CA2263266A1 - A process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling - Google Patents
A process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial foulingInfo
- Publication number
- CA2263266A1 CA2263266A1 CA002263266A CA2263266A CA2263266A1 CA 2263266 A1 CA2263266 A1 CA 2263266A1 CA 002263266 A CA002263266 A CA 002263266A CA 2263266 A CA2263266 A CA 2263266A CA 2263266 A1 CA2263266 A1 CA 2263266A1
- Authority
- CA
- Canada
- Prior art keywords
- alkaline earth
- earth metal
- alkali
- metal hypobromite
- hypobromite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/20—Oxygen compounds of bromine
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
- C02F1/766—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/11—Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/04—Surfactants, used as part of a formulation or alone
Abstract
The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:
a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;
b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;
c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and, d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;
b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;
c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and, d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/904,375 | 1997-08-01 | ||
US08/904,375 US5942126A (en) | 1997-01-03 | 1997-08-01 | Process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling |
PCT/US1998/015133 WO1999006320A1 (en) | 1997-08-01 | 1998-07-22 | A process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2263266A1 true CA2263266A1 (en) | 1999-02-11 |
CA2263266C CA2263266C (en) | 2009-03-10 |
Family
ID=25419041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002263266A Expired - Fee Related CA2263266C (en) | 1997-08-01 | 1998-07-22 | A process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling |
Country Status (17)
Country | Link |
---|---|
US (2) | US5942126A (en) |
EP (1) | EP0929500A1 (en) |
JP (1) | JP2001501869A (en) |
KR (1) | KR100567235B1 (en) |
CN (1) | CN1126713C (en) |
AR (1) | AR016580A1 (en) |
AU (1) | AU8506098A (en) |
BR (1) | BR9806044A (en) |
CA (1) | CA2263266C (en) |
CO (1) | CO5060540A1 (en) |
ID (1) | ID21776A (en) |
MY (1) | MY122300A (en) |
NO (1) | NO990679L (en) |
NZ (1) | NZ334130A (en) |
TW (1) | TW432011B (en) |
WO (1) | WO1999006320A1 (en) |
ZA (1) | ZA986669B (en) |
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US6419879B1 (en) * | 1997-11-03 | 2002-07-16 | Nalco Chemical Company | Composition and method for controlling biological growth using stabilized sodium hypobromite in synergistic combinations |
US8293795B1 (en) | 1998-06-01 | 2012-10-23 | Albemarle Corporation | Preparation of concentrated aqueous bromine solutions and biocidal applications thereof |
US6299909B1 (en) | 1998-06-01 | 2001-10-09 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
US6348219B1 (en) | 1998-06-01 | 2002-02-19 | Albemarle Corporation | Processes for preparing concentrated aqueous liquid biocidal compositions |
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US8414932B2 (en) | 1998-06-01 | 2013-04-09 | Albemarie Corporation | Active bromine containing biocidal compositions and their preparation |
US6068861A (en) * | 1998-06-01 | 2000-05-30 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
US6511682B1 (en) | 1998-06-01 | 2003-01-28 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
US6652889B2 (en) * | 1998-06-01 | 2003-11-25 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation and use |
US6156229A (en) * | 1998-06-29 | 2000-12-05 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
US6123870A (en) * | 1998-06-29 | 2000-09-26 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
WO2000034429A1 (en) * | 1998-12-09 | 2000-06-15 | The Procter & Gamble Company | Aqueous liquid automatic dishwashing detergent composition having bromine and chlorine bleach |
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BR9306779A (en) * | 1992-07-23 | 1998-12-08 | Unilever Nv | Process and apparatus for controlling microorganisms |
US5468377A (en) * | 1993-10-21 | 1995-11-21 | Betz Laboratories, Inc. | Solid halogen feed system |
US5641520A (en) * | 1995-06-07 | 1997-06-24 | Great Lakes Chemical Corporation | Halogen compositions for water treatment |
US6015782A (en) * | 1995-12-07 | 2000-01-18 | The Procter & Gamble Company | Process for manufacturing bleaching compositions |
JPH11506139A (en) * | 1996-03-22 | 1999-06-02 | ナルコ ケミカル カンパニー | Stabilized alkali or alkaline earth metal hypobromite and process for producing the same |
-
1997
- 1997-08-01 US US08/904,375 patent/US5942126A/en not_active Expired - Lifetime
-
1998
- 1998-07-22 BR BR9806044-9A patent/BR9806044A/en not_active IP Right Cessation
- 1998-07-22 NZ NZ334130A patent/NZ334130A/en not_active IP Right Cessation
- 1998-07-22 WO PCT/US1998/015133 patent/WO1999006320A1/en not_active Application Discontinuation
- 1998-07-22 EP EP98935905A patent/EP0929500A1/en not_active Withdrawn
- 1998-07-22 JP JP11510006A patent/JP2001501869A/en not_active Ceased
- 1998-07-22 AU AU85060/98A patent/AU8506098A/en not_active Abandoned
- 1998-07-22 ID IDW990020A patent/ID21776A/en unknown
- 1998-07-22 CA CA002263266A patent/CA2263266C/en not_active Expired - Fee Related
- 1998-07-22 CN CN98800812A patent/CN1126713C/en not_active Expired - Fee Related
- 1998-07-27 ZA ZA986669A patent/ZA986669B/en unknown
- 1998-07-30 CO CO98043531A patent/CO5060540A1/en unknown
- 1998-07-31 AR ARP980103815A patent/AR016580A1/en active IP Right Grant
- 1998-07-31 MY MYPI98003529A patent/MY122300A/en unknown
- 1998-08-01 KR KR1019980031435A patent/KR100567235B1/en not_active IP Right Cessation
- 1998-09-02 TW TW087112661A patent/TW432011B/en not_active IP Right Cessation
-
1999
- 1999-02-12 NO NO990679A patent/NO990679L/en unknown
- 1999-05-05 US US09/305,892 patent/US6136205A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2263266C (en) | 2009-03-10 |
US6136205A (en) | 2000-10-24 |
NZ334130A (en) | 2000-08-25 |
CN1126713C (en) | 2003-11-05 |
US5942126A (en) | 1999-08-24 |
KR100567235B1 (en) | 2006-07-12 |
KR19990023294A (en) | 1999-03-25 |
ID21776A (en) | 1999-07-22 |
CO5060540A1 (en) | 2001-07-30 |
WO1999006320A1 (en) | 1999-02-11 |
MY122300A (en) | 2006-04-29 |
EP0929500A1 (en) | 1999-07-21 |
JP2001501869A (en) | 2001-02-13 |
CN1273560A (en) | 2000-11-15 |
AR016580A1 (en) | 2001-07-25 |
TW432011B (en) | 2001-05-01 |
ZA986669B (en) | 1999-02-04 |
BR9806044A (en) | 1999-09-08 |
NO990679L (en) | 1999-06-01 |
NO990679D0 (en) | 1999-02-12 |
AU8506098A (en) | 1999-02-22 |
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