymer and preparation method thereof |
KR101660480B1 (en) | 2014-04-25 | 2016-09-27 | 주식회사 엘지화학 | Elastic diene terpolymer and preparation method thereof |
US20170200842A1 (en) | 2014-06-24 | 2017-07-13 | Dow Global Technologies Llc | Photovoltaic Modules Comprising Organoclay |
KR102396054B1 (en) | 2014-06-24 | 2022-05-10 | 다우 글로벌 테크놀로지스 엘엘씨 | Polyolefin photovoltaic backsheet comprising a stabilized polypropylene layer |
US20170152377A1 (en) | 2014-06-26 | 2017-06-01 | Dow Global Technologies Llc | Breathable films and articles incorporating same |
WO2015200426A1 (en) | 2014-06-27 | 2015-12-30 | Dow Global Technologies Llc | Ethylene-based polymers comprising units derived from carbon monoxide and a rheology modifying agent |
CN106470831B (en) | 2014-06-30 | 2020-04-14 | 陶氏环球技术有限责任公司 | Strip-shaped multilayer film |
ES2768760T3 (en) | 2014-12-01 | 2020-06-23 | Dow Global Technologies Llc | Polymeric compositions, shrink films and methods of preparing the same |
EP3237467A1 (en) | 2014-12-23 | 2017-11-01 | Dow Global Technologies LLC | Ethylene-based interpolymers and composition comprising the same |
US10370471B2 (en) | 2014-12-29 | 2019-08-06 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
EP3240808B1 (en) | 2014-12-29 | 2020-05-13 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin interpolymers |
SG11201705241QA (en) | 2014-12-30 | 2017-07-28 | Dow Global Technologies Llc | Process to control output and quality of ethylene-based polymer formed by high pressure free radical polymerization |
SG11201707846QA (en) | 2015-03-31 | 2017-10-30 | Dow Global Technologies Llc | Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching |
WO2016176821A1 (en) * | 2015-05-05 | 2016-11-10 | Dow Global Technologies Llc | Functionalized, halogenated olefin-based adhesive, articles containing and process for using thereof |
FR3037586A1 (en) | 2015-06-17 | 2016-12-23 | Michelin & Cie | PROCESS FOR CONTINUOUS POLYMERIZATION OF DIENE ELASTOMER |
WO2016204949A1 (en) | 2015-06-17 | 2016-12-22 | Dow Global Technologies Llc | Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent |
US10647789B2 (en) | 2015-06-22 | 2020-05-12 | Dow Global Technologies Llc | Process for making ethylene-based polymers using carbon-carbon free radical initiators |
EP3313905B1 (en) | 2015-06-24 | 2020-05-20 | Dow Global Technologies LLC | Processes to prepare ethylene-based polymers with improved melt-strength |
US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
US10490319B2 (en) | 2015-09-02 | 2019-11-26 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
JP6804519B6 (en) | 2015-09-02 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | Flexible cross-linked cable insulators, and methods for making flexible cross-linked cable insulators. |
WO2017048448A1 (en) | 2015-09-14 | 2017-03-23 | Exxonmobil Chemical Patents Inc. | Process for making branched epdm and epdm therefrom |
CN108137876B (en) | 2015-10-29 | 2021-01-08 | 陶氏环球技术有限责任公司 | Crosslinkable polymer composition for flexible crosslinked cable insulation and process for producing flexible crosslinked cable insulation |
EP3168239A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure free radical polymerizations |
EP3168237A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
EP3168238A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | Ethylene-based polymers formed by high pressure free radical polymerizations |
AU2016383056B2 (en) | 2015-12-29 | 2020-11-19 | Dow Global Technologies Llc | Highly grafted ethylene-based polymers, highly grafted ethylene-based polymer compositions, and processes for forming the same |
EP3420026A1 (en) | 2016-02-23 | 2019-01-02 | Dow Global Technologies LLC | Ethylene-based polymers and processes to make the same |
US10815375B2 (en) | 2016-04-29 | 2020-10-27 | Dow Global Technologies Llc | Compositions comprising ethylene-carbon monoxide copolymers |
WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
WO2017206008A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
CN107474194B (en) * | 2016-06-08 | 2022-03-18 | 中国石油化工股份有限公司 | Method for preparing high molecular polymer material |
EP3478732B1 (en) | 2016-06-30 | 2023-01-11 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
CN109563326A (en) | 2016-06-30 | 2019-04-02 | 陶氏环球技术有限责任公司 | Based on ethylene/alpha-olefin/polyenoid composition |
WO2018111638A1 (en) | 2016-12-16 | 2018-06-21 | Dow Global Technologies Llc | Ethylene/ alpha-olefin interpolymer compositions |
ES2893526T3 (en) | 2017-02-28 | 2022-02-09 | Dow Global Technologies Llc | Ethylene-based polymers with good processability for use in multilayer films |
US11084893B2 (en) | 2017-06-02 | 2021-08-10 | Dow Global Technologies Llc | Ethylene-based polymers and processes for the same |
CN111148641B (en) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | ethylene/C5-C10 alpha-olefin/polyene interpolymers |
KR20200068729A (en) | 2017-10-31 | 2020-06-15 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/CO interpolymer and method for manufacturing same |
EP3480220A1 (en) * | 2017-11-06 | 2019-05-08 | Borealis AG | Combined sequential parallel reactor configuration |
KR101918484B1 (en) | 2017-11-15 | 2019-01-31 | 금호폴리켐 주식회사 | Catalyst compositions for preparing elastomeric copolymers and preparation method for elastomeric copolymers containing ethylene and α-olefin, or ethylene, α-olefin and non-conjugated diene using the same |
US11041034B2 (en) | 2018-02-09 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Ethylene-a-olefin-diene elastomers and methods of making them |
KR102520418B1 (en) | 2018-02-14 | 2023-04-11 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin interpolymer composition with improved sustained high temperature resistance |
BR112020016322A2 (en) | 2018-02-14 | 2020-12-15 | Dow Global Technologies Llc | ETHYLENE /? LFA-OLEFINE INTERPOLYMER COMPOSITIONS WITH GREATER RESISTANCE TO CONTINUOUS HIGH TEMPERATURE |
EP3752560A4 (en) | 2018-02-14 | 2021-08-25 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
WO2019241475A1 (en) | 2018-06-15 | 2019-12-19 | Dow Global Technologies Llc | Bimodal ethylene-based polymers having high molecular weight high density fractions |
BR112020025506B1 (en) | 2018-06-15 | 2024-01-23 | Dow Global Technologies Llc | BIMODAL ETHYLENE-BASED POLYMER PRODUCTION METHOD |
US11926684B2 (en) | 2018-06-15 | 2024-03-12 | Dow Global Technologies Llc | Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions |
JP7419269B2 (en) | 2018-06-15 | 2024-01-22 | ダウ グローバル テクノロジーズ エルエルシー | Blown films containing bimodal ethylene-based polymers with high molecular weight high-density fractions |
WO2020006104A1 (en) | 2018-06-28 | 2020-01-02 | Dow Global Technologies Llc | Ethylene-based polymers with improved melt strength and thermal stability |
KR20210121029A (en) | 2018-12-28 | 2021-10-07 | 다우 글로벌 테크놀로지스 엘엘씨 | Curable composition comprising telechelic polyolefin |
EP4234594A1 (en) | 2018-12-28 | 2023-08-30 | Dow Global Technologies LLC | Curable compositions comprising unsaturated polyolefins |
SG11202107051UA (en) | 2018-12-28 | 2021-07-29 | Dow Global Technologies Llc | Telechelic polyolefins and processes for preparing the same |
SG11202107057WA (en) | 2018-12-28 | 2021-07-29 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
WO2020243426A1 (en) | 2019-05-31 | 2020-12-03 | Dow Global Technologies Llc | Low density polyethylene with improved processability |
KR20220066928A (en) | 2019-09-24 | 2022-05-24 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/polyene interpolymer composition |
WO2021061580A1 (en) | 2019-09-24 | 2021-04-01 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
WO2021206941A1 (en) | 2020-04-06 | 2021-10-14 | Dow Global Technologies Llc | Enhanced melt strength low-density polyethylene for use in films or blends |
US20230331966A1 (en) | 2020-10-14 | 2023-10-19 | Dow Global Technologies Llc | Polyethylene compositions suitable for use in cast stretch films |
Family Cites Families (84)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
US4200722A (en) | 1971-09-24 | 1980-04-29 | Stamicarbon, B.V. | Rubber-like copolymers of ethylene, at least one other α-alkene and one or more polyenes possessing increased building tack |
US4184027A (en) | 1971-10-26 | 1980-01-15 | Monsanto Company | Recycle control system for continuous polymerization |
US4102761A (en) | 1974-01-03 | 1978-07-25 | The Firestone Tire & Rubber Company | Radiation cure of synthetic rubbers |
JPS5111882A (en) | 1974-07-20 | 1976-01-30 | Sumitomo Chemical Co | Mihannotanryotaio jokyosuruhoho |
FR2297713A1 (en) | 1975-01-17 | 1976-08-13 | Telecommunications Sa | INTRODUCTION PROCEDURE |
FR2322883A1 (en) | 1975-09-02 | 1977-04-01 | Michelin & Cie | ELASTOMERS OF THE E P T TYPE, AND ARTICLES CONTAINING SUCH ELASTOMERS |
JPS52141888A (en) | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
US4075287A (en) | 1976-10-27 | 1978-02-21 | Phillips Petroleum Company | Separation process |
DE2735355A1 (en) | 1977-08-05 | 1979-02-15 | Basf Ag | PROCESS FOR PREPARING HOMOPOLYMERIZED AND COPOLYMERIZED PRODUCTS OF ETHYLENE |
US4182810A (en) | 1978-04-21 | 1980-01-08 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
JPS5948046B2 (en) | 1978-08-17 | 1984-11-24 | 三井化学株式会社 | Ethylene copolymer rubber |
US4340563A (en) | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
JPS587402A (en) | 1981-07-07 | 1983-01-17 | Mitsui Petrochem Ind Ltd | Polymerization process |
US4792595A (en) | 1983-06-15 | 1988-12-20 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
US4722971A (en) | 1985-08-02 | 1988-02-02 | Exxon Chemical Patents Inc. | Easy processing ethylene propylene elastomers |
US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5084534A (en) | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
EP0275925B1 (en) | 1987-01-19 | 1995-04-05 | Sumitomo Chemical Company, Limited | Rubbery copolymers of ethylene, propylene and a nonconjugated polyene and their use |
US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5096867A (en) | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5264405A (en) | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
US4804794A (en) | 1987-07-13 | 1989-02-14 | Exxon Chemical Patents Inc. | Viscosity modifier polymers |
JP2573613B2 (en) | 1987-08-14 | 1997-01-22 | 三菱化学株式会社 | Ethylene polymerization method |
US5147949A (en) | 1988-03-29 | 1992-09-15 | Exxon Chemical Patents Inc. | Polymerization process using a silica gel supported metallocene-alumoxane catalyst |
US5231106A (en) | 1988-05-18 | 1993-07-27 | Novo Nordisk A/S | Azacyclic carboxylic acid derivatives and their preparation and use |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
CA1327673C (en) | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
US5229022A (en) | 1988-08-01 | 1993-07-20 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920) |
CA2034759C (en) | 1988-08-01 | 2003-06-03 | Won R. Song | Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives |
WO1990003414A1 (en) * | 1988-09-30 | 1990-04-05 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
US5017665A (en) | 1989-07-25 | 1991-05-21 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin and 1,4-diolefin copolymerization |
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
JP2807502B2 (en) | 1989-10-05 | 1998-10-08 | 三井化学株式会社 | Ethylene-propylene-diene rubber, elastomer composition and vulcanized rubber thereof |
FR2654108B1 (en) | 1989-11-08 | 1993-08-20 | Norsolor Sa | NOVEL POLYOLEFIN RUBBERS AND THEIR PREPARATION METHOD. |
US5519091A (en) | 1990-02-13 | 1996-05-21 | Mitsui Petrochemical Industries, Ltd. | Method for the preparation of ethylene polymer compositions |
US5149318A (en) | 1990-03-14 | 1992-09-22 | Minnesota Mining And Manufacturing Company | Quick-changeover blood handling apparatus |
MY107639A (en) | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
JP2545006B2 (en) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | Addition polymerization catalyst |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
CA2060019A1 (en) | 1991-03-04 | 1992-09-05 | Phil Marvin Stricklen | Process for producing polyolefins having a bimodal molecular weight distribution |
JP2894858B2 (en) | 1991-04-05 | 1999-05-24 | 三井化学株式会社 | Ethylene / α-olefin / diene rubber and use thereof |
JP3275211B2 (en) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | Method for producing addition polymerization catalyst |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
GB9125934D0 (en) | 1991-12-05 | 1992-02-05 | Exxon Chemical Patents Inc | Process for polymerising olefinic feeds under pressure |
KR100253826B1 (en) | 1991-12-30 | 2000-04-15 | 그레이스 스티븐 에스. | Ethylene interpolymer polymerizations |
DE69232297T2 (en) | 1992-01-06 | 2002-08-14 | Dow Chemical Co | catalyst composition |
EP0552945B1 (en) | 1992-01-23 | 1997-05-07 | Mitsui Petrochemical Industries, Ltd. | Process for the preparation of polyolefin |
US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
BE1005795A3 (en) | 1992-05-13 | 1994-02-01 | Solvay | Olefin polymerization process and (co) polymer blocks derivatives at least olefine. |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
CA2117888C (en) | 1992-06-15 | 2001-05-15 | Howard William Turner | High temperature polymerization process using ionic catalysts to produce polyolefins |
JPH08501325A (en) | 1992-06-18 | 1996-02-13 | スペリレーネ エッセ.アール.エッレ. | Ethylene polymer manufacturing method |
WO1994000500A1 (en) | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
NL9201970A (en) | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenyl compounds and catalyst components for the polymerization of olefins. |
US5464905A (en) * | 1992-11-19 | 1995-11-07 | Mitsui Petrochemical Industries, Ltd. | Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
PT681592E (en) | 1993-01-29 | 2001-01-31 | Dow Chemical Co | ETHYLENE INTERPOLIMERIZATIONS |
US6313240B1 (en) | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
WO1995000526A1 (en) | 1993-06-24 | 1995-01-05 | The Dow Chemical Company | Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom |
WO1995016716A1 (en) | 1993-12-14 | 1995-06-22 | Exxon Chemical Patents Inc. | Process for producing elastomers with an indenyl metallocene catalyst system |
MX9500982A (en) | 1994-02-17 | 1997-02-28 | Union Carbide Chem Plastic | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture. |
US5486632A (en) | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
DE4432798A1 (en) | 1994-09-15 | 1996-03-21 | Basf Ag | Highly flexible propylene-ethylene copolymers |
US5677382A (en) | 1994-12-19 | 1997-10-14 | Japan Synthetic Rubber Co., Ltd. | Ethylene-α-olefin-non-conjugated diene copolymer rubber composition |
TW383314B (en) | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer |
US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
EP0743066A3 (en) | 1995-05-16 | 1998-09-30 | Mitsui Pharmaceuticals, Inc. | Wound-healing agent |
-
1996
- 1996-07-12 US US08/679,538 patent/US6545088B1/en not_active Expired - Lifetime
-
1997
- 1997-07-09 NZ NZ332880A patent/NZ332880A/en unknown
- 1997-07-09 PL PL97331038A patent/PL331038A1/en unknown
- 1997-07-09 AT AT97934156T patent/ATE200680T1/en active
- 1997-07-09 CN CN97195993A patent/CN1098289C/en not_active Expired - Lifetime
- 1997-07-09 EP EP97934156A patent/EP0910593B1/en not_active Expired - Lifetime
- 1997-07-09 TR TR1999/00050T patent/TR199900050T2/en unknown
- 1997-07-09 ES ES97934156T patent/ES2156001T3/en not_active Expired - Lifetime
- 1997-07-09 CZ CZ9994A patent/CZ9499A3/en unknown
- 1997-07-09 CA CA002256668A patent/CA2256668C/en not_active Expired - Lifetime
- 1997-07-09 AU AU37279/97A patent/AU718342B2/en not_active Ceased
- 1997-07-09 HU HU9904354A patent/HUP9904354A3/en unknown
- 1997-07-09 KR KR10-1999-7000204A patent/KR100496101B1/en not_active IP Right Cessation
- 1997-07-09 WO PCT/US1997/012294 patent/WO1998002471A1/en active IP Right Grant
- 1997-07-09 JP JP10506243A patent/JP2000514857A/en active Pending
- 1997-07-09 DE DE69704617T patent/DE69704617T2/en not_active Expired - Lifetime
- 1997-07-09 BR BR9710347A patent/BR9710347A/en not_active Application Discontinuation
- 1997-07-11 TW TW086109819A patent/TW341576B/en active
-
1999
- 1999-01-11 NO NO990095A patent/NO990095L/en not_active Application Discontinuation
Also Published As
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BR9710347A (en) | 1999-08-17 |
JP2000514857A (en) | 2000-11-07 |
CZ9499A3 (en) | 1999-03-17 |
AU718342B2 (en) | 2000-04-13 |
NO990095D0 (en) | 1999-01-11 |
EP0910593B1 (en) | 2001-04-18 |
PL331038A1 (en) | 1999-06-21 |
WO1998002471A1 (en) | 1998-01-22 |
US6545088B1 (en) | 2003-04-08 |
TW341576B (en) | 1998-10-01 |
HUP9904354A2 (en) | 2000-04-28 |
ATE200680T1 (en) | 2001-05-15 |
CN1098289C (en) | 2003-01-08 |
DE69704617D1 (en) | 2001-05-23 |
DE69704617T2 (en) | 2001-08-02 |
TR199900050T2 (en) | 1999-03-22 |
EP0910593A1 (en) | 1999-04-28 |
KR100496101B1 (en) | 2005-06-17 |
NZ332880A (en) | 2000-07-28 |
AU3727997A (en) | 1998-02-09 |
CA2256668C (en) | 2006-08-22 |
ES2156001T3 (en) | 2001-06-01 |
CN1223670A (en) | 1999-07-21 |
KR20000023740A (en) | 2000-04-25 |
NO990095L (en) | 1999-01-12 |
HUP9904354A3 (en) | 2000-05-29 |
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